Index

1 Input File
2 Solution History
3 Main

Index

Input File
$ Generated by PRO/II Keyword Generation System <version 9.1>
$ Generated on: Thu Oct 03 09:48:57 2013
TITLE
DIMENSION SI, STDTEMP=273.15, STDPRES=101.325
SEQUENCE SIMSCI
CALCULATION TVPBASIS=310.928, RVPBASIS=APIN
COMPONENT DATA
LIBID 1,PROPENE/2,PROPANE, BANK=SIMSCI,PROCESS
ASSAY FIT=ALTERNATE, CONVERSION=API94, CURVEFIT=CURRENT, &
KVRECONCILE=TAILS
THERMODYNAMIC DATA
METHOD SYSTEM=SRK, SET=SRK01, DEFAULT
STREAM DATA
PROPERTY STREAM=S1, TEMPERATURE=325, PRESSURE=2027, PHASE=M, &
RATE(M)=272.2, COMPOSITION(M)=1,0.6/2,0.4
UNIT OPERATIONS
COLUMN UID=T1
PARAMETER TRAY=150,IO
FEED S1,90
PRODUCT OVHD(M)=S2,159.2, BTMS(M)=S3,113
CONDENSER TYPE=BUBB
DUTY 1,1,,CONDENSER
DUTY 2,150,,REBOILER
PRINT PROPTABLE=PART
ESTIMATE MODEL=CONVENTIONAL, RRATIO=3
PRESSURE 1,1931/150,2069
SPEC ID=COL1SPEC1, STREAM=S2, RATE(KGM/H),TOTAL,WET, &
VALUE=159.2
SPEC ID=COL1SPEC2, RRATIO, VALUE=3
VARY DNAME=CONDENSER,REBOILER
REBOILER TYPE=KETTLE
END

Index

Input File
$ Generated by PRO/II Keyword Generation System <version 9.1>
$ Generated on: Thu Oct 03 09:48:57 2013
TITLE
DIMENSION SI, STDTEMP=273.15, STDPRES=101.325
SEQUENCE SIMSCI
CALCULATION TVPBASIS=310.928, RVPBASIS=APIN
COMPONENT DATA
LIBID 1,PROPENE/2,PROPANE, BANK=SIMSCI,PROCESS
ASSAY FIT=ALTERNATE, CONVERSION=API94, CURVEFIT=CURRENT, &
KVRECONCILE=TAILS
THERMODYNAMIC DATA
METHOD SYSTEM=SRK, SET=SRK01, DEFAULT
STREAM DATA
PROPERTY STREAM=S1, TEMPERATURE=325, PRESSURE=2027, PHASE=M, &
RATE(M)=272.2, COMPOSITION(M)=1,0.6/2,0.4
UNIT OPERATIONS
COLUMN UID=T1
PARAMETER TRAY=150,IO
FEED S1,90
PRODUCT OVHD(M)=S2,159.2, BTMS(M)=S3,113
CONDENSER TYPE=BUBB
DUTY 1,1,,CONDENSER
DUTY 2,150,,REBOILER
PRINT PROPTABLE=PART
ESTIMATE MODEL=CONVENTIONAL, RRATIO=3
PRESSURE 1,1931/150,2069
SPEC ID=COL1SPEC1, STREAM=S2, RATE(KGM/H),TOTAL,WET, &
VALUE=159.2
SPEC ID=COL1SPEC2, RRATIO, VALUE=3
VARY DNAME=CONDENSER,REBOILER
REBOILER TYPE=KETTLE
END

Index

Solution History
SIMULATION SCIENCES INC.
R
PAGE H-1
PROJECT
PRO/II VERSION 9.1 ELEC V8.2.4
PROBLEM
CALCULATION
HISTORY
10/03/13

