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An efficient and effective hot or cold pack is cheap to produce, and raises or lowers the
temperature with a small amount of salt. The Dystan Medical Supply Company has tasked the
lab to determine the most cost effective and efficient salt to use for a hot and cold pack:
ammonium nitrate, calcium chloride, lithium chloride, or potassium chloride.
By performing a calorimetry trial for each salt, the enthalpy of dissolution can be
determined. Calorimetry is the process by which you can measure the heat capacity of a
substance using a difference in temperature. The difference in temperature of a substance before
and after another hot one is added can be mathematically determined. However, it is usually
measured lower than predicted, do to the container absorbing some of the energy. This amount,
called the calorimeter constant, varies for each container, and is integral when performing
calculations for other experiments. After determining the Calorimetry constant, more
experiments can be performed substituting salts for hot water. This will allow the mass of the salt
required to make an effective hot or cold pack to be determined. An effective cold pack must be
able to achieve a temperature of 0, an effective hot pack can reach a temperature of 65,
therefore, a good salt will be able to achieve these temperatures with a small amount of salt.
Additionally, for the company to make a profit, the cost for each hot pack must be less
than $5.00. So the cost for each type of salt must also be considered, by determining the cost for
the amount of salt in each pack, as well as labor, overhead and the bag.
Start recording data for about 5 seconds, then carefully add the measured amount
of hot water to the calorimeter and close the lid. Continue recording data until the
temperature stabilizes. Repeat twice.
Using the data collected during the two trials prepare temperature vs. time
graphs using excel. Using the graph, determine the equilibrium temperature
(temperature which stabilizes), then find the temperature change for the hot and
cold water using the following equations:
i.
T(water) = T(equilibrium) -
Do this four times using different salts depending upon whether or not you are
raising or lowering the temperature, and find out the moles of each you will need.
Given your grams(you need to convert from moles to grams) of each salt
needed and the following information, determine how much each pack will cost
using each given salt:
a.
b.
c.
d.
e.
f.
g.
Lastly, compare these costs to determine which salt works best for each hot
and cold packs. Record your results.
Results
Part A- Determination of Calorimeter Constant
Experimental Data and Calculations - Trial 1
Bibliography
Zumdahl, Steven S., and Susan A. Zumdahl. Chemistry: An Atoms First Approach. Bellmont,
CA: Brooks/Cole, CENGAGE Learning, 2012. Print.
Stanton, Bobby, Lin Zhu, and Charles H. Atwood. Experiments in General Chemistry Featuring
Measurenet: Guided Inquiry, Self-directed, and Capstone. Belmont, CA: Brooks/Cole, Cengage
Learning, 2010. Print.