Professional Documents
Culture Documents
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Issue 1/2008
Contents
KBA Editorial 2
Plastics Modern substrates with great potential: PVC, PE, PP, PET 3 The making of plastic webs: Rigid PVC and its properties 5 Versatile polyester 8 In-mould labels based on PP film 10 Printability Simple determination of surface tension on plastic films 12 Raising surface tension with a corona tower 14 Sheet travel Antistatic systems on sheetfed offset presses
16
Inks and coatings Oil-based and UV-cured inks for printing on plastics 18 Finishing of plastic films with UV-cured coating systems in sheetfed offset 21 Applications KBA users hold the key to new fields of business: Examples 23 Lenticular film: Special effects for future-oriented niche markets 27 Glossary Resources and partners Contacts 29 30 31
Editorial
also to those readers with no previous experience in this field. We would be delighted if KBA Process No. 5 is able to provide a valuable tip here and there, whether for your first steps in plastics printing or the further expansion of existing activities; and when all's said and done, that is actually the whole idea behind this series of publications from KBA. Hoping that we can in this way contribute to your business success, we will continue to do all we can to pinpoint attractive business ideas and to open up new avenues for you, our customer. Because in the end, we all benefit together from the strengthening of print in its countless facets.
Yours,
2 Process 5 | 2008
Plastics | Substrates
Slipcase printed with a floral design in sheetfed offset on PriPlak, a corona-treated polypropylene film produced by ArjoWiggins and distributed by Papier Union
It is by no means the case that polymers are always modern synthetic products. In fact we have already been using naturally occurring biopolymers, such as asphalt or tree resins, for many thousands of years. When we speak of plastics, however, we usually mean the range of synthetic polymers encountered in practically every sphere of daily life, e.g. PVC, polypropylene, polyethylene or polyester (see box).
tion, further industrial developments have in the meantime led to an elementary shift in interests. Even more specific demands are being raised regarding the packaging, protection, transport and presentation of goods. Consequently, the demands to be met by the print substrate have also gained in complexity: Labels are to be tear- and waterproof, but nevertheless simple to print or write on. Reference works are to be more durable and must not tear even when subjected to heavy use. Transparent packaging is viewed as necessary to enhance the presentation of goods. Presentation possibilities at the point of sale are to be improved. In such a situation, conventional papers and boards soon reach the limits of their performance capabilities but the chemicals industry is on hand to save the day.
Process 5 | 2008 3
Plastics | Substrates
printing. In conjunction with special inks and the corresponding technology, this so-called corona treatment today permits relatively trouble-free printing of this once difficult material. At the same time, other synthetic print substrates such as polystyrene, rigid PVC and self-adhesive foils were developed further and are in the meantime in daily use in many print companies.
PowerJet Texpo banner of polyester fabric Trevira CS B1, printed in a digital inkjet process
Prospects
In future, too, there will still be countless fields of application for classic board materials, especially where it can be further refined by way of coating, embossing and lamination, etc. But the use of plastics for the
most varied products will continue to increase. Wholesalers such as Papier Union have already reacted to this trend by establishing independent sales departments with specifically trained specialists for the new synthetic materials. It remains to be seen whether the users of synthetic substrates will in future have to or choose to rely further on the tried and trusted materials of the past. Heated discussions are almost certain. Most likely, however, is that new developments will emerge, with plastics on the basis of renewable raw materials rather than the limited resource mineral oil. This development will require new printing inks, presses and techniques. And it will trigger new desires. Service providers hoping to gain a share of this interesting market are advised not to wait too long before jumping on the bandwagon because it is already moving faster and faster. Klaus Fischer (Papier Union GmbH), Cornelia Lillelund
Food-safe Lucprint PVC films are used, among other things, for exclusive packaging
4 Process 5 | 2008
The production of film materials is an established field of polymer processing, as such films can be used in an endless diversity of applications. Whether as semi-finished or end products, their broad range of modification possibilities helps meet the prerequisites of the most varied branches of industry. Several differing process technologies have been developed for the production of plastic webs, and together permit suitable films to be made available economically for a comprehensive spectrum of uses. These technologies are extrusion with slot-die or blow
900 000 t
9.3 4.7 2.8 2.8
8.4 3.7
8.4 3.7
8.4
8.4 4.7
10
11
12
13
The West European market for rigid PVC films accounts for a consumption of 900,000 tonnes. Of this, 60% is used for packaging (1 Foods, 2 Non-foods, 3 PVC composites, 4 Box lids, 5 Pharmaceuticals, 6 Oriented films, 7 Others) and 40% in technical applications (8 Adhesive tapes, 9 Office films, 10 Furniture and frames, 11 Offset/screen/digital printing, 12 Construction, 13 Others).
