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Compulsory
Unit-IV
Quantum Mechanics and its applications:
MO-VB Theory: Born-Oppenheimer approximation, Hydrogen Molecule ion. LCAO-Mo and
VB treatments of hydrogen molecule.
bonding. Hybridization and valence MOs of H2O, NH3 and CH4 .Huckel pi-electro theory
and its applications to Ethylene, Butadiene and Benzene. Idea of Self-consistent field method.
Reference Books:
1) J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London
2) A. H. Hanney, Solid State Chemistry, A. H. Publications
3) Cullen Dolphin and James, Biological aspects of Inorganic Chemistry
4) Williams, An Introduction to Bioinorganic Chemistry
5) Ochi, Bioinorganic Chemistry
6) L. V. Azoroff, J. J. Brophy, Electronic processes in materials, Mc Craw Hill
7) S. J. Lippard, J.M. Berg, Principles of bioinorganic Chemistry, University Science
Books
8) Coordination chemistry S.F.A. Kettle, (1969) Thomas Nelson and Sons Ltd.,London.
9) Physical Inorganic Chemistry- A Coordination Chemistry Approach S.F.A.Kettle,
Spektrum, Oxford, 1996
10) Quantum Chemistry, R.K.Prasad, New Age.
11) Quantum Mechanics, Chatwal & Anand, Himalya Publishing House.
12)Introductory Quantum Chemistry, A.K.Chandra, Tata MacGraw-Hill.
inorganic
(KBrO3),
Unit-II
Inorganic Polymers: Classification, types of Inorganic polymers, Chemistry of following
polymers
a)
Silicones
super
ionic
conductors,
phase
transition
&
Unit-IV
Supra molecular Chemistry: Definition of supra molecular chemistry. Nature of binding
interactions in supramolecular structures: ion-ion, ion-dipole, dipole-dipole, H-bonding, cation-p,
anion-p, p-p, and van der Waals interactions.Synthesis and
Reference Books:
1) Vogels Text book of Quantitative Inorganic Analysis, ELBS
2) Quantum Chemistry, R.K.Prasad, New Age.
3) Inorganic polymers: Mark J.F., Allock H.R. West, Prentice hall
4) Inorganic polymers: Ring N.H., Academic Press N.Y. 1978
5) Hagenmuller, Preparative Methods in Solis State Chemistry
6) LohnWulff, the Structure and Properties of Materials Vol. IV, Electronic Properties
(WilyEastern)
7) L.V. Azoroof and J.J. Brophy: Electronic Processes in Materials, MacGraw Hills.
8) J.-M. Lehn; Supramolecular Chemistry-Concepts and Perspectives (Wiley-VCH, 1995)
9) P. D. Beer, P. A. Gale, D. K. Smith; Supramolecular Chemistry (Oxford University Press,
1999)
10) J. W. Steed and J. L. Atwood; Supramolecular Chemistry (Wiley, 2000)
Unit-II
Aromatic electrophilic substitution reactions:
Unit-IV
Mechanism of ester formation and their hydrolysis, formation and hydrolysis of amides,
decarboxylation mechanisms.
Elimination reactions: Mechanism and stereochemistry of eliminationsE1, E2, E1cb
mechanism, cis-elimination, Hofmann and Saytzeff eliminations, competition between
elimination and substitution, Chugaev reaction.
Rearrangement reactions: Inter and Intra molecular.
References:
1) I. L. Finar, Organic Chemistry, ELBS Longmann, Vol. I & II, 1984
2) J. March Advanced Organic Chemistry, Wiley Interscience, 1994.
3) E. S. Gould, Mechanism and Structure in Organic Chemistry, Halt, Rinhart& Winston, New
York, 1964.
4) F. A. Carey and Sundberg, Advanced Organic Chemistry Part A & B, 3rd edition, Plenum
Press, New York, 1990.
5) Comprehensive Organic Synthesis B. M. Trost and I. Fleming series, Pergamon Press,
New York, 1991.
6) A Guide book to mechanism in organic chemistry Petersykes.
7) S. K. Ghosh, Advanced General Organic Chemistry, Book and Alleied (P) Ltd, 1998
8) R. K. Bansal, Organic Reaction Mechanism, Wiley Eastern Limited, New Delhi, 1993.
9) K.S. Tewari et al, Vikas publishing house private limited 2005.
Unit-IV
Mass Spectroscopy: Introduction, instrumentation, methods of ionization: EI, CI, DI and ESI.
Mass anaylsis. Fragmentation: principles, odd and EE ions, molecular ion and base peak,
Nitrogen rule, metastable ions. Isotope effects in chloro and bromo compounds. Stevenson rule.
