equation after quencher

C + (1/2)O2 = CO H2
C + 2H2 = CH4 CO
S + H2 = H2S CO2
H2 + (1/2)O2 = H2O CH4
CH4 + 2O2 = CO2 + 2H2O H2S
CH4 + (3/2)O2 = CO +2H2O N2

Product specification MW density H2 produce

H2 95% purity 2 1608.928
CO 1% 28 22524.99
CO2 1% 44 35396.41
N2 2% 28 22524.99
CH4 1% 16 12871.42
H2S Less than 1 ppm 34 27351.77

P 2060 kPa
T 308 K
R 0.008314 m3.kPa/mol.K
assume ideal gas

stream 1 mass mw mole stream 2 mass

C 1.72E+08 12 14304948 C 171659374
H2 22214743 2 11107371 H2 22214742.5
S 8078088 32 252440.26 S 8078088.19
2.02E+08 25664759 201952205

stream 4 mass mw mole stream 5 mass

H2O(v) 1.51E+08 18 8414675 O2 234264557
N2 12319084.5
246583642
 Stream Table
Stream Number 1 2 3 4 5 6
Temperature (°C) 37.8 50 200 20 210
Pressure (kPa) 206.9 206.9 206.9 4140 4140 4140
Vapor fraction 0 0 0
Mole flow (kmol/h) 25664759 25664759 25664759 8414675 7760734.7 7760734.72
Mass flow (kg/h) 2.02E+08 2.02E+08 201952205 1.51E+08 246583642 246583642
Component mass flow (kg/h)
Carbon (liquid) 1.72E+08 1.72E+08 171659374 0 0 0
Hydrogen (liquid) 22214743 22214743 22214743 0 0 0
Sulfur (liquid) 8078088 8078088 8078088 0 0 0
Oxygen (gas) 0 0 0 0 234264557 234264557
Nitrogen (gas) 0 0 0 0 12319084 12319084.5
Water vapor 0 0 0 1.51E+08 0 0
Carbon dioxide (gas) 0 0 0 0 0 0
Carbon monoxide (gas) 0 0 0 0 0 0
Water (liquid) 0 0 0 0 0 0
Hydrogen (gas) 0 0 0 0 0 0
Methane 0 0 0 0 0 0
Hydrogen sulfide 0 0 0 0 0 0
Carbon (gas) 0 0 0 0 0 0
fter quencher input 600000000
47.60% C 0.85
42.10% H2 0.11
8.30% S 0.04
0.10% O2 1.16 0.95 purity
0.50% N2 0.061 0.05
1.40% H2O(v) 0.75

heavy oil feedstock x

0.85x + 0.11x + 0.04x + 1.16x +0.061x +0.75x 600000000
2.971 x = 6E+08
x = 2.02E+08

mass of material input MW mole

1000000 m3/day C 171659374 kg/hr 12 14304948
67038647 kg/hr H2 22214743 kg/hr 2 11107371
S 8078088.2 kg/hr 32 252440.3
O2 234264557 kg/hr 32 7320767
N2 12319084 kg/hr 28 439967.3
H2O(v) 151464153 kg/hr 18 8414675

carbon used 1.69E+08

carbon suspension 3029283 252440.3 kmol/hr

mw mole stream 3 mass mw mole stream 7 mass

12 14304948 C 171659374 12 14304948 O2 2.34E+08
2 11107371 H2 22214743 2 11107371 N2 12319084
32 252440.3 S 8078088.2 32 252440.3 H2O(v) 1.51E+08
25664759 201952205 25664759 3.98E+08

mw mole stream 6 mass mw mole stream 8 mass

32 7320767 O2 234264557 32 7320767 CO 2.63E+08
28 439967.3 N2 12319084 28 439967.3 CO2 81542035
7760735 246583642 7760735 CH4 357248.8
H2 21256303
H2S 3795768
N2 12319084
C 3029283
 H2O 2.14E+08
6E+08

