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Chapter 3 Outline
Atoms: The Building Blocks of Matter
1. Democritus first coins the idea of the world being made up of atoms1 ; Aristotle
later presents his view (not believing in atoms); is accepted for 2000 years
2. In the 1790s, a new emphasis on the quantitative analysis of chemical reactions
sprung up; basic laws were established
a. Law of conservation of mass states that mass is neither created nor
destroyed during ordinary chemical reactions or physical changes
b. Law of definite proportions states that a chemical compound contains
the same elements in exactly the same proportions by mass regardless of
the size of the sample or source of the compound
c. Law of multiple proportions states that if two or more different
compounds are composed of the same two elements, then the ratio of the
masses of the second element combined with a certain mass of the first
element is always a ratio of small whole numbers.
3. Modern atomic theory; based on John Dalton’s atomic theory
a. All matter is composed of extremely small particles called atoms.
b. Atoms of a given element are identical in size, mass, and other
properties; atoms of different elements differ in size, mass, and other
properties.
c. Atoms can be subdivided into smaller particles.
d. Atoms of different elements combine in simple whole-number ratios
to form chemical compounds.
e. In chemical reactions, atoms are combined, separated, or rearranged.
1
A Greek word meaning “indivisible”.
Chapter 3 Outline
Atoms: The Building Blocks of Matter
1. An atom is the smallest particle of an element that retains the chemical properties
of that element
a. Nucleus (very small, central region)
i. Protons and neutrons (positively charged/uncharged particles)
b. Electrons (negatively charged particles)
c. Electrons, neutrons and protons are collectively called subatomic particles
2. The CRT experiments of the 1700s / 1800s led to the discovery of electrons
a. It was concluded that because the cathode rays were deflected away from
a negatively charged object (the negative end of a magnet) the particles of
the cathode were negatively charged
b. Thomson repeated these experiments various times, with different
size/material cathodes; all particles were always negatively charged
c. Named electrons
d. Because cathode rays have identical properties regardless of the element
used to produce them, it was concluded that electrons are present in the
atoms of all elements
3. 1909 American experiments investgated the charge of the electron
a. The mass of the electron is about one two-thousandth (1/.002) the mass of
the simplest type of hydrogen atom2
b. There had to be other particles making up an atom
i. Because electrons have so much less mass than atoms, atoms must
contain other particles that account for most of their mass
ii. Atoms are neutral, so positively charged particles must equate the
negative charge of electrons
4. J.J. Thomson suggests the plum pudding model of the atom
a. Spreads negative electrons evenly throughout the positive charge of the
rest of the atom
2
Simplest atom known.
Chapter 3 Outline
Atoms: The Building Blocks of Matter