*** PROBLEM SOLUTION BEGINS

FEED FLASH COMPLETE
SCALING 0 FACTORS = 1.078E+00 ERROR = 8.439E-05
INNER 0 : E(ENTH+SPEC) = 1.079E-04
ITER 1 E(K) = 0.000E+00 E(ENTH+SPEC) = 1.079E-04 E(SUM) = 3.518E-03
DAMP = 1.000E+00
INNER 0 : E(ENTH+SPEC) = 1.079E-04
CALCULATING NEW MATRIX
INNER 1 : E(ENTH+SPEC) = 1.752E-06 ALPHA = 1.0000
ITER 2 E(K) = 0.000E+00 E(ENTH+SPEC) = 1.752E-06 E(SUM) = 3.023E-03
UNIT 1
SOLVED - 'T1
'
*** PROBLEM SOLUTION REACHED
*** THIS RUN USED 153.44 PRO/II SIMULATION UNITS
*** RUN STATISTICS
STARTED 09:48:04 10/03/13
NO ERRORS
FINISHED 09:48:04 10/03/13
NO WARNINGS
RUN TIMES
NO MESSAGES
INTERACTIVE
0 MIN, 0.00 SEC
CALCULATIONS 0 MIN, 0.45 SEC
TOTAL
0 MIN, 0.45 SEC

Index

Solution History
SIMULATION SCIENCES INC.
R
PAGE H-1
PROJECT
PRO/II VERSION 9.1 ELEC V8.2.4
PROBLEM
CALCULATION
HISTORY
10/03/13

*** PROBLEM SOLUTION BEGINS

FEED FLASH COMPLETE
SCALING 0 FACTORS = 1.078E+00 ERROR = 8.439E-05
INNER 0 : E(ENTH+SPEC) = 1.079E-04
ITER 1 E(K) = 0.000E+00 E(ENTH+SPEC) = 1.079E-04 E(SUM) = 3.518E-03
DAMP = 1.000E+00
INNER 0 : E(ENTH+SPEC) = 1.079E-04
CALCULATING NEW MATRIX
INNER 1 : E(ENTH+SPEC) = 1.752E-06 ALPHA = 1.0000
ITER 2 E(K) = 0.000E+00 E(ENTH+SPEC) = 1.752E-06 E(SUM) = 3.023E-03
UNIT 1
SOLVED - 'T1
'
*** PROBLEM SOLUTION REACHED
*** THIS RUN USED 153.44 PRO/II SIMULATION UNITS
*** RUN STATISTICS
STARTED 09:48:04 10/03/13
NO ERRORS
FINISHED 09:48:04 10/03/13
NO WARNINGS
RUN TIMES
NO MESSAGES
INTERACTIVE
0 MIN, 0.00 SEC
CALCULATIONS 0 MIN, 0.45 SEC
TOTAL
0 MIN, 0.45 SEC

Index

Tray

Temperature
K

Pressure
kPa

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45

321.5312139
321.7262984
321.8878725
322.0215949
322.1325409
322.2250505
322.3027558
322.3686476
322.4251586
322.4742487
322.5174858
322.5561169
322.5911296
322.6233035
322.6532524
322.6814587
322.7083006
322.7340748
322.7590133
322.7832977
322.8070701
322.8304412
322.8534979
322.8763079
322.8989238
322.921387
322.9437297
322.965977
322.9881483
323.0102591
323.032321
323.0543436
323.0763338
323.0982973
323.1202386
323.142161
323.164067
323.1859589
323.207838
323.2297058
323.2515631
323.2734106
323.295249
323.3170786
323.3388999

1931
1931.926174
1932.852349
1933.778523
1934.704698
1935.630872
1936.557047
1937.483221
1938.409396
1939.33557
1940.261745
1941.187919
1942.114094
1943.040268
1943.966443
1944.892617
1945.818792
1946.744966
1947.671141
1948.597315
1949.52349
1950.449664
1951.375839
1952.302013
1953.228188
1954.154362
1955.080537
1956.006711
1956.932886
1957.85906
1958.785235
1959.711409
1960.637584
1961.563758
1962.489933
1963.416107
1964.342282
1965.268456
1966.194631
1967.120805
1968.04698
1968.973154
1969.899329
1970.825503
1971.751678