dered. A calender is thus to be treated as a processing machine purely for forming purposes. The first calender-like machines were already designed before 1800 for the smoothing of textile surfaces. In 1836, the first patents were granted for calender machines for rubberising and for the application of rubber to textiles. Demands for higher production speeds and closer tolerances promoted further development of the calender and expansion of its range of applications to include the processing of polyvinyl chloride (plasticised and unplasticised PVC) in addition to rubber. The first calender for unplasticised PVC, introduced in 1937, was designed to be heated to 220C. Once highly active stabilisers became available from around 1960, it was possible to supplement the previously used low-temperature process (LT) with a high-temperature process (HT) based on modified recipes and higher temperatures within the calender. The technical configurations and implementations have remained practically unchanged over the past decades. The only real variation has been to widen the calender rolls to increase output or to facilitate avenues of specialisation in film production. The established technology for the production of unplasticised PVC films is based on the HT process and four- or five-roll calenders in widths between 1,800 and
Unplasticised PVC
In terms of production capacity and consumption, PVC occupies third place in the list of most commonly used standard polymers with 28.6 million tonnes per year, after polyethylene (57 million tonnes) and polypropylene (35 million tonnes). The constantly increasing consumption over the past 60 years or so, from initially around 10,000 tonnes to now almost 30 million tonnes per year, is indicative of the continued industrial significance of PVC. Thanks to its compatibility with a whole range of auxiliaries and media, PVC has built up and maintained a very broad range of applications, from window frames and films to pastes and coatings. In Germany and the rest of Europe, the processing volume of unplasticised PVC is around double that of plasticised PVC. Unplasticised PVC films account for an approx. 15% share of the total consumption of PVC. Packaging films make up some 60% of the total film production. Further important applications are technical films and films for printing. 20% of the unplasticised PVC is calendered, with the most important market segments being packaging and technical applications. Vinyl chloride was first produced by Henri Victor Regnault in 1835. The first industrial-scale production began at IG Farben in Germany in 1938, and at almost the same time at Union Carbide
Process 5 | 2008 5
and DuPont in the USA. Nowadays, it is produced by way of a single- or two-stage reaction involving chlorine and ethylene. PVC, with a chlorine content of 57%, requires less mineral oil than any other polymer and is produced industrially by one of three methods: Emulsion polymerisation (EPVC) for pastes and film applications; Suspension polymerisation (SPVC) the main process, for all applications; Mass polymerisation (M-PVC) primarily for rigid PVC applications. The choice of a particular PVC type is governed by the demands of further processing and the purchasing price. S-PVC and MPVC are ver y versatile and mutually exchangeable. M-PVC, due to its purity, is preferred for transparent products.
2 Comparison of material properties of four different polymers: GB = Gas barrier, WB = Water vapour barrier, Mi = Migration, Mo = Modification, Tr = Transparency, EM = Elastic modulus, HR = Heat resistance, SpW = Specific weight
3 Comparison of processing properties of four different polymers: Pr = Printability, Th = Thermoforming, Fo = Folding, Se = Sealing, AS = Antistatic properties, En = Process energy, Gl = Gluing, Sc = Scratch resistance
elevations influences the optical quality of the film. Flow lines are caused by inhomogeneities in the kneaded polymer melts fed to the rolls, the reasons for which, in turn, may lie in throughput fluctuations or temperature differences. The current limit values for thickness fluctuation for different applications lie between 3 and 10% for rigid PVC films (see table). Own research has demonstrated that thickness deviations are rarely recipe-dependent.
Film properties
PVC can be distinguished not only by its production process, but also by its material and processing properties (Figs. 2 and 3). The standard international designations are PVC-U (for unplasticised or rigid PVC) and PVC-P (for plasticised PVC). Rigid PVC, as the variant suitable for printable films,
Processing improvement
Thermo-stabilisers Internally and externally effective slip agents Calendering aids
Film recipe
PVC S, M, E
Application improvement
UV stabilisers Impact strength enhancers Pigments Static eliminators Anti-blocking, dulling, flameproofing agents High-temperature modifiers SAN and ABS
Film shrinkage
Shrinkage refers to the changes in length and width of a film when exposed to heat. Shrinkage can be influenced by the temperature and speed control after the calender, additives influencing the glass transition temperature, additives influencing stretching, design measures to reduce relaxation. The cause for this shrinkage lies in the expansion of the film above the so-called glass transition temperature, which marks the relatively narrow transition range between hardness and elasticity.
6 Process 5 | 2008
100 % 75 50 25 0
160 C 120 80 40 0
1 2 3 4 5 6
7 8
1 2 3 4 5 6
7 8
5 Transparency (%) of different plastic films, relative to PMMA (100%): 1 PP random copolymer, 2 High-impact modified PVC, 3 PETG, 4 Rigid PVC, 5 PC, 6 PS (Styrolux), 7 High-impact modified PMMA, 8 PMMA
6 Temperature stability of different polymers on the basis of their Vicat softening temperature (C): 1 PP, 2 APET, 3 PETG, 4 High-impact modified PVC, 5 Rigid PVC, 6 PS, 7 PMMA, 8 PC
Oxygen and water vapour barrier properties of different plastics, relative to rigid PVC = 1
The expansion leads to orientation of the molecule chains, which are then frozen in their new state upon subsequent cooling. Later reheating to a temperature above the glass transition temperature releases the frozen stresses and the molecules return to their original configuration. The arising restoration forces reverse the original deformation and produce the shrinkage.
Transparency
One important optical property of a film is its transparency (Fig. 5), i.e. the extent to which contours behind the film, e.g. packaged goods or lettering, remain visible and accurately recognisable. The transparency is influenced by the recipe, the surfaces of the last calender roll and the first delivery roll, and the temperature control at these two rolls. Film defects affecting transparency include, among others, the abovedescribed flow lines, whose thickness fluctuations lead to optical distortions.
flatness defects, with the result that sheets refuse to lie flat and reels deviate from their true running direction when unwound. Such temperature differences may also be the cause of expansion over the film width, in exactly the same way as various expansion problems arising from out-ofparallel roll settings or truerunning errors. Such defects are noticeable above all at the edges of the film web, and in extreme cases may mean that these edges are no longer suitable for further processing. Excessive dwell times due to unfavourable flow processes in the plasticiser or the first roll gap also lead to variations in the thermal loads acting on the film and consequently to varying thermal degradation. The resultant inhomogeneities in the molecular structure are manifested as strength fluctuations when the film is stretched or flexed. This may lead, for example, to tears or holes in the film during crosswise stretching.
