Professional Documents
Culture Documents
Series OSR
Code No.
amob Z.
56/1
Roll No.
A{YH$V_ AH$ : 70
Maximum Marks : 70
1
P.T.O.
gm_m` {ZX}e :
(i)
(ii)
Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &
(iii)
(iv)
(v)
(vi)
Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &
General Instructions :
(i)
(ii)
(iii)
(iv)
(v)
(vi)
1.
amgm`{ZH$ emofU
(chemisorption) na
H3PO3 H$s
4.
5.
mW{_H$ Eoamo_{Q>H$ Eo_rZm| Ho$ S>mBEOmo{Z`_ bdUm| _| n[adVZ H$mo {H$g Zm_ go OmZm OmVm
h ?
p-_o{Wb~OpS>hmBS>
KZd 2.8 g cm3 H$m EH$ Vd \$bH$ Ho$pV KZmH$ma (f.c.c.) H$ma H$m _mH$ gob
~ZmVm h {OgHo$ {H$Zmao H$s b~mB 4 108 cm h & Bg Vd H$m _moba `_mZ
n[aH${bV H$s{OE &
({X`m J`m h : NA = 6.022 1023 _mob 1)
An element with density 2.8 g cm3 forms a f.c.c. unit cell with edge
length 4 108 cm. Calculate the molar mass of the element.
(Given : NA = 6.022 1023 mol 1)
56/1
P.T.O.
10.
(i)
(ii)
NaCl
AWdm
{ZZ{b{IV nXm| Ho$ OmoS>m| Ho$ ~rM Amn {d^oXZ H$go H$a|Jo
(i)
Q>oQ>mhoS>b VWm AmQ>mhoS>b [a{$`m
(ii)
{H$Q>b OmbH$ VWm _mH$ gob
(i)
(ii)
11.
(i)
(ii)
Am`Zm| Ho$ dV nbm`Z g~Yr H$mobamD$e (Kohlrausch) {Z`_ {b{IE & VZwH$aU
na {db`Z H$s MmbH$Vm H$_ `m| hmo OmVr h ?
56/1
(order) gwPmBE
(i)
(ii)
&
(t)
Ho$ {V gmVm
(R)
_| n[adVZ H$mo
2
(i)
(ii)
13.
YmVwAm| Ho$ {dwV-AnKQ>Zr n[aH$aU H$m AmYma_yb {gmV g_PmBE & BgH$m EH$
CXmhaU Xr{OE &
P4 + H2O
(ii)
XeF4 + O2F2
15.
(i)
P4 + H2O
(ii)
XeF4 + O2F2
XeF2
(ii)
BrF3
16.
(i)
XeF2
(ii)
BrF3
P.T.O.
17.
HBr
{ZZ ~hbH$m| H$mo m H$aZo Ho$ {bE `w$ EH$bH$m| Ho$ Zm_ {b{IE
(i)
~oHo$bmBQ>
(ii)
{ZAmorZ
Write the name of monomers used for getting the following polymers :
19.
(i)
Bakelite
(ii)
Neoprene
(a)
A{^{H$`m
Mg (s) + Cu2+ (Obr`) Mg2+ (Obr`) + Cu (s)
Ho$ {bE
rG
(a)
o
: E gob = + 2.71 V, 1 F = 96500 C _mob 1
{X`m J`m h
(b)
Anmobmo (Apollo) AV[aj moJm_ Ho$ {bE {dwV e{$ CnbY H$amZo Ho$ {bE
`w$ gob Ho$ H$ma H$m Zm_ {b{IE &
o
Given : E
(b)
56/1
cell
Name the type of cell which was used in Apollo space programme
for providing electrical power.
6
20.
pWa Am`VZ AdWm _| SO2Cl2 Ho$ W_ H$mo{Q> Ho$ Vmnr` {dKQ>Z Ho$ XmamZ {ZZ{b{IV
AmH$S>o m hE :
SO2Cl2 (Jg) SO2 (Jg) + Cl2 (Jg)
`moJ
g_`/s1
gH$b Xm~/dm`w_S>b
0 .4
100
0 .7
3
log 2 = 0.3010)
The following data were obtained during the first order thermal
decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) SO2 (g) + Cl2 (g)
Experiment
Time/s1
Total pressure/atm
0 .4
100
0 .7
B_eg `m hmoVo h
Xr{OE &
What are emulsions ? What are their different types ? Give one example
of each type.