46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97

323.360713
323.3825181
323.4043155
323.4261052
323.4478873
323.4696618
323.491429
323.5131886
323.5349409
323.5566859
323.5784234
323.6001537
323.6218766
323.6435922
323.6653004
323.6870014
323.7086951
323.7303815
323.7520606
323.7737324
323.7953969
323.8170542
323.8387042
323.8603469
323.8819824
323.9036106
323.9252316
323.9468453
323.9684518
323.990051
324.0116431
324.0332279
324.0548055
324.0763759
324.0979391
324.119495
324.1410438
324.1625854
324.1841199
324.2056471
324.2271672
324.2486801
324.2701858
324.2916844
324.3131758
324.334736
324.356289
324.3778346
324.3993729
324.4209038
324.4424276
324.463944

1972.677852
1973.604027
1974.530201
1975.456376
1976.38255
1977.308725
1978.234899
1979.161074
1980.087248
1981.013423
1981.939597
1982.865772
1983.791946
1984.718121
1985.644295
1986.57047
1987.496644
1988.422819
1989.348993
1990.275168
1991.201342
1992.127517
1993.053691
1993.979866
1994.90604
1995.832215
1996.758389
1997.684564
1998.610738
1999.536913
2000.463087
2001.389262
2002.315436
2003.241611
2004.167785
2005.09396
2006.020134
2006.946309
2007.872483
2008.798658
2009.724832
2010.651007
2011.577181
2012.503356
2013.42953
2014.355705
2015.281879
2016.208054
2017.134228
2018.060403
2018.986577
2019.912752

98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149

324.4854532
324.5069551
324.5284498
324.5499374
324.5714178
324.5928911
324.6143573
324.6358166
324.6572689
324.6787144
324.7001532
324.7215853
324.7430111
324.7644306
324.7858442
324.8072522
324.828655
324.8500531
324.8714473
324.8928383
324.9142275
324.9356161
324.9570063
324.9784004
324.9998021
325.0212156
325.0426469
325.0641039
325.0855972
325.1071408
325.1287534
325.1504603
325.1722953
325.1943037
325.2165464
325.2391052
325.2620901
325.2856488
325.3099802
325.3353514
325.3621218
325.3907745
325.4219595
325.4565504
325.4957218
325.5410533
325.5946674
325.6594167
325.7391323
325.8389551
325.9657724
326.1287846

2020.838926
2021.765101
2022.691275
2023.61745
2024.543624
2025.469799
2026.395973
2027.322148
2028.248322
2029.174497
2030.100671
2031.026846
2031.95302
2032.879195
2033.805369
2034.731544
2035.657718
2036.583893
2037.510067
2038.436242
2039.362416
2040.288591
2041.214765
2042.14094
2043.067114
2043.993289
2044.919463
2045.845638
2046.771812
2047.697987
2048.624161
2049.550336
2050.47651
2051.402685
2052.328859
2053.255034
2054.181208
2055.107383
2056.033557
2056.959732
2057.885906
2058.812081
2059.738255
2060.66443
2061.590604
2062.516779
2063.442953
2064.369128
2065.295302
2066.221477
2067.147651
2068.073826

150
Stream (Summary)

Name
Description
Phase
Thermodynamic System
Total Molar Rate
Total Mass Rate
Temperature
Pressure
Total Molecular Weight
Total Specific Enthalpy
Total Cp
Total Molar Component Rates

326.3401582
UOM

kg-mol / hr
kg / hr
K
kPa
kJ / kg
kJ / kg K
kg-mol / hr

PROPENE
PROPANE
Total Molar Component Fractions

PROPENE
PROPANE
Vapor Molar Rate
Vapor Mass Rate
Vapor Molecular Weight
Vapor Mole Fraction
Vapor Specific Enthalpy
Vapor CP
Vapor Composition