8 Permeation coefficients of polymers for oxygen permeation [cm3 m m2 d1 bar 1] and water vapour permeation [g m m2 d1]
acrylate. Their effect is greater, the higher the K value of the PVC concerned. Optimum setting of the plasticising and calendering processes in respect of homogeneity and temperature control is similarly significant for attainment of a particular impact strength. The rigidity of a film is dependent on its modulus of elasticity and its thickness. For example, a PP film would have to be 1.3 times the thickness of a PVC film to obtain the same flexural rigidity.
various polymers. Polycarbonates are excellently suited where such demand profiles apply.
Barrier properties
The higher the barrier effect of a film (Fig. 7), the lower its permeability for certain media. The barrier properties are quantified by the extent of permeation (Fig. 8) of a volume or amount of gas (gas permeation) or vapour (e.g. water vapour permeation) through one square metre of a film of a specified thickness at a defined gas or vapour pressure difference over the period of one day. Frank Wamann (Klckner Pentaplast GmbH, Montabaur)
Process 5 | 2008 7
Plastics | Versatility
The term ester derives from the German Essig-ther (literally: vinegar ether), which is an old name for ethyl acetate. Polyesters are thermoplastic polymers with the ester functional group [COO] in their main chain. Thermoplastic means that these polymers can be formed at higher temperatures and then maintain their new form after cooling. Polyesters are produced by various polycondensation processes, depending on their chemical composition.
as Trevira or fleece, or equally for tennis racquet strings. Colourlesstransparent amorphous PET (APET) is processed into films in thicknesses from 1 m up to that of cinematic film stock; PET is no longer interesting as a material for magnetic tapes. APET can also be used to form injection- or stretchblown bottles, e.g. disposable bottles for soft drinks, but is in this field gradually being replaced by polyethylene naphthalate (PEN). The high tensile strength, athermanous properties, and gas and water impermeability of even thin films serve to identify APET as an ideal barrier in composite films for aroma-sealed food packaging, which can then be printed quite easily in a flexo process. Biaxially oriented APET films (boPET, DuPont Mylar) are even used as insulation for space suits.
A selection of polycarbonate CDs and DVDs, printed in six-colour waterless UV offset on a KBA-Metronic CD-Print
APET film sheets, in some cases with different levels of glossiness for the top and reverse surfaces, are well suited for laser and digital inkjet printing, e.g. for projection foils and pointof-sale advertising. They are also in increasing use in UV offset (wet and waterless). APET, or better still glycol-modified PET (PETG), is furthermore the basis for lenticular substrates. In this case, the top side is formed with the narrow lens stripes, while the reverse accommodates high-precision printing Mini-movie on PET lenticular film, printed in waterless in sheetfed offset with sheetfed offset on a 74 Karat press from KBA waterless, UV or waterless UV inks. The ability to print on both smooth PET and lenticular Metronic Genius 52UV presses films has enabled users of the to capture considerable market KBA Rapida 74 UV and 105 UV, shares. For the booming producRapida 74 G, 74 Karat and KBA- tion of bank and customer loyalty cards a domain of the KBASoft drinks bottles and their labels are today Metronic presses APET is used often made from PET or PEN for the lamination.
8 Process 5 | 2008
Plastics | Versatility
AttoP-Check is a prefabricated PET tag which is applied to transparent packaging films. The nano-ink reacts with distinct discoloration as soon as the underlying package contents become even slightly discoloured. Paper supplier Mondi produces and uses such tags calibrated for the correct paper moisture level to monitor larger batches. (photos: Attophotonics.com)
The fastest decoration method for these discs is waterless UV offset, which at the same time achieves a photo-realistic image quality. With its keyless machines CD-Print (6,000 six-colour discs per hour) and Premius (7,200 four-colour discs per hour), KBA-Metronic offers two optimum solutions for this market. It is true that photorealistic results could also be achieved by thermal retransfer printing, but this process is too slow. The screen and inkjet processes, on the other hand, lag behind waterless UV offset in terms of both speed and quality. Polycarbonate is well known in prepress departments from the transparent and coloured housings of Apple computers. On account of its perfect transparency, PC has replaced the polymer polymethyl methacrylate (PMMA, Plexiglas) in many applications.
An HDTV flat-panel display from Samsung, using not liquid crystal polymers but instead active-matrix OLEDs on PET carriers a future prospect for sheetfed offset? (photo: Aving.net)
Another field of application for PETG is shrink labels. Oriented PETG permits the full enveloping of containers of any given form, e.g. wine bottle necks or preserve jars, with film labels printed on the reverse in flexo (full body sleeves, wrap-around labels, shrink sleeves). Like PVC and polypropylene, APET or an APET composite with polyethylene can also be used for deep-drawn packaging components. The coextrusion sequence PETGAPETPETG produces GAG-PET, which forms the blister cavities for press-out packaging, e.g. for tablets or for appropriately small products. The lidding then comprises a 4/1printed Chromolux card finished with a heat-sealing blister coating on the front. The coextrusion of APET with a PET modified with isophthalic acid (PETIP) achieves sealable films which are then usually bonded into metallised composites, e.g. for aroma-safe coffee packaging.
