Code No.

34

Total No. of Questions : 39 ]

[ Total No. of Printed Pages : 15

June, 2008

CHEMISTRY
( Kannada and English Versions )
Time : 3 Hours 15 Minutes ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O.

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR
x@ 5 40 - D Y D 1 10

D 2
Y XR x@ 5 10

B, C

Y XRR W

O.
iv)

WY XR O R .

- A
:

1.

i)

ii)

XR Y WY OR
. X XR O.
10 1 = 10

10

XRR O.

y Y _R
R .
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Code No. 34

Y W @ PR R .

2.

3d

3.

^ R .

4.

( NH3) V XWY XR .

5.

ZX XXY

( Spontaneous process )

|X

}O ?
6.

Y \O P

7.

( Dispersed phase )

( Ethylamine )

X Y

( Nitrous acid )

SO R .
8.

( Polysaccharide ) ?

9.

@ x@

10.

( Drying oil )

( Glycine )

}R x.

ZX R .

- B
:

i)

O XRR O.

ii)

X XR R O.
10 2 = 20

11.

W xX @ Zx] ( Cr2O3)
R YW x\ .

O .

3
12.

X yY ( H2SO4)

Code No. 34

y Y

O ? R .
13.

( d-Yy )

Z OR O. XO

yR .
14. K4 [ Fe(CN)6]

Y U }y zW

( EAN )

.
15.

X X

123 102 s1

Q,

X ( Half-life ) R @ .
16.

xR X WZWR
electrolytes )

( Strong and weak

i)

H2 S

ii)

CH3 COONa

iii)

KNO3

iv)

NH4 OH

17.

O X WWR .

18.

WZW

( Weak electrolytes )

ZL O R

x\.
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Code No. 34

19.

E X XWY. R .

20.

y X ( Racemic mixture ) ? } x.

21.

R ?

22.

xY]R } ?

X W R

- C
I.

xY XR O :
23. a)

2 5 = 10

xX| | xX| ( K2Cr2O7) R S

R . x@ R .

b)

x O R :
Pt NH Br Cl

(
3 ) 4
2
2

24. a)

25. a)

b)

O Pt( NH3) 4Cl2

Br2 . 1

UR QM Y

b)

(ii)

(iii)

(i)

J S Y

XR .

R .

QM Y [ Fe(CN)6] 4

, y

O @ R .

Y XK R .

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II.

Code No. 34

xY XR O :
26. a)

b)

27. a)

b)

28. a)

b)

( Cumene )

y Y

PCl5

3 5 = 15

R S R . 3
O ?

R .

xY X X WR .

y X ? R . 2
-Yx

W XR .

( Postulates )

QM

( Baeyers Strain theory )

R .

|] X B } .

b)

QMR .

c)

29. a)

( Dehydrohalogenation )

XY

y ( Reagent ) ?
III.

xY XR O :
30. a)

b)

3 5 = 15

X X R SR.

y T X{WR WzW.

1
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Code No. 34
31. a)

b)

32. a)

b)

33. a)

X Y 182 X R 50C Y
S OY 660 Pa x ( Lowering of vapour
pressure ). 50C Y QM S O 12260 Pa
QY R .
3
100

yxX xY
zWR @ .
X
|O ?

( Body centered cubic unit cell )

( Brownian movement )

01 M NH4 OH
pOH

015 M NH4 Cl

X X

R @ .

( NH4OHP =18 10

34. a)

Y ( Lewis acid ) ?

298 K

Y X

Q,
Y JO O }R
2
) @ .

(
b)

W } O QM ZR
XWY WR OE B .
3

b)

Kp

106 105

Go

WX X ? WX X
OR .
3

- D
D 1
IV.

xY XR O :
35. a)

QM

( molecular orbital theory )

( Assumptions )

1 10 = 10

@
4

7
b)

Code No. 34

] { XW ? ]Y J J
Y ?

c)

xU XR .

d)

0001 M HNO3

XY [ H+] O [ OH] R @ .

36. a)

x R WzW :
i)

ii)

b)

W X X ? }R x.

c)

Li2

W J x\R

XR @ , @ R

d)

( Magnetic property )

xR{ X X WR .

D 2
V.

xY XR O :
37. a)

b)

p-X|R

2 5 = 10

XY

O ?

| x\R .

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Code No. 34
38.

| T| O | XY
X N }R XR .

39.

X | xX| X R
T| XY T| }R
XY xR :
i)

X R .

ii)

T| XWR .

iii)

XY ?

iv)

X WY N } ?

2+1+1+1

Code No. 34

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks. Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In Part D D 1

carries 10 marks and D 2

carries

10marks. Each question of D2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the 10 questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

Name the metal used in the desilverization of lead by Parkes process.

2.

Name the transition metal in 3d series which shows maximum oxidation

state.

3.

Write Arrhenius equation.

4.

Write the formula of conjugate base of NH3 .

5.

How does entropy of universe vary in a spontaneous process ?

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Code No. 34

10

6.

What is the dispersed phase present in milk ?

