CBSE 12th 2015 Chemistry Question Paper Solution

Question Paper
CBSE 12th Board (Chemistry) Code No. A

Q 1.
Write the formulae of any two oxoacids of phosphorus.
Q 2.
Which would undergo SN2 reaction faster in the following pair :

C6H5 CH2 CH2 Br and C 6H5 CH CH3
|
Br
Q 3.
Out of AlCl3 and NaCl, which is more effective in causing coagulation of a negative sol and why ?
Q 4.
Write the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd
of tetrahedral voids.
Q 5.
Write the IUPAC name of the given compound :

CH3
|
CH3 C CH2 OH
|
CH3
Q 6.
Why do transition elements show variable states ? How is the variability in oxidation states of d-block
different from that of the p-block elements ?
Q 7.
(i)
Write down the IUPAC name of the following complex :

[Pt(NH3)(H2O)Cl2]
(ii)
Q 8.
Write the formula for the following complex :

tris(ethane-1,2-diamine)chromium (III) chloride
Calculate the time to deposit 1.5 g of silver at cathode when a current of 1.5A was passed through the
solution of AgNO3. (Molar mass of Ag = 108 g mol1, 1 F = 96500 C mol1)
Q 9.
Write the reagents used in the following reactions:

? C H CH CH
(i) C H CO CH
6
(ii)
? CH COCl
CH3 COOH
3
OR
Arrange the following compounds in increasing order of their property as indicated :
(i)
CH3CHO, C6H5CHO, HCHO
(ii)
(reactivity towards nucleophilic addition reaction)

2,4-dinitrobenzoic acid, 4-methoxybenzoic acid, 4-nitrobenzoic acid (acidic character)
06th to 12th April 2015

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PAGE # 1
Q 10.
Q 11.
Q 12.
(i)
(ii)
Why are aquatic species more comfortable in cold water than in warm water ?
What happens when we place the blood cell in saline water solution (hypertonic solution) ? Given
reason.
(i) Name the method used for the refining of titanium.
(ii) What is the role of Zn in the extraction of silver ?
(iii) Reduction of metal oxide to metal becomes easier if the metal obtained is in liquid state. Why ?
(i)
E0 value for the Mn3+/Mn2+ couple is positive (+ 1.5 V) whereas that of Cr3+/Cr2+ is negative
(0.4 V). Why ?

(ii) Transition metals form coloured compounds. Why ?
(iii) Complete the following equation :
2 MnO 4 16 H 5C2O 24
Q 13.
(i)
What type of isomerism is shown by [Co(NH3)5ONO]Cl2 ?
(ii)
On the basis of crystal field theory, write the electronic configuration for d4 ion if 0 < P.
(iii) Write the hybridization and shape of [Fe(CN)6]3.

Q 14.
Predict the products of the following reactions :

H NNHCONH2
2
?
(i)
CH3 C O
|
CH3
(ii)
C6H5CH2CH3
(a) KMnO 4 / KOH
?
(b) H
conc. HNO 3 / H2 SO 4
COOH
(iii)
Q 15.
Q 16.
Q 17.
Write the names and structures of the monomers of the following polymers :
(i) Nylon-6,6
(ii) Bakelite
(iii) Polystyrene
(i) Which one of the following is a disaccharide :
starch, maltose, fructose, glucose
(ii) What is the difference between acidic amino acid and basic amino acid ?
(iii) Write the name of the linkage joining two nucleotides.
Vapour pressure of water at 20C is 17.5 mm Hg. Calculate the vapour pressure of water at 20C when
15 g of glucose (Molar mass = 180 g mol1) is dissolved in 150 g of water.
Q 18.
Examine the given defective crystal :

X+
X+
X+
X+
X+
X+
X+
X+
X+
X+
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06 May to 10 May 2015

Last 10 Years Question papers will be provided Daily Test
PAGE # 2
Answer the following questions :

(i) Is the above defect stoichiometric or non-stoichiometric ?
(ii) Write the term used for the electron occupied site.
(iii) Give an example of the compound which shows this type of defect.
Q 19.
How do you convert the following :