Polycarbonate (PC)
PC is the most expensive polyester. It is produced from toxic carbonyl chloride (phosgene) and a glycol. All CDs, DVDs and Blu-ray discs are made from PC, because this polyester is highly transparent and also permits error-free writing of the data layer through the polymer.
areas of the printing plate suddenly become the image areas, whereafter the PEDOT:PSS is transferred fully to the substrate via a special blanket. The general goal of printed electronics is a drastic cost reduction compared to silicon wafers and liquid crystal polymers. To date, for example, it has been above all the costs for production and application which have prevented the wide-scale introduction of RFID tags (Radio Frequency IDentification). It is still the case that only the trivial RFID components electrodes and bipolar antenna are printed. More complicated electronic components, such as transistors, diodes, capacitors, oscillators, integrated circuits, power sources and light-emitting (OLED: Organic Light-Emitting Diodes, e.g. for logos, lettering or displays) or light-absorbing structures (OPV: Organic PhotoVoltaics, i.e. photocells) need to be built up in several layers when printed. Dieter Kleeberg
It is not yet possible to print all components of an RFID transponder (photo: Infineon)
Process 5 | 2008 9
Plastics | Substrates
Most injection-moulded packaging for ice cream and salads is decorated with the IML film Treofan Decor EUH. The five-layer film with a density of a mere 0.55 g/cm3 is corona-treated on both sides and displays very good antistatic properties. Its behaviour in connection with injection moulding varies. The cellular core is embedded in two white OPP intermediate layers.
In-mould labelling is generally understood as a process by which an injection-moulded, blow-moulded or thermoformed product is already provided with its label in its final mould. The special surface properties of the IML film cause it to bond permanently with the product. It is thus normally no longer removable.
Gravure is preferred for high-volume production, e.g. labels for margarine tubs. Medium runs are often entrusted to web offset printers. Die-cutting is performed either inline or offline, depending on the print process.
Film manufacturing
The use of polypropylene films or to be more precise: OPP (oriented, i.e. stretched PP) and CPP (cast PP) films for the decoration of injection-moulded packaging has seen enormous growth over the past 15 years. The substrates used are mostly OPP films, in some cases also for particularly large labels, e.g. for paint buckets. To manufacture a CPP film, a singleor multilayer PP film is extruded through a slit die. The film is then trimmed and usually also pretreated with a corona discharge ready for printing. Finally, the film is wound
Label printing
In-mould labels can be printed in various processes: Sheetfed offset with oxidatively drying or UV-cured inks, Gravure, Narrow web offset with UV inks, Flexo with UV inks, Letterpress with photopolymer plates and oxidatively drying or UVcured inks. The order of the list above corresponds more or less to the popularity of the individual processes. Sheetfed offset is a frequent choice on account of the possibilities to combine various images on a single sheet, as well as the excellent detail reproduction in its photorealistic printed images. Given the favourable price of reel supplies, it is also useful to configure a sheeter unit ahead of the press feeder when planning to work with IML films.
onto a reel and later cut to the width requested by the customer. Typical film thicknesses lie between 80 and 100 m. The manufacturing of an OPP film is much more complex. First of all, in the same way as for a CPP film, a multilayer PP film is extruded. For IML films, it is usual to coextrude three to five layers. The different melt flows are already combined in the die and are deposited together onto the chilling roller. After this socalled pre-film has cooled and set, it is heated once more to a defined
Blow-moulding Thermoforming
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Plastics | Substrates
These injection-moulded containers and lids for ice cream were decorated with the IML film Treofan Decor ETR. The three-layer film with a density of 0.91 g/cm3 is corona-treated on both sides and possesses a transparent OPP core.
the process, the film is wound onto a machine reel and passed on for cutting down to the widths required for printing or sheeting.
removal from the pile. In combination with special additives, the matt layer is also able to reduce the electrostatic charging arising from separation of the two surfaces. The demand for labels which lie as flat as possible, i.e. with only minimal tendency to curl, calls for careful selection of the raw materials for the various layers, as well as precise matching of the individual layer thicknesses. In this connection, it is also necessary to ensure that the print process and ink systems used similarly exclude unwanted curling.
Composition of a five-layer IML film: The top surface (1) is responsible for the glossiness, the antistatic properties and following corona discharge treatment for the bonding of the inks and a possible metallising coating. The two intermediate layers (2, 4), together with the core (3), determine the whiteness, opacity and density, and thus also the strength and flexural rigidity of the film. The bottom layer (5) provides for bonding to the moulded product.
