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Action Center Practice Problem Constitutional Isomers and Lewis Structure (Klein: Chapter 1)

Sections Covered: 1.2 - 1.4, 1.10, 1.12 1. Draw the Lewis Dot and Line structures for the following compounds. Include the Formal Charges , if present. CH2O C3H4 NH3 CH3NO2 C2H6 CH3O

2. Draw at least three constitutional isomers with the following molecular formulas: C3H8O C2H4Cl2 C6H12

3. For the following series, orderer the molecules from higher boiling point to lower boiling points and provide a brief explanation for the B.P.s. Consider the intermolecular interactions and spatial structure of the molecules.
N

A)

OH

NH2

OH

34.6C

55.5C

118C

77C

99C

B) 64C 58C 69C 60C 50C

4. Predict the geometry for the central atom in each of the compounds below: BH3 H3C CS2

5. In each of the following, please circle and label each functional group(s). Assume that each contains an alkane functionality.
OH H H O H
H 2N O

O O
Cl

H N

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