Infra Red

Infra Red

Atmanto Heru W
Hitungan teoritis
Beberapa gambar vibrasi
 Diagram energy
Diagram energy
A
List panjang gelombang
List panjang
instrumen
1‐propanol
ethyl oxamate
ethylenediamine
phenol
m‐cresol
Stretching Vibrations
Bending Vibrations
Contoh Serapan
 Esters: 1755-1650 C=O
Stretch
(1300-1000) (C-O
Stretch
)
Eth
Ethers: (1300 1000) (C-O
(1300-1000) (C O
Functional Group Absorption Type of Stretch
Names Ranges(cm-1) Vibration )
& [Look for a single causing IR Amines—Primary: 3500-3100 N-H
Example absorption absorption (TWO Stretch
compounds in these regions, PEAKS!)
unless stated 1640-1560 N-H
otherwise.] Bend
Alkanes: 3000-2800 H-C-H Amines—Secondary: 3500-3100 N-H
(Note: The Asymmetric & (ONE Stretch
absorptions
b i can be
b S
Symmetric
i PEAK!)
seen as several Stretch 1550-1450 N-H
distinct peaks in Bend
this region.) Nitriles: 2300-
1500-1440 H-C-H Bend 2200
Alk
Alkenes: 3100 3000
3100-3000 C CH
C=C-H Nitro Groups: 1600-1500 N=O
Asymmetric (Note: Both peaks are Stretch
Stretch <200 cm-1 apart.)
1675-1600 C-C=C
Symmetric 1400-1300 N=O
Stretch Bend
Alkynes: 3300-3200 Amides: 3500-3100 N-H
Stretch
2200-2100 (simila
Aromatic Rings: 3100-3000 C=C-H r to
Asymmetric amines
Stretch )
1600-1580 C-C=C 1670-1600 C=O
Symmetric Stretch
Stretch 1640-1550 N-H
1500-1450 C-C=C Bend