Professional Documents
Culture Documents
RODUCT FORMULATIONS
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ADVANCED
CLEANING
PRODUCT
FOR MULATlONS
Volume 5
Ernest W. Flick
NOYES PUBLICATIONS
WILLIAM ANDREW PUBLISHING, LLC
Nomich, New York, U.S.A.
Copyright 0 1999 by Ernest W. Flick
No part of this book may be reproduced or utilized in
any form or by any means, electronic or mechanical,
including photocopying, recording or by any informa-
tion storage and retrieval system, without permission
in writing from the Publisher.
Library of Congress Catalog Card Number: 89-30274
ISBN: 0-8155-1431-X
Printed in the United States
10 9 8 7 6 5 4 3 2
Flick, Ernest W.
Advanced cleaning product formulations
V
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reface
~ ~ in the cleaning
~ ~ industry
product ~ has gradually
a been~undergoing~ o
significant change during the past years. Raw materials costs have risen and
manufacturers have been reluctant to pass along these increases. Environmental
considerations have also played a part. By changing formulations to improve
cost/performance characteristics, manufacturers have been able to control costs
but still enhance performance. This book presents manufacturers' suggested
formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and
chapters, with the number of formulations indicated in ( ):
vii
viii Preface
Each formula is located in the chapter which is most applicable. The reader,
seeking a formula for a specific end use, should check each chapter which could
possibly apply. In addition to the above, there are two other sections which will
be helpful to the reader.
Key properties of the formula, which are the features that the source
considers to be more outstanding than other formulations of the same
type.
X
ntents and Subject Index
SECTION I
OUSEHOLD AND INDUSTRIAL
CLEANERS AND POLISHES
B OM CLEANERS: ............................... 2
Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . 4
Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . 4
Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
l d e w .................................
~ o w ~ ~ ~ Cleaner 5
Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . 6
Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . 6
Toilet Bowl Cleaner with Bleach ......................... 7
xi
xii Contents and Subject Index
.
3 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Aqueous Degreaser
d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21
Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22
Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24
4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 25
Automatic Dishwash Detergent-Consumer
(Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Consumer
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Industrial & Institutional
(Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7
Contents and Subject Index xiii
.
5 GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . 44
Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . 45
rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . 46
Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . 48
AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 49
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
&alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . 50
A1 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
xiv Contents and Subject Index
.
6 GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62
Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63
Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65
Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Windows/Glass
Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66
.
7 HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . 68
Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Contents and Subject Index xv
PRODUCTS ................................ 77
gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . 80
Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . 80
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . 80
dustrial Heavy Duty Laundry Liquid . . . . . . . . . . . . . . . . . . . . 81
Industrial Laundry Detergents
High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . 82
Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
Laundry Detergent-Consumer
phosphate. Powder) ............................... 84
bundry Break-Industrial & Institutional
(Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Break-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Detergent-Industrial & Institutional
(NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Break-Industrial & Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Detergent-Industrial & Institutional
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
Laundry Detergent-Industrial & Institutional
(Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . 87
mi Contents and Subject Index
.
9 METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 802
Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p03
Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . 104
Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . 104
Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1104
Contents and Subject Index xvii
.
11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . 141
Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . . 145
SECTION 11
TRANSPORATION CLEANERSl
AND POLISHES
.
15 AUTO CLEANERS AND POLISHES .................... 11’9’8
Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . 181
Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . 181
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 1181
Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . . 182
.
16 CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . %83
Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . 184
Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . 185
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 185
Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . 185
CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . 187
Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . 133
Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash and Care
Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . 190
Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . 190
Rinse-off Agent (Water-Repellent) Without Hydrocarbons . ~ 190
Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . 190
Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . 19B
Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . 193
Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . 194
Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Contents and Subject Index xxi
n SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
Aircraft Cleaner
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . 205
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant . . . . . . . 206
Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
ConcreteDriveway Cleaners
For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . 209
Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
xxii Contents and Subject Index
1
1. Bathroom Cleaner
a
Bathroom Cleaners 3
A c i d i c Toilet Bowl C l e a n e r
I n s r e d ie n t : 5
DI Water 43.00
Carbopol 6 7 4 ( 1 ) 2.00
C i t r i c A c i d (50%) 50.00
A l k y l benzene s u l f o n i c a c i d 97%) ( 2 ) 2.00
Sodi um d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) ( 3 ) 3.00
(1) BFGoodrich
i2j Stepan Co.: B i o s o f t 5-100
( 3 ) Dow Chemical Co.: Dowfax 2A1
Procedure:
1 . M i x t h e D I w a t e r and c i t r i c a c i d s o l u t i o n t o g e t h e r .
2 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d sol-
u t i o n . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 30 m i n u t e s . The
p r o d u c t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - h e a t i n g
t o 40-50C w i l l h a s t e n t h e p r o c e s s .
3 . Add t h e s u l f o n i c a c i d and t h e d i p h e n y l o x i d e d i s u l f o n a t e
surfactant.
4 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o
room t e m p e r a t u r e .
Total Actives:
C i t r i c a c i d : 25.00
A l k y l benzene s u l f o n i c a c i d : 1.94
Dodecyl d i p h e n y l o x i d e d i s u l f o n a t e : 1.35
M i 1dew Remover
Ingredients: Wt%*
Van Gel 0 3.00
D e i o n i z e d Water 85.55
Sodium H y d r o x i d e , 50% S o l u t i o n 0.45
Sodium H y p o c h l o r i t e , 10% S o l u t i o n ( H y p u r e N ) 10.00
Vanseal NALS-30 1.oo
Procedure:
4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e
w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t
5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2 . Add sodium h y d r o x i d e and m i x u n t i l u n i f o r m l y d i s s o l v e d .
Slow t h e m i x e r t o 1 0 0 0 rpm o r l e s s .
3 . Add t h e Vanseal NALS-30. A v o i d a i r e n t r a p m e n t . M i x u n t i l
uniform.
F o r m u l a t i o n No. 458
Ingredients:
A: Veegum T , Magnesium Aluminum S i l i c a t e 5.00
T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) 0.25
Water 50.75
8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % 34.00
Sodium M e t a s i l i c a t e , Anhydrous 10.00
Procedure:
1 . D r y b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e
a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth.
2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g
a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m .
F o r m u l a t i o n No. 424
*As r e c e i v e d b a s i s
Tile, P o r c e l a i n a n d Bathroom C l e a n e r , A c i d
Ingredients:
Water, D . I . 75.5
Xanthan Gum 0.5
P e t r o BAF Powder 2.0
P h o s p h o r i c A c i d , 75% 12.0
H y d r o x y a c e t i c A c i d , 70% 10.0
Perfume, Dye q.s.
B l e n d i n g Procedure:
Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w
t o m i x u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n
o r d e r l i s t e d . I f p r o b l e m s d e v e l o p a d d i n g Xanthan Gum t o w a t e r ,
p r e m i x t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o
water.
F o r m u l a 529
Tub and T i l e C l e a n e r
Ingredient:
Water, D . I . 67.4
P h o s p h o r i c A c i d , 86% 17.6
H y d r o c h l o r i c A c i d , 37% 13.5
R e w o t e r i c AM TEG 0.5
V a r o n i c T202 SR 1.o
Blending Procedure:
Add in g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ie s :
V i s c o s i t y , c p s : 293
S o l i d s : 16.3%
pH: 1 . 7
F o r m u l a 530
Ingredients:
Water, D . I . 44.9
Sodium H y d r o x i d e (30%) 1.o
Varox 365 1.5
Sodi urn H y p o c h l o r i t e ( 5 . 7 % ) 52.6
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .
Typical Properties:
V i s c o s i t y , cps: 4
S o l i d s : 3.8%
pH: 13.5
F o r m u l a 531
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Bathroom Cleaners 7
T o i l e t Bowl C l e a n e r w i t h B l e a c h
I n qr e di-w Wt%
D I Water 60.75
Carbopol 676 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) 5.00
Potassium carbonate 5.00
Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) 8.00
Amine O x i d e (30%) ( 3 ) 10.00
B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2 , 5 0 0 c p s
P r o d u c t pH: 12-13
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodri c h
( 2 ) PQ C o r p .
( 3 ) Lonza, I n c . : B a r l o x 12
Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r
s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s ,
d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r .
M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e
s l u r r y i s homogeneous.
2 . W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and
t h e p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous.
3 . C o n t i n u e a g i t a t i o n and add t h e p o t a s s i u m c a r b o n a t e f o l l o w e d
by t h e b l e a c h .
4 . Add t h e amine o x i d e s u r f a c t a n t and m i x u n t i l homogeneous.
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .
Total Actives:
S i l i c a t e (as Si02): 1.32
C a r b o n a t e ( a s Na2C03): 3 . 8 4
Available Chlorine: 1.OO
Amine O x i d e : 3 . 0 0
8
D a i q , Food and General Industrial Cleaners 9
A c i d I n d u s t r i a l and Household C l e a n e r s
O x a l i c A c i d Gel
Inqredients: W t .%*
Water 53.70
Van Gel B 2.50
Rhodopol 2 3 0.80
O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n 40.00
P o l y s o r b a t e 40 (Tween 4 0 ) 3.00
Procedure:
1 . Dry b l e n d t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e o x a l i c a c i d s o l u t i o n .
3 . When a l l t h e a c i d has been added, add t h e P o l y s o r b a t e 40
and mix u n t i l u n i f o r m .
F o r m u l a t i o n N o . 466
Rust Removal J e l IY
Procedure:
1 . D r y b l e n d t h e Van Gel 0 and Rhodopol 2 3 and add them t o he
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e P h o s p h o r i c A c i d s o l u t i o n .
3 . A f t e r a l l t h e a c i d has been added, add t h e O c t o x y n o l - 9
and mix u n t i l u n i f o r m .
F o r m u l a t i o n No. 467
*As r e c e i v e d b a s i s
Cleaners f o r I n d u s t r i a l A p p l i c a t i o n
D e s i n f e c t i n q Cleaner, A c i d
I n s ed ien t s : wts/,
water 48.0
P h o s p h o r i c a c i d (85Oh) 24.0
S u l p h u r i c a c i d (98%) 5.0
P r o p e t a l 241 3.0
Dodigen 226 20.0
F o r m u l a CT 06-06-01
D i ppi n q C1 e a n e r
In r e d ie-n-t-sL Wt%
itatger 75.5
Tetrapotassium pyrophosphate 10.0
C a u s t i c soda 1.5
D i p r o p y l e n e g l y c o l monomethyl ether 5.0
S u l f e t a l 4069 5.0
Zusol a t 1008/85 3.0
F o r m u l a CT 07-03-01
Spray C 1 e a n e r
Insredients: Q
Water 58.0
Cublen D50 3.0
T r i e t h a n o l ami ne 3.0
S u l f e t a l 4105 4.0
P r o p e t a l 241 2.0
Z u s o l a t l005/85 0.5
P h o s f e t a l 201 2.0
Butyl glycol 5.0
C i t r u s terpene 0.5
I n h i b i t o r 4000 22.0
F o r m u l a CT 07-06-01
Ingredients
water 86.0
Sul f e t a l 4105 6.0
P r o p e t a l 99 3.0
Zusolat 1005/85 0.5
Butyl glycol 4.0
Orange t e r p e n e 0.5
Formula CT 07-06-03
D e s t a in e r
(Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Method-Brush
Manufacture-Dry blend/Agglomeration
* FMC
** Rhone P o u l e n c I g e p a l C A - 6 3 0
Destai ner
(Reduced Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Methods-Brush
Manufacture-Dry blend/Agglomeration
Composi t i on: %
&
*STPP 10.0
M e t s o Beads 2048 25.0
Sodi um S u l f a t e 8.0
PQ Epsom S a l t 2.0
**Octylphenoxy Polyethoxyethanol, 9 - 1 0 Moles EO 2.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium P e r b o r a t e , Monohydrate 38.0
* FMC
** Rhone-Poulenc I g e p a l CA-630
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
12 Advanced Cleaning Product Formulations
Eaa C l e a n e r
L x o phosphatS?,.powder)
S o i 1- P r o t e i n
S u r f a c e - E g g and egg h a n d l i n g e q u i p m e n t
A p p l i c a t i o n M e t h o d - H i g h p r e s s u r e s p r a y (700-1400 psi)
Manufacture-Dry blend
Composi t i o n : Wt%
Sodium C a r b o n a t e 30.0
M e t s o Beads 2048 20.0
Sodium S u l f a t e 12.0
V a l f o r 100 Z e o l i t e A 30.0
* S o d i urn D i c h l o r o i s o c y a n u r a t e 2H20 3.0
* * S o d i um A1 k y l a r y l S u l f o n a t e Powder ( 9 0 % ) 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* O l i n Chemical
** Witco
B g k i - n g Pan C l e a n e r
(Phosphate,- Powder)
S o i l - A n i m a l f a t and g r e a s e , v e g e t a b l e o i l
S u r f a c e - A 1 umi num and s t e e l
A p p l i c a t i o n Method-Irnmersion/brush
Manufacture-Dry blend/Agglomeration
C So n
O ~ ~t 1 l : Wt%
*Sodium C a r b o n a t e 35.0
*STPP 12.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s € 0 3.0
Metso Pentabead 2 0 50.0
Use D i l u t i o n . 1 . 5 % bw ( 2 o z / g a l l o n )
* FMC
** Rhone-Poulenc I g e p a l CO-630
Heavv D u t v C l e a n e r s
A l l Purpose-Food P r o c e s s P l a n t
Ingredients: Weight%
Water 74.00
EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) 2.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.00
P i l o t SXS-40 5.00
KOH, 45% 10.00
Calamide C 5.00
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r l i s t e d .
2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n .
3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r .
4. EDTA can b e s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l
solution.
5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s .
6 . Use l e v e l . 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HDC-004-01
Inqredients:
- Weight%
Water 89.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 1.oo
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
C a l s u d s 81 4.00
NH40H, 28% 3.00
Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t Water and TKPP when m i x e d a r e c l e a r .
2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l M o n o b u t y l E t h e r i s added.
3 . W i t h t h e a d d i t i o n o f C a l s u d s 81 t h e s o l u t i o n t u r n s c l e a r and
has a pH o f 9.
4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 1 2 .
F o r m u l a t i o n HDC-002-01
H i qh Foaming A1 k a l ine C l e a n e r
M o n a t e r i c EH c o n t r i b u t e s t o d e t e r g e n c y and e f f e c t i v e l y con-
t r o l s b o t h t h e k r a f f t and c l o u d p o i n t i n t h i s h i g h foaming
formulation.
I n n r e d ie n t s : Wt9/o
Water 76.0
Sodium H y d r o x i d e (50%) 10.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 2.0
Dodecyl benzenesul f o n i c a c i d 2.0
M o n a t e r i c EH 8.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommened Use D i l u t i o n : 1 : 2 0 w i t h w a t e r
F o r m u l a t i o n F-768
Heavy D u t y A l k a l i n e Degreaser
M o n a t e r i c EH a i d s i n t h e removal o f o i l y s o i l s w i t h o u t emul-
s i f i c a t i o n . I t e a s i l y displaces o i l y s o i l s from hard surfaces
and keeps them f r o m r e d e p o s i t i n g .
Ingredients: Wt%
Water 65.0
Sodi u m H y d r o x i de ( 5 0 % ) 20.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 3.0
M o n a t e r i c EH 10.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommended Use D i l u t i o n : 1 : 2 0 w i t h w a t e r .
F o r m u l a t i o n F-769
Steam C1eaner
C1 e a n e r , Weakly A1 k a l ine
Ingredients: Wt%
Water 80.4
Cublen D 50 1.o
Tetrapotassium pyrophosphate 2.0
T r i e t h a n o l ami ne 3.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 0 6 - 1 3 - 0 2
Cleaner, S t r o n q l y A1 k a l i n e (Phosphate-Free)
I n g r e d i e c Wt%
Water 80.5
Cublen D50 1. o
Sodi um m e t a s i 1 i c a t e 4.9
C a u s t i c soda 0.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 06-13-03
Metal Cleaner
(m
S o i l - P e t r o l e u m and a n i m a l o i l and g r e a s e
Surface-Metal: Steel
A p p l ic a t i on Method-Immersi on
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : w.t%
Water 65.6
S t a r Sodi um S i 1 ic a t e 15.6
Sodium H y d r o x i d e (50%) 6.3
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 7.5
Use D i l u t i o n : 2%-5% b v
Food I n d u s t r y C l e a n e r
(W
S o i l - H e a v y f o o d g r e a s e , o i l and p r o t e i n
Surface-Metal, ceramic, polymeric, glass
A p p l i c a t i o n Method-Wipe, mop o r b r u s h
Manufacture-Mix t a n k w i t h p r o o e l l e r s t i r r e r
Composition: Wt%
Water 74.0
TKPP (60%) 3.0
N C l e a r Sodium S i l i c a t e 7.0
Sodi um H y d r o x i d e (50%) 3.5
*Phosphate E s t e r 2.5
**Ethylene Glycol n-Butyl Ether 5.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 6 . 5 Moles € 0 ) 5.0
Use D i l u t i o n : 6-12% bw ( 8 - 1 6 o z / g a l l o n )
M i l k Can C l e a n e r
(Phosphat_e, Powder)
Sol 1 - F a t and p r o t e i n
Surface-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend/Agglomeration
Compo_sition’ WX/,
*STPP 30.0
M e t s o Beads 2048 30.0
*Sod1 u m C a r b o n a t e 35.0
+*Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
* * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0
* FMC
** O l i n Chemical
*** w1 t c o
M i l k Can CLea-ner
(Zeco Phosphate, Powder)
S o l 1 - F a t and p r o t e i n
S u r f ace-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend
Composi t i on : Wt%
Val f o r 100 Z e o l i t e A 20.0
Metso Pentabead 20 40.0
Sodium C a r b o n a t e 35.0
*Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
**Sod1 um A 1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0
Use L e v e l : 1 - 2 o z / g a l l o n
* O l i n Chemical
** Stepan, W i t c o
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
18 Advanced Cleaning Product Formulations
Premi um Presoak
Component: 5
Soda Ash 40.0
STPP 35. n
Neodol 25.7 5.0
Sodium Metasi 1 icate Pentahydrate 10.0
Sodium Dodecylbenzenesulfonate Powder 5.0
Burcosperse AP Powder 3.0
Burcotase EP-60 2.0
Component: wtD/,
Water 49.0
Propyl ene G1 ycol 10.0
Dodecyl benzenesul foni c Acid 10.0
TEA-85 20.0
Burco TME 5.0
Nonionic Surfactant* 5.0
Burcotase LL-100 1.o
S a n i t i z i n s Cleaner
(Phosphate, Powder)
S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , e t c .
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry Blend
Composi t 1 1 0 ~ Wt%
Metso Beads 2048 20.0
*Sodium C a r b o n a t e 35.0
*STPP 30.0
**Sodi urn D i c h l o r o i s o c y a n u r a t e , 2H20 10.0
***Sod; um A1 k y l a r y l S u l f o n a t e Powder (99%) 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* FMC
** 01 i n Chemical
*** witco
Sani t i z i na A a e n t
(Phosphate, Powder)_
S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , etc.
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe, b r u s h
Manufacture-Dry blend/Agglomeration
Composi t i on : Wt%
*STPP 30.0
*Sodi um C a r b o n a t e 25.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; 12 M o l e s EO) 10.0
M e t s o Pentabead 20 30.0
Quaternary Germicide 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* FMC
** Rhone-Poulenc R h o d a s u r f LA-12
20
Degreasers 21
Aqueous D e s r e a s e r
Ingredients: Wei q h t %
Water 60.80
NaOH, 50% 2.00
Cal s o f t LAS-99 9.40
P i l o t SXS-40 8.70
C a l o x y l a t e N-9 4.60
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.70
Sodium M e t a s i 1 i c a t e 6.60
E t h y l e n e G l y c o l Monobutyl Ether 3.20
Comments a b o u t t h i s f o r m u l a :
D i s s o l v e t h e s a l t s i n t h e water f i r s t .
F o r m u l a t i o n DEG-001-01
Aqueous D e q r e a s e r
d - L i monene M i c r o e m u l s i o n
Ingredients: Weight%
d - L i monene 9.90
C a l s u d s CD-6 9.80
C a l imu1 se PRS 2.44
Diethylene Glycol n-Butyl Ether 4.93
Water 73.00
Comments a b o u t t h i s f o r m u l a :
1 . A d d i t i o n a l C a l s u d s CD-6 may b e needed t o c l a r i f y t h e sample.
2 . Add t h e w a t e r s l o w l y .
F o r m u l a t i o n DEG-002-01
Water Based D e a r e a s e r
Ingredients: Weight%
Water 68.50
NaOH, 50% 2.00
Cal s o f t LAS-99 7.00
P i lot SXS-40 7.50
Na4EDTA 2.00
C a l o x y l a t e N-9 5.00
E t h y l e n e G l y c o l Monobutyl Ether 3.00
Sodi urn M e t a s i 1 ic a t e 5.00
Comments a b o u t t h i s f o r m u l a :
1 . T h e r e i s a p h o s p h a t e v e r s i o n where 3 . 5 % sodium t r i p h o s p h a t e
i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA.
2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s .
F o r m u l a t i o n DEG-006-01
m r e a s e r Concentrate
( L i q u i d)
Soil-Grease, o i l
Surface-Pai n t , polymeric, metal
A p p l i c a t i o n Method-Spray o r w i p e
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : wt"/o
Water 67.0
M e t s o Beads 2048 8.0
*Sodi urn P o l y a c r y l a t e (40%) 5.0
**Phosphate E s t e r 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 M o l e s EO) 5.0
* * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 5.0
Soi 1 - P e t r o l e u m - b a s e d o i 1
S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c .
Appl i c a t i o n Method-Spray a n d / o r immersi on
Manufacture: Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : W B
Water 42.0
S t a r s o Sodi urn S i 1 i c a t e 12.0
EDTA, T e t r a s o d i u m (37%) 16.0
Sodium X y l e n e S u l f o n a t e (40%) 20.0
* L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 M o l e s EO) 3.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11 2 . 5 M o l e s EO) 7.0
Use D i l u t i o n : 2%-4% b v
* Rhone-Poulenc R h o d a s u r f 91-6
** Rhone-Poulenc R h o d a s u r f A-24
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t on G u i d e
aegreasers 23
S o l v e n t Denreaser
I n q r e d ient : 9
D I Water 81.18
Carbopol ETD 2623 ( 1 ) 0.32
d-Limonene ( 2 ) 10.00
Propylene g l y c o l methyl e t h e r ( 3 ) 2.00
Alkylbenzene s u l f o n i c a c i d ( 4 ) 2.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 5 ) 1.50
Isopropanol 2.50
Sodium h y d r o x i d e (50%) 0.50
(1) BFGoodrich
(2) A r y l e s s e n c e , I n c . : H-7892 d-limonene
(3) Dow Chemical : Dowanol PM
(4) Stepan C o . : B i o s o f t S-100
(5) S h e l l Chemical: Neodol 23-6.5
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogene-
ous.
3 . Reduce a g i t a t i o n and add t h e g l y c o l e t h e r , s u l f o n i c a c i d , and
alcohol ethoxyl ate.
4 . Add t h e i s o p r o p a n o l .
5 . Add t h e sodium h y d r o x i d e u n t i l t h e t a r g e t pH r a n g e i s
reached.
6 . Add c o l o r , as d e s i r e d .
T o t a l Actives:
d-limonene: 10.0
Propylene g l y c o l methyl e t h e r : 2.0
Sodium a1 k y l b e n z e n e s u l f o n a t e : 2.2
Psopropanol : 1.5
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 2.5
S o l v e n t Based Deqreaser
Comments a b o u t t h i s f o r m u l a :
1 . Use a l o w o d o r g r a d e o f t a l l o i l f a t t y a c i d .
2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d .
3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~
F o r m u l a t i o n DEG-004-01
S o l v e n t Based Degreaser
Ingredients: We ig h t %
Aristonate M 5.10
T r i t o n X-45 5.00
T r i t o n N-101 2.99
Kerosene 86.93
Comments a b o u t t h i s f o r m u l a :
1 . Kerosene can be s u b s t i t u t e d w i t h A r o m a t i c Naphtha.
2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L .
F o r m u l a t i o n DEG-003-01
E n q i n e C l e a n e r and Deqreaser
Ingredients: Weight%
Water 58.94
M I PA 20.33
C a l imu1s e PRS 5.08
Dowanol DPM 45.24
Na4EDTA 0.41
Comments a b o u t t h i s f o r m u l a :
Clear, p a l e y e l l o w product
F o r m u l a t i o n DEG-005-01
25
26 Advanced Cleaning Product Formulations
A u t o m a t i c Dishwash Deteraent-Consumer
( Z e r o Phosohate. C h l o r i n e F r e e . Powder1
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration
Composi t i on :
Sodi urn C i t r a t e D i h y d r a t e 10.0
* B r i t e s i l H20 Hydrous P o l y s i l i c a t e 20.0
Sodi urn C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol id s ) 4.0
****Sodium P e r b o r a t e Monohydrate 10.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 15.0
* 2 . 0 w e i g h t r a t i o powder w i t h 1 7 . 5 % w a t e r
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; o r use a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l
479ND ( 2 w t . % each)
**** O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m a t i c Dishwash Detersent-Consumer
(Phosphate, C h l o r i n e F r e e , Powder)
S o i 1-Food g r e a s e , o i 1 and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry blend/Agglomeration
Composi t i on :
RU L i q u i d Sodium S i l i c a t e 15.0
*Sodium C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND Sodi um P o l y a c r y l a t e (92% s o l id s ) 4.0
****Sodium P e r b o r a t e M o n o h y d r a t e 10.0
*STPP 30.0
Sodi um S u l f a t e 15.0
* FMC
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t . % each)
**** O r u s e Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t %. B a l a n c e w i t h s u l f a t e .
A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate, S o l i d B l o c k )
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Solid block
Composi t i on : Wt%
M e t s o Beads 2048 25.0
NaOH (50% S o l u t i o n ) 25.0
*STPP 35.0
*Sodi um C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 M o l e s EO; C12-15) 3.0
* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
A u t o m a t i c D i shwashi n g D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l
(L iquid)
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , c e r a m i c and g l a s s
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition : Wt%
Water 50.9
* A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) 6.9
* * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) 3.0
P o t a s s i um H y d r o x i d e (45%) 1.2
TKPP (60%) 25.0
N C l e a r Sodium S i l i c a t e 13.0
Use D i l u t i o n : 0 . 1 5 - 0 . 3 0 % bw ( 0 . 2 - 0 . 4 oz/gallon)
A u t o m a t i c D i s h w a s h D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j
(Zero-Phosphate, C h l o r i n e F r e e , Powde_rj
S o i l - F o o d g r e a s e , oil and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manuf a c t u r e - D r y B1 e n d / A g g l o m e r a t i on
Composi t io n : Wt%
M e t s o P e n t a b e a d 20 30.0
Sod1 um C a r b o n a t e 26.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s € 0 ; C12-15) 3.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e ( 9 2 % s o l i d s ) 4.0
***Sodium P e r b o r a t e M o n o h y d r a t e B l e a c h 10.0
Val f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 12.0
Autom.aticP~hwa~h_Dete~e_n~ . ~ I ~1.d_&-Ins
Stri-a -u t_ii-tluti_ o?e_a_8
LP h o s p h a t e _ , C h l _ o r i n e _Free- Pow_s1ec)
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration
Composition: Wt%
G t s o P e n t a b e a d 20 30.0
*STPP 25.0
* S o d i um C a r b o n a t e 28.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s EO; C12-15) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol i d s ) 4.0
****Sodium P e r b o r a t e Monohydrate B l e a c h 10.0
* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l C h e m i c a l Neodol 2 5 - 7
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t % e a c h )
**** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s
c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m a t i c D i s h w a s h i ng Gel w i tJ1_..Chlori n e B1 e a c h
Inqredient: Wt%
01 w a t e r 44.75
C a r b o p o l 672 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) 15.00
P o t a s s i urn c a r b o n a t e ( 3 ) 5.00
Sodium t r i p o l y p h o s p h a t e ( 4 ) 20.00
S o d i um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) 8.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 ) 1.oo
(1 BFGoodri c h
( 2 The PO C o r p .
( 3 Armand
(4 FMC C o r p .
( 5 ) O o w C h e m i c a l : Dowfax 382
Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l 1e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous
and f r e e o f p o l y m e r l u m p s .
2 . Add i n t h e p o t a s s i u m h y d r o x i d e a n d p o t a s s i u m s i l i c a t e . M i x
u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s
poi n-t.
3 . Add t h e p o t a s s i u m c a r b o n a t e and p h o s p h a t e . M i x u n t i l t h e r e
a r e no more p h o s p h a t e p a r t i c l e s . H e a t i n g t o 50-60C w i l l
speed t h i s p r o c e s s .
4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous.
A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o r e d u c e
t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . Cool t h e p r o d u c t t o
b e l o w 30C t o a v o i d e x c e s s i v e b l e a c h d e c o m p o s i t i o n .
Total Actives:
Phosphorous c o n t e n t : 5.0
S i l i c a t e (as Si02): 3.9
C a r b o n a t e ( a s Na2CO3): 3.8
Ava i 1a b 1e c ti 1o r ine : 1.o
Insredients: Wt%
Water, D . I. 57.5
W i t c o l a t e ES-3 34.2
R e w o t e r i c AM 8-14 5.0
Ethanol 3.0
Sodium C h l o r i d e 3.3
B l e n d i n g Procedure:
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . D i s s o l v e c o m p l e t e l y
between each a d d i t i o n .
