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64

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65

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66

O
4.6

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EPTHEI AKHEI
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6.
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;
;
;
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;
;
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TOXOI

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2
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5

67

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68

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69

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70

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.
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EPTHEI AKHEI
1. ;
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3. I
.
I
II
i.
. C
ii.
. SiO2
iii.
. Na2CO3
iv.
. CaO
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5. ;
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8. , ;

TOXOI

1
2
3

3
3
3
3
3

71

T
OI EHNIKOI INITE KAI H YMBOH TOY
THN APAH HEKTPIKH ENEPEIA
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72

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73

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74

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17
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, ,
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75

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, , , .
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Y : AgNO3
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76

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: .
EPTHEI AKHEI
1. . ;
. .
2. .
3. Na+(aq) Cl-(aq).
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;

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1
1
2

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77

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78

4. ,
.
Fe(s) + Cu2+(aq) Fe2+(aq) + Cu(s).
5. ,
.
6.
T
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80

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81

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102

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83

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86

O
TOXOI

EPTHEI AKHEI
1. . O X;
. ;
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87

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88

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90

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EPTHEI AKHEI
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TOXOI

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1, 2, 4
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6, 7, 8

95

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96

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98

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.
2. N :

TOXOI

T ..... ..... .
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101

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EPTHEI AKHEI
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2. . ;
. N .
3. ;
4. ;
5. . ;
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8. N I II III
I
II
III

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9. T ;
10. . T ;
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11. N .

TOXOI

2
3
5

4
4,5

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7
7

107

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2 .
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A
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Z .

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K
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110

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pH 4,5, pH
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pH
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B
American Chemical Society, Chemistry in Context, McGraw-Hill HE, 2000.
Atkins-Beran, General Chemistry, W.H. Freeman, 1990.
Atkins-Jones, Chemical Principles, W.H.Freeman & Co, 2000.
Atkins, T , K, 1995.
Baeza D., Fisica Y Quimica, EDITORIAL TEIDE, 1995.
B A.., X , T, 1992.
B A.., H X, T, 1994.
B A.., M X, Z, 1995.
B, T T, I 1982.
Carey F, Organic Chemistry, McGraw-Hill, 2000.
, B, 1980.
..., X , OEB, 1998.
Chadwick, Chemistry, G. Allen & Unwin Ltd, 1997.
Chang R., Chemistry, Mc Graw-Hill, 1996.
Chang R., Essential Chemistry, McGraw Hill, 2000.
Clank J., Longman GCSE Chemistry, Longman, 2003.
Clayden J., Organic Chemistry, Oxford, 2000.
Conquest N., Chemistry, Hodder Gibson, 1999.
Ebbing-Gammon, X, TPAYO, 2002.
Emsley J., Natures Building Blocks, OXFORD, 2003.
Gallart..., CIENCIES DE LA NATURALESA-CREDIT 7, Mc Graw-Hill, 2000.
Harvey D., Modern Analytical Chemistry, Mc Graw-Hill, 2000.
Herd Sandy, ..., Chemistry Leckie & Leckie, 2000.
Hill J., Kolb D., Chemistry for Changing Times, Prentice Hall, 2001.
Hill G., Chemistry counts, Hodder & Stoughton, 1986.
Hill G. & Holman, Chemistry in Context, Nelson, 1995.
Leicester H., I X, T, 1993.
Lister-Renshaw, Understanding Chemistry, S. Thornes Ltd, 1991.
M M., X, , 1998.
Mc Quarie-Rock, General Chemistry, Freeman, 1991.
Moore J., Chemistry for Dummies, Willey, 2003.
Murray, Principles of organic Chemistry, Heinemann Ed., 1977.
Salters Advanced Chemistry, Chemical Storylines, Heinemann, 2000.
Salters Advanced Chemistry Chemical Ideas, Heinemann, 2000.
Sancez D., ..., Fisica i Quimica, Grup Promotor Santillana, 2000.
Stengers I-Bensaude-Vincent B., I X, T, 1999.
T..., X, MAIAPH, 2003.
Yurkanis, Organic Chemistry, Prentice-Hall, 1992.

111

M E K , O
E B
. T ,
. K

7
N 1129 15/21 M 1946 (EK 1946, 108, A).

A ,
(copyright), ,
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