(i) Prop-1-ene to Propan-2-ol
(ii) Bromobenzene to 2-bromoacetophenone
(iii) 2-bromobutane to But-2-ene
OR
What happens when
(i) ethyl chloride is treated with NaI in the presence of acetone,
(ii) chlorobenzene is treated with Na metal in the presence of dry other
(iii) methyl chloride is treated with KNO2 ?
Write chemical equations in support of your answer.
Q 20.
Give reasons for the following :

(i) p-nitrophenol is more acidic than p-methylphenol.
(ii) Bond length of C O bond in phenol is shorter than that in methanol.
(iii) (CH3)3C Br on reaction with sodium methoxide (Na+ OCH3) gives alkene as the main product
and an ether.
Q 21.
Calculate E 0cell and r G 0 for the following reaction at 25C :

A2+ + B+ A3+ + B
Given : Kc = 1010, 1F = 96500 C mol1
Q 22.
Define adsorption with an example. Why is adsorption exothermic in nature ? Write the types of adsorption
based on the nature of forces between adsorbate and adsorbent.
Q 23.
Seeing the growing cases of diabets and depression among young children, Mr. Lugani, the principal of
one reputed school organized a seminor in which he invited parents and principals. They all resolved
this issue by strictly banning junk food in schools and introducing healthy snacks and drinks like soup,
lassi, milk, etc. in school canteens.
They also decided to make compulsory half an hour of daily physical activities for the students in the
morning assembly. After six months, Mr. Lugani conducted the health survey in most of the schools and
discovered a tremendous improvement in the health of the students.
After reading the above passage, answer the following questions :
(i)
What are the values (at least two) displayed by Mr. Lugani ?
(ii)
As a student, how can you spread awareness about this issue ?
(iii) What are antidepressant drugs ? Give an example.

PAGE # 3
(iv)
Q 24.
Name the sweetening agent used in the preparation of sweets for a diabetic patient.
For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :
t/s
-1
(CH3COOCH31/mol L
(i)
(ii)
(a)
30
60
0.60
0. 30
0. 15
Show that it follows pseudo first order reaction, as the concentration of water remains constant.
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
OR
For a reaction A + B P, the rate is given by
Rate = k [A]2[B]
Q 25.
(b)
(i) How is the rate of reaction affected if the concentration of A is doubled ?

(ii) What is the overall order of reaction if B is present in large excess ?
A first order reaction takes 23.1 minutes for 50% completion.
Calculate the time required for 75% completion of this reaction.
(Given : log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
(a)
Account for the following :

(i) Bond angle in NH4 is greater than that in NH3.
(ii) Reducing character decreases from SO2 to TeO2.
(iii) HClO4 is a stronger acid than HClO.
(b)
Draw the structures of the following :

(i) H2S2O8
(ii) XeOF4
(a)
(b)
(c)
(d)
(e)
OR
Which poisonous gas is evolved when white phosphorus is heated with conc. NaOH solution ?
Write tha chemical equation.
Write the formula of first noble gas compound prepared by N. Bartlett. What inspired N. Bartlett to
prepare this compound ?
Fluorine is a stronger oxidizing agent than chlorine. Why ?
Write one use of chlorine gas.
Complete the following equation :
CaF2 + H2SO4
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06 May to 10 May 2015

PAGE # 4
Q 26.
An aromatic compound A of molecular formula C7H7ON undergoes a series of reactions as shown

below. Write the structures of A, B, C, D and E in the following reactions :
(C7H7ON) A
Br2+KOH
C6H5NH2
NaNO2 + HCl
CHCl3 + NaOH
(a)
CuCN
H2O
E
D
OR
Write the structures of the main products when aniline reacts with the following reagents :
(i) Br2 water
(ii) HCl
(iii) (CH3CO)2O / pyridine
(b)
Arrange the following in the increasing order of their boiling point :

C2H5NH2, C2H5OH, (CH3)3N
(c)
Give a simple chemical test to distinguish between the following pair of compounds :
(CH3)2 NH and (CH3)3N