Comment:
R e w o t e r i c AM 8-14: Grease c u t t e r and foam b o o s t e r .
Formula 1 3 2
Powder S t a i n l e s s S i l v e r w a r e Pre-Soak
I n q r e d ie n t s : Wt%
Sodium Carbonate (Soda Ash) 67.0
P e t r o BAF Powder 5.0
DeSonic 1 1 N 11 . o
T r i s o d i um Phosphate, Anhydrous 2.0
C a u s t i c Soda Beads 25.0
61 e n d i ng P r o c e d u r e :
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d
Use D i 1u t u i on : 1 o z / g a l
Formula 1 2 7
I n q r e d ie n t s : W B
Water, D . I . 16.0
R.U. S i l i c a t e 29.0
DeSoni c LFD-97 2.0
Sodium Carbonate (Soda Ash) 23.0
Sodium T r i p o l y p h o s p h a t e Code 185 30.0
B l e n d i n g Procedure:
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . When s l u r r y i s
produced, p o u r i n t o molds and a l l o w t o harden.
Formula 1 2 9
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 31
Ingredi e m
A : H o s t a p u r SAS 6 0 33.30
Genapol Z R O l i q u i d 17.90
B: Water 48.50
Preservative 0.10
DY e
q.s.
Perfume 0.20
Tests:
v i s c o s i t y (rnPas) : 75
C l o u d p o i n t : <-5C
Inqredients: Wto/,
A : H o s t a p u r SAS 60 33.30
Genapol ZRO l i q u i d 17.90
B: Water 47.50
P r e s e r v a t iv e 0.10
DYe
q.s.
Perfume 0.20
Genagen LAB 1 .oo
Tests:
V i s c o s i t y (mPas): 100
Cloud p o i n t : <-5C
Inqredients:
A : H o s t a p u r SAS 60 33.30
Genapol ZRO l i q u i d 17.90
B: Water 44.50
Preservative 0.10
DY e
9,s.
Perfume 0.20
Genagen LAB 4.00
Tests:
V i s c o s i t y (mPas): 2 3 0
C l o u d p o i n t : <-5c
Manufacturing:
One a f t e r a n o t h e r , t h e components o f B a r e added t o A
D i s h Washi nq A g e n t s
C l e a r , liquid, 30% WAS
a1 k a n e s u l p h o n a t e : e t h e r s u l p h a t e = 4 : 1
Insredients: W B
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21 . 4 0
Tests:
V i s c o s i t y (mPas) : 380
C l o u d p o i n t : <-5C
Inqredients: wtsl,
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21.40
0 : Water 37.30
Preservative 0.10
q.s.
DY e
Perfume 0.20
Hoe S 3924 1 .oo
Tests:
V i s c o s i t y (mPas) : 420
C l o u d p o i n t : <-5C
Ingredients: wt./,
A : H o s t a p u r SAS 60 40.00
Genapol Z R O l i q u i d 21.40
Tests:
V i s c o s i t y (mPas) : 61 0
C l o u d p o i n t : <-5C
Manufacturing:
One a f t e r a n o t h e r , t h e components o f 8 a r e added t o A .
lngredients: Wtl
Water, D . I . 66.3
W i t c o n a t e 1240 10.3
Varox 1770 5.3
W i t c o l a t e SE-5 18.1
81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y
between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y .
Typical Properties:
V i s c o s i t y , c p s : 620
S o l i d s : 16.8%
pH: 9 . 1 2
F o r m u l a 117
I n g r e d i e n t s1
Water, D . I . 70.0
W i t c o n a t e 1240 13.8
Varox 1770 3.1
W i t c o l a t e LES-6OA 8.2
Ethanol 5.0
B1 end? ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5.
Typical Properties:
V i s c o s i t y , cps: 4
S o l i d s : 10.1%
pH: 6 . 6 8
F o r m u l a 118
Ingredients: K%
Water 60.0
W i t c o n a t e AOS 26.0
W i t c a m i de 128T 4.0
W i t c o l a t e LES-6OC 10.0
Blendjng Instructions:
Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g w e l l between
a d d i t i ons .
F o r m u l a 106
Economy Eormul a t i on
In g r e d i e n t s : Wt.%
Deionized water 59.7
Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) 2 5 . 9 ( 15)
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) 8.4(5)
Ethyl alcohol 0
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
Standard Formulation
In g r e d i e m wt>
Deionized water 52.9
Dodecylbenzene s u l f o n a t e , sodium s a l t , ( 6 0 % s o l i d s ) 31 . 0 ( 1 8 )
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) 10. l ( 6 )
Ethyl alcohol 1.5
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
_ _ urn _F o r _
Premi m u l a~t i o n- ~
I n q r e d i en& Wt.%
Deionized water 28.3
Dodecyl benzene s u l f o n a t e , s o d i um s a l t , (60% s o l i d s ) 46.6( 27)
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) 15.1 (9)
Ethyl alcohol 4
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 35
Hand D i s h D e t e r a e n t F o r m u l a t i o n s
C l e a r D i shwash
IngredienPs 1 \N t %
Water 12.30
SXS (4O%j 8.00
C12 A i f a O i e f in s u i f o n a t e ( 2 8 . 7 5 % s o i i d s j 52.50
Lauryl e t h e r s u l f a t e - 3E0 (27.5% s o l i d s ) 18.20
Tomah AO-728 S p e c i a l 6.00
NaCl* 3.00
M i x i ng I n s t r u c t i o n s :
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i l homogeneous a f t e r each a d d i t i o n
SpG 2 0 / 2 0 C : 1 . 0 5
pH: 6
V i s c o s i t y : 505 c p s ( B r o o k f i e i d LVT 3 0 rpm s p i n d l e number 2)
__
P e a r i e s c e n t U i shwash
ingredients: WLL7O
Water 54.40
Dodecyibenzene s u i f o n a t e ( 6 0 % s o l i d s ) 25.00
C a u r y i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j 8 . 30
O p a c i f i e r L a t e x (4OWja 0.04
P e a r l i z i n g Agent ( 4 7 % j * * 2.30
Tomah A0-728 S p e c i a i 4.00
Tomah A m p h o t e r i c L 6.00
Mixing Instructions:
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i i homogeneous a f t e r each a d d i t i o n .
SpG 2 0 / 2 0 C : 1 . 0 3
PH: 6.5
V i s c o s i t y : 1363 c p s ( B r o o k f i e l d LVT, 12 rpm, s p i n d l e number
Hand D i s h w a s h i n g L i q u i d
C a r b o p o l r e s i n s c a n be used t o b u i l d r h e o l o g y i n p l a c e o f
u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l
and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e ,
t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y .
Inqredient: Q
D I Water 38.11
Carbopol ETD 2623 ( 1 ) 0.70
5 8 0 0 MW p o l y a c r y l i c a c i d ( 2 ) 4.00
A l p h a s u l f o m e t h y l e s t e r (37%) ( 3 ) 27.03
TEA (99%) 5.50
Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) 17.86
Coconut d i e t h a n o l ami de ( 5 ) 2.00
( 1 ) BFGoodrich
( 2 ) BFGoodrich: Good-Rite K-7058
( 3 ) Stepan Co.: A l p h a s t e p ML-40
( 4 ) Henkel C o r p . : S t a n d a p o l ES-3
( 5 ) Stepan C o . : N i n o l 11-CM
Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
P r e h e a t t h e w a t e r t o 40-5OC. Screen t h e Carbopol r e s i n i n t o
t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w
t o m i x f o r a t l e a s t 15 m i n u t e s o r u n t i l homogeneous and f r e e
o f p o l y m e r lumps.
2 . Add i n t h e l o w m o l e c u l a r w e i g h t p o l y a c r y l a t e w i t h c o n s t a n t
mixing.
3 . Add i n t h e ASME s u r f a c t a n t w i t h a l o w l e v e l o f a g i t a t i o n
t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
4 . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and c o c o n u t DEA.
5 . A d j u s t t h e pH u s i n g TEA t o r e a c h t h e t a r g e t r a n g e . Add c o l o r
and p e r f u m e , a s d e s i r e d . Cool b a t c h t o room t e m p e r a t u r e .
Total Actives:
Alpha s u l f o methyl e s t e r : 10.00
Sodium l a u r y l e t h e r s u l f a t e : 5.00
Coconut d i e t h a n o l a m i d e : 2.00
5 8 0 0 MW p o l y a c r y l i c a c i d : 2.00
Hand Dishwashina P a s t e
I n a r e d ient : Wt%
D I water 41.50
Carbopol 672 ( 1 ) 1 .oo
A l k y l b e n z e n e s u l f o n i c a c i d (9796) ( 2 ) 17.00
Sodi um h y d r o x i d e (50%) 5.00
2 . 4 r sodium s i l i c a t e (52%) ( 3 ) 7.50
Sodium t r i p o l y p h o s p h a t e ( 4 ) 15.00
Sodium c a r b o n a t e 5.00
Sodium o l e f i n s u l f o n a t e (40%) (5) 8.00
( 1) BFGoodri ch
(2) Stepan Co.: B i o s o f t S-100
(3) The PO Corp.
(4) FMC Corp.
( 5 ) Stepan Go.: E i o t e r g e AS-40
Procedure:
1 . Use a L i g h t n i n ’ M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneou
and f r e e o f polymer lumps.
2 . Add t h e s u l f o n i c a c i d w i t h c o n t i n u o u s a a i t a t i o n .
3 . Add t h e sodium h y d r o x i d e and sodium s i l i c a t e w i t h c o n t i n u o u s
a g i t a t i on. M i x u n t i1 homogeneous.
4 . S l o w l y , add t h e phosphate. M i x u n t i l homogeneous and f r e e o f
phosphate p a r t i c l e s . H e a t i n g t h e p r o d u c t t o 50-60C w i l l speed
up t h i s p r o c e s s .
5 . Add t h e sodium c a r b o n a t e and o l e f i n s u l f o n a t e . M i x u n t i l
homogeneous.
6 . A d d c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t ives :
Phosphorous c o n t e n t : 3.7
S i l i c a t e (as Si02): 2.7
Carbonate ( a s Na2C03): 5.0
Sodium o l e f i n s u l f o n a t e : 3.2
Sodium a l k y l b e n z e n e s u l f o n a t e : 17.6
1
38 Advanced Cleaning Product Formulations
Ingredients: Wt%
Water, D . I . 30.2
W i t c o l a t e SE-5 21.7
W i t c o n a t e 1260 S l u r r y 36.7
W i t c a m i de 128T 5.0
P e t r o LBA L i q u i d 1.9
Sodium S u l f a t e 2.6
Ethanol 1.8
Formal i n 0.1
P e r f u m e , Dye 9,s.
81 e n d i n g P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0
using C i t r i c Acid.
Typical Properties:
V i s c o s i t y , c p s : 230
A p p e a r a n c e : C1 e a r L i q u i d
F o r m u l a 113
L i g h t D u t y L i q u i d Low C o s t Hand D i s h w a s h
Ingredients:.
W a t e r , D . I. 81 . 5
W i t c o l a t e SE-5 5.5
W i t c o n a t e 1260 S l u r r y 9.2
W i t c a m i d e 128T 1.2
P e t r o LBA L i q u i d 0.5
Sodium C h l o r i d e 2.0
Formal i n 0.1
Perfume, Dye q.s.
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t pH=6.5-7.0
using C i t r i c Acid.
Typical Properties:
V i s c o s i t y , c p s : 170
Appearance: C l e a r L i q u i d
Formula 116
B : T e t r a p o t a s s i u m P y r o p h o s p h a t e , t e c h n i c a l powder 10.00
Sodi um T r i p o l y p h o s p h a t e , t e c h n i c a l powder 20.00
D: Sodium X y l e n e s u l f o n a t e 2.25
Deceth-4-Phosphate 0.75
Procedure:
P r e h e a t t h e w a t e r t o 5 5 t o 60C. H y d r a t e t h e Van Gel ES
s l o w l y b y a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed
d i s p e r s e r . Preblend B i n g r e d i e n t s , Add B t o A s l o w l y w i t h
m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r
l i s t e d , mixing u n t i l dissolved. Continue mixing w h i l e c o o l i n g
r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e
m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n
of air).
C o n s i s t e n c y and pH:
Pumpable l i q u i d , V i s c o s i t y 1300-1800 c p s , B r o o k f i e l d Model
LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r
3 0 days a g i n g ; pH a p p r o x i m a t e l y 1 2 . 5 .
Manual D i shwashi n q G e l
F u n c t i o n s & B e n e f i t s : C a r b o p o l EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent
o f surfactant type
*provides high c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form
i n i r e d l ent : Wt%
DI w a t e r 37.50
C a r b o p o l EX-473 ( 3 0 % ) * 10.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e ( 1 8 % ) 2.00
Ammonium l a u r y l s u l f a t e (30%)** 25.00
Sodium l a u r y l e t h e r s u l f a t e (30%)*** 25.00
* V i s c o s i t y modi f i e r : B F G o o d r i c h
* * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical
* * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: S t e p a n C h e m i c a l
P h y s i c a l P r o p e r t i es :
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 , 0 0 0 C P
P r o d u c t pH: 6 . 5 - 7 . 0
Product c l a r i t y : c l e a r
Procedure:
1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d b y a L i g h - t n i n ' m i x e r
o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e C a r b o p o l
EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m a n d
homogeneous.
2 . Add t h e sodium c i t r a t e . M i x u n t i l t h e sodium c i t r a t e i s
completely dissolved.
3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH.
4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l s o d i u m h y d r o x i d e i f
necessary.
6 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
_ _ D i shwashi nq L i q u i d
Manual
F u n c t i o n s B B e n e f i t s : Carbopol EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, i n d e p e n d e n t
o f surfactant type
*provides h i g h c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form
I n g r e d i en t . yt%
DI w a t e r 43.00
Carbopol EX-473 ( 3 0 % ) 5.50
Ammonium l a u r y l s u l f a t e (30%)* 25.00
Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + 25.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e (18%) I .oo
* A n i o n i c s u r f a c t a n t : S t a r i d a p o l A : Stepari Chemical
* * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: Stepan Chemical
Physical Properties:
B r o o k f i e l d R V T v i s c o s i t y - 2 0 rpm: 5 0 0 CP
Product pH: 6.5-7.0
Product c l a r i t y : Clear
Procedure:
1 . Using slow a g i t a t i o n (200 r p m ) provided by a L i g h t n i n ' Mixer
o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e C a r b o p o l
E X - 4 7 3 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and
homogeneous.
2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
3 . Add t h e sodium c i t r a t e , M i x u n t i l t h e sodium c i t i - a t e i s
completely dissolved.
4 . A d j u s t t h e p H w i t h sodium h y d r o x i d e .
5 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
N o n - C h l o r i n a t e d M a c h i n e D i s h w a s h i n q Compound, Liquid
I n Q r e d ie n t s : \Mt%
Water, D . I . 79.5
Sodi um T r i p o l y p h o s p h a t e 2.0
Versene 2 2 0 , Powder 1 .o
Sodi um G1 u c o n a t e 1.o
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 7.0
C a u s t i c Soda 50% 8.5
P e t r o ULF L i q u i d 1 .o
81 e n d i ng P r o c e d u r e :
Add a l l components i n t h e o r d e r shown, m i x i n g w e l l between
a d d i t i ons.
F o r m u l a 109
Ingredients:
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 30.0
Sodi um T r i p o l y p h o s p h a t e (STPP) , L i g h t D e n s i t y 25.0
DeSoni c LFD-97 1. o
Sodium M e t a s i l i c a t e , Anhydrous 30.0
C a u s t i c Soda Beads 10.0
CDB C l e a r o n 4.0
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly w i t h
each a d d i t i o n .
F o r m u l a 111
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly
w i t h each a d d i t i o n .
F o r m u l a 112
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 43
P r e m i um Hand D i shwashi ng D e t e r q e n t
Inqredients: Wt%
Water, D . I . 6.9
A1 p h a - S t e p MC-48 56.0
S t e o l CS-330 30.0
N i n o l 30-LL o r N i n o l 40-CO 5.6
Sodium C h l o r i d e 1.5
P r o p e r t i es :
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 6 . 5 - 7 . 5
V i s c o s i t y @ 25 deg. C , c p s : 220
S o l i d s , % : 39-40
Density, l b s / g a l : 8 . 8
Freeze/thaw, 3 c y c l e s : Pass
C o l d s t o r a g e @ 4 deg. C . , 2 weeks: Pass
F l a s h p o i n t , deg. F: >200
M i x i n g Procedure:
CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO
and m i x u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n .
M i x u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e
as n e c e s s a r y .
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
Inqredi ents:
Water 79.0
Lumorol 4154 12.0
Z e t e s o l NL 6.0
Z u s o l a t 1008/85 1.o
Sodium c h l o r i d e approx. 2 . 0
F o r m u l a t i o n CT 02-01-04
m e d ien t s : Wt%
Water 76.5
Z e t e s o l 2056 20.0
Amphotensid B 4 2.0
Z u s o l a t 1008/85 1.o
P u r t o n CFD 0.5
F o r m u l a t i o n CT-02-01-05
44
General Purpose Cleaners 45
Carbopol r e s i n s a r e used t o a c h i e v e a s t a b l e s u s p e n s i o n o f
t h e c a l c i u m carbonate a b r a s i v e o a r t i c l e s i n t h e presence o f
c h l o r i n e bleach
lnqredient : Wt%
DI[ Water 53.76
Carbopol 674 o r 691* 0.80
Good-Rite K-7058 (50%)** 2.00
Sodi um h y d r o x i d e (50%) 2.80
2 . 4 ~sodium s i l i c a t e (52%) 2.50
Sodium h y p o c h l o r i t e (14%) 7.14
C a l c i urn c a r b o n a t e * * * 30.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e (45% **** 1 .oo
*Suspension a i d : BFGoodrich
* * A n t i - r e d e p o s i t i o n : BFGoodrich
+ * + A b r a s i v e : W h i t e #8 ( G e o r g i a M a r b l e )
* * * * A n i o n i c s u r f a c t a n t : Dowfax 382 (Dow Chemi
Physi ea9 P r o p e r t i e s :
B r o o k f i e l d RVT v i s c o s i t y - 20 rpm: 3,960 c p
Product pH: 12-13
P r o d u c t c l a r i t y : Opaque
~ ~ ~ ~ ~ d ~ r ~
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous
2. Add t h e low m o l e c u l a r w e i g h t p o l y a c r y l a t e p o l y m e r f o l l o w e d
by t h e sodium h y d r o x i d e and sodium s i l i c a t e . M i x u n t i l
homogeneous.
3. Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e b l e a c h .
(The p r o d u c t w i l l d r o p i n v i s c o s i t y a t t h i s p o i n t . )
4. Add t h e c a l c i u m c a r b o n a t e and f i n a l l y t h e s u r f a c t a n t w i t h
c o n s t a n t a g i t a t i o n . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .
A b r a s i v e Cleaner W i t h o u t B1 each
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m carbonate
abrasives .
Insredient: Wt%
D I Water 62.10
Ethanol 2.00
Carbopol 674 ( 1 ) 0.60
Sodium h y d r o x i d e (50%) 1 .00
Sodium b i c a r b o n a t e 1.20
Calcium carbonate ( 2 ) 30.00
C12-15 1in e a r a1 coho1 , 3 moles EO ( 3 ) 2.50
Coconut d i e t h a n o l ami de ( 4 ) 0.60
( 1 ) BFGoodr ich
( 2 ) G e o r g i a M a r b l e Co.: G e o r g i a M a r b l e W h i t e # 8
( 3 ) S h e l l Chemical: Neodol 25-3
( 4 ) Stepan Co.: N i n o l 11-CM
Procedure:
1 . Add t h e e t h a n o l t o t h e w a t e r - h o l d i n g back 10 p a r t s o f w a t e r
f o r s t e p #3.
2 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ’
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n
t h e Carbopol r e s i n i n t o t h e D I w a t e r / e t h a n o l m i x t u r e . M i x t h e
s l u r r y for a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s
homogeneous.
3 . P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f w a t e r w i t h
t h e sodium h y d r o x i d e and sodium b i c a r b o n a t e . Add t h i s t o t h e
m i x t u r e formed above and m i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e , a l c o h o l e t h o x y l a t e and coconut QEA.
M i x u n t i l homogeneous.
5 . Add f r a g r a n c e , as d e s i r e d .
Total Actives:
C a l c i um c a r b o n a t e : 30.0
C12-15 l i n e a r a l c o h o l , 3 moles EO: 2.5
Coconut DEA: 0.6
A l l Purpose C l e a n e r
Ingredients: Wei q h t %
Urea 2.00
Na4EOTA 2.00
Water 88.00
2990 Ammonia 1 .oo
C a l s o f t L-40 5.00
C a l o x y l a t e N-9 2.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-001-01
A l l Purpose C l e a n e r
Ingredients: Wei q h t %
Na4EDTA 4.00
Water, Perfume 84.00
Dowanol DPnB 4.00
C a l s o f t L-40 8.00
Comments a b o u t t h i s f o r m u l a :
Compare t o M r . C l e a n , a t r a d e m a r k o f P r o c t o r & Gamble.
F o r m u l a t i o n APC-002-01
A l l Purpose C l e a n e r
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s f i r s t and m i x .
2 . Add w a t e r s l o w l y .
3 . M i x u n t i l homogeneous.
F o r m u l a t i o n APC-005-01
A l l Purpose C l e a n e r
Comments a b o u t t h i s f o r m u l a :
Formula t h i c k e n s e f f e c t i v e l y .
F o r m u l a t i on APC-003-01
A l l Purpose C l e a n e r
Inqredients: Wei q h t %
Na4EDTA 5.00
Water 77.50
Calamide C 2.50
Calamide CWT 2.50
P i l o t SXS-40 2.50
Laurami ne O x i d e 10.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-006-01
A l l Purpose C l e a n e r
Inqredients: Wei q h t %
Na4EDTA 5.00
Water 76.10
50% NaOH 0.80
Cal s o f t LAS-99 2.80
P i l o t SXS-40 5.30
Calamide C 5.00
Calamide CWT 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-007-01
A l l Purpose C l e a n e r - No R i n s e
Inqredients: Weight%
Water 89.00
C a l f a x 1OL-45 3.00
Na4 EDTA 3.00
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
Calamide CWT 2.00
Comments a b o u t t h i s f o r m u l a :
Spray a s i s , t h e n w i p e w i t h a p a p e r t o w e l .
F o r m u l a t i o n APC-008-01
A 1 1- P u r p o s e C 1 e a n e r
Composi t ion :
K e l z a n x a n t h a n gum 0.3
A1 ip a l CD-128 1.7
G a f a m i d e CDD 518 0.5
B u t y l C e l l o s o l ve 3.5
S o d i urn M e t a s i 1 ic a t e 1.7
T r i s o d i urn P h o s p h a t e 1.o
Water, Perfume 91.3
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n a n d 15 p e r c e n t G e n e t r o n
12.
All-Purpose
- D i s i n f e c t a n t Cleaner
Composi ti= Q
K e l z a n x a n t h a n gum 0.5
Makon 1 0 10.0
Sodium T r i p o l y p h o s p h a t e 3.0
V e r s e n e 100 3.0
Hyarnine 1 O X 1.o
Water 82.5
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s a s i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t G e n e t r o n
12.
SOURCE: M o n s a n t o P e r f o r m a n c e M a t e r i a l s : K e l z a n S u g g e s t e d
Formulations
A l l Purpose C l e a n e r
l n q r e d i en& Wt%
R h o d a t e r g e SMC 10
STPP 2
Water 88
81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 145
S o l i d s : 17.0%
pH: 8 . 8
Formula 514
A l l Purpose C l e a n e r
Ingredients: wto/,
Water 56.0
W i t c o n a t e 1 2 6 0 S1 u r r y 38.5
Witcamide 6445 5.5
Blending Procedure:
B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d .
Typical Properties:
V i s c o s i t y , c p s : 670
Sol i d s : 33.0%
pH, as i s : 9 . 2
Formula 520
A1 1 Purpose C l e a n e r
Ingredients: W S
Water 90.0
Sodi um T r i p o l y p h o s p h a t e 2.0
C a u s t i c Soda, 50% 0.5
W i t c o 12988 2.0
W i t c a m i de 6 4 4 5 5.0
Perfume, Dye q.s.
Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d .
T y p i c a l P r o p e r t ie s :
Speci f ic G r a v i t y : 1 . 0 2 0 6
Wt./Gal. l b s . : 8 . 5
pH, as i s : 9 . 1 2
V i s c o s i t y , c p s : 107
Color: Beige
Use D i l u t i o n : 1 - 2 o z . / G a l .
Formula 535
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
General Purpose Cleaners 51
A l l Purpose C l e a n e r C o n c e n t r e
(Phosphate, - L i q u i d , Foam)
S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Spray
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Use D i l u t i o n : Normal D u t y - 1 . 5 % bw ( 2 o z / g a l l o n )
Heavy D u t y - 2 . 5 % b w ( 3 . 3 o z / g a l 1on)
Tough D u t y - a s s u p p l i e d
* Rhone-Poulenc R h o d a f a c RE-610
**( Dow, A r c 0 C h e m i c a l
*** Rhone-Poulenc I g e p a l CA-630
**** Rhone-Poulenc I g e p a l CA-520
A l l Purpose C o n c e n t r a t e
(Phosphate, Liquid1
S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : wto/,
Water 78.75
M e t s o Beads 2048 1 .oo
TKPP 3.00
Sodium X y l e n e S u l f o n a t e , 40% 3.50
*Ethylene Glycol n-Butyl Ether 6.00
Pine O i l 0.25
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 M o l e s EO) 5.00
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 M o l e s EO) 2.50
Use D i 1u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )
* Dow C h e m i c a l , U n i o n C a r b i d e
*l Rhone-Poul enc R h o d a s u r f LA-7
*S* Rhone-Poulenc R h o d a s u r f A-24
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
52 Advanced Cleaning Product Formulations
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m c a r b o n a t e
abrasives .
I n q r e d ie n t :
D I Water 62.10
Carbopol ETD 2623 ( 1 ) 0.25
Sodium h y d r o x i d e (50%) 0.20
C12-I5 l i n e a r a l c o h o l , 3 moles EO ( 2 ) 1.50
Sodium a l k y l benzene s u l f o n a t e ( 3 ) 0.50
Calcium carbonate ( 4 ) 30.00
P h y s i c a l P r o p e r t ies :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 7,500 c p
P r o d u c t pH: 8-10
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) Stepan Co. : Nacconol SQG
( 4 ) Georgia Marble C o . : Georgia Marble White #8
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i ng and b l endi ng o p e r a t i o n s , d i s p e r s e
o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e
s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y
i s homogeneous.
2. Add t h e sodium h y d r o x i d e t o r e a c h t a r g e t pli. The p r o d u c t
w i l l become v e r y t h i c k a t t h i s p o i n t .
3 . Add t h e a l c o h o l e t h o x y l a t e and a l k y l b e n z e n e s u l f o n a t e s u r f -
a c t a n t s . M i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .
Total Actives:
Calcium carbonate: 30.00
C12-15 l i n e a r a l c o h o l , 3 moles EO: 1.50
Sodium a1 k y l b e n z e n e s u l f o n a t e : 0.50
C i t r i c A c i d Cleaner
Inqiredi e n t : Wt%
DI Water 78.40
Carbopo? ETD 2623 R e s i n * 0.10
C12-15 l i n e a r a l c o h o l , 3 moles EO** 5.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO*** 2.50
Alkylbenzene s u l f o n i c acid**** 2.00
C i t r i c A c i d (50%) 12.00
P h y s i c a l P r o p e r t iee: S t o r a g e Temperature
-25C
. 5oc
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm:
Initial: 50cP 50cP
Age-Up V i s c o s i t y : Week 2 : 170cP 400cP
Week 4 : 250cP 600cP
Week 6: 350cP 400cP
P r o d u c t pH: 1 . 4
Product c l a r i t y : T r a n s l u c e n t
Procedurw:
4. U s i n g J m a r i n e b l a d e p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm)
p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t ,
s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l o w
t o h y d r a t e f o r 15-20 m i n u t e s o r u n t i l no lumps a r e p r e s e n t .
Warming t h e d e i o n i z e d w a t e r t o 30C w i l l decrease t h e h y d r a t i o n
t i m e and i m p r o v e t h e d i s p e r s i b i l i t y o f t h e Carbopol powder.
2. M i x t h e Neodol 25-3 and Neodol 2 3 - 6 . 5 ( o r warm s l i g h t l y i f
needed) t o e n s u r e homogeneity. A d d w i t h moderate m i x i n g (300
r p m ) . A l l o w t o mix u n t i l u n i f o r m and smooth.
3. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) m i x i n g and
a l l o w t o m i x u n t i l u n i f o r m and smooth.
4. S ~ O W add ~ Y t h e C i t r i c A c i d w i t h s l o w m i x i n g (200 r p m ) . M i x
u n t i l smooth and u n i f o r m .