PROPENE
PROPANE
Total Liquid Molar Rate
Total Liquid Mass Rate
Total Liquid Molecular Weight
Total Liquid Mole Fraction
Total Liquid Specific Enthalpy
Total Liquid CP
Total Liquid Composition

fraction

kg-mol / hr
kg / hr
fraction
kJ / kg
kJ / kg K
fraction

PROPENE
PROPANE
Liqud Molar Rate
Liquid Cp
Liquid Molecular Weight
Liquid Mole Fraction
Liquid Molar Enthalpy
Liquid Composition

PROPENE
PROPANE

0.6
0.4
272.2
11673.83898
42.88699112
1
424.1173067
2.255733803
0.6
0.4

kg-mol / hr

kg-mol / hr
kg / hr
fraction
kJ / kg
kJ / kg K
fraction

PROPENE
PROPANE
Total Liquid Component Rate

S1

S1
S1
Vapor
SRK01
272.2
11673.83898
325
2027
42.88699112
424.1173067
2.255733803
163.32
108.88

PROPENE
PROPANE
Vapor Component Rate

2069

163.32
108.88
0
0
N/A
0
N/A
N/A
N/A
N/A

kg-mol / hr

kg-mol / hr
kJ / kg K
fraction
kJ / kg-mol
fraction

N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A

Liquid Component Rate

PROPENE
PROPANE
Decant Water Mole Rate
Decant Water Moleculat Weight
Water Mole Fraction
Decant Water Molar Enthalpy
Decant Water Cp
Liquid1 Mole Rate
Liquid1 Mole Frac
Liquid1 Molecular Weight
Liquid1 Molar Enthalpy
Liquid1 Cp
Liquid1 Composition

kg-mol / hr

kg-mol / hr
fraction
kJ / kg-mol
kJ / kg K
kg-mol / hr
fraction
kJ / kg-mol
kJ / kg K
fraction

PROPENE
PROPANE
Liquid1 Component Rate

PROPENE
PROPANE
Liquid2 Mole Rate
Liquid2 Mole Frac
Liquid2 Molecular Weight
Liquid2 Molar Enthalpy
Liquid1 Cp
Liquid2 Composition

N/A
N/A
kg-mol / hr

kg-mol / hr
fraction
kJ / kg-mol
kJ / kg K
fraction

PROPENE
PROPANE
Liquid2 Component Rate

PROPENE
PROPANE

N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A

N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A

kg-mol / hr
N/A
N/A

Column T1 Profile Summary

Net Liq. Rate
kg-mol / hr

Net Vap. Rate

kg-mol / hr

477.6003076
477.93181
478.2115091
478.4508288
478.658925
478.8428321
479.0079882
479.1586118
479.2979815
479.4286453
479.5525829
479.6713256
479.7860569
479.8976861
480.0069083
480.1142538
480.220124
480.3248232
480.428581
480.5315708
480.6339246
480.7357438
480.8371061
480.9380746
481.0386985
481.1390204
481.2390756
481.338895
481.4385055
481.5379332
481.6372003
481.7363274
481.835335
481.9342399
482.0330599
482.1318101
482.2305044
482.3291563
482.4277776
482.5263791
482.6249708
482.7235622
482.8221605
482.9207738
483.0194081

0
636.8004097
637.1319125
637.4116116
637.6509313
637.8590275
638.0429346
638.2080907
638.3587144
638.498084
638.6287478
638.752685
638.8714282
638.9861594
639.0977886
639.2070108
639.314356
639.4202266
639.5249257
639.6286835
639.7316734
639.8340271
639.9358463
640.0372086
640.1381771
640.238801
640.339123
640.4391781
640.5389971
640.638608
640.7380357
640.8373025
640.9364299
641.0354375
641.1343424
641.2331624
641.3319126
641.430607
641.5292588
641.6278798
641.7264816
641.8250734
641.9236644
642.022263
642.1208764