22.
(CH3)3 P = O Vmo
(ii)
BboQ>mZ m H$aZo H$s G$Um_H$ {M dmbr EWnr H$m _mZ g\$a H$s Anojm
AmgrOZ Ho$ {bE H$_ hmoVm h &
H3PO3 H$s Anojm H3PO2 A{YH$ ~b AnMm`H$ h &
(iii)
56/1
(CH3)3 N = O Zht
{_bVm &
P.T.O.
23.
(i)
(ii)
Oxygen has less electron gain enthalpy with negative sign than
sulphur.
(iii)
(i)
gH$a
(ii)
(iii)
[NiCl4]2
{b{IE &
?
(i)
(ii)
?
3
(en = ethane-1,2-diamine)
24.
(iii)
(a)
{ZZ _| go `oH$ A{^{H$`m Ho$ _wI EH$hbmoOZr CnmXm| H$s gaMZmE ~ZmBE :
(b)
56/1
(CH3)3 C Cl
AWdm
CH3 Cl
8
SN2
25.
(a)
(b)
CH3Br or CH3I
(ii)
(CH3)3 C Cl or CH3 Cl
(i)
VVr`H$ Eo_rZm|
hmoVo h &
(R3N) H$s
(ii)
Eo{ZbrZ \$sS>ob
(iii)
Obr` {db`Z _|
(R-NH2) Ho$
dWZmH$ CVa
H$s VwbZm _|
(CH3)2NH
AWdm
{ZZ A{^{H$`mAm| _|
A, B
Ama
(i)
Sn HCl
H2O
NaNO2 HCl
C6H5NO2
A B
C
273 K
(ii)
H 2O / H
Br2 KOH
NH3
C
A
CH3CN
B
(ii)
(iii)
56/1
P.T.O.
Sn HCl
H2O
NaNO2 HCl
C6H5NO2
C
A B
273 K
(ii)
H 2O / H
Br2 KOH
NH3
CH3CN
C
A
B
26.
27.
56/1
(i)
Peptide linkage
(ii)
Primary structure
(iii)
Denaturation
{dd dm` {Xdg Ho$ Adga na, S>m. gVnmb Zo nmg Ho$ Jmd _| ahZo dmbo YZhrZ
{H$gmZm| Ho$ {bE EH$ dm` H$n bJm`m & OmM Ho$ ~mX, Cgo `h XoI H$a YH$m bJm
{H$ ~ma-~ma H$sQ>ZmeH$m| Ho$ gnH$ _| AmZo Ho$ H$maU {H$gmZm| _| go A{YH$m| H$mo H$ga H$m
amoJ hmo J`m Wm & CZ_| go ~hVm| H$mo _Yw_oh ^r Wm & Chm|Zo CZ_| YZ_w$ Amf{Y`m ~mQ>t &
S>m. gVnmb Zo Bg ~mV H$s gyMZm VH$mb ZoeZb y_Z amBQ>g H${_eZ (NHRC) H$mo
Xr & NHRC Ho$ gwPmdm| na gaH$ma Zo {ZU` {b`m H$s S>mQ>ar ghm`Vm Ama {dmr`
ghm`Vm bmoJm| H$mo Xr OmE Ama ^maV Ho$ g^r Jmdm| _| KmVH$ amoJm| Ho$ ^md H$mo amoH$Zo Ho$
{bE A`{YH$ gw{dYm dmbo AnVmb Imobo OmE &
(b) NHRC mam
(i)
(a)
(ii)
ApV_ H$ga _| nrS>m go ~MmZo Ho$ {bE _w`V`m H$mZ-gr nrS>mZmeH$ Amf{Y`m
`w$ H$s OmVr h ?