5. Add f r a g r a n c e and c o l o r , a s d e s i r e d .
S O U R C E : B F G o o d r i c k S p e c i a l t y ChemicaJs: DET-352
54 Advanced Cleaning Product Formulations
G e n e r a l P u r p o s e C1 e a n e r
(Consumer Low Alkaline, Non-Phasphate Powder)
S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y
and p a r t i c u l a t e s o i l
Surface-Hard surface, i . e . , metal, p l a s t i c , ceramic, concrete,
and a s p h a l t
A p p l i c a t i on Method-Wi p e o r B r u s h
Manufacture-Dry blend/Agglomeration
Composi t i o n : Wt%
Sodi um C a r b o n a t e ( 1 i g h t d e n s i t y ) 30.0
* B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e 10.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
* * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5
Sodi um S u l f a t e 14.5
Use L e v e l : 1-4 o z / g a l l o n
* 2 . 0 w e i g h t r a t i o s i l i c a t e powder, 82.5% s o l i d s
** Rhone-Poulenc R h o d a s u r f LA-9
*** Rohm & Haas
G e n e r a l Purpose C l e a n e r
(Consumer H i g h A 1 k a l ine, Non-Phosphated Powder1
Composi t i o n 1 Wt%
Sodium S u l f a t e 14.5
Sodi um C a r b o n a t e ( 1 ig h t d e n s i t y ) 30.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
M e t s o Beads 2048 10.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5
Use L e v e l : 1-4 o z / g a l l o n
* Rhone-Poulenc R h o d a s u r f LA-9
** Rohm & Haas
G e n e r a l P u r p o s e S p r a y & Wipe C l e a n e r
Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h i s
"no-drip" action w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e a s w e l l a s enhance consumer c o n v e n i e n c e .
Ingredient: wto/,
D I Water 90.70
C a r b o p o l ETD 2 6 9 1 ( 1 ) 0.20
EDTA ( t e t r a s o d i u m s a l t ) 2.00
Sodium m e t a s i l i c a t e , a n h y d r o u s 2.30
P r o p y l ene g l y c o l m e t h y l e t h e r ( 2 ) 3.00
C12-15 l i n e a r a l c o h o l , 7 m o l e s EO ( 3 ) 1.50
( 1 ) BFGoodri c h
( 2 ) Dow C h e m i c a l : Dowanol DPM
( 3 ) S h e l l C h e m i c a l : Neodol 25-7
Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e .
3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l
e t h o x y 1a t e .
4 . Add c o l o r and f r a g r a n c e , a s d e s i r e d .
T o t a l Actives:
Propylene g l y c o l methyl e t h e r : 3.0
C 1 2 - I 5 l i n e a r a l c o h o l , 7 m o l e s EO: 1.5
Ingredients: Wt%
Water, D.I. 79.0
Sodi um C i t r a t e 2.0
A1 p h a - S t e p MC-48 10.0
S t e p a n o l WA-Extra 7.0
N i n o l 11-CM 2.0
M i x i n g Procedure:
Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and
m i x u n t i 1 homogeneous.
T y p i c a l P r o p e r t i es :
Appearance: C l e a r c o l o r l e s s l i q u i d
pH, as i s : 9 . 4
Viscosity I 3 2 5 deg. C : V e r y t h i n
S o l i d s , %: 1 0 . 0
Density, l b s / g a l : 8.54
C o l d s t o r a g e @ 4 d e g . C, 1 d a y : p a s s
F r e e z e / t h a w , 3 c y c l e s : pass
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s
Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s
Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n c o m m e r c i a l
product.
Use I n s t r u c t i o n s : Use as i s
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
A1 1 -Purpose C1 e a n e r
Ingredients:
Water 82.0
Z e t e s o l 2056 14.0
Z u s o l a t 1008/85 4.0
H y p o c h l o r it e V e r t i c a l S u r f a c e C l e a n e r
M o n a t r o p e 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t
c o n t r i b u t e s t o w e t t i n g and f o a m i n g c h a r a c t e r i s t i c s .
In q r e d ie n t s : Wt%
M o n a t r o p e 1250 2.0
Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) 2.0
Laurami ne O x i d e (30%) 10.0
P o t a s s i u m H y d r o x i d e (45%) 15.0
Sodi um T r i p o l y p h o s p h t e 5.0
Sodium H y p o c h l o r i t e 5 . 2 5 % ) 66.0
Procedure:
Add i n g r e d i e n t s w t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r y e l l o w l i q u i d
p H : 13
Pump S p r a v A l l Purpose C l e a n e r
Inqredients: Wt%
Water 94.0
M o n a t e r g e 779 (DEA-Laureth S u l f a t e ) 3.0
Propylene Glycol B u t y l Ether 3.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Typical Properties:
Appearance: C l e a r l i q u i d
Recommended Use D i 1 u t i o n : As i s
L i q u i d C 1 eanser w i t R B1 each
Ingredients:
A : Van Gel B 2.25
Water 62.25
6 : Diatomaceous E a r t h '10.00
Sodium c a r b o n a t e 4.50
Sodium h y p o c h l o r i t e , 5 . 2 5 % s o l n . 20.00
Sodium L a u r y l S u l f a t e , 29% s o l n . 1 .oo
Procedure:
S l o w l y add Van Gel B t o t h e w a t e r w h i l e a g i t a t i n g a t maximum
a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add r e m a i n i n g
i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n .
A l l Purpose C l e a n e r
Clear, liquid
Ingredients: Wt%
A : H o s t a p u r SAS 6 0 10.0-15.0
Genapol ZRO 1 iq u i d 0.0- 4.0
Genapol UD-080 1.0- 3 . 0
B : Water ad 1 0 0 . 0
Perfume 0.2
Preservative 0.1
Dye q.s.
Manufacturing:
Add one a f t e r a n o t h e r , t h e components o f B t o A .
Ingredients: g
Pine o i l 20.0
N i n o l 11-CM 9.0
Makon 12 5.0
Ammonyx LO 0.5
B i o - S o f t S-1 0 0 2.0
Isopropanol 10.0
Water, D . I . 53.5
M i x i ng Procedure:
Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add
water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
Odor: P i n e
V i s c o s i t y @ 25C, c p s : 50
pH ( a s i s ) : 8 . 1
D e n s i t y 1b s / g a l : 8 . 0 6
Freeze/Thaw ( 3 c y c l e s ) : Pass
50 C oven ( 1 week): Pass
Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s
Commercial f o r m u l a t i o n : 5 5 . 5 % s o i l removed f r o m t i l e s
SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 208
D i s i n f e c t i n g Cleaner, Alkaline
Ingredients: Wt%
Water 57.5
C i t r i c acid 2.0
Z u s o l a t 1008/85 3.5
Lumorol 4192 5.0
Trilon A liquid 7.0
Lonzabac-1230 25.0
Ingredients: Wt%
Water 69.0
Disodium t e t r a b o r a t e decahydrate 0.5
Sodi um b i c a r b o n a t e 1.0
Burdac-114 20.0
Z u s o l a t '1008/85 9.5
Ingredients: g
Water 57.5
Trilon A liquid 7.0
Citric acid 2.0
S u l f e t a l 4069 5.0
Z u s o l a t 1008/85 3.5
Lonrabac-1230 25.0
Sodi urn B i c a r b o n a t e A b r a s i v e C l e a n e r W i t h o u t B l e a c h
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e s u s p e n s i o n o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e
abrasives.
Ingredient:
- wtsl,
D I Water 44.25
C a r b o p o l ETD 2691 ( 1 ) 0.50
A l k y l benzene s u l f o n i c a c i d ( 2 ) 0.75
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s € 0 ( 3 ) 2.50
Sodium h y d r o x i d e ( 5 0 % ) 2.00
Sodium b i c a r b o n a t e ( 4 ) :
Grade 1 : 20.00
Grade 5 : 30.00
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): 6,000 c p
Product pH: 8.50
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Stepan Co.: B i o s o f t 5-100
( 3 ) S h e l l C h e m i c a l C o . : Neodol 2 3 - 6 . 5
( 4 ) Church & Dwight
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d b y t h e a l c o h o l
e t h o x y l a t e . M i x u n t i l homogeneous.
3 . Add t h e s o d i u m h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH
t o 8.50 p r i o r t o t h e next step.
4 . W i t h m i n i m a l a g i t a t i o n , s l o w l y add t h e s o d i u m b i c a r b o n a t e .
M i x u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e l u m p s .
Re-check p H and a d j u s t , i f n e c e s s a r y .
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .
T o t a l A c t iv e s :
S o d i um b i c a r b o n a t e : 50.00
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s EO: 2.50
Sodium a1 k y l benzene s u l f o n a t e : 0.90
SOURCE: B F G o o d r i c h S p e c i a l t y C h e m i c a l s : DET-342
leaners/Polishes
61
62 Advanced Cleaning Product Formulations
In g r e d i e n t s : MIBo/o
Water 90.0
Isopropyl Alcohol 9.0
Adogen 66 0.I
Varox 365 0.5
Emcol 4500 0.4
Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l Alcohol can be used
t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can b e used t o
f a c i l i t a t e m i x i n g o f t h e Emcol 4500.
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, e t c . ) and
wipe onto t h e glass. A l l o w t o d r y .
Product I n f o r m a t i o n :
Product: Benefit :
Varox 365 W e t t i n g a g e n t , d e g r e a s e r and d e t e r g e n t
Adogen 66 A n t i - s t a t i c agent
Emcol 4500 W e t t i n g a g e n t , c o u p l e r and d e t e r g e n t
T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r
v a p o r ( f o g , steam, e t c . ) and t h e g l a s s w h i c h w i l l p r e v e n t
f o g g i n g . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r
prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o the glass;
t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much a s i t i s when p a s s i n g
through i n d i v i d u a l d r o p l e t s .
F o r m u l a 708
Ingredients:
Water, D . I . 84.9
P e t r o BAF L i q u i d 0.1
Isopropanol 10.0
E t h y l e n e G l y c o l Monobutyl E t h e r 5.0
Dye q.s.
B l e n d i ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r 1is t e d .
F o r m u l a 705
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Glass CleanerslPolishes 63
G l a s s C l e a n e r C o n c e n t r a t e (Non-Ammoniated)
Ingredients: K%
W a t e r , D . I. 7.5
I s o p r o p a n o l , 99% 82.0
P e t r o LBA Powder 1.o
Monoethanol ami ne 0.5
Perfume, Dye q. s
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
T h i s c o n c e n t r a t e s h o u l d be m i x e d w i t h n i n e p a r t s o f w a t e r
t o one p a r t c l e a n e r t o b e r e a d y t o u s e . T h i s p r o d u c t r e q u i r e s
a red label.
F o r m u l a 702
Use D i l u t i o n : 1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r .
F o r m u l a 703
Amrnoniated G l a s s C l e a n e r
m r e d ients: Wt%
Water 94.0
W i t c o l a t e 231 0 3.0
B u t y l C e l l o s o l ve 2.0
Aqua Ammonia, 26 B e ' 2.0
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
64 Advanced Cleaning Product Formulations
G l a s s and Window C l e a n e r
Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h j s
"no-drip" a c t i o n w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e as w e l l as enhance consumer c o n v e n i e n c e .
Inaredient: wel
D I Water 92 * 45
Carbopol ETD 2623 (4.10
Isopropanol 5.00
Ammonium h y d r o x i d e 0.20
A l k y l b e n z e n e s u l f o n i c a c i d (97%) ( 2 ) 0.25
Propylene g l y c o l methyl e t h e r (3) 2.00
Physical Properties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 200 c p
P r o d u c t pH: 9 . 5 - 1 0 . 0
Product C l a r i t y : Clear
Raw M a t e r i a1 Suppl ie r s :
( 1 ) BFGoodrich
( 2 ) Stepan Chemical: B i o s o f t 5-100
( 3 ) Dow Chemical: Dowanol PM
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e i s o p r o p a n o l .
3 . Add t h e ammonium h y d r o x i d e . M i x u n t i l homogeneous.
4 . Add t h e s u l f o n i c a c i d and g l y c o l e t h e r w i t h m i n i m a l a g i t a t i o n
t o a v o i d e x c e s s i v e foaming.
5 . Add a d d i t i o n a l ammonium h y d r o x i d e , i f necessary, t o r e a c h the
t a r g e t pH r a n g e .
6 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
Ammonium a l k y l b e n z e n e s u l f o n a t e : 0 . 3 0
Propylene g l y c o l methyl e t h e r : 2.00
Isopropanol: 5.00
H o u s e h o l d Window C l e a n e r
Inqredients: Wt%
Water. D . I . 89.3
Isopropanol 10.0
Varox 365 0.7
Methylene Blue q.s.
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ies:
V i s c o s i t y , cps: 4
S o l i d s : 0.2%
pH: 7 . 4
F o r m u l a 706
Ingredi ents: Q
Water, D . I . 89.4
Isopropanol 10.0
Varox 1770 0.6
Methylene Blue q. s
81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties :
V i s c o s i t y , cps: 4
S o l i d s : 0.23%
pH: 6 . 2
F o r m u l a 707
GI ass @1e a n e r
Ingredients: Wt%
Water. D . I . q.s.
Isopropanol 6.0
Dowanol EB 4.0
R e w o t e r i c AM V 0.85
81 endi ng P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r shown, mixing thoroughly bet-
ween each a d d i t i o n .
F o r m u l a 709
SQURCE: W i t c o G o r p . : Suggested F o r m u l a t i o n s
66 Advanced Cleaning Product Formulations
W i n d o w s / G l ass
Gl-ass Cl g a n g r C C o n c e n t r a t e )
Ingredients: We i s h t YO
Water 10.04
Ethylene G l y c o l Monobutyl Ether 21.34
Isopropyl Alcohol 53.30
Ammonia, 2 9 . 4 % 2.35
C a l foam SLS-30 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n WIN-001-01
W i n-dzhield Washer C c n c e n t r a t e
Ingredients: Weigh_%
Water 47.66
Isopropyl Alcohol 47.30
C a l s u d s 81 5.10
Comments a b o u t t h i s f o r m u l a :
Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n .
F o r m u l a t i o n WIN-002-01
Comments a b o u t t h i s f o r m u l a
Use l e v e l : 2-4 o z p e r g a l l o n .
F o r m u l a t i o n WIN-003-01
SOURCE: P i l o t C h e m i c a l C o . : Suggested F o r m u l a t i o n s
ard Surface Cleaners
67
68 Advanced Cleaning Product Formulations
In g r e d i e n t s :
Water, D . I . 34.0
Sodi um M e t a s i 1 ic a t e 8.0
Varami de A-83 12.0
W i t c o n a t e 30DS 40.0
W i t c o n a t e SXS L i q u i d 8.0
81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .
Typical Properties:
V i s c o s i t y , c p s : 205
S o l ids : 3 4 . 4 %
pH: 1 2 . 5
F o r m u l a 516
Ingredients: \Ne%
Water, D . I . 82.0
T e t r a s p o t a s s i u m P y r o p h o s p h a t e , Anhydrous 10.0
W i t c a m i de 1 PET 1.o
Emphos 5AP 4.0
W i t c o 1298S A 3.0
Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d , m i x i n g w e l l a f t e r each
addition.
Typical Properties:
S p e c i f i c G r a v i t y : 1.085
Wt./Gal. l b s : 9.04
pH, a s i s : 7 . 5 7
V i s c o s i t y , c p s : 94
3 Freeze/Thaw c y c l e s : Passed
1 Week @ 52C: Passed
4 Weeks Room Temp: Passed
S o l i d s : 17.8%
Appearance: C 1 e a r L i q u i d
Use D i l u t i o n : 1-3 o z . / g a l .
F o r m u l a 540
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Hand Surface Cleaners 69
Ingredients: Wei q h t %
D e o d o r i z e d Kerosene 25.00
Calamide CWT 16.30
C a l o x y l a t e N-9 9.00
E t h y l e n e G l y c o l Monobutyl E t h e r 9.00
Water 41 .30
N a4 E DTA 0.40
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1-2 o z p e r g a l l o n .
F o r m u l a t i o n HSC-009-01
P i n e Cleaner
Pine
- Cleaner
Ingredients: Weight%
Pine O i l 15.00
C a l s u d s CD-6 10.00
C a l o x y l a t e N-9 8.00
IPA 10.00
Water 57.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-007-01
H a r d S u r f a c e Cleanerc
Ingredients: weight%
Water 75.25
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
Dowanol PnB 6.00
P i l o t SXS-40 9.00
C a l o x y l a t e N-9 5.50
P i n e 01 1 0.25
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n HSC-001-01
Hard-Surface-C1 @anex
Ingredi ents : Wi q h t 9 6
Water 74.50
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
P i l o t SXS-40 7.00
Cal imu1 se PRS 3.00
Dowanol PnB 5.00
Cal o x y l a t e N-9 6.50
Comments s b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-002-01
H a r d S u r f a c e Cle&ne_r
Ingredisnts : Weisht_"L.
Water 79.30
Sodi um M e t a s i 1 i c a t e 5.20
Na4EDTA 2.50
P i l o t SXS-40 5.00
Calamide CWT 8.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1 - 4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-005-01
Hardsu.!-33Cs~_ec1eaner
Irns r e d i en t-s 1 We i_pht %
Water 58.50
Sodi um C i t r a t e 15.00
Soda Ash 5.00
Ammonia, 29% 3.50
P i l o t SXS-40 8.00
Calamide CWT 1O.DO
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-006-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Hand Sqface Cleaners 71
Blending Procedure:
Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 4
S o l i d s : 10.2%
pH: 10.8
F o r m u l a 507
H a r d S u r f a c e C l e a n e r C o n c e n t r a t e w/d'Limonene
Ingredients:
Phase I:
Isopropanol 10.0
Oleic A c i d 8.8
.Varoni c K205 5.0
d ' L i monene 12.0
Phase 11:
Water, D . I . 62.2
P o t a s s i u m H y d r o x i d e (87%) 2.0
B1 e n d i ng P r o c e d u r e :
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase 11.
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 75
S o l i d s : 13.8%
pH: 1 0 . 2
F o r m u l a 508
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
72 Advanced Cleaning Product Formulations
S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d )
M a n u f a c t u r e - M i x t a n k w i t h p r o p e l 1e r s t i r r e r
ComDosition A:
Water 71.4
TSP 1.6
S t a r s o Sodium S i l i c a t e 14.0
Sodium H y d r o x i d e (50%) 4.0
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 Moles EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) 1 .2
Composition B: Wt%
Water 65.4
TSP 1.6
S t a r s o Sodi um S i 1 ic a t e 18.0
Sodium H y d r o x i d e (50%) 5.0
*Phosphate E s t e r 6.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 M o l e s EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 1.2
S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Spray and w i p e
Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r
Composi t i on : Wt%
~-
Water 90.00
TKPP 2.00
N C l e a r Sodium S i l i c a t e 1.88
Sodium H y d r o x i d e (50%) 0.12
* D i p r o p y l ene G1 y c o l Monomethyl E t h e r 5.00
* * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 12-13 M o l e s EO 1 .00
Use: As i s , spray
* Dow Chemical
** Rhone-Poulenc I g e p a l CA-720
Hard S u r f a c e C l e a n e r C o n c e n t r a t e w/Dipentene
I nnredi e n t s : Wt%
Phase I :
Isopropanol 10.0
Oleic Acid 8.8
V a r o n i c K205 5.0
D i pentene 12.0
Phase 11:
Water, D . I . 62.2
Potassium H y d r o x i d e (87%) 2.0
B l e n d i n g Procedure:
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase XI ~
Typical Properties:
V i s c o s i t y , cps: 50
Solids: 13.8%
pH: 10.1
Formula 509
A 1 k a l ine Hard S u r f a c e C l e a n e r
I n q r e d ients: Wt%
Water, D . I . 62.7
Sodi um M e t a s i 1i c a t e 3.0
Varami de A-83 5.0
\Mi t c o n a t e 3 0 D S 6.8
W i t c o n a t e SXS L i q u i d 2.5
B l e n d i n g Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 32
S o l i d s : 1 1 .O%
pH: 12.0
Formula 515
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
74 Advanced Cleaning Product Formulations
L i q u i d A b r a s i v e C 1e a n s e r
Inqredients: Wt%
Water, t a p 48.5
C a l c i u m c a r b o n a t e , 100 mesh 42.5
Sodium t a l l o w soap, f l a k e s 2.0
A l p h a - S t e p MC-48 2.5
N i n o l 11-CM 2.0
Sodi um C h l o r i d e 2.5
M i x i ng P r o c e d u r e :
Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g .
Add soap and m i x u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m i x
u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .
P r o p e r t i es :
Appearance: Opaque, o f f - w h i t e creamy l i q u i d
pH, a s i s : 9 . 3
V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c
s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 c p s
s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 c p s
s p i n d l e # 3 , 30 rpm, B r o o k f i e l d : 3060 c p s
S o l i d s , % : 50
D e n s i t y , l b s / g a l : 11.69
S t o r a g e a t a m b i e n t temp, 1 week: N o s e p a r a t i o n
Use I n s t r u c t i o n s : Use as i s
Performance:
C l e a n s g r e a s e p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l
t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .
SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 3 1 4
T i l e and Sani t a r v C l e a n e r s
Inqredients: Wt%
Amphotensid B 4 30.0
Water 60.0
Citric acid 10.0
Ingredients: Wt%*
A : Van Gel ES, Magnesium Aluminum S i l i c a t e 4.00
Rhodopol 23, Xanthan Gum 0.50
D e i o n i z e d Water 68.50
Procedure:
1 . D r y b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m .
C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add P a r t I3 t o P a r t A, m i x f o r 5 m i n u t e s and t h e n add P a r t C
and m i x f o r 5 m i n u t e s .
F o r m u l a t i o n No. 303
Ingredients: W t .%*
A : Veegum, Magnesi um A1 umi num S i 1 i c a t e 1.20
Rhodopol 23, Xanthan Gum 0.40
D e i o n i z e d Water 48.40
C: C12-CI3 L i n e a r P r i m a r y A l c o h o l E t h o x y l a t e
(Neodol 23-6.5) 9.00
Cocamide DEA ( N i n o l 40-CO) 1 .oo
P r e s e r v a t i v e , Dye, F r a g r a n c e q.s.
Procedure:
1 . D r y b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm.
C o n t i n u e m i x i n g f o r 20 m i n u t e s .
2 . Add P a r t B and m i x f o r 10 m i n u t e s .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
m i n u t e s a f t e r each a d d i t i o n .
F o r m u l a t i o n f r o m S h e l l Chemical Co.
AS r e c e i v e d b a s i s
M o l d and M i l d e w Remover
I n p r e d ie n t : \Rlt%
D I water 84.50
Carbopol 672 ( 1 ) 1 .00
Sodium h y d r o x i d e (50%) 2.00
Sodium m e t a s i l i c a t e , p e n t a h y d r a t e 0.50
P r i m a r y a l k a n e s u l f o n a t e (40%) ( 2 ) 5.00
Sodium h y p o c h l o r i t e (15.00%) 7.00
B r o o k f ie l d v i s c o s i t y (RVT-PO rpm) : 120 cps
P r o d u c t p H : 12-13
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodrich
( 2 ) Stepan C o . : B i o - T e r g e PAS-8S
Procedure :
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i ng o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under moderate a g i t a t i o n , add t h e sodium h y d r o x i d e and t h e
metasilicate.
3. Add t h e a l k a n e s u l f o n a t e .
4 . Under l o w a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
Primary alkane sulfonate: 2.0
Available chlorine: 1.0
77
78 Advanced Cleaning Product Formulations
Inpredi ents: Q
Genapol OA-080 3.0
DDBS-Na* 15.0
Thermphos NW 25.0
T a l l o w soap, Powder 1 .O-3.0
Sodi um d i s i 1 i c a t e 3.0
S o k a l a n CP 5 1 .o
S o k a l a n HP 22 1 .o
A q u a m o l l i n BC Powder 0.5
Perfume q.s.
Sodi um s u l p h a t e ad 1 0 0 . 0
Manufacturing:
To b e p r e p a r e d by s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l p h o n a t e
Inqredients: Wt%
Genapol OA-080 3.0
DDBS-Na* 15.0
Z e o l i t h A (Wessalith 20.0-25.0
T a l l o w soap, Powder 1.0- 3.0
Sodi um d i s i 1 ic a t e 3.0
S o k a l a n CP 5 2.0- 3.0
S o k a l a n HP 22 1 .o
Aquamoll i n BC Powder 0.5
Perfume q.s.
Sodium s u l p h a t e ad 100.0
Manufacturing:
To b e p r e p a r e d b y s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l f o n a t e
SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
Laundry Products 79
Heavy D u t y L a u n d r y
Ingredients: Wei q h t %
Water 28.90
Sodi um H y d r o x i d e , 50% 6.60
Calamide C 7.00
P i l o t SXS-40 12.50
Cal s o f t LAS-99 40.00
Cal o x y l a t e N - 9 5.00
Comments a b o u t t h i s f o r m u l a :
Add C a l o x y l a t e N - 9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d .
F o r m u l a t i o n HDL-001-01
Heavy D u t y L a u n d r y
Inqredients: Wei o h t %
Water 42.50
P i l o t SXS-40 22.50
Calamide CWT 4.00
Sodium S i l i c a t e ( S o l i d ) 3.01
C a l s o f t L-60 18.00
EDTA (Ethylenediaminetetraacetic A c i d ) 2.50
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-006-01
Heavv D u t y L a u n d r y
I n q r e d ie n t s : Weight%
Water 78.50
C a l f a x DB-45 7.00
C a l o x y l a t e N-9 7.00
P r o p y l ene G1 y c o l 2.50
TKPP ( T e t r a P o t a s s i um Pyrophosphate) 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-007-01
Heavv D u t y L a u n d r y
Inqredients: Wei q h t %
Water 42.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 15.00
Sodium S i l i c a t e ( S o l i d ) 10.00
C a l s o f t L-60 18.00
P i l o t SXS-40 10.00
Calamide CWT 5.00
Comments a b o u t t h i s f o r m u l a :
May need t o be h e a t e d t o s o l u b i l i z e t h e s u r f a c t a n t .
F o r m u l a t i o n HDL-008-01
Components: % by Weisht
Water 50.00
T r i e t h a n o l ami ne 85% 3.25
D i e t h y l ene G1 y c o l 20.00
B u r c o l 117 10.00
B u r c o l LAF-6 10.00
Burcowi t e BBH-PO 1.25
B u r c o t a s e SL-160 0.50
Procedure:
Charge 1 / 2 o f w a t e r I3 120F. Add 1 , 2 , 3 , & 4 and b l e n d . Add
r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B l e n d u n t i l u n i f o r m .
1% pH: 9 . 5
% s o l i d s : 26
Lbs/gal : 8.66
S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes
Ingredients: % bv W e i q h t
Water 30
TKPP 5
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 5
B u r c o t e r g e DG-40 40
B u r c o NPS-876 10
SXS-40% 10
Powder f o r A u t o m a t i c D i s h w a s h i n n M a c h i n e s
Ingredients: YO by W e i q h t
A Genapol 2908 1 .oo
B Sodium m e t a s i 1 i c a t e x 5H20 52.00
C Sodium c a r b o n a t e 10.00
Sodi um d i c h l o r o i s o c y a n u r a t e 2.00
Thermphos NW 35.00
Manufacturing:
I Spray A on B .
I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1
A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i s h w a s h i n g l i q u o r
I nsredient : Wt%
D I water 49.00
Carbopol ETD 2691 ( 1 ) 0.50
612-15 l i n e a r a l c o h o l , 7 moles EO ( 2 ) 18.00
Sodium a l k y l b e n z e n e s u l f o n a t e (60%) ( 3 ) 5.50
Potassium h y d r o x i d e (45%) 2.00
Sodium m e t a s i l i c a t e , anhydrous 5.00
T e t r a p o t a s s i u m pyrophosphate 20.00
P h y s i c a l Pi-opert ie s :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900
P r o d u c t pH: 14
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical C o . : Neodol 25-7
( 3 ) Stepan Co.: B i o s o f t D-62
PP.0cedure:
I . Use a b i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous
and f r e e o f polymer lumps.
2. W i t h s l o w m i x i n g , add i n t h e a l c o h o l e t h o x y l a t e and a l k y l -
benzene s u l f o n a t e s u r f a c t a n t s .
3. C o n t i n u e a g i t a t i n g and add t h e p o t a s s i u m h y d r o x i d e and meta-
s i li c a t e .
4. Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o a v o i d a i r
entrapment.
5. Add dyes and f r a g r a n c e , as d e s i r e d .
I n d u s t r i a l Laundry D e t e r a e n t s
H i g h C a u s t i c Formula-
Components: % bv Weiaht
Burco NPS-816 15.0
Burcosperse LP 10.0
B u r c o l i t e BSGH-255 5.0
Dequest 2000 5.0
50% NaOH 65.0
Procedure:
B l e n d a l l components e x c e p t 50% NaOH. S l o w l y add NaOH w i t h
a g i t a t i o n . Keep t e m p e r a t u r e below 1 6 0 F d u r i n g t h e e n t i r e
agitation.
Mixed B u i l d e r F o r m u l a t i o n
Components: % by Weight
Water 31.5
45% KOH 23.5
B u r c o s p e r s e LP 10.0
TKPP 10.0
Burco NPS-816 15.0
S t a r Grade Sodium S i l i c a t e 10.0
Procedure:
D i s s o l v e KOH i n w a t e r . S l o w l y add Burcosperse LP w h i l e
a g i t a t i n g . Keep t e m p e r a t u r e below 160F. Add TKPP and s t i r u n t i l
d i s s o l v e d . Add Burco NPS-816, t h e n S t a r Grade Sodium S i l i c a t e
and b l e n d u n t i l u n i f o r m .