Feed To Tray
kg-mol / hr

Product From Tray

kg-mol / hr

159.2001025

483.1180693
483.216763
483.315493
483.4142636
483.513079
483.6119414
483.710854
483.8098187
483.9088381
484.0079137
484.1070469
484.2062392
484.3054915
484.4048051
484.5041802
484.6036176
484.703118
484.8026818
484.9023089
485.0019997
485.1017546
485.2015736
485.3014567
485.4014039
485.5014148
485.6014894
485.7016277
485.8018294
485.9020944
486.0024217
486.1028117
486.2032636
486.3037763
486.4043502
486.5049839
486.6056766
486.7064273
486.8072352
486.9080989
487.009017
487.1099887
487.2110119
487.3120862
487.4132102
486.5423231
486.6619151
486.781659
486.9015631
487.021631
487.1418649
487.2622655
487.3828316

642.2195106
642.3181718
642.4168655
642.5155955
642.6143662
642.7131815
642.812044
642.9109561
643.0099212
643.1089406
643.2080162
643.3071494
643.4063417
643.505594
643.6049076
643.7042827
643.8037201
643.9032205
644.0027839
644.1024114
644.2021022
644.3018572
644.4016762
644.5015592
644.601506
644.7015173
644.8015919
644.9017302
645.0019319
645.1021966
645.2025242
645.3029142
645.4033657
645.5038788
645.6044527
645.7050864
645.8057788
645.9065298
646.0073377
646.1082014
646.2091195
646.3100912
646.4111144
646.5121888
646.6133128
373.5424256
373.6620176
373.7817616
373.9016653
374.0217332
374.1419675
374.2623677

272.2

487.5035627
487.6244564
487.7455104
487.8667228
487.9880899
488.1096086
488.231275
488.3530842
488.475031
488.5971088
488.71931
488.8416262
488.9640467
489.0865594
489.2091502
489.3318032
489.4545002
489.5772196
489.6999374
489.8226276
489.9452605
490.0678034
490.1902214
490.3124771
490.4345311
490.5563429
490.6778728
490.7990812
490.9199328
491.0403992
491.1604592
491.2801063
491.3993509
491.5182272
491.6367997
491.755171
491.8734922
491.9919739
492.1109003
492.2306453
492.3516942
492.4746695
492.6003649
492.7297914
492.864237
493.0053498
493.1552524
493.3167023
493.4933129
493.6898725
493.9127935
494.0247391

374.3829342
374.5036652
374.6245586
374.745613
374.8668253
374.9881925
375.1097112
375.2313775
375.3531868
375.4751335
375.5972113
375.7194126
375.8417287
375.9641489
376.0866616
376.2092527
376.3319058
376.4546028
376.5773218
376.70004
376.8227302
376.9453627
377.0679056
377.190324
377.3125796
377.4346333
377.5564454
377.677975
377.7991834
377.9200354
378.0405014
378.1605618
378.2802089
378.3994535
378.5183298
378.6369019
378.7552735
378.8735947
378.9920765
379.1110028
379.2307478
379.3517964
379.4747717
379.6004675
379.729894
379.8643396
380.005452
380.1553549
380.3168045
380.4934154
380.6899751
380.9128961

112.9998975

381.0248417

S2

S3

S2
S2
Liquid
SRK01
159.2001025
6801.113822
321.5312139
1931
42.72053672
137.4415295
3.421320419

S3
S3
Liquid
SRK01
112.9998975
4872.725161
326.3401582
2069
43.1215007
155.2007617
3.595636848

108.6654622
50.53464025

54.65453778
58.34535973

0.68257156
0.317428441
N/A
N/A
N/A
0
N/A
N/A

0.483668915
0.516331085
N/A
N/A
N/A
0
N/A
N/A

N/A
N/A

N/A
N/A

N/A
N/A
159.2001025
6801.113822
42.72053672
1
137.4415295
3.421320419

N/A
N/A
112.9998975
4872.725161
43.1215007
1
155.2007617
3.595636848

0.68257156
0.317428441

0.483668915
0.516331085

108.6654622
50.53464025
N/A
N/A
N/A
N/A
N/A

54.65453778
58.34535973
N/A
N/A
N/A
N/A
N/A

N/A
N/A

N/A
N/A

112.9998975

N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
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Heater Duty
kJ / hr

-7710232.716

4448605.738