You are on page 1of 255

ADVANCED CLEANING

RODUCT FORMULATIONS
This page intentionally left blank
ADVANCED
CLEANING
PRODUCT
FOR MULATlONS
Volume 5

Ernest W. Flick

NOYES PUBLICATIONS
WILLIAM ANDREW PUBLISHING, LLC
Nomich, New York, U.S.A.
Copyright 0 1999 by Ernest W. Flick
No part of this book may be reproduced or utilized in
any form or by any means, electronic or mechanical,
including photocopying, recording or by any informa-
tion storage and retrieval system, without permission
in writing from the Publisher.
Library of Congress Catalog Card Number: 89-30274
ISBN: 0-8155-1431-X
Printed in the United States

Published in the United States of America by


Noyes Publications/William Andrew Publishing, LLC
13 Faton Avenue, Norwich, New York 13815

10 9 8 7 6 5 4 3 2

Library of Congress Cataloging-in-Publication Data


(Revised for vol. 5)

Flick, Ernest W.
Advanced cleaning product formulations

Includes bibliographical references and index.


1. Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274
ISBN 0-8155-1186-8 (v. 1)
ISBN 0-8155-1346-1 (v. 2)
ISBN 0-8155-1382-1 (v. 3)
ISBN 0-8155-1396-8 (v. 4)
ISBN 0-8155-1431-X (v. 5)
To
the late Ernie and Jeanne
and
Allyn and Barbara
and
Chris and Rachel

V
This page intentionally left blank
reface

ohme 5) presents more than 423 up-to-date advanced cleaning


product formulations for household, industrial and automotive applications. It is
the result of information received from numerous industrial companies and other
organizations. The data represent selections made at no cost to, nor influence
from, the makers or distributors of these materials. Only the most recent
formulas have been included. All formulations are completely different than
those contained in Volumes 1, 2, 3 and 4 published earlier.

~ ~ in the cleaning
~ ~ industry
product ~ has gradually
a been~undergoing~ o
significant change during the past years. Raw materials costs have risen and
manufacturers have been reluctant to pass along these increases. Environmental
considerations have also played a part. By changing formulations to improve
cost/performance characteristics, manufacturers have been able to control costs
but still enhance performance. This book presents manufacturers' suggested
formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and
chapters, with the number of formulations indicated in ( ):

H. Household and Industrial Cleaners and Polishes


1. Bathroom Cleaners (9)
2. Dairy, Food and General Industrial Cleaners (27)
3. Degreasers (9)
4. Dishwashing Detergents (34)
5. General Purpose Cleaners (31)
6. Glass CleanersPoiishes (12)
ard Surface Cleaners (21)
8. Laundry Products (55)
9. Metal Cleaners and Polishes (72)
10. Oven, Grill and Hot Plate Cleaners (9)
11. Polishes, Coatings and Finishes (6)
12. Rinse Aids (2)
13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33)
14. Miscellaneous (33)

vii
viii Preface

11. Transportation Cleaners and Polishes


15. Auto Cleaners and Polishes (6)
16. Car and Truck Wash Compounds (49)
17. Whitewall Tire Cleaners (3)
18. Miscellaneous (12)

Each formula is located in the chapter which is most applicable. The reader,
seeking a formula for a specific end use, should check each chapter which could
possibly apply. In addition to the above, there are two other sections which will
be helpful to the reader.

111. A chemical trademark section where each tradenamed raw material


included in the book is listed with a chemical description rand the
supplier's name. The specifications which each raw material meets are
included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials.


Each formulation in the book lists the following information, as available, in the
manufacturer's own words:

Description of end use and most outstanding properties.

The percent by weight or volume of each raw material included in the


formula, rounded to a decimal figure.

Key properties of the formula, which are the features that the source
considers to be more outstanding than other formulations of the same
type.

The formula source, which is the company or organization that supplied


the formula. The secondary source may be the originating company andlor
the primary source's publication title, or both. A formula number is
included, if applicable.

The table of contents is organized in such a way as to serve as a subject index.

My fullest appreciation is expressed to the companies and organizations who


supplied the original starting formulations included in this book. I also thank the
suppliers of the raw materials included in these formulations, who furnished
information describing their trademarked raw materials.

Newburyport, Massachusetts Ernest W. Flick


July 1999
This page intentionally left blank
NOTICE

To the best of our knowledge the information in this


publication is accurate; however, the Publisher does not assume
any responsibility or liability for the accuracy or completeness
of, or consequences arising from, such information. This book
is intended for informational purposes only. Mention of trade
names or commercial products does not constitute endorsement
or recommendation for use by the Publisher. Final
determination of the suitability of any information or product
for use contemplated by any user. We recommend that anyone
intending to rely on any recommendation of materials QB
procedures mentioned in this publication should satisfy himself
as to such suitability, and that he can meet all applicable safety
and health standards.

X
ntents and Subject Index

SECTION I
OUSEHOLD AND INDUSTRIAL
CLEANERS AND POLISHES

B OM CLEANERS: ............................... 2
Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . 4
Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . 4
Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
l d e w .................................
~ o w ~ ~ ~ Cleaner 5
Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . 6
Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . 6
Toilet Bowl Cleaner with Bleach ......................... 7

2. .FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8


Acid Industrial and Household Cleaners
Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Cleaners for Industrial Application
Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Destainer
sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11

Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12


Baking Pan Cleaner
phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Heavy Duty Cleaners
BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . 13
Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

xi
xii Contents and Subject Index

High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14


Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44
Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Industrial and High Pressure Cleaners
Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Cleaner. Strongly Alkaline (Phosphate-Free) . . . . . . . . . . . . . 15
Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45
Metal Cleaner
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Food Industry Cleaner
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Milk Can Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Powdered Enzyme Presoaks
Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS
Sanitizing Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Sanitizing Agent
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

.
3 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Aqueous Degreaser
d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21
Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22
Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24

4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 25
Automatic Dishwash Detergent-Consumer
(Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Consumer
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Industrial & Institutional
(Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7
Contents and Subject Index xiii

Automatic Dishwash Detergent-Industrial & Institutional


(Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28
Automatic Dishwash Detergent-Industrial & Institutional
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28
Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29
Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30
Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30
Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30
Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33
Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33
Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Foam Booster: E-14-5 in Hand Dishwashing Liquids
Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Hand Dish Detergent Formulations
Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38
Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38
Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39
Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42
Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42
Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42
Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43
Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43

.
5 GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . 44
Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . 45
rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . 46
Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . 48
AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 49
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
&alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . 50
A1 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
xiv Contents and Subject Index

All Purpose Cleaner Concentrate


(Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
All Purpose Concentrate
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5%
Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52
Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
General Purpose Cleaner
(Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54
General Purpose Cleaner
(Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54
General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55
General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57
Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57
Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59
Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60

.
6 GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62
Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63
Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65
Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Windows/Glass
Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66

.
7 HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . 68
Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Contents and Subject Index xv

Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . 71


Hard Surface Cleaner Concentrate w/d’Limonene . . . . . . . . . . . . . 71
Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . 72
Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . 72
Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . 73
Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . 75
old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76

PRODUCTS ................................ 77
gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . 80
Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . 80
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . 80
dustrial Heavy Duty Laundry Liquid . . . . . . . . . . . . . . . . . . . . 81
Industrial Laundry Detergents
High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . 82
Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
Laundry Detergent-Consumer
phosphate. Powder) ............................... 84
bundry Break-Industrial & Institutional
(Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Break-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Detergent-Industrial & Institutional
(NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Break-Industrial & Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Detergent-Industrial & Institutional
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
Laundry Detergent-Industrial & Institutional
(Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . 87
mi Contents and Subject Index

Laundry Break-Industrial & Institutional


phosphate. Powder. High Alkalinity) . . . . . . . . . . . . . . . . . . 88
Laundry Break-Industrial & Institutional
(Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88
Laundry Detergent-Industrial & Institutional
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89
Laundry Detergent-Industrial & Institutional
(NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
Laundry Detergent-Industrial & Institutional
(Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90
Laundry Detergant-Industrial & Institutional
(Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 964
Laundry Detergent-Industrial and Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
Laundry Detergent-Industrial and Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 911
Laundry Detergent-Industrial & Institutional
(Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
Laundry Detergent-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
Laundry Builder-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
Laundry Detergent-Industrial & Institutional
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 93
Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94
Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95
Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99
Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99
Two Part Industrial Laundry Detergents
Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5100
Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101
Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1641

.
9 METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 802
Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p03
Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . 104
Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . 104
Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1104
Contents and Subject Index xvii

Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . 105


Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . 106
t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . 106
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . 106
Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . 110
Aircraft Cleaner Type IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110
General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . 111
General Purpose Synthetic Fluid (€3) . . . . . . . . . . . . . . . . . . . . . 111
Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . 112
General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . 112
Metal Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
Aluminum Cleaner
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
eta1 Cleaner
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 115
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 116
Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 116
Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120
Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123
Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124
Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124
Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . 124
Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . 134
-40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . 134
Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
xviii Contents and Subject Index

10. OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . 135


Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . B36
High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . 140
Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140

.
11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . 141
Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . . 145

12. RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.46


Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147

13. RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS


AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . n48
Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . 150
Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1151
Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . 152
Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1152
Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 154
Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . 154
Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . . 156
Contents and Subject Index xix

Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . 156


Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . 157
Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . 157
Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . 158
Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . 158
uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . 158
aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . 159
m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 159
No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
No-Rinse Floor Cleaner Degreaser ...................... 160
Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . 161

CEELANEQUS ................................. 162


acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . 163
General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
d ' l h o n e n e Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . 165
Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
Dipentene Microemulsion Formulations
-alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . 166
line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
Hydrocarbon Solvent Microemulsions
Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . 168
Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . 170
Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
iao-Emulsions with d-Limonene ..................... 172
Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . 173
Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
Bottle Wash Formulations
w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . . 176
xx Contents and Subject Index

SECTION 11
TRANSPORATION CLEANERSl
AND POLISHES

.
15 AUTO CLEANERS AND POLISHES .................... 11’9’8
Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . 181
Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . 181
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 1181
Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . . 182

.
16 CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . %83
Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . 184
Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . 185
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 185
Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . 185
CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . 187
Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . 133
Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash and Care
Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . 190
Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . 190
Rinse-off Agent (Water-Repellent) Without Hydrocarbons . ~ 190
Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . 190
Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . 19B
Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . 193
Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . 194
Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Contents and Subject Index xxi

Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195


Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . 196
Heavy Duty Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . . 196
Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 197
Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Touchless Vehicle Wash Detergent
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198
Vehicle Wash Detergent (Low pH)
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198
Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Vehicle Wash Detergent
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
(Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Vehicle Wash Detergent (Low pH)
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201
Touchless Vehicle Wash Booster/Additive
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201

ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . 202


Mitewall Tire Cleaner
(Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 203
phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203

n SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
Aircraft Cleaner
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . 205
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant . . . . . . . 206
Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
ConcreteDriveway Cleaners
For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . 209
Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
xxii Contents and Subject Index

SECTION III: TRADEMARKED RAW MATE s . . . . . . . . . . 2nn


.
SECTION IV: SUPPLIERS' ADDRESSES . ... . . . . . . . . . . . . .
a ~ ~ 229
ection I
Household and Industrial
Cleaners and Polishes

1
1. Bathroom Cleaner

a
Bathroom Cleaners 3

A c i d i c Toilet Bowl C l e a n e r

Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl


c l e a n e r f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s
v e r t i c a l c l i n g t o increase t h e contact time o f t h e detergent
on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

I n s r e d ie n t : 5
DI Water 43.00
Carbopol 6 7 4 ( 1 ) 2.00
C i t r i c A c i d (50%) 50.00
A l k y l benzene s u l f o n i c a c i d 97%) ( 2 ) 2.00
Sodi um d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) ( 3 ) 3.00

B r o o k f ie l d v i s c o s i t y ( R V T 20 rpm): 4,000 cps


P r o d u c t pH: 1 .O-2.0
Product C l a r i t y : C l e a r

(1) BFGoodrich
i2j Stepan Co.: B i o s o f t 5-100
( 3 ) Dow Chemical Co.: Dowfax 2A1

Procedure:
1 . M i x t h e D I w a t e r and c i t r i c a c i d s o l u t i o n t o g e t h e r .
2 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d sol-
u t i o n . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 30 m i n u t e s . The
p r o d u c t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - h e a t i n g
t o 40-50C w i l l h a s t e n t h e p r o c e s s .
3 . Add t h e s u l f o n i c a c i d and t h e d i p h e n y l o x i d e d i s u l f o n a t e
surfactant.
4 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o
room t e m p e r a t u r e .

Total Actives:
C i t r i c a c i d : 25.00
A l k y l benzene s u l f o n i c a c i d : 1.94
Dodecyl d i p h e n y l o x i d e d i s u l f o n a t e : 1.35

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-351


4 Advanced Cleaning Product Formulatioris

Bathroom Cleaner with Disinfectant


Inqredi ents: Wt .%*
A: Veegum T, Magnesium Aluminum Silicate 1 .oo
Rhodopol 23, Xanthan Gum 0.35
Deionized Water 86.65

B: Diatomaceous Earth (Super Floss) 5.00


Tetrasodium EDTA (Hampene 100) 2.75
Sodium o-Phenylphenate (Dowicide A) 0.25
Sodi um A1 kyl benzene Sul fonate (Cal soft L - 4 0 ) 3.00
Butyl Cellosolve 1 .oo
Procedure:
1 . Dry blend the Veegum T and Rhodopol 23 and add them to the
water while stirring with an homogenizer at 5000 rpm.
Continue mixing for 30 minutes.
2. Slowly add the Part 8 ingredients in the order shown, mixing
each for 5 minutes.
* A s received basis
SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363

Heavy Duty Acid Bathroom Cleaner


Inqredi ents: Wt%
Hydroxyacetic acid 5.0
Sulfamic acid 5.0
Ammonyx LO 10.0
Water, D.I. 80.0
Mixing Procedure:
Add ingredients to water in the order given and mix until
homogeneous.
Properties:
Appearance: Clear liquid
pH, as is: 1.0
Solids, %: 1 4 . 0
Density, lbs/gal: 8.7
Use Instructions:
Use as is o r dilute as needed. Do not use on natural marble
or polished aluminum. Use gloves. Do not mix with bleach.
Storage Stability:
Formulation is freeze/thaw stable through 3 cycles.
Formulation is stable for 3 weeks @ 50C.
SOURCE: Stepan Co.: Formulation No. 200
Bathroom Cleaners 5

M i 1dew Remover

Ingredients: Wt%*
Van Gel 0 3.00
D e i o n i z e d Water 85.55
Sodium H y d r o x i d e , 50% S o l u t i o n 0.45
Sodium H y p o c h l o r i t e , 10% S o l u t i o n ( H y p u r e N ) 10.00
Vanseal NALS-30 1.oo

Procedure:
4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e
w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t
5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2 . Add sodium h y d r o x i d e and m i x u n t i l u n i f o r m l y d i s s o l v e d .
Slow t h e m i x e r t o 1 0 0 0 rpm o r l e s s .
3 . Add t h e Vanseal NALS-30. A v o i d a i r e n t r a p m e n t . M i x u n t i l
uniform.
F o r m u l a t i o n No. 458

Bowl /Mi 1dew C 1 e a n e r

Ingredients:
A: Veegum T , Magnesium Aluminum S i l i c a t e 5.00
T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) 0.25
Water 50.75

8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % 34.00
Sodium M e t a s i l i c a t e , Anhydrous 10.00

Procedure:
1 . D r y b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e
a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth.
2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g
a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m .
F o r m u l a t i o n No. 424
*As r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s


6 Advanced Cleaning Product Formulations

Tile, P o r c e l a i n a n d Bathroom C l e a n e r , A c i d

Ingredients:
Water, D . I . 75.5
Xanthan Gum 0.5
P e t r o BAF Powder 2.0
P h o s p h o r i c A c i d , 75% 12.0
H y d r o x y a c e t i c A c i d , 70% 10.0
Perfume, Dye q.s.
B l e n d i n g Procedure:
Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w
t o m i x u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n
o r d e r l i s t e d . I f p r o b l e m s d e v e l o p a d d i n g Xanthan Gum t o w a t e r ,
p r e m i x t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o
water.
F o r m u l a 529

Tub and T i l e C l e a n e r

Ingredient:
Water, D . I . 67.4
P h o s p h o r i c A c i d , 86% 17.6
H y d r o c h l o r i c A c i d , 37% 13.5
R e w o t e r i c AM TEG 0.5
V a r o n i c T202 SR 1.o
Blending Procedure:
Add in g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ie s :
V i s c o s i t y , c p s : 293
S o l i d s : 16.3%
pH: 1 . 7
F o r m u l a 530

H y p o c h l o r i t e Tub and T i l e C l e a n e r a n d M i l * S t a i n Remoz

Ingredients:
Water, D . I . 44.9
Sodium H y d r o x i d e (30%) 1.o
Varox 365 1.5
Sodi urn H y p o c h l o r i t e ( 5 . 7 % ) 52.6
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .
Typical Properties:
V i s c o s i t y , cps: 4
S o l i d s : 3.8%
pH: 13.5
F o r m u l a 531

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Bathroom Cleaners 7

T o i l e t Bowl C l e a n e r w i t h B l e a c h

Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h


c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n
provides v e r t i c a l c l i n g t o increase the contact time of the
d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

I n qr e di-w Wt%
D I Water 60.75
Carbopol 676 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) 5.00
Potassium carbonate 5.00
Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) 8.00
Amine O x i d e (30%) ( 3 ) 10.00

B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2 , 5 0 0 c p s
P r o d u c t pH: 12-13
P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodri c h
( 2 ) PQ C o r p .
( 3 ) Lonza, I n c . : B a r l o x 12

Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r
s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s ,
d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r .
M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e
s l u r r y i s homogeneous.
2 . W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and
t h e p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous.
3 . C o n t i n u e a g i t a t i o n and add t h e p o t a s s i u m c a r b o n a t e f o l l o w e d
by t h e b l e a c h .
4 . Add t h e amine o x i d e s u r f a c t a n t and m i x u n t i l homogeneous.
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .

Total Actives:
S i l i c a t e (as Si02): 1.32
C a r b o n a t e ( a s Na2C03): 3 . 8 4
Available Chlorine: 1.OO
Amine O x i d e : 3 . 0 0

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-350


2. Dairy, Food and
General Industrial Cleaner

8
D a i q , Food and General Industrial Cleaners 9

A c i d I n d u s t r i a l and Household C l e a n e r s
O x a l i c A c i d Gel

Inqredients: W t .%*
Water 53.70
Van Gel B 2.50
Rhodopol 2 3 0.80
O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n 40.00
P o l y s o r b a t e 40 (Tween 4 0 ) 3.00

Procedure:
1 . Dry b l e n d t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e o x a l i c a c i d s o l u t i o n .
3 . When a l l t h e a c i d has been added, add t h e P o l y s o r b a t e 40
and mix u n t i l u n i f o r m .
F o r m u l a t i o n N o . 466

Rust Removal J e l IY

Insredi ents: WtD/ou


Water 53.20
Van Gel B 3.00
Rhodopol 2 3 0.80
P h o s p h o r i c A c i d, 50% Aqueous Sol u t ion 40 0 0
Octoxynol-9 3 00

Procedure:
1 . D r y b l e n d t h e Van Gel 0 and Rhodopol 2 3 and add them t o he
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e P h o s p h o r i c A c i d s o l u t i o n .
3 . A f t e r a l l t h e a c i d has been added, add t h e O c t o x y n o l - 9
and mix u n t i l u n i f o r m .
F o r m u l a t i o n No. 467
*As r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s


10 Advanced Cleaning Product Formulations

Cleaners f o r I n d u s t r i a l A p p l i c a t i o n

D e s i n f e c t i n q Cleaner, A c i d

I n s ed ien t s : wts/,
water 48.0
P h o s p h o r i c a c i d (85Oh) 24.0
S u l p h u r i c a c i d (98%) 5.0
P r o p e t a l 241 3.0
Dodigen 226 20.0
F o r m u l a CT 06-06-01

D i ppi n q C1 e a n e r

In r e d ie-n-t-sL Wt%
itatger 75.5
Tetrapotassium pyrophosphate 10.0
C a u s t i c soda 1.5
D i p r o p y l e n e g l y c o l monomethyl ether 5.0
S u l f e t a l 4069 5.0
Zusol a t 1008/85 3.0
F o r m u l a CT 07-03-01

Spray C 1 e a n e r

Insredients: Q
Water 58.0
Cublen D50 3.0
T r i e t h a n o l ami ne 3.0
S u l f e t a l 4105 4.0
P r o p e t a l 241 2.0
Z u s o l a t l005/85 0.5
P h o s f e t a l 201 2.0
Butyl glycol 5.0
C i t r u s terpene 0.5
I n h i b i t o r 4000 22.0
F o r m u l a CT 07-06-01

Ingredients
water 86.0
Sul f e t a l 4105 6.0
P r o p e t a l 99 3.0
Zusolat 1005/85 0.5
Butyl glycol 4.0
Orange t e r p e n e 0.5
Formula CT 07-06-03

SOURCE: Zschimmer & Schwarz GmbH 8, C o . : General Formulations


Dairy, Food and General Industrial Cleaners I1

D e s t a in e r
(Phosphate, Powder)

S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Method-Brush
Manufacture-Dry blend/Agglomeration

Compos i t to^ Wt%


*STPP 25.0
M e t s o Beads 2048 25.0
Sodium S u l f a t e 8.0
PQ Epsom S a l t 2.0
**Octylphenoxy Polyethoxyethanol, 9- 0 M o l e s EO 2.0
Sodium P e r b o r a t e , Monohydrate 38.0

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 oz/ga ion)

* FMC
** Rhone P o u l e n c I g e p a l C A - 6 3 0

Destai ner
(Reduced Phosphate, Powder)

S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Methods-Brush
Manufacture-Dry blend/Agglomeration

Composi t i on: %
&
*STPP 10.0
M e t s o Beads 2048 25.0
Sodi um S u l f a t e 8.0
PQ Epsom S a l t 2.0
**Octylphenoxy Polyethoxyethanol, 9 - 1 0 Moles EO 2.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium P e r b o r a t e , Monohydrate 38.0

Use L e v e l : 3-6 oz/gallon

* FMC
** Rhone-Poulenc I g e p a l CA-630

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
12 Advanced Cleaning Product Formulations

Eaa C l e a n e r
L x o phosphatS?,.powder)
S o i 1- P r o t e i n
S u r f a c e - E g g and egg h a n d l i n g e q u i p m e n t
A p p l i c a t i o n M e t h o d - H i g h p r e s s u r e s p r a y (700-1400 psi)
Manufacture-Dry blend

Composi t i o n : Wt%
Sodium C a r b o n a t e 30.0
M e t s o Beads 2048 20.0
Sodium S u l f a t e 12.0
V a l f o r 100 Z e o l i t e A 30.0
* S o d i urn D i c h l o r o i s o c y a n u r a t e 2H20 3.0
* * S o d i um A1 k y l a r y l S u l f o n a t e Powder ( 9 0 % ) 5.0

Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)

* O l i n Chemical
** Witco

B g k i - n g Pan C l e a n e r
(Phosphate,- Powder)

S o i l - A n i m a l f a t and g r e a s e , v e g e t a b l e o i l
S u r f a c e - A 1 umi num and s t e e l
A p p l i c a t i o n Method-Irnmersion/brush
Manufacture-Dry blend/Agglomeration

C So n
O ~ ~t 1 l : Wt%
*Sodium C a r b o n a t e 35.0
*STPP 12.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s € 0 3.0
Metso Pentabead 2 0 50.0

Use D i l u t i o n . 1 . 5 % bw ( 2 o z / g a l l o n )

* FMC
** Rhone-Poulenc I g e p a l CO-630

SOURCE: PQ C o r p . . Detergent F o r m u l a t i o n Guide


Dairy, Food and General Industrial Cleaners 13

Heavv D u t v C l e a n e r s
A l l Purpose-Food P r o c e s s P l a n t

Ingredients: Weight%
Water 74.00
EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) 2.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.00
P i l o t SXS-40 5.00
KOH, 45% 10.00
Calamide C 5.00

Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r l i s t e d .
2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n .
3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r .
4. EDTA can b e s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l
solution.
5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s .
6 . Use l e v e l . 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HDC-004-01

Hard S u r f a c e Spray Cleaner

Inqredients:
- Weight%
Water 89.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 1.oo
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
C a l s u d s 81 4.00
NH40H, 28% 3.00

Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t Water and TKPP when m i x e d a r e c l e a r .
2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l M o n o b u t y l E t h e r i s added.
3 . W i t h t h e a d d i t i o n o f C a l s u d s 81 t h e s o l u t i o n t u r n s c l e a r and
has a pH o f 9.
4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 1 2 .
F o r m u l a t i o n HDC-002-01

SOURCE: P i 1o t Chemical Co. : Suggested Formul a t i ons


14 Advanced Cleaning Product Formulations

H i qh Foaming A1 k a l ine C l e a n e r

M o n a t e r i c EH c o n t r i b u t e s t o d e t e r g e n c y and e f f e c t i v e l y con-
t r o l s b o t h t h e k r a f f t and c l o u d p o i n t i n t h i s h i g h foaming
formulation.
I n n r e d ie n t s : Wt9/o
Water 76.0
Sodium H y d r o x i d e (50%) 10.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 2.0
Dodecyl benzenesul f o n i c a c i d 2.0
M o n a t e r i c EH 8.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommened Use D i l u t i o n : 1 : 2 0 w i t h w a t e r
F o r m u l a t i o n F-768

Heavy D u t y A l k a l i n e Degreaser

M o n a t e r i c EH a i d s i n t h e removal o f o i l y s o i l s w i t h o u t emul-
s i f i c a t i o n . I t e a s i l y displaces o i l y s o i l s from hard surfaces
and keeps them f r o m r e d e p o s i t i n g .
Ingredients: Wt%
Water 65.0
Sodi u m H y d r o x i de ( 5 0 % ) 20.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 3.0
M o n a t e r i c EH 10.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommended Use D i l u t i o n : 1 : 2 0 w i t h w a t e r .
F o r m u l a t i o n F-769

Steam C1eaner

Mona NF-20 c o n t r i b u t e s t h e non-foaming and d e t e r g e n c y proper-


t i e s i n t h i s formulation.
I n a r e d ients: WtO/o
Water 65.00
P o t a s s i um H y d r o x i d e 3.00
Sodium M e t a s i l i c a t e (Anhydrous) 10.00
T e t r a p o t a s s i um Pyrophosphate 10.00
Mona NF-20 12.00
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
Typical Properties:
Cloud P o i n t : 75C
K r a f f t Point: tOC
Recommended Use D i l u t i o n : 4-6 o z . / g a l .
F o r m u l a t i o n F-762

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Dairy, Food and General Industrial Cleaners 15

I n d u s t r i a l and Hiqh Pressure Cleaners


C1 eaner. Strong1 y A1 Kal ine
-
Inqredients: yw%
Water 76.5
Cublen D 50 1.o
Tetrapotassi um pyrophosphate 4.0
C a u s t i c soda 0.6
Sodi u m m e t a s i 1 i c a t e 4.9
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 06-13-01

C1 e a n e r , Weakly A1 k a l ine
Ingredients: Wt%
Water 80.4
Cublen D 50 1.o
Tetrapotassium pyrophosphate 2.0
T r i e t h a n o l ami ne 3.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 0 6 - 1 3 - 0 2

Cleaner, S t r o n q l y A1 k a l i n e (Phosphate-Free)
I n g r e d i e c Wt%
Water 80.5
Cublen D50 1. o
Sodi um m e t a s i 1 i c a t e 4.9
C a u s t i c soda 0.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 06-13-03

@1eaner, Weak1 y A1 k a l ine ( Phosphate-Free1


Ingredients: Wt%
Water 80.4
C u b l e n D 50 1. o
T r i s o d i um c i t r a t e 2.0
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
T r i e t h a n o l ami n e 3.6
F o r m u l a CT 06-13-04

SOURCE: Zschimmer & Schwarz GmbH & C o . : General Formulations


16 Advanced Cleaning Product Formulations

Metal Cleaner
(m
S o i l - P e t r o l e u m and a n i m a l o i l and g r e a s e
Surface-Metal: Steel
A p p l ic a t i on Method-Immersi on
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : w.t%
Water 65.6
S t a r Sodi um S i 1 ic a t e 15.6
Sodium H y d r o x i d e (50%) 6.3
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 7.5

Use D i l u t i o n : 2%-5% b v

* Rhone-Poulenc Rhodafac RE-610


** Rhone-Poulenc R h o d a s u r f 91-6

Food I n d u s t r y C l e a n e r
(W
S o i l - H e a v y f o o d g r e a s e , o i l and p r o t e i n
Surface-Metal, ceramic, polymeric, glass
A p p l i c a t i o n Method-Wipe, mop o r b r u s h
Manufacture-Mix t a n k w i t h p r o o e l l e r s t i r r e r

Composition: Wt%
Water 74.0
TKPP (60%) 3.0
N C l e a r Sodium S i l i c a t e 7.0
Sodi um H y d r o x i d e (50%) 3.5
*Phosphate E s t e r 2.5
**Ethylene Glycol n-Butyl Ether 5.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 6 . 5 Moles € 0 ) 5.0

Use D i l u t i o n : 6-12% bw ( 8 - 1 6 o z / g a l l o n )

* Rhone-Poulenc Rhodafac RE-600


** Dow C h e m i c a l , U n i o n C a r b i d e
*** Rhone-Poulenc R h o d a s u r f LA-7

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide


Dairy, Food and General Industrial Cleaners 17

M i l k Can C l e a n e r
(Phosphat_e, Powder)

Sol 1 - F a t and p r o t e i n
Surface-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend/Agglomeration

Compo_sition’ WX/,
*STPP 30.0
M e t s o Beads 2048 30.0
*Sod1 u m C a r b o n a t e 35.0
+*Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
* * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0

Use D i l u t i o n 0.75-1 5% bw (1-2 o z / g a l l o n )

* FMC
** O l i n Chemical
*** w1 t c o

M i l k Can CLea-ner
(Zeco Phosphate, Powder)

S o l 1 - F a t and p r o t e i n
S u r f ace-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend

Composi t i on : Wt%
Val f o r 100 Z e o l i t e A 20.0
Metso Pentabead 20 40.0
Sodium C a r b o n a t e 35.0
*Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
**Sod1 um A 1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0

Use L e v e l : 1 - 2 o z / g a l l o n

* O l i n Chemical
** Stepan, W i t c o

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
18 Advanced Cleaning Product Formulations

Powdered Enzyme Presoaks


Economy Presoak
Component: Wt%
Soda Ash 80.0
Sodium Metasilicate Pentahydrate 10.0
Sodium Dodecylbenzenesulfonate Powder 5.0
Burcosperse AP Powder 3.0
Burcotase EP-60 2.0

Premi um Presoak

Component: 5
Soda Ash 40.0
STPP 35. n
Neodol 25.7 5.0
Sodium Metasi 1 icate Pentahydrate 10.0
Sodium Dodecylbenzenesulfonate Powder 5.0
Burcosperse AP Powder 3.0
Burcotase EP-60 2.0

The recommended use concentration o f these products i s 1-4


g/1 in the presoak bath. F o r optimum results, the presoak
temperature should be 130-15OF.

Enzyme Prespotter f o r Oilv/Smuttv Soils

Component: wtD/,
Water 49.0
Propyl ene G1 ycol 10.0
Dodecyl benzenesul foni c Acid 10.0
TEA-85 20.0
Burco TME 5.0
Nonionic Surfactant* 5.0
Burcotase LL-100 1.o

*An HLB of 9 . 5 - 1 0 . 0 i s preferred. Alcohol ethoxylates are


preferred.
Add components in the order listed. Blend until uniform
between each addition. Cool before adding the enzyme.

SOURCE: Burlington Chemical G o . , Inc. : Suggested Formulations


Dairy,Food and General Industrial Cleaners 19

S a n i t i z i n s Cleaner
(Phosphate, Powder)

S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , e t c .
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry Blend

Composi t 1 1 0 ~ Wt%
Metso Beads 2048 20.0
*Sodium C a r b o n a t e 35.0
*STPP 30.0
**Sodi urn D i c h l o r o i s o c y a n u r a t e , 2H20 10.0
***Sod; um A1 k y l a r y l S u l f o n a t e Powder (99%) 5.0

Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)

* FMC
** 01 i n Chemical
*** witco

Sani t i z i na A a e n t
(Phosphate, Powder)_

S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , etc.
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe, b r u s h
Manufacture-Dry blend/Agglomeration

Composi t i on : Wt%
*STPP 30.0
*Sodi um C a r b o n a t e 25.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; 12 M o l e s EO) 10.0
M e t s o Pentabead 20 30.0
Quaternary Germicide 5.0

Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)

* FMC
** Rhone-Poulenc R h o d a s u r f LA-12

SOURCE: PQ C o r p . : Detergent F o r m u l a r y Guide


3. Degreaser

20
Degreasers 21

Aqueous D e s r e a s e r

Ingredients: Wei q h t %
Water 60.80
NaOH, 50% 2.00
Cal s o f t LAS-99 9.40
P i l o t SXS-40 8.70
C a l o x y l a t e N-9 4.60
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.70
Sodium M e t a s i 1 i c a t e 6.60
E t h y l e n e G l y c o l Monobutyl Ether 3.20

Comments a b o u t t h i s f o r m u l a :
D i s s o l v e t h e s a l t s i n t h e water f i r s t .
F o r m u l a t i o n DEG-001-01

Aqueous D e q r e a s e r
d - L i monene M i c r o e m u l s i o n

Ingredients: Weight%
d - L i monene 9.90
C a l s u d s CD-6 9.80
C a l imu1 se PRS 2.44
Diethylene Glycol n-Butyl Ether 4.93
Water 73.00

Comments a b o u t t h i s f o r m u l a :
1 . A d d i t i o n a l C a l s u d s CD-6 may b e needed t o c l a r i f y t h e sample.
2 . Add t h e w a t e r s l o w l y .
F o r m u l a t i o n DEG-002-01

Water Based D e a r e a s e r

Ingredients: Weight%
Water 68.50
NaOH, 50% 2.00
Cal s o f t LAS-99 7.00
P i lot SXS-40 7.50
Na4EDTA 2.00
C a l o x y l a t e N-9 5.00
E t h y l e n e G l y c o l Monobutyl Ether 3.00
Sodi urn M e t a s i 1 ic a t e 5.00

Comments a b o u t t h i s f o r m u l a :
1 . T h e r e i s a p h o s p h a t e v e r s i o n where 3 . 5 % sodium t r i p h o s p h a t e
i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA.
2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s .
F o r m u l a t i o n DEG-006-01

SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s


22 Advanced Cleaning Product Formulatiorrs

m r e a s e r Concentrate
( L i q u i d)

Soil-Grease, o i l
Surface-Pai n t , polymeric, metal
A p p l i c a t i o n Method-Spray o r w i p e
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : wt"/o
Water 67.0
M e t s o Beads 2048 8.0
*Sodi urn P o l y a c r y l a t e (40%) 5.0
**Phosphate E s t e r 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 M o l e s EO) 5.0
* * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 5.0

Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n )


Heavy D u t y - 3 . 0 % bw ( 4 o z / g a l l o n )

* Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%)


** Rhone-Poulenc Rhodafac R E - 6 1 0
*** Rhone-Poulenc R h o d a s u r f 91-6
**** Rhone-Poulenc R h o d a s u r f A-24

Metal De-Oiling L i q u i d Concentrate


( L i quid )

Soi 1 - P e t r o l e u m - b a s e d o i 1
S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c .
Appl i c a t i o n Method-Spray a n d / o r immersi on
Manufacture: Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : W B
Water 42.0
S t a r s o Sodi urn S i 1 i c a t e 12.0
EDTA, T e t r a s o d i u m (37%) 16.0
Sodium X y l e n e S u l f o n a t e (40%) 20.0
* L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 M o l e s EO) 3.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11 2 . 5 M o l e s EO) 7.0

Use D i l u t i o n : 2%-4% b v

* Rhone-Poulenc R h o d a s u r f 91-6
** Rhone-Poulenc R h o d a s u r f A-24

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t on G u i d e
aegreasers 23

S o l v e n t Denreaser

Carbopol r e s i n s a r e used t o e m u l s i f y and s t a b i l i z e t h i s


d-limonene o i l based e m u l s i o n . I n a d d i t i o n , t h e use o f t h e
r e s i n provides v e r t i c a l c l i n g t o increase the contact time o f
t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer
convenience.

I n q r e d ient : 9
D I Water 81.18
Carbopol ETD 2623 ( 1 ) 0.32
d-Limonene ( 2 ) 10.00
Propylene g l y c o l methyl e t h e r ( 3 ) 2.00
Alkylbenzene s u l f o n i c a c i d ( 4 ) 2.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 5 ) 1.50
Isopropanol 2.50
Sodium h y d r o x i d e (50%) 0.50

B r o o k f ie l d v i s c o s i t y (RVT-20 rpm) : 750 cps


P r o d u c t pH: 9 . 5 - 1 0
P r o d u c t C1 a r i t y : Opaque

(1) BFGoodrich
(2) A r y l e s s e n c e , I n c . : H-7892 d-limonene
(3) Dow Chemical : Dowanol PM
(4) Stepan C o . : B i o s o f t S-100
(5) S h e l l Chemical: Neodol 23-6.5

Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogene-
ous.
3 . Reduce a g i t a t i o n and add t h e g l y c o l e t h e r , s u l f o n i c a c i d , and
alcohol ethoxyl ate.
4 . Add t h e i s o p r o p a n o l .
5 . Add t h e sodium h y d r o x i d e u n t i l t h e t a r g e t pH r a n g e i s
reached.
6 . Add c o l o r , as d e s i r e d .

T o t a l Actives:
d-limonene: 10.0
Propylene g l y c o l methyl e t h e r : 2.0
Sodium a1 k y l b e n z e n e s u l f o n a t e : 2.2
Psopropanol : 1.5
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 2.5

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-330


24 Advanced Cleaning Product Formulations

S o l v e n t Based Deqreaser

Insredients: Wei ghP%


Kerosene 72.85
Aristonate M 3.00
Pine O i l 10.00
T a l l O i l F a t t y Acid 10.06
C a l o x y l a t e N-9 3.02
Hexyl ene G1 y c o l 1.06

Comments a b o u t t h i s f o r m u l a :
1 . Use a l o w o d o r g r a d e o f t a l l o i l f a t t y a c i d .
2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d .
3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~
F o r m u l a t i o n DEG-004-01

S o l v e n t Based Degreaser

Ingredients: We ig h t %
Aristonate M 5.10
T r i t o n X-45 5.00
T r i t o n N-101 2.99
Kerosene 86.93

Comments a b o u t t h i s f o r m u l a :
1 . Kerosene can be s u b s t i t u t e d w i t h A r o m a t i c Naphtha.
2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L .
F o r m u l a t i o n DEG-003-01

E n q i n e C l e a n e r and Deqreaser

Ingredients: Weight%
Water 58.94
M I PA 20.33
C a l imu1s e PRS 5.08
Dowanol DPM 45.24
Na4EDTA 0.41

Comments a b o u t t h i s f o r m u l a :
Clear, p a l e y e l l o w product
F o r m u l a t i o n DEG-005-01

SOURCE: P i 1o t Chemi c a l Co. : Suggested Formul a t ions


lshwashing Detergents

25
26 Advanced Cleaning Product Formulations

A u t o m a t i c Dishwash Deteraent-Consumer
( Z e r o Phosohate. C h l o r i n e F r e e . Powder1

S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration

Composi t i on :
Sodi urn C i t r a t e D i h y d r a t e 10.0
* B r i t e s i l H20 Hydrous P o l y s i l i c a t e 20.0
Sodi urn C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol id s ) 4.0
****Sodium P e r b o r a t e Monohydrate 10.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 15.0

* 2 . 0 w e i g h t r a t i o powder w i t h 1 7 . 5 % w a t e r
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; o r use a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l
479ND ( 2 w t . % each)
**** O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

A u t o m a t i c Dishwash Detersent-Consumer
(Phosphate, C h l o r i n e F r e e , Powder)

S o i 1-Food g r e a s e , o i 1 and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry blend/Agglomeration

Composi t i on :
RU L i q u i d Sodium S i l i c a t e 15.0
*Sodium C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND Sodi um P o l y a c r y l a t e (92% s o l id s ) 4.0
****Sodium P e r b o r a t e M o n o h y d r a t e 10.0
*STPP 30.0
Sodi um S u l f a t e 15.0

* FMC
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t . % each)
**** O r u s e Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t %. B a l a n c e w i t h s u l f a t e .

SOURCE: PO C o r p . : Detergent F o r m u l a t i o n Guide


Dishwashing Detergents 27

A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate, S o l i d B l o c k )

S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Solid block

Composi t i on : Wt%
M e t s o Beads 2048 25.0
NaOH (50% S o l u t i o n ) 25.0
*STPP 35.0
*Sodi um C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 M o l e s EO; C12-15) 3.0

* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7

A u t o m a t i c D i shwashi n g D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l
(L iquid)

S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , c e r a m i c and g l a s s
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition : Wt%
Water 50.9
* A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) 6.9
* * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) 3.0
P o t a s s i um H y d r o x i d e (45%) 1.2
TKPP (60%) 25.0
N C l e a r Sodium S i l i c a t e 13.0

Use D i l u t i o n : 0 . 1 5 - 0 . 3 0 % bw ( 0 . 2 - 0 . 4 oz/gallon)

* Rohm & Haas; o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % )


** Rohm & Haas; o r Rhone-Poulenc A n t a r o x EL-330

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide


28 Advarrced Clearring Product Formulatiorls

A u t o m a t i c D i s h w a s h D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j
(Zero-Phosphate, C h l o r i n e F r e e , Powde_rj

S o i l - F o o d g r e a s e , oil and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manuf a c t u r e - D r y B1 e n d / A g g l o m e r a t i on

Composi t io n : Wt%
M e t s o P e n t a b e a d 20 30.0
Sod1 um C a r b o n a t e 26.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s € 0 ; C12-15) 3.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e ( 9 2 % s o l i d s ) 4.0
***Sodium P e r b o r a t e M o n o h y d r a t e B l e a c h 10.0
Val f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 12.0

* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r


S h e l l C h e m i c a l Neodol 25-7
** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l
479ND ( 2 w t % e a c h ) .
*** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e )
a t 2 w t % . Balance w i t h s u l f a t e .