PAGE # 5
Solution
CBSE 12th Board (Chemistry) Code No. A
Ans 1.
(I)
H3PO3 (Phosphorous acid)
(ii)
H3PO4 (Phosphoric acid)
Ans 2.
C6H5 CH2 CH2 Br (due to less stearic hindrence)
Ans 3.
AlCl3 is more effective

due to high Positive Charge density on Al+3 as compared to Na+
Ans 4.
The no. of atoms Y in CCP = N

no. of tetrahedral voids = 2N
1
no. of X atoms = 2N
3
2
= N
3
Formula
2
N:
3
= x2y3
Ans 5.
2, 2 - Dimethylpropan-1-ol
Ans 6.
Transition elements show variable oxidation states since in these elements there is a small energy
difference between 3d and 4s orbital therefore 3d and 4s both e participate in the bond formation hence
Ans 7.
transtion elements shows variable oxidation states.

Oxidation State of P block elements both type that is positive and negetive
but d block elements shows only positive oxidation states.
(i) Ammineaquadichloridoplatinum (II)
(ii) Cr en 3 Cl3
en = CH2 CH2
|
|
NH2 NH2
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06 May to 10 May 2015

PAGE # 6
Ag+ + e Ag(s)
108 gm Ag required =
1.5 gm Ag required =
Ans 8.
96500 C
96500
1. 5
108
= 1340.2 C
Q
i
1340 .2
t=
1.5
t=
t = 893.5 sec.
Ans 9.
(i)
Zn Hg / HCl
(ii)
PCl5
or
(i)
C6H5CHO < CH3CHO < HCHO
(ii)
4-methoxybenzoic acid < 4-nitrobenzoic acid < 2, 4-dinitrobenzoic acid
Ans 10. (i)
aquatic species is more comfortable in cold water than in warm water it is due to the more dissolution
of O2 in cold water
(ii)
Blood cell will be squeeze.
dissolution of gases is a exothermic procees means at low temperature gases more dissolve in
Water
Ans 11. (i)

(ii)
van Arkel method

Zn displace silver form its salt solution.
2
2AgCN2 Zn ZnCN4
2Ag( s )
(iii) Since in the liquid state S = +ve

Ans 12. (i)
Mn 3
Mn 2
Couple is positive
Mn3+ Mn+2 due to stable half filled (d5) electronic configuration it has reduction tendency..
Cr 2 Cr 3 have oxidation tendency
Cr3+ is more stable than Cr2+

3
due to stable t 2g electronic Configuration.
(ii)
due to d-d transition
(iii)
2MnO 4 + 16H+ + 5C 2 O 24 10CO2 + 8H2O + 2Mn2+

PAGE # 7
Ans 13. (i)
it shows linkage isomerism

[ Co (NH3)5 ONO]Cl2 and [Co(NH3)5 NO2] Cl2
(ii)
If 0 < P then
1
3
d4 t 2g e g
(iii) [ Fe (CN)6 ]3
hybridisation d2sp3
shape actahedral
Ans 14. (i)
H N NHCONH 2
CH3 C N NHCONH 2 H2O
CH3 C 0 2
|
|
CH
CH3
3
( a ) KMnO
(ii)
4
C 6H5 CH2 CH3
C 6H5 COOH
(b ) H
COOH
(iii)
Ans 15. (i) Nylon 6,6

Monomer Adipic acid,
HOOC (CH2)4 COOH

(ii)
hexamethylenediamine
H2N (CH2)6 NH2
, formalaldehyde
O
H
(iii) Polystyrene
(ii)
NO2
Bakelite
Mnoner Phenal
OH
Ans 16. (i)
COOH
Con
HNO3 + H2SO4
Monomer Styrene
CH=CH2
Maltose
acidic amino acid have COOH > NH2 group
where as basic amino acid have NH2 > COOH group
(iii) Phosphodiester linkage
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06 May to 10 May 2015

PAGE # 8
Ans 17. PA = 17.5 mm Hg
W A = 150 gm
W B = 15 gm
MA = 18 gmmol1
MB = 180 gm mol1
PA PS
PA
WB MA
MB WA
17 5 Ps
15 18
17 5
180 150
PS = 17 . 325 mm Hg
Ans 18. (i) non stoichiometric

