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— 136 Chapter 3 Infrared Spectrometry Appendix C Characteristic Group Absorptions* ew! 3699300 pau 2400 ao tw0o $600 tao tg00 Bay I T T r ALKANES ALKENES VINYL =o TRANS = as VINYLIDENE == 7 TRisuBsTITUTED 2/ TerrasusstiTuTeD Z/ CONJUGATED «cacy CUMULATED = Yo: eyeLic ALKYNES, MONOSUBSTITUTED DisuestITUTED MONONUCLEAR AROMATICS BENZENE MONOSUBSTITUTED = L,2.DISUTSTITUTED 1,3.DISUBSTITUTED 14-DISUBSTITUTED 1,2,4-TRISUBSTITUTED 1,2.3-TRISUBSTITUTED a L3,STRISUBSTITUTED © ALCOHOLS AND PHENOLS FREE OH INTRAMOLECULAR BONDED (WEAK) INTRAMOLECULAR SONDED (STRONG) INTERMOLECULAR BONDED SATURATED TERT. } =CH OOO HIGHLY SYMMETRICAL SEC. ‘SATURATED SEC. ‘a- UNSATURATED OR CYCLIC TERT. ‘o-UNSATURATED SEC. ALICYCLIC SEC. (5 OR 6- MEMBERED RING) ‘SATURATED PRIMARY ‘O-UNSATURATED TERT. a-UNSATURATED AND a-BRANCHED SEC. Di-a- UNSATURATES SEC. ALICYCLIC SEC. (7 OR B- MEMBERED RING) ‘@-BRANGHED AND/OR a-UNSATURATED PRIM. 3400 9000 2600 ame to pg ent 360° 3200" aoa” —bae0™” 7800 Tada Te00 doe “Tee ia0—oa «absorptions are shown by heavy bars. bat indicate that two peaks may be present. ° May be absent, + Frequently a doublet. 4 Ring bending bands, wong, ma = medium, Weak, sit = sharp, br ~ broad, Two iatensity designations over : (ETALS *KETALS” ATHERS AUPHATIC AROMATIC CARYL —O—CH,) win, DXIRANE RING PEROXIDES (ALKYL AND ARYL) PEROXIDES (ACYL AND AROYL) | ~~ ~~ ' (ARBONYL COMPOUNDS tETONES® DIALKYL (—CH4,COCH—) ROMATIC (COND) ENOL OF 1,3-DIKETONE @HYDROXY ARYL KETONE \LDEHYDES® AKL. ‘AROMATIC (CONJ) SARBOXYLIC ACIDS® (DIMER JCARBOXYLATE ION ESTERS ‘FORMATES: "ACETATES ‘OTHER UNCONJ ESTERS CONJUGATED ESTERS IAROMATIC ESTERS m (doublet) [ bands, sometimes a fourth for ketals, and a fifth band for acetals, jugated aliphatic examples show C=O stretch at virtually the same position as aromatic structures, {Conjugated examples show C—O stretch at lower wavenumbers (1710-1680 em”), The O—H stretch (3300-2600 em-") is very broad. Appendix C139 1409 ITRILES (RCN) "ALIPHATIC AROMATIC CARBODIIMIDES ISONITRILES (RCN) ALIPHATIC. AROMATIC ISOCYANATES (RNCO) THIOCYANATES (RSCN) ISOTHIOCYANATES (RNCS) ALKYL AROMATIC NITRO COMPONDS ALIPHATIC. AROMATIC. CON. NITRAMINE. NITROSOAMINES: VAPOR Li@uID NITRATES (RONO2) NITRITES (RONO) NITROSO COMPOUNDS (RNO) ALIPHATIC DIMER (TRANS) ALIPHATIC DIMER (CIS) AROMATIC DIMER (TRANS) ‘AROMATIC DIMER (CIS) ALIPHATIC MONOMER ‘AROMATIC MONOMER SULFUR COMPOUNDS « MERCAPTANS, TH IOPHENOLS W---4---—4 j= at } ‘4 THIO ACIDS “HIOCARBONYL GROUP C=S (NOT LINKED TO N) 'C=S (LINKED TO N) ULFOXIDES, ULFONES ULFONYL CHLORIDES RIM, SULFONAMIDE (SOLID) Ec. SULFORNAMIDE (SOLID) ULFONATES sueo seu 26002209) poi py L L to yy ew! 3609” 3256 aba 2400 Zao lacd—“Téoa" 1400" ~Te00 1000 oo Fon ee eee 138 Chapter 3 Infrared Spectrometry em) 3600 32002002400 zom gon tesa 120039 LACTONES BETA GAMMA, DELTA ACID CHLORIDES ALIPHATIC AROMATIC ANHYDRIDES. NON-CYCLIC (UNCON) NON-CYCLIC (CONJ} CYCLIC UNCON) CYCLIC (CONS) AMIDES PRIMARY SOLUTION SOLID ‘SECONDARY SOLUTION SOLID TERTIARY LACTAMS. SOLUTION SOLID 5-MEMBERED RING 6 OR 7- MEMBERED RING 5 | AMINES PRIMARY ALIPHATIC AROMATIC SECONDARY ALIPHATIC AROMATIC TERTIARY ALIPHATIC AROMATIC AMINE SALTS. PRIMARY ‘SECONDARY TERTIARY AMMONIUM ION ew! ego 8200 aad Zac 2060 1ace— BO] —Ta05—T200——‘1009

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