Fragmentation of: i) Normal and Branched Alkanes. ii) Alkenes. iii) Benzene and its derivatives.
iv) Alcohols. v) Aldehydes. vi) Ketones. vii) Acids. viii) Esters. ix) Ethers. x) Amines. xi) Nitro
compounds. xii) Halo compounds. xii) Peptides
Reference:
1) Introduction to Spectroscopy by D.L.Pavia, G.M.Lampman and G.S.Kriz,
2) Saunders Golden Sunburst Series London, (1979).
3) Spectroscopic Identification of organic compounds by R.M.Silverstein and
4) F.X.Webster, 6th Edition, Wiley and Sons, India Ltd (2006).
5) Organic Spectroscopy by William Kemp, 3rd Edition, Palgrave publishers, (2002).
6) Organic Structural Spectroscopy by J.B. Lambert, H.F.Shurvell, D.A.Lightner,
7) R.G.Cooks, Prentice Hall Publishers, Jersey (1998).
8) Organic Spectroscopy by D.W.Brown, A.J.Floyd and M.Sainsbury, John Wiley and Sons.
9) Applications of Absorption Spectroscopy of Organic Compounds by J.R Dyer
10) Prentice Hall Publishers, New Delhi (1969).
11) Interpretation of Mass Spectroscopy by McLafferty.
12) Organic Spectroscopy by V.R. Dani, Tata McGraw-Hill, Ltd (1995).
13) Spectroscopy of Organic Compounds by P.S. Kalsi, 4th Edition, New Delhi (2005).
14) Organic Spectroscopy by Jag Mohan (Narosa Publishing House) 2001.
Unit II
Statistical Thermodynamics: Basic terms: Probability, cell, phase space, micro and macro
states, thermodynamic probability, statistical weight factor, statistical equilibrium, assembly,
ensemble and its classification, Derivation of Boltzmann-Maxwell, Bose-Einstein and
Fermi-Dirac
statistics, partition
function
and
derivations
of
translational,
rotational,
Unit IV
Nuclear Chemistry: Nuclear properties, binding energies, nuclear force radii, angular
momentum in nuclear chemistry, spin magnetic and quantum moments, pairing energy, Square
Well and Wood Saxon potentials, Nuclear Models: Fermi, Shell, Collective, nuclear reaction
energetic, Q values and thresholds, barriers for charged particles, cross section, partial cross
sections,
elastic
in
fission and
radioactive elements like Na, P, S, Y and Br, accelerators, use of radioactive isotopes as tracers.
References:
1) Chemical Kinetics- KJ. Laidler, McGrawhill pub.
2) The text book of physical chemistry, Samuel Glasstone, Mcmillan Pub.
3) GlasstoneS : Textbook of Physical Chemistry, Affiliated East West Press.
4) GlasstoneS : Thermodynamic for Chemists, Affiliated East West Press.
5) Gurdeep and Rajesh : Thermodynamics, Goel Publishing House, Meerut.
6) Barrow G M : Physical Chemistry, 5th Ed, Mcgraw Hill Co. (1968).
7) S Baluja : Nuclear chemistry and Radio activity, SaurashtraUniversty, Rajkot.
reactions,
self-propagating
high
temperature
synthesis,
ion
synthesis; High pressure synthesis Methods of Single Crystal Growth: Solution growth; Melt
Growth-Bridgeman, Czochralski, Kyropoulus, Verneuil; Chemical Vapour Transport; Fused Salt
Electrolysis; Hydrothermal method; Flux Growth.
Unit-II
Crystal Structure: Crystalline and amorphous solids; crystal systems, point groups: methods
of characterizing crystal structure - Powder x-ray diffraction, electron and neutron diffraction;
types of close packing - hcp and ccp, packing efficiency, radius ratios; polyhedral
description of solids; structure types -NaCl, ZnS, Na2O, CdCl2, wurtzite, nickel arsenide,
CsCl, CdI2, rutile and Cs2O, perovskite ABO3, K2NiF4, spinels.
Unit-III
Electrode Kinetics: Metal/solution interface- Dependence of electrochemical reaction rate on
over potential-current density for single step and multi-step processes-Influence of electrical
double layer on rate constants. Activation and diffusion controlled processes- Marcus kinetics
and quadratic dependence of Gibbs free energies-electron transfer processes involving
organic and inorganic compounds. Different types of overpotentials- polarization behaviorMechanism
of
Unit-IV
Quantum Mechanics: Solution of the Schrodinger equation for exactly solvable problems
such as particle-in-a- box, particle-in-a-ring, harmonic oscillator and rigid rotor. Tunneling,
one dimensional potential barriers and wells. Postulates of quantum mechanics, wave functions
and probabilities, operators, matrix representations, commutation relationships. Hermitian
Reference:
1) R. West, Solid State Chemistry and its Applications, John Wiley & Sons, 1984.