(ii) F - Center (Ferb Centre)
(iii) NaCl in presence of excess Na
Ans 19. (i)
CH3
CH = CH2
CH3
+
H
H2 O
CH CH3
OH
O
Br
C C6H5
Br
(ii)
An. AlCl3
C6H5
(iii)
CH3
CH2
COCl
CH
CH3
CH3
CH = CH CH3
Br
Alc KOH
OR
(i)
acetone
C 2H5 Cl Na I
C 2H5 I NaCl

PAGE # 9
(ii)
dryether
2C 6H5 Cl 2Na C 6H5 C6H5 2NaCl
(iii)
CH3 Cl KNO 2 CH3 ONO KCl

OH
Ans 20. (i)
P-nitrophenol
is more acidic it is due to I, M effect of NO2 group.

NO2
(ii)
due to resonance bond length of C O bond in phenol is shorter than that is methanol.
(ii)
CH3
|
CH3 3 C Br CH3O Na H3 C C NaBr CH3 OH
||
CH2
Since 3 alkyl halide gives more preference for elemination reaction as compared to substution reaction
Ans 21. G = 2.303 RT log KC
G = 2.303 8.314 298 log 1010
G = 57058.483 J/mol
= -5. 7104
G = nF E cell
G
nF
( 5.7 10 4 )
1 96500
E cell =
E Cell
E Cell 5 9 10 1 V
Ans 22. AdsorptionThe accumulation of molecular species at the surface rather than in the bulk of a solid
or liquid is called adsorption.
e.g. water molecules adsorbed by silicagel
* during the adsorption process there is a force of attraction between adsorbate and adsorbent
hence energy is released.
* Two types
(a) Physisorption
(b) Chemisorption.
th
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06 May to 10 May 2015

10
PAGE # 10
Ans 23. (i)
(a) He is very concious towards the health of students.

(b) He is very deceplined.
(ii) As a student i am also motivate to my friend.
(iii) Phenelzine
(iv) Saccharin (ortho-sulphobenzimide)
Ans 24. Case 1

(I)
2.303
a
log
t
ax
2.303
0.60
log
K1 =
30
0.30
.303
2
K1 =
log 2
30
K1 =
Case 2
2 303
a
log
t
ax
2 303
0 60
K2
log
60
0 15
2 303
K2
2 log 2
60
.
K2 = 2 303 log2
30
K2
K1 = K2 it means it follows Pseudo first order reaction.

(II)
R
t
0 15 0 30
=
60 30
0 15
=
30
1
=
200
average rate
= 5 10-3 sec
OR
(a)
(I)
rate1 = K |A|2 |B|

rate2 = K [2A]2 |B|
rate2 = 4K |A|2 |B|
r2 = 4r1

11
PAGE # 11
(II)
(b)
Second order
For 50% Completion of reaction

K=
N
2 303
log 0
t
N
N0 = initial amount of the substance

N = amount left after t lime
2 303
100
log
23 1
50
2 303
log 2
K=
23 1
K=
___________(1)
For 75% Completion of reaction

2 303
100
log
t
25
2 303
K=
log 4
t
2 303
2 log 2 ___________(2)
K=
t
K=
Divide equation 1 and 2
2 303
log 2
K
23 1
2 303
K
2 log 2
t
t = 46.2 minute
Ans. 25 (a)
(i)
in NH4+ and NH3 nitrogen is SP3 hybridised but due to lPbP replusion bond angle in NH3 but
there is no lP in NH4+ hence its bond angle is 10928 but in NH3 it is 107
(ii)
due to inert pair effect.
(iii) due to higher oxidation state of Cl and high oxygen content in HClO4 it is more acidic then HOCl.
in HClO4
O.S of Cl = +7
in HClO
O.S of Cl = +1
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06 May to 10 May 2015

12
PAGE # 12
(b)
O
(i)
S
O
HO
(ii)
OH
F
Xe
F
O
OR
(a)
P4 + 3NaOH + 3H2O PH3 + 3NaH2PO2
* Poisonous gas is PH3 (Phosphine)