Autom.aticP~hwa~h_Dete~e_n~ . ~ I ~1.d_&-Ins
Stri-a -u t_ii-tluti_ o?e_a_8
LP h o s p h a t e _ , C h l _ o r i n e _Free- Pow_s1ec)
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration

Composition: Wt%
G t s o P e n t a b e a d 20 30.0
*STPP 25.0
* S o d i um C a r b o n a t e 28.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s EO; C12-15) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol i d s ) 4.0
****Sodium P e r b o r a t e Monohydrate B l e a c h 10.0

* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l C h e m i c a l Neodol 2 5 - 7
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t % e a c h )
**** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s
c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

SOURCE: PP C o r p . : Detergent F o r m u l a t i o n Guide


Dishwashing Detergents 29

A u t o m a t i c D i s h w a s h i ng Gel w i tJ1_..Chlori n e B1 e a c h

Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce


s p l a s h i n g , p r o v i d e c u p r e t e n t i o n i n t h e d i s h w a s h e r , and c r e a t e a
s t a b l e suspension o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s
AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h .

Inqredient: Wt%
01 w a t e r 44.75
C a r b o p o l 672 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) 15.00
P o t a s s i urn c a r b o n a t e ( 3 ) 5.00
Sodium t r i p o l y p h o s p h a t e ( 4 ) 20.00
S o d i um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) 8.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 ) 1.oo

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 15,000 cps


P r o d u c t p H : 12-13
P r o d u c t c l a r i t y : Opaque

(1 BFGoodri c h
( 2 The PO C o r p .
( 3 Armand
(4 FMC C o r p .
( 5 ) O o w C h e m i c a l : Dowfax 382

Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l 1e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous
and f r e e o f p o l y m e r l u m p s .
2 . Add i n t h e p o t a s s i u m h y d r o x i d e a n d p o t a s s i u m s i l i c a t e . M i x
u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s
poi n-t.
3 . Add t h e p o t a s s i u m c a r b o n a t e and p h o s p h a t e . M i x u n t i l t h e r e
a r e no more p h o s p h a t e p a r t i c l e s . H e a t i n g t o 50-60C w i l l
speed t h i s p r o c e s s .
4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous.
A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o r e d u c e
t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . Cool t h e p r o d u c t t o
b e l o w 30C t o a v o i d e x c e s s i v e b l e a c h d e c o m p o s i t i o n .

Total Actives:
Phosphorous c o n t e n t : 5.0
S i l i c a t e (as Si02): 3.9
C a r b o n a t e ( a s Na2CO3): 3.8
Ava i 1a b 1e c ti 1o r ine : 1.o

SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-100


30 Advanced Cleaning Product Formulations

Clear, C o l o r l e s s Manual - D i s h Wash

Insredients: Wt%
Water, D . I. 57.5
W i t c o l a t e ES-3 34.2
R e w o t e r i c AM 8-14 5.0
Ethanol 3.0
Sodium C h l o r i d e 3.3

B l e n d i n g Procedure:
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . D i s s o l v e c o m p l e t e l y
between each a d d i t i o n .

Comment:
R e w o t e r i c AM 8-14: Grease c u t t e r and foam b o o s t e r .
Formula 1 3 2

Powder S t a i n l e s s S i l v e r w a r e Pre-Soak

I n q r e d ie n t s : Wt%
Sodium Carbonate (Soda Ash) 67.0
P e t r o BAF Powder 5.0
DeSonic 1 1 N 11 . o
T r i s o d i um Phosphate, Anhydrous 2.0
C a u s t i c Soda Beads 25.0

61 e n d i ng P r o c e d u r e :
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d

Use D i 1u t u i on : 1 o z / g a l
Formula 1 2 7

Low A1 k a l ine Warewashi nq Block

I n q r e d ie n t s : W B
Water, D . I . 16.0
R.U. S i l i c a t e 29.0
DeSoni c LFD-97 2.0
Sodium Carbonate (Soda Ash) 23.0
Sodium T r i p o l y p h o s p h a t e Code 185 30.0

B l e n d i n g Procedure:
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . When s l u r r y i s
produced, p o u r i n t o molds and a l l o w t o harden.
Formula 1 2 9

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 31

Dish Washi nq Agents


clear, liquid, 25% W A S
alkanesulphonate:ethersulphate=4:l

Ingredi e m
A : H o s t a p u r SAS 6 0 33.30
Genapol Z R O l i q u i d 17.90

B: Water 48.50
Preservative 0.10
DY e
q.s.
Perfume 0.20

Tests:
v i s c o s i t y (rnPas) : 75
C l o u d p o i n t : <-5C

Inqredients: Wto/,
A : H o s t a p u r SAS 60 33.30
Genapol ZRO l i q u i d 17.90

B: Water 47.50
P r e s e r v a t iv e 0.10
DYe
q.s.
Perfume 0.20
Genagen LAB 1 .oo

Tests:
V i s c o s i t y (mPas): 100
Cloud p o i n t : <-5C

Inqredients:
A : H o s t a p u r SAS 60 33.30
Genapol ZRO l i q u i d 17.90

B: Water 44.50
Preservative 0.10
DY e
9,s.
Perfume 0.20
Genagen LAB 4.00

Tests:
V i s c o s i t y (mPas): 2 3 0
C l o u d p o i n t : <-5c

Manufacturing:
One a f t e r a n o t h e r , t h e components o f B a r e added t o A

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s


32 Advanced Cleaning Product Formulations

D i s h Washi nq A g e n t s
C l e a r , liquid, 30% WAS
a1 k a n e s u l p h o n a t e : e t h e r s u l p h a t e = 4 : 1

Insredients: W B
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21 . 4 0

€3: Water 37.30


Preservative 0.10
q.s.
DY e
Perfume 0.20
Genagen LAB 1.oo

Tests:
V i s c o s i t y (mPas) : 380
C l o u d p o i n t : <-5C

Inqredients: wtsl,
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21.40

0 : Water 37.30
Preservative 0.10
q.s.
DY e
Perfume 0.20
Hoe S 3924 1 .oo

Tests:
V i s c o s i t y (mPas) : 420
C l o u d p o i n t : <-5C

Ingredients: wt./,
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21.40

El: Water 34.30


P r e s e r v a t iv e 0.10
DY e
q.s.
Perfume 0.20
Hoe S 3924 4.00

Tests:
V i s c o s i t y (mPas) : 61 0
C l o u d p o i n t : <-5C

Manufacturing:
One a f t e r a n o t h e r , t h e components o f 8 a r e added t o A .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s


Dishwashing Detergents 33

D i s h Wash w/Am&e Oxide/LABS/SLES

lngredients: Wtl
Water, D . I . 66.3
W i t c o n a t e 1240 10.3
Varox 1770 5.3
W i t c o l a t e SE-5 18.1

81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y
between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y .

Typical Properties:
V i s c o s i t y , c p s : 620
S o l i d s : 16.8%
pH: 9 . 1 2
F o r m u l a 117

D i s h Wash w / A m i n e Oxi de/LABS/ALES

I n g r e d i e n t s1
Water, D . I . 70.0
W i t c o n a t e 1240 13.8
Varox 1770 3.1
W i t c o l a t e LES-6OA 8.2
Ethanol 5.0

B1 end? ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5.

Typical Properties:
V i s c o s i t y , cps: 4
S o l i d s : 10.1%
pH: 6 . 6 8
F o r m u l a 118

Hand Di shwashi ng L i sui d


__

Ingredients: K%
Water 60.0
W i t c o n a t e AOS 26.0
W i t c a m i de 128T 4.0
W i t c o l a t e LES-6OC 10.0

Blendjng Instructions:
Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g w e l l between
a d d i t i ons .
F o r m u l a 106

SOURCE: Witco Corp.: Suggested F o r m u l a t i o n s


34 Advanced Cleaning Product Formulations

Foam B o o s t e r : Ez-4-5 in Hand D i shwashi na L i q u i d s

L i q u i d d i s h f o r m u l a t o r s a r e challenged t o produce low c o s t


q u a l i t y p r o d u c t s . Hand d i s h d e t e r g e n t s a r e e x p e c t e d t o foam i n
t h e p r e s e n c e o f f o o d s o i l s , c u t g r e a s e and c l e a n . I n a d d i t i o n ,
a e s t h e t i c s , s k i n m i l d n e s s , and e n v i r o n m e n t a l i m p a c t a r e a l s o
m a j o r p r o d u c t c o n s i d e r a t i o n s . The f o l l o w i n g d a t a i l l u s t r a t e d how
E-14-5 can b e used t o f o r m u l a t e c o s t e f f e c t i v e p r o d u c t s s u i t a b l e
f o r t h e v a r i o u s l i q u i d d i s h soap m a r k e t segments. O p t i m i z e d
l i q u i d d i s h d e t e r g e n t s c o n t a i n i n g E-14-5 p r o v i d e t h e optimum i n
c o s t p e r f o r m a n c e when compared t o a l l o t h e r t y p e s o f foam
b o o s t e r s . A l t h o u g h i t p e r f o r m s w e l l a l o n e , E-14-5 s y n e r g i s t i c a l l y
enhances t h e p e r f o r m a n c e o f most t r a d i t i o n a l foam b o o s t e r s a s
i l l u s t r a t e d b e l o w w i t h Coco d i e t h a n o l a m i d e .

Economy Eormul a t i on

In g r e d i e n t s : Wt.%
Deionized water 59.7
Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) 2 5 . 9 ( 15)
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) 8.4(5)
Ethyl alcohol 0
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3

Standard Formulation

In g r e d i e m wt>
Deionized water 52.9
Dodecylbenzene s u l f o n a t e , sodium s a l t , ( 6 0 % s o l i d s ) 31 . 0 ( 1 8 )
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) 10. l ( 6 )
Ethyl alcohol 1.5
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3

90% Premi u m Formul a t ion

Inqredi ents: Wt.%


Deionized water 38.6
Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) 38.8(22.5)
L a u r y i a l c o h o e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) 12.6(7.5)
Ethyl alcohol 4
Tomah E-14-5 3
Coco d i e t h a n o ami de

_ _ urn _F o r _
Premi m u l a~t i o n- ~

I n q r e d i en& Wt.%
Deionized water 28.3
Dodecyl benzene s u l f o n a t e , s o d i um s a l t , (60% s o l i d s ) 46.6( 27)
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) 15.1 (9)
Ethyl alcohol 4
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 35

Hand D i s h D e t e r a e n t F o r m u l a t i o n s
C l e a r D i shwash

IngredienPs 1 \N t %
Water 12.30
SXS (4O%j 8.00
C12 A i f a O i e f in s u i f o n a t e ( 2 8 . 7 5 % s o i i d s j 52.50
Lauryl e t h e r s u l f a t e - 3E0 (27.5% s o l i d s ) 18.20
Tomah AO-728 S p e c i a l 6.00
NaCl* 3.00

M i x i ng I n s t r u c t i o n s :
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i l homogeneous a f t e r each a d d i t i o n

SpG 2 0 / 2 0 C : 1 . 0 5
pH: 6
V i s c o s i t y : 505 c p s ( B r o o k f i e i d LVT 3 0 rpm s p i n d l e number 2)

NOTES: *Add more N a c l t o i n c r e a s e v i s c o s i t y .

__
P e a r i e s c e n t U i shwash

ingredients: WLL7O
Water 54.40
Dodecyibenzene s u i f o n a t e ( 6 0 % s o l i d s ) 25.00
C a u r y i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j 8 . 30
O p a c i f i e r L a t e x (4OWja 0.04
P e a r l i z i n g Agent ( 4 7 % j * * 2.30
Tomah A0-728 S p e c i a i 4.00
Tomah A m p h o t e r i c L 6.00

Mixing Instructions:
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i i homogeneous a f t e r each a d d i t i o n .

SpG 2 0 / 2 0 C : 1 . 0 3
PH: 6.5
V i s c o s i t y : 1363 c p s ( B r o o k f i e l d LVT, 12 rpm, s p i n d l e number

NOTES: * L y t r o n 295 Mortor! i n t e r n a t i o n a l


** E u p e r i a n PK-771, Henkei

SOURCE: Tomah P r o d u c t s , f n c . : Suggested F o r m u l a t i o n s


36 Advanced Cleaning Product Formulations

Hand D i s h w a s h i n g L i q u i d

C a r b o p o l r e s i n s c a n be used t o b u i l d r h e o l o g y i n p l a c e o f
u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l
and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e ,
t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y .

Inqredient: Q
D I Water 38.11
Carbopol ETD 2623 ( 1 ) 0.70
5 8 0 0 MW p o l y a c r y l i c a c i d ( 2 ) 4.00
A l p h a s u l f o m e t h y l e s t e r (37%) ( 3 ) 27.03
TEA (99%) 5.50
Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) 17.86
Coconut d i e t h a n o l ami de ( 5 ) 2.00

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 400-600 cps


P r o d u c t pH: 6 . 0 - 7 . 0
Product c l a r i t y : Clear

( 1 ) BFGoodrich
( 2 ) BFGoodrich: Good-Rite K-7058
( 3 ) Stepan Co.: A l p h a s t e p ML-40
( 4 ) Henkel C o r p . : S t a n d a p o l ES-3
( 5 ) Stepan C o . : N i n o l 11-CM

Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
P r e h e a t t h e w a t e r t o 40-5OC. Screen t h e Carbopol r e s i n i n t o
t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w
t o m i x f o r a t l e a s t 15 m i n u t e s o r u n t i l homogeneous and f r e e
o f p o l y m e r lumps.
2 . Add i n t h e l o w m o l e c u l a r w e i g h t p o l y a c r y l a t e w i t h c o n s t a n t
mixing.
3 . Add i n t h e ASME s u r f a c t a n t w i t h a l o w l e v e l o f a g i t a t i o n
t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
4 . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and c o c o n u t DEA.
5 . A d j u s t t h e pH u s i n g TEA t o r e a c h t h e t a r g e t r a n g e . Add c o l o r
and p e r f u m e , a s d e s i r e d . Cool b a t c h t o room t e m p e r a t u r e .

Total Actives:
Alpha s u l f o methyl e s t e r : 10.00
Sodium l a u r y l e t h e r s u l f a t e : 5.00
Coconut d i e t h a n o l a m i d e : 2.00
5 8 0 0 MW p o l y a c r y l i c a c i d : 2.00

SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-I10


Dishwashing Detergents 37

Hand Dishwashina P a s t e

Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n


t h i s hand d i s h w a s h i n g p a s t e . A d d i t i o n a l l y , because o f t h e i r h i g h
y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e t h e foam
s t a b i 1it y .

I n a r e d ient : Wt%
D I water 41.50
Carbopol 672 ( 1 ) 1 .oo
A l k y l b e n z e n e s u l f o n i c a c i d (9796) ( 2 ) 17.00
Sodi um h y d r o x i d e (50%) 5.00
2 . 4 r sodium s i l i c a t e (52%) ( 3 ) 7.50
Sodium t r i p o l y p h o s p h a t e ( 4 ) 15.00
Sodium c a r b o n a t e 5.00
Sodium o l e f i n s u l f o n a t e (40%) (5) 8.00

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 75,000 cps


P r o d u c t pH: 10-11
P r o d u c t c l a r i t y : Opaque

( 1) BFGoodri ch
(2) Stepan Co.: B i o s o f t S-100
(3) The PO Corp.
(4) FMC Corp.
( 5 ) Stepan Go.: E i o t e r g e AS-40

Procedure:
1 . Use a L i g h t n i n ’ M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneou
and f r e e o f polymer lumps.
2 . Add t h e s u l f o n i c a c i d w i t h c o n t i n u o u s a a i t a t i o n .
3 . Add t h e sodium h y d r o x i d e and sodium s i l i c a t e w i t h c o n t i n u o u s
a g i t a t i on. M i x u n t i1 homogeneous.
4 . S l o w l y , add t h e phosphate. M i x u n t i l homogeneous and f r e e o f
phosphate p a r t i c l e s . H e a t i n g t h e p r o d u c t t o 50-60C w i l l speed
up t h i s p r o c e s s .
5 . Add t h e sodium c a r b o n a t e and o l e f i n s u l f o n a t e . M i x u n t i l
homogeneous.
6 . A d d c o l o r and f r a g r a n c e , as d e s i r e d .

T o t a l A c t ives :
Phosphorous c o n t e n t : 3.7
S i l i c a t e (as Si02): 2.7
Carbonate ( a s Na2C03): 5.0
Sodium o l e f i n s u l f o n a t e : 3.2
Sodium a l k y l b e n z e n e s u l f o n a t e : 17.6

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-111

1
38 Advanced Cleaning Product Formulations

L i g h t Duty Liquid, Premium Hand D i s h w a s h

Ingredients: Wt%
Water, D . I . 30.2
W i t c o l a t e SE-5 21.7
W i t c o n a t e 1260 S l u r r y 36.7
W i t c a m i de 128T 5.0
P e t r o LBA L i q u i d 1.9
Sodium S u l f a t e 2.6
Ethanol 1.8
Formal i n 0.1
P e r f u m e , Dye 9,s.

81 e n d i n g P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0
using C i t r i c Acid.

Typical Properties:
V i s c o s i t y , c p s : 230
A p p e a r a n c e : C1 e a r L i q u i d
F o r m u l a 113

L i g h t D u t y L i q u i d Low C o s t Hand D i s h w a s h

Ingredients:.
W a t e r , D . I. 81 . 5
W i t c o l a t e SE-5 5.5
W i t c o n a t e 1260 S l u r r y 9.2
W i t c a m i d e 128T 1.2
P e t r o LBA L i q u i d 0.5
Sodium C h l o r i d e 2.0
Formal i n 0.1
Perfume, Dye q.s.

Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t pH=6.5-7.0
using C i t r i c Acid.

Typical Properties:
V i s c o s i t y , c p s : 170
Appearance: C l e a r L i q u i d
Formula 116

SOURCE: Witco Corp.: Suggested F o r m u l a t i o n s


Dishwashing Detergents 39

Liquid Automatic Dishwasher Deterqent

T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum


s i l i c a t e , as a s u s p e n d i n g a g e n t and r h e o l o g y m o d i f i e r . The
sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g a g e n t
and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a p H . The
p h o s p h a t e b l e n d p r o v i d e s d e t e r g e n c y and t h e s u r f a c t a n t s
contribute excellent r i n s a b i l i t y .

Inqredi ents: Wt%


A : Van Gel ES 4.00
D e i o n i z e d Water 53.00

B : T e t r a p o t a s s i u m P y r o p h o s p h a t e , t e c h n i c a l powder 10.00
Sodi um T r i p o l y p h o s p h a t e , t e c h n i c a l powder 20.00

C: Sodium M e t a a s i l i c a t e . Anhydrous 2.00


Sodium H y p o c h l o r i t e , 1 2 . 5 % s o l n . 8.00

D: Sodium X y l e n e s u l f o n a t e 2.25
Deceth-4-Phosphate 0.75

Procedure:
P r e h e a t t h e w a t e r t o 5 5 t o 60C. H y d r a t e t h e Van Gel ES
s l o w l y b y a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed
d i s p e r s e r . Preblend B i n g r e d i e n t s , Add B t o A s l o w l y w i t h
m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r
l i s t e d , mixing u n t i l dissolved. Continue mixing w h i l e c o o l i n g
r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e
m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n
of air).

C o n s i s t e n c y and pH:
Pumpable l i q u i d , V i s c o s i t y 1300-1800 c p s , B r o o k f i e l d Model
LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r
3 0 days a g i n g ; pH a p p r o x i m a t e l y 1 2 . 5 .

Suggested P a c k a g i n g : Squeeze b o t t l e o r pump.

SOURCE: R.T. V a n d e r b i l t Co., Inc.: F o r m u l a t i o n No. 438


40 Advanced Cleaning Product Formulations

Manual D i shwashi n q G e l

F u n c t i o n s & B e n e f i t s : C a r b o p o l EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent
o f surfactant type
*provides high c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form

i n i r e d l ent : Wt%
DI w a t e r 37.50
C a r b o p o l EX-473 ( 3 0 % ) * 10.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e ( 1 8 % ) 2.00
Ammonium l a u r y l s u l f a t e (30%)** 25.00
Sodium l a u r y l e t h e r s u l f a t e (30%)*** 25.00

* V i s c o s i t y modi f i e r : B F G o o d r i c h
* * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical
* * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: S t e p a n C h e m i c a l

P h y s i c a l P r o p e r t i es :
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 , 0 0 0 C P
P r o d u c t pH: 6 . 5 - 7 . 0
Product c l a r i t y : c l e a r

Procedure:
1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d b y a L i g h - t n i n ' m i x e r
o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e C a r b o p o l
EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m a n d
homogeneous.
2 . Add t h e sodium c i t r a t e . M i x u n t i l t h e sodium c i t r a t e i s
completely dissolved.
3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH.
4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l s o d i u m h y d r o x i d e i f
necessary.
6 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-130


Dishwashing Detergents 41

_ _ D i shwashi nq L i q u i d
Manual

F u n c t i o n s B B e n e f i t s : Carbopol EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, i n d e p e n d e n t
o f surfactant type
*provides h i g h c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form

I n g r e d i en t . yt%
DI w a t e r 43.00
Carbopol EX-473 ( 3 0 % ) 5.50
Ammonium l a u r y l s u l f a t e (30%)* 25.00
Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + 25.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e (18%) I .oo

* A n i o n i c s u r f a c t a n t : S t a r i d a p o l A : Stepari Chemical
* * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: Stepan Chemical

Physical Properties:
B r o o k f i e l d R V T v i s c o s i t y - 2 0 rpm: 5 0 0 CP
Product pH: 6.5-7.0
Product c l a r i t y : Clear

Procedure:
1 . Using slow a g i t a t i o n (200 r p m ) provided by a L i g h t n i n ' Mixer
o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e C a r b o p o l
E X - 4 7 3 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and
homogeneous.
2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
3 . Add t h e sodium c i t r a t e , M i x u n t i l t h e sodium c i t i - a t e i s
completely dissolved.
4 . A d j u s t t h e p H w i t h sodium h y d r o x i d e .
5 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .

SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-120


42 Advanced Cleaning Product Formulations

N o n - C h l o r i n a t e d M a c h i n e D i s h w a s h i n q Compound, Liquid

I n Q r e d ie n t s : \Mt%
Water, D . I . 79.5
Sodi um T r i p o l y p h o s p h a t e 2.0
Versene 2 2 0 , Powder 1 .o
Sodi um G1 u c o n a t e 1.o
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 7.0
C a u s t i c Soda 50% 8.5
P e t r o ULF L i q u i d 1 .o

81 e n d i ng P r o c e d u r e :
Add a l l components i n t h e o r d e r shown, m i x i n g w e l l between
a d d i t i ons.
F o r m u l a 109

C h l o r i n a t e d M a c h i n e D i shwashi n q Compound, Powder

Ingredients:
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 30.0
Sodi um T r i p o l y p h o s p h a t e (STPP) , L i g h t D e n s i t y 25.0
DeSoni c LFD-97 1. o
Sodium M e t a s i l i c a t e , Anhydrous 30.0
C a u s t i c Soda Beads 10.0
CDB C l e a r o n 4.0

Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly w i t h
each a d d i t i o n .
F o r m u l a 111

N o n - C h l o r i n a t e d M a c h i n e D i shwashi n g Compound. Powder

Inqredi ents: Wt%


Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 33.0
Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y 25.0
DeSoni c LFD-97 2.0
Sodium M e t a s i l i c a t e , Anhydrous 30.0
C a u s t i c Soda Beads 10.0

Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly
w i t h each a d d i t i o n .
F o r m u l a 112

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 43

P r e m i um Hand D i shwashi ng D e t e r q e n t

Inqredients: Wt%
Water, D . I . 6.9
A1 p h a - S t e p MC-48 56.0
S t e o l CS-330 30.0
N i n o l 30-LL o r N i n o l 40-CO 5.6
Sodium C h l o r i d e 1.5

P r o p e r t i es :
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 6 . 5 - 7 . 5
V i s c o s i t y @ 25 deg. C , c p s : 220
S o l i d s , % : 39-40
Density, l b s / g a l : 8 . 8
Freeze/thaw, 3 c y c l e s : Pass
C o l d s t o r a g e @ 4 deg. C . , 2 weeks: Pass
F l a s h p o i n t , deg. F: >200

M i x i n g Procedure:
CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO
and m i x u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n .
M i x u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e
as n e c e s s a r y .

Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE: Stepan C o . : F o r m u l a t i o n No. 173

D i s h Washina A q e n t s f o r Manual Use

Inqredi ents:
Water 79.0
Lumorol 4154 12.0
Z e t e s o l NL 6.0
Z u s o l a t 1008/85 1.o
Sodium c h l o r i d e approx. 2 . 0
F o r m u l a t i o n CT 02-01-04

m e d ien t s : Wt%
Water 76.5
Z e t e s o l 2056 20.0
Amphotensid B 4 2.0
Z u s o l a t 1008/85 1.o
P u r t o n CFD 0.5
F o r m u l a t i o n CT-02-01-05

SOURCE: Zschimmer & Schwarz GmbH & C o . : Suggested F o r m u l a t i o n s


5. General Purpose

44
General Purpose Cleaners 45

Abrasive Cleaner w i t h Bleach

Carbopol r e s i n s a r e used t o a c h i e v e a s t a b l e s u s p e n s i o n o f
t h e c a l c i u m carbonate a b r a s i v e o a r t i c l e s i n t h e presence o f
c h l o r i n e bleach

lnqredient : Wt%
DI[ Water 53.76
Carbopol 674 o r 691* 0.80
Good-Rite K-7058 (50%)** 2.00
Sodi um h y d r o x i d e (50%) 2.80
2 . 4 ~sodium s i l i c a t e (52%) 2.50
Sodium h y p o c h l o r i t e (14%) 7.14
C a l c i urn c a r b o n a t e * * * 30.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e (45% **** 1 .oo

*Suspension a i d : BFGoodrich
* * A n t i - r e d e p o s i t i o n : BFGoodrich
+ * + A b r a s i v e : W h i t e #8 ( G e o r g i a M a r b l e )
* * * * A n i o n i c s u r f a c t a n t : Dowfax 382 (Dow Chemi

Physi ea9 P r o p e r t i e s :
B r o o k f i e l d RVT v i s c o s i t y - 20 rpm: 3,960 c p
Product pH: 12-13
P r o d u c t c l a r i t y : Opaque

~ ~ ~ ~ ~ d ~ r ~
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous
2. Add t h e low m o l e c u l a r w e i g h t p o l y a c r y l a t e p o l y m e r f o l l o w e d
by t h e sodium h y d r o x i d e and sodium s i l i c a t e . M i x u n t i l
homogeneous.
3. Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e b l e a c h .
(The p r o d u c t w i l l d r o p i n v i s c o s i t y a t t h i s p o i n t . )
4. Add t h e c a l c i u m c a r b o n a t e and f i n a l l y t h e s u r f a c t a n t w i t h
c o n s t a n t a g i t a t i o n . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .

FGoedrich S p e c i a l t y Chemicals: DET-343


46 Advanced Cleaning Product Formulations

A b r a s i v e Cleaner W i t h o u t B1 each
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m carbonate
abrasives .
Insredient: Wt%
D I Water 62.10
Ethanol 2.00
Carbopol 674 ( 1 ) 0.60
Sodium h y d r o x i d e (50%) 1 .00
Sodium b i c a r b o n a t e 1.20
Calcium carbonate ( 2 ) 30.00
C12-15 1in e a r a1 coho1 , 3 moles EO ( 3 ) 2.50
Coconut d i e t h a n o l ami de ( 4 ) 0.60

B r o o k f ie l d v i s c o s i t y (RVT-20 rpm) : 4,500 cps


P r o d u c t pH: 8-10
P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodr ich
( 2 ) G e o r g i a M a r b l e Co.: G e o r g i a M a r b l e W h i t e # 8
( 3 ) S h e l l Chemical: Neodol 25-3
( 4 ) Stepan Co.: N i n o l 11-CM

Procedure:
1 . Add t h e e t h a n o l t o t h e w a t e r - h o l d i n g back 10 p a r t s o f w a t e r
f o r s t e p #3.
2 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ’
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n
t h e Carbopol r e s i n i n t o t h e D I w a t e r / e t h a n o l m i x t u r e . M i x t h e
s l u r r y for a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s
homogeneous.
3 . P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f w a t e r w i t h
t h e sodium h y d r o x i d e and sodium b i c a r b o n a t e . Add t h i s t o t h e
m i x t u r e formed above and m i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e , a l c o h o l e t h o x y l a t e and coconut QEA.
M i x u n t i l homogeneous.
5 . Add f r a g r a n c e , as d e s i r e d .

Total Actives:
C a l c i um c a r b o n a t e : 30.0
C12-15 l i n e a r a l c o h o l , 3 moles EO: 2.5
Coconut DEA: 0.6

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-340


General Purpose Cleaners 47

A l l Purpose C l e a n e r

Ingredients: Wei q h t %
Urea 2.00
Na4EOTA 2.00
Water 88.00
2990 Ammonia 1 .oo
C a l s o f t L-40 5.00
C a l o x y l a t e N-9 2.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-001-01

A l l Purpose C l e a n e r

Ingredients: Wei q h t %
Na4EDTA 4.00
Water, Perfume 84.00
Dowanol DPnB 4.00
C a l s o f t L-40 8.00

Comments a b o u t t h i s f o r m u l a :
Compare t o M r . C l e a n , a t r a d e m a r k o f P r o c t o r & Gamble.
F o r m u l a t i o n APC-002-01

A l l Purpose C l e a n e r

Inqredi ent s : Wei q h t %


d - L i monene 40.00
Calamide C 4.00
C a l a m i d e CWT 4.00
Cal imu1 se PRS 10.00
Water 42.00

Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s f i r s t and m i x .
2 . Add w a t e r s l o w l y .
3 . M i x u n t i l homogeneous.
F o r m u l a t i o n APC-005-01

A l l Purpose C l e a n e r

Inqredi ents: Weight%


Water 85.00
Calamide CWT 15.00

Comments a b o u t t h i s f o r m u l a :
Formula t h i c k e n s e f f e c t i v e l y .
F o r m u l a t i on APC-003-01

SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s


48 Advanced Cleaning Product Formulations

A l l Purpose C l e a n e r
Inqredients: Wei q h t %
Na4EDTA 5.00
Water 77.50
Calamide C 2.50
Calamide CWT 2.50
P i l o t SXS-40 2.50
Laurami ne O x i d e 10.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-006-01

A l l Purpose C l e a n e r

Inqredients: Wei q h t %
Na4EDTA 5.00
Water 76.10
50% NaOH 0.80
Cal s o f t LAS-99 2.80
P i l o t SXS-40 5.30
Calamide C 5.00
Calamide CWT 5.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-007-01

A l l Purpose C l e a n e r - No R i n s e

Inqredients: Weight%
Water 89.00
C a l f a x 1OL-45 3.00
Na4 EDTA 3.00
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
Calamide CWT 2.00

Comments a b o u t t h i s f o r m u l a :
Spray a s i s , t h e n w i p e w i t h a p a p e r t o w e l .
F o r m u l a t i o n APC-008-01

SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s


General Purpose Cleaners 49

A 1 1- P u r p o s e C 1 e a n e r

Composi t ion :
K e l z a n x a n t h a n gum 0.3
A1 ip a l CD-128 1.7
G a f a m i d e CDD 518 0.5
B u t y l C e l l o s o l ve 3.5
S o d i urn M e t a s i 1 ic a t e 1.7
T r i s o d i urn P h o s p h a t e 1.o
Water, Perfume 91.3

Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n a n d 15 p e r c e n t G e n e t r o n
12.

All-Purpose
- D i s i n f e c t a n t Cleaner

Composi ti= Q
K e l z a n x a n t h a n gum 0.5
Makon 1 0 10.0
Sodium T r i p o l y p h o s p h a t e 3.0
V e r s e n e 100 3.0
Hyarnine 1 O X 1.o
Water 82.5

Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s a s i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t G e n e t r o n
12.

SOURCE: M o n s a n t o P e r f o r m a n c e M a t e r i a l s : K e l z a n S u g g e s t e d
Formulations

A l l Purpose C l e a n e r

l n q r e d i en& Wt%
R h o d a t e r g e SMC 10
STPP 2
Water 88

SOURCE: Rhone-Poulenc Surfactants & Specialties: Suggested


Formulations
50 Advanced Cleaning Product Formulations

A l l Purpose C l e a n e r w/Amide/Phosphate Ester

Innredi ents: Wt%


W a t e r , D.I. 83.0
Tetrapotassium Pyrophosphate 5.0
Varami de A-1 0 10.0
Emphos 5AP 2.0

81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 145
S o l i d s : 17.0%
pH: 8 . 8
Formula 514

A l l Purpose C l e a n e r

Ingredients: wto/,
Water 56.0
W i t c o n a t e 1 2 6 0 S1 u r r y 38.5
Witcamide 6445 5.5

Blending Procedure:
B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d .
Typical Properties:
V i s c o s i t y , c p s : 670
Sol i d s : 33.0%
pH, as i s : 9 . 2
Formula 520

A1 1 Purpose C l e a n e r

Ingredients: W S
Water 90.0
Sodi um T r i p o l y p h o s p h a t e 2.0
C a u s t i c Soda, 50% 0.5
W i t c o 12988 2.0
W i t c a m i de 6 4 4 5 5.0
Perfume, Dye q.s.

Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d .
T y p i c a l P r o p e r t ie s :
Speci f ic G r a v i t y : 1 . 0 2 0 6
Wt./Gal. l b s . : 8 . 5
pH, as i s : 9 . 1 2
V i s c o s i t y , c p s : 107
Color: Beige
Use D i l u t i o n : 1 - 2 o z . / G a l .
Formula 535
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
General Purpose Cleaners 51

A l l Purpose C l e a n e r C o n c e n t r e
(Phosphate, - L i q u i d , Foam)

S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Spray
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t ion: Wt%


Water 78.1
M e t s o Beads 2048 2.4
TKPP ( 6 0 % ) 3.0
*Phosphate E s t e r 3.0
* * D i p r o p y l e n e G l y c o l Monomethyl E t h e r 6.0
* * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 M o l e s E O 5.0
****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 M o l e s EO 2.5

Use D i l u t i o n : Normal D u t y - 1 . 5 % bw ( 2 o z / g a l l o n )
Heavy D u t y - 2 . 5 % b w ( 3 . 3 o z / g a l 1on)
Tough D u t y - a s s u p p l i e d

* Rhone-Poulenc R h o d a f a c RE-610
**( Dow, A r c 0 C h e m i c a l
*** Rhone-Poulenc I g e p a l CA-630
**** Rhone-Poulenc I g e p a l CA-520

A l l Purpose C o n c e n t r a t e
(Phosphate, Liquid1

S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : wto/,
Water 78.75
M e t s o Beads 2048 1 .oo
TKPP 3.00
Sodium X y l e n e S u l f o n a t e , 40% 3.50
*Ethylene Glycol n-Butyl Ether 6.00
Pine O i l 0.25
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 M o l e s EO) 5.00
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 M o l e s EO) 2.50

Use D i 1u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )

* Dow C h e m i c a l , U n i o n C a r b i d e
*l Rhone-Poul enc R h o d a s u r f LA-7
*S* Rhone-Poulenc R h o d a s u r f A-24

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
52 Advanced Cleaning Product Formulations

Calcium Carbonate A b r a s i v e Cleaner W i t h o u t Bleach

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m c a r b o n a t e
abrasives .
I n q r e d ie n t :
D I Water 62.10
Carbopol ETD 2623 ( 1 ) 0.25
Sodium h y d r o x i d e (50%) 0.20
C12-I5 l i n e a r a l c o h o l , 3 moles EO ( 2 ) 1.50
Sodium a l k y l benzene s u l f o n a t e ( 3 ) 0.50
Calcium carbonate ( 4 ) 30.00

P h y s i c a l P r o p e r t ies :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 7,500 c p
P r o d u c t pH: 8-10
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) Stepan Co. : Nacconol SQG
( 4 ) Georgia Marble C o . : Georgia Marble White #8

Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i ng and b l endi ng o p e r a t i o n s , d i s p e r s e
o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e
s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y
i s homogeneous.
2. Add t h e sodium h y d r o x i d e t o r e a c h t a r g e t pli. The p r o d u c t
w i l l become v e r y t h i c k a t t h i s p o i n t .
3 . Add t h e a l c o h o l e t h o x y l a t e and a l k y l b e n z e n e s u l f o n a t e s u r f -
a c t a n t s . M i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .

Total Actives:
Calcium carbonate: 30.00
C12-15 l i n e a r a l c o h o l , 3 moles EO: 1.50
Sodium a1 k y l b e n z e n e s u l f o n a t e : 0.50

SOURCE: BFGoodrich S p e c i a l t y Chemicals: BET-341


General Purpose Cleaners 53

C i t r i c A c i d Cleaner

F u n c t i a n e 8 B e n e f i t s : Carbopol ETD 2623:


* P r o v i d e s l o w p H t h i c k e n i n g v i a hydrogen b o n d i n g w i t h s u r f -
actant
* I m p a r t s y i e l d v a l u e f o r suspension o f a b r a s i v e p a r t i c l e s
*Provides v e r t i c a l c l i n g f o r increased s u r f a c e c o n t a c t t i m e
*Shear t h i n n i n g r h e o l o g y f o r easy d i s p e n s i n g t h r o u g h t r i g g e r
sprayer o r nozzle
* E a s y - t o - d i s p e r s e r e s i n f o r improved and e a s i e r f u l l - s c a l e
processing

Inqiredi e n t : Wt%
DI Water 78.40
Carbopo? ETD 2623 R e s i n * 0.10
C12-15 l i n e a r a l c o h o l , 3 moles EO** 5.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO*** 2.50
Alkylbenzene s u l f o n i c acid**** 2.00
C i t r i c A c i d (50%) 12.00

*V iscos ity modi f ie r : BFGoodr ic h


s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical
>N**Nonionic s u r f a c t a n t : Neodol 23-6.5: S h e l l Chemical
* * r * A n i o n i c s u r f a c t a n t : B i o s o f t 5-100: Stepan

P h y s i c a l P r o p e r t iee: S t o r a g e Temperature
-25C
. 5oc
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm:
Initial: 50cP 50cP
Age-Up V i s c o s i t y : Week 2 : 170cP 400cP
Week 4 : 250cP 600cP
Week 6: 350cP 400cP
P r o d u c t pH: 1 . 4
Product c l a r i t y : T r a n s l u c e n t

Procedurw:
4. U s i n g J m a r i n e b l a d e p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm)
p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t ,
s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l o w
t o h y d r a t e f o r 15-20 m i n u t e s o r u n t i l no lumps a r e p r e s e n t .
Warming t h e d e i o n i z e d w a t e r t o 30C w i l l decrease t h e h y d r a t i o n
t i m e and i m p r o v e t h e d i s p e r s i b i l i t y o f t h e Carbopol powder.
2. M i x t h e Neodol 25-3 and Neodol 2 3 - 6 . 5 ( o r warm s l i g h t l y i f
needed) t o e n s u r e homogeneity. A d d w i t h moderate m i x i n g (300
r p m ) . A l l o w t o mix u n t i l u n i f o r m and smooth.
3. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) m i x i n g and
a l l o w t o m i x u n t i l u n i f o r m and smooth.
4. S ~ O W add ~ Y t h e C i t r i c A c i d w i t h s l o w m i x i n g (200 r p m ) . M i x
u n t i l smooth and u n i f o r m .
5. Add f r a g r a n c e and c o l o r , a s d e s i r e d .

S O U R C E : B F G o o d r i c k S p e c i a l t y ChemicaJs: DET-352
54 Advanced Cleaning Product Formulations

G e n e r a l P u r p o s e C1 e a n e r
(Consumer Low Alkaline, Non-Phasphate Powder)

S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y
and p a r t i c u l a t e s o i l
Surface-Hard surface, i . e . , metal, p l a s t i c , ceramic, concrete,
and a s p h a l t
A p p l i c a t i on Method-Wi p e o r B r u s h
Manufacture-Dry blend/Agglomeration

Composi t i o n : Wt%
Sodi um C a r b o n a t e ( 1 i g h t d e n s i t y ) 30.0
* B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e 10.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
* * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5
Sodi um S u l f a t e 14.5

Use L e v e l : 1-4 o z / g a l l o n

* 2 . 0 w e i g h t r a t i o s i l i c a t e powder, 82.5% s o l i d s
** Rhone-Poulenc R h o d a s u r f LA-9
*** Rohm & Haas

G e n e r a l Purpose C l e a n e r
(Consumer H i g h A 1 k a l ine, Non-Phosphated Powder1

S o i -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y


and p a r t i c u l a t e s o i l
Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , c e r a m i c , c o n c r e t e ,
and a s p h a l t
App i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend/Agglomeration

Composi t i o n 1 Wt%
Sodium S u l f a t e 14.5
Sodi um C a r b o n a t e ( 1 ig h t d e n s i t y ) 30.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
M e t s o Beads 2048 10.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5

Use L e v e l : 1-4 o z / g a l l o n

* Rhone-Poulenc R h o d a s u r f LA-9
** Rohm & Haas

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide


General Purpose Cleaners 55

G e n e r a l P u r p o s e S p r a y & Wipe C l e a n e r

Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h i s
"no-drip" action w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e a s w e l l a s enhance consumer c o n v e n i e n c e .