Washi np P a s t e w i t h 81 e a c h i n g A g e n t
Ingredients: % b y Weiaht
Water 39.0
Sodium t r i p o l y p h o s p h a t e 3.0
Sodium d i t h i o n i t 12.0
Xanthan Gum 2.0
Whi t e - s p i r i t 10.0
Lumorol 4154 30.0
Zusol a t 1005/85 5.0
L a u n d r y Deteraent-Consumer
(Liquid)
Composition: Wt%
Water 37.6
Fluorescent Brightener 0.2
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l A S E - I 08 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s €0 10.0
Potassium H y d r o x i d e (45%) 2.2
***Sodium C i t r a t e ( a n d / o r C i t r i c A c i d ) 25.0
K a s i l #6 Potassium S i l i c a t e 12.5
EDTA 5.0
Enzymes ( P r o t e a s e ) 1.o
L a u n d r y Detergent-Consumer
I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )
Composition : Wt%
Water 52.6
C a r b o p o l 674 0.5
D L i q u i d Sodium S i l i c a t e 8.1
* A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 0.9
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-.13, EO 6 . 5 M o l e s ) 4.3
Laundry Detergent-Consumer
( Z e r o Phosphate, Powder)
Laundry Detergent-Consumer
(Phosphate, Powder)
Composi t i on : Q
B r i t e s i l H20 Hydrous P o l y s i l i c a t e 10.0
*STPP 30.0
*Sodium Carbonate 30.0
Sodi um S u l f a t e 14.5
* * L i n e a r A1 k y l benzene Sul f o n a t e (LAS) 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 5.0
O p t i c a l B r i g h t e n e r , Perfume 0.5
* FMC
** Stepan Nacconol 90G (90% a c t i v e ; powder)
*** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co.
Neodol 25-7
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 85
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
( L i q u i d , Phosphate1
Composition A :
Water 34.1
TKPP 10.0
P o t a s s i urn H y d r o x i d e (45%) 30.4
S t a r Sodium S i l i c a t e 18.0
Sodium H y d r o x i d e (50%) 7.5
C o m p o s i t i o n B: wts/,
Water 25.6
TKPP 10.0
P o t a s s i u m H y d r o x i d e (45%) 30.4
S t a r Sodi um S i 1 i c a t e 24.0
Sodium H y d r o x i d e (50%) 10.0
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: %
Water 0-20
N C l e a r Sodium S i l i c a t e 70-90
Sodium H y d r o x i d e (50%) 10-20
Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA/Zeol it e , P o w d e d
Composi t i on :
M e t s o Beads 2048 25.0
Sodi um C a r b o n a t e 38.0
NTA 15.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) 12.0
V a l f o r 100 Z e o l i t e A 10.0
Use L e v e l : L i g h t S o i l - O . 2 5 % b y w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
L a u n d r y B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - U s e as r e c e i v e d
Composi t i on : Wt46
M e t s o Beads 2048 100.0
Use D i l u t i o n : L i g h t S o i l - O . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y -
Heavy S o i l - O . 7 5 % by w e i g h t o r 3 l b s p e r 100 I b s
1a u n d r y
N o t e : Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) at
2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundqi Products 87
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Phosphate, Powder)
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Sodium Carbonate, Powder)
SQURCE: PQ G o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
88 Advanced Cleaning Product Formulations
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate. Powder, H i g h A l k a l i n i t y )
Laundrv B r e a k - I n d u s t r i a1 8, I n s t i t u t i o n a l
( Z e r o Phosphate Powder, H i ah A1 k a l in i t v )
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Reduced Phosphate, Powder)
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA, Powder)
SOURCE: PQ C s r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
90 Advanced Cleaning Product Formulations
Laundry D e t e r q e n t - I n d u s t r i a l B I n s t i t u t i o n a l
(Sodium Carbonate w i t h F l o w A i d . Powder)
Use L e v e l : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 1 0 0 l b s
1aundry
Medium S o i l : 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1 aundry
Heavy S o i l : 0.75% b y w e i g h t o r 3 l b s p e r 100 l b s
1 aundry
Laundry D e t e r g a n t - I n d u s t r i a l & I n s t i t u t i o n a l
IPhosphate, S o l i d Block)
Composi t i on : Wt%
Metso Beads 2048 25.0
NaOH ( 5 0 % S o l u t i o n ) 25.0
*STPP 35.0
*Sodium Carbonate 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 3.0
* FMC
** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 91
Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
(Zero Phosphate, Powder)
Composition : Wt%
Sodi um C a r b o n a t e 35.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles € 0 ; C12-15) 15.0
V a l f o r 100 Z e o l i t e A 25.0
M e t s o Beads 2048 25.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a1 k a l in i t y is d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t blend.
*Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
L a u n d r y D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
92 Advanced Cleaning Product Formulations
Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l
[ P h o s p h a t e B u i 1t , L i q u i d )
Composition A: Wt%
Water 54.5
TKPP 4.6
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodium S i l i c a t e 15.0
Sodi um H v d r o x i d e (,5 0 %.) 4.2
*PhosphaGe E s t e r 5.0
**Liquid Nonionic Surfactant (C12-C15, 7-9 M o l e s € 0 ) 3.0
C o m p o s i t i o n B: Wt%
Water 59.1
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodi um S i 1 i c a t e 15.0
Sodium H y d r o x i d e ( 5 0 % ) 4.2
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3.0
Use D i l u t i o n : 0 . 2 5 % - 0 . 5 0 % b y w e i g h t or 1-2 l b s p e r 1 0 0 l b s
1a u n d r y
* Rhone-Poulenc Rhodafac RE-610
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9
Composition: wts/,
Water 28.7
F1 u o r e s c e n t B r i g h t e n e r 0.1
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l ASE-108 ( A c r y l i c P o l y m e r ) 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 M o l e s EO 10.0
P o t a s s i um H y d r o x i d e (45%) 2.2
TKPP (60%) 40.0
K a s i 1 #6 P o t a s s i um S i 1 i c a t e 12.5
Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 1 0 0 I b s
1a u n d r y
* Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%)
**Rhone-Poulenc I g e p a l CO-630
Composition A : Wt%
P o t a s s i u m H y d r o x i d e (45%) 35-45
iU C l e a r o r E Sodium S i l i c a t e 55-65
C o m p o s i t i o n B: Wt%
Water 11.0
Potassium Hydroxide ( S o l i d ) 37.0
N C l e a r or E Sodium S i l i c a t e 52.0
Composition C: Wt%
Water 6.0
Potassium Hydroxide ( S o l i d ) 28.0
N C l e a r o r E Sodium S i l i c a t e 52.0
Sodium H y d r o x i d e ( S o l i d ) 14.0
N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
( Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )
Composition: WtO/o
Water 57.06
C a r b o p o l 674 0.5
Metso Beads 2048 2.7
*Acusol 445N Sodi um P o l y a c r y a t e (45% s o l d s ) 1.04
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-13; EO 6 . 5 M o l e s ) 4.3
8 Rohm 8: Haas
** S h e l l Chemical Neodol 2 3 - 6 . 5
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
94 Advanced Cleaning Product Formulations
Laundry P r e s o o t t e r S p r a y a b l e Gel
Inaredi ent:
D I water 83.75
Carbopol ETD 2623 ( 1 ) 0.20
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 males €0 ( 3 ) 5.00
EDTA ( t e t r a sodium s a l t ) 0.50
Sodium h y d r o x i d e (18%) 0.55
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) S h e l l Chemical C o . : Neodol 23-6.5
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . M i x u n t i l
homogeneous.
3. Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO ( 2 ) : 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 3 ) : 5.0
I n s r e d ie n t : Wt%
D I water 84.30
Carbopol ETO 2623 ( 1 ) 0.05
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) 5.00
EOTA ( t e t r a sodium s a l t ) 0.50
Sodi um h y d r o x i d e (18%) 0.15
( 1 ) BFGoodri ch
( 2 ) S h e l l Chemical Co.: Neodol 2 5 - 3
( 3 ) S h e l l Chemical Co.: Neodol 2 3 - 6 . 5
Procedure:
I . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2. Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . Mix u n t i l
homogeneous.
3 . Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r s o l u t i o n and f r a g r a n c e , as d e s i r e d .
Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO: 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 5.0
L i g h t Duty L i q u i d Detergent
Ingredients: wej-ghs
Water 48.45
P i l o t SXS-40 7.50
C a l s o f t L-60 30.00
Calamide C 5.00
C a l foam EA-603 8.30
C a l s o f t LAS-99 0.60
C i t r i c Acid 0.10
Sodium C i t r a t e 0.05
Comments a b o u t t h i s f o r m u l a :
1 . pH=7.1
2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e i f pH i s l o w .
3 . V i s c o s i t y s h o u l d b e 300 c P s .
F o r m u l a t i o n LDL-001-01
Ingredients: Weight%
Water 22.31
C a l s o f t L-60 39.70
P1 l o t s x s - 4 0 22.10
Calamide C 7.06
C a l f o a m EA-603 7.35
C a l s o f t LAS-99 0.56
Opaci f i e r 0.88
Sod1 um C i t r a t e 0.04
Comments a b o u t t h i s f o r m u l a :
1 . Add e i t h e r C i t r i c A c i d o r C a l s o f t LAS-99 t o a d j u s t pH t o
7.0-7.2.
2 . S o l i d s 45%.
3 . S u b s t i t u t i n g C a l s o f t L-40 for C a l s o f t L-60 w i l l lower
p r o d u c t s o l i d s t o 42%.
F o r m u l a t i o n LDL-002-01
L i g h t Duty L i q u i d Detergent
Ingredients: Weight%
Water 18.80
Calsuds A 70.00
C a l foam ES-303 10.00
Perfume 0.10
K a t h o n CG 0.10
Opaci f ie r 1.oo
Comments a b o u t t h i s f o r m u l a :
1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r
2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e
detergent.
F o r m u l a t i o n LDL-004-01
L i g h t -Duty L i q u i d Detergent
Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n
blending.
2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH a d j u s t m e n t
t o 7+.
3 . S a l t ( S o d i u m o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y .
F o r m u l a t i o n LDL-006-01
L i g h t Duty L i q u i d Detergent
In g r e d i e n t s : Weight%
Water 36.90
P i l o t SXS-40 5.00
C a l s o f t T-60 40.00
C a l foam ES-303 15.00
Calamide C 2.00
P r e s e r v a t iv e 0.10
S o d i um C h l o r i d e 1 .00
Comments a b o u t t h i s f o r m u l a :
V i s c o s i t y 275 cPs.
Sol i d ~ = 3 2 - 3 3 %
pH=6.2
F o r m u l a t i o n LOI-007-01
L i g h t Duty L i q u i d Detergent
Ingredients: Weight%
Water 65.16
P i l o t sxs-40 6.29
L i n e a r A1 coho1 E t h o x y l a t e 2.52
NaOH, 5 0 % 2.81
D i e t h a n o l am1 ne 0.43
C a l s o f t LAS-99 19.77
Comments a b o u t t h i s f o r m u l a :
S o l 1 ds=30%
Good f o r g r e a s y a p p l i c a t i o n s .
F o r m u l a t i o n IDL-006-01
SOURCE: P i l o t C h e m i c a l Co : S u g g e s t e d F o r m u l a t i o n s
98 Advanced Cleaning Product Formulations
L i g h t Duty L i q u i d Detergent
I n g r e d i ent-sl Weight%
Water 13.90
Ammonium C h l o r i d e 2.40
P i l o t sxs-40 19.60
C a l s o f t L-60 44.10
Cal foam ES-303 15.80
Calamide C 4.00
C i t r i c Acid 0.10
P r e s e r v a t iv e 0.10
Comments a b o u t t h i s f o r m u l a :
1 . “ A s i s ” pH=8.0.
2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH.
F o r m u l a t i o n LDL-009-01
Ligh-t- D u t y L i q u i d D e t e r q e n t
C a l s o f t LAS-99 Based
Ingredients: Weight%
Water 43.60
NaOH, 50% 5.80
C a l s o f t LAS-99 21.70
P i l o t SXS-40 16.70
Cal foam ES-303 3.00
C a l o x y l a t e N-9 8.00
C i t r i c Acid 0.10
Opaci f ie r 1 .oo
Preservative 0.10
Comments a b o u t t h i s f o r m u l a :
A d d in g r e d i e n t s i n o r d e r 1 is t e d .
F o r m u l a t i o n LDL-011-01
L i g h t D u t y L i q u i d Detergent
C a l s o f t LAS-99 Based
Ingredients: Weight%
Water 52.40
NaOH, 50% 4.40
Cal s o f t LAS-99 16.30
Calamide C 5.00
P i l o t SXS-40 12.50
Cal foam ES-303 2.20
C a l o x y l a t e N-9 6.00
C i t r i c Acid 0.10
Opaci f ie r 1.oo
Comments a b o u t t h i s f o r m u l a :
Add ingredients i n order l i s t e d .
F o r m u l a t i o n LDL-012-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Laundry Products 99
a h t Duty L i q u i d Detergent
__
C a l s o f t LAS-99 Based
Inaredients; Weight%
Water 54.60
C a l s o f t LAS-99 16.30
NaOH, 50% 4.35
Alcohol Ethoxyl a t e 10.00
Calamide C 2.05
P i l o t SXS-40 12.50
Perfume 0.10
P r e s e r v a t iv e 0.10
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Formul a t i on LDL-014-01
Light DutLLCquid D e t e r E n t
Dry Cleaner: Pre-Spot-Water S o l u b l e
Ingredients: Weight%
Water 75.70
Calamide C 2.00
C a l o x y l a t e N-9 11.00
C a l i mu1 s e PRS 11 .oo
C i t r i c Acid 0.20
Perfume & C o l o r 0.10
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as
C a l o x y l a t e N-9 i s added.
2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e m i x e d
together.
3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a .
4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r .
F o r m u l a t i o n LDY-001-01
Li-ght D u t y Li.qu2d D e t e r g e n t
Wool _Wash
I c g r e d i ents-: Wei g h t %
C a l s o f t T-60 14.15
C a l ami d e CW-100 5.48
C a l f o a m ES-303 39.64
C i t r i c Acid 0.13
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 520 c P s .
F o r m u l a t i o n LDY-002-01
L i g h t D u t E L i q u j d Detergent
--
Wool Wash
Ing r e d i g n t s : We1 g h t %
Calsuds A 50.06
Water 49.93
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 25 c P s .
F o r m u l a t i o n LDY-004-01
Detergent Additive
Components: % by Weight
Water 60.00
Burco NPS-816 10.00
Neodol 25-7 12.50
Dodecylbenzenesulfonic Acid 11.65
TEA-85 5.85
Procedure:
Add components in the order listed. Blend until homogeneous
between each addition.
Use Level:
Break: 4-12 ounces/100 pounds
Detergent: 2-4 ounces/100 pounds
U l t r a L i q u i d Laundrv Deterqent
Ingredients: Wt%
A l p h a - S t e p MC-48 29.0
Sodi urn 01e a t e 5.0
Alcohol, Ethoxylate, 7 19.0
Borax 1.3
3A A l c o h o l 0.5
P r o p y l ene G1 y c o l 5.0
PVP K-15 0.8
W a t e r , f r a g r a n c e & dye Q . S . t o 100.0
M i x i n g Procedure:
Combine A l p h a - S t e p MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y -
l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous.
H e a t t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m i x
u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o
c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h
m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f n e c e s s a r y .
Typical Formulation Properties:
F o r m u l a t i o n D e s c r i p t i o n : SME/Soap Based HDL
pfl: 8-10
V i s c o s i t y : 200-350 c p s
Density: 8.6
Appearance: C l e a r , l i g h t y e l l o w 1 q u i d
Use I n s t r u c t i o n s : Use 1 / 3 c u p p e r n o r m a l s i z e w a s h l o a d
Comment:
A l p h a - S t e p MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t c a n
make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s .
F o r m u l a t i o n N o . 658
F i n e F a b r i c Wash
Ingredients: Wt%
Water, D . I . 43.4
A l p h a - S t e p MC-48 46.0
N i n o l 30-LL 4.6
Sodi um c h l o r i d e 6.0
M i x i n g Procedure:
Charge w a t e r and MC-48 and m i x . Add 30-LL and m i x u n t i l
homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h
s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 7 . 5
V i s c o s i t y @ 25 deg. C, c p s : 220
S o l i d s , %: 2 9 . 0
F r e e z e / t h a w , 3 c y c l e s : pass
C o l d s t o r a g e @ 4 deg. C, 1 week: p a s s
H i g h temp. s t o r a g e @ 50 deg. C, 1 week: p a s s
Density, l b s / g a l : 0.6
Use I n s t r u c t i o n s :
Use s m a l l amount f o r hand w a s h i n g o r 1 / 4 cup f o r machine
washing.
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
F o r m u l a t i o n No. 358
SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s
9. Metal Cleaners and Polish
Metal Cleaners and Polishes 103
Inqredients: y
&
A: Veegum 0.8
Rhodopol 23 0.4
Water 72.1
6: T e t r a s o d i u m EDTA 0.9
1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i ine 0.8
Phosphoric a c i d 15.0
Diatomaceous E a r t h 10.0
Procedure:
B l e n d Veegum and Rhodopol S l o w l y add them t o t h e w a t e r w h i l e
a g i t a t i ng a t maximum a v a i 1ab e s h e a r . C o n t i n u e m i x i n g u n t i l
smooth. Add B i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each
a d d i t i o n u n t i l smooth and un f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) .
Consistency: White, pourable l i q u i d .
Suggested P a c k a g i n g : P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y
labeling f o r acid.
*U.S. P a t e n t No. 4,302,253
D i ppi ns C1 e a n e r f o r S i 1v e r
Ingredients:
Z u s o l a t 1008/85 2.5
Thiourea 8.0
Hydrochloric acid 3.0
Water 86.5
A1 umi num C1 e a n e r / B r i g h t e n e r
T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t -
ergency t h e n n o n i o n i c s , b u t were n o t c o m p a t i b l e i n a c i d systems.
T h i s f o r m u l a t i o n uses Avanel S - 7 0 , an a n i o n i c m o l e c u l e w h i c h
p e r f o r m s even a t v e r y low p H ' s and a i d s i n t h e removal o f s u r f a c e
o i l s and d e p o s i t s . U n l i k e n o n i o n i c s , Avanel 5-70 w i l l d i s s o l v e
r e a d i l y i n t o the formulation without forming gel p a r t i c l e s thus
e l i m i n a t i n g t h e need f o r e x c e s s i v e a g i t a t i o n . T h i s f o r m u l a t i o n
can be used f o r o v e r - t h e - r o a d aluminum t r a i l e r s , w i r e wheels
on a u t o m o b i l e s o r i n t h e p r e p a r a t i o n o f aluminum f o r a n o d i z i n g
and c l eani ng.
Inqredients: Wt%
Dei o n i zed Water 83.0
Phosphoric A c i d ( 8 5 % ) 6.0
C i t r i c Acid (50%) 8.0
N i t r i c Acid (70%) 1.o
Avanel S-70 2.0
Procedure:
Charge t h e w a t e r t o a m i x i n g v e s s e l . Under slow a g i t a t i o n and
w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0
and m i x 10 m i n u t e s . NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d ,
t h e n i t r i c a c i d c o n c e n t r a t i o n may be i n c r e a s e d t o 1 . 5 % .
F o r m u l a t i o n CM-101
Powdered M e t a l C l e a n i n g C o n c e n t r a t e
I n a r e d ients: Wt%
Sodi um H y d r o x i d e 58.5
Sodium Carbonate 13.5
STPP 20.0
Avanel 5-70 8.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
A1 u m i num C1 eaner
Ingredients:
D e i o n i z e d Water 85.0
Avanel S - 7 0 6.0
T e t r a p o t a s s i u m Pyrophosphate 5.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
C a r b i t o l Solvent 3.0
Procedure:
Charge v e s s e l w i t h i n g r e d i e n t s i n t h e o r d e r l i s t e d u s i n g mod-
e r a t e a g i t a t i o n . NOTE: Other Avanel p r o d u c t s c o u l d be used i n
t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .
UhWeight
Water 75
Sodium M e t a s i l i c a t e (Anhydrous) 10
T e t r a Potassium Pyrophosphate (Powder) 5
Mona NF-10 10
Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e
i n w a t e r w i t h m i x i n g , t h e n add Mona N F - 1 0 .
Typical Properties:
Appearance : C l e a r 1 iq u i d
Cloud P o i n t : 8 8 C
Recommended Use D i l u t i o n : 1 t o 4 o z / g a l
% By Weiaht
Water 88
Sodium M e t a s i l i c a t e (Anhydrous) 2
T e t r a Sodium Pyrophosphate (Powder) 3
B u t y l Carbi t o 1 2
Mona N F - I 0 5
Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a sodium p y r o p h o s p h a t e
i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10.
Typical Properties:
Appearance: C l e a r 1 iq u i d
pH: 1 2 . 8
B u f f i nq Compound Remover
Component: %
Water 42.5
TEA 20.0
B u r c o t r o p e 1250 12.5
B u r c o s p e r s e LP 12.5
Borax 5.0
B u r c o TME 5.0
B u r c o LAF-6 5.0
H o t A1 k a l in e P a i n t S t r i p p e r C o n c e n t r a t e
Compo n e n t s : a
45% KOH 67
K a s i l #1 32
B u r c o HCS-50 NF 1
M e t a l De-Oi 1 in g L i q u i d C o n c e n t r a t e
(Liquid)
S o i l - Petroleum-based o i l
S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c .
A p p l i c a t i o n Method - Spray a n d / o r i m m e r s i o n
Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r
Composi t i on : wtu/,
Water 42.0
Starso 12.0
EDTA, T e t r a s o d i u m ( 3 7 % ) 16.0
Sodi um X y l ene S u l f o n a t e ( 4 0 % ) 20.0
C9-C11 L i n e a r A l c o h o l , 6 Moles EO 3.0
C9-C11 L i n e a r A l c o h o l , 2.5 M o l e s EO 7.0
Use D i l u t i o n : 2%-4% b v
Cutting O i l
Cutting O i 1
Inqredients:
100 P a l e O i l 90.0
Monalube 205 5.0
Monalube 215 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C l e a r Amber L i q u i d
V i s c o s i t y ( 4 0 C ) : 25 CS
.
Fa1 e x : 2250 Lbs / 6 0 I n . -Lbs .
Appl i c a t i ons: F o r machi n i ng s t a m p i n g and d r a w i n g .
F o r m u l a t i o n F-792
Cutting O i l
Inqredients: Wt%
100 P a l e O i l 85.0
Monalube 205 5.0
Monalube 215 5.0
Monalube 225 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
V i s c o s i t y / 4 0 C : 30 CS
Performance Data:
F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 7 0 I n . . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Appl i c a t i ons: Heavy d r a w i n g and s t a m p i n g
F o r m u l a t i o n F-793
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
108 Advanced Cleaning Product Formulations
Cutting O i l
Ingredients: %
&
100 P a l e O i l 90.0
Monalube 215 5.0
Monalube 225 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
T y p i c a l P r o p e r t ie s :
Appearance: C l e a r Amber L i q u i d
V i s c o s i t y 40C: 27 CS
Performance D a t a :
F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Formul a t ion F-794
Cuttina O i l
Insredients: WtO/o
100 Pale O i l 95.0
Monalube 225 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
V i s c o s i t y 40C: 24 C S
Performance D a t a :
F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s .
Draw Bead E f f i c i e n c y : 90
Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115
Formul a t ion F-795
Cutting Oi1
Inqredients: Wt%
100 P a l e O i l 90.0
Monalube 215 5.0
Monalube 325 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C l e a r Dark Brown L i q u i d
V i s c o s i t y 40C: 22 CS
P e r f o r m a n c e Data:
F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 5 I n . - L b s .
F o r m u l a t i o n F-796
Cutting O i l s
Semi-Synthetic-Cutting Oi1
Ingredients: Wei q h t %
A r i s t o n a t e M-LF 17.77
Oleic Acid 2.98
TEA 2.75
P r o p y l ene G l y c o l 15.04
Water 61.48
Comments a b o u t t h i s f o r m u l a :
1 . M i x a l l of t h e i n g r e d i e n t s , e x c e p t t h e P r o p y l e n e G l y c o l .
2 . Add t h e w a t e r SLOWLY.
3 . Add t h e P r o p y l e n e G l y c o l l a s t .
F o r m u l a t i o n SOF-001-01
C u t t i n g O i 1 Concentrate
Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-001-01
Cutting O i 1 C o n c e n t m e
I ny,,edie n t s : Weight%
Aristonate M 51.80
Neodol 2 5 - 3 21.60
TEA, 85% 4.50
Oleic Acid 8.50
D i e t h y l ene G1 y c o l 8.60
Water 5.00
Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 1 0 0 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 1 6 0 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-002-01
G e n e r a l Purpose Machine C l e a n e r
T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l
t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s
i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .
In g r e d i e n t s :
Water 69.00
T r i e t h a n o l a m i ne 4.00
Monacor 4000 3.50
Monami ne CF-1 OOM 6.00
M o n a t e r i c CyNa-50 6.00
T e t r a s o d i u m EDTA (40%) 10.00
T r i a d i n e 10 ( P r e s e r v a t i v e ) I .50
Procedure:
Mix t h e i n g r e d i e n t s i n o r d e r a t ambient temperature. M i x we1 1
between each a d d i t i o n a t moderate speed.
Typical Properties:
Appearance: C l e a r amber l i q u i d
S p e c i f i c G r a v i t y : 1 .06
pH C o n c e n t r a t e : 1 0 . 2
p H o f a 1:10 s o l u t i o n : 9 . 8
Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r
Cast I r o n B l o c k : Pass
Corrosion Test: 1:10 D i l u t i o n
F o r m u l a t i o n F-770
A i r c r a f t C l e a n e r Type I V
Inaredient: vvts/,
P a r t A:
Monamulse 653-0313 7.0
Monami ne 1-76 2.7
A r o m a t i c 150 7.5
Isopar M (Odorless Mineral S p i r i t s ) 7.5
Diethylene Glycol Butyl Ether 3.5
Decanol 1.6
P a r t B:
T r i s o d i u m Phosphate (Dodecahydrate) 2.7
Water 55.1
P l u r o n i c F98 1.8
Hycar 1422 10.6
Procedure:
Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n .
Add P a r t B t o P a r t A . A g i t a t e u n t i l u n i f o r m .
Typical Properties:
Appearance: C1 e a r L i q u i d
F o r m u l a t i o n F-784
General Purpose S y n t h e t i c F l u i d ( A )
Ingredients: Wt96
M a s l i p 501 Bas= 5.0
Maphos 8135 8.0
Mazon R I 4 A 8.0
T r i e t h a n o l a m i n e , 85% 12.0
B i o c i de 0.5
Water Balance
Procedure:
4 . Add i n g r e d i e n t s as l i s t e d .
2. T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 4 A .
For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r
extreme p r e s s u r e a d d i t i v e .
Ingredients: Wt%
M a s l i p 500 38.0
Mazon R I 8 B 12.0
P r o p y l ene G1 y c o l 2.5
T o l y t r i a z o l e (Climax) 2.5
T r i e t h a n o l a m i ne, 85% 10.0
8 i o c i de 0.5
Water Balance
Procedure:
1 . Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 B . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f
l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e .
Copper M a c h i n i n a F l u i d
Ingredients: Wt%
Macol 5100 15.0
Mazon R I 6 8.0
Maphos 8135 7.0
P o t a s s i um H y d r o x i d e 6.0
B i o c i de 0.5
Water Balance
Procedure:
Add i n g r e d i e n t s as l i s t e d .
G e n e r a l Purpose S y n t h e t i c F l u i d ( C )
Ingredients: Mle9/0
M a s l i p 501 A 30.0
Mazon R I 8 B 12.0
Maphos 58 6.0
T r i e t h a n o l ami ne, 85% 7.0
B i o c i de 0.5
Water 5al ance
Procedure:
1. Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e
f u r t h e r d i l u t e d f r o m 1:lO ( h e a v y d u t y ) t o 1 : 4 0 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of
l u b r i c a n t o r extreme pressure a d d i t i v e .
G e n e r a l Purpose S y n t h e t i c F l u i d ( D )
I n s r e d ients: Wt%
M a s l i p 501 Base 12.0
Mazon R I 8 A 25.0
Maphos 8135 5.0
T r i e t h a n o l ami n e , 85% 12.0
B i o c i de 0.5
Water 5 a l ance
Procedure:
1 . Add i n g r e d i e n t s as l i s t e d .
2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e
f u r t h e r d i l u t e d f r o m 1 : l O (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y )
w i t h water t o form a ready-to-use f l u i d . For increased
r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon
R I 8 A . F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f
l u b r i c a n t o r extreme pressure a d d i t i v e .