7 8 9 10 11 12 13 14 15 16
210 1300 250 50 35
4140 4140

16175410 34624377 22707864 11916513 22455424 252440.3 5958257 5958257 111638.57 28302042
3.98E+08 6E+08 3.86E+08 2.14E+08 382473481 3029283 1.07E+08 1.07E+08 3795711.4 4.86E+08

0 0 0 0 0 3029283 0 0 0 0
0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
2.34E+08 0 0 0 0 0 0 0 0 0
12319084 12319084 12319084 0 12319084 0 0 0 0 12319084
1.51E+08 2.14E+08 0 2.14E+08 0 0 1.07E+08 1.07E+08 0 1.07E+08
0 81542035 81542035 0 81542035 0 0 0 0 81542035
0 2.63E+08 2.63E+08 0 263203042 0 0 0 0 2.63E+08
0 0 0 0 0 0 0 0 0 0
0 21256303 21256303 0 21256303 0 0 0 0 21256303
0 357248.8 357248.8 0 357248.78 0 0 0 0 357248.8
0 3795768 3795768 0 3795768.3 0 0 0 3795711.4 56.93653
0 3029283 3029283 0 0 0 0 0 0 0
COMBUSTOR
mole balance
n1 9400108.6 11528105

mole mass
C balance (kmol/h) mole% mw (kg/hr)
CO n1 9400109 41.86119 28 2.63E+08
CO2 0.1971496 n1 1853228 8.25292 44 81542035
CH4 0.0023753 n1 22328.05 0.099433 16 357248.8

H balance
CH4 22328.049
H2 10628151 10628151 47.33 2 21256303
H2S 111640.25 111640.2 0.497164 34 3795768

N2 439967.3 439967.3 1.959292 28 12319084

22455424 3.82E+08

H2O 214497236 kg/hr 2.14E+08

carbon suspension 3029283 kg/hr 3029283
6E+08

mw mole stream 9 mass mw mole stream 11

32 7320767.4 WASTE HEAT BOILER QUENCHER
28 439967.3 output output
18 8414675.2 CO 2.63E+08 28 9400109 CO
16175410 CO2 81542035 44 1853228 CO2
CH4 357248.8 16 22328.05 CH4
mw mole H2 21256303 2 10628151 H2
28 9400108.6 H2S 3795768 34 111640.2 H2S
44 1853228.1 N2 12319084 28 439967.3 N2
16 22328.049 C 3029283 12 252440.3
2 10628151 3.86E+08 22707864
34 111640.25 stream 10 mass mw mole stream 12
28 439967.3 out H2O 2.14E+08 18 11916513 C
12 252440.26 6E+08
 18 11916513
34624377

17 18 19 20 21 22 23 24 25 26
 stream 17
H2O

mass mw mole
QUENCHER stream 13 mass mw mole stream 18
out CO conversion
2.63E+08 28 9400109 H2O 1.07E+08 18 5958257 consumption of CO
81542035 44 1853228
357248.8 16 22328.05 stream 14 CO
21256303 2 10628151 H2O 1.07E+08 18 5958257 CO2
3795768 34 111640.2 CH4
12319084 28 439967.3 H2
3.82E+08 22455424 stream 16 mass mw mole H2S
SCRUBBER N2
mass mw mole output H2O
3029283 12 252440.3 CO 2.63E+08 28 9400109
3.86E+08 CO2 81542035 44 1853228
 CH4 357248.8 16 22328.05 stream 19
H2 21256303 2 10628151 CO
H2S 56.93653 34 1.674604 CH4
N2 12319084 28 439967.3 H2S
3.79E+08 N2
H2O 1.07E+08 18 5958257 H2O
4.86E+08 28302042
stream 15 mass mw mole
H2S reduc 3795711 34 111638.6 stream 20
4.9E+08 CO2
H2