Ingredient: wto/,
D I Water 90.70
C a r b o p o l ETD 2 6 9 1 ( 1 ) 0.20
EDTA ( t e t r a s o d i u m s a l t ) 2.00
Sodium m e t a s i l i c a t e , a n h y d r o u s 2.30
P r o p y l ene g l y c o l m e t h y l e t h e r ( 2 ) 3.00
C12-15 l i n e a r a l c o h o l , 7 m o l e s EO ( 3 ) 1.50

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 c p s


P r o d u c t p H : 12-13
P r o d u c t C l a r i t y : C l e a r t o hazy

( 1 ) BFGoodri c h
( 2 ) Dow C h e m i c a l : Dowanol DPM
( 3 ) S h e l l C h e m i c a l : Neodol 25-7

Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e .
3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l
e t h o x y 1a t e .
4 . Add c o l o r and f r a g r a n c e , a s d e s i r e d .

T o t a l Actives:
Propylene g l y c o l methyl e t h e r : 3.0
C 1 2 - I 5 l i n e a r a l c o h o l , 7 m o l e s EO: 1.5

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-310


56 Advanced Cleaning Product Formulations

G e n e r a l P u r p o s e Spray & Wipe

Ingredients: Wt%
Water, D.I. 79.0
Sodi um C i t r a t e 2.0
A1 p h a - S t e p MC-48 10.0
S t e p a n o l WA-Extra 7.0
N i n o l 11-CM 2.0

M i x i n g Procedure:
Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and
m i x u n t i 1 homogeneous.

T y p i c a l P r o p e r t i es :
Appearance: C l e a r c o l o r l e s s l i q u i d
pH, as i s : 9 . 4
Viscosity I 3 2 5 deg. C : V e r y t h i n
S o l i d s , %: 1 0 . 0
Density, l b s / g a l : 8.54
C o l d s t o r a g e @ 4 d e g . C, 1 d a y : p a s s
F r e e z e / t h a w , 3 c y c l e s : pass

Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s
Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s
Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n c o m m e r c i a l
product.

Use I n s t r u c t i o n s : Use as i s

Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE: Stepan Co.: Suggested F o r m u l a t i o n No. 575

A1 1 -Purpose C1 e a n e r

Ingredients:
Water 82.0
Z e t e s o l 2056 14.0
Z u s o l a t 1008/85 4.0

SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n CT 02-04-02


General Purpose Cleaners 57

H y p o c h l o r it e V e r t i c a l S u r f a c e C l e a n e r

M o n a t r o p e 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t
c o n t r i b u t e s t o w e t t i n g and f o a m i n g c h a r a c t e r i s t i c s .

In q r e d ie n t s : Wt%
M o n a t r o p e 1250 2.0
Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) 2.0
Laurami ne O x i d e (30%) 10.0
P o t a s s i u m H y d r o x i d e (45%) 15.0
Sodi um T r i p o l y p h o s p h t e 5.0
Sodium H y p o c h l o r i t e 5 . 2 5 % ) 66.0

Procedure:
Add i n g r e d i e n t s w t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r y e l l o w l i q u i d
p H : 13

Recommended Use D i l u t i o n : 1:lO w i t h w a t e r


Formul a t i on F-783

Pump S p r a v A l l Purpose C l e a n e r

A f a s t a c t i o n s p r a y and w i p e f o r m u l a t i o n . Surfaces w i l l dry


streak-f ree.

Inqredients: Wt%
Water 94.0
M o n a t e r g e 779 (DEA-Laureth S u l f a t e ) 3.0
Propylene Glycol B u t y l Ether 3.0

Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.

Typical Properties:
Appearance: C l e a r l i q u i d

Recommended Use D i 1 u t i o n : As i s

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


58 Advanced Cleaning Product Formulations

L i q u i d C 1 eanser w i t R B1 each

I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and


t o a d j u s t t h e v i s c o s i t y . The sodium c a r b o n a t e b u f f e r h e l p s
m a i n t a i n a pH o f a b o u t 1 1 , n e c e s s a r y f o r t h e s t a b i l i t y o f t h e
h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d -
ness i n u s e and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l
s u r f a c e s a s compared t o powders.

Ingredients:
A : Van Gel B 2.25
Water 62.25

6 : Diatomaceous E a r t h '10.00
Sodium c a r b o n a t e 4.50
Sodium h y p o c h l o r i t e , 5 . 2 5 % s o l n . 20.00
Sodium L a u r y l S u l f a t e , 29% s o l n . 1 .oo

Procedure:
S l o w l y add Van Gel B t o t h e w a t e r w h i l e a g i t a t i n g a t maximum
a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add r e m a i n i n g
i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n .

Consistency: Medium v i s c o s i t y liquid.

Suggested Packaging: P l a s t i c squeeze b o t t l e .

SOURCE: R . T . V a n d e r b i l t Co., Inc.: F o r m u l a t i o n N o . 391

A l l Purpose C l e a n e r
Clear, liquid

Ingredients: Wt%
A : H o s t a p u r SAS 6 0 10.0-15.0
Genapol ZRO 1 iq u i d 0.0- 4.0
Genapol UD-080 1.0- 3 . 0

B : Water ad 1 0 0 . 0
Perfume 0.2
Preservative 0.1
Dye q.s.

Manufacturing:
Add one a f t e r a n o t h e r , t h e components o f B t o A .

Modern s t a n d a r d f o r m u l a t i o n s a r e based on a l k a n s u l p h o n a t e s and


noni oni c s .
E t h e r s u l p h a t e s a r e used i n r a r e cases.
Phosphates, sodium c a r b o n a t e and ammonia a r e n o t common any
1onger .
The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n


General Purpose Cleaners 59

Pine O i l Cleaner Concentrate

Ingredients: g
Pine o i l 20.0
N i n o l 11-CM 9.0
Makon 12 5.0
Ammonyx LO 0.5
B i o - S o f t S-1 0 0 2.0
Isopropanol 10.0
Water, D . I . 53.5

M i x i ng Procedure:
Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add
water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
Odor: P i n e
V i s c o s i t y @ 25C, c p s : 50
pH ( a s i s ) : 8 . 1
D e n s i t y 1b s / g a l : 8 . 0 6
Freeze/Thaw ( 3 c y c l e s ) : Pass
50 C oven ( 1 week): Pass
Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s
Commercial f o r m u l a t i o n : 5 5 . 5 % s o i l removed f r o m t i l e s
SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 208

D i s i n f e c t i n g Cleaner, Alkaline

Ingredients: Wt%
Water 57.5
C i t r i c acid 2.0
Z u s o l a t 1008/85 3.5
Lumorol 4192 5.0
Trilon A liquid 7.0
Lonzabac-1230 25.0
Ingredients: Wt%
Water 69.0
Disodium t e t r a b o r a t e decahydrate 0.5
Sodi um b i c a r b o n a t e 1.0
Burdac-114 20.0
Z u s o l a t '1008/85 9.5
Ingredients: g
Water 57.5
Trilon A liquid 7.0
Citric acid 2.0
S u l f e t a l 4069 5.0
Z u s o l a t 1008/85 3.5
Lonrabac-1230 25.0

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n s CT 06-09-01,


CT 06-09-02, CT 06-09-03
60 Advanced Cleaning Product Formulatiorrs

Sodi urn B i c a r b o n a t e A b r a s i v e C l e a n e r W i t h o u t B l e a c h

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e s u s p e n s i o n o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e
abrasives.

Ingredient:
- wtsl,
D I Water 44.25
C a r b o p o l ETD 2691 ( 1 ) 0.50
A l k y l benzene s u l f o n i c a c i d ( 2 ) 0.75
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s € 0 ( 3 ) 2.50
Sodium h y d r o x i d e ( 5 0 % ) 2.00
Sodium b i c a r b o n a t e ( 4 ) :
Grade 1 : 20.00
Grade 5 : 30.00

Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): 6,000 c p
Product pH: 8.50
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Stepan Co.: B i o s o f t 5-100
( 3 ) S h e l l C h e m i c a l C o . : Neodol 2 3 - 6 . 5
( 4 ) Church & Dwight
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d b y t h e a l c o h o l
e t h o x y l a t e . M i x u n t i l homogeneous.
3 . Add t h e s o d i u m h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH
t o 8.50 p r i o r t o t h e next step.
4 . W i t h m i n i m a l a g i t a t i o n , s l o w l y add t h e s o d i u m b i c a r b o n a t e .
M i x u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e l u m p s .
Re-check p H and a d j u s t , i f n e c e s s a r y .
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .

T o t a l A c t iv e s :
S o d i um b i c a r b o n a t e : 50.00
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s EO: 2.50
Sodium a1 k y l benzene s u l f o n a t e : 0.90

SOURCE: B F G o o d r i c h S p e c i a l t y C h e m i c a l s : DET-342
leaners/Polishes

61
62 Advanced Cleaning Product Formulations

A n t i -Foggi ng , A n t i -Stat ic G l a s s C l eaner

In g r e d i e n t s : MIBo/o
Water 90.0
Isopropyl Alcohol 9.0
Adogen 66 0.I
Varox 365 0.5
Emcol 4500 0.4

Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l Alcohol can be used
t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can b e used t o
f a c i l i t a t e m i x i n g o f t h e Emcol 4500.

Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, e t c . ) and
wipe onto t h e glass. A l l o w t o d r y .

Product I n f o r m a t i o n :
Product: Benefit :
Varox 365 W e t t i n g a g e n t , d e g r e a s e r and d e t e r g e n t
Adogen 66 A n t i - s t a t i c agent
Emcol 4500 W e t t i n g a g e n t , c o u p l e r and d e t e r g e n t

T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r
v a p o r ( f o g , steam, e t c . ) and t h e g l a s s w h i c h w i l l p r e v e n t
f o g g i n g . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r
prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o the glass;
t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much a s i t i s when p a s s i n g
through i n d i v i d u a l d r o p l e t s .
F o r m u l a 708

Glass Cleaner, Ready t o Use

Ingredients:
Water, D . I . 84.9
P e t r o BAF L i q u i d 0.1
Isopropanol 10.0
E t h y l e n e G l y c o l Monobutyl E t h e r 5.0
Dye q.s.

B l e n d i ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r 1is t e d .
F o r m u l a 705

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Glass CleanerslPolishes 63

G l a s s C l e a n e r C o n c e n t r a t e (Non-Ammoniated)

Ingredients: K%
W a t e r , D . I. 7.5
I s o p r o p a n o l , 99% 82.0
P e t r o LBA Powder 1.o
Monoethanol ami ne 0.5
Perfume, Dye q. s
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

T h i s c o n c e n t r a t e s h o u l d be m i x e d w i t h n i n e p a r t s o f w a t e r
t o one p a r t c l e a n e r t o b e r e a d y t o u s e . T h i s p r o d u c t r e q u i r e s
a red label.
F o r m u l a 702

Glass Cleaner Concentrate

Inqredi ents: Wt%


Water, D . I . 77.0
P e t r o BAF L i q u i d 20.0
DeSonic 5 N 1.o
Ammonia, 29% 2.0
Dye q.s.

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

Use D i l u t i o n : 1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r .
F o r m u l a 703

Amrnoniated G l a s s C l e a n e r

m r e d ients: Wt%
Water 94.0
W i t c o l a t e 231 0 3.0
B u t y l C e l l o s o l ve 2.0
Aqua Ammonia, 26 B e ' 2.0

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .


F o r m u l a 704

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
64 Advanced Cleaning Product Formulations

G l a s s and Window C l e a n e r

Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h j s
"no-drip" a c t i o n w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e as w e l l as enhance consumer c o n v e n i e n c e .

Inaredient: wel
D I Water 92 * 45
Carbopol ETD 2623 (4.10
Isopropanol 5.00
Ammonium h y d r o x i d e 0.20
A l k y l b e n z e n e s u l f o n i c a c i d (97%) ( 2 ) 0.25
Propylene g l y c o l methyl e t h e r (3) 2.00

Physical Properties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 200 c p
P r o d u c t pH: 9 . 5 - 1 0 . 0
Product C l a r i t y : Clear

Raw M a t e r i a1 Suppl ie r s :
( 1 ) BFGoodrich
( 2 ) Stepan Chemical: B i o s o f t 5-100
( 3 ) Dow Chemical: Dowanol PM

Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e i s o p r o p a n o l .
3 . Add t h e ammonium h y d r o x i d e . M i x u n t i l homogeneous.
4 . Add t h e s u l f o n i c a c i d and g l y c o l e t h e r w i t h m i n i m a l a g i t a t i o n
t o a v o i d e x c e s s i v e foaming.
5 . Add a d d i t i o n a l ammonium h y d r o x i d e , i f necessary, t o r e a c h the
t a r g e t pH r a n g e .
6 . Add c o l o r and f r a g r a n c e , as d e s i r e d .

Total Actives:
Ammonium a l k y l b e n z e n e s u l f o n a t e : 0 . 3 0
Propylene g l y c o l methyl e t h e r : 2.00
Isopropanol: 5.00

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-300


Glass CleanerslPolishes 65

H o u s e h o l d Window C l e a n e r

Inqredients: Wt%
Water. D . I . 89.3
Isopropanol 10.0
Varox 365 0.7
Methylene Blue q.s.

Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

T y p i c a l P r o p e r t ies:
V i s c o s i t y , cps: 4
S o l i d s : 0.2%
pH: 7 . 4
F o r m u l a 706

Bremi u m Household W i ndow C1 e a n e r

Ingredi ents: Q
Water, D . I . 89.4
Isopropanol 10.0
Varox 1770 0.6
Methylene Blue q. s

81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

Typical Properties :
V i s c o s i t y , cps: 4
S o l i d s : 0.23%
pH: 6 . 2
F o r m u l a 707

GI ass @1e a n e r
Ingredients: Wt%
Water. D . I . q.s.
Isopropanol 6.0
Dowanol EB 4.0
R e w o t e r i c AM V 0.85

81 endi ng P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r shown, mixing thoroughly bet-
ween each a d d i t i o n .
F o r m u l a 709

SQURCE: W i t c o G o r p . : Suggested F o r m u l a t i o n s
66 Advanced Cleaning Product Formulations

W i n d o w s / G l ass

Gl-ass Cl g a n g r C C o n c e n t r a t e )

Ingredients: We i s h t YO
Water 10.04
Ethylene G l y c o l Monobutyl Ether 21.34
Isopropyl Alcohol 53.30
Ammonia, 2 9 . 4 % 2.35
C a l foam SLS-30 5.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n WIN-001-01

W i n-dzhield Washer C c n c e n t r a t e

Ingredients: Weigh_%
Water 47.66
Isopropyl Alcohol 47.30
C a l s u d s 81 5.10

Comments a b o u t t h i s f o r m u l a :
Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n .
F o r m u l a t i o n WIN-002-01

W i ndshjeld-pWashec C o n c e n t y a t e (Low VOC)

Ing r e d i-en t s : We i gh ts/,


Water 62.20
P r o p y l ene G1 y c o l 33.80
Calsuds 81 4.02

Comments a b o u t t h i s f o r m u l a
Use l e v e l : 2-4 o z p e r g a l l o n .
F o r m u l a t i o n WIN-003-01

SOURCE: P i l o t C h e m i c a l C o . : Suggested F o r m u l a t i o n s
ard Surface Cleaners

67
68 Advanced Cleaning Product Formulations

A l k a l i n e Hard Surface Cleaner

In g r e d i e n t s :
Water, D . I . 34.0
Sodi um M e t a s i 1 ic a t e 8.0
Varami de A-83 12.0
W i t c o n a t e 30DS 40.0
W i t c o n a t e SXS L i q u i d 8.0

81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .

Typical Properties:
V i s c o s i t y , c p s : 205
S o l ids : 3 4 . 4 %
pH: 1 2 . 5
F o r m u l a 516

Hard Surface CleaEer Concentrate ( A l l P u r p o s e Type)

Ingredients: \Ne%
Water, D . I . 82.0
T e t r a s p o t a s s i u m P y r o p h o s p h a t e , Anhydrous 10.0
W i t c a m i de 1 PET 1.o
Emphos 5AP 4.0
W i t c o 1298S A 3.0

Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d , m i x i n g w e l l a f t e r each
addition.

Typical Properties:
S p e c i f i c G r a v i t y : 1.085
Wt./Gal. l b s : 9.04
pH, a s i s : 7 . 5 7
V i s c o s i t y , c p s : 94
3 Freeze/Thaw c y c l e s : Passed
1 Week @ 52C: Passed
4 Weeks Room Temp: Passed
S o l i d s : 17.8%
Appearance: C 1 e a r L i q u i d
Use D i l u t i o n : 1-3 o z . / g a l .
F o r m u l a 540

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Hand Surface Cleaners 69

Concentrated Hard Surface Cleaner

Ingredients: Wei q h t %
D e o d o r i z e d Kerosene 25.00
Calamide CWT 16.30
C a l o x y l a t e N-9 9.00
E t h y l e n e G l y c o l Monobutyl E t h e r 9.00
Water 41 .30
N a4 E DTA 0.40
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1-2 o z p e r g a l l o n .
F o r m u l a t i o n HSC-009-01

Hard Surface Cleaner-Spray

Inqredi ents: Wei q h t %


Water 86.50
Ammonia, 29% 3.00
Na4EDTA 0.50
Ethylene G l y c o l Monobutyl E t h e r 5.00
C a l s u d s 81 5.00
Comments a b o u t t h i s f o r m u l a :
1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobutyl E t h e r , t h e
mixture i s cloudy.
2 . It becomes c l e a r w i t h t h e a d d i t i o n o f C a l s u d s 8 1 .
F o r m u l a t i o n HSC-008-01

P i n e Cleaner

Inqredi ents : Weight%


Pine O i l 20.00
IPA 10.00
Calamide CWT 9.00
Cal o x y l a t e N-9 5.00
C a l s o f t LAS-99 2.00
Water 54.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use a t 1-2 o z p e r g a l l o n .
F o r m u l a t i o n HSC-004-01