Metal Cleaner
(Phosphate, Powder)
Composi t i on :
*STPP 10.0
*Sodi um C a r b o n a t e 25.0
**Alkoxylated l i n e a r alcohol nonion c s u r f a c t a n t
( 1ow foam) 5.0
Metso Beads 2048 30.0
Sodi um H y d r o x i d e Beads 30.0
FMC
** O l i n P o l y t e r g e n t S-305LF o r
Rhone-Poulenc I g e p a l CO-530
A1 umi num C1 e a n e r
(Phosphate, Powder)
Soi 1- L i g h t d r a w i n g o i 1
Surface-Aluminum
A p p l i c a t i o n Method-Spray washer
M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on
Composi t i on : Wt%
Metso Beads 2048 45.0
*STPP 30.0
*Sodi um B i c a r b o n a t e 20.0
**Sodium P o l y a c r y l a t e 3.0
* * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 Moles EO 2.0
Use D i l u t i o n : 1.5-3.036 bw ( 2 - 4 o z / g a l )
* FMC
** Rohm 8, Haas A c u s o l 445ND (92% s o l i d s )
*** Rhone-Poul enc I g e p a l CA-630
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
114 Advanced Cleaning Product Formulations
M e t a l C1 e a n e r
(Phosphate. Powder2
S o i l - O i l , d r a w i n g l u b r i c a n t , a n i m a l f a t and g r e a s e
Surface-Steel
A p p l i c a t i o n Method-Immersion
ManufacturekDry blend/Agglomeration
Composi t i o m
*Sodium C a r b o n a t e 20.0
*STPP 8.0
**Octylphenoxy Polyethoxyethanol ( 6 Moles € 0 ) 2.0
Metso Beads 2048 30.0
Sodi um H y d r o x i d e Beads 40.0
Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l l o n )
* FMC
** Rhone-Poulenc I g e p a l CA-630
M e t a l C1 eaner
(Phosphate, Powder)
S o i l - O i l , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e
Surface-Steel
A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g
Manufacture-Dry blend/Agglorneration
Com o s i t i o n : Wt%
TSPF 15.0
TSP 5.0
Metso Beads 2048 35.0
Sodium C a r b o n a t e 28.0
* O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (12-13 Moles EO) 2.0
Sodium H y d r o x i d e Beads 15.0
Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l )
* Rhone-Poulenc I g e p a l CA-720
SOURCE: PO C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Metal Cleaners and Polishes 115
Metal Cleaner
I Phosphate, Powder 1
S o i 1 - 0 i 1, f a t , p r o t e i n
Surface-Stai nless s t e e l
A p p l i c a t i o n Method-Cleaning i n p l a c e
Manufacture-Dry blend/Agglomeration
Composi t i o n A :
*STPP 40.0
*Sodium C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 M o l e s EO) 3.0
M e t s o Beads 2048 25.0
Sodi um H y d r o x i d e Beads 20.0
Composition
- 0: WtO/o
*STPP 40.0
*Sodium C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) 3.0
Metso Pentabead 20 45.0
Use D i l u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )
* FMC
** Rhone-Poluenc R h o d a s u r f A-24
M e t a l C1 e a n e r
( Z e r o Phosphate, Powder)
Composi t i o n
: WtO/o
V a l f o r 100 Z e o l i t e A 15.0
Sodium C a r b o n a t e 38.0
* O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (9-10 Moles E O ) 2.0
Metso Pentabead 20 43.0
A c u s o l 445ND Sodi um P o l y a c r y l a t e 2.0
Use L e v e l : 3-6 o z / g a l l o n
g Rhone-Poulenc I g e p a l CA-630
Non-Phosphorous Aluminum C l e a n e r
T h i s i s a t o t a l l y o r g a n i c , p h o s p h a t e - f r e e aluminum c l e a n e r
t h a t p r o v i d e s e x c e l 1e n t c l e a n i ng and b r i g h t e n i ng o f a1 umi num.
The Avanel S - 7 0 p r o v i d e s f o r removal o f o r g a n i c s u r f a c e d e p o s i t s
and, by s u r f a c e t e n s i o n r e d u c t i o n , b e t t e r c o n t a c t between
t h e aluminum s u r f a c e and t h e o r g a n i c a c i d s . I n a d d i t i o n t o
i n d u s t r i a l a p p l i c a t i o n s l i k e c l e a n i n g o v e r - t h e - r o a d aluminum
t r a i l e r s and aluminum p r i o r t o a n o d i z i n g , t h i s c l e a n e r may also
be used i n household a p p l i c a t i o n s such as c l e a n i n g aluminum
f l a s h i n g , windows and door f i x t u r e s . Depending on t h e a p p l i c a -
t i o n , t h i s p r o d u c t may be used i n a D r e s s u r e wash, pump s p r a y o r
d i p tank.
Inqredients: w.e-l
C i t r i c A c i d , 50% 12.0
G l u c o n i c A c i d , 50% 8.0
Avanel S-70 3.0
D e i o n i z e d Water, Dye Balance
Procedure:
Charge t h e w a t e r , c i t r i c a c i d , g l u c o n c a c i d and Avanel S - 7 0
M i x w e l l . Ifdye i s t o be added, p a r t o f t h e w a t e r s h o u l d be he d
o u t ; and t h e dye added t o t h i s w a t e r w i t good a g i t a t i o n . The
d i s s o l v e d dye can t h e n be added t o t h e b a t c h . NOTE: C e r t a i n
dyes may n o t be s t a b l e under t h e s e c o n d i t i o n s . Consequently,
s h e l f s t a b i l i t y t e s t s s h o u l d be p e r f o r m e d .
F o r m u l a t i o n CM-102
I n a r e d ie n t s :
Dei o n i zed Water 87.0
Avanel S - 7 0 4.0
T e t r a p o t a s s i u m Pyrophosphate 5.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
Macol 48 3.0
pH ( a s i s ) : 1 1 . 5 - 1 2 . 5
Appearance: C l e a r , w a t e r - w h i t e l i q u i d
S p e c i f i c G r a v i t y : 1.05
Procedure:
Charge t h e w a t e r and d i s s o l v e t h e b u i l d e r s a l t s under a g i t -
a t i o n . When d i s s o l v e d , c h a r g e t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e
m i x i n g f o r a t l e a s t 15 m i n u t e s . NOTE: T h i s a l k a l i n e aluminum
c l e a n e r has shown e x c e l l e n t c l eani ng p r o p e r t i e s w i t h o u t
c h e m i c a l a t t a c k o f t h e m e t a l . T h i s f o r m u l a t i o n may b e c u t -!:I
w i t h water t o prepare a m i l d hard-surface c l e a n e r .
F o r m u l a t i o n CM-1034
Semi S y n t h e t i c
T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy m a c h i n i n g
and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l .
Ingredients: wt9j0
100 P a l e O i l 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 205 0.8
Monalube 215 0.8
T r i e t h a n o l ami ne (99%) 3.2
Monacor BE 5.0
Water 58.6
Procedure:
Combi ne i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . /50 I n . - L b s .
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
Appearance: C l e a r
pH: 9 . 6
F o r m u l a t i o n F-797
Semi S y n t h e t i c
InQredients: wt9j0
100 P a l e O i 1 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 220 1.6
T r i e t h a n o l a m i n e (99%) 3.2
Monacor BE 5.0
Water 58.6
Procedure:
M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f
c o n c e n t r a t e t o 95% w a t e r f o r m s m i c r o e m u l s i o n . F o r m u l a t i o n c a n
be u s e d f o r g r i n d i n g and l i g h t m a c h i n i n g .
T y p i ca9 P r o p e r t i es :
Appearance : C1 e a r Amber L i q u i d
Performance Data ( 5 % i n Water):
Appearance: C l e a r L i q u i d
pH: 9.5
S u r f a c e T e n s i o n (dynes/cm): 32
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s .
Formul a t ion F-800
Semi S y n t h e t i c
Inaredients: y&
100 P a l e O i l 10.0
Monalube 225 5.5
TEA 7.5
Monalube 610 25.0
Water 47.5
Typical Properties:
Appearance: C 1 e a r Amber L i q u i d
Performance Data ( 5 % i n w a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 9 . 0
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2750 Lbs. / 5 5 I n . -Lbs .
F o r m a c h i n i n g l i g h t s t a m p i n g and d r a w i n g .
F o r m u l a t i o n F-799
Semi S y n t h e t i c
Inqredients: Wt%
100 P a l e O i l 9.0
Monalube 320 9.0
Monalube 610 13.6
Monalube 205 1.6
T r i e t h a n o l a m i n e (99%) 3.2
Monacor BE 5.0
Water 58.6
Procedure:
M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 .
5% o f c o n c e n t r a t e added t o w a t e r f o r m s m i c r o e m u l s i o n . S u g g e s t e d
f o r g r i n d i n g and m a c h i n i n g f o r b o t h f e r r o u s and n o n f e r r o u s
metals.
Typical Properties:
Appearance: C l e a r Amber L i q u i d
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Insredient: Wt%
SF96 S i l i c o n e F l u i d (350) ( 1 ) 1 .oo
Dow C o r n i n p 20 Release C o a t i n g ( 2 ) 2.00
S t o d d a r d S o l v e n t (3) 20.00
P r i f a c 2922 L a u r i c A c i d 2.00
D I Water 43.48
Morphol ine 0.86
Carbopol EZ-2 ( 4 ) 0.35
Ammoni um h y d r o x i d e 0.31
b g o p g l i e K a o l i C l a y (5) 14.00
ysp c a f Proper€+es.
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 1 0 , 0 0 0 cps
P r o d u c t pH: 8.50
Product C l a r i t y : P a s t e
Raw M a t e r i a l S u p p l i e r s :
( 1 ) General E l e c t r i c
( 2 ) Dow C o r n i n g Corp.
( 3 ) Exxon Corp.
( 4 ) BFGoodrich
(5) Kaopolite, Inc.
Procedure:
4 . Add t h e s i l i c o n e f l u i d , r e l e a s e c o a t i n g , s o l v e n t , and l a u r i c
a c i d P o a v e s s e l . Mix u s i n g a h i g h shear m i x e r .
2 . C o n t i n u e t o m i x , and add t h e water (43.48 p a r t s ) and t h e
morphol ine.
3 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r (16.00 p a r t s ) by s i m p l y
"dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s .
Add t h e d i s p e r s i o n t o t h e above m i x t u r e w i t h good a g i t a t i o n .
4 . Add t h e ammonium h y d r o x i d e t o r e a c h t h e t a r g e t pH.
5 . Add t h e c l a y and mix u n t i l u n i f o r m .
T o t a l A c t ives :
Silicone f l u i d : 1 .oo
Stoddard s o l v e n t : 20.00
Re1ease c o a t i ng : 2.00
Abras i vet 14.00
Soluble O i 1
Ingredients: WtO/o
100 P a l e O i l 80.0
Monalube 605 20.0
P a r o i l 160 20.0
Procedure:
Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typi c a l P r o p e r t i es :
Appearance: C l e a r Dark Brown
Soluble O i 1
Ingredients: Wt%
100 P a l e O i l 85.0
Monalube 605 15.0
Procedure:
Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C .
Typical Properties:
Appearance: C l e a r L i g h t Brown L i q u i d
Appl i c a t i o n :
For g r i n d i n g and v e r y l i g h t m a c h i n i n g .
Formul a t ion F-804
1
S o l u b l e Qi
Inaredients: Wt%
100 P a l e O i l 78.0
Monalube 6 0 5 15.0
Wonalube 2 1 5 5.0
T EA 2.0
Procedure:
M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l -
u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d .
Typical Properties:
Appearance: M i l k y E m u l s i o n
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: M i 1 ky Emu1 s i o n
pH: 8 . 0
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . / 5 5 I n . - L b s .
Soluble O i 1
Ingredients: Wt%
100 P a l e O i l 85.0
Monalube 6 0 5 10.0
Monalube 215 5.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i a t i o n w h i l e warming t o 50C.
Typical Properties:
Appearance: C l e a r Amber L i q u d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
..
Aooearance: M i 1 k v E m u l s i o n
pH: 8 . 0
Falex ( D i r e c t S c a l e ) : 1250 Lbs./45 In.-Lbs.
Soluble O i l Machining F l u i d
Ingredients: Wt%
N a p h t h e n i c O i l (lOOSUS/lOO) 72.0
Monalube 225 5.0
Monalube 605 20.0
T r i e t h a n o l a r n i n e (99%) 3.0
Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t :
D i r e c t Load S c a l e : 2 7 5 0 l b s
Torque: 47 i n c h pounds
Use D i l u t i o n s :
G r i n d i n g : I-2% i n water
L i g h t M a c h i n i n g : 3-5% i n w a t e r
M o d e r a t e M a c h i n i n g : 5-7% i n w a t e r
Heavy M a c h i n i n g : 8-10% i n w a t e r
F o r m u l a F-764
S y n t h e t i c Machininq F l u i d
Ingredients: wto/,
Monalube 225 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0
Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t P r o c e d u r e :
C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n
D i r e c t Load S c a l e 3000 l b s .
T o r q u e 60 i n c h pounds
Formul a t i on F-766
Svnthetic
Ingredients: Wt%
Monalube 210 16.6
T r i e t h a n o l a m i n e (99%) 33.3
Water 50.0
A n t i foam 0.1
Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
The f o r m u l a t i o n i s d e s i g n e d f o r f e r r o u s and n o n f e r r o u s m e t a l s
primarily f o r grinding.
Formul a t i on F-819
Synthetic
Inqredi ents: K%
Monalube 210 12.5
Monalube 315 12.5
T r i e t h a n o l a m i n e (99%) 25.0
Water 50.0
Procedure.:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 0
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s .
F o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems p r i m a r i l y f o r g r i n d i n g .
F o r m u l a t i o n F-820
S y n t h e t i c Drawing/Stampinp F l u i d
T h i s f o r m u l a t i o n i s i d e a l f o r stamping hot o r c o l d r o l l e d s t e e l .
Ingredients:
Monalube 225 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Monalube 315 20.0
Water 35.0
Procedure:
Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t P r o c e d u r e :
C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n
D i r e c t Load S c a l e 3 0 0 0 l b s .
T o r q u e 55 i n c h pounds
F o r m u l a t i o n F-765
Ingredients: Wt%
Paraffinic O i l (300SUS/lOO) 90.0
Monalube 225 10.0
Procedure:
B l e n d Monalube 225 i n t o t h e o i l
F a l e x EP T e s t :
D i r e c t Load S c a l e : 3000 l b s
T o r q u e 57 i n c h pounds
F o r m u l a t i o n F-763
S p r a y M e t a l C1 e a n i n g C o n c e n t r a t e
Ingredients:
Water 75.00
Sodi um M e t a s i 1 i c a t e 3.00
Sodium C a r b o n a t e 4.00
Sodi um H y d r o x i d e 5.00
M o n a t r o p e 1250 11.00
Alkyl Polyal kylene Ether 2.00
Procedure:
Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each
ingredient i s dissolved before next addition.
F o r m u l a t i o n F-751
S y n t h e t i c Formula
Inqredients: Wyt
Monalube 205 5.0
Monalube 210 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8.7
S u r f a c e T e n s i o n : 27
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 7 I n . - L b s .
T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d
s t a m p i ng.
F o r m u l a t i o n F-813
S y n t h e t i c Formula
Inqredients: wt%
Monalube 205 5.0
Monalube 210 10.0
Monalube 315 10.0
T r i e t h a n o l ami ne (99%) 30.0
Water 45.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s
systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d
s t a m p i ng.
F o r m u l a t i o n F-814
S y n t h e t i c Formula
Inqredients: w%%
Monalube 2 0 5 4.5
Monalube 2 2 0 9.0
T r i e t h a n o l a m i n e (99%) 27.0
Monalube 315 20.0
Water 39.5
Procedure:
M i x i t e m s 1, 2 , 3, and 4 . Add w a t e r and mix u n t i l homogeneous.
Typical Properties:
Appearance: C l e a r Amber L i q u i d
S y n t h e t i c Formula
C l e a r product designed f o r f e r r o u s g r i n d i n g .
Ingredients:
Monalube 210 15.0
Mona1ube 1 1 0 40.0
Water 45.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C1 e a r Sol u t i on
S y n t h e t i c Formula
P r o d u c t d e s i gned f o r g r i n d i ng and 1 ig h t m a c h i n i n g
Ingredients: Wt%
Monalube 2 1 0 15.0
T r i e t h a n o l a m i n e (99%) 30.0
Monalube 315 10.0
Water 45.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties :
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 8 . 0
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 5 I n . - L b s .
F o r m u l a t i o n F-817
S y n t h e t i c Formula
Inaredients: Wt%
Monalube 215 16.6
T r i e t h a n o l ami ne (99%) 33.3
A n t i foam 0.1
Water 50.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 5
S u r f a c e T e n s i o n : 42
F a l e x ( D i r e c t S c a l e ) : 2500 bs./44 In.-Lbs.
P r o d u c t d e s i g n e d f o r machi n ng f e r r o u s and n o n f e r r o u s m e t a l .
A l s o some v e r y l i g h t s t a m p i n g .
F o r m u l a t i o n F-818
S y n t h e t i c Formula
Ingredients: Q
Monalube 210 16.6
Monoethanol ami ne 33.3
Water 50.4
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
S y n t h e t i c Formula
Ingredients:
Monalube 205 16.6
T r i e t h a n o l a m i n e (99%) 33.3
A n t i foam 0.1
Water 50.0
Procedure:
Combi ne in g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i es :
Appearance: C l e a r Amber L i q u i d
S v n t h e t i c Formul a
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r S o l u t i o n
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
ptl: 8 . 0
S u r f a c e T e n s i o n : 28
C a s t I r o n B l o c k C o r r o s i o n e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2250 Lbs./5O I n . - L b s .
*thetic Formula
Ingredients:
Monalube 2 0 5 25.0
Monoethanol ami ne 25.0
Water 50.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 10
C a s t I r o n B l o c k : Pass
Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /50 I n . -Lbs.
F o r f e r r o u s systems f o r m a c h i n i n g and g r i n d i n g .
Formul a t ion F-824
Synthetic Formulation
Inqredients:
Monalube 210 10.0
Monalube 225 10.0
TEA 40 0~
Water 40.0
Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i es :
Appearance: C l e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C1 e a r L i q u i d
pH: 8 . 5
S u r f a c e T e n s i o n ( d y n e s / c m ) : 42
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 6 I n - L b s .
S y n t h e t i c Formulat
Inqredients:
Monalube 225 15.0
Monalube 3 1 0 25.0
T r i e t h a n o l ami ne (99%) 30.0
Water 30.0
Procedure:
M i x Monalube 225 w i t h t r i e t h a n o l a m i n e and add Monalube 315.
M i x u n t i l c l e a r , t h e n add w a t e r .
T y p i c a l P r o p e r t i es :
Appearance: C l e a r C o n c e n t r a t e
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 6
S u r f a c e T e n s i o n : 41
Cast I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n . -Lbs
F o r heavy d u t y s t a m p i n g o f f e r r o u s m e t a l s a t 1 0 t o 20% i n w a t e r .
F o r m u l a t i o n F-808
Svnthetic Formulation
I n g r e d i en t s :
Monalube 2 0 5 5.0
Monalube 210 10.0
Monalube 220 10.0
T r i e t h a n o l a m i n e (99%) 50.0
Water 25.0
Procedure:
M i x i t e m s 1, 2, 3 , and 4 . Then add w a t e r .
Typical Properties:
Appearance: C l e a r L i q u i d
F o r s t a m p i n g , d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r .
Formul a t ion F-809
Synthetic Formulation
Inqredients: wtsl,
Monalube 205 5.0
Monalube 225 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0
Procedure:
Mix items 1, 2, 3, and 4 , t h e n add w a t e r and m i x .
Typical Properties:
Appearance: C1 e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 8 . 7
Surface Tension: 35
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s .
Application:
F o r f e r r o u s and n o n f e r r o u s systems f o r mach n i ng, forming,
and s t a m p i n g .
F o r m u l a t i o n F-810
Synthetic Formulation
Inqredients: Wt%
Monalube 215 9.0
Monalube 220 9.0
T r i e t h a n o l a m i n e (99%) 36.0
Water 46.0
Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r Amber L i q u i d
Synthetic Formulation
Inqredients:
Monalube 205 5.0
Monalube 220 10.0
T r i e t h a n o l a m i n e (99%) 30.0
Water 55.0
Procedure:
Combine in g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i es :
Appearance: C1 e a r Amber L i q u i d
P e r f o r m a n c e D a t a (5% i n W a t e r ) :
Appearance: C l e a r L i q u i d
pH: 0.7
S u r f a c e T e n s i o n : 35
C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass
F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 3 5 I n . - L b s .
U n i v e r s a 1 S c o u r i na P a s t e
Inqredients: WtO/o
A : T y l o s e CBR 10000 5.00
5: Water (50C) 51 . 8 0
C: H o s t a p u r SAS 60 21.80
Genapol ZRO 1 iq u i d 10.70
Genapol U D - 0 3 0 2.00
K o m p e r l a n KD 0.70
NaCl 0.00
M a n u f a c k u r i ng:
I. A, w h i c h i s added b y c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l ,
u n t i l a homogeneous g e l f r e e o f lumps h a s been o b t a i n e d
I I . Add one a f t e r a n o t h e r , t h e components o f C t o I .
1 1 1 . F i n a l l y D i s added.
Tests :
V i s c o s i t y ( B r o o k i e l d RVT, sp. 6, 1 0 m i n -1, 25C): 49b00 mPas
A1 u m i n u m C 1 e a n e r
Comoosi t i o n : Wt%
K e l z a n x a n t h a n gum 1 .o
Butyl Cellosolve 4.0
T e r g i t o l NP 3.0
Phosphoric A c i d (85%) 3.0
Citric Acid 4.0
S o d i um D i c h r o m a t e trace
Water 85.0
Procedure:
D i s s o l v e K e l z a n x a n t h a n gum i n w a t e r . Add t h e c i t r i c and
p h o s p h o r i c a c i d s f o l l o w e d b y 5 u t y l C e l l o s o l v e a n d T e r g i t o l NP.
To u s e , s p r e a d e v e n l y on t h e s u r f a c e t o b e c l e a n e d and a l l o w
s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accomplished.
Ingredients: \nit%
M a s l i p 501 Base 30.0
Mazon R I 8 B 12.0
D i e t h a n o l ami ne 8.8
P r o p y l ene G1 y c o l 1.2
T r i e t h a n o l a m i n e , 85% 10.0
Water Balance
Procedure:
Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s r e q u i r e d , add
Macol 5 1 0 0 . I f more c o r r o s i o n i n h i b i t o r i s r e q u i r e d , add more
Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy d u t y a p p l i c a t i o n .
WD-40 Type L u b r i c a n t C o n c e n t r a t e
Inq r e d ien t s : W
S-Maz 8 0 3.7
Mazawet 7 7 1.Q
H i t e c E-515 ( E t h y l ) 5.2
Palmetic Acid 0.7
S h e l l f l e x 213 10.5
S h e l l Sol 135 70.9
Procedure: Add i n g r e d i e n t s as l i s t e d .
Penetrating O i l
I n a r e d ie n t s : Wt%
S-Maz 80 2- 6
Mazon R I 6 7-1 2
M a s i l SF-10 0- 1
Nekal WT-27 0- 1
Gafac RE-40 0- 1
I n d o p o l H-100 0- 6
Odor1 ess M i n e r a S p i r i t s 11ance
Procedure:
Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e m i n e r a l
s p i r i t s may be d e l e t e d and s u b s t i t u t e d w i t h a n a p h t h e n i c o i l
( 5 - 1 5%).
B u r n i s h i n s Compound
Ingredients: Wt%
Mazamide 65 10.0
Mafo 1 3 MOD 1 7.0
Mazon R I 4 A 5.0
T r i s o d i um Phosphate 7.0
EDTA 1 .o
Water 70.0
Procedure: Add i n g r e d i e n t s as l i s t e d .
C a u s t i c Oven C l e a n e r
Inaredients: Wt%*
A : Van Gel C, 4 . 8 % Aqueous D i s p e r s i o n 62.50
Dei o n i zed Water 45.75
Procedure:
1 . Make t h e 4.8% Van Gel C d i s p e r s i o n b y s l o w l y a d d i n g 4 . 8 p a r t s
b y w e i g h t o f Van Gel C i n t o 9 5 . 2 p a r t s b y w e i g h t o f w a t e r o f
a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000
rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . Add t h e r e m a i n i n g P a r t A
w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m i x u n t i l
uniform.
2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d
t o a c h i e v e good m i x i n g o f e n t i r e b a t c h .
3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each
u n t i l u n i f o r m . A v o i d e n t r a p m e n t o f a i r and g e n e r a t i o n o f foam.
4. S l o w l y add P a r t D and m i x u n t i l u n i f o r m .
F o r m u l a t i o n N o . 461
N o n - C a u s t i c Oven C l e a n e r
6 : D i e t h a n o l ami n e 5.00
Triethanolamine 5.00
T r i p r o p y l e n e g l y c o l M e t h y l E t h e r (Dowanol TPM) 5.00
P o t a s s i u m C a r b o n a t e , 25% Aqueous S o l u t i o n 28.00
Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e 1.oo
Procedure:
1 . D r y b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e
t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t
5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s .
2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x
each f o r 5 m i n u t e s . Package.
F o r m u l a t i o n No. 468
*As r e c e i v e d b a s i s
H i g h C a u s t i c Oven C l e a n e r
Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c f o r m -
u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l
c l i n g t o i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e
s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .
(1) 8FGoodrich
( 2 ) Dow Chemical : Dowanol PM
( 3 ) Henkel C o r p . : Glucopon 425CS
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e DI w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e p o t a s s i u m h y d r o x i d e w i t h c o n t i n u o u s m i x i n g .
3 . Add t h e g l y c o l e t h e r .
4 . Add t h e APG s u r f a c t a n t . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .
Total Actives:
Potassium h y d r o x i d e : 10.00
P r o p y l e n e g l y c o l m e t h y l e t h e r : 3.00
C8-16 a l k y l p o l y g l y c o s i d e : 1.50
Oven C l e a n e r
Ingredients: VVt%*
A : Veegum T, Magnesium Aluminum S i l i c a t e 0.40
Rhodopol 23, Xanthan Gum 1.20
D e i o n i z e d Water 80.40
Procedure:
1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m i x w i t h an homogenizer
a t 5000 rpm.
2 . D r y b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o
t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
p r o d u c e a s m a l l v o r t e x . Cool t o 55C.
4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
m i n u t e s a f t e r each a d d i t i o n .
NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e
s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e
batch.
F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s
A e r o s o l Oven C1 e a n e r
Ingredients: .
W t %*
A : Veegum T, Magnesium Aluminum S i l i c a t e 1 .50
Dei o n i zed Water 74.25
Procedure:
1 . Weigh w a t e r and p l a c e on h o m o g e n i z e r .
2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t
5000 r p m . C o n t i n u e m i x i n g for 20 m i n u t e s , w h i l e h e a t i n g t o
70C.
3 . Combine t h e i n g r e d i e n t s o f P a r t 8 , h e a t t o 70C.
4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed
t o provide a s l i g h t vortex.
5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C.
6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t .
Formulation from I n t e r n a t i o n a l S p e c i a l t y Products.
*As r e c e i v e d b a s i s
Oven C l e a n e r
Composition:
K e l z a n x a n t h a n gum 0.1
T r i s o d i um Phosphate 3.2
Sodi urn m e t a s i 1 ic a t e 1.l
S u l f o n a t e OA5 2.1
B r i j 96 3.2
S i 1 icone 2 0 0 F l u i d 3 5 0 c s 4.0
Hexane 4.2
Water 82.1
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum as b e f o r e and
add n e x t t h r e e i n g r e d i e n t s . M i x t h e B r i j 96, S i l i c o n e and hexane
s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m i x
w i t h c o n s t a n t a g i t a t i o n . F o r a e r o s o l u s e c h a r g e w i t h 90% conc-
e n t r a t e and 10% G e n e t r o n 1 2 .
Heavy D u t y Oven C l e a n e r
Compos i t i on : Wt%
Kelzan xanthan gum 0.3
A n t a r o n FC-34 2.0
Sodi um h y d r o x i d e 10.0
Water 87.0
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum t h e n add A n t a r o n .
S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y
add t o m i x . F o r a e r o s o l use c h a r g e w i t h 80% m i x t u r e and 20% o f
1 : l m i x o f G e n e t r o n 1 2 and 1 1 4 .
SOURCE: Monsanto P e r f o r m a n c e M a t e r i a l s : T e c h n i c a l B u l l e t i n 1 - 2 0 :
K e l zan Formul a t i ons
140 Advanced Cleaning Product Formulatioris
Oven C 1 e a n e r w / A m p h o t e r i c
Ingredients: \Mt96
Water, D . I . 71 . 6
Sodi urn C i t r a t e 2.1
Sodi um M e t a s i 1 ic a t e 4.2
Sodium H y d r o x i d e , 40% 6.5
Monoethanol ami ne 4.2
Dowanol PM 3.1
R e w o t e r i c AM HC 3.1
W i t c o 1298SA 3.1
DeSonic 9 N 2.1
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i on.
Typical Properties:
V i s c o s i t y , c p s : 96
pH: 1 3 . 9
F o r m u l a 1114
Oven
- C l e a n e r w/Phosphate
Ingredient s :
Phase I :
Water, D . I . 71 . 4
C a r b o p o l 940 1.3
Phase 11:
Water, D . I . 15.4
P o t a s s i u m H y d r o x i d e , 87% 2.4
Tetrapotassium Pyrophosphate 3.6
Phase 111:
R e w o t e r i c AM HC 5.9
Blending Procedure:
Combine Phase I i n g r e d i e n t s and m i x u n t i l homogeneous.
Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r -
o u g h l y . W h i l e m i x i n g , p o u r Phase I1 i n t o Phase I . M i x t h o r o u g h l y
t h e n add Phase 1 1 .
Formula 1115
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
dishes, Coatings and Finishes
141
142 Advanced Cleaning Product Formulations
F u r n i t u r e P o l i sh
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creaming" o r phase separ-
a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Inqredient: wp9b
P a r t A:
D I Water 91.10
Carbopol EZ-2 (1) 0.20
TEA 0.20
P a r t B:
C a r d i s 36 Wax ( 2 ) 0.25
Hoechst Wax S ( 3 ) 0.25
Oleic Acid 0.08
Morphol i ne 0.10
D I Water 1.82
Part C:
SM2133 S i l i c o n e Emulsion ( 4 ) 4.00
SM2135 S i l i c o n e Emulsion ( 4 ) 2.00
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 9,500 cps
Product pH: 7.00
Product C l a r i t y : P o l i s h
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BF G o o d r i c h
( 2 ) P e t r o l i t e S p e c i a l t y Polymers
( 3 ) Hoechst Celanese
( 4 ) General E l e c t r i c
Procedure:
1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r b y s i m p l y "dumping" i t
i n . The p o l y m e r w i l l wet o u t i n a few m i n u t e s .