(iii)
_Yw_oh Ho$ amo{J`m| Ho$ {bE gwPmE JE H${_ _YwH$mam| _| go {H$gr EH$ H$m CXmhaU
Xr{OE &
10
On the occasion of World Health Day, Dr. Satpal organized a health camp
for the poor farmers living in a nearby village. After check-up, he was
shocked to see that most of the farmers suffered from cancer due to regular
exposure to pesticides and many were diabetic. They distributed free
medicines to them. Dr. Satpal immediately reported the matter to the
National Human Rights Commission (NHRC). On the suggestions of
NHRC, the government decided to provide medical care, financial
assistance, setting up of super-speciality hospitals for treatment and
prevention of the deadly disease in the affected villages all over India.
(i)
28.
Dr. Satpal
(b)
NHRC.
(ii)
What type of analgesics are chiefly used for the relief of pains of
terminal cancer ?
(iii)
(a)
(b)
(i)
_mobaVm
(ii)
(Kb)
2, 3
AWdm
56/1
11
P.T.O.
(a)
EWoZmb Ama EogrQ>moZ H$m {_lU {H$g H$ma H$m {dMbZ {XImVm h
Xr{OE &
(b)
Ob _| byH$moO (_moba `_mZ = 180 g _mob 1) Ho$ EH$ {db`Z na bo~b bJm
h, 10% (`_mZ AZwgma) & Bg {db`Z H$s _mobbVm Ama _mobaVm `m hm|Jo ?
({db`Z H$m KZd = 1.2 g mL1)
(a)
(b)
H$maU
Molarity
(ii)
(a)
(b)
29.
56/1
(a)
(i)
Cr2O72 + 2OH
(ii)
MnO4 + 4H+ + 3e
12
2, 3
(b)
(i)
Zn
(ii)
(iii)
2, 3
AWdm
(i)
(ii)
(iii)
+4
AmgrH$aU AdWm
MnO4 + 8H+ + 5e
(iv)
(na_mUw H$_mH$
(a)
(b)
: Mn = 25, Cr = 24)
(i)
Cr2O72 + 2OH
(ii)
MnO4 + 4H+ + 3e
(ii)
(iii)
56/1
13
P.T.O.
(i)
(ii)
(iii)
(iv)
30.
(a)
(b)
{ZZ A{^H$maH$m| go
(i)
HCN
(ii)
H2N OH
(iii)
VZw
NaOH
CH3CHO H$s
CH3CHO
H$s CnpW{V _|
{ZZ `m{JH$ `w_m| _| AVa {XImZo Ho$ {bE gab amgm`{ZH$ narjU {b{IE :
(i)
(ii)
3, 2
AWdm
(a)
(b)
(c)
(i)
CH3COOH H$s
(ii)
amoOoZ_wS> AnM`Z
(ii)
H${ZOmamo A{^{H$`m
Ama
_| go
2, 2, 1
14
(a)
(b)
HCN
(ii)
H2N OH
(iii)
(ii)
(a)
(b)
(c)
(ii)
Rosenmund reduction
(ii)
Cannizzaros reaction
56/1
15
P.T.O.
Marking Scheme
Chemistry - 2014
Outside Delhi- SET (56 /1)
1
1
2Chlorobutane
or
Proteins
6.
Diazotization
7.
8.
9.
Given; d = 2.8g/cm3 ;
d=
M=
Z=4
a = 4 x 108 cm
or
M=
x 6.022x1023
(i) Metal excess defect / Metal excess defect due to anionic vacancies filled by free electrons 1
/ Due to F centers.
(ii) Schottky defect.
1
Or
10
OR
radius ratio (r + /r -) for Tetrahedral void is 0.225 & radius ratio for octahedral voids is 0.414
(ii) A regular three dimensional arrangement of points in space is called a crystal lattice.
Unit cell is the smallest portion of a crystal lattice which, when repeated in three directions, 1
generates an entire lattice. / unit cell is the miniature of crystal lattice / microscopic edition of the
crystal lattice.
11
Kohlrausch law of independent migration of ions. The law states that limiting molar 1
conductivity of an electrolyte can be stated as the sum of the individual contributions of the anion
and cation of the electrolyte.