Pine
- Cleaner

Ingredients: Weight%
Pine O i l 15.00
C a l s u d s CD-6 10.00
C a l o x y l a t e N-9 8.00
IPA 10.00
Water 57.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-007-01

~~~~~~~ P i l o t Chemical Co. : Suggested F o r m u l a t i o n s


70 Advanced Cleatiing Product Formulations

H a r d S u r f a c e Cleanerc

Ingredients: weight%
Water 75.25
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
Dowanol PnB 6.00
P i l o t SXS-40 9.00
C a l o x y l a t e N-9 5.50
P i n e 01 1 0.25
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n HSC-001-01

Hard-Surface-C1 @anex

Ingredi ents : Wi q h t 9 6
Water 74.50
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
P i l o t SXS-40 7.00
Cal imu1 se PRS 3.00
Dowanol PnB 5.00
Cal o x y l a t e N-9 6.50
Comments s b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-002-01

H a r d S u r f a c e Cle&ne_r

Ingredisnts : Weisht_"L.
Water 79.30
Sodi um M e t a s i 1 i c a t e 5.20
Na4EDTA 2.50
P i l o t SXS-40 5.00
Calamide CWT 8.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1 - 4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-005-01

Hardsu.!-33Cs~_ec1eaner
Irns r e d i en t-s 1 We i_pht %
Water 58.50
Sodi um C i t r a t e 15.00
Soda Ash 5.00
Ammonia, 29% 3.50
P i l o t SXS-40 8.00
Calamide CWT 1O.DO
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-006-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Hand Sqface Cleaners 71

Hard Surface Cleaner w/Amphoteric

Inqredi ents: Wt%


Water, D . I . 75.0
Sodi um C a r b o n a t e 4.0
R e w o t e r i c AM KSF-40 10.0
Dowanol DPM 5.0
Versene 100 2.0
W i t c o n a t e SXS (40%) 4.0

Blending Procedure:
Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 4
S o l i d s : 10.2%
pH: 10.8
F o r m u l a 507

H a r d S u r f a c e C l e a n e r C o n c e n t r a t e w/d'Limonene

Ingredients:
Phase I:
Isopropanol 10.0
Oleic A c i d 8.8
.Varoni c K205 5.0
d ' L i monene 12.0

Phase 11:
Water, D . I . 62.2
P o t a s s i u m H y d r o x i d e (87%) 2.0

B1 e n d i ng P r o c e d u r e :
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase 11.

T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 75
S o l i d s : 13.8%
pH: 1 0 . 2
F o r m u l a 508

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
72 Advanced Cleaning Product Formulations

Hard Surface Cleaner Concentrate


IPhosphate. L i q u i d )

S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d )
M a n u f a c t u r e - M i x t a n k w i t h p r o p e l 1e r s t i r r e r

ComDosition A:
Water 71.4
TSP 1.6
S t a r s o Sodium S i l i c a t e 14.0
Sodium H y d r o x i d e (50%) 4.0
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 Moles EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) 1 .2

Composition B: Wt%
Water 65.4
TSP 1.6
S t a r s o Sodi um S i 1 ic a t e 18.0
Sodium H y d r o x i d e (50%) 5.0
*Phosphate E s t e r 6.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 M o l e s EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 1.2

Use D i l u t i o n : 3-6% bw ( 4 - 8 oz/gallon)

* Rhone-Poulenc Rhodafac RE-600


** Rhone-Poulenc R h o d a s u r f 91-6
*** Rhone-Poulenc R h o d a s u r f A-24

Hard S u r f a c e Spray Cleaner


LPhosphate, L i q u i d )

S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Spray and w i p e
Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : Wt%
~-
Water 90.00
TKPP 2.00
N C l e a r Sodium S i l i c a t e 1.88
Sodium H y d r o x i d e (50%) 0.12
* D i p r o p y l ene G1 y c o l Monomethyl E t h e r 5.00
* * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 12-13 M o l e s EO 1 .00

Use: As i s , spray

* Dow Chemical
** Rhone-Poulenc I g e p a l CA-720

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide


Hand Surface Cleaners 73

Hard S u r f a c e C l e a n e r C o n c e n t r a t e w/Dipentene

I nnredi e n t s : Wt%
Phase I :
Isopropanol 10.0
Oleic Acid 8.8
V a r o n i c K205 5.0
D i pentene 12.0

Phase 11:
Water, D . I . 62.2
Potassium H y d r o x i d e (87%) 2.0

B l e n d i n g Procedure:
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase XI ~

Typical Properties:
V i s c o s i t y , cps: 50
Solids: 13.8%
pH: 10.1
Formula 509

A 1 k a l ine Hard S u r f a c e C l e a n e r

I n q r e d ients: Wt%
Water, D . I . 62.7
Sodi um M e t a s i 1i c a t e 3.0
Varami de A-83 5.0
\Mi t c o n a t e 3 0 D S 6.8
W i t c o n a t e SXS L i q u i d 2.5

B l e n d i n g Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

Typical Properties:
V i s c o s i t y , c p s : 32
S o l i d s : 1 1 .O%
pH: 12.0
Formula 515

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
74 Advanced Cleaning Product Formulations

L i q u i d A b r a s i v e C 1e a n s e r

Inqredients: Wt%
Water, t a p 48.5
C a l c i u m c a r b o n a t e , 100 mesh 42.5
Sodium t a l l o w soap, f l a k e s 2.0
A l p h a - S t e p MC-48 2.5
N i n o l 11-CM 2.0
Sodi um C h l o r i d e 2.5

M i x i ng P r o c e d u r e :
Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g .
Add soap and m i x u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m i x
u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .

P r o p e r t i es :
Appearance: Opaque, o f f - w h i t e creamy l i q u i d
pH, a s i s : 9 . 3
V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c
s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 c p s
s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 c p s
s p i n d l e # 3 , 30 rpm, B r o o k f i e l d : 3060 c p s
S o l i d s , % : 50
D e n s i t y , l b s / g a l : 11.69
S t o r a g e a t a m b i e n t temp, 1 week: N o s e p a r a t i o n

Use I n s t r u c t i o n s : Use as i s

Performance:
C l e a n s g r e a s e p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l
t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .

SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 3 1 4

T i l e and Sani t a r v C l e a n e r s

Inqredi ents: Wt%


Z u s o l a t 1008/85 5.0
Water 79.6
Xanthan Gum 0.4
C i t r i c acid 15.0

Inqredients: Wt%
Amphotensid B 4 30.0
Water 60.0
Citric acid 10.0

SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested F o r m u l a t i o n s


CT 02-10-03 and CT 02-10-04
Hand Sutface Cleaners 75

L i q u i d Hard Surface Cleaner

Ingredients: Wt%*
A : Van Gel ES, Magnesium Aluminum S i l i c a t e 4.00
Rhodopol 23, Xanthan Gum 0.50
D e i o n i z e d Water 68.50

0 : Cocamide DEA (Monamid 150-ADD) 0.50


A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) 2.50
T e t r a p o t a s s i um P y r o p h o s p h a t e 1.25
P o t a s s i u m Phosphate T r i b a s i c 0.75
D e i o n i z e d Water 21 .oo

C: Ammonium H y d r o x i d e , 28% 1 .oo

Procedure:
1 . D r y b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m .
C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add P a r t I3 t o P a r t A, m i x f o r 5 m i n u t e s and t h e n add P a r t C
and m i x f o r 5 m i n u t e s .
F o r m u l a t i o n No. 303

Hard Surface C l e a n e r - A l l Purpose

Ingredients: W t .%*
A : Veegum, Magnesi um A1 umi num S i 1 i c a t e 1.20
Rhodopol 23, Xanthan Gum 0.40
D e i o n i z e d Water 48.40

B : Calcium Carbonate 40.00

C: C12-CI3 L i n e a r P r i m a r y A l c o h o l E t h o x y l a t e
(Neodol 23-6.5) 9.00
Cocamide DEA ( N i n o l 40-CO) 1 .oo
P r e s e r v a t i v e , Dye, F r a g r a n c e q.s.

Procedure:
1 . D r y b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm.
C o n t i n u e m i x i n g f o r 20 m i n u t e s .
2 . Add P a r t B and m i x f o r 10 m i n u t e s .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
m i n u t e s a f t e r each a d d i t i o n .
F o r m u l a t i o n f r o m S h e l l Chemical Co.
AS r e c e i v e d b a s i s

SOURCE: R . T . V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n H a r d


S u r f a c e C l e a n e r s and P o l i s h e s : Suggested F o r m u l a t i o n s
76 Advanced Cleaning Product Formulations

M o l d and M i l d e w Remover

Carbopol r e s i n s a r e used t o reduce s p l a s h i n g and t o p r o v i d e


v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l surface. This
"no-drip" a c t i o n w i l l increase the contact time o f the deter-
g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

I n p r e d ie n t : \Rlt%
D I water 84.50
Carbopol 672 ( 1 ) 1 .00
Sodium h y d r o x i d e (50%) 2.00
Sodium m e t a s i l i c a t e , p e n t a h y d r a t e 0.50
P r i m a r y a l k a n e s u l f o n a t e (40%) ( 2 ) 5.00
Sodium h y p o c h l o r i t e (15.00%) 7.00
B r o o k f ie l d v i s c o s i t y (RVT-PO rpm) : 120 cps
P r o d u c t p H : 12-13
P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodrich
( 2 ) Stepan C o . : B i o - T e r g e PAS-8S

Procedure :
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i ng o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under moderate a g i t a t i o n , add t h e sodium h y d r o x i d e and t h e
metasilicate.
3. Add t h e a l k a n e s u l f o n a t e .
4 . Under l o w a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .

Total Actives:
Primary alkane sulfonate: 2.0
Available chlorine: 1.0

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-320


Laundry Products

77
78 Advanced Cleaning Product Formulations

Detergent f o r Fine Fabrics-1


Powder

Inpredi ents: Q
Genapol OA-080 3.0
DDBS-Na* 15.0
Thermphos NW 25.0
T a l l o w soap, Powder 1 .O-3.0
Sodi um d i s i 1 i c a t e 3.0
S o k a l a n CP 5 1 .o
S o k a l a n HP 22 1 .o
A q u a m o l l i n BC Powder 0.5
Perfume q.s.
Sodi um s u l p h a t e ad 1 0 0 . 0

Manufacturing:
To b e p r e p a r e d by s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l p h o n a t e

Detergent f o r Fine Fabrics-2


Powder

Inqredients: Wt%
Genapol OA-080 3.0
DDBS-Na* 15.0
Z e o l i t h A (Wessalith 20.0-25.0
T a l l o w soap, Powder 1.0- 3.0
Sodi um d i s i 1 ic a t e 3.0
S o k a l a n CP 5 2.0- 3.0
S o k a l a n HP 22 1 .o
Aquamoll i n BC Powder 0.5
Perfume q.s.
Sodium s u l p h a t e ad 100.0

Manufacturing:
To b e p r e p a r e d b y s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l f o n a t e

SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
Laundry Products 79

Heavy D u t y L a u n d r y

Ingredients: Wei q h t %
Water 28.90
Sodi um H y d r o x i d e , 50% 6.60
Calamide C 7.00
P i l o t SXS-40 12.50
Cal s o f t LAS-99 40.00
Cal o x y l a t e N - 9 5.00
Comments a b o u t t h i s f o r m u l a :
Add C a l o x y l a t e N - 9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d .
F o r m u l a t i o n HDL-001-01

Heavy D u t y L a u n d r y

Inqredients: Wei o h t %
Water 42.50
P i l o t SXS-40 22.50
Calamide CWT 4.00
Sodium S i l i c a t e ( S o l i d ) 3.01
C a l s o f t L-60 18.00
EDTA (Ethylenediaminetetraacetic A c i d ) 2.50
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-006-01

Heavv D u t y L a u n d r y

I n q r e d ie n t s : Weight%
Water 78.50
C a l f a x DB-45 7.00
C a l o x y l a t e N-9 7.00
P r o p y l ene G1 y c o l 2.50
TKPP ( T e t r a P o t a s s i um Pyrophosphate) 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-007-01

Heavv D u t y L a u n d r y

Inqredients: Wei q h t %
Water 42.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 15.00
Sodium S i l i c a t e ( S o l i d ) 10.00
C a l s o f t L-60 18.00
P i l o t SXS-40 10.00
Calamide CWT 5.00
Comments a b o u t t h i s f o r m u l a :
May need t o be h e a t e d t o s o l u b i l i z e t h e s u r f a c t a n t .
F o r m u l a t i o n HDL-008-01

SOURCE: P i 1o t Chemical Co. : Suggested Formul a t i ons


80 Advanced Cleaning Product Formulations

I & I L i q u i d Laundrv Detergent


w i t h Enzyme & O p t i c a l

Components: % by Weisht
Water 50.00
T r i e t h a n o l ami ne 85% 3.25
D i e t h y l ene G1 y c o l 20.00
B u r c o l 117 10.00
B u r c o l LAF-6 10.00
Burcowi t e BBH-PO 1.25
B u r c o t a s e SL-160 0.50

B u r c o LAF-6 i s used t o c o n t r o l foam as w e l l a s t o p r o v i d e


w e t t i n g and d e t e r g e n c y .

Procedure:
Charge 1 / 2 o f w a t e r I3 120F. Add 1 , 2 , 3 , & 4 and b l e n d . Add
r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B l e n d u n t i l u n i f o r m .

1% pH: 9 . 5
% s o l i d s : 26
Lbs/gal : 8.66

S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes

Ingredients: % bv W e i q h t
Water 30
TKPP 5
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 5
B u r c o t e r g e DG-40 40
B u r c o NPS-876 10
SXS-40% 10

6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e


s l i g h t l y higher levels.

SOURCE: B u r l i n g t o n Chemical Co.: Suggested F o r m u l a t i o n s

Powder f o r A u t o m a t i c D i s h w a s h i n n M a c h i n e s

Ingredients: YO by W e i q h t
A Genapol 2908 1 .oo
B Sodium m e t a s i 1 i c a t e x 5H20 52.00
C Sodium c a r b o n a t e 10.00
Sodi um d i c h l o r o i s o c y a n u r a t e 2.00
Thermphos NW 35.00

Manufacturing:
I Spray A on B .
I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1
A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i s h w a s h i n g l i q u o r

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n


Laundry Products 81

IndustriaT Heavy Duty Laundry L i q u i d


Carbopol ETD 2691 is t o p r o v i d e p r o d u c t phase s t a b i l i z a t i o n i n
t h i s high a l k a l i n i t y i n d u s t r i a l strength cleaner.

I nsredient : Wt%
D I water 49.00
Carbopol ETD 2691 ( 1 ) 0.50
612-15 l i n e a r a l c o h o l , 7 moles EO ( 2 ) 18.00
Sodium a l k y l b e n z e n e s u l f o n a t e (60%) ( 3 ) 5.50
Potassium h y d r o x i d e (45%) 2.00
Sodium m e t a s i l i c a t e , anhydrous 5.00
T e t r a p o t a s s i u m pyrophosphate 20.00

P h y s i c a l Pi-opert ie s :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900
P r o d u c t pH: 14
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical C o . : Neodol 25-7
( 3 ) Stepan Co.: B i o s o f t D-62

PP.0cedure:
I . Use a b i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous
and f r e e o f polymer lumps.
2. W i t h s l o w m i x i n g , add i n t h e a l c o h o l e t h o x y l a t e and a l k y l -
benzene s u l f o n a t e s u r f a c t a n t s .
3. C o n t i n u e a g i t a t i n g and add t h e p o t a s s i u m h y d r o x i d e and meta-
s i li c a t e .
4. Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o a v o i d a i r
entrapment.
5. Add dyes and f r a g r a n c e , as d e s i r e d .

Total Wcti ves :


Sodi um a1 k y l benzene sul f o n a t e : 3.30
C12-15 l i n e a r a l c o h o l , 7 moles EO: 18.00
T e t r a p o t a s s i u m pyrophosphate: 20.00

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-201


82 Advanced Cleaning Product Formulatioris

I n d u s t r i a l Laundry D e t e r a e n t s
H i g h C a u s t i c Formula-

Components: % bv Weiaht
Burco NPS-816 15.0
Burcosperse LP 10.0
B u r c o l i t e BSGH-255 5.0
Dequest 2000 5.0
50% NaOH 65.0

Procedure:
B l e n d a l l components e x c e p t 50% NaOH. S l o w l y add NaOH w i t h
a g i t a t i o n . Keep t e m p e r a t u r e below 1 6 0 F d u r i n g t h e e n t i r e
agitation.

Mixed B u i l d e r F o r m u l a t i o n

Components: % by Weight
Water 31.5
45% KOH 23.5
B u r c o s p e r s e LP 10.0
TKPP 10.0
Burco NPS-816 15.0
S t a r Grade Sodium S i l i c a t e 10.0

Procedure:
D i s s o l v e KOH i n w a t e r . S l o w l y add Burcosperse LP w h i l e
a g i t a t i n g . Keep t e m p e r a t u r e below 160F. Add TKPP and s t i r u n t i l
d i s s o l v e d . Add Burco NPS-816, t h e n S t a r Grade Sodium S i l i c a t e
and b l e n d u n t i l u n i f o r m .

Use l e v e l s a r e 6-12 ounces p e r 100 pounds, depending on s o i l


l o a d i n g , temperature, e t c .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

Washi np P a s t e w i t h 81 e a c h i n g A g e n t

Ingredients: % b y Weiaht
Water 39.0
Sodium t r i p o l y p h o s p h a t e 3.0
Sodium d i t h i o n i t 12.0
Xanthan Gum 2.0
Whi t e - s p i r i t 10.0
Lumorol 4154 30.0
Zusol a t 1005/85 5.0

SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n CT 07-06-01


Laundry Products 83

L a u n d r y Deteraent-Consumer
(Liquid)

S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e . make-up, food s o i l


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n Method-Household w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition: Wt%
Water 37.6
Fluorescent Brightener 0.2
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l A S E - I 08 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s €0 10.0
Potassium H y d r o x i d e (45%) 2.2
***Sodium C i t r a t e ( a n d / o r C i t r i c A c i d ) 25.0
K a s i l #6 Potassium S i l i c a t e 12.5
EDTA 5.0
Enzymes ( P r o t e a s e ) 1.o

x( Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e


(40%)
** Rhone-Poul enc I g e p a l CO-630
*** A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e
enzyme p e r f o r m a n c e ( i . e . 8 . 5 - 9 . 5 p H ) .

L a u n d r y Detergent-Consumer
I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e , f o o d s o i l , make-up


S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r
A p p l i c a t i o n Method-Household w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition : Wt%
Water 52.6
C a r b o p o l 674 0.5
D L i q u i d Sodium S i l i c a t e 8.1
* A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 0.9
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-.13, EO 6 . 5 M o l e s ) 4.3

t: Rohm & Haas


** S h e l l Chemical Neodol 23-6.5

SOURCE: PQ C o r p . : Detergent Formulary Guide


84 Advanced Cleaning Product Formulations

Laundry Detergent-Consumer
( Z e r o Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste


S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r
A p p l i c a t i o n Method-Household Washing Machine
Manufacture-Dry Blend/Agglomeration
Composition: Wt9/o
Sodi um Carbonate 30.0
B r i t e s i l H20 Hydrous P o l y s i l i c a t e 10.0
*Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.0
* * L i n e a r A 1 k y l benzene S u l f o n a t e (LAS) 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 5.0
V a l f o r 100 Z e o l i t e A 30.0
Sodi um S u l f a t e 12.5
O p t i c a l B r i g h t e n e r , Perfume 0.5

Use L e v e l : 1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 gram


d e t e r g e n t / l i t e r o f water)

* Rohm & Haas


** Stepan Nacconol 9OG (90% a c t i v e ; powder)
*** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical
Neodol 25-7

Laundry Detergent-Consumer
(Phosphate, Powder)

S o i l - A c i d i c f o o d f a t and p r o t e i n , body p e r s p i r a t i o n , g r a s s and


dirt
Surface-Polyester, cotton/polyester, cotton
A p p l i c a t i o n Method-Household washing machine
Manufacture-Dry blend/agglomeration

Composi t i on : Q
B r i t e s i l H20 Hydrous P o l y s i l i c a t e 10.0
*STPP 30.0
*Sodium Carbonate 30.0
Sodi um S u l f a t e 14.5
* * L i n e a r A1 k y l benzene Sul f o n a t e (LAS) 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 5.0
O p t i c a l B r i g h t e n e r , Perfume 0.5

Use L e v e l : 1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 g r a m / l i t e r of


water)

* FMC
** Stepan Nacconol 90G (90% a c t i v e ; powder)
*** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co.
Neodol 25-7

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 85

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
( L i q u i d , Phosphate1

S o i l - A c i d i c f o o d f a t , o i l a n d g r e a s e ; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition A :
Water 34.1
TKPP 10.0
P o t a s s i urn H y d r o x i d e (45%) 30.4
S t a r Sodium S i l i c a t e 18.0
Sodium H y d r o x i d e (50%) 7.5

C o m p o s i t i o n B: wts/,
Water 25.6
TKPP 10.0
P o t a s s i u m H y d r o x i d e (45%) 30.4
S t a r Sodi um S i 1 i c a t e 24.0
Sodium H y d r o x i d e (50%) 10.0

Use D i l u t i o n : Light Soil: 0.25% by w e i g h t o r 1 l b p e r 100 l b s


1a u n d r y
Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y
N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t .

Laundry B r e a k - I n d u s t r i a l & Institutional


(Liquid)

S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition: %
Water 0-20
N C l e a r Sodium S i l i c a t e 70-90
Sodium H y d r o x i d e (50%) 10-20

Use D i l u t i o n : Light Soil: 0.25% b y w e i g h t o r 1 l b p e r 100 l b s


1a u n d r y
Medium/Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y
Notes: Blend t h i s b u i l d e r s o l u t i o n t o 1.7-2.0 r a t i o Si02/Na20 b w
f o r b e s t s t a b i l i t y and i n d u s t r i a l d e t e r g e n c y .
D o r BJ-120 sodium s i l i c a t e s c a n a l s o b e used as b u i l d e r
solutions without blending.
Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
86 Advanced Cleaning Product Formulatiom

Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA/Zeol it e , P o w d e d

S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry blend/Agglomeration

Composi t i on :
M e t s o Beads 2048 25.0
Sodi um C a r b o n a t e 38.0
NTA 15.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) 12.0
V a l f o r 100 Z e o l i t e A 10.0

Use L e v e l : L i g h t S o i l - O . 2 5 % b y w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y

N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y or


f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r


S h e l l Chemical Neodol 25-7

L a u n d r y B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)

S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - U s e as r e c e i v e d

Composi t i on : Wt46
M e t s o Beads 2048 100.0

Use D i l u t i o n : L i g h t S o i l - O . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y -
Heavy S o i l - O . 7 5 % by w e i g h t o r 3 l b s p e r 100 I b s
1a u n d r y

N o t e : Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) at
2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundqi Products 87

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composition: WtO/o
Metso Beads 2048 25.0
*Sodium C a r b o n a t e 35.0
*STPP 30.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 m o l e s EO; C12-15) 10.0
Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - O . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend-
i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o
i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d .
x< FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Sodium Carbonate, Powder)

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composi t i on : Q
Metso Beads 2048 25.0
Sodium C a r b o n a t e 55.0
Sodi um S u l f a t e 10.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0
Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
'k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol
25-7

SQURCE: PQ G o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
88 Advanced Cleaning Product Formulations

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate. Powder, H i g h A l k a l i n i t y )

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry b l end/Agglomeration
Composition A : Wt%
Metso Beads 2048 60.0
Sodium H y d r o x i d e Beads 40.0
Composition 8: Wt%
Metso Beads 2048 30.0
*STPP 20.0
*Sodium Carbonate 28.0
Carboxymethylcellulose 2.0
Sodium H y d r o x i d e Beads 20.0
Use D i l u t i o n : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s
1aundry
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 1 0 0 I b s
1aundry
Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 1 0 0 lbs
1aundry
Note: Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y
d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t
detergent
* FMC

Laundrv B r e a k - I n d u s t r i a1 8, I n s t i t u t i o n a l
( Z e r o Phosphate Powder, H i ah A1 k a l in i t v )

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composi t i on A : Wt%
Metso Beads 2048 60.0
Sodium H y d r o x i d e Beads 40.0
Composition 8: W S
Metso Beads 2048 30.0
Sodi um Carbonate 28.0
Carboxymethylcel l u l o s e 2.0
Sodium H y d r o x i d e Beads 20.0
V a l f o r 100 Z e o l i t e A 20.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 I b s
1aundry
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 0 0 l b s
1aundry
N o t e : Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t -
e r g e n t ( u n b u i l t ) a t 2 - 4 p a r t s bw o f b u i l d e r w t h 1 p a r t
detergent
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 89

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Reduced Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry blend/Agglomeration
Composition: Wt%
M e t s o Beads 2048 25.0
*Sodium C a r b o n a t e 35.0
*STPP 20.0
% * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 m o l e s EO; C12-15) 10.0
V a l f o r 100 Z e o l i t e A 10.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend-
i n g / e m u l s i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so
i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
96 FMC
dc* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7

Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA, Powder)

S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine
Manufacture-Dry blend/Agglomeration
Composi t i on : Wt%
M e t s o Beads 2048 25.0
Sodium C a r b o n a t e 40.0
NTA 25.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : U s e B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
*Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol
25-7

SOURCE: PQ C s r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
90 Advanced Cleaning Product Formulations

Laundry D e t e r q e n t - I n d u s t r i a l B I n s t i t u t i o n a l
(Sodium Carbonate w i t h F l o w A i d . Powder)

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
Appl ic a t ion Method-I n d u s t r ia1 wash ing mach i ne
Manufacture-Dry blend/agglomeration

Composi t ion : Wt%


Metso Beads 2048 20.0
Sodium Carbonate 55.0
Sodi um S u l f a t e 10.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) 10.0
V a l f o r 100 Z e o l i t e A 5.0

Use L e v e l : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 1 0 0 l b s
1aundry
Medium S o i l : 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1 aundry
Heavy S o i l : 0.75% b y w e i g h t o r 3 l b s p e r 100 l b s
1 aundry

Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y


o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more sus-
p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l
a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

* Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r


S h e l l Chemical Neodol 25-7

Laundry D e t e r g a n t - I n d u s t r i a l & I n s t i t u t i o n a l
IPhosphate, S o l i d Block)

S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washing machine
Manufacture-Sol i d b l o c k

Composi t i on : Wt%
Metso Beads 2048 25.0
NaOH ( 5 0 % S o l u t i o n ) 25.0
*STPP 35.0
*Sodium Carbonate 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 3.0
* FMC
** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 91

Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
(Zero Phosphate, Powder)

S o i l - A c i d i c f o o d f a t , o i l g r e a s e , b l o o d , sebum and body w a s t e


S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry Blend/Agglomeration

Composition : Wt%
Sodi um C a r b o n a t e 35.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles € 0 ; C12-15) 15.0
V a l f o r 100 Z e o l i t e A 25.0
M e t s o Beads 2048 25.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a1 k a l in i t y is d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t blend.
*Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7

L a u n d r y D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)

S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on

Composi t ion : Wt%


Sodium C a r b o n a t e 44.5
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 18.0
V a l f o r 100 Z e o l i t e A 30.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.5
M e t s o Beads 2048 5.0
Use L e v e l : L i g h t S o i 1-0.25% b y w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y
Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
** Rohm & Haas

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
92 Advanced Cleaning Product Formulations

Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l
[ P h o s p h a t e B u i 1t , L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, food s o i l


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition A: Wt%
Water 54.5
TKPP 4.6
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodium S i l i c a t e 15.0
Sodi um H v d r o x i d e (,5 0 %.) 4.2
*PhosphaGe E s t e r 5.0
**Liquid Nonionic Surfactant (C12-C15, 7-9 M o l e s € 0 ) 3.0

C o m p o s i t i o n B: Wt%
Water 59.1
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodi um S i 1 i c a t e 15.0
Sodium H y d r o x i d e ( 5 0 % ) 4.2
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3.0
Use D i l u t i o n : 0 . 2 5 % - 0 . 5 0 % b y w e i g h t or 1-2 l b s p e r 1 0 0 l b s
1a u n d r y
* Rhone-Poulenc Rhodafac RE-610
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9

Laundry D e t e r g e n t - I n d u s t r i a l & Institutional


( L i quid)

Soi 1-Body o i 1 and p e r s p i r a t i o n , body w a s t e , make-up, food soi 1


S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition: wts/,
Water 28.7
F1 u o r e s c e n t B r i g h t e n e r 0.1
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l ASE-108 ( A c r y l i c P o l y m e r ) 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 M o l e s EO 10.0
P o t a s s i um H y d r o x i d e (45%) 2.2
TKPP (60%) 40.0
K a s i 1 #6 P o t a s s i um S i 1 i c a t e 12.5
Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 1 0 0 I b s
1a u n d r y
* Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%)
**Rhone-Poulenc I g e p a l CO-630

SOURCE: PQ C o r p . : Detergent Formulary Guide


Laundry Products 93

Laundry B u i l d e r - I n d u s t r i a l & Institutional


(L iquid)

S o i l - A c i d i c f o o d , f a t , o i l and grease; b l o o d , sebum and body


waste
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition A : Wt%
P o t a s s i u m H y d r o x i d e (45%) 35-45
iU C l e a r o r E Sodium S i l i c a t e 55-65

C o m p o s i t i o n B: Wt%
Water 11.0
Potassium Hydroxide ( S o l i d ) 37.0
N C l e a r or E Sodium S i l i c a t e 52.0

Composition C: Wt%
Water 6.0
Potassium Hydroxide ( S o l i d ) 28.0
N C l e a r o r E Sodium S i l i c a t e 52.0
Sodium H y d r o x i d e ( S o l i d ) 14.0

Use D i l u t i o n : Light Soil: 0.25% by w e i g h t o r 1 l b p e r 100 l b s


1a u n d r y
Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y

N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t

Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
( Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )

S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , make-up


S u r f a c e - C o t t o n and. c o t t o n - p o l y e s t e r -
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing a c h i ne
Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r

Composition: WtO/o
Water 57.06
C a r b o p o l 674 0.5
Metso Beads 2048 2.7
*Acusol 445N Sodi um P o l y a c r y a t e (45% s o l d s ) 1.04
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-13; EO 6 . 5 M o l e s ) 4.3

8 Rohm 8: Haas
** S h e l l Chemical Neodol 2 3 - 6 . 5

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
94 Advanced Cleaning Product Formulations

Laundry P r e s o o t t e r S p r a y a b l e Gel

Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o c o s t e f f e c -


t i v e l y t h i c k e n t h e s u r f a c t a n t system i n t o a g e l f o r m - which can
be a p p l i e d t o t h e f a b r i c by b r u s h o r sprayed on due to C a r b o p a l ' s
shear t h i n n i n g n a t u r e .

Inaredi ent:
D I water 83.75
Carbopol ETD 2623 ( 1 ) 0.20
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 males €0 ( 3 ) 5.00
EDTA ( t e t r a sodium s a l t ) 0.50
Sodium h y d r o x i d e (18%) 0.55

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps


P r o d u c t pH: 7.0-8.0
P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) S h e l l Chemical C o . : Neodol 23-6.5

Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . M i x u n t i l
homogeneous.
3. Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .

Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO ( 2 ) : 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 3 ) : 5.0

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-224


Laundry Products 95

Laundry Presootter Sorayable L i q u i d

Carbopol ETD 2 6 2 3 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y


t h i c k e n t h e s u r f a c t a n t system and e n a b l e t h e p r o d u c t t o s t a y i n
c o n t a c t w i t h t h e s o i l l o n g e r b y r e d u c i n g seepage t h r o u g h t h e
fabric.

I n s r e d ie n t : Wt%
D I water 84.30
Carbopol ETO 2623 ( 1 ) 0.05
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) 5.00
EOTA ( t e t r a sodium s a l t ) 0.50
Sodi um h y d r o x i d e (18%) 0.15

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 2 5 0 cps


P r o d u c t pH: 7 . 0 - 8 . 0
P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodri ch
( 2 ) S h e l l Chemical Co.: Neodol 2 5 - 3
( 3 ) S h e l l Chemical Co.: Neodol 2 3 - 6 . 5

Procedure:
I . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2. Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . Mix u n t i l
homogeneous.
3 . Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r s o l u t i o n and f r a g r a n c e , as d e s i r e d .

Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO: 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 5.0

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-220


96 Advanced Cleaning Product Formulations

L i g h t Duty L i q u i d Detergent

Ingredients: wej-ghs
Water 48.45
P i l o t SXS-40 7.50
C a l s o f t L-60 30.00
Calamide C 5.00
C a l foam EA-603 8.30
C a l s o f t LAS-99 0.60
C i t r i c Acid 0.10
Sodium C i t r a t e 0.05
Comments a b o u t t h i s f o r m u l a :
1 . pH=7.1
2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e i f pH i s l o w .
3 . V i s c o s i t y s h o u l d b e 300 c P s .
F o r m u l a t i o n LDL-001-01

L i s h t Duty Liquid Detergent

Ingredients: Weight%
Water 22.31
C a l s o f t L-60 39.70
P1 l o t s x s - 4 0 22.10
Calamide C 7.06
C a l f o a m EA-603 7.35
C a l s o f t LAS-99 0.56
Opaci f i e r 0.88
Sod1 um C i t r a t e 0.04
Comments a b o u t t h i s f o r m u l a :
1 . Add e i t h e r C i t r i c A c i d o r C a l s o f t LAS-99 t o a d j u s t pH t o
7.0-7.2.
2 . S o l i d s 45%.
3 . S u b s t i t u t i n g C a l s o f t L-40 for C a l s o f t L-60 w i l l lower
p r o d u c t s o l i d s t o 42%.
F o r m u l a t i o n LDL-002-01

L i g h t Duty L i q u i d Detergent

Ingredients: Weight%
Water 18.80
Calsuds A 70.00
C a l foam ES-303 10.00
Perfume 0.10
K a t h o n CG 0.10
Opaci f ie r 1.oo
Comments a b o u t t h i s f o r m u l a :
1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r
2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e
detergent.
F o r m u l a t i o n LDL-004-01

SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s


Laundry Products 97

L i g h t -Duty L i q u i d Detergent

Ingredi ents : Weight%


Water 50.20
C a l s u d s CD-6 25.00
P i l o t SXS-40 6.80
C a l foam EA-603 10.00
Cal s o f t LAS-99 6.00

Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n
blending.
2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH a d j u s t m e n t
t o 7+.
3 . S a l t ( S o d i u m o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y .
F o r m u l a t i o n LDL-006-01

L i g h t Duty L i q u i d Detergent

In g r e d i e n t s : Weight%
Water 36.90
P i l o t SXS-40 5.00
C a l s o f t T-60 40.00
C a l foam ES-303 15.00
Calamide C 2.00
P r e s e r v a t iv e 0.10
S o d i um C h l o r i d e 1 .00

Comments a b o u t t h i s f o r m u l a :
V i s c o s i t y 275 cPs.
Sol i d ~ = 3 2 - 3 3 %
pH=6.2
F o r m u l a t i o n LOI-007-01

L i g h t Duty L i q u i d Detergent

Ingredients: Weight%
Water 65.16
P i l o t sxs-40 6.29
L i n e a r A1 coho1 E t h o x y l a t e 2.52
NaOH, 5 0 % 2.81
D i e t h a n o l am1 ne 0.43
C a l s o f t LAS-99 19.77

Comments a b o u t t h i s f o r m u l a :
S o l 1 ds=30%
Good f o r g r e a s y a p p l i c a t i o n s .
F o r m u l a t i o n IDL-006-01

SOURCE: P i l o t C h e m i c a l Co : S u g g e s t e d F o r m u l a t i o n s
98 Advanced Cleaning Product Formulations

L i g h t Duty L i q u i d Detergent

I n g r e d i ent-sl Weight%
Water 13.90
Ammonium C h l o r i d e 2.40
P i l o t sxs-40 19.60
C a l s o f t L-60 44.10
Cal foam ES-303 15.80
Calamide C 4.00
C i t r i c Acid 0.10
P r e s e r v a t iv e 0.10

Comments a b o u t t h i s f o r m u l a :
1 . “ A s i s ” pH=8.0.
2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH.
F o r m u l a t i o n LDL-009-01

Ligh-t- D u t y L i q u i d D e t e r q e n t
C a l s o f t LAS-99 Based

Ingredients: Weight%
Water 43.60
NaOH, 50% 5.80
C a l s o f t LAS-99 21.70
P i l o t SXS-40 16.70
Cal foam ES-303 3.00
C a l o x y l a t e N-9 8.00
C i t r i c Acid 0.10
Opaci f ie r 1 .oo
Preservative 0.10

Comments a b o u t t h i s f o r m u l a :
A d d in g r e d i e n t s i n o r d e r 1 is t e d .
F o r m u l a t i o n LDL-011-01

L i g h t D u t y L i q u i d Detergent
C a l s o f t LAS-99 Based

Ingredients: Weight%
Water 52.40
NaOH, 50% 4.40
Cal s o f t LAS-99 16.30
Calamide C 5.00
P i l o t SXS-40 12.50
Cal foam ES-303 2.20
C a l o x y l a t e N-9 6.00
C i t r i c Acid 0.10
Opaci f ie r 1.oo

Comments a b o u t t h i s f o r m u l a :
Add ingredients i n order l i s t e d .
F o r m u l a t i o n LDL-012-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Laundry Products 99

a h t Duty L i q u i d Detergent
__
C a l s o f t LAS-99 Based
Inaredients; Weight%
Water 54.60
C a l s o f t LAS-99 16.30
NaOH, 50% 4.35
Alcohol Ethoxyl a t e 10.00
Calamide C 2.05
P i l o t SXS-40 12.50
Perfume 0.10
P r e s e r v a t iv e 0.10
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Formul a t i on LDL-014-01

Light DutLLCquid D e t e r E n t
Dry Cleaner: Pre-Spot-Water S o l u b l e
Ingredients: Weight%
Water 75.70
Calamide C 2.00
C a l o x y l a t e N-9 11.00
C a l i mu1 s e PRS 11 .oo
C i t r i c Acid 0.20
Perfume & C o l o r 0.10
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as
C a l o x y l a t e N-9 i s added.
2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e m i x e d
together.
3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a .
4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r .
F o r m u l a t i o n LDY-001-01

Li-ght D u t y Li.qu2d D e t e r g e n t
Wool _Wash
I c g r e d i ents-: Wei g h t %
C a l s o f t T-60 14.15
C a l ami d e CW-100 5.48
C a l f o a m ES-303 39.64
C i t r i c Acid 0.13
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 520 c P s .
F o r m u l a t i o n LDY-002-01

L i g h t D u t E L i q u j d Detergent
--

Wool Wash
Ing r e d i g n t s : We1 g h t %
Calsuds A 50.06
Water 49.93
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 25 c P s .
F o r m u l a t i o n LDY-004-01

SOURCE: P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s


100 Advanced Cleaning Product Formulations

Two Part Industria1 Laundry Deteraents


Break Formulations
Hi q h l v A 1 kal ine Break
Components: % by Weight
Water 5
Burcosperse LP 10
Burcolite BSGH-255 5
Dequest 2000 5
50% NaOH 75

Mixed Builder Break


Components: % by Weight
Water 40.0
45% KOH 27.5
Burcosperse LP 10.0
TKPP 10.0
Sodi um Si 1 i cate (Star Grade) 12.5
Procedure:
Add components in the order listed. Blend until homogeneous
between each addition. Keep temperature below 160F during
bl endi ng.

Detergent Additive
Components: % by Weight
Water 60.00
Burco NPS-816 10.00
Neodol 25-7 12.50
Dodecylbenzenesulfonic Acid 11.65
TEA-85 5.85
Procedure:
Add components in the order listed. Blend until homogeneous
between each addition.
Use Level:
Break: 4-12 ounces/100 pounds
Detergent: 2-4 ounces/100 pounds

SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations


Laundry Products 101

U l t r a L i q u i d Laundrv Deterqent
Ingredients: Wt%
A l p h a - S t e p MC-48 29.0
Sodi urn 01e a t e 5.0
Alcohol, Ethoxylate, 7 19.0
Borax 1.3
3A A l c o h o l 0.5
P r o p y l ene G1 y c o l 5.0
PVP K-15 0.8
W a t e r , f r a g r a n c e & dye Q . S . t o 100.0
M i x i n g Procedure:
Combine A l p h a - S t e p MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y -
l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous.
H e a t t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m i x
u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o
c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h
m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f n e c e s s a r y .
Typical Formulation Properties:
F o r m u l a t i o n D e s c r i p t i o n : SME/Soap Based HDL
pfl: 8-10
V i s c o s i t y : 200-350 c p s
Density: 8.6
Appearance: C l e a r , l i g h t y e l l o w 1 q u i d
Use I n s t r u c t i o n s : Use 1 / 3 c u p p e r n o r m a l s i z e w a s h l o a d
Comment:
A l p h a - S t e p MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t c a n
make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s .
F o r m u l a t i o n N o . 658
F i n e F a b r i c Wash
Ingredients: Wt%
Water, D . I . 43.4
A l p h a - S t e p MC-48 46.0
N i n o l 30-LL 4.6
Sodi um c h l o r i d e 6.0
M i x i n g Procedure:
Charge w a t e r and MC-48 and m i x . Add 30-LL and m i x u n t i l
homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h
s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 7 . 5
V i s c o s i t y @ 25 deg. C, c p s : 220
S o l i d s , %: 2 9 . 0
F r e e z e / t h a w , 3 c y c l e s : pass
C o l d s t o r a g e @ 4 deg. C, 1 week: p a s s
H i g h temp. s t o r a g e @ 50 deg. C, 1 week: p a s s