27 28 29 30 31 32 33 34 35 36
 mole MW mass
10000000 18 1.8E+08

mole mw mass stream 21 mole mw mass

CO conversion 90 % 0.9 CO conversion 80 % 0.8
consumption of CO 8460098 0.1 consumption of CO 752008.7 0.2

940010.9 28 26320304 CO 188002.2 28 5264061

10313326 44 4.54E+08 CO2 752008.7 44 33088382
22328.05 16 357248.8 CH4 22328.05 16 357248.8
19088249 2 38176498 H2 752008.7 2 1504017
1.674604 34 56.93653 H2S 1.674604 34 56.93653
439967.3 28 12319084 N2 439967.3 28 12319084
7498159 18 1.35E+08 H2O 6746150 18 1.21E+08
38302042 6.66E+08 8900467 1.74E+08
mass mw mole stream 22 mass mw mole
26320304 28 940010.9 CO2 33088382 44 752008.7
357248.8 16 22328.05 H2 1504017 2 752008.7
56.93653 34 1.674604 34592400 1504017
12319084 28 439967.3
1.35E+08 18 7498159 stream 23 mass mw mole
1.74E+08 8900467 CO 5264061 28 188002.2
CH4 357248.8 16 22328.05
mass mw mole H2S 56.93653 34 1.674604
4.54E+08 44 10313326 N2 12319084 28 439967.3
38176498 2 19088249 H2O 1.21E+08 18 6746150
1.39E+08 7396449

37 38 39 40 41 42 43 44 45 46
stream 24 mass mw mole stream 31 mass mw mole
CO 5264061 28 188002.2 H2O 91073026 18 5059613
CH4 357248.8 16 22328.05
H2S 56.93653 34 1.674604 stream 32 mass mw mole
N2 12319084 28 439967.3 H2O 91073026 18 5059613
H2O 1.21E+08 18 6746150
1.39E+08 7396449
stream 26 mass mw mole
stream 25 mass mw mole CO 1316015 28 47000.54
CO 2632030 28 94001.09 CH4 89312.2 16 5582.012
CH4 178624.4 16 11164.02 H2S 14.23413 34 0.418651
H2S 28.46826 34 0.837302 N2 3079771 28 109991.8
N2 6159542 28 219983.7 CO2 2.35E+08 44 5344665
 CO2 16544191 44 376004.3 H2 19464253 2 9732127
H2 752008.7 2 376004.3 H2O 30357675 18 1686538
H2O 60715351 18 3373075 2.89E+08 16925904
86981776 4450233
stream 29 mass mw mole
stream 28 mass mw mole CO 1316015 28 47000.54
CO 2632030 28 94001.09 CH4 89312.2 16 5582.012
CH4 178624.4 16 11164.02 H2S 14.23413 34 0.418651
H2S 28.46826 34 0.837302 N2 3079771 28 109991.8
N2 6159542 28 219983.7 CO2 2.35E+08 44 5344665
CO2 16544191 44 376004.3 H2 19464253 2 9732127
H2 752008.7 2 376004.3 H2O 30357675 18 1686538
H2O 60715351 18 3373075 2.89E+08 16925904
86981776 4450233

47 48
stream 30 mass mw mole stream 27 mass mw mole
CO 3948046 28 141001.6 CO 1316015 28 47000.54
CH4 267936.6 16 16746.04 CH4 89312.2 16 5582.012
H2S 42.70239 34 1.255953 H2S 14.23413 34 0.418651
N2 9239313 28 329975.5 N2 3079771 28 109991.8
CO2 2.52E+08 44 5720669 CO2 2.35E+08 44 5344665
H2 20216262 2 10108131 H2 19464253 2 9732127
H2O 91073026 18 5059613 H2O 1.38E+08 18 7644794
3.76E+08 21376137 3.97E+08 22884161