On dilution,the conductivity () of the electrolyte decreases as the number of ions per unit 1
volume of solution decreases.
12
13
(ii) slope = -k
In this method, the impure metal is made to act as anode. A strip of the same metal in pure form is 1
used as cathode. They are put in a suitable electrolytic bath containing soluble salt of the same
metal. Pure metal is deposited at the cathode and impurities remain in the solution.
14
15
16
Reimer-Tiemann reaction
1
1+1
Williamson synthesis
1
17
HBr H+ + Br-
Or
( where R = -CH3)
18
19
F = 96500C mol-1
rGO = n x F x EoCell
SO2 Cl2
At t = 0s
0.4 atm
SO2
0 atm
x atm
Cl2
0 atm
x atm
Pt = 0.4 x + x + x
Pt = 0.4 + x
0.7 = 0.4 + x
x = 0.3
k=
2.303
k=
2.303
k=
2.303
k=
21
t
t
100s
.
log
0.4
log 0.8-0.7
0.4
log 0.1
These are liquid-liquid colloidal systems or the dispersion of one liquid in another liquid.
Types: (i) Oil dispersed in water (O/W type) Example; milk and vanishing cream
(ii) Water dispersed in oil (W/O type) Example; butter and cream.
(ii) This is due to very small size of Oxygen atom / repulsion between electrons is large in 1
relatively small 2p sub-shell.
23
(iii) In [NiCl4] ; Cl acts as weak ligand therefore does not cause forced pairing, thus electrons
will remain unpaired hence paramagnetic.
In [Ni(CO)4] ; CO acts as strong ligand therefore causes forced pairing, thus electrons will
become paired hence diamagnetic.
24
(a)
(i) As primary amines form inter molecular H bonds, but tertiary amines dont form H bonds.
(iii) This is because of the combined effect of hydration and inductive effect (+I effect).
Or
25
(i) C6H5NO2
26
++
++
(i) Peptide linkage is an amide formed between COOH group and NH2 group ( -CO-NH- )
(ii) Specific sequence of amino acids in a polypeptide chain is said to be the primary structure 1
of the protein.
(iii) When a protein in its native form, is subjected to change in temperature or change in pH, 1
protein loses its biological activity. This is called denaturation of protein
27
(b) Dutiful / caring / humane in the large interest of public health in rural area.
28
(a)
(i) Molarity is defined as number of moles of solute dissolved in one litre of solution.
(b)
urea = glucose
or
W Glucose =
= 45g
OR
28
It is due to weaker interaction between acetone and ethanol than ethanol-ethanol interactions.
M=
M=
.
.
m=
= 0.66 M
& d = 1.2g/m L
or
0.66 mol/L
m=
= 0.61m
or 0.61mol/kg
29
MnO2 + 2H2O
(ii) This is due to smaller ionic sizes / higher ionic charge and availability of d orbitals.
(iii) because Mn
+2
is more stable(3d5) than Mn3+ (3d4). Cr+3 is more stable due to t2g3 / d3 1
configuration.
Or
29
(i)
Lanthanoids
Actinoids
Atomic / ionic radii does not show much Atomic / ionic radii show much variation /
variation / +3 is the most common oxidation Besides
+4,+5,+6,+7 also.
1
Mn2+ + 4H2O
Because Mn3+ has 4 unpaired electrons (3d4) therefore more paramagnetic whereas Cr3+ has 3
unpaired electrons (3d3).
30
(a) (i)
1
1
(ii) CH3CH=NOH
(iii)
1
(b) (i) Add neutral FeCl3 in both the solutions, phenol forms violet colour but benzoic acid does 1
not.
1
(ii) Tollens reagent test: Add ammoniacal solution of silver nitrate (Tollens reagent) in
both the solutions propanal gives silver mirror whereas propanone does not.
(or any other correct test)
OR
30
(a) (i) As Cl acts as electron withdrawing group ( I effect) ,CH3 shows +I effect.
Or
Or With bezaldehyde
(c) CH3CH2CH2COCH3.