2. Add t h e TEA. M i x u n t i l homogeneous.
3. P r e p a r e P a r t B. Add t h e C a r d i s Wax, Hoechst Wax S, and o l e i c
a c i d t o a vessel. With m i l d s t i r r i n g , b r i n g t h e temperature
up t o 96-IOOC. When m e l t e d , add t h e m o r p h o l i n e u n t i l t h e
m i x t u r e i s homogeneous. Add t h e w a t e r a t 95C. C o n t i n u e
s t i r r i n g u n t i l t h e t e m p e r a t u r e reaches 45C. Cool t o room
temperature.
4. Add P a r t B.
5. Add i n t h e s i l i c o n e e m u l s i o n s w i t h m i l d m i x i n g .
Total Actives:
T o t a l Wax : 0.50
T o t a l S i l i c o n e : 6.00
Leather/Plastic Polish
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r -
a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
I n q r e d ie n t : Wt%
DI Water 50.00
Renex 20 ( 1 ) 2.00
Morphol ine 1.oo
SF96 S i l i c o n e F l u i d ( 3 5 0 ) (2) 5.00
Oleic Acid 2.00
Mineral S p i r i t s 20.00
01 Water 19.60
Carbopol EZ-2 ( 3 ) 0.40
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 c p s
P r o d u c t pH: 8 . 5
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
(1) I C I Surfactants
( 2 ) General E l e c t r i c
( 3 ) BFGoodrich
Procedure:
1 . D i s s o l v e t h e Renex 2 0 and m o r p h o l i n e i n t h e w a t e r w i t h m i l d
agitation.
2 . D i s s o l v e t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e m i n e r a l
s p i r i t s . Add t o t h e above m i x t u r e w i t h good a g i t a t i o n .
3 . I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 4 0 p a r t s o f Carbopol i n t o
49.60 p a r t s o f w a t e r b y s i m p l y "dumping" t h e p o l y m e r i n t o
t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y
wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e .
4 . M i x u n t i l homogeneous.
Total A c t i wes:
Silicone Fluid: 5.00
Mineral S p i r i t s : 20.00
M a r b l e P o l ish
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Ingredient: we%
D I Water 74.80
Carbopol EZ-2 ( 1 ) 0.20
Mineral S p i r i t s 15.00
I g e p a l 630 ( 2 ) 3.70
Diatomaceous e a r t h ( 3 ) 8.00
T r i e t h a n o l ami ne 0.30
Physical Properties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 1 I , 700 cp
P r o d u c t pH: 7 . 5 0
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Rhone-Poul enc
(3) Kaopolite
Procedure:
1 . D i s p e r s e t h e Carbopol i n t h e w a t e r b y s i m p l y "dumping" i t
i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e s u r f -
a c t a n t w h i l e m i x i n g under moderate a g i t a t i o n .
2 . Add t h e m i n e r a l s p i r i t s . M i x u n t i l t h e e m u l s i o n becomes
homogeneous.
3 . Add t h e TEA. M i x u n t i l smooth.
4 . Add t h e diatomaceous e a r t h . Mix u n t i l homogeneous.
DET-552
Rust Removing P o l i s h
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t o t h i c k e n t h e g l u c -
o n i c a c i d t o e n a b l e improved a p p l i c a t i o n e f f i c a c y . The p o l y m e r
w i l l a l s o i m p a r t v e r t i c a l c l i n g t o e n a b l e a p p l i c a t i o n s on v e r t -
i c a l o r angled surfaces.
I n q r e d ie n t : Wt%
D I Water 44.64
Carbopol €2-2 ( 1 ) 1-79
Sodium h y d r o x i d e (50%) 35.71
G l u c o n i c a c i d s o l u t i o n (50%) ( 2 ) 17.86
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 c p
P r o d u c t p H : 13.90
Product C l a r i t y : T r a n s l u c e n t
Procedure:
1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r .
2. A d d t h e sodium h y d r o x i d e w i t h a g i t a t i o n . T h i c k e n i n g will o c c u r
immedi a t e l y .
3 . Add t h e g l u c o n i c a c i d s o l u t i o n . M i x u n t i l homogeneous.
DET-560
S c r a t c h e d Wood P o l i s h
Ingredients: Wt%
A: Veegum T, Magnesium Aluminum S i l i c a t e 1.50
Dei o n i zed Water 31.25
B: S t e a r i c A c i d 4.50
Carnauba Wax 16.50
Beeswax, Ye1 1ow 16.50
Procedure:
1 . Weigh t h e w a t e r and m i x w i t h a p r o p e l l e r m i x e r a t 1800 rpm.
2 . S l o w l y add t h e Veegum T and m i x f o r 20 m i n u t e s w h i l e
h e a t i n g t o 9OC.
3 . Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC.
4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e
o r d e r shown, m i x i n g each f o r 10 m i n u t e s .
5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s .
6 . Cool t h e b a t c h t o 35C, add P a r t D, and m i x u n t i l u n i f o r m .
*As r e c e i v e d b a s i s
H i qh Gloss, D e t e r q e n t R e s i s t a n t P o l ish
A wax-free p o l i s h , which provides a high-gloss, detergent
r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S i m p l e a p p l i c a t i o n ,
w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f
g l o s s and d e t e r g e n t r e s i s t a n c e f o r e x t e n d e d p r o t e c t i o n .
Ingredients: Wt%
( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e 9.0
( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e 1.5
( 3 ) Stoddard Solvent 3.5
( 4 ) Mineral S p i r i t s (Odorless) 3.5
( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n 9.0
( 6 ) K a o p o l i t e SF 3.4
( 7 ) S o f t Water 70.0
( 8 ) Bactericide 0.1
Combine i n o r d e r shown w i t h h i g h s h e a r m i x i n g u n t i l t h i c k e n i n g
o c c u r s . M i x u n t i l homogeneous and package.
Formulation Properties:
C o n t a i n s no wax Non-smeari ng
High g l o s s Cost e f f i c i e n t
Detergent r e s i s t a n t Cold b l e n d (Only m i x i n g r e q u i r e d )
E a s i 1 y a p p l ied Resistant t o wash-off
SQURCE: Genesee P o l y m e r s C o r p . : Formula 20-12
12. Rinse Aids
146
Rinse Aids 147
R i nse A i d , Acid
Inqredients: Wt9/o
Water, D . I . 50.0
P e t r o 22 Powder 5.0
DeSoni c LFD-97 35.0
Hydroxyacetic Acid, 70% 10.0
Blending Procedure:
51 end i n g r e d i e n t s in t h e o r d e r 1 is t e d .
Typical Properties:
S p e c i f i c G r a v i t y : 1.105
Wt/Gal, l b s : 9 . 2 1
V i s c o s i t y , c p s : 85
C l o u d P o i n t , C : 59
S o l i d s , %: 4 0
Formula 131
R i nse A i d
Ingredients: Wt%
Water, D . I . 60.0
P e t r o 22 Powder 5.0
DeSoni c LFD-97 35.0
Typical Properties:
S p e c i f i c G r a v i t y : 1.029
Wt/Gal. l b s : 8 . 5 8
pH, as i s : 6 . 4
V i s c o s i t y , c p s : 80
C l o u d P o i n t , C : 68
S o l i d s : 40%
Formula 130
148
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 149
C a r p e t C1 e a n e r
I n qr e d i e n t s : wt%
Water 56.0
T r i s o d i urn Phosphate 15.0
Tetrapotassium Pyrophosphate 10.0
P l u r a f a c D-25 7.0
A1 ip a l CO-436 10.0
Mazawet 7 7 1.25
EDTA ( T e t r a s o d i u m S a l t ) 0.5
T i n o p a l 5 BM 0.25
Procedure:
Add i n g r e d i e n t s as l i s t e d .
Ingredients: Wt%
Macol 2LF 6.0
Ethylene Glycol Methyl Ether 10.0
Sodi urn T r i p o l y p h o s p h a t e 1. o
Sodi urn X y l ene S u l f o n a t e 1 .o
Mazu DF 210 SX 0.5
Water ( s o f t ) 81 . 5
Procedure:
Add i n g r e d i e n t s as l i s t e d .
Steam Rua C l e a n e r - A
Ingredients: w
a
Macol OP 1 0 SP 5.0
Sodium S i l i c a t e 10.0
Sodi urn X y l ene S u l f o n a t e 5.0
Water 80.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
S t e a m Rug C l e a n e r - 8
Inqredients: Wt%
Macol OP 1 0 SP 3.0
Sodi um S i 1 ic a t e 10.0
Sodium X y l e n e S u l f o n a t e 3.0
Water 84.0
Procedure:
Add i n g r e d i e n t s as l i s t e d
Inqredients: W S
C u b l e n 0 50 1.o
Tetrapotassium pyrophosphate 5.0
P r o p e t a l 241 2.0
P r o p e t a l 281 3.0
S u l f e t a l 4105 4.0
Isopropanol 4.0
Water 81 . o
F o r m u l a CT 02-08-01
Ingredients: Wt%
Water 75.0
Soap 1 .o
S u l f e t a l 4105 5.0
P r o p e t a l 99 5.0
Cont raspum 3 0 0 1. o
U b a t o l TR 1138 3.0
Isopropanol 10.0
F o r m u l a C T 02-08-02
C a r p e t Shampoo
Liquid, transparent
Ingredients: wtu/,
A : Hostapur 0s l i q u i d 25.00
M e d i a l a n KA c o n c . 3.00
B: W a t e r , Preservative 72.00
Manu f a c t u r i ng :
One a f t e r a n o t h e r , t h e components o f A a r e added t o 8 .
C a r p e t Shampoo
I Phosphate, L i quid)
Composi t i on : Wt%
Water 62.5
*TSP 2.0
*STPP 5.0
K a s i 1 # 6 P o t a s s i um S i 1 ic a t e 20.0
**Phosphate E s t e r 3.0
***Sodi um A1 k y l naphtha1 ene S u l f o n a t e 3.5
****Octylphenoxy P o l y e t h o x y e t h a n o l , 7 - 8 M o l e s EO 4.0
Use D i l u t i o n : 0 . 8 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )
* FMC
** Rhone-Poulenc Rhodafac RE-610
*** DeSoto
**** Rhone-Poulenc I g e p a l CA-620
RUQ Steam C l e a n e r
Composi t i on :
Water 84.0
Wetso Beads 2048 5.0
Sodi um X y l ene S u l f o n a t e , 40% 6.0
* M i r a n o l JEM C o n c e n t r a t e (34%) 5.0
Use D i l u t i o n : 4 . 7 - 9 . 4 % b w ( 6 - 1 2 o z / g a l l o n )
C a r p e t Shampoo, H i s h Foam
In Q r e d ie n t s : WtS/o
Water 78.3
P e t r o BAF L i q u i d 5.0
W i t c o l a t e WAC-LA 16.7
B1 e n d i n g P r o c e d u r e : B1 end in g r e d i e n t s i n t h e o r d e r 1 is t e d .
P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s
t h e low temperature cloud p o i n t , g i v i n g e x c e l l e n t freeze/thaw
p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n
sodium l a u r y l s u l f a t e a l o n e .
F o r m u l a 908
C a r p e t Shampoo, H i g h Foam
Inqredients: Wt%
Water 71.1
P e t r o BAF L i q u i d 6.7
W i t c o l a t e WAC-LA 22.2
B l e n d i n g P r o c e d u r e : B 2nd i n g r e d i e n t s i n t h e o r d e r is I
Use L e v e l : 1 t o 2 ounces p e r g a l l o n .
Comments :
P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s
t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w
p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n
sodium l a u r y l s u l f a t e a l o n e .
F o r m u l a 910
C a r p e t S p o t Remover
Inqredients: Wt%
Water, 13.1. 90.3
W i t c o l a t e WAC-LA 3.3
P e t r o BA L i q u i d 0.5
G l y c o l E t h e r DPM 3.5
G l y c o l E t h e r PM 2.3
FC-129 ( 1 % S o l i d s ) 0.1
Typical Properties:
S p e c i f i c G r a v i t y : 0.999
Wt./Gal. l b s . : 8.33
pH: 1 0 . 3 5
Use D i l u t i o n : Use as i s
F o r m u l a 945
SOURCE: W i t c o C o r p . : S u g g e s t e d F o r m u l a t i o n s
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 153
Carpet 8 U p h o l s t e r y Cleaner
T h i s o e n e r a l Duroose s t a i n remover f o r m u l a t i o n is o a r t i c u l a r l v
e f f e c t i v e i n removing o i l s t a i n s .
Ingredient : Wt%
D e i o n i z e d Water ( h o t ) 37.0
SMA-2625 R e s i n 2.4
Aqua Ammonia 0.7
W i t c o l a t e WACLA 18.0
W i t c o n a t e 60T L i q u i d 4.0
Avanel 5-70 4.0
Dei o n i zed Water 34.0
Dye, Fragrance, e t c . (2.5.
pH ( a s i s ) : 8.0-9.0
Appearance: C l e a r l i q u i d
S p e c i f i c G r a v i t y : 1.016
Procedure:
1 . Charge t h e h o t w a t e r t o a m i x i n g v e s s e l and s t a r t a g i t a t i o n .
S l o w l y s i f t i n t h e SMA-2625 R e s i n t o a v o i d c l u m p i n g . Add
t h e Aqua Ammonia, a p p l y c o o l i n g , and mix w e l l u n t i l t h e
r e s i n i s dissolved.
2 . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . S t o p
a g i t a t i o n t o permit deaeration o f t h e product p r i o r t o
filling off.
3 . I f t h i s p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l
w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r
t h e dye is t h o r o u g h l y mixed, t h e dye s o l u t i o n may be
added
NOTE: Use " a s i s " on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h
water f o r u pholstery.
V i n y l Dressing ( 8 )
Ingredient: Wt%
Part A:
M a s i l EM 250 C 18.0
M a s i l EM 10,000 C 10.0
Dei o n i zed Water 30.0
P a r t B:
Macol OP-10 SP 2.0
G1 y c e r i ne 1.o
D e i o n i r e d Water 38.0
Sodium Benzoate 1.o
Procedure:
1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and M a s i l
EM 10,000 C . S t a r t g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r
so as n o t t o b r e a k t h e e m u l s i o n .
2. I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol OP-10 SP and
g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l
components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h
e y e s " . Charge t h e sodium b e n z o a t e and m i x u n t i l d i s s o l v e d .
3 . Under g e n t l e a g i t a t i o n , add P a r t 0 t o P a r t A. C o n t i n u e m i x i n g
g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d
to b e used "as i s " . I f d e s i r e d , UV a b s o r b e r s and o t h e r compon-
e n t s may be added t o t h e f o r m u l a t i o n .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
154 Advanced Cleaning Product Formulations
Ingredients: Wt%
Dei o n i zed Water ( H o t ) 37.0
SMA-2625 R e s i n 2.37
Aqua Ammonia 0.67
Sodi u m L a u r y l S u l f a t e 18.0
R i chami de 5725 4.0
Avanel 5-70 4.0
Dei o n i zed Water 33.96
Dye, F r a g r a n c e , E t c . As d e s i r e d
pH (as i s ) : 8.0-9.0
Appearance: C l e a r l i q u i d
S p e c i f i c G r a v i t y : 1 .016
Procedure:
Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n .
S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e
Aqua Ammonia, a p p l y c o o l i n g and m i x w e l l u n t i l t h e r e s i n i s
d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s .
I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l water
s h o u l d b e r e s e r v e d f o r d i s s o l v i n g t h e d y e . A f t e r t h e dye i s
t h o r o u g h l y m i x e d , t h e d y e s o l u t i o n may b e added t o t h e p r o d u c t .
Stop a g i t a t i o n t o p e r m i t deaeration o f t h e product p r i o r t o
filling off.
Notes :
T h i s i s a g e n e r a l p u r p o s e o i l y s t a i n remover. T h i s f o r m u l a t i o n
i s p a r t i c u l a r l y e f f e c t i v e a t r e m o v i n g o i l s t a i n s . Use a s - i s on
c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h w a t e r f o r u p h o l s t e r y .
N o t e : The dye s h o u l d b e t h o r o u g l y s c r e e n e d t o a v o i d f a b r i c
staining.
F o r m u l a t i o n CP-101
L i q u i d Steam C a r p e t C 1 e a n e r
F o r H a r d Water Systems
Ingredients: Wt%
Sodium M e t a s i 1 i c a t e A 7.5
Tetrapotassium Pyrophosphate 12.5
Emphos PS-331 4.0
Macol NP 11 1.o
D e i o n i z e d Water 76.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
F1oor C l e a n e r
Ingredients: wtsl,
M a z a m i de 1281 8.0
Sodi urn T r i p o l y p h o s p h a t e 2.0
T e t r a p o t a s s i u m Pyrophosphate 2.0
Water 88.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
L i q u i d F l o o r Cleaner
Ingredients: Q
Macol NP 9 . 5 7.0
Sodi urn T r i p o l yphosphate 8.0
T r i s o d i urn Phosphate 2.0
Sodi urn M e t a s i 1i c a t e P e n t a h y d r a t e 2.0
Maphos 60A 3.0
Water 78.0
Procedure:
A d d i n g r e d i e n t s as l i s t e d .
NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F.
F l o o r Scrubber
Ingredients:
Sodi urn M e t a s i 1 ic a t e 2.0
Tetrasodium Pyrophosphate 18.0
Emphos PS-331 15.0
D e i o n i z e d Water 53.95
Mazami de 1281 6.0
Sodium H y d r o x i d e , 50% 5.05
Procedure :
Add i n g r e d i e n t s as l i s t e d .
Household Carpet F r e s h e n e r / A n t i s t a t
InQredients: Wt%
P a r t A:
P u f f e d Borax ( 1 0 l b s / c u f t ) 1.8
Fragrance 0.2
Sodi um B i c a r b o n a t e 15.0
L a r o s t a t 519 3.0
P a r t 6:
Sodi um B i c a r b o n a t e 80.0
Procedure:
I n a r i b b o n m i x e r o r V - b l e n d e r , c h a r g e t h e p u f f e d b o r a x and
f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y
add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added,
c o n t i n u e m i x i n g f o r 5 m i n u t e s t o c o m p l e t e a b s o r p t i o n . Add t h e
L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15
m i n u t e s more.
Notes :
T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t .
The p r o d u c t i s d e s i g n e d t o b e shaken o n t o t h e c a r p e t , l i g h t l y
r u b b e d i n t o t h e c a r p e t and t h e n t h e e x c e s s removed b y vacuuming.
F o r m u l a t i o n SP-I01
Pump S p r a y C a r p e t A n t i s t a t
Ingredients:
P a r t A:
Water 94.3
Isopropyl Alcohol 5.0
L a r o s t a t 264 A 0.7
Appearance: C l e a r , w a t e r - w h i t e t o pale-yellow l i q u i d
S p e c i f i c G r a v i t y : 0.98
Procedure:
To a m i x i n g vessel, charge t h e water, f o l l o w e d by t h e i s o p r o -
p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r .
Notes :
T h i s i s a n o n - a e r o s o l , pump s p r a y c a r p e t a n t i s t a t f o r t h e
removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and
other surfaces, spray l i g h t l y w i t h t h i s formulation. It i s not
necessary t o s a t u r a t e t h e surface. I f a d d i t i o n a l p r o t e c t i o n i s
needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n
one, t o i n s u r e even t r e a t m e n t .
F o r m u l a t i o n SP-102
h i qlai d L e a t h e r . V i n v l , a n d P l a s t i c C l e a n e r and R e s t o r e r
Inqredients: Wt%
DeSonic 9N 10.0
Dowanol PM G l y c o l E t h e r 5.0
Isopropyl Alcohol 2.5
Amy1 A c e t a t e 1.o
Water 81 . 5
Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e -
l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few
m i n u t e s , t h e n r i n s e o r hose o f f .
Product I n f o r m a t i o n :
Product: Benefit :
DeSonic 9N Detergent and degreaser
Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g a g e n t
Amyl A c e t a t e Solvent
Isopropyl Alcohol Sol vent
Formula 1000
InQredients: Wt%
W i t c o n o l NP-100 10.0
Dowanol PM G l y c o l E t h e r 5.0
Isopropyl Alcohol 2.5
Amy1 A c e t a t e 1 .o
Water 81.5
Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e -
l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few
m i n u t e s , t h e n r i n s e o r hose o f f .
Product I n f o r m a t i o n : Benefit :
W i t c o n o l NP-100 D e t e r g e n t and d e g r e a s e r
Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g a g e n t
Amyl A c e t a t e Sol vent
I s o p r o p y l A1 coho1 Sol vent
Formula 1001
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
158 Advanced Cleaning Product Formulations
Low Cost E x t r a c t i o n C a r p e t C l e a n e r
Ingredients:
Water, D . I . 91 . o
P e t r o 22 Powder 5.0
EDTA Powder 4.0
Perfume q. s .
81 e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s in t h e o r d e r 1 isteci.
Use D i l u t i o n : 1-2 o z / g a l of w a t e r
F o r m u l a 901
Inqredients:
Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y 65.0
Sodi urn M e t a s i 1 i c a t e , P e n t a h y d r a t e 29.5
P e t r o 2 2 Powder 5.0
Optical Brightener 0.5
Use D i l u t i o n : 1-2 o z / g a l
Formula 904
Heavy D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r
Use D i l u t i o n : 1-2 o z / g a l
F o r m u l a 905
Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t
Component: Wt%
Sodi um B i c a r b o n a t e t o 100% t o t a l
STPP 47.0
B u r c o LAF-6 2.5
Burco SZS 0.25
B u r c o s p e r s e AP Powder 2.5
B u r c o t a s e SP-60 ( i f d e s i r e d ) 1.o
Fragrance as d e s i r e d
Procedure:
S p r a y LAF-6 ( a n d i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d
u n t i l a b s o r b e d . Add B u r c o S Z S , t h e n Sodium B i c a r b o n a t e and
b l e n d u n t i l u n i f o r m . Add B u r c o s p e r s e A P Powder ( a n d i f d e s i r e d )
B u r c o t a s e SP-60. B l e n d u n t i 1 u n i f o r m .
Use C o n c e n t r a t i o n :
2-3 ounces p e r g a l l o n i n e x t r a c t o r .
RUQ Steam C l e a n e r
(Liquid)
Composition: Wt%
Water 79.6
M e t s o Beads 2048 7.0
Sodium X y l e n e S u l f o n a t e , 40% 6.7
C12-Cl5 L i n e a r A l c o h o l , 12 M o l e s EO 3.9
Use D i 1u t i on : 4 . 7 - 9 . 4 % bw ( 6 - 1 2 o z / g a l 1o n )
No Rinse F l o o r Cleaner
I npredie n t s : \Mt%
Water, D.I. 79.0
Sodi um Carbonate 4.0
Rewoteric AM 8-14 10.0
Versene 100 2.0
Butyl Cellosolve 5.0
Blending Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each addi t ion.
Formula 932
Heavy D u t y F l o o r Cleaner
Ingredients: Wt%
Water, D.I. 78.0
Varami de A-1 2 7.0
T r i sodi um Phosphate 10.0
Sodium Tripolyphosphate 5.0
81 end$ng Procedure:
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
each a d d i t i o n .
T y p i c a l Propert ies :
S o l i d s : 22.0%
Formula 933
Typical Properties:
S o l i d s : 8.1%
pH: 10.9
V i s c o s i t y : 4 cps
Formula 951
Wax S t r i p p e r ( A )
Inqredients: Wt%
Oleic Acid 7.0
Monoethanol ami ne 2.0
Avanel S - 7 4 2.0
Potassium H y d r o x i d e , 45% 1 .o
Sodi um H y d r o x i d e , 50% 1 .o
Versene 100 1 .o
Dowanol TBA 5.0
Water 81 . o
Procedure:
Add i n g r e d i e n t s as l i s t e d .
Wax S t r i p p e r ( B )
Inaredients:
Oleic Acid 7.0
Monoethanolamine 2.0
Avanel S - 7 4 2.0
Potassium H y d r o x i d e , 45% 1 .o
Sodi um H y d r o x i d e , 50% 1 .o
Versene 1 0 0 1 .o
E t h y l e n e G1 y c o l Monobutyl E t h e r 81 . o
Water 5.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
C o n c e n t r a t e d Wax S t r i p p e r
Inaredients: WtO/o
Sodium H y d r o x i d e , 50% 6.5
Macol NP 9 . 5 1 .o
EDTA, 40% 0.5
Mazox LDA 1 .o
B a r q u a t MB-50 1 .o
Monoethanolami ne 8.5
Water 81 .5
Procedure:
Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1 : l O t o 1:30.
Mac01 NP 1 0 . 5 can be s u b s t i t u t e d f o r t h e Macol NP 9 . 5 . Mafo CB-40
can be s u b s t i t u t e d f o r t h e Mazox LDA.
1 fi7
Miscellaneous 163
B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021
I n q r e d ie n t s : Wt%
Phase I :
Isopropanol 10.0
Oleic Acid 8.8
Varox 1 7 7 0 5.0
Pine O i 1 12.0
Phase 11:
Water, D . I . 62.2
P o t a s s i um H y d r o x i d e (87%) 2.0
81 e n d i ng P r o c e d u r e :
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine
Phase I T i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add
Phase I t o Phase 1 1 .
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 5
S o l i d s : 10.6%
pH: 9 . 3
Formula 302
_
G e n~e r a
~l D
_ i s_i n f _
e c t_a n _
t S_o l u_t i o_n ~ ~
Ingredi e n t s : wtsl,
Water. D . I . 68.0
V a r q u a t 5 0 MC 10.0
G1 y o x a l ( 4 0 % ) 5.0
R e w o t e r i c AM DML-35 17.0
Blending Procedure:
Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each add1 t ion,
Typical Properties:
V l s c o s l t y , cps: 4
Sol 1 d s : 1 3 . 0 %
pH: 7 . 1
Formula 3 0 3
Hospital D is infectant
Ingredi
-~ ents: Wt%
Water, D . I . 84.2
V a r i q u a t 50 MC 9.6
Varox 365 4.0
Versene 100 1.5
Sod1 urn H y d r o x i d e ( 3 0 % ) 0.7
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
Viscosity, cps: 4
S o l i d s : 6.7%
pH: 1 2 . 2
Formula 304
C u t t i n g O i l Concentrate
Ingredients: Wei s h t %
Aristonate M 36.00
I g e p a l CO-430 20.00
TEA, 85% 8.00
Oleic A c i d 8.00
100 SUS N a p h t h e n i c O i l 28.00
Comments a b o u t t h i s f o r m u l a :
1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l .
2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-003-01
Cutting Oi 1
Ingredients: Wei q h t %
Aristonate M 10.50
TEA, 85% 0.90
T a l l O i l A c i d , A c t i n o l FA-1 1.20
C a l a m i d e SM 1.65
100 SUS N a p h t h e n i c O i l 85.00
Water 0.75
Comments a b o u t t h i s f o r m u l a :
E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-004-01
C o n c r e t e C 1e a n e r
Ingredients: Weight%
C a l s o f t F-90 5.00
Sodi um S i 1 ic a t e 30.00
Sodium C a r b o n a t e 30.00
Sodi um H y d r o x i d e 25.00
Sodi um T r i p h o s p h a t e 10.00
Comments a b o u t t h i s f o r m u l a :
G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder.
F o r m u l a t i o n CON-001-01
Insredients : Wei s h t %
Water 60.20
C a l s o f t L-40 29.30
P i l o t SXS-40 2.20
Na4 EDTA 1.30
C a l o x y l a t e N-9 7.00
Comments a b o u t t h i s f o r m u l a :
V i s c o s i t y o f t h e p r o d u c t i s a b o u t 160 cPs a t room t e m p e r a t u r e .
F o r m u l a t i o n TIR-001-01
Ingredients: Wt%
Phase I :
Water, D . I . 81 . O
T r i s o d i u m Phosphate 1 .o
Sodium C i t r a t e 2.0
Glycerin 2.0
Phase 11:
d - L i monene 7.0
DeSonic 9N 5.0
V a r o n i c T202 2.0
B l e n d i n g Procedure:
I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y .
H e a t t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l
and m i x t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase
11 Po Phase I.Cool q u i c k l y t o s t a b i l i z e e m u l s i o n .
Typical Properties :
Appearance, Room Temp.: Heavy Cream
S o l i d s : 12.0%
pH: 1 0 . 4
Formula 1120
P a s t e Hand C l e a n e r
Ingredients: WtS/o
Water, D . I . 70.0
Varami de MA-1 10.0
R e w o t e r i c AM 8-15 10.0
W i t c o l a t e SE-5 10.0
81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i on.
Typical Properties:
V i s c o s i t y , c p s : 6360
S o l i d s : 19.5%
pH: 8 . 7
Formula 1121
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
166 Advanced Cleaning Product Formulations
D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e
o i l s c o n t a i n i n g r e l a t e d monocyclic t e r p e n e hydrocarbons, predomi-
n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m -
onene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . )
O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and
a l p h a - and b e t a - p i n e n e .
