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    Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling
    Helium Isotopes in Nature
    Ebook series2 titles

    Developments in Geochemistry Series

    By Luigi Marini, B.A. Mamyrin, Bjorn O. Mysen and

    ()

    About this series

    The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates.

    Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises.

    Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer.

    * Provides applications for investigating and predicting geological carbon dioxide sequestration
    * Reviews the geochemical literature in the field
    * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration
    LanguageEnglish
    PublisherElsevier Science
    Release dateOct 22, 2013
    Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling
    Helium Isotopes in Nature

    Titles in the series (2)

    • 3

      Helium Isotopes in Nature
      Helium Isotopes in Nature

      Helium Isotopes in Nature

      B.A. Mamyrin
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      0 ratings

      Developments in Geochemistry, Volume 3: Helium Isotopes in Nature presents the isotopic investigations of noble gases. This book describes the origin, the history, and the contemporary distribution of isotopes of helium. Organized into 11 chapters, this volume begins with an overview of mass-spectrometric methods and measurements of the helium isotope abundance. This text then discusses the methods of collecting various terrestrial samples as well as the apparatus for helium extraction, volumetric measurements, and purification. Other chapters consider the isotope composition of primordial, radiogenic, and spallogenic light noble gases. This book discusses as well the origin and distribution of helium isotopes in meteorites, in the Earth's mantle, the crust and ocean, and in the atmosphere. The final chapter deals with the scientific and applied problems that can be resolved to the progress in helium isotope geochemistry. This book is a valuable resource for scientists. Research workers and students interested in the geochemistry of helium will also find this book useful.

      Developments in Geochemistry, Volume 3: Helium Isotopes in Nature presents the isotopic investigations of noble gases. This book describes the origin, the history, and the contemporary distribution of isotopes of helium. Organized into 11 chapters, this volume begins with an overview of mass-spectrometric methods and measurements of the helium isotope abundance. This text then discusses the methods of collecting various terrestrial samples as well as the apparatus for helium extraction, volumetric measurements, and purification. Other chapters consider the isotope composition of primordial, radiogenic, and spallogenic light noble gases. This book discusses as well the origin and distribution of helium isotopes in meteorites, in the Earth's mantle, the crust and ocean, and in the atmosphere. The final chapter deals with the scientific and applied problems that can be resolved to the progress in helium isotope geochemistry. This book is a valuable resource for scientists. Research workers and students interested in the geochemistry of helium will also find this book useful.

    • 11

      Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling
      Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling

      Geological Sequestration of Carbon Dioxide: Thermodynamics, Kinetics, and Reaction Path Modeling

      Luigi Marini
      0 ratings
      0 ratings

      The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

      The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

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