2) L. Smart and E. Moore, Solid State Chemistry - An Introduction, Chapman & Hall, 1992.
3) H. V. Keer, Principles of the Solid State, Wiley Eastern Limited, 1993.
4) Chemical Kinetics and Dynamics; Jeffrey I Steinfeld, Joseph S. Francisco and William L.
Hase. Prentice Hall, 2nd edition, 1998.
5) Laidler, K. J.; Chemical Kinetics", 3rd Edition 1997 , Benjamin-Cummings. Indian reprint Pearson 2009.
6) W.J.Albery; Electrode kinetics Clarendon Press, Oxford 1975.
7) C.H. Banford and R.G. Compton (ed) Comprehensive chemical kinetics, Vol 26 Electrode
kinetics principles and methodology, Elsevier science publishers 1986
8) D. A. McQuarrie, Quantum Chemistry, University Science Books, 1983.
9) I. N. Levine, Quantum Chemistry, 3rd edition, Allyn and Bacon, 1983.
10) J. P. Lowe, Quantum Chemistry, K. A. Peterson, Third edition, Academic Press, 2006.
11) Principles of quantum chemistry, R.K.Prasad, McgrwHill publications.
Unit- II
Flame Photometry and Atomic Absorption Spectroscopy: Introduction, Principle, flames and
flame spectra vibration of emission intensity with flames, flame back ground, metallic spectra
inflame, total consumption and premix burners, interferences, role of temperature
on
absorption, atomic absorption spectroscopy, sources, hallow cathode lamp, line sources,
comparative study of AAS and flame spectroscopy; applications of AAS and Flame
photometry.
Unit-III
Luminescence Spectroscopy (Molecular Luminescence): Introduction, Fluorescence and
phosphorescence, excited states, deactivation processes, variable that affect fluorescence and
phosphorescence. Relation between intensity and concentration, Instrumentation, Basic
difference in the measurement of fluorescence and phosphorescence, general scope of
application, comparison of flourimetry and phosphometry, Flourescent indicators, applications;
flourimetric analysis of inorganic, organic, pharmaceutical and biological materials;
chemilumineacencess.
Unit-IV
Electron Spin Resonance (ESR) Spectroscopy: Basic principle, interaction between electron
spin and magnetic field; Origin of spectral lines; intensity, width and position of spectral lines;
Relaxation process; multiplicity in ESR hyper fine splitting; g-value and factors affecting; Rules
for interpretation of spectra; zero field splitting and Krammers degeneracy, John-Tellers
distortion, isotropic and Anisotropic coupling constants; Nuclear quadrapole coupling
interaction; spin Hamiltonian, ESR spectra of radical containing a single set of equivalent
protons-methyl, p-benzoquine anion, cyclopentadienyl, benzene, cycloheptatrienyl anions;
ESR spectra of transition metal complexes; applications.
Reference:
1) Analytical Chemistry, G.D. Christian, 5th ed., 2001 John Wiley & Sons, Inc, India.
2) Quantitative Analysis, R.A. Day and A.L. Underwood, 6th edition,1993 prentice Hall,
Inc. New Delhi.
3) Vogels Textbook of Quantitative Chemical Analysis, J. Mendham, R.C. Denney, J.D.
4) Barnes and M.J.K. Thomas, 6th edition, Third Indian Reprint.2003 Pearson Education
Pvt. Ltd., New Delhi.
5) Analytical Chemistry Principles, John H. Kennedy, 2nd edition, Saunders College
Publishing, California, 1990.
6) Introduction to Instrumental Analysis R.D. Braun 1986.
7) Principles of Instrumental Analysis, Skoog, Hollar and Niemann, Harcourt Asian Pvt
ltd India, New Delhi, 5th edition 1998.
8) Instrumental method of analysis Willard, merit and Dean, 7th edition 1998.
9) Organic spectroscopy William Kemp, 3rd Edition ELBS 1991.
10) Organic spectroscopy Kalasi, Tata Mc.Graw Hill 1993.
Unit-II
Paper chromatography (PC):
dimensional and circular PC, mechanism of separation, structure of cellulose and types of
paper, methodology preparation of sample, choice of solvents, location of spots and
measurement of RF value, factors affecting RF values, advantages and applications.