Non-alkaline Formulations
Ingredients: &%
D i p e n t e n e 122 5.00
Tomah E-14-5 6.40
Tomah E-14-2 0.80
Tomah A l k a l i S u r f a c t a n t 0.80
Water 87 00
~
CPL, c : 1 1
CPH, C : 30
Emulsifier/Dipentene Ratio: 1.60
Ingredients: VVt.%
D i p e n t e n e 122 10.00
Tomah E-14-5 8.80
Tomah E-14-2 1.10
Tomah A l k a i S u r f a c t a n t 1.10
Water 79.00
C P L , c : 11
CPH, C : 50
Emu1 s i f e r / D i p e n t e n e R a t i o : 1.10
Inaredients: Wt.%
D i p e n t e n e 122 20.00
Tomah E-14-5 14.40
Tomah E-14-2 1.80
Tomah A l k a l i S u r f a c t a n t 1 .80
Water 62.00
CPL, c : 19
CPH, C : 41
Emulsifier/Dipentene Ratio: 0.90
D i p e n t e n e M i c r o e m u l s i o n Formul a t i o n s ( C o n t i nued)
D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne
o i l s c o n t a i n i n g r e l a t e d m o n o c y c l i c t e r p e n e h y d r o c a r b o n s , predom-
i n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same a s l i m o n -
ene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . )
O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and
a l p h a - and b e t a - p i n e n e .
A l k a l i n e Formulations
Ingredients: Wt.96
D i p e n t e n e 122 5.00
E-14-5 8.00
E-14-2 0.50
A1 k a l i S u r f a c t a n t 1 .50
Water 83.30
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.70
CPL, C : 15
CPH, C : 4 4
Emulsifier/Dipentene Ratio: 2.00
Ingredients: Wt.%
D i p e n t e n e 122 10.00
E-14-5 12.00
E-14-2 0.75
A1 k a l i S u r f a c t a n t 2.25
Water 73.50
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.50
CPL, c : 20
CPH, C : 46
Emulsifier/Dipentene Ratio: 1 .50
Ingredients: Wt.%
D i p e n t e n e 122 20.00
E- 1 4 - 5 17.60
E-14-2 1.10
A1 k a l i S u r f a c t a n t 3.30
Water 56.80
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.20
CPL, C : 18
CPH, C : 43
E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0
Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i -
f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r
and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .
CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h
temperature cloud p o i n t " .
H y d r o c a r b o n S o l v e n t M i c r o e m u l s i ons
Formula A:
Ingredients: \Nt.%
E x x s o l D-110 20.0
Tomah E-14-2 11.9
Tomah E-14-5 5.4
Tomah A l k a l i S u r f a c t a n t 4.3
S o f t Water 58.4
Formula 8 :
Inaredients: Wt.%
E x x s o l D-110 30.0
Tomah E-14-2 17.9
Tomah E - 1 4 - 5 8.1
Tomah A l k a l i S u r f a c t a n t 6.5
S o f t Water 37.5
Formula C :
Inqredients: Wt.%
E x x s o l D-110 40.0
Tomah E-14-2 23.9
Tomah E-14-5 10.8
Tomah A l k a l i S u r f a c t a n t 8.7
S o f t Water 16.6
Hydrocarbon S o l v e n t Microemulsions ( C o n t i n u e d l
Developed i n o r d e r t o o f f e r r e p l a c e m e n t s f o r e x p e n s i v e
d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have
f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .
Isopar M F o r m u l a t i o n s
I s o p a r M can b e s u b s t i t u t e d d i r e c t l y f o r t h e E x x s o l D-110 i n
t h e above f o r m u l a t i o n s . I n a d d i t i o n , t w o f o r m u l a t i o n s w i t h l o w e r
s o l v e n t c o n t e n t have been d e v e l o p e d .
Unbui 1 t :
Component: Wt.%
S o f t Water 83.0
Sodium Metas l i c a t e P e n t a h y d r a t e 0.0
Tomah E-14-2 4.7
Tomah E-14-5 4.7
Tomah A1 k a l i S u r f a c t a n t 1.6
I s o p a r Wi 6.0
L i g h t l y b u i 1t :
Component: Wt.%
S o f t Water 79.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
Tomah E-14-2 5.6
Tomah E-14-5 5.6
Tomah A l k a l i S u r f a c t a n t 1.a
Isopar M 7.0
S t a r t b y d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f u s e d ) i n t h e
w a t e r . Then add t h e E-14-2, E-14-5, a n d A l k a l i S u r f a c t a n t . M i x
u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h
m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r a s t h e l a s t o f
t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l b e c l e a r and
s t a b l e i n t h e t e m p e r a t u r e r a n g e f r o m 20-5OC. The c l o u d p o i n t c a n
be r a i s e d f u r t h e r b y a d d i n g a s m a l l amount o f a d d i t i o n a l A l k a l i
Surfactant.
Inycedi e n t l W t"/.
D I Water 83.80
Pemulen 1622 ( 1 ) 0.20
Makon 10 ( 2 ) 0.70
Dow 200 S i l i c o n e F l u i d ( 3 ) 15.00
Triethanolamine 0.30
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 1,000 c p
Product pH: 7.3
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a1 S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Stepan C o .
( 3 ) Dow C o r n i n g
Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
S c r e e n t h e Pemuleri r e s i n i n t . o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous
and f r e e o f p o l y m e r l u m p s .
2 . Add t h e Makon 10 and m i x u n t i l homogeneous.
3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M i x u n t i l
uniform.
4 . Add t h e T E A . M i x u n t i l smoot.h.
Total Actives:
Silicone O i l : 15.00%
Lumi n i z i n g P e t C o n d i t i o n e r
Inaredients: Wt%
Water 85.2
Hydroxyethyl C e l l u l o s e 0.8
Stearic acid 2.0
Stearyl alcohol 2.0
Monaquat TG 7.0
Monaquat I S I E S ( I s o s t e a r y l E t h y l m i d o n i u m E t h o s u l f a t e ) 0.5
P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e
Phosphate) 2.0
Sodium C h l o r i d e 0.5
Procedure:
Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u -
l o s e and t u r n h e a t o n . A t 50-60C add s t e a r i c a c i d , s t e a r y l
a l c o h o l , Monaquat TG, Monaquat I S I E S , P h o s p h o l i p i d EFA, and
sodium c h l o r i d e . Heat and m i x t o 70-75C ( a smooth c r e m e ) . Cool
t o 40C. A d j u s t pH t o 4 . 5 - 5 . 0 . A d d c o l o r , f r a g r a n c e and p r e s e r v -
a t iv e . Package.
Typical Properties:
Appearance: Opaque v i s c o u s l o t i o n
Recommended Use D i l u t i o n : As i s
F o r m u l a t i o n F-777
P e t Shampoo
Ingredients: Wt%
Water 70.0
M o n a t e r g e 779 25.0
d - L i monene 5.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t
pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package.
Typical Properties:
Appearance: C l e a r y e l l o w l i q u i d
The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m i c r o - e m u l s i o n s o f
imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used b y
u t i n g i n w a t e r a r e v e r y e f f e c t i v e f o r r e m o v i n g many o i l y
. .I r e s i n o u s s o i l s . The f o r m u l a t h e m s e l v e s a r e c l e a r and e x h i b i t
a bloom e f f e c t upon d i l u t i o n .
Formula I
Inqredients: Wt%
d - L i monene 10.0
Monamul s e dL-1273 18.0
Water 62.0
F o r m u l a I1
Inqredients: Wt%
d - L i monene 35.0
Monamulse dL-1273 28.0
Isopropanol 5.0
Water 32.0
Formula I11
Ingredients: Wt%
d - L i monene 65.0
Monamul se dL-1273 23.0
Water 12.0
Procedure:
I n a l l c a s e s , mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d .
Add o t h e r i n g r e d i e n t s e x c e p t w a t e r . M i x u n t i l homogeneous. Add
water s l o w l y w i t h s t i r r i n g .
Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r
M i cro-Emu1 s i ons w i t h P i ne O i 1
Formula 1
Inaredients: &y&
Pine O i l 35.0
Monamulse TRP 20.0
Water 45.0
Appearance: C l e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 2
I ngredients : WtO/o
Pine O i l 20.0
Monamul s e TRP 20.0
Isopropanol 5.0
Water 55.0
Appearance: C1 e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 3
Ingredients: Wt%
Pine O i l 9.0
Monamul se TRP 10.0
Isopropanol 10.0
Water 71 .O
Appearance: C1 e a r
D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 4
Inqredients: WtO/o
Pine O i l 2.0
Monamul se TRP 5.0
Water 93.0
Appearance: C l e a r
D i l u t i o n (1% i n t a p w a t e r ) : Clear
Procedure:
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package
Recommended Use D i l u t i o n : 1 : l O w i t h w a t e r
F o r m u l a F-785
P l a s t i c B o t t l e Wash
Stable i n hard water
Inqredients: Wt%
Water 26.5
KOH-45% 19.5
K a s i l #I 39.0
STPP 8.0
B u r c o HCS-5ONF 7.0
% S o l i d s : 31.0
To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o o f t h e
components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n
i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n d e g r e e
o f s o i l t o b e removed. N o r m a l l y , a 2% end use c o n c e n t r a t i o n i s
s u f f i c i e n t f o r b o t t l e cleaning.
A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .
B o t t l e Wash F o r m u l a t i o n s
Low Foam
Inqredie n t s : y
&
50% NaOH To 100% T o t a l
B u r c o BSGH-270 2.5-5.0%
B u r c o HCS-50NF 0.5-2.5%
M o d e r a t e Foam
Inqredients: W O
The f o r m u l a t i o n s g i v e n h e r e w i l l p r o d u c e c l e a r s t a b l e m i c r o -
e m u l s i o n s c o n t a i n i n g f r o m 15% t o 40% d - l i m o n e n e .
G l i d s o l 180 ( f r o m SCM G l i d c o O r g a n i c s C o r p . ) , a p i n e o i l
d e r i v a t i v e can b e s u b s t i t u t e d f o r d - l i m o n e n e i n t h e f o r m u l a t i o n s
t o g i v e a f l a s h p o i n t above 1 4 0 F . N o t e t h a t o t h e r p i n e o i l s may
n o t work i n t h e s e f o r m u l a t i o n s .
Formula A:
D-Limonene 40.0
Tomah E-14-5 22.4
Tomah E-14-2 2.8
Tomah A l k a l i S u r f a c t a n t 2.8
Water 32.0
% t o t a l s u r f a c t a n t : 28.0%
Emul s i f i e r / T e r p e n e r a t i 0 : 0 . 7 0 0
F o r m u l a 5: Wt.9/o
D-Li monene 30.0
Tomah E-14-5 19.2
Tomah E-14-2 2.4
Tomah A l k a l i S u r f a c t a n t 2.4
Water 46.0
% t o t a l s u r f a c t a n t : 24.0%
Emul s i f ie r / T e r p e n e r a t i 0 : 0 . 8 0 0
Formula C : Wt.%
D-Li monene 20.0
Tomah E - 1 4 - 5 12.8
Tomah E-14-2 1.6
Tomah A l k a l i S u r f a c t a n t 1.6
Water 64.0
% t o t a l s u r f a c t a n t : 16.0%
E m u l s i f i e r / T e r p e n e r a t i o : 0.800
Formula D: Wt.o/a
D-Li monene 15.0
Tomah E-14-5 12.0
Tomah E-14-2 1.5
Tomah A l k a l i S u r f a c t a n t 1.5
Water 70.0
% t o t a l s u r f a c t a n t : 15.0%
Emulsifier/Terpene r a t i o : 1.000
Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogen-
eous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s
w i t h mixing.
A t y p i c a l use l e v e l w o u l d b e a t 1 0 / 1 t o 4 0 / 1 w i t h w a t e r . About
1-2% d - l i m o n e n e a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g r e a s e
would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d-limonene.
Concentrated Formula
Formula:
D-Limonene 70.0
Tomah E-14-5 14.0
Monamid 7 0 5 4.0
T a l l O i l Fatty Acid 1.6
Monoethanolamine 0.4
Water 10.0
SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : T e r p e n e M i c r o e m u l s i o n s
176 Advanced Cleaning Product Formulatioris
Ingredient: vytsb
Bareco C-36 Wax ( 1 ) 12.00
Hoechst Wax E ( 2 ) 8.00
Pemulen 1622 ( 3 ) 0.30
01 Water 79 5 0
~
Physical Properties :
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) P e t r o l i t e Corp.
( 2 ) American Hoechst Corp.
( 3 ) BFGoodrich
Procedure:
1. M e l t t h e waxes t o g e t h e r i n a v e s s e l , a p p r o x i m a t e l y a t 9 0 C .
2 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
Screen t h e Pemulen r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous
and f r e e o f p o l y m e r lumps.
3 . Heat t h e Pemulen d i s p e r s i o n t o 9OC. Add t h e Pemulen d i s p e r -
s i o n t o t h e m e l t e d wax w i t h v i g o r o u s a g i t a t i o n .
4 . Add t h e m o r p h o l i n e and cool q u i c k l y .
Total Actives:
T o t a l Wax: 20.00%
177
15. Auto Cleaners and Polis
178
Auto Cleaners and Polishes 179
Chrome P o l i s h
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Ingredient:
D I Water 39.25
Morphol ine 1.39
Pumice 14.00
Snow F l o s s 9.25
SFSB S i l i c o n e F l u i d ( 3 5 0 ) ( 1 ) 1.85
Yarmor 302 P i n e O i l ( 2 ) 0.46
Oleic Acid 1.85
Mineral S p i r i t s 24.50
TEA l a u r y l s u l f a t e ( 3 ) 2.30
Cocamide DEA ( 4 ) 0.50
D I Water 4.46
Carbopol EZ-2 ( 5 ) 0.19
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 10,800 c p
P r o d u c t pH: 9 . 0
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) General E l e c t r i c
( 2 ) Hercules
( 3 ) Rhone-Poul enc
( 4 ) H e n k e l : Standamid PO
( 5 ) BFGoodri c h
Procedure:
1 . D i s s o l v e t h e morpholine i n t h e water.
2 . W i t h r a p i d a g i t a t i o n , add t h e pumice and Snow F l o s s .
3 . D i s s o l v e t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e
m i n e r a l s p i r i t s . S l o w l y add i n t o t h e above m i x t u r e w i t h
rapid agitation.
4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. B l e n d t h o r -
oughl y .
5. I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 1 9 p a r t s o f Carbopol i n t o
4.48 p a r t s o f w a t e r by s i m p l y "dumping" t h e polymer i n t o t h e
w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y
wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . B l e n d
thorough1y .
T o t a l Asti ves :
Silicone Fluid: 1.85
Total Surfactant: 4.65
Mineral S p i r i t s : 24.50
T o t a l Abrasives: 23.25
L i q u i d Car Polish
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r -
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Insredient: Wt96
D I Water 37.80
T r i e t h a n o l ami ne 8.20
Wax Emulsion ( 1 ) 2.50
Morphol ine 2.00
SF90 S i l i c o n e F l u i d (350) ( 2 ) 1 * 50
Oleic Acid 2.50
Kerosene 10.00
Mineral S p i r i t s 8.00
D I Water 49.70
Carbopol EZ-2 ( 3 ) 0.30
Isopropanol 0.40
Mineral S p i r i t s 5.00
SF1706 R e a c t i v e Amine Polymer ( 4 ) 1.50
SF1705 R e a c t i v e Amine Polymer ( 4 ) 2.10
Kaopolite kaolin clay (5) 8.50
Physical P r o p erties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps
P r o d u c t pH: 8-9
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) see EiFGoodrich L i t e r a t u r e DET-501
( 2 ) General E l e c t r i c
( 3 ) BFGoodrich
( 4 ) General E l e c t r i c
(5) Kaopolite, I n c .
Procedure:
1 . M i x t o g e t h e r t h e w a t e r , TEA, wax emulsion, and t h e m o r p h o l i n e
2 . I n a s e p a r a t e v e s s e l , mix t h e s i l i c o n e f l u i d , o l e i c a c i d ,
kerosene and t h e m i n e r a l s p i r i t s t o g e t h e r . Add t h i s t o t h e
above m i x t u r e w i t h v i g o r o u s a g i t a t i o n .
3. I n a s e p a r a t e v e s s e l , d i s p e r s e 0.30 p a r t s o f Carbopol i n t o
19.70 p a r t s o f water by s i m p l y "dumping" i t i n . The polymer
w i l l wet o u t i n a few minutes. Add t h i s d i s p e r s i o n t o t h e
above m i x t u r e . M i x u n t i l homogeneous.
4 . I n a s e p a r a t e v e s s e l , mix t h e i s o p r o p a n o l , m i n e r a l s p i r i t s ,
and t h e t w o r e a c t i v e amine polymers t o g e t h e r . Add t o t h e
above m i x t u r e . M i x u n t i l homogeneous.
5 . S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous.
Total Actives:
T o t a l Wax : 0.50
Silicone Fluid: 1.50
Mineral S p i r i t s : 11 .oo
React ive A m i ne Polymer : 3.60
Abrasive: 8.50
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-BOO
Auto Cleaners and Polishes 181
L i q u i d Spray C l e a n e r f o r A l u m i n u m T r u c k s
Bngredi e n t s : -
Wt%
Water 50.0
Phosphoric A c i d , 75% 20.0
C i t r i c Acid 10.0
Macol 48 4.0
Ammoni um B i f 1u o r i de 3.0
Avanel S-30 3.0
~ r ~ c ~ d U r ~ ~
Add i n g r e d i e n t s i n o r d e r as l i s t e d . D i l u t e one p a r t c l e a n e r
w i t h f i v e p a r t s w a t e r t o use.
A 1 umi n u m C l e a n e r / B r i n h t e n e r
Pnaredi e n t : Wt%
Phosphoric A c i d , 85% 6.0
C i t r i c A c i d , 50% 8.0
N i t r i c A c i d , 70% 1.o
Avanel S-70 2.0
Water 83.0
Procedure:
Charge t h e w a t e r t o t h e m i x i n g v e s s e l . Under s l o w a g i t a t i o n
and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel
S - 7 0 and mix f o r 10 m i n u t e s . Note: I f a d d i t i o n a l b r i g h t e n i n g i s
r e q u i r e d , t h e n i t r i c a c i d may be i n c r e a s e d t o 1.5%.
F o r m u l a t i o n CM-101
Non-Phosphorous A l u m i n u m C l e a n e r
PPOC@dUr&?:
Charae t h e w a t e r , c i t r i c a c i d , g l u c o n i c a c i d and Avanel S-70
t o t h e G i x i n g v e s s e i . M i x w e l l . I f - d y e i s t o be added, p a r t of
t h e water s h o u l d be h e l d o u t . Add t h e dye t o t h e w a t e r w i t h good
a g i t a t i o n and t h e n add t h e w a t e r t o t h e b a t c h .
Formu 1a t ion CM- 102
M i l d A b r a s i v e A u t o m o b i l e Polish
I n q r e d ie n t : Wt%
Part A:
Masi 1 SF 1 , 0 0 0 4.0
Oleic Acid 2.0
Carnauba Wax #1 Y e l l o w 6.0
Isopar M 14.5
Mazami de SS-1 0 0.75
P a r t B:
Isopar M 12.0
M a s i l 123 2.0
Part C :
Isopar M 2.5
Morphol ine 1.1
P a r t D:
Water 45.15
K a o p o l i t e SF 10.0
pH ( a s i s ) : 7 . 5 - 8 . 5
Appearance: Cream-Colored Paste
Procedure:
1 . Charge t h e components i n P a r t A t o a steam-heated m i x i n g
v e s s e l equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and h e a t t o
9QC.
2. I n s e p a r a t e v e s s e l s , charge P a r t B and P a r t C components.
When P a r t A reaches 9OC and a l l t h e wax has m e l t e d , add P a r t
B t o t h e v e s s e l f o l l o w e d by P a r t C . Apply c o o l i n g .
3 . I n a s e p a r a t e v e s s e l , p r e p a r e P a r t D by a d d i n g t h e K a o p o l d t e
SF t o t h e w a t e r under a g i t a t i o n . Add P a r t D t o P a r t A and
c o n t i n u e c o o l i n g . NOTE: The f i n i s h e d p r o d u c t i s a p a s t e .
A s t i f f e r p a s t e can be p r e p a r e d by i n c r e a s i n g t h e o l e i c a c i d
charge.
SOURCE: PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n S A - 1 0 1
0 r and Truck Wash Compounds
183
184 Advanced Cleaning Product Formulations
Car Shampoo C o n c e n t r a t e
Ingredient: Wt%
Part A:
Dei o n i zed Water 30.0
Sodi um C i t r a t e 0.5
P a r t 8:
Mafo CSB-50 5.0
W i t c o n a t e 60 T L i q u i d 7.5
Macol TD-12 4.0
T r i e t h a n o l ami ne, 85% 1.o
D e i o n i z e d Water 52.0
pH ( a s i s ) : 8 . 0 - 9 . 0
Appearance: C l e a r , l i g h t - y e l l o w l i q u i d
S p e c i f i c G r a v i t y : 1.00
Procedure:
1 . Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and
d i s s o l v e t h e sodium c i t r a t e i n i t .
2 . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . S t o p
a g i t a t i o n and p e r m i t t h e p r o d u c t t o d e a e r a t e p r i o r t o
f i l l i n g o f f . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r
g a l l o n o f warm w a t e r .
A u t o m a t i c Car Wash C o n c e n t r a t e
I n a r e d ie n t s : w.t%
Dei o n i zed Water 50.0
Maphos 60-A 6.0
P o t a s s i um H y d r o x i d e 3.0
T e t r a p o t a s s i u m Pyrophosphate 2.0
Sodium M e t a s i l i c a t e , Anhydrous 2.0
Macol LF 120 2.0
Mazamide 00 2.0
Sodium X y l e n e S u l f o n a t e , 40% 3.0
Macol 48 3.0
D e i o n i z e d Water 27.0
pH ( a s i s ) : 12.5-13.5
Appearance: C l e a r , l i g h t - y e l l o w l i q u i d
S p e c i f i c Gravity: 1 .06
Procedure:
Charge t h e f i r s t p o r t i o n o f w a t e r t o t h e m i x i n g v e s s e l and
s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix
u n t i l c l e a r . NOTE: T h i s i s a h i g h l y a l k a l i n e c l e a n e r d e s i g n e d t o
be used i n commercial a u t o m a t i c c a r washes a t a d i l u t i o n r a t e o f
1-2 ounces p e r g a l l o n . Do n o t use d i r e c t l y on a u t o m o t i v e f i n i s h e s
F o r m u l a t i o n CA-102
1
Car and Truck Wash Compounds 185
Car Wash
Readi l y removes a w i d e v a r i e t y o f r o a d s o i 1 s .
Ingredients:
Water 70.0
Monaterge ALX-100s (Cocamide DEA ( a n d ) DEA D o d e c y l -
benzenesulfonate (and) Diethanolamine) 30.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH
t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package.
Typi c a l P r o p e r t i e s :
Appearance: C l e a r y e l l o w l i q u i d
Recommnded Use D i l u t i o n : 1 : 2 0 w i t h w a t e r
F o r m u l a t i o n F-772
P a s t e Car Wax
T h i s e a s i l y a p p l i e d a u t o m o b i l e p a s t e wax f o r m u l a w i l l p r o v i d e
i m p r o v e d c l e a n i n g , d e p t h o f g l o s s , l a s t i n g b e a u t y and s h i n e t o
new and o l d e r a u t o m o b i l e f i n i s h e s . M o n a s i l PCA w i l l p r o v i d e
s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a .
Ingredients: We96
P a r t I:
M o n a s i l PCA 4.5
Dimethicone (12,500 c s t ) 2.0
Carnauba Wax #1 Y e l l o w 6.0
T a l l O i l Fatty Acid 3.0
Isopar K 24.0
Kaopol it e 11 5 2 10.0
P a r t 11:
Water 50.0
TEA (99%) 0.5
Procedure:
P r e p a r e each phase s e p a r a t e l y , h e a t t o 70C. Add P a r t I I
s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo t o 40-50C and
package.
F o r m u l a t i o n F-826
Car Wash w / A m p h o t e r i c
Ingredients: wt%
Water, D . I . 55.0
Sodi um T r i p o l y p h o s p h a t e 4.0
R e w o t e r i c AM 8-14 10.0
V a r o n i c DM-55 2.0
Sodi um H y d r o x i d e , 30% 9.0
W i t c o 1298SA 20.0
B1 e n d i ngProcedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 290
S o l i d s : 29.5%
pH: 8 . 9
F o r m u l a 630
W i n d s h i e l d Washer C o n c e n t r a t e
Ingredients: Wt%
Water, D . I . 56.0
Isopropanol 30.0
P e t r o BAF Powder 1.o
DeSophos 5AP 0.5
EDTA, 38% 2.5
F o r m u l a 666
W i n d s h i e l d Washer F o r m u l a t i o n
51 e n d i ng P r o c e d u r e :
D i s s o l v e W i t c o n a t e 1240 in w a t e r , t h e n add i s o p r o p a n o l
F o r m u l a 867
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
188 Advanced Cleaning Product Formulations
I n q r e d ie n t s :
Water, D . I . 64.9
W i t c o l a t e SE-5 8.3
W i t c o n a t e 1260 S l u r r y 16.7
P e t r o LBA L i q u i d 1.3
DeSonic 81-6 5.0
W i t c a m i d e 128T 3.8
Typical Properties:
V i s c o s i t y , c p s : 210
A c t i v e s , %: 2 3 . 7
F o r m u l a 61 1
Ingredients: W S
Water, D . I . 43.3
W i t c o l a t e SE-5 13.9
W i t c o n a t e 1260 S l u r r y 27.8
P e t r o LBA L i q u i d 5.0
DeSonic 81-6 7.0
W i t c a m i d e 128T 3.0
T y p i c a l P r o p e r t ie s :
V i s c o s i t y , c p s : 335
A c t i v e s , %: 37.5
F o r m u l a 611
I n a r e d ie n t s :
Water, D . I . 36.0
W i t c o l a t e SE-5 15.0
W i t c o n a t e 1260 S l u r r y 30.0
P e t r o LBA L i q u i d 6.0
DeSonic 81-6 8.0
W i t c a m i d e 128T 5.0
B l e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d .
Typical Properties:
V i s c o s i t y , c p s : 315
A c t i v e s , %: 4 3 . 0
F o r m u l a 611
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 189
C a r and T r u c k Wash F o r m u l a
Ingredients: Wei q h t %
C a l f a x DB-45 19.83
C a l s o f t L-40 24.95
T r i s o d i um Phosphate 10.02
Water 45.18
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-001-01
Car a n d T r u c k Wash F o r m u l a
Ingredients: Wei q h t %
C a l f a x DB-45 20.00
C a l s o f t L-40 25.17
D i s o d i um Phosphate 10.04
Water 44.76
Comments a b o u t t h i s f o r m u l a :
1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01.
2 . H e a t i n g i s n e c e s s a r y t o homogenize.
F o r m u l a t i o n CWC-002-01
Ingredients: Wei q h t %
Sodi um T r i p o l y p h o s p h a t e 85.00
C a l s o f t F-90 5.00
Cal o x y l a t e N-9 10.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-003-01
C a r Wash ( C a l s u d s A-Based)
Inqredients: Wei g h t %
Calsuds A 50.00
C a l foam EA-603 3.00
C a l o x y l a t e N-9 2.00
Water 45.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n CWC-004-01
Windshield-Cleaner (Summer)
Inqredi ents: Wt%
Water 67.9
Ethanol 20.0
Zusol at 1 0 0 5 / 8 5 5.2
Zusolat 1 0 0 8 / 8 5 6.9
Formula CT 0 4 - 0 6 - 0 1
Windshield-Cleaner (Winter)
Ingredients: Wtl
Water 29.5
Isopropanol 70.0
Z e t e s o l 2056 0.5
F o r m u l a CT 04-06-07
I n s e c t Remover
Wheel C 1 e a n e r . A 1 k a l in e
Ingredients: Wt%
Water 77.5
Tetrapotassium pyrophosphate 3.0
Lumorol 4192 10.0
Z u s o l a t 1005/85 4.0
Butyl diglycol 5.0
Orange t e r p e n e 0.5
F o r m u l a CT 0 4 - 1 1 - 0 4
T a r Remover
Inqredients: Wt%
M u l s i f a n K 326 S p e z i a l 15.0
Whi t e - s p i r i t 60.0
n-butanol 7.0
Oleic acid 3.0
Water 15.0
F o r m u l a CT 04-13-02
Car Wax
Ingredient: Wt%
Part A:
Morphol ine 0.8
Water 44.2
P a r t B:
Wax S 8.0
Oleic Acid 1.o
M i n e r a l Spi r i t s 18.0
Kerosene 9.0
Part C:
M a s i l EM 250 C 10.0
M a s i l EM 1 0 , 0 0 0 C 3.0
Snow F l o s s 3.0
Kaopol it e SF 3.0
Carbopol 941 ( 1 % i n w a t e r ) As needed
Procedure:
1 . Add t h e m o r p h o l i n e t o t h e w a t e r w i t h h i g h speed m i x i n g .
2 . I n P a r t B , add t h e o l e i c a c i d , m i n e r a l s p i r i t s , kerosene,
and Wax S w i t h h i g h speed m i x i n g . Add P a r t B t o P a r t A w i t h
h i g h shear m i x i n g .
3 . Add t h e M a s i l EM 250 C and M a s i l EM 10,000 C f r o m P a r t C t o
t h e c o n c e n t r a t e w i t h s l o w m i x i n g . Add t h e Snow F l o s s and
K a o p o l i t e S F . T h i c k e n w i t h t h e Carbopol 941 s o l u t i o n .