Density, l b s / g a l : 0.6
Use I n s t r u c t i o n s :
Use s m a l l amount f o r hand w a s h i n g o r 1 / 4 cup f o r machine
washing.
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
F o r m u l a t i o n No. 358
SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s
9. Metal Cleaners and Polish
Metal Cleaners and Polishes 103

Acid Metal Cleaner*

The c o m b i n a t i o n o f Veegum and Rhodopol 2 3 suspends t h a a b r a -


s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good
v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n
i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d -
a z o l i n e . T e t r a s o d i u m EDTA f a c i l i t a t e s t h i s exchange. Veegum
and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y
s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h
e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s -
i n g and p o l i s h i n g .

Inqredients: y
&
A: Veegum 0.8
Rhodopol 23 0.4
Water 72.1

6: T e t r a s o d i u m EDTA 0.9
1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i ine 0.8
Phosphoric a c i d 15.0
Diatomaceous E a r t h 10.0

Procedure:
B l e n d Veegum and Rhodopol S l o w l y add them t o t h e w a t e r w h i l e
a g i t a t i ng a t maximum a v a i 1ab e s h e a r . C o n t i n u e m i x i n g u n t i l
smooth. Add B i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each
a d d i t i o n u n t i l smooth and un f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) .
Consistency: White, pourable l i q u i d .

Suggested P a c k a g i n g : P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y
labeling f o r acid.
*U.S. P a t e n t No. 4,302,253

SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 392

D i ppi ns C1 e a n e r f o r S i 1v e r

Ingredients:
Z u s o l a t 1008/85 2.5
Thiourea 8.0
Hydrochloric acid 3.0
Water 86.5

SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n CT 0 2 - 1 5 - 0 2


104 Advanced Cleaning Product Formulations

A1 umi num C1 e a n e r / B r i g h t e n e r

T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t -
ergency t h e n n o n i o n i c s , b u t were n o t c o m p a t i b l e i n a c i d systems.
T h i s f o r m u l a t i o n uses Avanel S - 7 0 , an a n i o n i c m o l e c u l e w h i c h
p e r f o r m s even a t v e r y low p H ' s and a i d s i n t h e removal o f s u r f a c e
o i l s and d e p o s i t s . U n l i k e n o n i o n i c s , Avanel 5-70 w i l l d i s s o l v e
r e a d i l y i n t o the formulation without forming gel p a r t i c l e s thus
e l i m i n a t i n g t h e need f o r e x c e s s i v e a g i t a t i o n . T h i s f o r m u l a t i o n
can be used f o r o v e r - t h e - r o a d aluminum t r a i l e r s , w i r e wheels
on a u t o m o b i l e s o r i n t h e p r e p a r a t i o n o f aluminum f o r a n o d i z i n g
and c l eani ng.

Inqredients: Wt%
Dei o n i zed Water 83.0
Phosphoric A c i d ( 8 5 % ) 6.0
C i t r i c Acid (50%) 8.0
N i t r i c Acid (70%) 1.o
Avanel S-70 2.0

Procedure:
Charge t h e w a t e r t o a m i x i n g v e s s e l . Under slow a g i t a t i o n and
w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0
and m i x 10 m i n u t e s . NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d ,
t h e n i t r i c a c i d c o n c e n t r a t i o n may be i n c r e a s e d t o 1 . 5 % .
F o r m u l a t i o n CM-101

Powdered M e t a l C l e a n i n g C o n c e n t r a t e

I n a r e d ients: Wt%
Sodi um H y d r o x i d e 58.5
Sodium Carbonate 13.5
STPP 20.0
Avanel 5-70 8.0

Procedure:
Add i n g r e d i e n t s as l i s t e d .

A1 u m i num C1 eaner

Ingredients:
D e i o n i z e d Water 85.0
Avanel S - 7 0 6.0
T e t r a p o t a s s i u m Pyrophosphate 5.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
C a r b i t o l Solvent 3.0

Procedure:
Charge v e s s e l w i t h i n g r e d i e n t s i n t h e o r d e r l i s t e d u s i n g mod-
e r a t e a g i t a t i o n . NOTE: Other Avanel p r o d u c t s c o u l d be used i n
t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 105

A1 umi num C l e a n e r C o n c e n t r a t e F-498

UhWeight
Water 75
Sodium M e t a s i l i c a t e (Anhydrous) 10
T e t r a Potassium Pyrophosphate (Powder) 5
Mona NF-10 10

Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e
i n w a t e r w i t h m i x i n g , t h e n add Mona N F - 1 0 .

Typical Properties:
Appearance : C l e a r 1 iq u i d
Cloud P o i n t : 8 8 C

Recommended Use D i l u t i o n : 1 t o 4 o z / g a l

Aluminum Wash F-499

% By Weiaht
Water 88
Sodium M e t a s i l i c a t e (Anhydrous) 2
T e t r a Sodium Pyrophosphate (Powder) 3
B u t y l Carbi t o 1 2
Mona N F - I 0 5

Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a sodium p y r o p h o s p h a t e
i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10.

Typical Properties:
Appearance: C l e a r 1 iq u i d
pH: 1 2 . 8

Recommended Use D i l u t i o n : 1 : l O w i t h water

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


106 Advanced Cleaning Product Formulations

B u f f i nq Compound Remover

Component: %
Water 42.5
TEA 20.0
B u r c o t r o p e 1250 12.5
B u r c o s p e r s e LP 12.5
Borax 5.0
B u r c o TME 5.0
B u r c o LAF-6 5.0

Add components i n o r d e r l i s t e d . B l e n d u n t i l homogeneous between


each a d d i t i o n .

H o t A1 k a l in e P a i n t S t r i p p e r C o n c e n t r a t e

Compo n e n t s : a
45% KOH 67
K a s i l #1 32
B u r c o HCS-50 NF 1

Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l homogeneous


between each a d d i t i o n .

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

M e t a l De-Oi 1 in g L i q u i d C o n c e n t r a t e
(Liquid)

S o i l - Petroleum-based o i l
S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c .
A p p l i c a t i o n Method - Spray a n d / o r i m m e r s i o n
Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : wtu/,
Water 42.0
Starso 12.0
EDTA, T e t r a s o d i u m ( 3 7 % ) 16.0
Sodi um X y l ene S u l f o n a t e ( 4 0 % ) 20.0
C9-C11 L i n e a r A l c o h o l , 6 Moles EO 3.0
C9-C11 L i n e a r A l c o h o l , 2.5 M o l e s EO 7.0

Use D i l u t i o n : 2%-4% b v

SOURCE: The PQ C o r p . : Suggested F o r m u l a t i o n


Metal Cleaners and Polishes 107

Cutting O i l

Monalube 215 p r o v i d e s e x c e l l e n t l u b r i c i t y , and e x t r e m e p r e s s -


u r e p r o p e r t i e s . T h i s f o r m u l a t i o n i s used i n machining, stamping
and d r a w i n g f e r r o u s and n o n f e r r o u s m e t a l s .
Innredients: Wt%
100 P a l e O i l 95.0
Monalube 215 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
V i s c o s i ty/4OC: 24 CS
Performance Data:
Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /56 I n . -Lbs .
Draw Bead E f f i c i e n c y : 95
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Formul a t ion F-791

Cutting O i 1

Inqredients:
100 P a l e O i l 90.0
Monalube 205 5.0
Monalube 215 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C l e a r Amber L i q u i d
V i s c o s i t y ( 4 0 C ) : 25 CS
.
Fa1 e x : 2250 Lbs / 6 0 I n . -Lbs .
Appl i c a t i ons: F o r machi n i ng s t a m p i n g and d r a w i n g .
F o r m u l a t i o n F-792

Cutting O i l

Inqredients: Wt%
100 P a l e O i l 85.0
Monalube 205 5.0
Monalube 215 5.0
Monalube 225 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
V i s c o s i t y / 4 0 C : 30 CS
Performance Data:
F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 7 0 I n . . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Appl i c a t i ons: Heavy d r a w i n g and s t a m p i n g
F o r m u l a t i o n F-793
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
108 Advanced Cleaning Product Formulations

Cutting O i l

Ingredients: %
&
100 P a l e O i l 90.0
Monalube 215 5.0
Monalube 225 5.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
T y p i c a l P r o p e r t ie s :
Appearance: C l e a r Amber L i q u i d
V i s c o s i t y 40C: 27 CS
Performance D a t a :
F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Formul a t ion F-794

Cuttina O i l

Insredients: WtO/o
100 Pale O i l 95.0
Monalube 225 5.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
V i s c o s i t y 40C: 24 C S
Performance D a t a :
F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Formul a t ion F-795

Cutting Oi1

Inqredients: Wt%
100 P a l e O i l 90.0
Monalube 215 5.0
Monalube 325 5.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C l e a r Dark Brown L i q u i d
V i s c o s i t y 40C: 22 CS
P e r f o r m a n c e Data:
F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 5 I n . - L b s .
F o r m u l a t i o n F-796

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 109

Cutting O i l s

Semi-Synthetic-Cutting Oi1

Ingredients: Wei q h t %
A r i s t o n a t e M-LF 17.77
Oleic Acid 2.98
TEA 2.75
P r o p y l ene G l y c o l 15.04
Water 61.48

Comments a b o u t t h i s f o r m u l a :
1 . M i x a l l of t h e i n g r e d i e n t s , e x c e p t t h e P r o p y l e n e G l y c o l .
2 . Add t h e w a t e r SLOWLY.
3 . Add t h e P r o p y l e n e G l y c o l l a s t .
F o r m u l a t i o n SOF-001-01

C u t t i n g O i 1 Concentrate

Ingredi ents: Wei g h t %


Aristonate M 60.60
D r e s i n a t e 91 20.20
I g e p a l CO-430 0.10
KOH, 45% 1.25
O l e i c A c i d , Emersol 2 1 3 O l e i c A c i d 8.25
Diethylene Glycol 7.10
Water 2.50

Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-001-01

Cutting O i 1 C o n c e n t m e

I ny,,edie n t s : Weight%
Aristonate M 51.80
Neodol 2 5 - 3 21.60
TEA, 85% 4.50
Oleic Acid 8.50
D i e t h y l ene G1 y c o l 8.60
Water 5.00

Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 1 0 0 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 1 6 0 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-002-01

SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s


I 10 Advanced Cleaning Product Formulations

G e n e r a l Purpose Machine C l e a n e r

T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l
t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s
i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .

In g r e d i e n t s :
Water 69.00
T r i e t h a n o l a m i ne 4.00
Monacor 4000 3.50
Monami ne CF-1 OOM 6.00
M o n a t e r i c CyNa-50 6.00
T e t r a s o d i u m EDTA (40%) 10.00
T r i a d i n e 10 ( P r e s e r v a t i v e ) I .50
Procedure:
Mix t h e i n g r e d i e n t s i n o r d e r a t ambient temperature. M i x we1 1
between each a d d i t i o n a t moderate speed.
Typical Properties:
Appearance: C l e a r amber l i q u i d
S p e c i f i c G r a v i t y : 1 .06
pH C o n c e n t r a t e : 1 0 . 2
p H o f a 1:10 s o l u t i o n : 9 . 8
Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r
Cast I r o n B l o c k : Pass
Corrosion Test: 1:10 D i l u t i o n
F o r m u l a t i o n F-770

A i r c r a f t C l e a n e r Type I V

The f o l l o w i n g f o r m u l a t i o n uses Monamulse 653-838 as an emul-


s i f i e r i n a m i l i t a r y s p e c i f i c a t i o n (MIL-C-855706) f o r m u l a t i o n .

Inaredient: vvts/,
P a r t A:
Monamulse 653-0313 7.0
Monami ne 1-76 2.7
A r o m a t i c 150 7.5
Isopar M (Odorless Mineral S p i r i t s ) 7.5
Diethylene Glycol Butyl Ether 3.5
Decanol 1.6

P a r t B:
T r i s o d i u m Phosphate (Dodecahydrate) 2.7
Water 55.1
P l u r o n i c F98 1.8
Hycar 1422 10.6
Procedure:
Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n .
Add P a r t B t o P a r t A . A g i t a t e u n t i l u n i f o r m .
Typical Properties:
Appearance: C1 e a r L i q u i d
F o r m u l a t i o n F-784

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 111

General Purpose S y n t h e t i c F l u i d ( A )

Ingredients: Wt96
M a s l i p 501 Bas= 5.0
Maphos 8135 8.0
Mazon R I 4 A 8.0
T r i e t h a n o l a m i n e , 85% 12.0
B i o c i de 0.5
Water Balance

Procedure:
4 . Add i n g r e d i e n t s as l i s t e d .
2. T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 4 A .
For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r
extreme p r e s s u r e a d d i t i v e .

General Purpose S y n t h e t i c F l u i d (BZ

Ingredients: Wt%
M a s l i p 500 38.0
Mazon R I 8 B 12.0
P r o p y l ene G1 y c o l 2.5
T o l y t r i a z o l e (Climax) 2.5
T r i e t h a n o l a m i ne, 85% 10.0
8 i o c i de 0.5
Water Balance

Procedure:
1 . Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 B . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f
l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e .

Copper M a c h i n i n a F l u i d
Ingredients: Wt%
Macol 5100 15.0
Mazon R I 6 8.0
Maphos 8135 7.0
P o t a s s i um H y d r o x i d e 6.0
B i o c i de 0.5
Water Balance

Procedure:
Add i n g r e d i e n t s as l i s t e d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


112 Advanced Cleaning Product Formulations

G e n e r a l Purpose S y n t h e t i c F l u i d ( C )

Ingredients: Mle9/0
M a s l i p 501 A 30.0
Mazon R I 8 B 12.0
Maphos 58 6.0
T r i e t h a n o l ami ne, 85% 7.0
B i o c i de 0.5
Water 5al ance

Procedure:
1. Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e
f u r t h e r d i l u t e d f r o m 1:lO ( h e a v y d u t y ) t o 1 : 4 0 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of
l u b r i c a n t o r extreme pressure a d d i t i v e .

G e n e r a l Purpose S y n t h e t i c F l u i d ( D )

I n s r e d ients: Wt%
M a s l i p 501 Base 12.0
Mazon R I 8 A 25.0
Maphos 8135 5.0
T r i e t h a n o l ami n e , 85% 12.0
B i o c i de 0.5
Water 5 a l ance

Procedure:
1 . Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e
f u r t h e r d i l u t e d f r o m 1 : l O (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 A . F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f
l u b r i c a n t o r extreme pressure a d d i t i v e .

SOURCE: PPG I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 113

Metal Cleaner
(Phosphate, Powder)

Soi 1 -Drawing l u b r i c a n t , a n i m a l f a t and g r e a s e


Surface-Steel
A p p l i c a t i o n Method-Spray
M a n u f a c t u r e - D r y b l e n d / A g g l o m e r a t on

Composi t i on :
*STPP 10.0
*Sodi um C a r b o n a t e 25.0
**Alkoxylated l i n e a r alcohol nonion c s u r f a c t a n t
( 1ow foam) 5.0
Metso Beads 2048 30.0
Sodi um H y d r o x i d e Beads 30.0

Use: Heavy d u t y l o w - f o a m i n g m e t a l c l e a n e r w h i c h i s good f o r a


spray c l e a n i n g process.
Use D i l u t i o n : 0.8-1.5% bw ( 1 - 2 o z / g a l l o n )

FMC
** O l i n P o l y t e r g e n t S-305LF o r
Rhone-Poulenc I g e p a l CO-530

A1 umi num C1 e a n e r
(Phosphate, Powder)

Soi 1- L i g h t d r a w i n g o i 1
Surface-Aluminum
A p p l i c a t i o n Method-Spray washer
M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on

Composi t i on : Wt%
Metso Beads 2048 45.0
*STPP 30.0
*Sodi um B i c a r b o n a t e 20.0
**Sodium P o l y a c r y l a t e 3.0
* * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 Moles EO 2.0

Use D i l u t i o n : 1.5-3.036 bw ( 2 - 4 o z / g a l )

* FMC
** Rohm 8, Haas A c u s o l 445ND (92% s o l i d s )
*** Rhone-Poul enc I g e p a l CA-630

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
114 Advanced Cleaning Product Formulations

M e t a l C1 e a n e r
(Phosphate. Powder2

S o i l - O i l , d r a w i n g l u b r i c a n t , a n i m a l f a t and g r e a s e
Surface-Steel
A p p l i c a t i o n Method-Immersion
ManufacturekDry blend/Agglomeration

Composi t i o m
*Sodium C a r b o n a t e 20.0
*STPP 8.0
**Octylphenoxy Polyethoxyethanol ( 6 Moles € 0 ) 2.0
Metso Beads 2048 30.0
Sodi um H y d r o x i d e Beads 40.0

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l l o n )

* FMC
** Rhone-Poulenc I g e p a l CA-630

M e t a l C1 eaner
(Phosphate, Powder)

S o i l - O i l , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e
Surface-Steel
A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g
Manufacture-Dry blend/Agglorneration

Com o s i t i o n : Wt%
TSPF 15.0
TSP 5.0
Metso Beads 2048 35.0
Sodium C a r b o n a t e 28.0
* O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (12-13 Moles EO) 2.0
Sodium H y d r o x i d e Beads 15.0

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l )

* Rhone-Poulenc I g e p a l CA-720

SOURCE: PO C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Metal Cleaners and Polishes 115

Metal Cleaner
I Phosphate, Powder 1

S o i 1 - 0 i 1, f a t , p r o t e i n
Surface-Stai nless s t e e l
A p p l i c a t i o n Method-Cleaning i n p l a c e
Manufacture-Dry blend/Agglomeration

Composi t i o n A :
*STPP 40.0
*Sodium C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 M o l e s EO) 3.0
M e t s o Beads 2048 25.0
Sodi um H y d r o x i d e Beads 20.0

Composition
- 0: WtO/o
*STPP 40.0
*Sodium C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) 3.0
Metso Pentabead 20 45.0

Use D i l u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )

* FMC
** Rhone-Poluenc R h o d a s u r f A-24

M e t a l C1 e a n e r
( Z e r o Phosphate, Powder)

S o i 1-Oi 1 , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e


Surface-Steel
A p p l i c a t i o n Method-Immersion
M a n u f a c t u r e - D r y b l e n d / A g g l o r n e r a t i on

Composi t i o n
: WtO/o
V a l f o r 100 Z e o l i t e A 15.0
Sodium C a r b o n a t e 38.0
* O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (9-10 Moles E O ) 2.0
Metso Pentabead 20 43.0
A c u s o l 445ND Sodi um P o l y a c r y l a t e 2.0

Use L e v e l : 3-6 o z / g a l l o n

g Rhone-Poulenc I g e p a l CA-630

SOURCE: PB C o r p . : Detergent F o r m u l a t i o n Guide


116 Advanced Cleaning Product Formulations

Non-Phosphorous Aluminum C l e a n e r

T h i s i s a t o t a l l y o r g a n i c , p h o s p h a t e - f r e e aluminum c l e a n e r
t h a t p r o v i d e s e x c e l 1e n t c l e a n i ng and b r i g h t e n i ng o f a1 umi num.
The Avanel S - 7 0 p r o v i d e s f o r removal o f o r g a n i c s u r f a c e d e p o s i t s
and, by s u r f a c e t e n s i o n r e d u c t i o n , b e t t e r c o n t a c t between
t h e aluminum s u r f a c e and t h e o r g a n i c a c i d s . I n a d d i t i o n t o
i n d u s t r i a l a p p l i c a t i o n s l i k e c l e a n i n g o v e r - t h e - r o a d aluminum
t r a i l e r s and aluminum p r i o r t o a n o d i z i n g , t h i s c l e a n e r may also
be used i n household a p p l i c a t i o n s such as c l e a n i n g aluminum
f l a s h i n g , windows and door f i x t u r e s . Depending on t h e a p p l i c a -
t i o n , t h i s p r o d u c t may be used i n a D r e s s u r e wash, pump s p r a y o r
d i p tank.

Inqredients: w.e-l
C i t r i c A c i d , 50% 12.0
G l u c o n i c A c i d , 50% 8.0
Avanel S-70 3.0
D e i o n i z e d Water, Dye Balance

Procedure:
Charge t h e w a t e r , c i t r i c a c i d , g l u c o n c a c i d and Avanel S - 7 0
M i x w e l l . Ifdye i s t o be added, p a r t o f t h e w a t e r s h o u l d be he d
o u t ; and t h e dye added t o t h i s w a t e r w i t good a g i t a t i o n . The
d i s s o l v e d dye can t h e n be added t o t h e b a t c h . NOTE: C e r t a i n
dyes may n o t be s t a b l e under t h e s e c o n d i t i o n s . Consequently,
s h e l f s t a b i l i t y t e s t s s h o u l d be p e r f o r m e d .
F o r m u l a t i o n CM-102

A 1 k a l ine A1 u m i num C1 eaner

I n a r e d ie n t s :
Dei o n i zed Water 87.0
Avanel S - 7 0 4.0
T e t r a p o t a s s i u m Pyrophosphate 5.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
Macol 48 3.0

pH ( a s i s ) : 1 1 . 5 - 1 2 . 5
Appearance: C l e a r , w a t e r - w h i t e l i q u i d
S p e c i f i c G r a v i t y : 1.05

Procedure:
Charge t h e w a t e r and d i s s o l v e t h e b u i l d e r s a l t s under a g i t -
a t i o n . When d i s s o l v e d , c h a r g e t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e
m i x i n g f o r a t l e a s t 15 m i n u t e s . NOTE: T h i s a l k a l i n e aluminum
c l e a n e r has shown e x c e l l e n t c l eani ng p r o p e r t i e s w i t h o u t
c h e m i c a l a t t a c k o f t h e m e t a l . T h i s f o r m u l a t i o n may b e c u t -!:I
w i t h water t o prepare a m i l d hard-surface c l e a n e r .
F o r m u l a t i o n CM-1034

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 117

Semi S y n t h e t i c

T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy m a c h i n i n g
and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l .

Ingredients: wt9j0
100 P a l e O i l 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 205 0.8
Monalube 215 0.8
T r i e t h a n o l ami ne (99%) 3.2
Monacor BE 5.0
Water 58.6

Procedure:
Combi ne i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . /50 I n . - L b s .
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
Appearance: C l e a r
pH: 9 . 6
F o r m u l a t i o n F-797

Semi S y n t h e t i c

InQredients: wt9j0
100 P a l e O i 1 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 220 1.6
T r i e t h a n o l a m i n e (99%) 3.2
Monacor BE 5.0
Water 58.6

Procedure:
M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f
c o n c e n t r a t e t o 95% w a t e r f o r m s m i c r o e m u l s i o n . F o r m u l a t i o n c a n
be u s e d f o r g r i n d i n g and l i g h t m a c h i n i n g .

T y p i ca9 P r o p e r t i es :
Appearance : C1 e a r Amber L i q u i d
Performance Data ( 5 % i n Water):
Appearance: C l e a r L i q u i d
pH: 9.5
S u r f a c e T e n s i o n (dynes/cm): 32
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s .
Formul a t ion F-800

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


I18 Advanced Cleaning Product Forniulations

Semi S y n t h e t i c

Inaredients: y&
100 P a l e O i l 10.0
Monalube 225 5.5
TEA 7.5
Monalube 610 25.0
Water 47.5

Typical Properties:
Appearance: C 1 e a r Amber L i q u i d

Performance Data ( 5 % i n w a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 9 . 0
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2750 Lbs. / 5 5 I n . -Lbs .
F o r m a c h i n i n g l i g h t s t a m p i n g and d r a w i n g .
F o r m u l a t i o n F-799

Semi S y n t h e t i c

Inqredients: Wt%
100 P a l e O i l 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 205 1.6
T r i e t h a n o l a m i n e (99%) 3.2
Monacor BE 5.0
Water 58.6

Procedure:
M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 .
5% o f c o n c e n t r a t e added t o w a t e r f o r m s m i c r o e m u l s i o n . S u g g e s t e d
f o r g r i n d i n g and m a c h i n i n g f o r b o t h f e r r o u s and n o n f e r r o u s
metals.

Typical Properties:
Appearance: C l e a r Amber L i q u i d

Performance Data ( 5 % i n Water):


Appearance: C l e a r L i q u i d
pH: 9.5
Surface Tension: 27.0
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 e x ( D i r e c t S c a l e ) : 2500 L b s . /57 I n . -Lbs .
F o r m u l a t i o n F-801

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 119

Silver and M e t a l Polish


I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become permanently
suspended The r e s i n a1 so p r e v e n t s "creami ng" o r phase separ-
~

a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Insredient: Wt%
SF96 S i l i c o n e F l u i d (350) ( 1 ) 1 .oo
Dow C o r n i n p 20 Release C o a t i n g ( 2 ) 2.00
S t o d d a r d S o l v e n t (3) 20.00
P r i f a c 2922 L a u r i c A c i d 2.00
D I Water 43.48
Morphol ine 0.86
Carbopol EZ-2 ( 4 ) 0.35
Ammoni um h y d r o x i d e 0.31
b g o p g l i e K a o l i C l a y (5) 14.00
ysp c a f Proper€+es.
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 1 0 , 0 0 0 cps
P r o d u c t pH: 8.50
Product C l a r i t y : P a s t e

Raw M a t e r i a l S u p p l i e r s :
( 1 ) General E l e c t r i c
( 2 ) Dow C o r n i n g Corp.
( 3 ) Exxon Corp.
( 4 ) BFGoodrich
(5) Kaopolite, Inc.

Procedure:
4 . Add t h e s i l i c o n e f l u i d , r e l e a s e c o a t i n g , s o l v e n t , and l a u r i c
a c i d P o a v e s s e l . Mix u s i n g a h i g h shear m i x e r .
2 . C o n t i n u e t o m i x , and add t h e water (43.48 p a r t s ) and t h e
morphol ine.
3 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r (16.00 p a r t s ) by s i m p l y
"dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s .
Add t h e d i s p e r s i o n t o t h e above m i x t u r e w i t h good a g i t a t i o n .
4 . Add t h e ammonium h y d r o x i d e t o r e a c h t h e t a r g e t pH.
5 . Add t h e c l a y and mix u n t i l u n i f o r m .

T o t a l A c t ives :
Silicone f l u i d : 1 .oo
Stoddard s o l v e n t : 20.00
Re1ease c o a t i ng : 2.00
Abras i vet 14.00

FGoodrich S p e c i a l t y Chemicals: DET-563


120 Advanced Cleaning Product Formulations

Soluble O i 1

Ingredients: WtO/o
100 P a l e O i l 80.0
Monalube 605 20.0
P a r o i l 160 20.0

Procedure:
Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.

Typi c a l P r o p e r t i es :
Appearance: C l e a r Dark Brown

Performance Data (5% i n w a t e r ) :


Appearance: M i 1 ky L i q u i d
pH: 8 . 5
F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 6 0 In.-Lbs.

Above f o r m u l a t i o n f o r heavy d u t y m a c h i n i n g and d r a w i n g f o r


use on s t a i n l e s s s t e e l and f e r r o u s m e t a l s .
F o r m u l a t i o n F-803

Soluble O i 1
Ingredients: Wt%
100 P a l e O i l 85.0
Monalube 605 15.0

Procedure:
Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C .

Typical Properties:
Appearance: C l e a r L i g h t Brown L i q u i d

Performance Data (5% i n w a t e r ) :


Appearance: M i 1 ky Emulsion
pH: 8 . 8
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 1750 L b s . / 4 7 I n . - L b s .

Appl i c a t i o n :
For g r i n d i n g and v e r y l i g h t m a c h i n i n g .
Formul a t ion F-804

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 121

1
S o l u b l e Qi

Inaredients: Wt%
100 P a l e O i l 78.0
Monalube 6 0 5 15.0
Wonalube 2 1 5 5.0
T EA 2.0

Procedure:
M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l -
u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d .

Typical Properties:
Appearance: M i l k y E m u l s i o n

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: M i 1 ky Emu1 s i o n
pH: 8 . 0
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . / 5 5 I n . - L b s .

The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t


machining.
F o r m u l a t i o n F-805

Soluble O i 1

Ingredients: Wt%
100 P a l e O i l 85.0
Monalube 6 0 5 10.0
Monalube 215 5.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i a t i o n w h i l e warming t o 50C.

Typical Properties:
Appearance: C l e a r Amber L i q u d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
..
Aooearance: M i 1 k v E m u l s i o n
pH: 8 . 0
Falex ( D i r e c t S c a l e ) : 1250 Lbs./45 In.-Lbs.

The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t


machining.
F o r m u l a t i o n F-806

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


122 Advanced Cleaning Product Formulations

Soluble O i l Machining F l u i d

Monalube 225 p r o v i d e s l u b r i c i t y , and EP p r o p e r t i e s i n t h i s


m a c h i n i n g f l u i d . T h i s f o r m u l a t i o n was d e s i g n e d f o r m a c h i n i n g
c a r b o n s t e e l , b r a s s , b r o n z e c o p p e r and s t a i n l e s s s t e e l .

Ingredients: Wt%
N a p h t h e n i c O i l (lOOSUS/lOO) 72.0
Monalube 225 5.0
Monalube 605 20.0
T r i e t h a n o l a r n i n e (99%) 3.0

Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t :
D i r e c t Load S c a l e : 2 7 5 0 l b s
Torque: 47 i n c h pounds

Use D i l u t i o n s :
G r i n d i n g : I-2% i n water
L i g h t M a c h i n i n g : 3-5% i n w a t e r
M o d e r a t e M a c h i n i n g : 5-7% i n w a t e r
Heavy M a c h i n i n g : 8-10% i n w a t e r
F o r m u l a F-764

S y n t h e t i c Machininq F l u i d

T h i s f o r m u l a t i o n i s i d e a l f o r machining carbon s t e e l , brass,


b r o n z e , c o p p e r , aluminum and s t a i n l e s s s t e e l .

Ingredients: wto/,
Monalube 225 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0

Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t P r o c e d u r e :
C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n
D i r e c t Load S c a l e 3000 l b s .
T o r q u e 60 i n c h pounds
Formul a t i on F-766

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 123

Svnthetic

Ingredients: Wt%
Monalube 210 16.6
T r i e t h a n o l a m i n e (99%) 33.3
Water 50.0
A n t i foam 0.1

Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

Performance Data (5% i n Water):


Appearance: C l e a r L i q u i d
pH: 8 . 5
S u r f a c e T e n s i o n : 42
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s .

The f o r m u l a t i o n i s d e s i g n e d f o r f e r r o u s and n o n f e r r o u s m e t a l s
primarily f o r grinding.
Formul a t i on F-819

Synthetic

Inqredi ents: K%
Monalube 210 12.5
Monalube 315 12.5
T r i e t h a n o l a m i n e (99%) 25.0
Water 50.0

Procedure.:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 0
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s .

F o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems p r i m a r i l y f o r g r i n d i n g .
F o r m u l a t i o n F-820

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


124 Advanced Cleaning Product Formulations

S y n t h e t i c Drawing/Stampinp F l u i d

T h i s f o r m u l a t i o n i s i d e a l f o r stamping hot o r c o l d r o l l e d s t e e l .

Ingredients:
Monalube 225 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Monalube 315 20.0
Water 35.0

Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .

F a l e x EP T e s t P r o c e d u r e :
C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n
D i r e c t Load S c a l e 3 0 0 0 l b s .
T o r q u e 55 i n c h pounds
F o r m u l a t i o n F-765

O i 1 Based Drawi ng/Stampi ng F1ui d

Monalube 225 p r o v i d e s l u b r i c i t y , EP and c o n t r i b u t e s t o t h e


c o r r o s i o n p r o t e c t i o n p r o p e r t i e s i n t h i s heavy-duty stamping/
d r a w i n g f 1u i d .

Ingredients: Wt%
Paraffinic O i l (300SUS/lOO) 90.0
Monalube 225 10.0

Procedure:
B l e n d Monalube 225 i n t o t h e o i l

F a l e x EP T e s t :
D i r e c t Load S c a l e : 3000 l b s
T o r q u e 57 i n c h pounds
F o r m u l a t i o n F-763

S p r a y M e t a l C1 e a n i n g C o n c e n t r a t e

Ingredients:
Water 75.00
Sodi um M e t a s i 1 i c a t e 3.00
Sodium C a r b o n a t e 4.00
Sodi um H y d r o x i d e 5.00
M o n a t r o p e 1250 11.00
Alkyl Polyal kylene Ether 2.00

Procedure:
Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each
ingredient i s dissolved before next addition.
F o r m u l a t i o n F-751

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 125

S y n t h e t i c Formula

Inqredients: Wyt
Monalube 205 5.0
Monalube 210 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C1 e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8.7
S u r f a c e T e n s i o n : 27
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 7 I n . - L b s .

T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d
s t a m p i ng.
F o r m u l a t i o n F-813

S y n t h e t i c Formula

Inqredients: wt%
Monalube 205 5.0
Monalube 210 10.0
Monalube 315 10.0
T r i e t h a n o l ami ne (99%) 30.0
Water 45.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C1 e a r Amber L i q u i d

Performance Data ( 5 % i n Water):


Appearance: C1 e a r L i q u i d
pH: 8 . 0
S u r f a c e T e n s i o n : 32
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s .

T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d
s t a m p i ng.
F o r m u l a t i o n F-814

SOURCE: Mona I n d u s t r i e s , Inc,: Suggested F o r m u l a t i o n s


126 Advanced Cleaning Product Formulations

S y n t h e t i c Formula

Inqredients: w%%
Monalube 2 0 5 4.5
Monalube 2 2 0 9.0
T r i e t h a n o l a m i n e (99%) 27.0
Monalube 315 20.0
Water 39.5

Procedure:
M i x i t e m s 1, 2 , 3, and 4 . Add w a t e r and mix u n t i l homogeneous.

Typical Properties:
Appearance: C l e a r Amber L i q u i d

Performance Data (5% i n W a t e r ) :


Appearance: T r a n s l u c e n t S o l u t i o n
pH: 9 . 0
Surface Tension: 32
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
Falex ( D i r e c t S c a l e ) : 2500 Lbs./47 I n . - L b s .
F o r m u l a t i o n F-815

S y n t h e t i c Formula

C l e a r product designed f o r f e r r o u s g r i n d i n g .

Ingredients:
Monalube 210 15.0
Mona1ube 1 1 0 40.0
Water 45.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C1 e a r Sol u t i on

Performance Data (5% i n W a t e r ) :


Appearance: C1 e a r L i q u i d
pH: 7 . 5
F a l e x ( D i r e c t S c a l e ) : 2 5 0 0 Lbs./45 In.-Lbs.

N o t e : No TEA needed. Excess DEA i n Monalube 110 n e u t r a l i z e s PE.


F o r m u l a t i o n F-816

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 127

S y n t h e t i c Formula

P r o d u c t d e s i gned f o r g r i n d i ng and 1 ig h t m a c h i n i n g

Ingredients: Wt%
Monalube 2 1 0 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Monalube 315 10.0
Water 45.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties :
Appearance: C l e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 8 . 0
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 5 I n . - L b s .
F o r m u l a t i o n F-817

S y n t h e t i c Formula

Inaredients: Wt%
Monalube 215 16.6
T r i e t h a n o l ami ne (99%) 33.3
A n t i foam 0.1
Water 50.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 5
S u r f a c e T e n s i o n : 42
F a l e x ( D i r e c t S c a l e ) : 2500 bs./44 In.-Lbs.

P r o d u c t d e s i g n e d f o r machi n ng f e r r o u s and n o n f e r r o u s m e t a l .
A l s o some v e r y l i g h t s t a m p i n g .
F o r m u l a t i o n F-818

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


128 Advanced Cleaning Product Formulations

S y n t h e t i c Formula

Ingredients: Q
Monalube 210 16.6
Monoethanol ami ne 33.3
Water 50.4

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

Performance Data (5% i n W a t e r ) :


Appearance: C l e a r L i q u i d
pH: 1 1
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1ex ( D i r e c t Scal e ) : 2250 Lbs. /58 I n . - L b s .

Formulated f o r g r i n d i n g a p p l i c a t i o n s . Ferrous metals o n l y .


F o r m u l a t i o n F-821

S y n t h e t i c Formula

Ingredients:
Monalube 205 16.6
T r i e t h a n o l a m i n e (99%) 33.3
A n t i foam 0.1
Water 50.0

Procedure:
Combi ne in g r e d i e n t s w i t h a g i t a t i o n .

T y p i c a l P r o p e r t i es :
Appearance: C l e a r Amber L i q u i d

Performance Data (5% i n W a t e r ) :


Appearance: C1 e a r L i q u i d
pH: 8 . 3
S u r f a c e T e n s i o n (dynes/cm): 24
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
.
Fa1ex ( D i r e c t S c a l e ) : 2500 Lbs / 5 5 In. -Lbs .
T h i s i s t h e most u n i v e r s a l f o r m u l a s i n c e i t can be used on all
m e t a l l u r g y a t 1% t o 2%. I t a l s o can be used f o r g r i n d i n g a t 5% t o
8% f o r m a c h i n i n g and a t 8% t o 15% f o r r e a l heavy m a c h i n i n g .
F o r m u l a t i o n F-822

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 129

S v n t h e t i c Formul a

Inaredi ents: Wt%


Monalube 205 10.0
Monalube 1 1 0 30.0
Water 60.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r S o l u t i o n

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
ptl: 8 . 0
S u r f a c e T e n s i o n : 28
C a s t I r o n B l o c k C o r r o s i o n e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2250 Lbs./5O I n . - L b s .

F o r use i n m a c h i n i n g and 1 g h t s t a m p i n g f o r f e r r o u s and


nonferrous metals.
NOTE: Excess DEA i n Monalube 10 i s enough t o n e u t r a l i z e t h e
phosphate e s t e r .
F o r m u l a t i o n F-823

*thetic Formula

Ingredients:
Monalube 2 0 5 25.0
Monoethanol ami ne 25.0
Water 50.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 10
C a s t I r o n B l o c k : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /50 I n . -Lbs.

F o r f e r r o u s systems f o r m a c h i n i n g and g r i n d i n g .
Formul a t ion F-824

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


130 Advanced Cleaning Product Formulations

Synthetic Formulation

Inqredients:
Monalube 210 10.0
Monalube 225 10.0
TEA 40 0~

Water 40.0

Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .

T y p i c a l P r o p e r t i es :
Appearance: C l e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 8 . 5
S u r f a c e T e n s i o n ( d y n e s / c m ) : 42
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 6 I n - L b s .

For machining, forming, and s t a m p i n g a l l m e t a l s


Forrnul a t i on F-807

S y n t h e t i c Formulat

Inqredients:
Monalube 225 15.0
Monalube 3 1 0 25.0
T r i e t h a n o l ami ne (99%) 30.0
Water 30.0

Procedure:
M i x Monalube 225 w i t h t r i e t h a n o l a m i n e and add Monalube 315.
M i x u n t i l c l e a r , t h e n add w a t e r .

T y p i c a l P r o p e r t i es :
Appearance: C l e a r C o n c e n t r a t e

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 6
S u r f a c e T e n s i o n : 41
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n . -Lbs

F o r heavy d u t y s t a m p i n g o f f e r r o u s m e t a l s a t 1 0 t o 20% i n w a t e r .
F o r m u l a t i o n F-808

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 131

Svnthetic Formulation

I n g r e d i en t s :
Monalube 2 0 5 5.0
Monalube 210 10.0
Monalube 220 10.0
T r i e t h a n o l a m i n e (99%) 50.0
Water 25.0

Procedure:
M i x i t e m s 1, 2, 3 , and 4 . Then add w a t e r .

Typical Properties:
Appearance: C l e a r L i q u i d

Performance Data (5% i n W a t e r ) :


Appearance: C l e a r L i q u i d
pH: 9 . 0
S u r f a c e T e n s i o n : 32
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s

F o r s t a m p i n g , d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r .
Formul a t ion F-809

Synthetic Formulation

Inqredients: wtsl,
Monalube 205 5.0
Monalube 225 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0

Procedure:
Mix items 1, 2, 3, and 4 , t h e n add w a t e r and m i x .

Typical Properties:
Appearance: C1 e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 7
Surface Tension: 35
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s .

Application:
F o r f e r r o u s and n o n f e r r o u s systems f o r mach n i ng, forming,
and s t a m p i n g .
F o r m u l a t i o n F-810

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested Formu a t i ons


132 Advanced Cleaning Product Formulations

Synthetic Formulation

Inqredients: Wt%
Monalube 215 9.0
Monalube 220 9.0
T r i e t h a n o l a m i n e (99%) 36.0
Water 46.0

Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .

Typical Properties:
Appearance: C l e a r Amber L i q u i d

Performance Data (5% i n Water):


Appearance: C l e a r L i q u i d
pH: 9 . 0
S u r f a c e T e n s i o n : 42
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. / 4 7 I n . -Lbs

Use i n m a c h i n i n g and s t a m p i n g f o r b o t h f e r r o u s and n o n f e r r o u s


metallurgy.
F o r m u l a t i o n F-811

Synthetic Formulation

Inqredients:
Monalube 205 5.0
Monalube 220 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0

Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .

T y p i c a l P r o p e r t i es :
Appearance: C1 e a r Amber L i q u i d

P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 0.7
S u r f a c e T e n s i o n : 35
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 3 5 I n . - L b s .

For machining, forming, and s t a m p i n g f o r a1 1 m e t a l 1u r g y


F o r m u l a t i o n F-812

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Metal Cleaners and Polishes 133

U n i v e r s a 1 S c o u r i na P a s t e

Inqredients: WtO/o
A : T y l o s e CBR 10000 5.00

5: Water (50C) 51 . 8 0

C: H o s t a p u r SAS 60 21.80
Genapol ZRO 1 iq u i d 10.70
Genapol U D - 0 3 0 2.00
K o m p e r l a n KD 0.70
NaCl 0.00

0: Preservative, Perfume q.s.

M a n u f a c k u r i ng:
I. A, w h i c h i s added b y c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l ,
u n t i l a homogeneous g e l f r e e o f lumps h a s been o b t a i n e d
I I . Add one a f t e r a n o t h e r , t h e components o f C t o I .
1 1 1 . F i n a l l y D i s added.

Tests :
V i s c o s i t y ( B r o o k i e l d RVT, sp. 6, 1 0 m i n -1, 25C): 49b00 mPas

SOURCE: Hoeckst A k t e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

A1 u m i n u m C 1 e a n e r

Comoosi t i o n : Wt%
K e l z a n x a n t h a n gum 1 .o
Butyl Cellosolve 4.0
T e r g i t o l NP 3.0
Phosphoric A c i d (85%) 3.0
Citric Acid 4.0
S o d i um D i c h r o m a t e trace
Water 85.0

Procedure:
D i s s o l v e K e l z a n x a n t h a n gum i n w a t e r . Add t h e c i t r i c and
p h o s p h o r i c a c i d s f o l l o w e d b y 5 u t y l C e l l o s o l v e a n d T e r g i t o l NP.
To u s e , s p r e a d e v e n l y on t h e s u r f a c e t o b e c l e a n e d and a l l o w
s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accomplished.

SOURCE: Monsanto P e r f o r m a n c e M a t e r i a l s : K e l z a n Suggested


Formulation
134 Advanced Cleaning Product Formulations

Water Sol u b l e Stampi ng F1u i d

Ingredients: \nit%
M a s l i p 501 Base 30.0
Mazon R I 8 B 12.0
D i e t h a n o l ami ne 8.8
P r o p y l ene G1 y c o l 1.2
T r i e t h a n o l a m i n e , 85% 10.0
Water Balance
Procedure:
Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s r e q u i r e d , add
Macol 5 1 0 0 . I f more c o r r o s i o n i n h i b i t o r i s r e q u i r e d , add more
Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy d u t y a p p l i c a t i o n .

WD-40 Type L u b r i c a n t C o n c e n t r a t e

Inq r e d ien t s : W
S-Maz 8 0 3.7
Mazawet 7 7 1.Q
H i t e c E-515 ( E t h y l ) 5.2
Palmetic Acid 0.7
S h e l l f l e x 213 10.5
S h e l l Sol 135 70.9
Procedure: Add i n g r e d i e n t s as l i s t e d .

Penetrating O i l

I n a r e d ie n t s : Wt%