of the label surface (glossy or matt) and the product form. Products with high-gloss labels can only be produced with a heavy OPP film (e.g. EWR, ETR) or a CPP film (CWD, CTD). One undesirable side-effect manifested with OPP films, in particular, is a strong tendency to distortion after injection moulding when applied to thin-walled, non-symmetrical products. This could be avoided by choosing a film with a cellular structure (EUH). The trade-off here, however, is that it is not possible to create high-gloss labels. For the marketing specialists, on the other hand, it is a simple matter to turn the necessity of a matt surface into a virtue and to sell the orange-peel effect as a soft-touch finish. Cast PP films display practically no influence with regard to distortion of an injection-moulded product. Due to their greater thickness and thus greater weight, however, they are more likely to be used for very large items, such as 5 or 25-litre paint buckets, than for food packages. As the pressures involved are lower when forming blow-moulded products, such as HDPE or PP bottles, the materials used are mostly films with a specific sealing coating. This sealing coating is furthermore applied with a certain pattern to promote the escaping of the air between the product and the label. Tests aiming to achieve this same effect with an OPP or CPP film designed for injection moulding have not yet produced reliable solutions. With the film type UND, however, Treofan GmbH is developing an alternative which permits the air to escape through a permeable film. At the same time, this film requires no coating. Thermoformed products are subject to similar problems to those faced
when blow-moulding. In the past, it proved very difficult to displace the air from between the moulded product and the label surface. Earlier tests sought a solution by perforating the labels. This approach, however, demanded an additional process step, and also brought the disadvantage that the perforation remained visible later. Since 2006, new progress has been made in this field. Through optimisation of the deep-drawing process, use of a foil with a cellular structure and modification of the sealing, it has become possible to produce bubble-free IML labels. The label surface, on the other hand, is once more a matt orange-peel finish. If a breathable film such as Treofan UND is used, however, it is also feasible to produce a gloss label in conjunction with suitable coatings. Wilfrid Tews (Treofan GmbH, Neunkirchen and Raunheim)
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Surface tension characterises the behaviour of an interface between a liquid (e.g. water) or solid (e.g. film) and a gas (e.g. air), and is thus also referred to as interfacial tension. This phenomenon is manifested, for example, in the way a liquid naturally seeks to minimise its surface area. Consequently, a droplet of liquid which is not subject to external forces in free fall, for instance will always assume a near-spherical shape.
Molecular interactions
Neighbouring molecules are subject to attractive and repulsive forces, so-called cohesive forces. In the bulk of a liquid, these forces are able to interact equally in all directions. This is not true for the molecules at the surface, however, as they possess fewer neighbours than the interior molecules. Within the liquid, the motions of the individual molecules exist in state of energy equilibrium, whereas motion at the surface requires energy to be expended to break molecular bonds. If the surface of a liquid is to be increased, therefore, a certain
quantity of work must be done. The work required to enlarge the surface is dependent on the surface tension of the liquid. The ratio between the work done and the resultant surface enlargement is the surface tension (represented by the symbol sigma) = W / A which is usually expressed in the unit mN/m (millinewtons per metre), corresponding to the SI units 0.001 kg m/s2 or mJ/m2 (millijoules per square metre). Water at 20C displays a surface tension of 72.8 mN/m, compared to 484 mN/m for mercury or 21.7 mN/m for isopropanol. Surface tension is temperaturedependent and generally decreases as the temperature rises. Surfactant substances, such as the tensides in dampening solution additives, reduce the surface tension of the liquid to improve the wetting of an offset printing plate.
work done to achieve this. Examples are the ring method developed by Pierre Lecomte du Noy, the Wilhelmy plate method and the frame method after Philipp Lenard. In all three methods, a solid body (ring, plate or frame) is immersed in the liquid, and then drawn back out such that a film of liquid
The surface tension of solids can similarly only be measured indirectly. When using the contact angle method, a solid is wetted with two different liquids with a known surface tension. The chosen liquids are frequently water and diiodomethane. In Youngs equation, to be seen alongside, the indices S and L stand for Solid and Liquid; the symbols S and L describe the surface tension components of the two phases; YSL represents the interfacial tension between the two phases, and stands for the contact angle, cor-
12 Process 5 | 2008
One commercially available camera contact angle measuring device is the pocket goniometer PG-2 from Swedish manufacturer Fibro Systems Test inks in use: On the left, the ink has spread, i.e. this full wetting shows that the surface tension of the film is at least as high as the known surface tension of the test ink. On the right, there is no wetting, i.e. the surface tension of the film is lower than the known surface tension of the test ink
responding to the angle between the vectors L and YSL. To determine the surface energy, various initial equations for YSL are combined with Youngs equation, with cos representing a function of the phase surface tensions. With this system of equations, it is possible to calculate the surface tension of the solid. The market offers a range of instruments for the fast and simple determination of contact angles. Such goniometers comprise a system to inject a test liquid and a camera to measure the bead cross-section. This measurement is then used to calculate the corresponding contact angle values. A contact angle of 0 results if the liquid spreads, i.e. if the solid is completely wetted. A contact angle between 0 and 90 is considered to represent good wetting, while a contact angle between 90 and 180 is treated
as poor wetting. A contact angle of 180 means that the liquid is repelled in the form of spherical beads. This phenomenon is commonly referred to as the lotus effect, after the corresponding properties exhibited by leaves of the lotus plant. Another typical method to determine the surface tension of solids is to use test inks. An ink with a known surface tension is applied to the material to be tested with a brush. If the test ink wets the surface, then the surface tension of the material is equal to or higher than that of the ink. On the other hand, if the test ink retracts into a bead within 3 seconds, then the surface tension of the solid is lower than that of the test ink.