A u t o Wipe B S h i n e P o l i s h
Ingredient;
Part A:
M a s i l SF 100 3.5
A-C 617A 2.0
Oleic Acid 1.5
M i n e r a l O i 1 , 70 SUS 5.6
Part 0 :
Morphol ine 1.4
Carbopol 934 0.2
Triethanolamine 0.2
Water 85.6
Procedure:
1 . Add t h e i n g r e d i e n t s i n P a r t A as l i s t e d and h e a t t o 9OC.
2 . F o r P a r t B, h e a t t h e w a t e r t o 85C. D i s p e r s e t h e Carbopol 934
i n t h e w a t e r . When c o m p l e t e l y d i s s o l v e d , add t h e t r i e t h a n o l -
amine. Then, add t h e m o r p h o l i n e .
3. Add P a r t A t o P a r t 0 and b l e n d .
Concentrated T r a f f i c F i l m Removers
% anhydrous b u i l d e r : 19.00
S u r f a c t a n t / b u i l d e r r a t i o : 1.68
% anhydrous b u i l d e r : 9.82%
S u r f a c t a n t / b u i l d e r r a t i o : 4.07
N o t e t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y a b o u t
57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s
a b o u t 38% t e t r a s o d i u m EDTA on an a n h y d r o u s b a s i s . Thus t h e s e
f o r m u l a t i o n s a r e a b o u t 50% t o t a l w a t e r when c a l c u l a t e d on an
a n h y d r o u s b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an
a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t .
Anhydrous sodium m e t a s i l i c a t e and a n h y d r o u s t e t r a s o d i u m EDTA
a r e r e a d i l y a v a i l a b l e ; a n h y d r o u s a m p h o t e r i c s and amine o x i d e s
are not.
These f o r m u l a t i o n s were made up and f o u n d t o b e f r e e z e - t h a w
s t a b 1 e.
F o r m u l a 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and
t e s t e d b y s p r a y i n g on a d i r t y c a r . It was compared w i t h F o r m u l a -
t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g -
n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c
d i d n o t adversely a f f e c t t h e performance o f t h e concentrated
f o r m u l a t i on.
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
194 Advanced Cleaning Product Formulatioris
Inqredients: Wtg
Water, D . I . * 79.75
C a u s t i c Soda, 50% 1.40
W i t c o 1298SA 5.00
W i t c o l a t e SE-5 7.00
P e t r o BAF L i q u i d 3.00
W i t c a m i d e 128T 3.00
Formal i n 0.10
Sodi um C h l o r i d e 0.75
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d . Sodium C h l o r i d e i s
used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t .
T y p i c a l P r o p e r t i es :
S p e c i f i c G r a v i t y : 1.015
Wt./Gal. l b s . : 8.46
pH, a s i s : 9 . 8
V i s c o s i t y , cps: 410
D i l u t i o n R a t i o a t Wand=l : 4 0
* I f u n s o f t e n e d t a p w a t e r i s used, add 0 . 2 5 % l i q u i d EDTA, 40%
t o counteract hardness.
F o r m u l a 621
Low C o s t Car=
Ingredients: Wt%
Water. D . I . 89.9
P e t r o LBA Powder 1 .o
W i t c o l a t e SE-5 6.0
W i t c a m i d e 128T 3.0
Formal in 0.1
Sodi um C h l o r i d e 4.s.
Perfume, Dye 4.s.
Blending Procedure:
Blend t h e i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t t h e
p H = 7 . 5 - 8 . 0 . The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y
o f the f i n a l product.
F o r m u l a 609
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 195
G e n e r a l Purpose C a r Wash
T h i s i s a c o p i o u s - f o a m i n g , a l l - p u r p o s e c a r wash f o r m u l a t e d t o
b e s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d
g r i m e and o t h e r s o i l s .
Insredient : w b
D e i o n i z e d Water 50.0
Mazon 98 9.5
Macol TD-3 1.5
W i t c o l a t e WACLA 2.5
Mazamide 80 3.0
Macol 48 1.o
Triethanolamine, 85% 1.5
D e i o n i z e d Water 31 . O
pH ( a s i s ) : 8 . 5 - 9 . 5
Appearance: C l e a r , l i g h t - y e l l o w liquid
S p e c i f i c G r a v i t y : 1.02
Procedure:
Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and
s t a r t slow a g i t a t i o n (excessive a g i t a t i o n w i l l produce a
f o a m i n g p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r
l i s t e d and m i x u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2
ounces p e r g a l l o n o f warm w a t e r .
F o r m u l a t i o n CA-103
L i q u i d Car Wash
Ingredient: NtS
Water 34.0
W i t c o n a t e 60 T L i q u i d 30.0
Macol OP-10 SP 10.0
Mazamide 80 6.0
Hexyl Carbi t o 1 10.0
Methanol 10.0
Procedure:
Add i n g r e d i e n t s i n o r d e r a s l i s t e d .
Ingredient: vvt%
Water 39.0
Mazamide 80 11 . o
Macol NP 9 . 5 5.0
W i t c o n a t e 60 T L i q u i d 45.0
Procedure:
Add i n g r e d i e n t s i n o r d e r as l i s t e d .
Heavy D u t y T r u c k Wash, L i q u i d
Inqredients:
Water, D . I . 70.0
T r i s o d i um Phosphate, C r y s t a l 2.0
C a u s t i c Soda Beads 2.0
W i t c o 1298 S o f t A c i d 10.0
P e t r o BAF L i q u i d 3.0
Sodium S i l i c a t e 40 Be' ( S t a r ) 3.0
W i t c o l a t e SE-5 3.0
E t h y l e n e G l y c o l M o n o b u t y l E t h e r (EB) 3.0
Emcol 6744 4.0
Blending Procedure:
B l e n d i n g r e d i e n t s in o r d e r 1 i s t e d .
Typical Properties:
S p e c i f i c G r a v i t y : 1.042
Wt./Gal. l b s . : 8.69
pH, a s i s : 1 2 . 7
D i l u t i o n R a t e : D i l u t e 1 : 4 0 a t Wand
F o r m u l a 603
Inqredients: wtd/,
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 47.25
Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y 55.00
DeSophos 5AP 2.90
DeSonic 9N 7.50
Sodium M e t a s i l i c a t e , Anhydrous 5.00
Sodium S u l f a t e ( S a l t Cake) 10.00
C a u s t i c Soda Beads 2.30
Dye* 0.05
B1 e n d i ng P r o c e d u r e :
P r e m i x Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos
5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n a p p e a r a n c e . Add
DeSonic 9 N w h i l e m i x i n g . M i x u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5
m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda
beads.
* I f d y e i s used, m i x w i t h t h e DeSonic 9N.
F o r m u l a 604
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 197
Ingredients: Wt%
Water, D . I . 11.7
Ethanol 5.9
Varox 1 7 7 0 17.6
W i t c o n a t e AOS L i q u i d 46.8
W i t c o l a t e SE-5 17.6
B l e n d i ng P r o c e d u r e :
Add a l l i n g r e d i e n t s e x c e p t W i t c o l a t e SE-5, i n o r d e r shown and
d i s s o l v e completel’y between each a d d i t i o n . Add W i t c o l a t e SE-5
l a s t i n s m a l l a l i q u o t s a l l o w i n g c o m p l e t e d i s s o l u t i o n between
additions.
T y p i c a l P r o p e r t i es :
V i s c o s i t y , c p s : 160
S o l i d s : 35.4%
pH: 8.4
Formula 629
Car Wash
Ingredients: Wt%
Water 91.67
T e t r a p o t a s s i um Pyrophosphate, 60% 3.33
W i t c a m i de 6445 5.00
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 2100
S o l i d s : 6.8%
pH, as i s : 9 . 3
Formula 615
A u t o Shampoo C o n c e n t r a t e
P n g r e d ie n t s : Wt%
Water, D . I . 80.0
R e w o t e r i c AM KSF-40 15.0
W i t c o l a t e SE-5 5.0
Blending Procedure:
Add in g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , cps: 4.0
S o l i d s : 9.0%
ptl: 9 . 5
Formula 628
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
198 Advanced Cleaning Product Formulations
T o u c h l e s s V e h i c l e Wash D e t e r a e n t
l Z e r o Phosphate, Powder)
Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal surface, Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on
Composition: \nrt36
Sodium C a r b o n a t e 25-30
M e t s o Beads 2048 20-25
*Sodium P o l y a c r y l a t e (92% s o l i d s ) 1.0- 3.0
Surfactant 5-1 0
T u r b o b r i t e A1 umi n o s i 1 ic a t e 25-35
F i 1l e r s Balance
D i l u t i o n : 1.0-2.0% by weight ( 0 . 1 - 0 . 2 pounds/gallon)
Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o
t h e s p r a y n o z z l e . M i x powder d e t e r g e n t i n t a n k and m e t e r i n t o
c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f
T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash
systems f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s ,
and haze f r o m body p a r t s and w i n d s h i e l d s .
C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep T u r b o b r i t e
suspended.
Truck/Bus Wash
Components: % by Weight
Burco TME 7
B u r c o s o l v TM 5
Neodol 91-6 20
TEA 85% 5
Burcene 1 0 0 2
Water 8 a l ance
Components: % by Weight
Water 76
Burco TME
Meodol 1.5
C i t r i c A c i d L i q u i d 50%
KOH. 45%
Ammonyx LO
TEA 85%
Car Shampoo
In g r e d ien t s : % by Wei a h t
Z e t e s o l 2056 15.0
Lumo WW 75 10.0
Z u s o l a t 1008/85 3.0
P u r t o n CFD 1. o
Water 75.0
Formula D 1 1 / 1 0
Ingredients: % by Weiqht
Zusol a t 1008/85 10.0
Wachsemul s i on 1864 10.0
Isopropanol 2.0
Water, p r e s e r v a t i v e q . s . t o make 1 0 0 . 0
Formula D 12/2
V e h i c l e Wash D e t e r g e n t
e h o s p h a t e . Powder1
V e h i c l e Wash D e t e r g e n t
( L i q u i d , low foam)
Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal s u r f a c e , Polymeric
Appl ic a t i on Method-Hi gh p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Mix t a n k w i t h p r o p e l l e r spray
Composi t i on : Wt%
Water 51.66
Carbopol 674 0.5
D L i q u i d Sodium S i l i c a t e 8.1
*Acusol 445N Sodi um P o l y a c r y l a t e (45% s o l i d s ) 1.84
Sodium Carbonate 9.1
T u r b o b r i t e A 1 umi n o s i 1 ic a t e 24.5
* * L i q u i d Nonionic Surfactant 4.3
D i l u t e l i q u i d d e t e r g e n t w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 64
g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system.
M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s
e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , w a t e r
d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d .
* Rohm & Haas
** Low Foam: Rhone-Poulenc A n t a r o x BL-240
H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7
T o u c h l e s s V e h i c l e Wash B o o s t e r / A d d i t i v e
L Z e r o Phosphate, L i q u i d )
Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
road f i l m
Surface-Painted metal s u r f a c e , Polymeric
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: Wt%
T u r b o b r i t e L (25 w t . % a c t i v e T u r b o b r i t e A l u m i n o s i l i c a t e
S1u r r y ) 100.0
D i l u t e l i q u i d T u r b o b r i t e L a t h i g h p r e s s u r e pump w i t h w a t e r
( 1 g a l l o n d e t e r g e n t : 128 g a l l o n s w a t e r ) and d e l i v e r t o h i g h
p r e s s u r e s p r a y wash system.
M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e
i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c l a y s ,
c a r b o n b l a c k , b r a k e d u s t ) , w a t e r d e p o s i t s , and haze f r o m body
p a r t s and w i n d s h i e l d .
T u r b o b r i t e L can be used as an a d d i t i v e o r b o o s t e r f o r con-
v e n t i o n a l t o u c h l e s s , h i g h p r e s s u r e carwash o r f l e e t w a s h d e t e r -
gents.
O r make a d e t e r g e n t by b l e n d i n g T u r b o b r i t e L w i t h 1-2% low-
foaming n o n i o n i c s u r f a c t a n t t o make f o r b e s t c l e a n i n g r e s u l t s .
D i l u t e T u r b o b r i t e L / s u r f a c t a n t b l e n d a t h i g h p r e s s u r e pump w i t h
w a t e r (128: 1 ) .
T u r b o b r i t e L a l s o works i n waxes, p o l i s h e s , and o t h e r d e t a i l -
ing p r o d u c t s .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
17. Whitewall Tire Cleaners
202
Whi tena 1 1 Ti.r&C!ean.ey
1z e ro .P.b-s phate -?.w&cl
Soil-Clay, p a r t i c u l a t e , o i l , grease
Surface-Whitewal 1 t i r e s
Application Method-High pressure s p r a y / b r u s h / w i p e
M a n u f a c t tire - D r y b 1 end/Agg 1 o m e r a t i On
c_q.m3osi t i . o n l Nt%
Valfor 100 Zeolite A 35.0
* A c u s o l 4 4 5 N D Sodium P o l y a c r y l a t e ( 9 2 % Solids) 2.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) 8.0
Sodium A l k y l a r y l S u l f o n a t e 10.0
M e t s o Beads 2 0 4 8 35.0
Sodium Carbonate 12.0
* Rohm & Haas
** Rhone-Pou 1 e n c R h o d a s u r f 91 - 6
wi j.t.ew a
n-T i.r,e C L Y C ~e 1:
1Pbes?batePowde.!’l
Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e
Surface-Whi tewal1 t i r e s
Application M e t h o d s - H i g h pressure spray/brush/wipe
Manufacture-Dry blend
re,&!ea_n_er
WRitewal..1..Ti
(.Lictuj.d).
Soil-Clay, p a r t i c u l a t e , o i l , p r e a s e
Surface-Whi tewall tires
A p p l i c a t i o n Method-High p r e s s u r ’ e s p r a y / b r u s h / w i p e
M a n u f a c t u r e - M i x t a n k w i t h propeller s t i r r e r
C o m q . ~!.f.bn:
S flL?b
Water 70.0
Potassium H y d r o x i d e 145%) 16.0
N C l e a r o r S t a r Sodium Silicate 10.0
S o d i uni A 1 k y l a r y l Sulfonate ( 6 0 % ) 2.0
* L i q u i d N o n i o n i c S u r f a c t a n t (CS-Cll; 6 m o l e s E O ) 2.0
* R h o n e - P o u l e m R h o d a s u r f 91 - 6
S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
18. Miscellaneous
204
Miscellaneous 205
A i r c r a f t Cleaner
(Reduced Phosphate. Powder)
Composi t i on : Wt%
Metso Pentabead 20 30.0
V a l f o r 100 Z e o l i t e A 30.0
Ammoni u m B i f 1u o r ide 8.0
TSPP 20.0
*Sodi um A1 k y l naphtha1 ene Sul f o n a t e 8.0
**Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 4.0
* Rhone-Poulenc S u p r a g i l N K
** Witco
N o t e : C o n s t a n t a g i t a t i o n i s r e q u i r e d i n s t o c k t a n k t o keep
V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t
Carbopol 647 (BFGoodrich) as a suspending a g e n t .
A i r c r a f t 61 eaner
(Phosphate, Powder)
S o i l - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i l and grease
Surface-Metal
A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i )
M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on
Composi t i on : Wt%
Metso Pentabead 20 30.0
*STPP 30.0
Ammonium B i f l u o r i d e 8.0
*TSPP 20.0
**Sodium A1 k y l n a p h t h a l e n e S u l f o n a t e 8.0
***Sodi um A1 k y l a r y l Sul f o n a t e Powder (90%) 4.0
Use D i l u t i o n : 1 . 5 - 6 . 0 % bw ( 2 - 8 o z / g a l l o n )
* FMC
** DeSoto, Inc.
*%Xc Witco
OURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
206 Advanced Cleaning Product Formulations
A u t o Care: I n t e r i o r / E x t e r i o r Rubber B V i n y l P r o t e c t a n t
F u n c t i ons 8 Benef it s :
Pemul an 1622 :
*Primary e m u l s i f i e r f o r s i l i c o n e o i l
*NO s u r f a c t a n t s and no s o l v e n t s r e q u i r e d e q u a l s z e r o VOC
*Imparts y i e l d value f o r v e r t i c a l c l i n g
* E x c e l l e n t w e t t i n g f o r " s p r a y and no-wipe" a p p l i c a t i o n s
*Improved d u r a b i l i t y and w a t e r - r e s s t a n c e
Good-Rite K-752:
* R e d u c t i o n i n emu1s i on v i s c o s i t y w t h o u t l o s s i n s t a b i l i t y
I n q r e d ient : Wtl
D I water 78.55
Pemulen 1622* 0.20
1000 c S t s i l i c o n e o i l * * 20.00
DC Q2-5211*** 0.50
T r i e t h a n o l a m i n e (99%) 0.25
Good-Rite K-752 (63%)**** 0.50
* E m u l s i f i e r : BFGoodrich
* * P r o t e c t a n t : DC 200 F l u i d : Dow C o r n i n g
* * * S u p e r - w e t t i n g a g e n t : DC (12-5211: Dow C o r n i n g
* * * * V i s c o s i t y r e d u c t i o n : BFGoodrich
Physical Properties:
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP
P r o d u c t pH: 5.5-6.0
P r o d u c t C l a r i t y : Opaque
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n
t h e Pemulen r e s i n i n t o t h e D I w a t e r . Mix t h e s l u r r y f o r app-
r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous.
2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n .
3. Add t h e DC Q2-5211 s u p e r - w e t t i n g a g e n t w i t h moderate a g i t a t i o n
4 . Add t h e t r i e t h a n o l a m i n e w i t h moderate a g i t a t i o n .
5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 p o l y m e r . The
v i s c o s i t y w i l l d r o p f r o m a b o u t 3,000 CP t o <200 CP w i t h t h i s
addition.
6. A d j u s t t h e pH w i t h a d d i t i o n a l t r i e t h a n o l a m i n e , i f n e c e s s a r y .
7 . Add f r a g r a n c e and c o l o r , as d e s i r e d .
Boat Polish
I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e
a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y
suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase separ-
a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .
Physical P r o p erties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 7,200 cps
P r o d u c t pH: 9.00
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) General E l e c t r i c
( 3 ) Hoechst Celanese
(4) Kaopolite, Inc.
Procedure:
4 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r by s i m p l y "dumping" i t
i n . The polymer w i l l wet o u t i n a few m i n u t e s .
2 . Add t h e m o r p h o l i n e , m i x w i t h good a g i t a t i o n . Heat t o 60-65C.
3 . I n a s e p a r a t e v e s s e l , combine t h e s i l i c o n e f l u i d , V i s c a s i l ,
o l e i c a c i d , and t h e wax i n t h e m i n e r a l s p i r i t s . Heat t o 90-95C
u n t i l t h e wax m e l t s and t h e m i x t u r e appears homogeneous. Add
to t h e above m i x t u r e w i t h good m i x i n g .
4 . When homogeneous, c o o l t o 60-65C.
5. I n a s e p a r a t e v e s s e l , combine t h e m i n e r a l s p i t i t s and t h e
r e a c t i v e amine p o l y m e r . Add t o t h e above m i x t u r e w i t h h i g h
shear m i x i n g .
6. S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous.
Total Actives:
T o t a l Wax : 1.50
Total Silicone Fluid: 4.50
R e a c t i v e A m i ne Polymer : 2.00
Mineral S p i r i t s : 13.00
Abrasive: 12.00
$ ~ BFGoodrich
~ ~S p e c i a~l t y Chemicals:
~ : DET-520
208 Advanced Cleaning Product Formulations
C o n c r e t e Cleaner/Deqreaser
I n g r e d ie n t s : WtB
Water, D . I . 81 . O
Sodium T r i p o l y p h o s p h a t e 2.0
T r i s o d i um Phosphate 1.o
Varami de A-83 6.0
V a r o n i c DM55 10.0
B l e n d i n g Procedure:
Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t ion.
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 0
S o l i d s : 19.0%
Formula 937
Garage F l o o r C1eaner
I n s r e d ie n t s : Wt%
Water 82.0
T r i s o d i um Phosphate 8.0
Emphos PS-236 4.0
W i t c o n a t e 45 L i q u i d 6.0
B l e n d i n g Procedure:
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A l l o w f o r complete
b l e n d i n g between a d d i t i o n s .
Formula 941
A c i d Rust Remover
I n q r e d ients: \Me%
Water, D . I . 81 . O
Phosphoric A c i d , 86% 15.0
C i t r i c Acid 3.0
Varox 365 1.o
B l e n d i n g Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ies :
V i s c o s i t y , cps: 4
S o l i d s : 16.2%
pH: 1.3
Formula 1116
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Miscellaneous 209
Concrete/Driveway Cleaners
F o r l e a f and o t h e r t a n n i n s t a i n s - u s e as i s . Wet s p o t .
S p r i n k l e FB Sodium P e r c a r b o n a t e o n t o s p o t . S c r u b i n and r i n s e
w i t h hose when s p o t i s removed.
For O t h e r S t a i n s
Component: Wt%
Soda Ash (Dense) 25
B r i t e s i 1 H-24 15
TSP Anhydrous 20
B u r c o s p e r s e AP Powder 5
Dry S u r f a c t a n t * 5
FB-Sodi um P e r c a r b o n a t e 30
Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . S c r u b i n and a l l o w t o
s t a n d . R i n s e w i t h hose.
*Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r
Sodium Cocoyl T a u r a t e s can b e used.
Neavv D u t y C o n c r e t e C l e a n e r ( P h o s p h a t e F r e e ) F o r m u l a 1C
Wt%
Water, D . I . 75.0
EDTA, 38% 0.5
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 2.0
Sodium C a r b o n a t e (Soda Ash) 1.5
W i t c a m i d e S-780 6.5
W i t c o n o l NP-120 1.5
B u t y l Cel l o s o l v e 3.0
Mineral S p i r i t s 4.0
KOH, 45% 2.5
W i t c o n a t e SXS L i q u i d 1.5
Pine O i l 2.0
Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d , m i x i n g w e l l a f t e r each
addition.
Typical Properties:
S p e c i f i c G r a v i t y : 1 .022
Wt./Gal. I b s . : 8.52
pH, as i s : 1 3 . 1 8
3 Freeze/Thaw C y c l e s : Passed
1 Week @ 52C: Passed
4 Weeks Room Temp: Passed
S o l i d s : 13.5%
Use D i l u t i o n : As s t r o n g as needed, d e p e n d i n g on t y p e o f s o i l .
__
V i n y l Dressing
In g r e d i& ~-
Wt%
Part A:
M a s i l EM 250 C 30.0
Dei o n i zed Water 30.0
P a r t 8:
M a c o l NP 9 . 5 1.5
G1 y c e r i n e 1.5
D e i o n i z e d Water 36.9
Sodium B e n z o a t e 0.1
Procedure:
1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and s t a r t
g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r s o a s n o t t o b r e a k t h e
emu1 s i o n .
2 . I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol NP 9 . 5 a n d
g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l
components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h
e y e s " . Charge t h e sodium b e n z o a t e a n d m i x u n t i l d i s s o l v e d .
3 . Under g e n t l e a g i t a t i o n , c h a r g e P a r t B t o P a r t A . C o n t i n u e
m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s
d e s i g n e d t o be u s e d " a s i s " as a d r e s s i n g f o r r u b b e r and v i n y l
p r o d u c t s . I f d e s i r e d , UV a b s o r b e r s a n d o t h e r components may
be added t o t h e f o r m u l a t i o n .
F o r m u l a t i o n SV-101
Inqredient: &%
M a s i l EM 1 0 , 0 0 0 C 10.0
M a s i l EM 2 5 0 C 18.0
Macol NP 9 . 5 2.0
Glycerine 1.5
B a r q u a t MB-50 0.1
Water 68.4
Procedure:
Add t h e s i l i c o n e e m u l s i o n t o a b l e n d e r . S l o w l y a d d a p o r t i o n
o f t h e w a t e r and a g i t a t e . Add t h e M a c o l NP 9 . 5 and g l y c e r i n e .
M i x f o r 10 m i n u t e s . Add t h e b a l a n c e o f t h e w a t e r a n d m i x f o r 15
minutes.
211
212 Advanced Cleaning Product Formulations
A m p h o t e n s i d 84 Amphoteric s u r f a c t a n t Zschim
A m p h o t e r i c SC A m p h o t e r i c (35% a c t i v e ) Tomah
A m p h o t e r i c TC Hydrotrope Tomah
Aquamoll i n BC Powder
Aristonate M P e t r o l e u m s u l f o n a t e (61%) Pi l o t
83-120 b q u i d Sodi um S i 1 ic a t e PO
B r i j 96 Surfactant ICI
B r i t e s i 1 c20 Hydrous sodium p o l y s 1 i c a t e PQ
B u r c o l i t e BSGH-255 Burlin
B u r c o s o l v TM Water s o l u b l e s o l v e n t m i x t u r e Burli n
B u r c o s p e r s e AP Powder S o d i um p o l y a c r y l a t e B u r l in
B u r c o s p e r s e LP Sodium p o l y a c r y l a t e s o l u t i o n Burli n
B u r c o s p e r s e SP-60 Sodium p o l y a c r y l a t e B u r l in
B u r c o t a s e EP-60 P r o p r i e t a r y d e t e r g e n t enzyme B u r l in
B u r c o t r o p e 1250 Burlin
B u r c o w h i t e BBH-20 B u r l in
Burdac-114
C a l f a x 1OL-45 S o d i um a1 k y l ( 1 in e a r ) d i p h e n y l Mona
o x i d e d i s u l f o n a t e 45%
C a l s o f t F-90 L i n e a r a1 k y l a t e s u l f o n a t e Pilot
Ca r b o p o l 69 1 Suspension a i d BFGood
CDB C l e a r o n C h l o r i n a t e d is o c y a n u r a t e 01 i n
Cublen D50
Decanol
Diatomaceous E a r t h Kaopol
D L i q u i d Sodium S i l i c a t e PQCorp
D i p r o p y l e n e G l y c o l Monoethyl E t h e r S o l v e n t Dow or
Arc0
Dodigen 226
Dow C o r n i n g 20 R e l e a s e C o a t i n g DowCor
D r e s i n a t e 91 R o s i n soap Hercul
E L i q u i d Sodium S i l i c a t e PQ
E m u l s i f i e r F o u r HF D i a1 k y l q u a t e r n a r y ( 7 5 % a c t i v e ) Tomah
Epsom S a l t PQ
218 Advanced Cleaning Product Formulations
G e o r g i a M a r b l e W h i t e #8 c a l c i u m c a r b o n a t e GaMarb
G l u c o n i c A c i d S o l u t i o n (50%) Ashlan
G l y c o l E t h e r DPM
G l y c o l E t h e r PM
GP-121 S i l i c o n e P o l i s h A d d i t i v e Genes
GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n Genes
Trademarked Raw Materials 219
H i t e c E-515 Ethyl
I g e p a l CA-520 O c t y l p h e n o x y p o l y e t h o x y e t h a n o l . 5 EO Rhone-
I g e p a l CA-620 O c t y l p h e n o x y p o l y e t h o x y e t h a n o l , 8 EO Rhone-
K a o p o l i t e SF A n h y d r o u s a l u m i num s i 1 ic a t e Kaopol
K a s i l #1 P o t a s s i um s i 1 i c a t e PQ
K a s i l #6 P o t a s s i um s i 1 ic a t e PQ
Kerr-McGee M i n e r a l S e a l O i Kerr-
K o m p e r l a n KD
L a r o s t a t 88 Ant s t a t PPGMaz
L a u n d r y A d d i t i v e LA-5 Tomah
Lonzabac-1230 Lonza
Lumo WW 75 Zschim
M e d i a l a n KA Conc.
M o n a s i l PCA Mona
M o n a t e r i c CyNa-50 1 - H y d r o x y e t h y l e n e - 2 - c a p r y l im i d - Mona
a z o l i fie ( 5 0 % a c t iv e )
Monat r o p e 1 2 5 0 Mona
N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e PQ
N i n o l 30-LL A1 k y l o l a m i d e Stepan
PQ Epsom S a l t PQ
P r o p e t a l 99 A1 k y l p o l y a l k y l e n e g l y c o l e t h e r Zschi m
224 Advanced Cleaning Product Formulations
P r o p e t a l 281 A1 k y l p o l y a l k y l e n e g l y c o l e t h e r Eschirn
RU L i q u i d Sodium S i l i c a t e c o r r o s i o n i n h i b i t o r PO
Trademarked Raw Materials 225
SM2135 S i l i c o n e Emulsion GE
Snow F l o s s M i n e r a l f i 1l e r JM
Sodium A l k y l n a p h t h a l e n e S u l f o n a t e DeSoto
Starso L i q u i d sodium s i l i c a t e PO
Stoddard S o l v e n t Exxon
STPP FMC
Super F l o s s Diatomaceous e a r t h JM
S u p r a g i l NK Sodium a l k y l n a p h t h a l e n e s u l f o n a t e Rhone-
TEA L a u r y l S u l f a t e Rhone-
T e r g i t o l NP Nonoxynol UnCarb
Thermphos Hoechs
Thermphos NW Hoechs
T r i l o n A Liquid Zschim
Tween 40 P o l y s o r b a t e 40 ICI
T y l o s e CBR 10000
U b a t o l TR1138
V i scasi a F l u i d ( 1 0 , O O O ) S i 1 icone GE
W i t c o 12986 W itco
Wessalith P Zeolith P
2 . l r Potassium s i l i c a t e (39%) PQ
2 . 4 r Sodium s i l i c a t e (52%) BQ
Section IV
pliers' Addresses
230 Advanced Cleaning Product Formulations
3M
3M Center
S t . P a u l , MN 55144
(612)-733-5454