S-Maz 80 2- 6
Mazon R I 6 7-1 2
M a s i l SF-10 0- 1
Nekal WT-27 0- 1
Gafac RE-40 0- 1
I n d o p o l H-100 0- 6
Odor1 ess M i n e r a S p i r i t s 11ance
Procedure:
Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e m i n e r a l
s p i r i t s may be d e l e t e d and s u b s t i t u t e d w i t h a n a p h t h e n i c o i l
( 5 - 1 5%).

B u r n i s h i n s Compound

Ingredients: Wt%
Mazamide 65 10.0
Mafo 1 3 MOD 1 7.0
Mazon R I 4 A 5.0
T r i s o d i um Phosphate 7.0
EDTA 1 .o
Water 70.0
Procedure: Add i n g r e d i e n t s as l i s t e d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


10. Oven, Grill and
Hot Plate Cleaners
136 Advanced Cleaning Product Formulations

C a u s t i c Oven C l e a n e r

Inaredients: Wt%*
A : Van Gel C, 4 . 8 % Aqueous D i s p e r s i o n 62.50
Dei o n i zed Water 45.75

B: Sodium H y d r o x i d e , 50% S o l u t i o n 5.00

C: Butyl Carbitol '10.00


Aminomethyl P r o p a n o l (AMP-95) 1.50
Sodium Cocoamphoacetate ( M o n a t e r i c CM-36s) 0.25

D . Sodium H y d r o x i d e , 50% S o l u t i o n 5.00

Procedure:
1 . Make t h e 4.8% Van Gel C d i s p e r s i o n b y s l o w l y a d d i n g 4 . 8 p a r t s
b y w e i g h t o f Van Gel C i n t o 9 5 . 2 p a r t s b y w e i g h t o f w a t e r o f
a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000
rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . Add t h e r e m a i n i n g P a r t A
w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m i x u n t i l
uniform.
2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d
t o a c h i e v e good m i x i n g o f e n t i r e b a t c h .
3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each
u n t i l u n i f o r m . A v o i d e n t r a p m e n t o f a i r and g e n e r a t i o n o f foam.
4. S l o w l y add P a r t D and m i x u n t i l u n i f o r m .
F o r m u l a t i o n N o . 461

N o n - C a u s t i c Oven C l e a n e r

Inqredi ents: Wt%*


A : Water 55.00
Van Gel C, Magnesium Aluminum S i l i c a t e 0.75
Rhodopol 50MD, Xanthan Gum 0.25

6 : D i e t h a n o l ami n e 5.00
Triethanolamine 5.00
T r i p r o p y l e n e g l y c o l M e t h y l E t h e r (Dowanol TPM) 5.00
P o t a s s i u m C a r b o n a t e , 25% Aqueous S o l u t i o n 28.00
Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e 1.oo

Procedure:
1 . D r y b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e
t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t
5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s .
2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x
each f o r 5 m i n u t e s . Package.
F o r m u l a t i o n No. 468
*As r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s


Oven, Grill and Hot Plate Cleaners 137

H i g h C a u s t i c Oven C l e a n e r

Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c f o r m -
u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l
c l i n g t o i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e
s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

Inaredient: Wei Qht P e r c e n t


D I Water 71.03 69.78
Carbopol 674 ( 1 ) 0.75 2.00
Potassium h y d r o x i d e (45%) 22.22 22.22
Propylene g l y c o l methyl e t h e r ( 2 ) 3.00 3.00
C8-16 a l k y l p o l y g l y c o s i d e (50%) ( 3 ) 3.00 3.00

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 250 5,000


CPS CPS
Product pH: 13-14 13-14
Product c l a r i t y : Clear Clear

(1) 8FGoodrich
( 2 ) Dow Chemical : Dowanol PM
( 3 ) Henkel C o r p . : Glucopon 425CS

Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e DI w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e p o t a s s i u m h y d r o x i d e w i t h c o n t i n u o u s m i x i n g .
3 . Add t h e g l y c o l e t h e r .
4 . Add t h e APG s u r f a c t a n t . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .

Total Actives:
Potassium h y d r o x i d e : 10.00
P r o p y l e n e g l y c o l m e t h y l e t h e r : 3.00
C8-16 a l k y l p o l y g l y c o s i d e : 1.50

FGoodrich S p e c i a l t y Chemicals: OET-360


138 Advanced Cleaning Product Formulations

Oven C l e a n e r

Ingredients: VVt%*
A : Veegum T, Magnesium Aluminum S i l i c a t e 0.40
Rhodopol 23, Xanthan Gum 1.20
D e i o n i z e d Water 80.40

B: Sodium H y d r o x i d e , 50% 8.00


Deceth-4 Phosphate (Rhodafac RA-600) 10.00

Procedure:
1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m i x w i t h an homogenizer
a t 5000 rpm.
2 . D r y b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o
t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
p r o d u c e a s m a l l v o r t e x . Cool t o 55C.
4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
m i n u t e s a f t e r each a d d i t i o n .
NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e
s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e
batch.
F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s

A e r o s o l Oven C1 e a n e r

Ingredients: .
W t %*
A : Veegum T, Magnesium Aluminum S i l i c a t e 1 .50
Dei o n i zed Water 74.25

8 : n-Methyl P y r r o l i d o n e (M-Pyrol) 20.00


D i s o d i u m C o c o a m p h o d i p r o p i o n a t e ( M i r a n o l C2M-SF C o n c . ) 3.25
Nonoxynol ( I g e p a l CO-630) 1 .oo

Procedure:
1 . Weigh w a t e r and p l a c e on h o m o g e n i z e r .
2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t
5000 r p m . C o n t i n u e m i x i n g for 20 m i n u t e s , w h i l e h e a t i n g t o
70C.
3 . Combine t h e i n g r e d i e n t s o f P a r t 8 , h e a t t o 70C.
4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed
t o provide a s l i g h t vortex.
5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C.
6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t .
Formulation from I n t e r n a t i o n a l S p e c i a l t y Products.
*As r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co., Inc.: Suggested F o r m u l a t i o n s


Oven, Grill and Hot Plate Cleaners 139

Oven C l e a n e r

Composition:
K e l z a n x a n t h a n gum 0.1
T r i s o d i um Phosphate 3.2
Sodi urn m e t a s i 1 ic a t e 1.l
S u l f o n a t e OA5 2.1
B r i j 96 3.2
S i 1 icone 2 0 0 F l u i d 3 5 0 c s 4.0
Hexane 4.2
Water 82.1

Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum as b e f o r e and
add n e x t t h r e e i n g r e d i e n t s . M i x t h e B r i j 96, S i l i c o n e and hexane
s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m i x
w i t h c o n s t a n t a g i t a t i o n . F o r a e r o s o l u s e c h a r g e w i t h 90% conc-
e n t r a t e and 10% G e n e t r o n 1 2 .

Heavy D u t y Oven C l e a n e r

Compos i t i on : Wt%
Kelzan xanthan gum 0.3
A n t a r o n FC-34 2.0
Sodi um h y d r o x i d e 10.0
Water 87.0

Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum t h e n add A n t a r o n .
S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y
add t o m i x . F o r a e r o s o l use c h a r g e w i t h 80% m i x t u r e and 20% o f
1 : l m i x o f G e n e t r o n 1 2 and 1 1 4 .

SOURCE: Monsanto P e r f o r m a n c e M a t e r i a l s : T e c h n i c a l B u l l e t i n 1 - 2 0 :
K e l zan Formul a t i ons
140 Advanced Cleaning Product Formulatioris

Oven C 1 e a n e r w / A m p h o t e r i c

Ingredients: \Mt96
Water, D . I . 71 . 6
Sodi urn C i t r a t e 2.1
Sodi um M e t a s i 1 ic a t e 4.2
Sodium H y d r o x i d e , 40% 6.5
Monoethanol ami ne 4.2
Dowanol PM 3.1
R e w o t e r i c AM HC 3.1
W i t c o 1298SA 3.1
DeSonic 9 N 2.1

Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i on.

Typical Properties:
V i s c o s i t y , c p s : 96
pH: 1 3 . 9
F o r m u l a 1114

Oven
- C l e a n e r w/Phosphate

Ingredient s :
Phase I :
Water, D . I . 71 . 4
C a r b o p o l 940 1.3
Phase 11:
Water, D . I . 15.4
P o t a s s i u m H y d r o x i d e , 87% 2.4
Tetrapotassium Pyrophosphate 3.6
Phase 111:
R e w o t e r i c AM HC 5.9

Blending Procedure:
Combine Phase I i n g r e d i e n t s and m i x u n t i l homogeneous.
Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r -
o u g h l y . W h i l e m i x i n g , p o u r Phase I1 i n t o Phase I . M i x t h o r o u g h l y
t h e n add Phase 1 1 .
Formula 1115

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
dishes, Coatings and Finishes

141
142 Advanced Cleaning Product Formulations

F u r n i t u r e P o l i sh

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creaming" o r phase separ-
a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Inqredient: wp9b
P a r t A:
D I Water 91.10
Carbopol EZ-2 (1) 0.20
TEA 0.20

P a r t B:
C a r d i s 36 Wax ( 2 ) 0.25
Hoechst Wax S ( 3 ) 0.25
Oleic Acid 0.08
Morphol i ne 0.10
D I Water 1.82

Part C:
SM2133 S i l i c o n e Emulsion ( 4 ) 4.00
SM2135 S i l i c o n e Emulsion ( 4 ) 2.00

Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 9,500 cps
Product pH: 7.00
Product C l a r i t y : P o l i s h

Raw M a t e r i a l S u p p l i e r s :
( 1 ) BF G o o d r i c h
( 2 ) P e t r o l i t e S p e c i a l t y Polymers
( 3 ) Hoechst Celanese
( 4 ) General E l e c t r i c

Procedure:
1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r b y s i m p l y "dumping" i t
i n . The p o l y m e r w i l l wet o u t i n a few m i n u t e s .
2. Add t h e TEA. M i x u n t i l homogeneous.
3. P r e p a r e P a r t B. Add t h e C a r d i s Wax, Hoechst Wax S, and o l e i c
a c i d t o a vessel. With m i l d s t i r r i n g , b r i n g t h e temperature
up t o 96-IOOC. When m e l t e d , add t h e m o r p h o l i n e u n t i l t h e
m i x t u r e i s homogeneous. Add t h e w a t e r a t 95C. C o n t i n u e
s t i r r i n g u n t i l t h e t e m p e r a t u r e reaches 45C. Cool t o room
temperature.
4. Add P a r t B.
5. Add i n t h e s i l i c o n e e m u l s i o n s w i t h m i l d m i x i n g .

Total Actives:
T o t a l Wax : 0.50
T o t a l S i l i c o n e : 6.00

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-530


Polishes, Coatings and Finishes 143

Leather/Plastic Polish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r -
a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

I n q r e d ie n t : Wt%
DI Water 50.00
Renex 20 ( 1 ) 2.00
Morphol ine 1.oo
SF96 S i l i c o n e F l u i d ( 3 5 0 ) (2) 5.00
Oleic Acid 2.00
Mineral S p i r i t s 20.00
01 Water 19.60
Carbopol EZ-2 ( 3 ) 0.40

Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 c p s
P r o d u c t pH: 8 . 5
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
(1) I C I Surfactants
( 2 ) General E l e c t r i c
( 3 ) BFGoodrich

Procedure:
1 . D i s s o l v e t h e Renex 2 0 and m o r p h o l i n e i n t h e w a t e r w i t h m i l d
agitation.
2 . D i s s o l v e t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e m i n e r a l
s p i r i t s . Add t o t h e above m i x t u r e w i t h good a g i t a t i o n .
3 . I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 4 0 p a r t s o f Carbopol i n t o
49.60 p a r t s o f w a t e r b y s i m p l y "dumping" t h e p o l y m e r i n t o
t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y
wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e .
4 . M i x u n t i l homogeneous.

Total A c t i wes:
Silicone Fluid: 5.00
Mineral S p i r i t s : 20.00

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-540


144 Advanced Cleaning Product Formulations

M a r b l e P o l ish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Ingredient: we%
D I Water 74.80
Carbopol EZ-2 ( 1 ) 0.20
Mineral S p i r i t s 15.00
I g e p a l 630 ( 2 ) 3.70
Diatomaceous e a r t h ( 3 ) 8.00
T r i e t h a n o l ami ne 0.30
Physical Properties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 1 I , 700 cp
P r o d u c t pH: 7 . 5 0
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Rhone-Poul enc
(3) Kaopolite
Procedure:
1 . D i s p e r s e t h e Carbopol i n t h e w a t e r b y s i m p l y "dumping" i t
i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e s u r f -
a c t a n t w h i l e m i x i n g under moderate a g i t a t i o n .
2 . Add t h e m i n e r a l s p i r i t s . M i x u n t i l t h e e m u l s i o n becomes
homogeneous.
3 . Add t h e TEA. M i x u n t i l smooth.
4 . Add t h e diatomaceous e a r t h . Mix u n t i l homogeneous.
DET-552

Rust Removing P o l i s h

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t o t h i c k e n t h e g l u c -
o n i c a c i d t o e n a b l e improved a p p l i c a t i o n e f f i c a c y . The p o l y m e r
w i l l a l s o i m p a r t v e r t i c a l c l i n g t o e n a b l e a p p l i c a t i o n s on v e r t -
i c a l o r angled surfaces.
I n q r e d ie n t : Wt%
D I Water 44.64
Carbopol €2-2 ( 1 ) 1-79
Sodium h y d r o x i d e (50%) 35.71
G l u c o n i c a c i d s o l u t i o n (50%) ( 2 ) 17.86
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 c p
P r o d u c t p H : 13.90
Product C l a r i t y : T r a n s l u c e n t
Procedure:
1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r .
2. A d d t h e sodium h y d r o x i d e w i t h a g i t a t i o n . T h i c k e n i n g will o c c u r
immedi a t e l y .
3 . Add t h e g l u c o n i c a c i d s o l u t i o n . M i x u n t i l homogeneous.
DET-560

SOURCE: BFGoodrich S p e c i a l t y Chemicals: Suggested Formulations


Polishes, Coatings and Finishes 145

S c r a t c h e d Wood P o l i s h

Ingredients: Wt%
A: Veegum T, Magnesium Aluminum S i l i c a t e 1.50
Dei o n i zed Water 31.25

B: S t e a r i c A c i d 4.50
Carnauba Wax 16.50
Beeswax, Ye1 1ow 16.50

C: T r i e t h a n o l ami ne, 99% 2.75


M i n e r a l Spi r it s 27.00

D: P r e s e r v a t i v e , Dye, Fragrance q.s

Procedure:
1 . Weigh t h e w a t e r and m i x w i t h a p r o p e l l e r m i x e r a t 1800 rpm.
2 . S l o w l y add t h e Veegum T and m i x f o r 20 m i n u t e s w h i l e
h e a t i n g t o 9OC.
3 . Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC.
4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e
o r d e r shown, m i x i n g each f o r 10 m i n u t e s .
5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s .
6 . Cool t h e b a t c h t o 35C, add P a r t D, and m i x u n t i l u n i f o r m .
*As r e c e i v e d b a s i s

SOURCE: R.T. V a n d e r b i l t Co., Inc.: F o r m u l a t i o n No. 2 1 0

H i qh Gloss, D e t e r q e n t R e s i s t a n t P o l ish
A wax-free p o l i s h , which provides a high-gloss, detergent
r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S i m p l e a p p l i c a t i o n ,
w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f
g l o s s and d e t e r g e n t r e s i s t a n c e f o r e x t e n d e d p r o t e c t i o n .

Ingredients: Wt%
( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e 9.0
( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e 1.5
( 3 ) Stoddard Solvent 3.5
( 4 ) Mineral S p i r i t s (Odorless) 3.5
( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n 9.0
( 6 ) K a o p o l i t e SF 3.4
( 7 ) S o f t Water 70.0
( 8 ) Bactericide 0.1

Combine i n o r d e r shown w i t h h i g h s h e a r m i x i n g u n t i l t h i c k e n i n g
o c c u r s . M i x u n t i l homogeneous and package.

Formulation Properties:
C o n t a i n s no wax Non-smeari ng
High g l o s s Cost e f f i c i e n t
Detergent r e s i s t a n t Cold b l e n d (Only m i x i n g r e q u i r e d )
E a s i 1 y a p p l ied Resistant t o wash-off
SQURCE: Genesee P o l y m e r s C o r p . : Formula 20-12
12. Rinse Aids

146
Rinse Aids 147

R i nse A i d , Acid

Inqredients: Wt9/o
Water, D . I . 50.0
P e t r o 22 Powder 5.0
DeSoni c LFD-97 35.0
Hydroxyacetic Acid, 70% 10.0

Blending Procedure:
51 end i n g r e d i e n t s in t h e o r d e r 1 is t e d .

Typical Properties:
S p e c i f i c G r a v i t y : 1.105
Wt/Gal, l b s : 9 . 2 1
V i s c o s i t y , c p s : 85
C l o u d P o i n t , C : 59
S o l i d s , %: 4 0
Formula 131

R i nse A i d

Ingredients: Wt%
Water, D . I . 60.0
P e t r o 22 Powder 5.0
DeSoni c LFD-97 35.0

Typical Properties:
S p e c i f i c G r a v i t y : 1.029
Wt/Gal. l b s : 8 . 5 8
pH, as i s : 6 . 4
V i s c o s i t y , c p s : 80
C l o u d P o i n t , C : 68
S o l i d s : 40%
Formula 130

SOURCE; W i t c o C o r p . : Suggested Formul a t ions


13. Rug, Floor, Carpet,
Upholstery Shampoos an

148
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 149

C a r p e t C1 e a n e r

I n qr e d i e n t s : wt%
Water 56.0
T r i s o d i urn Phosphate 15.0
Tetrapotassium Pyrophosphate 10.0
P l u r a f a c D-25 7.0
A1 ip a l CO-436 10.0
Mazawet 7 7 1.25
EDTA ( T e t r a s o d i u m S a l t ) 0.5
T i n o p a l 5 BM 0.25

Procedure:
Add i n g r e d i e n t s as l i s t e d .

Low Foam C a r p e t Shampoo

Ingredients: Wt%
Macol 2LF 6.0
Ethylene Glycol Methyl Ether 10.0
Sodi urn T r i p o l y p h o s p h a t e 1. o
Sodi urn X y l ene S u l f o n a t e 1 .o
Mazu DF 210 SX 0.5
Water ( s o f t ) 81 . 5

Procedure:
Add i n g r e d i e n t s as l i s t e d .

Steam Rua C l e a n e r - A

Ingredients: w
a
Macol OP 1 0 SP 5.0
Sodium S i l i c a t e 10.0
Sodi urn X y l ene S u l f o n a t e 5.0
Water 80.0

Procedure:
Add i n g r e d i e n t s as l i s t e d .

S t e a m Rug C l e a n e r - 8

Inqredients: Wt%
Macol OP 1 0 SP 3.0
Sodi um S i 1 ic a t e 10.0
Sodium X y l e n e S u l f o n a t e 3.0
Water 84.0

Procedure:
Add i n g r e d i e n t s as l i s t e d

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


150 Advanced Cleaning Product Formulations

Carpet Cleaners f o r t h e Spray-Extraction Process

Inqredients: W S
C u b l e n 0 50 1.o
Tetrapotassium pyrophosphate 5.0
P r o p e t a l 241 2.0
P r o p e t a l 281 3.0
S u l f e t a l 4105 4.0
Isopropanol 4.0
Water 81 . o
F o r m u l a CT 02-08-01

Ingredients: Wt%
Water 75.0
Soap 1 .o
S u l f e t a l 4105 5.0
P r o p e t a l 99 5.0
Cont raspum 3 0 0 1. o
U b a t o l TR 1138 3.0
Isopropanol 10.0
F o r m u l a C T 02-08-02

SOURCE: Zschimmer & Schwarz GmbH & C o . : G e n e r a l F o r m u l a t i o n s

C a r p e t Shampoo
Liquid, transparent

Ingredients: wtu/,
A : Hostapur 0s l i q u i d 25.00
M e d i a l a n KA c o n c . 3.00

B: W a t e r , Preservative 72.00

Manu f a c t u r i ng :
One a f t e r a n o t h e r , t h e components o f A a r e added t o 8 .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n


Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 151

C a r p e t Shampoo
I Phosphate, L i quid)

S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , clay


and p a r t i c u l a t e
S u r f a c e - P o l y e s t e r and n y l o n
A p p l i c a t i o n Method-Rug s c r u b b e r
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composi t i on : Wt%
Water 62.5
*TSP 2.0
*STPP 5.0
K a s i 1 # 6 P o t a s s i um S i 1 ic a t e 20.0
**Phosphate E s t e r 3.0
***Sodi um A1 k y l naphtha1 ene S u l f o n a t e 3.5
****Octylphenoxy P o l y e t h o x y e t h a n o l , 7 - 8 M o l e s EO 4.0

Use D i l u t i o n : 0 . 8 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )

* FMC
** Rhone-Poulenc Rhodafac RE-610
*** DeSoto
**** Rhone-Poulenc I g e p a l CA-620

RUQ Steam C l e a n e r

S o i 1 -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , clay


and p a r t i c u l a t e
S u r f a c e - P o l y e s t e r and n y l o n
A p p l i c a t i o n Method-Rug s c r u b b e r
Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r

Composi t i on :
Water 84.0
Wetso Beads 2048 5.0
Sodi um X y l ene S u l f o n a t e , 40% 6.0
* M i r a n o l JEM C o n c e n t r a t e (34%) 5.0

Use D i l u t i o n : 4 . 7 - 9 . 4 % b w ( 6 - 1 2 o z / g a l l o n )

*Rhone-Poul enc; o r She1 1 Chemical Neodol 25-1 2

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide


152 Advanced Cleaning Product Formulations

C a r p e t Shampoo, H i s h Foam

In Q r e d ie n t s : WtS/o
Water 78.3
P e t r o BAF L i q u i d 5.0
W i t c o l a t e WAC-LA 16.7

B1 e n d i n g P r o c e d u r e : B1 end in g r e d i e n t s i n t h e o r d e r 1 is t e d .

P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s
t h e low temperature cloud p o i n t , g i v i n g e x c e l l e n t freeze/thaw
p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n
sodium l a u r y l s u l f a t e a l o n e .
F o r m u l a 908

C a r p e t Shampoo, H i g h Foam

Inqredients: Wt%
Water 71.1
P e t r o BAF L i q u i d 6.7
W i t c o l a t e WAC-LA 22.2

B l e n d i n g P r o c e d u r e : B 2nd i n g r e d i e n t s i n t h e o r d e r is I

Use L e v e l : 1 t o 2 ounces p e r g a l l o n .

Comments :
P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s
t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w
p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n
sodium l a u r y l s u l f a t e a l o n e .
F o r m u l a 910

C a r p e t S p o t Remover

Inqredients: Wt%
Water, 13.1. 90.3
W i t c o l a t e WAC-LA 3.3
P e t r o BA L i q u i d 0.5
G l y c o l E t h e r DPM 3.5
G l y c o l E t h e r PM 2.3
FC-129 ( 1 % S o l i d s ) 0.1

Blending Procedure: Blend ingredients i n t h e order l i s t e d .

Typical Properties:
S p e c i f i c G r a v i t y : 0.999
Wt./Gal. l b s . : 8.33
pH: 1 0 . 3 5

Use D i l u t i o n : Use as i s
F o r m u l a 945
SOURCE: W i t c o C o r p . : S u g g e s t e d F o r m u l a t i o n s
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 153

Carpet 8 U p h o l s t e r y Cleaner
T h i s o e n e r a l Duroose s t a i n remover f o r m u l a t i o n is o a r t i c u l a r l v
e f f e c t i v e i n removing o i l s t a i n s .
Ingredient : Wt%
D e i o n i z e d Water ( h o t ) 37.0
SMA-2625 R e s i n 2.4
Aqua Ammonia 0.7
W i t c o l a t e WACLA 18.0
W i t c o n a t e 60T L i q u i d 4.0
Avanel 5-70 4.0
Dei o n i zed Water 34.0
Dye, Fragrance, e t c . (2.5.
pH ( a s i s ) : 8.0-9.0
Appearance: C l e a r l i q u i d
S p e c i f i c G r a v i t y : 1.016
Procedure:
1 . Charge t h e h o t w a t e r t o a m i x i n g v e s s e l and s t a r t a g i t a t i o n .
S l o w l y s i f t i n t h e SMA-2625 R e s i n t o a v o i d c l u m p i n g . Add
t h e Aqua Ammonia, a p p l y c o o l i n g , and mix w e l l u n t i l t h e
r e s i n i s dissolved.
2 . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . S t o p
a g i t a t i o n t o permit deaeration o f t h e product p r i o r t o
filling off.
3 . I f t h i s p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l
w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r
t h e dye is t h o r o u g h l y mixed, t h e dye s o l u t i o n may be
added
NOTE: Use " a s i s " on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h
water f o r u pholstery.

V i n y l Dressing ( 8 )
Ingredient: Wt%
Part A:
M a s i l EM 250 C 18.0
M a s i l EM 10,000 C 10.0
Dei o n i zed Water 30.0
P a r t B:
Macol OP-10 SP 2.0
G1 y c e r i ne 1.o
D e i o n i r e d Water 38.0
Sodium Benzoate 1.o
Procedure:
1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and M a s i l
EM 10,000 C . S t a r t g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r
so as n o t t o b r e a k t h e e m u l s i o n .
2. I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol OP-10 SP and
g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l
components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h
e y e s " . Charge t h e sodium b e n z o a t e and m i x u n t i l d i s s o l v e d .
3 . Under g e n t l e a g i t a t i o n , add P a r t 0 t o P a r t A. C o n t i n u e m i x i n g
g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d
to b e used "as i s " . I f d e s i r e d , UV a b s o r b e r s and o t h e r compon-
e n t s may be added t o t h e f o r m u l a t i o n .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
154 Advanced Cleaning Product Formulations

Carpet & Upholstery Cleaner

Ingredients: Wt%
Dei o n i zed Water ( H o t ) 37.0
SMA-2625 R e s i n 2.37
Aqua Ammonia 0.67
Sodi u m L a u r y l S u l f a t e 18.0
R i chami de 5725 4.0
Avanel 5-70 4.0
Dei o n i zed Water 33.96
Dye, F r a g r a n c e , E t c . As d e s i r e d

pH (as i s ) : 8.0-9.0
Appearance: C l e a r l i q u i d
S p e c i f i c G r a v i t y : 1 .016

Procedure:
Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n .
S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e
Aqua Ammonia, a p p l y c o o l i n g and m i x w e l l u n t i l t h e r e s i n i s
d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s .
I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l water
s h o u l d b e r e s e r v e d f o r d i s s o l v i n g t h e d y e . A f t e r t h e dye i s
t h o r o u g h l y m i x e d , t h e d y e s o l u t i o n may b e added t o t h e p r o d u c t .
Stop a g i t a t i o n t o p e r m i t deaeration o f t h e product p r i o r t o
filling off.

Notes :
T h i s i s a g e n e r a l p u r p o s e o i l y s t a i n remover. T h i s f o r m u l a t i o n
i s p a r t i c u l a r l y e f f e c t i v e a t r e m o v i n g o i l s t a i n s . Use a s - i s on
c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h w a t e r f o r u p h o l s t e r y .
N o t e : The dye s h o u l d b e t h o r o u g l y s c r e e n e d t o a v o i d f a b r i c
staining.
F o r m u l a t i o n CP-101

L i q u i d Steam C a r p e t C 1 e a n e r
F o r H a r d Water Systems

Ingredients: Wt%
Sodium M e t a s i 1 i c a t e A 7.5
Tetrapotassium Pyrophosphate 12.5
Emphos PS-331 4.0
Macol NP 11 1.o
D e i o n i z e d Water 76.0

Procedure:
Add i n g r e d i e n t s as l i s t e d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 155

F1oor C l e a n e r

Ingredients: wtsl,
M a z a m i de 1281 8.0
Sodi urn T r i p o l y p h o s p h a t e 2.0
T e t r a p o t a s s i u m Pyrophosphate 2.0
Water 88.0

Procedure:
Add i n g r e d i e n t s as l i s t e d .

L i q u i d F l o o r Cleaner

Ingredients: Q
Macol NP 9 . 5 7.0
Sodi urn T r i p o l yphosphate 8.0
T r i s o d i urn Phosphate 2.0
Sodi urn M e t a s i 1i c a t e P e n t a h y d r a t e 2.0
Maphos 60A 3.0
Water 78.0

Procedure:
A d d i n g r e d i e n t s as l i s t e d .
NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F.

F l o o r Scrubber

Ingredients:
Sodi urn M e t a s i 1 ic a t e 2.0
Tetrasodium Pyrophosphate 18.0
Emphos PS-331 15.0
D e i o n i z e d Water 53.95
Mazami de 1281 6.0
Sodium H y d r o x i d e , 50% 5.05

Procedure :
Add i n g r e d i e n t s as l i s t e d .

SOURCE: PPG I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


156 Advanced Cleaning Product Formulations

Household Carpet F r e s h e n e r / A n t i s t a t

InQredients: Wt%
P a r t A:
P u f f e d Borax ( 1 0 l b s / c u f t ) 1.8
Fragrance 0.2
Sodi um B i c a r b o n a t e 15.0
L a r o s t a t 519 3.0

P a r t 6:
Sodi um B i c a r b o n a t e 80.0

Procedure:
I n a r i b b o n m i x e r o r V - b l e n d e r , c h a r g e t h e p u f f e d b o r a x and
f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y
add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added,
c o n t i n u e m i x i n g f o r 5 m i n u t e s t o c o m p l e t e a b s o r p t i o n . Add t h e
L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15
m i n u t e s more.

Notes :
T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t .
The p r o d u c t i s d e s i g n e d t o b e shaken o n t o t h e c a r p e t , l i g h t l y
r u b b e d i n t o t h e c a r p e t and t h e n t h e e x c e s s removed b y vacuuming.
F o r m u l a t i o n SP-I01

Pump S p r a y C a r p e t A n t i s t a t

Ingredients:
P a r t A:
Water 94.3
Isopropyl Alcohol 5.0
L a r o s t a t 264 A 0.7

Appearance: C l e a r , w a t e r - w h i t e t o pale-yellow l i q u i d
S p e c i f i c G r a v i t y : 0.98

Procedure:
To a m i x i n g vessel, charge t h e water, f o l l o w e d by t h e i s o p r o -
p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r .

Notes :
T h i s i s a n o n - a e r o s o l , pump s p r a y c a r p e t a n t i s t a t f o r t h e
removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and
other surfaces, spray l i g h t l y w i t h t h i s formulation. It i s not
necessary t o s a t u r a t e t h e surface. I f a d d i t i o n a l p r o t e c t i o n i s
needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n
one, t o i n s u r e even t r e a t m e n t .
F o r m u l a t i o n SP-102

SOURCE: PPG I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 157

h i qlai d L e a t h e r . V i n v l , a n d P l a s t i c C l e a n e r and R e s t o r e r

Inqredients: Wt%
DeSonic 9N 10.0
Dowanol PM G l y c o l E t h e r 5.0
Isopropyl Alcohol 2.5
Amy1 A c e t a t e 1.o
Water 81 . 5

Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .

Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e -
l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few
m i n u t e s , t h e n r i n s e o r hose o f f .

Product I n f o r m a t i o n :
Product: Benefit :
DeSonic 9N Detergent and degreaser
Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g a g e n t
Amyl A c e t a t e Solvent
Isopropyl Alcohol Sol vent
Formula 1000

L i q u i d Leather, Vinyl, and P l a s t i c C l e a n e r

InQredients: Wt%
W i t c o n o l NP-100 10.0
Dowanol PM G l y c o l E t h e r 5.0
Isopropyl Alcohol 2.5
Amy1 A c e t a t e 1 .o
Water 81.5

Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .

Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e -
l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few
m i n u t e s , t h e n r i n s e o r hose o f f .

Product I n f o r m a t i o n : Benefit :
W i t c o n o l NP-100 D e t e r g e n t and d e g r e a s e r
Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g a g e n t
Amyl A c e t a t e Sol vent
I s o p r o p y l A1 coho1 Sol vent
Formula 1001

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
158 Advanced Cleaning Product Formulations

Low Cost E x t r a c t i o n C a r p e t C l e a n e r
Ingredients:
Water, D . I . 91 . o
P e t r o 22 Powder 5.0
EDTA Powder 4.0
Perfume q. s .

81 e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s in t h e o r d e r 1 isteci.

Use D i l u t i o n : 1-2 o z / g a l of w a t e r
F o r m u l a 901

Premium, Medium D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r

Inqredients:
Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y 65.0
Sodi urn M e t a s i 1 i c a t e , P e n t a h y d r a t e 29.5
P e t r o 2 2 Powder 5.0
Optical Brightener 0.5

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

Use D i l u t i o n : 1-2 o z / g a l
Formula 904

Heavy D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r

Inqredi ents: Wt%


Sodium C a r b o n a t e (Soda Ash) 10.0
T r i s o d i u m Phosphate, C r y s t a l 10.0
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 20.0
Sodium S u l f a t e ( S a l t Cake) 56.0
P e t r o 2 2 Powder 4.0

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d

Use D i l u t i o n : 1-2 o z / g a l
F o r m u l a 905

SOURCE: Witco Corp.: Suggested F o r m u l a t i o n s


Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 159

Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t

Component: Wt%
Sodi um B i c a r b o n a t e t o 100% t o t a l
STPP 47.0
B u r c o LAF-6 2.5
Burco SZS 0.25
B u r c o s p e r s e AP Powder 2.5
B u r c o t a s e SP-60 ( i f d e s i r e d ) 1.o
Fragrance as d e s i r e d

Procedure:
S p r a y LAF-6 ( a n d i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d
u n t i l a b s o r b e d . Add B u r c o S Z S , t h e n Sodium B i c a r b o n a t e and
b l e n d u n t i l u n i f o r m . Add B u r c o s p e r s e A P Powder ( a n d i f d e s i r e d )
B u r c o t a s e SP-60. B l e n d u n t i 1 u n i f o r m .

Use C o n c e n t r a t i o n :
2-3 ounces p e r g a l l o n i n e x t r a c t o r .

SOURCE: B u r l i n g t o n Chemical C o . , Inc.: Suggested F o r m u l a t i o n s

RUQ Steam C l e a n e r
(Liquid)

S o i l - Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , clay


and p a r t i c u l a t e
S u r f a c e - P o l y e s t e r and n y l o n
A p p l i c a t i o n Method - Rug s c r u b b e r
Manufacture - Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition: Wt%
Water 79.6
M e t s o Beads 2048 7.0
Sodium X y l e n e S u l f o n a t e , 40% 6.7
C12-Cl5 L i n e a r A l c o h o l , 12 M o l e s EO 3.9

Use D i 1u t i on : 4 . 7 - 9 . 4 % bw ( 6 - 1 2 o z / g a l 1o n )

SOURCE: The PQ C o r p . : Suggested F o r m u l a t i o n


160 Advanced Cleaning Product Formulations

No Rinse F l o o r Cleaner
I npredie n t s : \Mt%
Water, D.I. 79.0
Sodi um Carbonate 4.0
Rewoteric AM 8-14 10.0
Versene 100 2.0
Butyl Cellosolve 5.0

Blending Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each addi t ion.
Formula 932

Heavy D u t y F l o o r Cleaner

Ingredients: Wt%
Water, D.I. 78.0
Varami de A-1 2 7.0
T r i sodi um Phosphate 10.0
Sodium Tripolyphosphate 5.0

81 end$ng Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each a d d i t i o n .

T y p i c a l Propert ies :
S o l i d s : 22.0%
Formula 933

No-Rinse F l o o r Cleaner Deareaser


Ingredients: WtO/o
Deionized water 79.0
Sodium carbonate 4.0
Rewoteric AM V 10.0
Versene 100 2.0
Butyl Cellosolve 5.0
Blending Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each a d d i t i o n .

Typical Properties:
S o l i d s : 8.1%
pH: 10.9
V i s c o s i t y : 4 cps
Formula 951

SOURCE: Witco Corp. : Suggested Formulations


Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 161

Wax S t r i p p e r ( A )

Inqredients: Wt%
Oleic Acid 7.0
Monoethanol ami ne 2.0
Avanel S - 7 4 2.0
Potassium H y d r o x i d e , 45% 1 .o
Sodi um H y d r o x i d e , 50% 1 .o
Versene 100 1 .o
Dowanol TBA 5.0
Water 81 . o

Procedure:
Add i n g r e d i e n t s as l i s t e d .

Wax S t r i p p e r ( B )

Inaredients:
Oleic Acid 7.0
Monoethanolamine 2.0
Avanel S - 7 4 2.0
Potassium H y d r o x i d e , 45% 1 .o
Sodi um H y d r o x i d e , 50% 1 .o
Versene 1 0 0 1 .o
E t h y l e n e G1 y c o l Monobutyl E t h e r 81 . o
Water 5.0

Procedure:
Add i n g r e d i e n t s as l i s t e d .

C o n c e n t r a t e d Wax S t r i p p e r

Inaredients: WtO/o
Sodium H y d r o x i d e , 50% 6.5
Macol NP 9 . 5 1 .o
EDTA, 40% 0.5
Mazox LDA 1 .o
B a r q u a t MB-50 1 .o
Monoethanolami ne 8.5
Water 81 .5

Procedure:
Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1 : l O t o 1:30.
Mac01 NP 1 0 . 5 can be s u b s t i t u t e d f o r t h e Macol NP 9 . 5 . Mafo CB-40
can be s u b s t i t u t e d f o r t h e Mazox LDA.

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


14. Miscellaneous

1 fi7
Miscellaneous 163

B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021
I n q r e d ie n t s : Wt%
Phase I :
Isopropanol 10.0
Oleic Acid 8.8
Varox 1 7 7 0 5.0
Pine O i 1 12.0
Phase 11:
Water, D . I . 62.2
P o t a s s i um H y d r o x i d e (87%) 2.0
81 e n d i ng P r o c e d u r e :
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine
Phase I T i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add
Phase I t o Phase 1 1 .
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 5
S o l i d s : 10.6%
pH: 9 . 3
Formula 302

_
G e n~e r a
~l D
_ i s_i n f _
e c t_a n _
t S_o l u_t i o_n ~ ~
Ingredi e n t s : wtsl,
Water. D . I . 68.0
V a r q u a t 5 0 MC 10.0
G1 y o x a l ( 4 0 % ) 5.0
R e w o t e r i c AM DML-35 17.0
Blending Procedure:
Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each add1 t ion,
Typical Properties:
V l s c o s l t y , cps: 4
Sol 1 d s : 1 3 . 0 %
pH: 7 . 1
Formula 3 0 3

Hospital D is infectant
Ingredi
-~ ents: Wt%
Water, D . I . 84.2
V a r i q u a t 50 MC 9.6
Varox 365 4.0
Versene 100 1.5
Sod1 urn H y d r o x i d e ( 3 0 % ) 0.7
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
Viscosity, cps: 4
S o l i d s : 6.7%
pH: 1 2 . 2
Formula 304

SOURCE: Witco Corp,: Suggestecl F o r m u l a t i o n s


I64 Advanced Cleaning Product Formulations

C u t t i n g O i l Concentrate

Ingredients: Wei s h t %
Aristonate M 36.00
I g e p a l CO-430 20.00
TEA, 85% 8.00
Oleic A c i d 8.00
100 SUS N a p h t h e n i c O i l 28.00
Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-003-01

Cutting Oi 1

Ingredients: Wei q h t %
Aristonate M 10.50
TEA, 85% 0.90
T a l l O i l A c i d , A c t i n o l FA-1 1.20
C a l a m i d e SM 1.65
100 SUS N a p h t h e n i c O i l 85.00
Water 0.75
Comments a b o u t t h i s f o r m u l a :
E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-004-01

C o n c r e t e C 1e a n e r

Ingredients: Weight%
C a l s o f t F-90 5.00
Sodi um S i 1 ic a t e 30.00
Sodium C a r b o n a t e 30.00
Sodi um H y d r o x i d e 25.00
Sodi um T r i p h o s p h a t e 10.00
Comments a b o u t t h i s f o r m u l a :
G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder.
F o r m u l a t i o n CON-001-01

White Wall Cleaner

Insredients : Wei s h t %
Water 60.20
C a l s o f t L-40 29.30
P i l o t SXS-40 2.20
Na4 EDTA 1.30
C a l o x y l a t e N-9 7.00
Comments a b o u t t h i s f o r m u l a :
V i s c o s i t y o f t h e p r o d u c t i s a b o u t 160 cPs a t room t e m p e r a t u r e .
F o r m u l a t i o n TIR-001-01

SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s


Miscellaneous 165

d L i monene Water1 e s s Hand C1 e a n e r

Ingredients: Wt%
Phase I :
Water, D . I . 81 . O
T r i s o d i u m Phosphate 1 .o
Sodium C i t r a t e 2.0
Glycerin 2.0

Phase 11:
d - L i monene 7.0
DeSonic 9N 5.0
V a r o n i c T202 2.0

B l e n d i n g Procedure:
I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y .
H e a t t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l
and m i x t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase
11 Po Phase I.Cool q u i c k l y t o s t a b i l i z e e m u l s i o n .

Typical Properties :
Appearance, Room Temp.: Heavy Cream
S o l i d s : 12.0%
pH: 1 0 . 4
Formula 1120

P a s t e Hand C l e a n e r

Ingredients: WtS/o
Water, D . I . 70.0
Varami de MA-1 10.0
R e w o t e r i c AM 8-15 10.0
W i t c o l a t e SE-5 10.0

81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i on.

Typical Properties:
V i s c o s i t y , c p s : 6360
S o l i d s : 19.5%
pH: 8 . 7
Formula 1121

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
166 Advanced Cleaning Product Formulations

Dipentene Microemulsion Formulations

D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e
o i l s c o n t a i n i n g r e l a t e d monocyclic t e r p e n e hydrocarbons, predomi-
n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m -
onene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . )
O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and
a l p h a - and b e t a - p i n e n e .

Non-alkaline Formulations

Ingredients: &%
D i p e n t e n e 122 5.00
Tomah E-14-5 6.40
Tomah E-14-2 0.80
Tomah A l k a l i S u r f a c t a n t 0.80
Water 87 00
~

CPL, c : 1 1
CPH, C : 30
Emulsifier/Dipentene Ratio: 1.60

Ingredients: VVt.%
D i p e n t e n e 122 10.00
Tomah E-14-5 8.80
Tomah E-14-2 1.10
Tomah A l k a i S u r f a c t a n t 1.10
Water 79.00

C P L , c : 11
CPH, C : 50
Emu1 s i f e r / D i p e n t e n e R a t i o : 1.10

Inaredients: Wt.%
D i p e n t e n e 122 20.00
Tomah E-14-5 14.40
Tomah E-14-2 1.80
Tomah A l k a l i S u r f a c t a n t 1 .80
Water 62.00

CPL, c : 19
CPH, C : 41
Emulsifier/Dipentene Ratio: 0.90

Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and emuls-


i f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r
and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .
C P L i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h
temperature cloud p o i n t " .

SOURCE: Tomah P r o d u c t s , Inc.: B u l l e t i n : Terpene M i c r o e m u l s i o n s


Miscellaneous 167

D i p e n t e n e M i c r o e m u l s i o n Formul a t i o n s ( C o n t i nued)

D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne
o i l s c o n t a i n i n g r e l a t e d m o n o c y c l i c t e r p e n e h y d r o c a r b o n s , predom-
i n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same a s l i m o n -
ene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . )
O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and
a l p h a - and b e t a - p i n e n e .

A l k a l i n e Formulations

Ingredients: Wt.96
D i p e n t e n e 122 5.00
E-14-5 8.00
E-14-2 0.50
A1 k a l i S u r f a c t a n t 1 .50
Water 83.30
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.70

CPL, C : 15
CPH, C : 4 4
Emulsifier/Dipentene Ratio: 2.00

Ingredients: Wt.%
D i p e n t e n e 122 10.00
E-14-5 12.00
E-14-2 0.75
A1 k a l i S u r f a c t a n t 2.25
Water 73.50
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.50

CPL, c : 20
CPH, C : 46
Emulsifier/Dipentene Ratio: 1 .50

Ingredients: Wt.%
D i p e n t e n e 122 20.00
E- 1 4 - 5 17.60
E-14-2 1.10
A1 k a l i S u r f a c t a n t 3.30
Water 56.80
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.20

CPL, C : 18
CPH, C : 43
E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0
Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i -
f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r
and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .
CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h
temperature cloud p o i n t " .

SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s


168 Advanced Cleaning Product Formulatioris

H y d r o c a r b o n S o l v e n t M i c r o e m u l s i ons

Developed i n o r d e r t o o f f e r replacements f o r expensive


d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l
have f l a s h p o i n t s above I O O C and l o w VOC c o n t e n t .

Exxsol D-I10 Formulations

Formula A:
Ingredients: \Nt.%
E x x s o l D-110 20.0
Tomah E-14-2 11.9
Tomah E-14-5 5.4
Tomah A l k a l i S u r f a c t a n t 4.3
S o f t Water 58.4

Formula 8 :
Inaredients: Wt.%
E x x s o l D-110 30.0
Tomah E-14-2 17.9
Tomah E - 1 4 - 5 8.1
Tomah A l k a l i S u r f a c t a n t 6.5
S o f t Water 37.5

Formula C :
Inqredients: Wt.%
E x x s o l D-110 40.0
Tomah E-14-2 23.9
Tomah E-14-5 10.8
Tomah A l k a l i S u r f a c t a n t 8.7
S o f t Water 16.6

Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogen-


eous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s
with mixing.

These m i c r o e m u l s i o n s s h o u l d be c l e a r and s t a b l e i n t h e temp-


e r a t u r e r a n g e f r o m 20-37C. O u t s i d e t h a t r a n g e t h e y may c l o u d o r
s e p a r a t e , b u t w i l l r e g a i n c l a r i t y upon r e t u r n i n g t o room temp-