With a set of test inks, the surface tension of a film substrate can be determined iteratively
surface tension is lower than that of the solid in question. This is also why it is problematical to print on substrates with a low surface tension. To guarantee sufficient wetting of the substrate by
the printing inks, it is necessary to ensure that its surface tension is higher than that of the inks, either through appropriate selection or pretreatment, etc. A set of test inks is thus a very convenient means to check the properties of a particular plastic substrate. Beatrix Genest (SID Schsisches Institut fr die Druckindustrie GmbH, Leipzig)
Source: Fraunhofer IGB Surface tension 22.5 mN/m 36.1 mN/m 38 44 mN/m 38.4 mN/m 43.5 mN/m 47.0 mN/m 49.0 mN/m 46.7 mN/m
Process 5 | 2008 13
The keyless and waterless KBA Rapida 74 G in the customer demonstration centre at KBA in Radebeul incorporates a corona tower ahead of the first printing unit (right-hand arrow) and direct ozone extraction (left-hand arrow). In this particular configuration, it is already able to print selected film types. The Rapida 74 G can also be supplied with UV equipment, in which case it is able to process all types of plastic substrate.
radicals are channelled from a quartz electrode to a ceramiccoated back roller or in the case of the KBA Rapida to the chromeplated impression cylinder. In the process, they are accelerated along the field lines and penetrate up to 0.1 nanometres into the film surface, hurling hydrogen atoms out of the polymer chains as they do so. Atoms are also released in similar fashion from the surface of a metallised substrate. Within just a few milliseconds, gaps are left in the surface cross-linking structure; this effect is also referred to as roughening. The cylinder here functions as the counter-electrode, i.e. it dissipates the charge, and at the same time provides for the correct clearance between film and corona electrode.
View into the corona tower of a KBA Rapida 74: The blue shine around the activated quartz electrode can be seen behind the white sheet guide rollers. The chrome-plated back cylinder in the foreground is effectively a double-size impression cylinder.
14 Process 5 | 2008
unit. In such a corona tower, it is necessary to increase the clearance between electrode and film sheet to approx. 5 mm and with it also the discharge power. Depending on the format width, and thus the available space in the corona tower, up to three 15 kV electrodes are installed, each with a power rating of 3 kW or more. At full discharge power, the surface tension is raised to the desired degree even at maximum production speed. One important factor contributing to uniform surface roughening is the full-area contact between the film sheet and the back cylinder, which thus takes the form and dimensions of an impression cylinder. There is no need to adjust the electrode length for different film widths. The ozone arising in the dielectric is extracted directly.
In the tower frame designed by KBA, the Ahlbrandt corona unit is mounted with optimum clearance to the back cylinder (top photo). All three electrodes of this corona unit possess individual hoses for ozone extraction (bottom photo)
Alternative methods
Factory-treated substrates have not always been processed in a corona discharge system. But there are no cost advantages to be derived from alternative treatment methods. Film manufacturer Klckner Pentaplast, for example, has developed the so-called Dynox process, which is used at least for rigid PVC
films. This treatment raises the surface tension to over 45 mN/m. In contrast to corona treatment, the surface effect lasts for more than a year, and is also not destroyed on the feeder. Another method is plasma treatment. The desired effect is here achieved by bombarding the surface with ions. And once again, the effect remains stable for longer than with corona discharge.
A third alternative is for the film manufacturer to finish the material with a special primer, a so-called top coat which preserves the corona effect. The Ciba Prime IT technology is a similar method.
less expensive untreated materials. And if they do so, they can at the same time be sure that the printability of the chosen sheets is absolutely reproducible. Dieter Kleeberg Matthias Lange (KBA Radebeul)
Summary
Printers working with plastic substrates on a regular basis can easily calculate whether it makes sense to purchase an inline corona unit and to use
Process 5 | 2008 15
Principle of electrostatic charging through electron transfer Principle of electrostatic charging (voltage U > 0) at sheet separation
tive of whether positive or negative repel each other, whereas differently charged objects are attracted to each other.
feeder. The two central components are DK 106 antistatic heads, which are mounted on the KBA separating air nozzles (1.1) and thus use the air of the separation burst for static elimination. Alongside, four DD 406 antistatic nozzles are used to blow a variable volume of antistatic air into the top of the pile as loosening air (1.2 and 1.3). Two further static eliminators are mounted at the pile side edges. Here, too, the antistatic heads are fitted to the KBA air nozzles. On the feed table, a DE 206 electrode (4) is used to treat the top surface of the sheet, a DR 106-8 electrode array (5) takes care of the underside, and a DR 206-6 array (7) helps to lift the first sheet.
16 Process 5 | 2008
The KERSTEN antistatic systems (depicted in yellow) on the feeder of the KBA Rapida 106 in the test print centre: Two DK 106 antistatic heads (photo top left, component 1.1, on the separating air nozzles), one of four DD 406 antistatic nozzles (top right, components 1.2 and 1.3, as loosening blowers), and for the feed table a DE 206 antistatic electrode (bottom left, component 4, for the top sheet surface) and a DR 206-6 array (top centre, component 7, to lift the first sheet). As can be recognised from the schematic drawing, the DR 106-8 array (component 5, for the underside of the sheet) is not visible.
Function principle
As already explained above, electrostatic charging is the expression of an imbalance in the charges at atomic or molecular level. To elimi-
nate the disturbing effect, this imbalance must be neutralised, i.e. the positive charges must be compensated with an appropriate number of negative inputs, and vice versa. The result is then once more a neutral charge distribution. Antistatic systems draw the necessary compensating charges from the
molecules of the surrounding air. To this end, a voltage of at least 2,500 V is applied to needle-point electrodes, producing charged particles (ions) in the immediate vicinity of the needle points. These ions can carry either a positive or negative charge, depending on the polarity of the applied voltage.
50.13
9.1
8.1 8.2
The KERSTEN DE 206 antistatic electrodes in the delivery of the KBA Rapida 106 in the test print centre: Static elimination for the underside at the sheet decurler (component 8.2) and after the sheet brake (component 8.1), and for the top surface of the sheet at the powder sprayer (component 9.1) and above the pile (components 50.1 to 50.3).