stream 33 mass mw mole stream 36 mass mw mole

H2O 91073026 18 5059613 CO 1316015 28 47000.54
CH4 89312.2 16 5582.012
stream 34 mass mw mole H2S 14.23413 34 0.418651
H2O 91073026 18 5059613 N2 3079771 28 109991.8
CO2 2.35E+08 44 5344665
stream 35 mass mw mole H2 19464253 2 9732127
CO 3948046 28 141001.6 H2O 1.38E+08 18 7644794
CH4 267936.6 16 16746.04 3.97E+08 22884161
H2S 42.70239 34 1.255953
N2 9239313 28 329975.5 stream 37 mass mw mole
CO2 2.52E+08 44 5720669 CO 5264061 28 188002.2
H2 20216262 2 10108131 CH4 357248.8 16 22328.05
2.85E+08 16316525 H2S 56.93653 34 1.674604
N2 12319084 28 439967.3
CO2 4.87E+08 44 11065335
H2 39680516 2 19840258
H2O 1.38E+08 18 7644794
6.82E+08 39200686
assume H2S 11 ppm H2S 1 ppm
stream 38 mass mw mole stream 41 mass mw
CO 5264060.839 28 188002.2 CO 5264060.839 28
CH4 357248.7845 16 22328.05 CH4 357248.7845 16
H2S 0.000626302 34 1.842E-05 H2S 1.315234E-20 34
N2 12319084.48 28 439967.3 N2 12319084.48 28
CO2 486874719.6 44 11065335 CO2 486874719.6 44
H2 39680515.61 2 19840258 H2 39680515.61 2
H2O 137606293.2 18 7644794 H2O 137606293.2 18
682101922.5 39200684 682101922.5
H2S reduc 56.93589872
assume H2S 7 ppm assume K2CO3 solution
stream 39 mass mw mole stream 42 mass mw
CO 5264060.839 28 188002.2 K2CO3 solu 1000000
CH4 357248.7845 16 22328.05 K2CO3 400000 138.204
H2S 4.384112E-09 34 1.289E-10 H2O 600000 18
N2 12319084.48 28 439967.3 1000000
CO2 486874719.6 44 11065335
H2 39680515.61 2 19840258
H2O 137606293.2 18 7644794 stream 43
682101922.5 39200684 K2CO3 solu 139606293.2
H2S reduc 0.000626297 K2CO3 55842517.27 138.204
assume H2S 3 ppm H2O 83763775.91 18
stream 40 mass mw mole
CO 5264060.839 28 188002.2
CH4 357248.7845 16 22328.05
H2S 1.315234E-14 34 3.868E-16 stream 44
N2 12319084.48 28 439967.3 K2CO3 solu 138606293.2
CO2 486874719.6 44 11065335 K2CO3 55442517.27 138.204
H2 39680515.61 2 19840258 H2O 83163775.91 18
H2O 137606293.2 18 7644794
682101922.5 39200684
H2S reduc 4.384099E-09
mole
188002.2 stream 46
22328.05 CO
3.868E-22 CH4
439967.3 H2S
11065335 N2
19840258 H2
7644794 CO2
39200684

1000000 kg/h assume

mole stream 45 mass mw mole stream 47
K2CO3 solutio 138606293.2 H2O
2894.272 K2CO3 55442517.27 138.204
33333.33 H2O 83163775.91 18 stream 48
36227.61 H2O
CO2

product
reactant
H2 produced
CO2 removed 97.74069

mass mw mole mole%

5264060.83893478 28 188002.2 0.906447151
357248.784454346 16 22328.05 0.107654056
1.31523372802E-20 34 3.868E-22 1.865107E-27
12319084.4833389 28 439967.3 2.121289888
39680515.6113053 2 19840258 95.65924099
11000000 44 250000 1.205367918
68620909.7180334 20740555

steam 10000000 kg/h

10000000 18 555555.6
 10000000 18 555555.6
475874719.649683 44 10815335
485874719.649683 11370890

561320680.772217
257038646.543097
1023602.2541702 m3/day
95.6592409871448 % purity