Thin-layer chromatography (TLC):
paper
chromatography
and
column
Unit-III
High pressure liquid chromatography (HPLC): Apparatus, pumps, column packing,
characteristics of liquid chromatographic detectors-UV, IR, refractometer and fluorescence
detectors, advantages and applications.
Ion-exchange chromatography(IEC): Definitions, requirements for ion-exchange resin,
(GPC),
materials
for
packing-factors
governing
column
efficiency,
fluid
extraction:
instrumentation, supercritical
fluid
Advantages
choice,
of
off-line
supercritical
and
on-line
fluid
extraction,
extractions,
typical
Reference:
1) Fundamental of Analytical Chemistry, D.A. Skoog, D.M. West, Holler and Crouch 8th
edition, 2005, Saunders College Publishing, New York.
2) Analytical Chemistry, G.D. Christian, 5th ed., 2001 John Wiley & Sons, Inc, India.
3) Quantitative Analysis, R.A. Day and A.L. Underwood, 6th edition, 1993 prentice Hall,
Inc. New Delhi.
4) Vogels Textbook of Quantitative Chemical Analysis, J. Mendham, R.C. Denney, J.D.
Barnes and M.J.K. Thomas, 6th edition, Third Inidan Reprint.2003 Pearson Education
Pvt. Ltd., New Delhi.
5) Analytical Chemistry Principles, John H. Kennedy, 2nd edition, Saunders College
Publishing, California, 1990.
of
Instrumentation,
Unit-III
Laser Based Techniques: Atomic fluorescent spectrometry (AFS), Resonant ionisation
spectroscopy (RIS), Laser enhanced ionization (LEI). Principle types of transition tunable
laser, Classification of medium pumping and controlling mechanisms, Instrumentation detailing
of various gaseous, liquid and solid sources, cell, mono chromators, detectors.
Atomic Emission Spectrometry (AES): Inductively coupled plasma ICP / AES and
Flame emission spectroscopy (FES). Sources electrical discharge, dc/ac arcs, spark laser
microprobe, qualitative and quantitative analysis, problems discussion .
Unit-IV
Imaging techniques including MRI : Magnetic
resonance
imaging
(MRI)-
principle,
Reference Books:
1) Elements of x-ray diffraction, B.DCullity, Addison Wisley, 1967.
2) Diffraction Method, Wormald, Oxford University, Press, 1973
3) Standard Method of Chemical Analysis IIIA6th end.
4) Neutron Scattering in Chemistry, Baun, G.E. Butleworth, London, 1971.
5) Mossbaur Spectroscopy, Greenwood N.N., Gibbs T.C., Chapmann Hall, 1971.
6) Chemical Application of Mossbaur Spectroscopy, Goldanski V.I &Harber R.H., Academic
Press 1968.
7) Spectroscopy in Inorganic Compounds CNR Rao& Ferraro G.R., Academic Press,1970.
8) Basic Principles of Spectroscopy Cheney R.Mac Grows Hill, 1971.
9) Thermal Method, Wendlandt, W.W. John, Wiley, 1986.
10) Principles of Instrumental analysis, Skoog, III rdedn., Sounders, 1985/
11) MRI : Basic principles and applications, M. A. Brown, R. C. Semelka (1995).
silicate
nanocomposite
technology,
structure-property
relationships,
nanoparticles,
Magnetic
polymer
nanocomposites,
Polymer/graphite
Unit-III
Nanomagnetic Materials:
Basics of ferromagnetism, Effect of bulk structuring of Magnetic properties, Dynamics of
Nanomagnets, Nanopore containment of magnetic properties, Nano carbon ferromagnets, Giant
Magnetoresistance, Colossal magnetoresistance, Applications in data storage, Feerofluids, Band
structure in magnetic fields, Parallel and perpendicular field. Thin films, Atomic layer deposition
(ALD), Electrochemical deposition (ECD), Sol-Gel films.
Unit-IV
Characterization of Nano-structured materials:
Principle, instrumentation and applications of Powder X-ray diffraction, Fourier transform
infrared spectroscopy, Scanning electron microscopy, tunneling electron microscopy, atomicforce microscopy, magnetic-force microscopy (MFM), scanning near-field optical microscopy
(SNOM).
Reference:
1) Nanomaterials AK Bandyopadhyay, Newage International (p) limited publishers.
2) Nanomaterials- J Dutta and H Hofmann
3) Nanostructured materials processing, properties and applications- Carl C Koch, Jaico
publishing house.
4) Nanotechnology- William Illsey Atkinson, Jaico publishing house.