An antistatic system for a printing press provides for a constant adequate supply of both negative and positive ions. With the neXt systems from KERSTEN, this is ensured by using a stabilised bipolar DC voltage. Both polarities are present at the electrodes at the same time. Consequently, a maximum availability of both positive and negative charge carriers can be maintained constantly. This technology also produces significantly more ions than the previously used AC systems. An electrical field provides for homogeneous distribution of the ions over a wide surrounding area. The relevant law of physics states that opposite charges are always attracted to each other. The charged sheet thus soaks up precisely those ions which are required to neutralise its surface. If sufficient ions are made available, the electrostatic charging of the sheet will be eliminated completely. Any excess ions are taken back by the antistatic system itself.
Process 5 | 2008 17
The most important and above all tangible effects for the user at a glance: Improved sheet separation at the feeder; Fewer double sheets and press stoppages; Reduced non-productive times; More exact alignment at the front lays; Enhanced productivity through higher production speeds;
Handling of substrates for which static elimination is imperative (plastic films); Neutral delivery piles with tidy pile edges; Better and faster further processing of the printed sheets; Fast return of investment; Greater operator satisfaction.
Function principle of the KERSTEN antistatic systems: An electrical field provides for homogeneous distribution of the ions and full charge compensation (electrical charge Q = 0).
The challenge to find a suitable offset ink system for these applications include good printability, improved running characteristics on increasingly faster presses,
1 The torque (y axis) of a rotation viscosimeter mapped against the water content (x axis) of the ink permits conclusions on how the ink-water balance influences the printability of inks. The more water an ink can absorb, the greater the margin for problem-free printing of films and foils. Here a higher torque denotes a lower influence of the dampening ratio. Older types of UV inks (1 and 2) did not absorb enough water. Latest-generation UV inks (3) exhibit an equally suitable behaviour as oil-based inks (4)
18 Process 5 | 2008
*) Higher fount solution acidity slows drying down; **) Up to 12% recommended for printing with smallest possible amount of fount solution; ***) To prevent blocking and set-off; ****) Do not over-ink, coating if scratch resistance is too low
solution exhibit a much greater margin between over and underdamping. For some years now, alcohol-free printing has been on the increase. Especially in film and foil printing, however, the use of isopropanol has proved to be the better choice, with reduced surface tension of the fount solution for optimal printing and a good ink-water balance. Instead of IPA, alcohol substitutes might be used depending on press configuration, plates etc.
especially of the UV coating, the more volume is there to shrink. One result is reduced adhesion. Especially in the crosscut test, the adhesive force of the adhesive tape can exceed the bonding force between the ink/coating and the printing substrate, causing the inkcoating layer to lift off from the substrate. Adhesion quality also depends strongly on the use of highly flexible ink/coating/binding vehicle systems that reduce shrinking.
Adhesion of UV inks
In the past, UV inks showed restricted adhesion on foils and films, but these issues have been overcome by newly developed special ingredients and optimized ink formulas. An essential condition is, however, that the substrate such as PVC does not contain any plasticizers, static inhibitors and other substances that might diminish adhesion. The recommended surface tension for PVC is 35 mN/m. For substrates made of ABS, PP, PET, PE and PS, a surface tension of over 40 mN/m is essential. These substrates should also be free of problematic additives like static inhibitors, which might impede uniform ink adhesion due to their separating effects. The correct surface tension in a synthetic substrate lies in the material formulation and thus with the manufacturer of the substrate. Manufacturers also sometimes use so-called corona discharge technology to electrically treat the surface of films. The surface tension might fall during longer storage of the substrate, and the corona pretreatment must be repeated directly in the web or sheet-fed press. This option is also advisable if non pre-treated substrates are used for economical reasons. Moreover, the molecular structure of the cured ink layer widely influences adhesive characteristics, flexibility and scratch resistance.
Curing of UV inks
Differing curing characteristics can also influence the adhesion of the ink/coating layer. If the ink does not cure completely, adhesion might be diminished by insufficient cross-linking of the ink/ coating layer. In rare cases, an over-cured ink/coating layer might shrink strongly and become brittle, which results in lower flexibility and adhesion.
secure adhesion and scratch resistance on non-absorbent substrates. In contrast to most paper and carton substrates, the surface structure of typical plastic film does not allow the ink to set. Drying and adhesion support by filtration into the substrate is not possible. Additionally, the presence of fount solution in oil-based ink offset generally impairs the drying process. Therefore, a good ink-water balance is a key factor in influencing the drying process. Special oil-based inks have been developed for synthetic substrates to accommodate special technical requirements concerning the quality of the printed product. However, a good compromise between fast drying, safe piling, adhesion and abrasion resistance remains a difficult thing to achieve with oil-based inks (see Table 1).
Here the advantages of UV curing technology should be used, including immediate hardening of the ink layer, low influence of the amount of fount solution, and fast readiness for further processing.
Versatility of UV inks
In the early days of UV technology, it was rarely possible to use inks specially formulated for film and foil printing also for printing on paper and carton due to the high tackiness of the oligomers, which ensure adhesion. Today, optimized qualities allow the use of UV film printing inks on paper-based substrates in many cases.