e r a t u r e . I f i t i s necessary t o r a i s e t h e c l o u d p o i n t temperature,
a s m a l l amount o f a d d i t i o n a l Tomah A l k a l i S u r f a c t a n t s h o u l d b e
added.

SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s


Miscellaneous 169

Hydrocarbon S o l v e n t Microemulsions ( C o n t i n u e d l

Developed i n o r d e r t o o f f e r r e p l a c e m e n t s f o r e x p e n s i v e
d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have
f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .

Isopar M F o r m u l a t i o n s

I s o p a r M can b e s u b s t i t u t e d d i r e c t l y f o r t h e E x x s o l D-110 i n
t h e above f o r m u l a t i o n s . I n a d d i t i o n , t w o f o r m u l a t i o n s w i t h l o w e r
s o l v e n t c o n t e n t have been d e v e l o p e d .

Unbui 1 t :
Component: Wt.%
S o f t Water 83.0
Sodium Metas l i c a t e P e n t a h y d r a t e 0.0
Tomah E-14-2 4.7
Tomah E-14-5 4.7
Tomah A1 k a l i S u r f a c t a n t 1.6
I s o p a r Wi 6.0

L i g h t l y b u i 1t :
Component: Wt.%
S o f t Water 79.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
Tomah E-14-2 5.6
Tomah E-14-5 5.6
Tomah A l k a l i S u r f a c t a n t 1.a
Isopar M 7.0

S t a r t b y d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f u s e d ) i n t h e
w a t e r . Then add t h e E-14-2, E-14-5, a n d A l k a l i S u r f a c t a n t . M i x
u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h
m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r a s t h e l a s t o f
t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l b e c l e a r and
s t a b l e i n t h e t e m p e r a t u r e r a n g e f r o m 20-5OC. The c l o u d p o i n t c a n
be r a i s e d f u r t h e r b y a d d i n g a s m a l l amount o f a d d i t i o n a l A l k a l i
Surfactant.

SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s


I70 Advanced Cleaning Product Formulations

. !oL . ..Emu 1-si-o~n-UsinxPemulens


V i_s_cosi_tv_s_jlicon resins
S i l i c o n e o i l c a n b e e m u l s i f i e d and s t a b i l i z e d v i a t h e u s e o f
Pemulen r e s i n s . The r e s i n s s t a b i l i z e e m u l s i o n s v i a e l e c t r o s t a t i c
s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e e k i n g an approp-
r i a t e surfactant emulsifier.

Inycedi e n t l W t"/.
D I Water 83.80
Pemulen 1622 ( 1 ) 0.20
Makon 10 ( 2 ) 0.70
Dow 200 S i l i c o n e F l u i d ( 3 ) 15.00
Triethanolamine 0.30

Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 1,000 c p
Product pH: 7.3
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a1 S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Stepan C o .
( 3 ) Dow C o r n i n g

Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
S c r e e n t h e Pemuleri r e s i n i n t . o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous
and f r e e o f p o l y m e r l u m p s .
2 . Add t h e Makon 10 and m i x u n t i l homogeneous.
3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M i x u n t i l
uniform.
4 . Add t h e T E A . M i x u n t i l smoot.h.

Total Actives:
Silicone O i l : 15.00%

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-510


Miscellaneous 171

Lumi n i z i n g P e t C o n d i t i o n e r

P h o s p h o l i p i d EFA adds s h i n e and a s i l k y t e x t u r e t o t h e


a n i m a l ' s c o a t o r mane. The Monaquat TG p r o v i d e s body b u i l d i n g
c o n d i t i o n i n g and d e t a n g l i n g w h i l e l e a v i n g a s o f t smooth f e e l .
Monaquat I S I E S i s an e f f e c t i v e l o n g l a s t i n g a n t i s t a t t h a t
controls d i r t attraction.

Inaredients: Wt%
Water 85.2
Hydroxyethyl C e l l u l o s e 0.8
Stearic acid 2.0
Stearyl alcohol 2.0
Monaquat TG 7.0
Monaquat I S I E S ( I s o s t e a r y l E t h y l m i d o n i u m E t h o s u l f a t e ) 0.5
P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e
Phosphate) 2.0
Sodium C h l o r i d e 0.5

Procedure:
Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u -
l o s e and t u r n h e a t o n . A t 50-60C add s t e a r i c a c i d , s t e a r y l
a l c o h o l , Monaquat TG, Monaquat I S I E S , P h o s p h o l i p i d EFA, and
sodium c h l o r i d e . Heat and m i x t o 70-75C ( a smooth c r e m e ) . Cool
t o 40C. A d j u s t pH t o 4 . 5 - 5 . 0 . A d d c o l o r , f r a g r a n c e and p r e s e r v -
a t iv e . Package.

Typical Properties:
Appearance: Opaque v i s c o u s l o t i o n
Recommended Use D i l u t i o n : As i s
F o r m u l a t i o n F-777

P e t Shampoo

A h i g h foaming, m i l d detergent which w i l l leave your p e t


f r e s h and c l e a n .

Ingredients: Wt%
Water 70.0
M o n a t e r g e 779 25.0
d - L i monene 5.0

Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t
pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package.

Typical Properties:
Appearance: C l e a r y e l l o w l i q u i d

Recommended Use D i l u t i o n : 1:50 w i t h water


F o r m u l a t i o n F-774

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


172 Advanced Cleaning Product Formulations

M i cro-Emu1 s i ons with d-Li monene

The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m i c r o - e m u l s i o n s o f
imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used b y
u t i n g i n w a t e r a r e v e r y e f f e c t i v e f o r r e m o v i n g many o i l y
. .I r e s i n o u s s o i l s . The f o r m u l a t h e m s e l v e s a r e c l e a r and e x h i b i t
a bloom e f f e c t upon d i l u t i o n .

Formula I
Inqredients: Wt%
d - L i monene 10.0
Monamul s e dL-1273 18.0
Water 62.0

F o r m u l a I1

Inqredients: Wt%
d - L i monene 35.0
Monamulse dL-1273 28.0
Isopropanol 5.0
Water 32.0

Formula I11

Ingredients: Wt%
d - L i monene 65.0
Monamul se dL-1273 23.0
Water 12.0

Procedure:
I n a l l c a s e s , mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d .
Add o t h e r i n g r e d i e n t s e x c e p t w a t e r . M i x u n t i l homogeneous. Add
water s l o w l y w i t h s t i r r i n g .

Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r

SOURCE: Mona I n d u s t r i e s , I n c . : F o r m u l a t i o n F-786


Miscellaneous 173

M i cro-Emu1 s i ons w i t h P i ne O i 1

The fol 1owi ng f o r m u l a s a r e c l e a r m i c r o e m u l s i ons o f p i ne o i 1


and w a t e r . They r e p r e s e n t t h e r a n g e o f p i n e o i l and w a t e r concen-
t r a t i o n s commonly used. The f o r m u l a s t h e m s e l v e s a r e c l e a r and
e x h i b i t a bloom e f f e c t upon d i l u t i o n .

Formula 1

Inaredients: &y&
Pine O i l 35.0
Monamulse TRP 20.0
Water 45.0
Appearance: C l e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 2

I ngredients : WtO/o
Pine O i l 20.0
Monamul s e TRP 20.0
Isopropanol 5.0
Water 55.0
Appearance: C1 e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 3

Ingredients: Wt%
Pine O i l 9.0
Monamul se TRP 10.0
Isopropanol 10.0
Water 71 .O
Appearance: C1 e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms

Formula 4

Inqredients: WtO/o
Pine O i l 2.0
Monamul se TRP 5.0
Water 93.0
Appearance: C l e a r
D i l u t i o n (1% i n t a p w a t e r ) : Clear

Procedure:
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package
Recommended Use D i l u t i o n : 1 : l O w i t h w a t e r
F o r m u l a F-785

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


174 Advanced Cleaning Product Formulations

P l a s t i c B o t t l e Wash
Stable i n hard water

Inqredients: Wt%
Water 26.5
KOH-45% 19.5
K a s i l #I 39.0
STPP 8.0
B u r c o HCS-5ONF 7.0

% S o l i d s : 31.0

Add components i n o r d e r l i s t e d . B l e n d between a d d i t i o n s .

To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o o f t h e
components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n
i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n d e g r e e
o f s o i l t o b e removed. N o r m a l l y , a 2% end use c o n c e n t r a t i o n i s
s u f f i c i e n t f o r b o t t l e cleaning.

A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .

B o t t l e Wash F o r m u l a t i o n s
Low Foam

Inqredie n t s : y
&
50% NaOH To 100% T o t a l
B u r c o BSGH-270 2.5-5.0%
B u r c o HCS-50NF 0.5-2.5%

Add BSGH-270 and HCS-50 NF t o 50% NaOH.

M o d e r a t e Foam

Inqredients: W O

50% NaOH To 100% T o t a l


B u r c o BSGH-270 2.5-5.0%
B u r c o NPS-225 0.5-2.5%
Water 3.0-7.5%

I t i s recommended t h a t t h e BSGH-270 and NPS-225 b e d i s s o l v e d


i n an e q u a l amount o f w a t e r and t h e c a u s t i c added t o t h a t p r e m i x .
T o defoam t h i s f o r m u l a t i o n use a 3/1 r a t i o o f NPS-225/Burco
LAF-I 25.

SOURCE: B u r l i n g t o n Chemical Co., Inc.: Suggested F o r m u l a t i o n s


Miscellaneous 175

Teroene M icroemul s i ons

The f o r m u l a t i o n s g i v e n h e r e w i l l p r o d u c e c l e a r s t a b l e m i c r o -
e m u l s i o n s c o n t a i n i n g f r o m 15% t o 40% d - l i m o n e n e .
G l i d s o l 180 ( f r o m SCM G l i d c o O r g a n i c s C o r p . ) , a p i n e o i l
d e r i v a t i v e can b e s u b s t i t u t e d f o r d - l i m o n e n e i n t h e f o r m u l a t i o n s
t o g i v e a f l a s h p o i n t above 1 4 0 F . N o t e t h a t o t h e r p i n e o i l s may
n o t work i n t h e s e f o r m u l a t i o n s .
Formula A:
D-Limonene 40.0
Tomah E-14-5 22.4
Tomah E-14-2 2.8
Tomah A l k a l i S u r f a c t a n t 2.8
Water 32.0
% t o t a l s u r f a c t a n t : 28.0%
Emul s i f i e r / T e r p e n e r a t i 0 : 0 . 7 0 0
F o r m u l a 5: Wt.9/o
D-Li monene 30.0
Tomah E-14-5 19.2
Tomah E-14-2 2.4
Tomah A l k a l i S u r f a c t a n t 2.4
Water 46.0
% t o t a l s u r f a c t a n t : 24.0%
Emul s i f ie r / T e r p e n e r a t i 0 : 0 . 8 0 0
Formula C : Wt.%
D-Li monene 20.0
Tomah E - 1 4 - 5 12.8
Tomah E-14-2 1.6
Tomah A l k a l i S u r f a c t a n t 1.6
Water 64.0
% t o t a l s u r f a c t a n t : 16.0%
E m u l s i f i e r / T e r p e n e r a t i o : 0.800
Formula D: Wt.o/a
D-Li monene 15.0
Tomah E-14-5 12.0
Tomah E-14-2 1.5
Tomah A l k a l i S u r f a c t a n t 1.5
Water 70.0
% t o t a l s u r f a c t a n t : 15.0%
Emulsifier/Terpene r a t i o : 1.000
Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogen-
eous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s
w i t h mixing.
A t y p i c a l use l e v e l w o u l d b e a t 1 0 / 1 t o 4 0 / 1 w i t h w a t e r . About
1-2% d - l i m o n e n e a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g r e a s e
would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d-limonene.
Concentrated Formula
Formula:
D-Limonene 70.0
Tomah E-14-5 14.0
Monamid 7 0 5 4.0
T a l l O i l Fatty Acid 1.6
Monoethanolamine 0.4
Water 10.0
SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : T e r p e n e M i c r o e m u l s i o n s
176 Advanced Cleaning Product Formulatioris

Wax Emulsion U s i n g Pemulen R e s i n s

T h i s wax e m u l s i o n can be c r e a t e d and s t a b i l i z e d v i a t h e use


o f Pemulen r e s i n s . The r e s i n s s t a b i i z e e m u l s i o n s v i a e l e c t r o s t a t -
i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e l e c t i n g an
appropriate surfactant emulsifier.

Ingredient: vytsb
Bareco C-36 Wax ( 1 ) 12.00
Hoechst Wax E ( 2 ) 8.00
Pemulen 1622 ( 3 ) 0.30
01 Water 79 5 0
~

Morphol ine 0.20

Physical Properties :
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) P e t r o l i t e Corp.
( 2 ) American Hoechst Corp.
( 3 ) BFGoodrich

Procedure:
1. M e l t t h e waxes t o g e t h e r i n a v e s s e l , a p p r o x i m a t e l y a t 9 0 C .
2 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
Screen t h e Pemulen r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous
and f r e e o f p o l y m e r lumps.
3 . Heat t h e Pemulen d i s p e r s i o n t o 9OC. Add t h e Pemulen d i s p e r -
s i o n t o t h e m e l t e d wax w i t h v i g o r o u s a g i t a t i o n .
4 . Add t h e m o r p h o l i n e and cool q u i c k l y .

Total Actives:
T o t a l Wax: 20.00%

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-501


Section II
sportation Cleaners
and Polishes

177
15. Auto Cleaners and Polis

178
Auto Cleaners and Polishes 179

Chrome P o l i s h

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Ingredient:
D I Water 39.25
Morphol ine 1.39
Pumice 14.00
Snow F l o s s 9.25
SFSB S i l i c o n e F l u i d ( 3 5 0 ) ( 1 ) 1.85
Yarmor 302 P i n e O i l ( 2 ) 0.46
Oleic Acid 1.85
Mineral S p i r i t s 24.50
TEA l a u r y l s u l f a t e ( 3 ) 2.30
Cocamide DEA ( 4 ) 0.50
D I Water 4.46
Carbopol EZ-2 ( 5 ) 0.19

Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 10,800 c p
P r o d u c t pH: 9 . 0
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) General E l e c t r i c
( 2 ) Hercules
( 3 ) Rhone-Poul enc
( 4 ) H e n k e l : Standamid PO
( 5 ) BFGoodri c h

Procedure:
1 . D i s s o l v e t h e morpholine i n t h e water.
2 . W i t h r a p i d a g i t a t i o n , add t h e pumice and Snow F l o s s .
3 . D i s s o l v e t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e
m i n e r a l s p i r i t s . S l o w l y add i n t o t h e above m i x t u r e w i t h
rapid agitation.
4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. B l e n d t h o r -
oughl y .
5. I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 1 9 p a r t s o f Carbopol i n t o
4.48 p a r t s o f w a t e r by s i m p l y "dumping" t h e polymer i n t o t h e
w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y
wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . B l e n d
thorough1y .
T o t a l Asti ves :
Silicone Fluid: 1.85
Total Surfactant: 4.65
Mineral S p i r i t s : 24.50
T o t a l Abrasives: 23.25

FGoodrich S p e c i a l t y Chemicals: DET-551


I80 Advanced Cleaning Product Formulations

L i q u i d Car Polish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Insredient: Wt96
D I Water 37.80
T r i e t h a n o l ami ne 8.20
Wax Emulsion ( 1 ) 2.50
Morphol ine 2.00
SF90 S i l i c o n e F l u i d (350) ( 2 ) 1 * 50
Oleic Acid 2.50
Kerosene 10.00
Mineral S p i r i t s 8.00
D I Water 49.70
Carbopol EZ-2 ( 3 ) 0.30
Isopropanol 0.40
Mineral S p i r i t s 5.00
SF1706 R e a c t i v e Amine Polymer ( 4 ) 1.50
SF1705 R e a c t i v e Amine Polymer ( 4 ) 2.10
Kaopolite kaolin clay (5) 8.50

Physical P r o p erties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps
P r o d u c t pH: 8-9
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) see EiFGoodrich L i t e r a t u r e DET-501
( 2 ) General E l e c t r i c
( 3 ) BFGoodrich
( 4 ) General E l e c t r i c
(5) Kaopolite, I n c .
Procedure:
1 . M i x t o g e t h e r t h e w a t e r , TEA, wax emulsion, and t h e m o r p h o l i n e
2 . I n a s e p a r a t e v e s s e l , mix t h e s i l i c o n e f l u i d , o l e i c a c i d ,
kerosene and t h e m i n e r a l s p i r i t s t o g e t h e r . Add t h i s t o t h e
above m i x t u r e w i t h v i g o r o u s a g i t a t i o n .
3. I n a s e p a r a t e v e s s e l , d i s p e r s e 0.30 p a r t s o f Carbopol i n t o
19.70 p a r t s o f water by s i m p l y "dumping" i t i n . The polymer
w i l l wet o u t i n a few minutes. Add t h i s d i s p e r s i o n t o t h e
above m i x t u r e . M i x u n t i l homogeneous.
4 . I n a s e p a r a t e v e s s e l , mix t h e i s o p r o p a n o l , m i n e r a l s p i r i t s ,
and t h e t w o r e a c t i v e amine polymers t o g e t h e r . Add t o t h e
above m i x t u r e . M i x u n t i l homogeneous.
5 . S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous.
Total Actives:
T o t a l Wax : 0.50
Silicone Fluid: 1.50
Mineral S p i r i t s : 11 .oo
React ive A m i ne Polymer : 3.60
Abrasive: 8.50
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-BOO
Auto Cleaners and Polishes 181

L i q u i d Spray C l e a n e r f o r A l u m i n u m T r u c k s

Bngredi e n t s : -
Wt%
Water 50.0
Phosphoric A c i d , 75% 20.0
C i t r i c Acid 10.0
Macol 48 4.0
Ammoni um B i f 1u o r i de 3.0
Avanel S-30 3.0

~ r ~ c ~ d U r ~ ~
Add i n g r e d i e n t s i n o r d e r as l i s t e d . D i l u t e one p a r t c l e a n e r
w i t h f i v e p a r t s w a t e r t o use.

A 1 umi n u m C l e a n e r / B r i n h t e n e r

Pnaredi e n t : Wt%
Phosphoric A c i d , 85% 6.0
C i t r i c A c i d , 50% 8.0
N i t r i c A c i d , 70% 1.o
Avanel S-70 2.0
Water 83.0

Procedure:
Charge t h e w a t e r t o t h e m i x i n g v e s s e l . Under s l o w a g i t a t i o n
and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel
S - 7 0 and mix f o r 10 m i n u t e s . Note: I f a d d i t i o n a l b r i g h t e n i n g i s
r e q u i r e d , t h e n i t r i c a c i d may be i n c r e a s e d t o 1.5%.
F o r m u l a t i o n CM-101

Non-Phosphorous A l u m i n u m C l e a n e r

Inaredi ent : Wt%


C i t r i c A c i d , 50% 12.0
G l u c o n i c A c i d , 50% 8.0
Avanel 5-70 3.0
Water, Dye 77.0

PPOC@dUr&?:
Charae t h e w a t e r , c i t r i c a c i d , g l u c o n i c a c i d and Avanel S-70
t o t h e G i x i n g v e s s e i . M i x w e l l . I f - d y e i s t o be added, p a r t of
t h e water s h o u l d be h e l d o u t . Add t h e dye t o t h e w a t e r w i t h good
a g i t a t i o n and t h e n add t h e w a t e r t o t h e b a t c h .
Formu 1a t ion CM- 102

UWCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


182 Advanced Cleaning Product Formulations

M i l d A b r a s i v e A u t o m o b i l e Polish

I n q r e d ie n t : Wt%
Part A:
Masi 1 SF 1 , 0 0 0 4.0
Oleic Acid 2.0
Carnauba Wax #1 Y e l l o w 6.0
Isopar M 14.5
Mazami de SS-1 0 0.75

P a r t B:
Isopar M 12.0
M a s i l 123 2.0

Part C :
Isopar M 2.5
Morphol ine 1.1

P a r t D:
Water 45.15
K a o p o l i t e SF 10.0

pH ( a s i s ) : 7 . 5 - 8 . 5
Appearance: Cream-Colored Paste

Procedure:
1 . Charge t h e components i n P a r t A t o a steam-heated m i x i n g
v e s s e l equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and h e a t t o
9QC.
2. I n s e p a r a t e v e s s e l s , charge P a r t B and P a r t C components.
When P a r t A reaches 9OC and a l l t h e wax has m e l t e d , add P a r t
B t o t h e v e s s e l f o l l o w e d by P a r t C . Apply c o o l i n g .
3 . I n a s e p a r a t e v e s s e l , p r e p a r e P a r t D by a d d i n g t h e K a o p o l d t e
SF t o t h e w a t e r under a g i t a t i o n . Add P a r t D t o P a r t A and
c o n t i n u e c o o l i n g . NOTE: The f i n i s h e d p r o d u c t i s a p a s t e .
A s t i f f e r p a s t e can be p r e p a r e d by i n c r e a s i n g t h e o l e i c a c i d
charge.

SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n S A - 1 0 1
0 r and Truck Wash Compounds

183
184 Advanced Cleaning Product Formulations

Car Shampoo C o n c e n t r a t e

T h i s f o r m u l a t i o n produces c o p i o u s amounts o f foam w h i l e


c l e a n i n g a u t o m o t i v e f i n i s h e s . I t i s m i l d t o b o t h t h e u s e r and
t h e automotive f i n i s h .

Ingredient: Wt%
Part A:
Dei o n i zed Water 30.0
Sodi um C i t r a t e 0.5

P a r t 8:
Mafo CSB-50 5.0
W i t c o n a t e 60 T L i q u i d 7.5
Macol TD-12 4.0
T r i e t h a n o l ami ne, 85% 1.o
D e i o n i z e d Water 52.0
pH ( a s i s ) : 8 . 0 - 9 . 0
Appearance: C l e a r , l i g h t - y e l l o w l i q u i d
S p e c i f i c G r a v i t y : 1.00
Procedure:
1 . Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and
d i s s o l v e t h e sodium c i t r a t e i n i t .
2 . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . S t o p
a g i t a t i o n and p e r m i t t h e p r o d u c t t o d e a e r a t e p r i o r t o
f i l l i n g o f f . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r
g a l l o n o f warm w a t e r .

A u t o m a t i c Car Wash C o n c e n t r a t e

I n a r e d ie n t s : w.t%
Dei o n i zed Water 50.0
Maphos 60-A 6.0
P o t a s s i um H y d r o x i d e 3.0
T e t r a p o t a s s i u m Pyrophosphate 2.0
Sodium M e t a s i l i c a t e , Anhydrous 2.0
Macol LF 120 2.0
Mazamide 00 2.0
Sodium X y l e n e S u l f o n a t e , 40% 3.0
Macol 48 3.0
D e i o n i z e d Water 27.0
pH ( a s i s ) : 12.5-13.5
Appearance: C l e a r , l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1 .06
Procedure:
Charge t h e f i r s t p o r t i o n o f w a t e r t o t h e m i x i n g v e s s e l and
s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix
u n t i l c l e a r . NOTE: T h i s i s a h i g h l y a l k a l i n e c l e a n e r d e s i g n e d t o
be used i n commercial a u t o m a t i c c a r washes a t a d i l u t i o n r a t e o f
1-2 ounces p e r g a l l o n . Do n o t use d i r e c t l y on a u t o m o t i v e f i n i s h e s
F o r m u l a t i o n CA-102

SOURCE: PPG I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s

1
Car and Truck Wash Compounds 185

Car Wash ( C a l s o f t LAS-gg-Basedl


Ingredients: Weight%
Water 72.50
NaOH, 50% 2.40
D i e t h a n o l ami ne 0.50
C a l s o f t LAS-99 10.10
Calamide C 3.70
P i l o t SXS-40 7.00
Cal foam EA-603 2.80
Ammonium C h l o r i d e 1.oo
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-008-01

Car Wash ( C a l s o f t LAS-99-Based)


Ingredients: Wei q h t %
Water 59.80
NaOH, 50% 4.35
Cal s o f t LAS-99 16.30
Calamide C 2.05
P i l o t SXS-40 12.50
C a l foam EA-603 3.00
C a l o x y l a t e N-9 2.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s in o r d e r 1 is t e d
F o r m u l a t i o n CWC-007-01

Car Wash ( C a l s u d s A-Based)


Ingredients: Wei a h t %
Water 64.20
Calsuds A 28.00
C a l foam EA-603 2.80
C a l s u d s CD-6 4.00
Ammonium C h l o r i d e 1 .oo
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-006-01

Car Wash ( C a l s o f t T-60-Based)


Ingredients : Weight%
Water 70.00
C a l s o f t T-60 20.00
Pi l o t sxs-40 5.00
C a l o x y l a t e N-9 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-005-01

SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s


186 Advanced Cleaning Product Formulatioris

Car Wash

Readi l y removes a w i d e v a r i e t y o f r o a d s o i 1 s .

Ingredients:
Water 70.0
Monaterge ALX-100s (Cocamide DEA ( a n d ) DEA D o d e c y l -
benzenesulfonate (and) Diethanolamine) 30.0

Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH
t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package.

Typi c a l P r o p e r t i e s :
Appearance: C l e a r y e l l o w l i q u i d
Recommnded Use D i l u t i o n : 1 : 2 0 w i t h w a t e r
F o r m u l a t i o n F-772

P a s t e Car Wax

T h i s e a s i l y a p p l i e d a u t o m o b i l e p a s t e wax f o r m u l a w i l l p r o v i d e
i m p r o v e d c l e a n i n g , d e p t h o f g l o s s , l a s t i n g b e a u t y and s h i n e t o
new and o l d e r a u t o m o b i l e f i n i s h e s . M o n a s i l PCA w i l l p r o v i d e
s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a .

Ingredients: We96
P a r t I:
M o n a s i l PCA 4.5
Dimethicone (12,500 c s t ) 2.0
Carnauba Wax #1 Y e l l o w 6.0
T a l l O i l Fatty Acid 3.0
Isopar K 24.0
Kaopol it e 11 5 2 10.0

P a r t 11:
Water 50.0
TEA (99%) 0.5

Procedure:
P r e p a r e each phase s e p a r a t e l y , h e a t t o 70C. Add P a r t I I
s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo t o 40-50C and
package.
F o r m u l a t i o n F-826

SOURCE: Mona I n d u s t r i e s , Inc.: Suggested Formu a t i o n s


Car and Truck Wash Compounds 187

Car Wash w / A m p h o t e r i c

Ingredients: wt%
Water, D . I . 55.0
Sodi um T r i p o l y p h o s p h a t e 4.0
R e w o t e r i c AM 8-14 10.0
V a r o n i c DM-55 2.0
Sodi um H y d r o x i d e , 30% 9.0
W i t c o 1298SA 20.0

B1 e n d i ngProcedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between
each a d d i t i o n .

Typical Properties:
V i s c o s i t y , c p s : 290
S o l i d s : 29.5%
pH: 8 . 9
F o r m u l a 630

W i n d s h i e l d Washer C o n c e n t r a t e

Ingredients: Wt%
Water, D . I . 56.0
Isopropanol 30.0
P e t r o BAF Powder 1.o
DeSophos 5AP 0.5
EDTA, 38% 2.5

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

Use " a s i s " i n w i n t e r ; d i l u t e up t o 2 9 : l f o r summer u s e .

F o r m u l a 666

W i n d s h i e l d Washer F o r m u l a t i o n

Inqredi ents: Wt%


W i t c o n a t e 1240 1.o
Isopropanol 39.0
Water 60.0

51 e n d i ng P r o c e d u r e :
D i s s o l v e W i t c o n a t e 1240 in w a t e r , t h e n add i s o p r o p a n o l
F o r m u l a 867

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
188 Advanced Cleaning Product Formulations

Car Wash C o n c e n t r a t e w / A l c o h o l Ethoxylate

I n q r e d ie n t s :
Water, D . I . 64.9
W i t c o l a t e SE-5 8.3
W i t c o n a t e 1260 S l u r r y 16.7
P e t r o LBA L i q u i d 1.3
DeSonic 81-6 5.0
W i t c a m i d e 128T 3.8

B l e n d i n g Procedure: Blend ingredients i n t h e order l i s t e d

Typical Properties:
V i s c o s i t y , c p s : 210
A c t i v e s , %: 2 3 . 7
F o r m u l a 61 1

Car Wash C o n c e n t r a t e w / A l c o h o l Ethoxylate

Ingredients: W S
Water, D . I . 43.3
W i t c o l a t e SE-5 13.9
W i t c o n a t e 1260 S l u r r y 27.8
P e t r o LBA L i q u i d 5.0
DeSonic 81-6 7.0
W i t c a m i d e 128T 3.0

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .

T y p i c a l P r o p e r t ie s :
V i s c o s i t y , c p s : 335
A c t i v e s , %: 37.5
F o r m u l a 611

Car Wash C o n c e n t r a t e w / A l c o h o l Ethoxylate

I n a r e d ie n t s :
Water, D . I . 36.0
W i t c o l a t e SE-5 15.0
W i t c o n a t e 1260 S l u r r y 30.0
P e t r o LBA L i q u i d 6.0
DeSonic 81-6 8.0
W i t c a m i d e 128T 5.0

B l e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d .

Typical Properties:
V i s c o s i t y , c p s : 315
A c t i v e s , %: 4 3 . 0
F o r m u l a 611

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 189

C a r and T r u c k Wash F o r m u l a

Ingredients: Wei q h t %
C a l f a x DB-45 19.83
C a l s o f t L-40 24.95
T r i s o d i um Phosphate 10.02
Water 45.18

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-001-01

Car a n d T r u c k Wash F o r m u l a

Ingredients: Wei q h t %
C a l f a x DB-45 20.00
C a l s o f t L-40 25.17
D i s o d i um Phosphate 10.04
Water 44.76

Comments a b o u t t h i s f o r m u l a :
1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01.
2 . H e a t i n g i s n e c e s s a r y t o homogenize.
F o r m u l a t i o n CWC-002-01

Car Wash [Powder)

Ingredients: Wei q h t %
Sodi um T r i p o l y p h o s p h a t e 85.00
C a l s o f t F-90 5.00
Cal o x y l a t e N-9 10.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-003-01

C a r Wash ( C a l s u d s A-Based)

Inqredients: Wei g h t %
Calsuds A 50.00
C a l foam EA-603 3.00
C a l o x y l a t e N-9 2.00
Water 45.00

Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-004-01

SOURCE: B1 io t Chemi c a l Co. : Suggested F o r m u l a t i o n s


190 Advanced Cleaning Product Formulations

Car Wash and Care


Car Shampoo with Water-Repellent Effect
Ingredients: Wt%
Autopur WK 4332 45.0
Amphotensid 0 4 5.0
Water 50.0
Formula CT 0 4 - 0 3 - 0 2

Rinse-off ARent (Water-Repellent)


Ingredients: wtu/,
Autopoon GK 4004 17.0
Mulsifan RT 1 6.0
Produkt 2058 6.0
Pine oil 3.0
Butyl di glycol 8.0
Water 60.0
Formula CT 0 4 - 0 5 - 0 7

Rinse-off Aqent (Water-Repellent) Without Hydrocarbons


Ingredients: Wt%
Autopoon GK 4008 17.0
Mulsifan RT 1 6.0
Produkt 2058 6.0
Butyl di glycol 8.0
Water 63.0
Formula CT 04-05-03

Windshield-Cleaner (Summer)
Inqredi ents: Wt%
Water 67.9
Ethanol 20.0
Zusol at 1 0 0 5 / 8 5 5.2
Zusolat 1 0 0 8 / 8 5 6.9
Formula CT 0 4 - 0 6 - 0 1

Innredi ents: Wt%


Water 23.7
Zetesol NL 64.0
Zusol at 1 0 0 8 / 8 5 1.3
Isopropanol 11 . o
Formula CT 0 4 - 0 6 - 0 4
SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested Formulations
Car and Truck Wash Compounds 191

Car Wash and C a r e

Windshield-Cleaner (Winter)

Ingredients: Wtl
Water 29.5
Isopropanol 70.0
Z e t e s o l 2056 0.5
F o r m u l a CT 04-06-07

I n s e c t Remover

Inqredi ents: Wt%


S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Trilon A liquid 4.0
Monoethanol ami ne 4.0
Butyl d i g l ycol 5.0
Water 79.0
F o r m u l a CT 04-07-01

Wheel C 1 e a n e r . A 1 k a l in e
Ingredients: Wt%
Water 77.5
Tetrapotassium pyrophosphate 3.0
Lumorol 4192 10.0
Z u s o l a t 1005/85 4.0
Butyl diglycol 5.0
Orange t e r p e n e 0.5
F o r m u l a CT 0 4 - 1 1 - 0 4

T a r Remover

Inqredients: Wt%
M u l s i f a n K 326 S p e z i a l 15.0
Whi t e - s p i r i t 60.0
n-butanol 7.0
Oleic acid 3.0
Water 15.0
F o r m u l a CT 04-13-02

SOURCE: Zschimmer & Schwarz GmbH & C o . : General Formulations


192 Advanced Cleaning Product Formulations

Car Wax

Ingredient: Wt%
Part A:
Morphol ine 0.8
Water 44.2

P a r t B:
Wax S 8.0
Oleic Acid 1.o
M i n e r a l Spi r i t s 18.0
Kerosene 9.0

Part C:
M a s i l EM 250 C 10.0
M a s i l EM 1 0 , 0 0 0 C 3.0
Snow F l o s s 3.0
Kaopol it e SF 3.0
Carbopol 941 ( 1 % i n w a t e r ) As needed

Procedure:
1 . Add t h e m o r p h o l i n e t o t h e w a t e r w i t h h i g h speed m i x i n g .
2 . I n P a r t B , add t h e o l e i c a c i d , m i n e r a l s p i r i t s , kerosene,
and Wax S w i t h h i g h speed m i x i n g . Add P a r t B t o P a r t A w i t h
h i g h shear m i x i n g .
3 . Add t h e M a s i l EM 250 C and M a s i l EM 10,000 C f r o m P a r t C t o
t h e c o n c e n t r a t e w i t h s l o w m i x i n g . Add t h e Snow F l o s s and
K a o p o l i t e S F . T h i c k e n w i t h t h e Carbopol 941 s o l u t i o n .

A u t o Wipe B S h i n e P o l i s h

Ingredient;
Part A:
M a s i l SF 100 3.5
A-C 617A 2.0
Oleic Acid 1.5
M i n e r a l O i 1 , 70 SUS 5.6

Part 0 :
Morphol ine 1.4
Carbopol 934 0.2
Triethanolamine 0.2
Water 85.6

Procedure:
1 . Add t h e i n g r e d i e n t s i n P a r t A as l i s t e d and h e a t t o 9OC.
2 . F o r P a r t B, h e a t t h e w a t e r t o 85C. D i s p e r s e t h e Carbopol 934
i n t h e w a t e r . When c o m p l e t e l y d i s s o l v e d , add t h e t r i e t h a n o l -
amine. Then, add t h e m o r p h o l i n e .
3. Add P a r t A t o P a r t 0 and b l e n d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


Car and Truck Wash Compounds 193

Concentrated T r a f f i c F i l m Removers

Two f o r m u l a t i o n s were d e v e l o p e d w h i c h c o n t a i n 50% t o t a l w a t e r ,


i n c l u d i n g t h e w a t e r i n t h e sodium m e t a s i l i c a t e p e n t a h y d r a t e . One
c o n t a i n s n o n i o n i c , t h e o t h e r h a s no n o n i o n i c b u t has more AO-14-2
and A l k a l i S u r f a c t a n t , t h e c o m b i n a t i o n o f w h i c h s h o u l d do as w e l l
as t h e n o n i o n i c f o r h a r d s u r f a c e c l e a n i n g .

Mix i n t h e order given:


Formula 1:
Component: Wt%
Water 22.00
Versene 1 0 0 38.00
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 8.00
Tomah A l k a l i S u r f a c t a n t 16.00
Tomah AO-14-2 8.00
Tomah Q-17-2 8.00

% anhydrous b u i l d e r : 19.00
S u r f a c t a n t / b u i l d e r r a t i o : 1.68

Mix i n t h e order given:


Formula 2 :
Component: Wt.%
Water 36.20
Versene 100 19.70
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 4.10
Tomah A l k a l i S u r f a c t a n t 10.00
Tomah AO-14-2 10.00
Tomah Q-17-5 10.00
Noni o n i c NP-9.5 10.00

% anhydrous b u i l d e r : 9.82%
S u r f a c t a n t / b u i l d e r r a t i o : 4.07

N o t e t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y a b o u t
57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s
a b o u t 38% t e t r a s o d i u m EDTA on an a n h y d r o u s b a s i s . Thus t h e s e
f o r m u l a t i o n s a r e a b o u t 50% t o t a l w a t e r when c a l c u l a t e d on an
a n h y d r o u s b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an
a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t .
Anhydrous sodium m e t a s i l i c a t e and a n h y d r o u s t e t r a s o d i u m EDTA
a r e r e a d i l y a v a i l a b l e ; a n h y d r o u s a m p h o t e r i c s and amine o x i d e s
are not.
These f o r m u l a t i o n s were made up and f o u n d t o b e f r e e z e - t h a w
s t a b 1 e.
F o r m u l a 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and
t e s t e d b y s p r a y i n g on a d i r t y c a r . It was compared w i t h F o r m u l a -
t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g -
n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c
d i d n o t adversely a f f e c t t h e performance o f t h e concentrated
f o r m u l a t i on.
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
194 Advanced Cleaning Product Formulatioris

Foamy B r u s h Car Wash, Liquid

Inqredients: Wtg
Water, D . I . * 79.75
C a u s t i c Soda, 50% 1.40
W i t c o 1298SA 5.00
W i t c o l a t e SE-5 7.00
P e t r o BAF L i q u i d 3.00
W i t c a m i d e 128T 3.00
Formal i n 0.10
Sodi um C h l o r i d e 0.75

Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d . Sodium C h l o r i d e i s
used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t .

T y p i c a l P r o p e r t i es :
S p e c i f i c G r a v i t y : 1.015
Wt./Gal. l b s . : 8.46
pH, a s i s : 9 . 8
V i s c o s i t y , cps: 410

D i l u t i o n R a t i o a t Wand=l : 4 0
* I f u n s o f t e n e d t a p w a t e r i s used, add 0 . 2 5 % l i q u i d EDTA, 40%
t o counteract hardness.
F o r m u l a 621

Low C o s t Car=

Ingredients: Wt%
Water. D . I . 89.9
P e t r o LBA Powder 1 .o
W i t c o l a t e SE-5 6.0
W i t c a m i d e 128T 3.0
Formal in 0.1
Sodi um C h l o r i d e 4.s.
Perfume, Dye 4.s.

Blending Procedure:
Blend t h e i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t t h e
p H = 7 . 5 - 8 . 0 . The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y
o f the f i n a l product.
F o r m u l a 609

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 195

G e n e r a l Purpose C a r Wash

T h i s i s a c o p i o u s - f o a m i n g , a l l - p u r p o s e c a r wash f o r m u l a t e d t o
b e s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d
g r i m e and o t h e r s o i l s .

Insredient : w b
D e i o n i z e d Water 50.0
Mazon 98 9.5
Macol TD-3 1.5
W i t c o l a t e WACLA 2.5
Mazamide 80 3.0
Macol 48 1.o
Triethanolamine, 85% 1.5
D e i o n i z e d Water 31 . O

pH ( a s i s ) : 8 . 5 - 9 . 5
Appearance: C l e a r , l i g h t - y e l l o w liquid
S p e c i f i c G r a v i t y : 1.02

Procedure:
Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and
s t a r t slow a g i t a t i o n (excessive a g i t a t i o n w i l l produce a
f o a m i n g p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r
l i s t e d and m i x u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2
ounces p e r g a l l o n o f warm w a t e r .
F o r m u l a t i o n CA-103

L i q u i d Car Wash

Ingredient: NtS
Water 34.0
W i t c o n a t e 60 T L i q u i d 30.0
Macol OP-10 SP 10.0
Mazamide 80 6.0
Hexyl Carbi t o 1 10.0
Methanol 10.0

Procedure:
Add i n g r e d i e n t s i n o r d e r a s l i s t e d .

~ B o a t Wash & CarPCleaner


~~ ~~~~

Ingredient: vvt%
Water 39.0
Mazamide 80 11 . o
Macol NP 9 . 5 5.0
W i t c o n a t e 60 T L i q u i d 45.0

Procedure:
Add i n g r e d i e n t s i n o r d e r as l i s t e d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s


196 Advanced Cleaning Product Formulatiom

Heavy D u t y T r u c k Wash, L i q u i d

Inqredients:
Water, D . I . 70.0
T r i s o d i um Phosphate, C r y s t a l 2.0
C a u s t i c Soda Beads 2.0
W i t c o 1298 S o f t A c i d 10.0
P e t r o BAF L i q u i d 3.0
Sodium S i l i c a t e 40 Be' ( S t a r ) 3.0
W i t c o l a t e SE-5 3.0
E t h y l e n e G l y c o l M o n o b u t y l E t h e r (EB) 3.0
Emcol 6744 4.0

Blending Procedure:
B l e n d i n g r e d i e n t s in o r d e r 1 i s t e d .

Typical Properties:
S p e c i f i c G r a v i t y : 1.042
Wt./Gal. l b s . : 8.69
pH, a s i s : 1 2 . 7

D i l u t i o n R a t e : D i l u t e 1 : 4 0 a t Wand
F o r m u l a 603

Heavy D u t y T r u c k Wash, Powder

Inqredients: wtd/,
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 47.25
Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y 55.00
DeSophos 5AP 2.90
DeSonic 9N 7.50
Sodium M e t a s i l i c a t e , Anhydrous 5.00
Sodium S u l f a t e ( S a l t Cake) 10.00
C a u s t i c Soda Beads 2.30
Dye* 0.05

B1 e n d i ng P r o c e d u r e :
P r e m i x Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos
5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n a p p e a r a n c e . Add
DeSonic 9 N w h i l e m i x i n g . M i x u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5
m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda
beads.
* I f d y e i s used, m i x w i t h t h e DeSonic 9N.
F o r m u l a 604

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 197

Premium Car Wash C o n c e n t r a t e

Ingredients: Wt%
Water, D . I . 11.7
Ethanol 5.9
Varox 1 7 7 0 17.6
W i t c o n a t e AOS L i q u i d 46.8
W i t c o l a t e SE-5 17.6

B l e n d i ng P r o c e d u r e :
Add a l l i n g r e d i e n t s e x c e p t W i t c o l a t e SE-5, i n o r d e r shown and
d i s s o l v e completel’y between each a d d i t i o n . Add W i t c o l a t e SE-5
l a s t i n s m a l l a l i q u o t s a l l o w i n g c o m p l e t e d i s s o l u t i o n between
additions.

T y p i c a l P r o p e r t i es :
V i s c o s i t y , c p s : 160
S o l i d s : 35.4%
pH: 8.4
Formula 629

Car Wash

Ingredients: Wt%
Water 91.67
T e t r a p o t a s s i um Pyrophosphate, 60% 3.33
W i t c a m i de 6445 5.00

51ending Procedure: Blend i n g r e d i e n t s i n o r d e r l i s t e d .

T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 2100
S o l i d s : 6.8%
pH, as i s : 9 . 3
Formula 615

A u t o Shampoo C o n c e n t r a t e

P n g r e d ie n t s : Wt%
Water, D . I . 80.0
R e w o t e r i c AM KSF-40 15.0
W i t c o l a t e SE-5 5.0

Blending Procedure:
Add in g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

Typical Properties:
V i s c o s i t y , cps: 4.0
S o l i d s : 9.0%
ptl: 9 . 5
Formula 628
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
198 Advanced Cleaning Product Formulations

T o u c h l e s s V e h i c l e Wash D e t e r a e n t
l Z e r o Phosphate, Powder)

Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal surface, Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on
Composition: \nrt36
Sodium C a r b o n a t e 25-30
M e t s o Beads 2048 20-25
*Sodium P o l y a c r y l a t e (92% s o l i d s ) 1.0- 3.0
Surfactant 5-1 0
T u r b o b r i t e A1 umi n o s i 1 ic a t e 25-35
F i 1l e r s Balance
D i l u t i o n : 1.0-2.0% by weight ( 0 . 1 - 0 . 2 pounds/gallon)
Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o
t h e s p r a y n o z z l e . M i x powder d e t e r g e n t i n t a n k and m e t e r i n t o
c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f
T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash
systems f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s ,
and haze f r o m body p a r t s and w i n d s h i e l d s .
C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep T u r b o b r i t e
suspended.

V e h i c l e Wash D e t e r g e n t (Low pH)


( Z e r o Phosphate. Powder)

Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s ,


road f i l m .
Surface-Painted metal surface, Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Dry blend/Agglomeration
Composi t i on : Wt%
Sodium C a r b o n a t e 27.9
B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1 i c a t e 21 . o
* A c u s o l 445ND Sodi um Pol y a c r y l a t e (92% s o l id s ) 3.0
**Liquid Nonionic Surfactant 12.0
V a l f o r 100 Z e o l i t e A 36.1
* D i l u t i o n : 1 . 5 % by w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n )
Add 0 . 1 2 5 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o
t h e s p r a y n o z z l e . D i s s o l v e powder d e t e r g e n t i n t a n k and m e t e r
i n t o c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g
e f f e c t o f V a l f o r 100 i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e
s p r a y wash s y s t e m s f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t -
i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s .
C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep V a l f o r 100
suspended i n s o l u t i o n .
* Rohm & Haas
** Low Foam: Rhone-Poulenc A n t a r o x BL-330 ( 3 moles E O )
H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7

SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide


Car and Truck Wash Compounds 199

Truck/Bus Wash

Components: % by Weight
Burco TME 7
B u r c o s o l v TM 5
Neodol 91-6 20
TEA 85% 5
Burcene 1 0 0 2
Water 8 a l ance

D i l u t e 50:l t o 1OO:l depending on degree o f s o i l t o be removed

Economy Truck/Bus Wash

Components: % by Weight
Water 76
Burco TME
Meodol 1.5
C i t r i c A c i d L i q u i d 50%
KOH. 45%
Ammonyx LO
TEA 85%

D i l u t e 20:l t o 50:l depending on degree o f s o i l t o be removed.

SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s

Car Shampoo

In g r e d ien t s : % by Wei a h t
Z e t e s o l 2056 15.0
Lumo WW 75 10.0
Z u s o l a t 1008/85 3.0
P u r t o n CFD 1. o
Water 75.0
Formula D 1 1 / 1 0

Car Wash and Wax Shampoo

Ingredients: % by Weiqht
Zusol a t 1008/85 10.0
Wachsemul s i on 1864 10.0
Isopropanol 2.0
Water, p r e s e r v a t i v e q . s . t o make 1 0 0 . 0
Formula D 12/2

SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested F o r m u l a t i o n s


200 Advanced Cleaniris Product Formulations

V e h i c l e Wash D e t e r g e n t
e h o s p h a t e . Powder1

Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s ,


road f i l m
Surface-Painted metal surface, Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y
Manufacture-Dry blend/Agglomeration
Composition A : We9/0
Metso Beads 2048 20.0
*STPP 40.0
*TSP 5.0
*Sodi um C a r b o n a t e 20.0
**Sodium A 1 k y l a r y l Sul f o n a t e Powder (90%) 5.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-10; 6 Moles EO) 10.0
Composition 8: Wt%
Metso Pentabead 20 30.0
*STPP 44. 0
*Sodi um C a r b o n a t e 10. 0
CMC 1 0
**Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 5 0
* * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 7-8 Moles EO 5 0