(b)
Formula Xe+ PtF6

N Barlett Prepared the compund O2+ PtF6 He then realised that the first jonisation enthalpy of
melecular oxygen (1175 KJ mol1) was almost identical with that of xenon (1170 KJ mol1) he
made efforts to prepare same type of compound with Xe and was successful in Preparing another
red colour compound Xe+ PtF6.
(c)
due to low dissociation bond enthalpy and High hydration enthalpy F2 is a strong oxidising agent.
(d)
Use In sterilising drinking water.
(e)
CaF2 + H2SO4 CaSO4 + 2HF
Ans 26. C7 H7OH
N2 Cl
CN
C NH2
(A)
N=C
(B)
(C)
(D)
COOH
(E)

13
PAGE # 13
OR
Br
NH2
(a)
(i)
3Br2
Br
H O
2
Br
NH3Cl
+
NH2
(ii)
NH2
HCl
NH2
NH
Py
(iii)
O
C CH3
CH3 CO 2 O
(b)
C2H5 OH > C2H5NH2 > (CH3)3 N
(c)
(CH3)2 NH react with Hinsberg reagent (C6H5SO2Cl)
CH3 2 NH
C 6H5 SO 2 Cl CH3 2
C6H5
O
(CH3)3 N does not react with Hinsberg reagent
th
th
06 May to 10 May 2015

14
PAGE # 14

CBSE 12th 2015 Chemistry Question Paper Solution

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Question Paper

CBSE 12th Board (Chemistry) Code No. A

Write the formulae of any two oxoacids of phosphorus.

Which would undergo SN2 reaction faster in the following pair :

Write the IUPAC name of the given compound :

Write down the IUPAC name of the following complex :

Write the formula for the following complex :

Write the reagents used in the following reactions:

CH3CHO, C6H5CHO, HCHO

(reactivity towards nucleophilic addition reaction)

06th to 12th April 2015

(0.4 V). Why ?

What type of isomerism is shown by [Co(NH3)5ONO]Cl2 ?

(iii) Write the hybridization and shape of [Fe(CN)6]3.

Predict the products of the following reactions :

(a) KMnO 4 / KOH

Examine the given defective crystal :

06 May to 10 May 2015

Answer the following questions :

How do you convert the following :

Give reasons for the following :

Calculate E 0cell and r G 0 for the following reaction at 25C :

As a student, how can you spread awareness about this issue ?

(iii) What are antidepressant drugs ? Give an example.

06th to 12th April 2015

(i) How is the rate of reaction affected if the concentration of A is doubled ?

Account for the following :

Draw the structures of the following :

06 May to 10 May 2015

An aromatic compound A of molecular formula C7H7ON undergoes a series of reactions as shown

Arrange the following in the increasing order of their boiling point :

06th to 12th April 2015

H3PO3 (Phosphorous acid)

H3PO4 (Phosphoric acid)

C6H5 CH2 CH2 Br (due to less stearic hindrence)

AlCl3 is more effective

The no. of atoms Y in CCP = N

transtion elements shows variable oxidation states.

06 May to 10 May 2015

C6H5CHO < CH3CHO < HCHO

4-methoxybenzoic acid < 4-nitrobenzoic acid < 2, 4-dinitrobenzoic acid

Ans 10. (i)

Blood cell will be squeeze.

Ans 11. (i)

van Arkel method

(iii) Since in the liquid state S = +ve

Cr3+ is more stable than Cr2+

due to d-d transition

2MnO 4 + 16H+ + 5C 2 O 24 10CO2 + 8H2O + 2Mn2+

06th to 12th April 2015

Ans 13. (i)

it shows linkage isomerism

Ans 14. (i)

Ans 15. (i) Nylon 6,6

HOOC (CH2)4 COOH

H2N (CH2)6 NH2

Ans 16. (i)

(iii) Phosphodiester linkage

06 May to 10 May 2015

Ans 17. PA = 17.5 mm Hg

Ans 18. (i) non stoichiometric

Ans 19. (i)

06th to 12th April 2015