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0-mL of 3.0 M KOH(aq) is transferred to a 250.0-mL volumetric flask and diluted to the mark. It was found that 38.5-mL of this diluted solution was needed to reach the stoichiometric point (also called equivalence point) in a titration of 10.0-mL of a Phosphoric acid solution. Note that Phosphoric acid has 3 acidic protons and therefore is a triprotic acid. (a) Calculate the molarity of H3PO4 in the solution. (b) What mass of H3PO4 is in the initial sample? (Atkins and Jones F92) 2. A forensic laboratory is analyzing a mixture of the two solids Calcium Chloride Dihydrate (CaCl22H2O) and anhydrous (without any waters of hydration) Potassium Chloride (KCl). The mixture is heated to drive the waters of hydration off the Calcium Chloride dihydrate to form a mix of CaCl2 and KCl anhydrous. A sample of the mixture weighed 2.543 g before heating and 2.312 g after heating. Assuming only water left the mixture, what is the percent by mass of each compound in the original mixture? (Atkins and Jones F92) 3. Thiosulfate ions (S2O32-) can be made to "disproportionate" in acidic solution upon the addition of HCl to give solid sulfur (S) and hydrogen sulfite ion (HSO3-). The following net ionic equation is given for this "disproportionation"reaction:
to contain only carbon, hydrogen, and oxygen. A chemist wanting to determine the molecular formula of gallic acid burned 1.000 g of the compound in an elemental analyzer in the presence of excess O2(g). The only products of the combustion were 1.811 g of CO2(g) and 0.3172 g of H2O(g), which were isolated from the excess oxygen used. (a) Determine the empirical formula of the compound. (b) If the molar mass is found to be 170.12 g/mol, what is the molecular formula of gallic acid? (Atkins and Jones F101) 6. A mixture of 5.00 g of Cr(NO3)2 and 6.00 g of CuSO4 is dissolved in sufficient water to make 250.0 mL of solution, where the cations react. In the reaction, copper metal is formed and each chromium ion loses one electron. (a) Write the net ionic equation. (b) What is the number of electrons transferred in the balanced equation written with the smallest wholenumber coefficients? (c) What are the molar concentrations of the two anions in the final solution? (Atkins and Jones F85) 7. The iron content of ores can be determined by titrating a sample with a solution of potassium permanganate KMnO4. The ore is dissolved in hydrochloric acid, forming iron(II) ions, which react with MnO4-:
10. A 6.42% (by mass) Fe(NO3)3 solution has a density of 1.059 g/mL. Calculate (a) The molar concentration of Fe(NO3)3 in this solution. (b) The molar NO3- concentration of the solution. (c) The mass in grams of Fe(NO3)3 in each liter of this solution (Skoog et al. 77)
11. Exactly 0.1120 g of pure Na2CO3 was dissolved in 100.0 mL of 0.0497 M HClO4. (a) What mass in grams of CO2 was evolved? (b) What was the molarity of the excess reactant? (Skoog et al. 77)
12. Exactly 750.0 mL of a solution that contained 480.4 ppm of Ba(NO3)2 was mixed with 200.0 mL of a solution that was 0.03090 M in Al2(SO4)3. (a) What mass of solid BaSO4 was formed? (b) What was the molarity of the unreacted reagent? (Skoog et al. 78) (HINT to find molarity of Ba(NO3)2: What will the approximate density of such a dilute solution be?)
Sources
Atkins, Peter W., and Loretta Jones. Chemical Principles: The Quest for Insight. 4th ed. New York, NY: Freeman, 2008. Print. Skoog, Douglas A., Donald M. West, F. James Holler, and Stanley R. Crouch. Analytical Chemistry: An Introduction. 7th ed. N.p.: Brooks/Cole Thomson Learning, 1999. Print.