*****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 Moles EO 5 0
Use D i l u t i o n : 1 . 5 % b y w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n )
D i s s o l v e i n s t o c k t a n k and meter i n t o wash system. Compos P i on
6 can be u t i l i z e d i n h i g h p r e s s u r e s p r a y carwash systems and
s u p p l i e s adequate s o i l r e m o v a l .
* FMC
** Witco
*** Rhone-Poulenc Rhodasurf 91-6
**** Rhone-Poulenc I g e p a l CA-620
***** Rhone-Poulenc I g e p a l CA-520

V e h i c l e Wash D e t e r g e n t
( L i q u i d , low foam)

Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s ,


road f i l m
Surface-Painted metal surface, Polymeric
A p p l i c a t i o n Method: H i g h p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : Wt%
Water 79.0
Metso Beads 2048 2.0
*Sodium P o l y a c r y l a t e (40%) 5.0
**Sodium X y l e n e S u l f o n a t e (40%) 8.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 3.0
* * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles € 0 ) 3.0
Use D i l u t i o n : 10% bw ( 1 3 o z / g a l l o n )
* Rhone-Poulenc C o l l o i d 226/35 (40%)
** Stepan, W i t c o
*** Rhone-Poulenc R h o d a s u r f 91-6
**** Rhone-Poulenc Rhodasurf A-24
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Car and Truck Wash Compounds 201

V e h i c l e Wash D e t e r g e n t (Low PH)


( Z e r o Phosphate, L i q u i d )

Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal s u r f a c e , Polymeric
Appl ic a t i on Method-Hi gh p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Mix t a n k w i t h p r o p e l l e r spray
Composi t i on : Wt%
Water 51.66
Carbopol 674 0.5
D L i q u i d Sodium S i l i c a t e 8.1
*Acusol 445N Sodi um P o l y a c r y l a t e (45% s o l i d s ) 1.84
Sodium Carbonate 9.1
T u r b o b r i t e A 1 umi n o s i 1 ic a t e 24.5
* * L i q u i d Nonionic Surfactant 4.3
D i l u t e l i q u i d d e t e r g e n t w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 64
g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system.
M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s
e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , w a t e r
d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d .
* Rohm & Haas
** Low Foam: Rhone-Poulenc A n t a r o x BL-240
H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7

T o u c h l e s s V e h i c l e Wash B o o s t e r / A d d i t i v e
L Z e r o Phosphate, L i q u i d )

Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal s u r f a c e , Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: Wt%
T u r b o b r i t e L (25 w t . % a c t i v e T u r b o b r i t e A l u m i n o s i l i c a t e
S1u r r y ) 100.0
D i l u t e l i q u i d T u r b o b r i t e L a t h i g h p r e s s u r e pump w i t h w a t e r
( 1 g a l l o n d e t e r g e n t : 128 g a l l o n s w a t e r ) and d e l i v e r t o h i g h
p r e s s u r e s p r a y wash system.
M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e
i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c l a y s ,
c a r b o n b l a c k , b r a k e d u s t ) , w a t e r d e p o s i t s , and haze f r o m body
p a r t s and w i n d s h i e l d .
T u r b o b r i t e L can be used as an a d d i t i v e o r b o o s t e r f o r con-
v e n t i o n a l t o u c h l e s s , h i g h p r e s s u r e carwash o r f l e e t w a s h d e t e r -
gents.
O r make a d e t e r g e n t by b l e n d i n g T u r b o b r i t e L w i t h 1-2% low-
foaming n o n i o n i c s u r f a c t a n t t o make f o r b e s t c l e a n i n g r e s u l t s .
D i l u t e T u r b o b r i t e L / s u r f a c t a n t b l e n d a t h i g h p r e s s u r e pump w i t h
w a t e r (128: 1 ) .
T u r b o b r i t e L a l s o works i n waxes, p o l i s h e s , and o t h e r d e t a i l -
ing p r o d u c t s .

SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
17. Whitewall Tire Cleaners

202
Whi tena 1 1 Ti.r&C!ean.ey
1z e ro .P.b-s phate -?.w&cl

Soil-Clay, p a r t i c u l a t e , o i l , grease
Surface-Whitewal 1 t i r e s
Application Method-High pressure s p r a y / b r u s h / w i p e
M a n u f a c t tire - D r y b 1 end/Agg 1 o m e r a t i On

c_q.m3osi t i . o n l Nt%
Valfor 100 Zeolite A 35.0
* A c u s o l 4 4 5 N D Sodium P o l y a c r y l a t e ( 9 2 % Solids) 2.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) 8.0
Sodium A l k y l a r y l S u l f o n a t e 10.0
M e t s o Beads 2 0 4 8 35.0
Sodium Carbonate 12.0
* Rohm & Haas
** Rhone-Pou 1 e n c R h o d a s u r f 91 - 6

wi j.t.ew a
n-T i.r,e C L Y C ~e 1:
1Pbes?batePowde.!’l
Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e
Surface-Whi tewal1 t i r e s
Application M e t h o d s - H i g h pressure spray/brush/wipe
Manufacture-Dry blend

Cs-mmeo s.i.t j P.V :. Y!%.t


*STPP 45.0
**tiquid Noninnic Surfactant (C9-Cll; 6 nroles € 0 ) 5.0
GTSP 10.0
Sodium A l k y l a r y l Sulfonate 10.0
Met50 B e a d s 2 0 4 8 30.0
* FMC
* a R h o n e - P o u l e n c Rhodasurf 91 -6

re,&!ea_n_er
WRitewal..1..Ti
(.Lictuj.d).
Soil-Clay, p a r t i c u l a t e , o i l , p r e a s e
Surface-Whi tewall tires
A p p l i c a t i o n Method-High p r e s s u r ’ e s p r a y / b r u s h / w i p e
M a n u f a c t u r e - M i x t a n k w i t h propeller s t i r r e r

C o m q . ~!.f.bn:
S flL?b
Water 70.0
Potassium H y d r o x i d e 145%) 16.0
N C l e a r o r S t a r Sodium Silicate 10.0
S o d i uni A 1 k y l a r y l Sulfonate ( 6 0 % ) 2.0
* L i q u i d N o n i o n i c S u r f a c t a n t (CS-Cll; 6 m o l e s E O ) 2.0
* R h o n e - P o u l e m R h o d a s u r f 91 - 6

S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
18. Miscellaneous

204
Miscellaneous 205

A i r c r a f t Cleaner
(Reduced Phosphate. Powder)

Soi 1 - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i 1 and grease


Surface-Aluminum, m e t a l
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Dry b l e n d / A g g l o m e r a t i on

Composi t i on : Wt%
Metso Pentabead 20 30.0
V a l f o r 100 Z e o l i t e A 30.0
Ammoni u m B i f 1u o r ide 8.0
TSPP 20.0
*Sodi um A1 k y l naphtha1 ene Sul f o n a t e 8.0
**Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 4.0

Use D i l u t i o n : 1.5-6.096 bw (2-8 oz/gallon)

* Rhone-Poulenc S u p r a g i l N K
** Witco

N o t e : C o n s t a n t a g i t a t i o n i s r e q u i r e d i n s t o c k t a n k t o keep
V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t
Carbopol 647 (BFGoodrich) as a suspending a g e n t .

A i r c r a f t 61 eaner
(Phosphate, Powder)

S o i l - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i l and grease
Surface-Metal
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on

Composi t i on : Wt%
Metso Pentabead 20 30.0
*STPP 30.0
Ammonium B i f l u o r i d e 8.0
*TSPP 20.0
**Sodium A1 k y l n a p h t h a l e n e S u l f o n a t e 8.0
***Sodi um A1 k y l a r y l Sul f o n a t e Powder (90%) 4.0

Use D i l u t i o n : 1 . 5 - 6 . 0 % bw ( 2 - 8 o z / g a l l o n )

* FMC
** DeSoto, Inc.
*%Xc Witco

OURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
206 Advanced Cleaning Product Formulations

A u t o Care: I n t e r i o r / E x t e r i o r Rubber B V i n y l P r o t e c t a n t

F u n c t i ons 8 Benef it s :
Pemul an 1622 :
*Primary e m u l s i f i e r f o r s i l i c o n e o i l
*NO s u r f a c t a n t s and no s o l v e n t s r e q u i r e d e q u a l s z e r o VOC
*Imparts y i e l d value f o r v e r t i c a l c l i n g
* E x c e l l e n t w e t t i n g f o r " s p r a y and no-wipe" a p p l i c a t i o n s
*Improved d u r a b i l i t y and w a t e r - r e s s t a n c e

Good-Rite K-752:
* R e d u c t i o n i n emu1s i on v i s c o s i t y w t h o u t l o s s i n s t a b i l i t y

I n q r e d ient : Wtl
D I water 78.55
Pemulen 1622* 0.20
1000 c S t s i l i c o n e o i l * * 20.00
DC Q2-5211*** 0.50
T r i e t h a n o l a m i n e (99%) 0.25
Good-Rite K-752 (63%)**** 0.50

* E m u l s i f i e r : BFGoodrich
* * P r o t e c t a n t : DC 200 F l u i d : Dow C o r n i n g
* * * S u p e r - w e t t i n g a g e n t : DC (12-5211: Dow C o r n i n g
* * * * V i s c o s i t y r e d u c t i o n : BFGoodrich

Physical Properties:
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP
P r o d u c t pH: 5.5-6.0
P r o d u c t C l a r i t y : Opaque

Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n
t h e Pemulen r e s i n i n t o t h e D I w a t e r . Mix t h e s l u r r y f o r app-
r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous.
2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n .
3. Add t h e DC Q2-5211 s u p e r - w e t t i n g a g e n t w i t h moderate a g i t a t i o n
4 . Add t h e t r i e t h a n o l a m i n e w i t h moderate a g i t a t i o n .
5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 p o l y m e r . The
v i s c o s i t y w i l l d r o p f r o m a b o u t 3,000 CP t o <200 CP w i t h t h i s
addition.
6. A d j u s t t h e pH w i t h a d d i t i o n a l t r i e t h a n o l a m i n e , i f n e c e s s a r y .
7 . Add f r a g r a n c e and c o l o r , as d e s i r e d .

SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-512


Miscellaneous 207

Boat Polish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase separ-
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Inqredi ent : Wt%


#I Water 37.80
Carbopol EZ-2 ( 1 ) 0.20
Morphol ine 2.50
SF96 S i l i c o n e F l u i d (350) ( 2 ) 2.00
V i s c a s i l F l u i d (10,000) ( 2 ) 1.50
Oleic Acid 2.50
Mineral S p i r i t s 10.00
Hoechst Wax E (3) 6.00
M i n e r a l Spi r i t s 5.00
SF1 706 React ive A m i ne Polymer 1.50
Kaopolite kaolin clay (4) 8.50

Physical P r o p erties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 7,200 cps
P r o d u c t pH: 9.00
P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) General E l e c t r i c
( 3 ) Hoechst Celanese
(4) Kaopolite, Inc.

Procedure:
4 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r by s i m p l y "dumping" i t
i n . The polymer w i l l wet o u t i n a few m i n u t e s .
2 . Add t h e m o r p h o l i n e , m i x w i t h good a g i t a t i o n . Heat t o 60-65C.
3 . I n a s e p a r a t e v e s s e l , combine t h e s i l i c o n e f l u i d , V i s c a s i l ,
o l e i c a c i d , and t h e wax i n t h e m i n e r a l s p i r i t s . Heat t o 90-95C
u n t i l t h e wax m e l t s and t h e m i x t u r e appears homogeneous. Add
to t h e above m i x t u r e w i t h good m i x i n g .
4 . When homogeneous, c o o l t o 60-65C.
5. I n a s e p a r a t e v e s s e l , combine t h e m i n e r a l s p i t i t s and t h e
r e a c t i v e amine p o l y m e r . Add t o t h e above m i x t u r e w i t h h i g h
shear m i x i n g .
6. S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous.

Total Actives:
T o t a l Wax : 1.50
Total Silicone Fluid: 4.50
R e a c t i v e A m i ne Polymer : 2.00
Mineral S p i r i t s : 13.00
Abrasive: 12.00

$ ~ BFGoodrich
~ ~S p e c i a~l t y Chemicals:
~ : DET-520
208 Advanced Cleaning Product Formulations

C o n c r e t e Cleaner/Deqreaser

I n g r e d ie n t s : WtB
Water, D . I . 81 . O
Sodium T r i p o l y p h o s p h a t e 2.0
T r i s o d i um Phosphate 1.o
Varami de A-83 6.0
V a r o n i c DM55 10.0

B l e n d i n g Procedure:
Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t ion.

T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 0
S o l i d s : 19.0%
Formula 937

Garage F l o o r C1eaner

I n s r e d ie n t s : Wt%
Water 82.0
T r i s o d i um Phosphate 8.0
Emphos PS-236 4.0
W i t c o n a t e 45 L i q u i d 6.0

B l e n d i n g Procedure:
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A l l o w f o r complete
b l e n d i n g between a d d i t i o n s .
Formula 941

A c i d Rust Remover

I n q r e d ients: \Me%
Water, D . I . 81 . O
Phosphoric A c i d , 86% 15.0
C i t r i c Acid 3.0
Varox 365 1.o

B l e n d i n g Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .

T y p i c a l P r o p e r t ies :
V i s c o s i t y , cps: 4
S o l i d s : 16.2%
pH: 1.3
Formula 1116

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Miscellaneous 209

Concrete/Driveway Cleaners

F o r l e a f and o t h e r t a n n i n s t a i n s - u s e as i s . Wet s p o t .
S p r i n k l e FB Sodium P e r c a r b o n a t e o n t o s p o t . S c r u b i n and r i n s e
w i t h hose when s p o t i s removed.

For O t h e r S t a i n s

Component: Wt%
Soda Ash (Dense) 25
B r i t e s i 1 H-24 15
TSP Anhydrous 20
B u r c o s p e r s e AP Powder 5
Dry S u r f a c t a n t * 5
FB-Sodi um P e r c a r b o n a t e 30

Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . S c r u b i n and a l l o w t o
s t a n d . R i n s e w i t h hose.
*Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r
Sodium Cocoyl T a u r a t e s can b e used.

SOURCE: B u r l i n g t o n Chemical C o . : Suggested F o r m u l a t i o n

Neavv D u t y C o n c r e t e C l e a n e r ( P h o s p h a t e F r e e ) F o r m u l a 1C

Wt%
Water, D . I . 75.0
EDTA, 38% 0.5
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 2.0
Sodium C a r b o n a t e (Soda Ash) 1.5
W i t c a m i d e S-780 6.5
W i t c o n o l NP-120 1.5
B u t y l Cel l o s o l v e 3.0
Mineral S p i r i t s 4.0
KOH, 45% 2.5
W i t c o n a t e SXS L i q u i d 1.5
Pine O i l 2.0

Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d , m i x i n g w e l l a f t e r each
addition.

Typical Properties:
S p e c i f i c G r a v i t y : 1 .022
Wt./Gal. I b s . : 8.52
pH, as i s : 1 3 . 1 8
3 Freeze/Thaw C y c l e s : Passed
1 Week @ 52C: Passed
4 Weeks Room Temp: Passed
S o l i d s : 13.5%
Use D i l u t i o n : As s t r o n g as needed, d e p e n d i n g on t y p e o f s o i l .

SOURCE: Witco Corp.: F o r m u l a 949


210 Advanced Cleaning Product Formulations

__
V i n y l Dressing

In g r e d i& ~-
Wt%
Part A:
M a s i l EM 250 C 30.0
Dei o n i zed Water 30.0

P a r t 8:
M a c o l NP 9 . 5 1.5
G1 y c e r i n e 1.5
D e i o n i z e d Water 36.9
Sodium B e n z o a t e 0.1

Procedure:
1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and s t a r t
g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r s o a s n o t t o b r e a k t h e
emu1 s i o n .
2 . I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol NP 9 . 5 a n d
g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l
components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h
e y e s " . Charge t h e sodium b e n z o a t e a n d m i x u n t i l d i s s o l v e d .
3 . Under g e n t l e a g i t a t i o n , c h a r g e P a r t B t o P a r t A . C o n t i n u e
m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s
d e s i g n e d t o be u s e d " a s i s " as a d r e s s i n g f o r r u b b e r and v i n y l
p r o d u c t s . I f d e s i r e d , UV a b s o r b e r s a n d o t h e r components may
be added t o t h e f o r m u l a t i o n .
F o r m u l a t i o n SV-101

Inqredient: &%
M a s i l EM 1 0 , 0 0 0 C 10.0
M a s i l EM 2 5 0 C 18.0
Macol NP 9 . 5 2.0
Glycerine 1.5
B a r q u a t MB-50 0.1
Water 68.4

Procedure:
Add t h e s i l i c o n e e m u l s i o n t o a b l e n d e r . S l o w l y a d d a p o r t i o n
o f t h e w a t e r and a g i t a t e . Add t h e M a c o l NP 9 . 5 and g l y c e r i n e .
M i x f o r 10 m i n u t e s . Add t h e b a l a n c e o f t h e w a t e r a n d m i x f o r 15
minutes.

SOURCE: PPG I n d u s t r i e s , Inc.: Suggested F o r m u l a t i o n s


Section Ill
demarked Raw Materials

211
212 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


A-C 617A Polyethylene Allied

Acid Thickener Cationi c surfactant Tomah

A c r y s o l AS€-108 P o l y a c r y l a t e (40%) Rohm&

Actinol FA-I Tall o i l f a t t y acid A r i zon

A c u s o l 445ND Sodium p o l y a c r y l a t e (92% s o l i d s ) Rohm&

Acusol 479ND Sodium p o l y a c r y l a t e RohmB

Adogen 66 Anti-static agent Witco

A 1 ip a l CO-128 Anionic surfactant Rho ne -

A1 ip a l CO-436 Anionic surfactant Rhone-

Alkylaryl S u l f o n i c A c i d (98%) Witco

Alpha-Step MC-48 Alpha s u l f o methyl e s t e r Stepan

A 1 p h a - S t e p ML-40 Alpha s u l f o methyl e s t e r (37%) Stepan

Ammonyx LO Amine o x i d e Stepan

AMP-95 A m i nomethyl p r o p a n o l Angus

A m p h o t e n s i d 84 Amphoteric s u r f a c t a n t Zschim

A m p h o t e r i c SC A m p h o t e r i c (35% a c t i v e ) Tomah

A m p h o t e r i c TC Hydrotrope Tomah

A n t a r o n FC-34 Amphoteric s u r f a c t a n t Rhone-

A n t a r o x BL-240 L i q u i d nonion c s u r f a c t a n t Rhone-

A n t a r o x BL-330 L i q u i d nonion c s u r f a c t a n t Rhone-

A n t a r o x LF-330 Surfactant Rhone-

Aquamoll i n BC Powder

Aristonate M P e t r o l e u m s u l f o n a t e (61%) Pi l o t

A r i s t o n a t e M-LF Petroleum s u l fonate Pilot

A r o m a t i c 150 Sol v e n t Exxon


Trademarked Raw Materials 213

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Autopoon GK4004 Blend o f s u r f a c t a n t s Zschim

Autopoon GK4008 Blend o f s u r f a c t a n t s Zschim

A u t o p u r WK4332 Blend o f s u r f a c t a n t s Zschim

Avanel S-30 Anionic surfactant PPGMaz

Avanel S-70 Sodium l i n e a r a l k y l p o l y e t h e r PPGMaz

Avanel S-74 Anionic surfactant PPGMaz

5;mrlOX 12 Amine o x i d e (30%) Lonza

B a r q u a t NIB-50 Q u a t e r n a r y ammonium compound Lonza

BiQSOft D-62 Sodium a l k y l benzene s u l f o n a t e ( 6 0 % ) Stepan

B i o s o f t s-100 Alkylbenzene s u l f o n i c a c i d , linear Stepan

B i o t e r g e AS-40 Sodium o l e f i n s u l f o n a t e (40%) Stepan

B i o t e r g e PAS-8S P r i m a r y a l k a n e s u l f o n a t e (40%) Stepan

83-120 b q u i d Sodi um S i 1 ic a t e PO

B r i j 96 Surfactant ICI
B r i t e s i 1 c20 Hydrous sodium p o l y s 1 i c a t e PQ

B r i t e s i I H20 Hydrous sodium p o l y s 1 ic a t e PQ

B r i t e s i 1 H24 Hydrous sodium p o l y s 1 i c a t e PQ

Burcene I00 Burl i n

Burco BSGH-270 Proprietary t e x t i l e auxiliary Burl i n

Burco WCS-SONF Proprietary t e x t i l e auxiliary Burl i n

NPS-225 Proprietary t e x t i l e auxiliary Burl i n

NPS-816 Proprietary t e x t i l e auxiliary Burl i n

SZS Proprietary t e x t i l e auxiliary Burl i n

LAF-6 Proprietary t e x t i l e auxiliary Burl i n


21 4 Advanced Cleaning Product Formulations

RAW M A T E R I A L CHEMICAL D E S C R I P T I O N SOURCE


B u r c o l 117 Proprietary t e x t i l e auxiliary Burli n

B u r c o l i t e BSGH-255 Burlin

B u r c o s o l v TM Water s o l u b l e s o l v e n t m i x t u r e Burli n

B u r c o s p e r s e AP Powder S o d i um p o l y a c r y l a t e B u r l in

B u r c o s p e r s e LP Sodium p o l y a c r y l a t e s o l u t i o n Burli n

B u r c o s p e r s e SP-60 Sodium p o l y a c r y l a t e B u r l in

B u r c o t a s e LL-100 P r o p r i e t a r y d e t e r g e n t enzyme Burl i n

B u r c o t a s e EP-60 P r o p r i e t a r y d e t e r g e n t enzyme B u r l in

B u r c o t a s e SL-160 P r o p r i e t a r y d e t e r g e n t enzyme Burli n

B u r c o t e r g e DG-40 Detergent concentrate Burlin

B u r c o TME Proprietary t e x t i l e a u x i l i a r y Burl i n

B u r c o t r o p e 1250 Burlin

B u r c o w h i t e BBH-20 B u r l in

Burdac-114

Butyl Carbi t o 1 I n d u s t r i a1 s o l v e n t UnCarb

Butyl Cellosolve Ethylene g l y c o l monobutyl e t h e r UnCarb

Calamide C C o c o n u t d e r i v e d ami de Pilot

C a l a m i d e CW-100 Coconut d i e t h a n o l a m i d e 100% Pilot

C a l a m i d e CWT Super ami de Pilot

C a l a m i d e SM Non-DEA 1 iq u i d ami d e Pilot

C a l f a x DB-45 Sodium a l k y l ( b r a n c h e d ) d i p h e n y l Mona


o x i d e d i s u l f o n a t e 45%

C a l f a x 1OL-45 S o d i um a1 k y l ( 1 in e a r ) d i p h e n y l Mona
o x i d e d i s u l f o n a t e 45%

C a l foam EA-603 Liquid detergent Pilot


Trademarked Raw Materials 215

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Cal foam ES-303 Sodium l a u r y l e t h e r s u l f a t e (30%) Pilot

Cal foam SLS-30 Sodium l a u r y l s u l f a t e 30% Pi l o t

Gal i mu1 se PRS Emu1s i f ie r Pilot

Caloxylate M-9 Nonyl p h e n o l e t h o x y l a t e ( 9 M o l e EO) P i l o t

C a l s o f t F-90 L i n e a r a1 k y l a t e s u l f o n a t e Pilot

C a l s o f t L-40 Sodi um 1 inear a1 k y l benzene Pilot


s u l f o n a t e 1 i q u i d 40%

C a l s o f t L-60 Sodi um 1 inear a1 k y l benzene Pilot


s u l f o n a t e p a s t e 60%

Cal s o f t LAS- 99 L i n e a r a1 k y l benzene s u l f o n C Pi l o t


a c i d 99%

C a l s o f t T-60 TEA l i n e a r a l k y l benzene su f o n a t e Pilot


60%

Calsuds A Conc. b l e n d o f a n i o n i c d e t e r g e n t s Pilot


and amides

Calsuds CD-6 M o d i f i e d c o c o n u t diethanolamidelOO% P i l o t

Calsuds 8 1 Conc. b l e n d o f a n i o n i c d e t e r g e n t s Pilot


and amides

Carbi t o 1 Solvent I n d u s t r i a l solvent UnCarb

Carbopol 672 T h i c k e n i n g agent BFGood

Carbopol 674 T h i c k e n i n g agent BFGood

Carbopo 1 676 T h i c k e n i n g agent BFGood

Ca r b o p o l 69 1 Suspension a i d BFGood

Ca rbopo 1 934 Thickening agent BFGood

Carbopol 940 Thickening agent BFGood

Carbopol 941 T h i c k e n i n g agent BFGood

Carbopol ETD 2623 Resin v i scosi t y m o d i f i e r BFGood

Ca rbopol ETD 2691 Resin v i s c o s i t y m o d i f i e r BFGood


216 Advanced Cleaning Product Formulations

RAW MATERIALS CHEMICAL DESCRIPTION SOURCE:


Carbopol EX-473 (30%) V i s c o s i t y modi f i e r BF600d

Carbopol EZ-2 V i scosi t y modi f ie r BFGood


C a r d i s 36 Wax O x i d i z e d m i c r o c r y s t a l l i n e wax Petrol

CDB C l e a r o n C h l o r i n a t e d is o c y a n u r a t e 01 i n

C o l l o i d 225/35 P o l y a c r y l a t e (40%) RAOPa@

Col 1o i d 226/35 P o l y a c r y l a t e (40%) Rhone

Contraspum 300 G l y c o l e t h e r defoamer Zschi e

Cublen D50

DC (22-5211 S u p e r - w e t t i n g agent DowCor

Decanol

Dequest 2000 Organophosphorous p r o d u c t I\iiCN7san

DeSonic LFD-97 Nonionic s u r f a c t a n t DeSoto

DeSonic 5N Nonioni c s u r f a c t a n t DeSoto

DeSonic 9N Detergent/degreaser DeSoto

DeSonic 11N Nonionic s u r f a c t a n t DeSoto

DeSonic 81-6 Nonionic s u r f a c t a n t DeSoto

DeSophos 5AP Phosphate e s t e r DeSoto

Diatomaceous E a r t h Kaopol

D L i q u i d Sodium S i l i c a t e PQCorp

D i p r o p y l e n e G l y c o l Monoethyl E t h e r S o l v e n t Dow or
Arc0

Dodigen 226

Dowanol DPM Glycol ether Dow

Dowanol DPnB Glycol ether Bow


Trademarked Raw Materials 21 7

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Dowanol EB Ethylene glycol n-butyl ether Dow

Dowanol PM P r o p y l e n e g l y c o l methy ether Dow

Dowanol PnB Glycol ether Dow

Dowanol TBA Glycol ether Dow

Dowanol TPM T r i p r o p y l e n e g l y c o l me ether Dow

Dow C o r n i n g 20 R e l e a s e C o a t i n g DowCor

Dowfax 382 S o d i um n - d e c y l d i p h e n y l o x d e Dow


d i s u l f o n a t e (45%)

Dowicide A Sodium o - P h e n y l p h e n a t e Dow

Dow 200 S i l i c o n e F l u i d ( 1 0 0 0 c S t ) DowCor

Dowfax 2A1 S o d i um d o d e c y l d i p h e n y l o x i de Dow


d i s u l f o n a t e (45%)

Dowfax 382 Anionic surfactant Dow

D r e s i n a t e 91 R o s i n soap Hercul

E L i q u i d Sodium S i l i c a t e PQ

Emcol 4500 W e t t i n g agent W itco

Emcol 6744 Surface-active agent Witco

E m e r s o l 213 Oleic acid Henkel

Emphos PS-236 Phosphate e s t e r s u r f a c t a n t Witco

Emphos PS-331 Phosphate e s t e r s u r f a c t a n t W itco

Emphos 5AP Phosphate e s t e r s u r f a c t a n t Witco

E m u l s i f i e r F o u r HF D i a1 k y l q u a t e r n a r y ( 7 5 % a c t i v e ) Tomah

Emul s i f ie r 827 Mixed d i a l k y l q u a t e r n a r y (75% a c t ) Tomah

Emul s i o n C340 Tomah

Epsom S a l t PQ
218 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Ethylene G l y c o l n-Butyl Ether Solvent Dow or Union @ a r b

E u p e r l a n PK-771 P e a r l iz i ng a g e n t (47%) Henkel

Foam B o o s t e r 14 Def oamer Tornah

Gafac RE-40 Anionic surfactant Rhone

Gafamide CDD 518 Ethanolamide Rhone

Genagen LAB C12C14 a l k y l d i m e t h y l b e t a i n e Hoechs

Genapol OA-80 Alcohol ethoxylate Hoechs

Genapol UD-030 C11 0x0 e t h o x y a t e ( 3 moles EO) H Q ~ C ~ S

Genapol UD-080 A l c o h o l ethoxy a t e Hoechs

Genapol ZRO l i q u i d Alkyltriglycol ether sulfate soln Hoechs

Genapol 2908 Alcohol ethoxylate Hoechs

G e o r g i a M a r b l e W h i t e #8 c a l c i u m c a r b o n a t e GaMarb

G l u c o n i c A c i d S o l u t i o n (50%) Ashlan

G1 ucopon 425CS C8-16 a l k y l p o l y g l y c o s i d e (50%) Henkel

G l y c o l E t h e r DPM

G l y c o l E t h e r PM

Good-Ri t e K-752 V i s c o s i t y reducer BFGood

Good-Rite K-7058 5800 MW p o l y a c r y l i c a c i d BFGood

GP-RA-159 S i 1 icone P o l ish A d d i t i v e Genes

GP-121 S i l i c o n e P o l i s h A d d i t i v e Genes

GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n Genes
Trademarked Raw Materials 219

RAW MATERIAL CHEMICAL D E S C R I P T I O N SOURCE


H-7892 d-Limonene A r y l es

Hampene 100 T e t r a s o d i um EDTA Grace

Hexyl C a r b i t o 1 I n d u s t r ia1 s o l v e n t UnCarb

H i t e c E-515 Ethyl

Hoe S3924 Hoechs

Hoechst Wax E Wax Hoechs

Hoechst Wax S Wax Hoechs

Hostapur 0s Liquid Hoechs

Hostapur SAS6O Secondary a l k a n e s u l f o n a t e Hoechs

Hyamine 1 O X Q u a t e r n a r y ammonium compound Lonza

Hypure N Secondary h y p o c h l o r i t e , 10% s o l n

I g e p a l CA-520 O c t y l p h e n o x y p o l y e t h o x y e t h a n o l . 5 EO Rhone-

I g e p a l CA-620 O c t y l p h e n o x y p o l y e t h o x y e t h a n o l , 8 EO Rhone-

Pgepal CA-630 O c t y l p h e n o x y p o l y e t h o x y e t h a n o 1 , g EO Rhone-

I g e p a l CA-720 Octylphenoxy p o l y e t h o x y e t h a n o l , Rhone-


12-13 moles EO

I g e p a l CO-430 Nonionic ethoxylat e s u r f a c t a n t Rhone-

I g e p a l CO-530 A1 k o x y l a t e d 1 in e a r a1 coho1 Rhone-


n o n i o n i c s u r f a c t a n t (low foam)

I g e p a l 60-630 Nonylphenoxy p o l y e t h o x y e t h a n o l , Rhone-


9-10 moles € 0

Pndopol H-100 Viscous polybutene Amoco

I n h i b i t o r 4000 A1 kanolami ne b o r a t e Zschim

Isopar K I s o p a r a f f i n solvent Exxon

Isopar M I s o p a r a f f i n solvent Exxon


220 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Kaopol it e Kaolin clay Kaopol

K a o p o l i t e SF A n h y d r o u s a l u m i num s i 1 ic a t e Kaopol

Kaopol it e 1 152 A n h y d r o u s a l u m i n u m s i 1i c a t e Kaopol

K a s i l #1 P o t a s s i um s i 1 i c a t e PQ

K a s i l #6 P o t a s s i um s i 1 ic a t e PQ

K a t h o n CG Fungicide (biocide) Rohrn&

K e l zan Xan h a n gum Kel co

Kerr-McGee M i n e r a l S e a l O i Kerr-

K o m p e r l a n KD

L a r o s t a t 88 Ant s t a t PPGMaz

L a r o s t a t 264A Antistat PPGMaz

L a r o s t a t 519 Anti stat PPGMaz

L a u n d r y A d d i t i v e LA-5 Tomah

Lonzabac-1230 Lonza

Lumo WW 75 Zschim

Lumorol 4154 Surfactant blend Zschirn

L u m o r o l 4192 Surfactant blend Zschim

L y t r o n 295 Opacifier. Polystyrene emulsion Morton

Macol NP 9 . 5 & NP-11 & P o l y o x y e t h y l e n e f a t t y e t h e r PPGMaz


OPlOSP & TD-3 & T D - 1 2
& 2LF & 48 & 5100

M a f o CSB Amphoteric s u r f a c t a n t PPGMaz

M a f o 13 MOD 1 Amphoteric s u r f a c t a n t PPGMaz


Trademarked Raw Materials 221

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Makon 10 A l k y l phenol e t h e r Stepan

Makon 12 A l k y ? pheno7 e t h e r Stepan

Maphos 58 Phosphate e s t e r PPGMaz

Maphos 60A Phosphate e s t e r PPGMaz

Maphos 8135 Phosphate e s t e r PPGMaz

M a s i l EM250C & Silicone fluids PPGMaz


EM10,OOOC & SF-10 &
SF-100 & SF-1,000 & 123

M a s l i p 500 & 501A & Synthetic lubricant additives PPGMaz


501 Base

Mazamide SS-10 & 65 & S p e c i a l t y alkanolamides PPGMaz


80 & 1281

Mazawet 77 Surfactant PPGMaz

Mazon R I 4A & R I 6 & Specialty proprietaries PPGMaz


RI 8A & R I 88 & 98
Mazox LDA F a t t y amine o x i d e PPGMaz

Mazu DF 210 SX Def oamer PPGMaz

M e d i a l a n KA Conc.

Metso Beads 2048 Anhydrous sodium m e t a s i l i c a t e PQ

Metso Pentabead 20 Sodium m e t a s i l i c a t e p e n t a h y d r a t e PQ

M i r a n o l CPM-SF Conc. D i s o d i um cocoamphodi p r o p i o n a t e Rhone-

M i r a n o l J E M Conc.(34%) Sodium mixed C8-amphocarboxylate Rhone-

Monacor BE Corrosion i n h i b i t o r Mona

Monacor 4000 Corrosion i nhi bi t o r Mona

Monalube 110 & 205 & Synthetic lubricants Mona


210 & 215 & 220 & 225
& 310 & 315 & 320 & 325
Ik 605 & 610

Monamid 150-ADD Cocamide DEA Mona


222 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Monamine CF-100M & 2 : 1 f a t t y a1 k a n o l a m i d e s Mona
1-76

Monamulse dL-1273 P r o p r i e t a r y emu1 s i f ie r / s o l u b i 1 iz e r s Mona

Mona NF-10 & N F - 2 0 Surfactants Mona

Monamulse TRP & L i q u i d e m u l s i f i e r and s o l u b i l i z e r Mona


653-83D

Monaquat I S I E S I s o s t e a r y l e t h y l d i m o n i urn e t h o - Mona


sulfate

Monayuat TG Q u a t e r n a r y p h o s p h o l i p i d compound Mona

M o n a s i l PCA Mona

M o n a t e r g e ALX-100s Cocami de DEA & DEA-Dodecyl benzene- Mona


s u l f o n a t e & diethanolamine

Monaterge 779 DEA-Laureth s u l f a t e Mona

M o n a t e r i c CM-36s Sodium c o c o a m p h o a c e t a t e Mona

M o n a t e r i c CyNa-50 1 - H y d r o x y e t h y l e n e - 2 - c a p r y l im i d - Mona
a z o l i fie ( 5 0 % a c t iv e )

M o n a t e r i c EH M i I d amphoteric detergent/emul- Mona


sifier

Monat r o p e 1 2 5 0 Mona

M-Pyrol n-Methyl-2-pyrrolidone ISP

M u l s i f a n K326 S p e z i a l Emulsifier for solvents Zschim

M u l s i f a n RTI Fatty acid ethoxylate. Emulsifier. Zschim

Nacconol 9 0 G Linear alkylbenzene sulfonate(LAS) Stepan

N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e PQ

N e k a l WT-27 A n i o n i c w e t t i n g agent Rhone-

Neodol 1 . 5 Ethoxylate. Linear primary alcohol Shell


Trademarked Raw Materials 223

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


Neodol 23-6.5 C12-13 l i n e a r a l c o h o l . 6 . 5 moles EO Shel 1

Neodol 25-3 Cf2-15 l i n e a r a l c o h o l . 3 moles EO Shel 1

Neodol 25-7 C12-15 l i n e a r a l c o h o l . 7 moles EO Shel 1

Neodol 25-12 Linear primary alcohol Shel 1

Neodol 91-6 Linear primary alcohol. Ethoxylate Shel 1

N i n o l 11-CWI Coconut d i e t h a n o l a m i d e , modified Stepan

N i n o l 30-LL A1 k y l o l a m i d e Stepan

N i n o l 40-CO Cocamide DEA Stepan

P a r o i l 160 Chlor nated p a r a f f i n Dover

Pemulen 1622 Resin BFGood

P e t r o BW L i q u d & BAF A n i o n c s u r f a c t a n t / d s p e r s a n t DeSoto


L i q u i d & BAF Powder &
LBA L i q u i d & LBA Powder &
ULF L i q u i d & 22 Powder

P h o s f e t a l 201 Phosphoric a c i d e s t e r Zschi m

Phosphol ip i d EFA L i ndeamidopropyl PE-Dimoni um Mona


c h l o r i d e phosphate

P i l o t SXS-40 Sodi um x y l e n e s u l f o n a t e 40% Pilot

P l u r a f a c C-17 A1 k o x y l a t e d f a t t y a1 coho1 BASF

P l u r a f a c 0-25 Linear alcohol ethoxylate. MW:930 BASF

P o l y t e r g e n t S-305LF Alkoxylated l i n e a r alcohol nonionic O l i n


s u r f a c t a n t ( l o w foam)

PQ Epsom S a l t PQ

P r i f a c 2922 Lauric acid Uni che

P r o d u k t 2058 Fatty alcohol f a t t y acid ester Zschi m

P r o p e t a l 99 A1 k y l p o l y a l k y l e n e g l y c o l e t h e r Zschi m
224 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


P r o p e t a l 241 A1 k y l p o l y a l k y l e n e g l y c o l e t h e r Zschirn

P r o p e t a l 281 A1 k y l p o l y a l k y l e n e g l y c o l e t h e r Eschirn

P u r t o n CFD F a t t y a c i d alkanolamide Zschi m

PVP K-15 P o l y v i n y l p y r r o l i d o n e polymer Rhone-

Renex 2 0 Surfactant ICI


R e w o t e r i c AM 8-14 Grease c u t t e r & foam b o o s t e r Wi t c o
R e w o t e r i c AM B-15 & Surfactants w i eco
AM DML 35 & AM HC &
AM KSF 40 & AM TEG
& AMV

Rhodafac RA-600 Linear alcohol ethoxylate RhOne-

Rhodafac RE-600 Phosphate e s t e r RhOn@-

Rhodafac RE-61 0 Phosphate e s t e r Rhone-

Rhodasurf A-24 L i q u i d nonionic surfactant. 2.5 Rhone-


moles EO

Rhodasurf LA-7 L i q u i d nonionic surfactant. 7-9 Rhone-


moles EO

Rhodasurf LA-9 L i q u i d nonionic surfactant. 9 Rhone-


moles EO

Rhodasurf LA-12 L i q u i d nonionic surfactant. 12 Rhone-


moles EO

Rhodasurf 91 -6 Liquid nonionic surfactant. 6


moles EO

Rhodaterge SMC Cleaner c o n c e n t r a t e Rhone-

Rhodopol 23 Xanthan gum Rhone-

Rhodopol 50MD Xanthan gum Rhone-

R i chami de 5725 Richar

RU L i q u i d Sodium S i l i c a t e c o r r o s i o n i n h i b i t o r PO
Trademarked Raw Materials 225

RAW M A T E R I A L CHEMICAL DESCRIPTION SOURCE


SF96 S i l i c o n e F l u i d Polydimethyl s i l i c o n e f l u i d GE

S F I 705 R e a c t i ve S i 1 icone Polymer GE

S F I 706 R e a c t i v e S i 1icone Polymer GE

S h e l l f e x 213 Rubber p r o c e s s o i l Shel 1

S h e l l S o l 135 Solvent Shel 1

SM2133 S i 1 icone Emu1s i on GE

SM2135 S i l i c o n e Emulsion GE

SMA-2625 R e s i n Cop01ymer r e s i n Arco

S-Mar 80 Sorbitan f a t t y ester PPGMaz

Snow F l o s s M i n e r a l f i 1l e r JM

Sodium A l k y l a r y l S u l f o n a t e Powder (99%) W itco

Sodium A l k y l n a p h t h a l e n e S u l f o n a t e DeSoto

Sodium B i c a r b o n a t e (Grades 1 & 5 ) Church

Sodium Carbonate FMC

Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 Olin

Sodi um T r ipol yphosphate FMC

Sodium Xylene S u l f o n a t e (40%) Stepan, W i t c o

Sokalan CP5 B HP22

Standamid PD Cocamide DEA Hen k e l

Standapol A A n i o n i c s u r f a c t a n t . Ammonium Stepan


l a u r y l s u l f a t e (30%)

Standapol ES-3 A n i o n i c s u r f a c t a n t . Sodium l a u r y l Stepan


e t h e r s u l f a t e (30%)

Star Sodium s i 1 i c a t e 4QBe' PQ

Starso L i q u i d sodium s i l i c a t e PO

Steal CS-330 Alcohol ether s u l f a t e Stepan


226 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL DESCRIPTION SOURCE


S t e p a n o l WA-Extra Hydrotrope Stepan

Stoddard S o l v e n t Exxon

STPP FMC

S u l f e t a l 4069 Fatty alcohol s u l f a t e . Anionic Zschim


surfactant

S u l f e t a l 4105 Fatty alcohol s u l f a t e . Anionic Zschim


surfactant

Sul f o n a t e OA5 W e t t i n g agent Tennes

Super F l o s s Diatomaceous e a r t h JM

S u p r a g i l NK Sodium a l k y l n a p h t h a l e n e s u l f o n a t e Rhone-

S u r f o n i c N-150 S u r f a c e a c t i v e agent Texaco

TEA L a u r y l S u l f a t e Rhone-

T e r g i t o l NP Nonoxynol UnCarb

Thermphos Hoechs

Thermphos NW Hoechs

T i n o p a l 5BM F l u o r e s c e n t w h i t e n i n g agent C i ba-

Tomah A l k a l i S u r f a c t a n t Amphoteric (35% a c t i v e ) Toma h

Tomah Amphoteric L M i I d surfactant Tomah

Tomah AO-14-2 E t h e r amine o x i d e (50% a c t i v e Tomah

Tomah A0-728 Special Amine o x i d e - h i g h foaming (50% a c t 1 Tomah

Tomah Q-14-2 Quaternary Toma h

Tomah Q-17-2 Quaternary Tomah

T r i l o n A Liquid Zschim

T r i t o n DF-16 & N-101 Nonionic surfactants Rohm


& x-45
Trademarked Raw Materials 227

R A W MATERIAL CHEMICAL DESCRIPTION SOURCE


Tur b o b r i t e Aluminosilicate PO

Turbobrite L Aluminosilicate slurry PQ

Tween 40 P o l y s o r b a t e 40 ICI

T y l o s e CBR 10000

U b a t o l TR1138

V a l f o r 100 Zeolite A builder PQ

Van Gel B & C & ES & 0 Magnesium aluminum s i l i c a t e s RTVan

Vanseal NACS-30 Sodi um 1a u r o y l s a r c o s i n a t e RTVan

Vanseal NALS-30 RTVan

Varami de A-1 0 & A - 1 2 D e t e r g e n t a1 kanolami des W itco


& A-83 & MA-1

V a r o n i c DM-55 & K205 Nonionic w e t t i n g agents witCO


8 T202 & T202SR
Varox 365 8 1770 W e t t i n g agents W itco

V a r q u a t 50MC S p e c i a l t y quaternary, germicide w itco


Veegum & Veegum T Magnesi um a1 umi num s i 1 ic a t e s RTVan

Versene 100 & 220 C h e l a t i n g agents Dow

V i scasi a F l u i d ( 1 0 , O O O ) S i 1 icone GE

Wachsemulsion 1864 Zschim

Witcamide S-780 & 128T A l k a n o l a m i d e s u r f a c t a n t s W i tco


& 6445

W i t c o 12986 W itco

W i t c o 1298SA Soft acid W i tco

W i t c o l a t e ES-3 & Sulfated surfactants witco


LES-6OA & LES-6OC &
S E - 5 & WAC-LA & 2310
228 Advanced Cleaning Product Formulations

RAW MATERIAL CHEMICAL D E S C R I P T I O N SOUWGE


W i t c o n a t e AOS & SXS Surfactants \Mi ~ C O
& 30DS & 45 L i q u i d
& 60T L i q u i d & 1240
& 1260 S l u r r y

W i t c o n o l NP-100 Detergents & degreasers w i tco


& NP-120

Wessalith P Zeolith P

Ya rmor 3 02 Pine o i l Hercul

Z e t e s o l 2056 Fatty alcohol ether s u l f a t e Zschim

Z e t e s o l NL Fatty alcohol ether s u l f a t e Pschi I

Zusol a t 1005/85 A1 k y l p o l y e t h y l e n e g l y c o l e t h e r Zschim

Zusol a t 1008/85 Alkyl polyethylene glycol ether Zschi rn

2 . l r Potassium s i l i c a t e (39%) PQ

2 . 4 r Sodium s i l i c a t e (52%) BQ
Section IV
pliers' Addresses
230 Advanced Cleaning Product Formulations

A1 1 ied-Si g n a l , I n c . Dover Chemical Corp


P . O . Box 2332R W15 & D a v i s
M o r r i s t o w n , NJ 07962 P.O. Box 40
(201)-455-2000/(800)-526-0717 Dover, OH 44622
(800)-321 -8805
Amoco Chemical Co.
200 E. Randolph D r . Dow Chemical USA
Chicago, I L 60601 M i d l a n d , M I 48674
(312)-856-3200/(800)-621-8888 (8 0 0 )-2 5 8 - C H E M

Angus Chemical Co. Dow C o r n i n g Corp.


2211 Sanders Rd. Box 0994
N o r t h b r o o k , I L 60062 M i d l a n d , M I 48686
(708)-498-6700/(800)-323-6209 (517)-496-4000
A r c o Chemical Co. E t h y l Corp.
3801 West C h e s t e r P i k e 451 F l o r i d a
Newtown Square, PA 19073 Baton Rouge, LA 70801
(215)-359-2000 (504)-388-7556/(800)-535-3030
A r izona Chemical Co. Exxon Chemical Americas
1001 E . B u s i n e s s Hwy 98 13501 K a t y Frwy
Panama C i t y , FL 32401 Houston, TX 77079
(904)-785-6700/(800)-526-5294 (713)-870-6000/(800)-231-6f333
Ash1 and Chemical Co. FMC Corp.
P . O . Box 2219 2000 Market S t .
Columbus, OH 43216 Philadelphia, PA 19103
(614)-889-3333/(800)-848-7485 (215)-299-6000/(800)-526-3649
BASF Corp. GE S i l i c o n e s
100 C h e r r y H i l l Rd. 260 Hudson R i v e r Rd.
P a r s i p p a n y , N J 07054 W a t e r f o r d , NY 12188
(201)-316-3000/(800)-526-1072 (518)-237-3330/(800)-255-8886
B u r l i n g t o n Chemical Co. Inc. Genesee Polymers Corp.
P . O . Box 1 1 1 Fenton Rd./P.O. Box 7047
615 Huffman M i l l Rd. F l i n t , M I 48507
B u r l i n g t o n , NC 27215 (313)-238-4966
(919)-584-0111/(800)-672-5888
Georgia Marble Co.
C i ba-Gei gy Corp. 1201 R o b e r t s B l v d .
7 Skyline Drive Kennesaw, GA 30144
Hawthorne, NY 10532 (404)-421-6500
(914)-374-4700/(800)-431-1900
B.F. G o o d r i c h G o .
DeSoto I n c . 991 1 B r e c k s v i 1 1 e Rd ,
1700 S . M t . P r o s p e c t Rd. B r e c k s v i l l e , OH 44141
Des P l a i n e s , I L 60018 (216)-447-5000/(800)-331-1~44
(312)-391-9000
Suppliers' Addresses 231

W.R. Grace 8 Co. Mona I n d u s t r i e s I n c .


55 Hayden Ave. 76 E . 24 S t .
L e x i n g t o n , MA 02173 P . O . Box 425
( 6 1 7 )-861 -6600 P a t e r s o n , N3 07544
(201)-345-8220/(800)-553-6662
Henkel Corp.
5325 S . N i n t h Ave. Monsanto Chemical Co.
LaGrange, I L 60525 800 N. L i n d b e r g h B l v d .
(708)-530-7300/(800)-543-7370 S t . L o u i s , MO 63167
(314)-694-1000/(800)-325-43
blercul es I n c .
H e r c u l e s P1aza Morton I n t e r n a t i o n a l
W i l m i n g t o n , DE 19894 100 N. R i v e r s i d e P l a z a
(800)-247-4372 Chicago, I L 60606
(312)-807-2000/(800)-367-33
Woechst Celanese Corp.
801 Water S t . O l i n Corp.
Portsmouth, V A 23704 120 Long Ridge Rd.
(804)-393-3100/(800)-368-2822 P . O . Box 1355
Stamford, CT 06904
I C I Specialties (203)-356-2000/(800)-243-9171
Concord P i k e & New Murphy Rd.
W i 1m i n g t o n , DE 19897 P e t r o l i t e Corp.
(302)-886-3000/(800)-822-8215 6910 E. 1 4 S t .
T u l s a , OK 74112
Johns-Manvi 11e (918)-836-1601
Ken C a r y l Ranch
Denver, CO 80217 P i l o t Chemical Co.
11756 Burke S t .
Kaopolite, Inc. Santa Fe S p r i n g s , CA 90670
2444 M o r r i s Ave. (310)-723-0036
Union, W J 07083
(9081-789-0609 PPG/Mazer
One PPG P l a c e
Kel c o D i v i s i on P i t t s b u r g h , PA 15272
Merck & Co., I n c . (412)-434-3131/(800)-243-6774
8355 Aero D r i v e
San Diego, CA 92123 PQ Corp.
(61 9)-292-4900 P . O . Box 840
V a l l e y Forge, PA 19482
Kerr-McGee Chemical Corp. (215)-293-7200
Kerr-McGee C t r .
P . O . 80x 25861 Quest I n t e r n a t i o n a l Fragrances
Oklahoma C i t y , OK 73125 400 I n t e r n a t i o n a l D r i v e
(405)-270-1313/(800)-654-3911 Mount O l i v e , NJ 07828
(201 )-691-7100
Lonfa I n c .
1717 R t a 208
F a i r Lawn, NJ 07410
(201)-794-2400/(800)-777-1875
232 Advanced Cleaning Product Formulatioris

Rhone-Poul enc Tomah P r o d u c t s , I n c .


P r o s p e c t P l a i n s Rd. 1012 T e r r a D r i v e
Cranbury, N J 08512 M i 1t o n , W I 53563
(609)-860-4000/(800)-626-2613 (608)-868-68ll/(800)-441-0708
Richardson Co. Uni chema Chemicals I n c .
2400 East Devon Ave. 4650 S . Racine Ave.
Des P l a i n e s , I L 60018 Chicago, I L 60609
(312)-376-9000/(800)-833-2884
Rohm & Haas Co.
Independence M a l l West Union C a r b i d e Corp.
P h i l a d e l p h i a , PA 19105 39 O l d Ridgebury Rd.
(215)-592-3000 Danbury, CT 06817
(203)-794-2000
S h e l l Chemical Co.
P . O . Box 2463 R . T . V a n d e r b i l t Co., Inc.
Houston, TX 77252 P . O . Box 5150
(713)-241-6161 30 W i n f i e l d S t .
Norwalk, CT 06856
Stepan Co. (203)-853-1400/(800)-243-6084
22 W . F r o n t a g e Rd.
N o r t h f i e l d , I L 60093 W i t c o Corp.
(708)-446-7500/(800)-745-7837 520 Madison Ave.
New York, NY 10022
Tennessee Chemical Co. (212)-605-3941/(800)-634-4010
3400 Peachtree Rd NE
A t l a n t a , GA 30326 Zschimmer & Schwarz
(404)-239-6700/(800)-241-1912 Max-Schwarz-Strabe 3-5
D-56112 L a h n s t e i n/RH
Texaco Chemical Co. D 26 21/120
3040 Post Oak 8 l v d .
Houston, T X 77056
(713)-961-3711

3M
3M Center
S t . P a u l , MN 55144
(612)-733-5454

You might also like