7.

Name the gas liberated when ethylamine reacts with nitrous acid.

8.

What is a polysaccharide ?

9.

Give an example for a drying oil.

10. Write the Zwitterion structure of Glycine.

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. With the help of Ellingham diagram explain, why Aluminium is used as a
reducing agent for Chromium sesquioxide ( Cr2O 3) .

12. How does conc. H2 SO4 react with Formic acid ? Write the equation.

13. Mention two reasons for the formation of co-ordinate compounds by

transition metals ( d-block elements ).

14. Calculate the EAN of Iron in K4 [ Fe(CN)6] .

15. The rate constant for a first order reaction is 123 102 s1 . Calculate
the half-life period of the reaction.

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Code No. 34

16. Classify the following into strong and weak electrolytes :

i)

H2 S

ii)

CH3 COONa

iii)

KNO3

iv)

NH4 OH.

17. Write any two differences between ideal and non-ideal solutions.
18. Derive Ostwalds dilution law for weak electrolytes.
19. Explain why methylamine is a stronger base than ammonia.
20. What is a racemic mixture ? Give one example.
21. How do you convert methane to ethane ?
22. What is Clemmensens reduction ? Write its general equation.

PART C
I.

Answer any two of the following questions :

23. a)

b)

2 5 = 10

Explain the manufacture of potassium dichromate ( K2Cr2O 7 )

from chromite. Write the equations involved.

Name the type of isomerism exhibited by the following pair :

Pt NH Br Cl

(
3 ) 4
2
2

and

Pt NH Cl Br

(
3 ) 4
2
2 .
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Code No. 34
24. a)

12
Explain the reactions taking place in the extraction of cast iron
at (i) zone of combustion, (ii)

b)
25. a)

II.

b)

27. a)

b)

zone of
3

Write two uses of Helium.

Explain the formation, geometry and magnetic property of

4

on the basis of valence bond theory.

Name the noble gas that does not occur in air.

Answer any three of the following questions :

26. a)

(iii)

slag formation of blast furnace.

[ Fe(CN)6]
b)

zone of reduction,

1
3 5 = 15

How is phenol manufactured by cumene process ?

How does acetic acid react with PCl5 ? Write the equation.

Explain the mechanism of chlorination of benzene.

What is carbylamine reaction ? Write the chemical equation

involved.

Write the Haworth structure of -glucose.

Write the postulates of Baeyers Strain theory.

Explain Wurtz reaction with an example.

b)

Explain refining of oil.

c)

Name the reagent used for dehydrohalogenation reaction.

28. a)

b)
29. a)

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Code No. 34

III. Answer any three of the following questions :

30. a)

b)
31. a)

3 5 = 15

Derive an expression for the velocity constant of a first order

reaction.

Define radius ratio in an ionic crystal.

182 g of urea is dissolved in 100 g of water at 50C. The

lowering of vapour pressure produced is 660 Pa. The vapour
pressure of pure water at 50C is 12260 Pa. Calculate the
molecular weight.

b)

32. a)
b)

Calculate the number of particles present in a body centered

cubic unit cell.

What is Brownian movement ? How is it caused ?

Explain the application of common ion effect and principles of

solubility product in the precipitation of second group Basic
radicals.

33. a)

A buffer solution contains 01 M NH4 OH and 015 M NH4 Cl.

Calculate the pOH of the buffer solution.

( DissociationconstantofNH4OH=18 10
b)
34. a)

What is a Lewis acid ?

The value of equilibrium constant Kp
be 106 105

b)

4
1

for a reaction is found to

at 298 K. Calculate Go

the same temperature.

of the reaction at
2

What is electrochemical series ? Mention any two applications of

electrochemical series.

3
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Code No. 34

14
PART D
D 1

IV. Answer any one of the following :

35. a)

b)

1 10 = 10

Write any four assumptions of molecular orbital theory.

What is the biological importance of Insulin ? How many amino

acid units are present per molecule in Insulin ?

c)

Explain Kolbes reaction.

d)

Calculate the [ H+]

and

[ OH]

in 0001 M HNO3

solution.
2
36. a)

Define the following terms :

i)

Dialysis

ii)

Tyndall effect.

b)

What is a Pseudo first order reaction ? Give one example.

c)

Write the energy level diagram for the formation of Li2

molecule. What is its bond order ? Predict its magnetic

d)

property.

Explain the mechanism of Cannizzaros reaction.

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Code No. 34

D 2
V.

Answer any two of the following :

37. a)

b)

2 5 = 10

How is p-bromoacetanilide prepared from acetanilide in the

laboratory?

Explain Biuret test.

38. Describe an experiment to study the effect of temperature on the

rate of the reaction between potassium persulphate and potassium
iodide.

39. For the estimation of ferrous ammonium sulphate using standard

potassium dichromate solution
i)

write chemical equation for the reaction involved.

ii)

give the equivalent mass of ferrous ammonium sulphate.

iii)

name the indicator used.

iv)

what is the colour change at the end point ?

2+1+1+1

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