Printability of UV inks
In non-absorbent substrates such as plastic film, the fount solution cannot filter into the surface. The first generation of UV inks tended to build up on rollers, plates and/or blankets due to excessive fount solution absorption and the resulting loss of tack. Here, an 2 Ink-water balance profile in the production run. The wet optimized ink-water tack of the ink changes over time because of alternating balance improved downtimes (make-ready, pile change, intermediate washing) and optimum production speed. Recent UV inks (green) printability. New ink retain the set ink-water balance while former-generation UV generations with inks get increasingly out of control optimized absorption and release of fount
Process 5 | 2008 19
3 Characteristics of the UV offset ink series developed by Siegwerk for printing on plastics: Pr = printability, Mi = low migration, Ad = adhesion, Ve = versatility, Od = low odour
initiator systems, the use of ultrapure monomers and oligomers of high molecular weights and adapted formulations result in very low migration and thus help to meet new demands. With all the high purity of materials and sophisticated manufacturing technology, users still should check and coordinate the qualities recommended by the ink supplier with the technical environment in the printing shop (press, UV system, printing speed, etc.) according to the legal regulations. Apart from ink and coating, organoleptic and
inherent odour after UV radiation. Careful handling and storage of the printed run is another important factor. For questions or special jobs, especially in the sensitive area of food packaging, it is always advisable to contact the local representative of the ink and coating manufacturer in order to receive the best possible technical support and advice.
Resume
Printing on increasingly demanding substrates with impenetrable surfaces from plastic films to metalized substrates or even sheet metal requires ink manufacturers to constantly develop their products. Increasing press speeds and the resulting shorter drying times present a particular challenge. Due to their absence of shrinking, oil-based systems continue to be used for special applications. However, UV technology will continue to occupy an ever increasing place in the graphic industr y, with constantly improving ink formulations and manufacture (in particular with regard to organoleptic qualities), tonal value control in pre-press and physical properties of radiation equipment. Peter Psotta and Walter J. Bolliger (Siegwerk Backnang GmbH), Marc Larvor and Olivier Deage (Siegwerk France S.A.)
4 For the testing of printing inks, a liquid chromatograph/mass spectrometer (LC/MS) system may be used to measure impurities, which might migrate in very small amounts
with special materials that minimize the organoleptic effects, e.g. the excitation of sensitive receptors such as olfactory and gustatory nerves in the mucous membranes, and reduce molecular migration. Optimized photo
migration data can be influenced by many other parameters beyond the influence of the ink manufacturer. This applies in particular to suitable cleaners and dampening additives. Printing substrates also might develop an
*) Not fit to purpose but can be used; **) Recommended; ***) Highly recommended; X) No possible use
20 Process 5 | 2008
Printability | UV coating
Chemical curing by way of UV radiation is one of the most innovative technologies used in the print industry for the drying of inks and coatings. With the aid of the UV technology, it is also possible to print on a diversity of nonabsorbent substrates. The first applications in the early 1970s already exploited the same process benefits as remain valid today (Table 1). In the narrow-web sector,
UV curing has in the meantime secured a share of over 90%. UV systems are also gaining in popularity among packaging printers, where sheetfed offset is increasingly the process of choice for printing and coating. Intensive research and development concerning both raw materials on the one hand, and the inks and coatings on the other, has promoted ever more widespread use of the technol-
ogy in many areas of the modern print industry also for the printing of plastic films. When compared to paper and board applications, however, there are various special points to be taken into account when applying coatings to plastic films (Table 2).
Process 5 | 2008 21
Printability | UV coating
Excessive shrinking within the coating prevents proper bonding to the substrate
The bonding is good, but the coating contracts due to polymerisation shrinking and causes the plastic film to curl
A matched coating with the correct polarity and reduced polymerisation shrinking provides for optimum bonding without curling
ally necessary, but may still prove useful if adhesion problems are encountered. KBA offers corona modules for inline pre-treatment ahead of the first printing unit.
sheets, this leads to problems with separation at the press feeder and during downstream further processing. Besides installation of antistatic systems on the presses and finishing machines (see the article on antistatic systems by Kersten), correct storage is also able to reduce charging. To permit proper acclimatisation, the films should be kept at temperatures between 20 and 22C and a relative humidity of 55% for three days before printing. Especially in the case of very thin films, poor separation of the printed film is almost to be expected. For this reason, it may be useful to use a coating with a static eliminator component to avoid the so-called glass plate effect, where the mutual attraction of the sheets is further enhanced by the air being forced out from between the sheets and by the very smooth film and coating surfaces.
Table 4: Formulation differences between UV coatings for paper/board and for plastic films
Component Binder (high-viscosity pre-polymers) Reactive thinner, monomers/polyether (low to medium viscosity) Photoinitators Additives UV coating for paper/board Epoxyacrylates: Hard, brittle, high gloss, average bonding Di-tetrafunctional, average bonding, medium to high polymerisation shrinking Diverse Flow-control agent, foam inhibitor, stabilisers UV coating for plastic films Modified epoxyacrylates: Flexibilised, good gloss, improved bonding properties; Urethane acrylates: Flexible, good bonding Mono- to trifunctional, good bonding, low polymerisation shrinking Diverse; no significant differences Flow-control agent, foam inhibitor, stabilisers, static eliminator
film coatings thus possess very good binding properties, and the flexibility of the final coating on the sheet is enhanced. In addition to the standard highgloss and matt coating types, various gold and silver effects, pearlescent finishes and opaque white grades are similarly available for use on plastic film. UV film coatings can also be tailored to provide individual functions, such as chemical resistance to the most varied solvents, acids and alkalis. Special formulations, furthermore, are able to influence the mechanical properties of the result. High rub resistance and friction values across the whole range from antislip to instant release effect are possible. Further options are heat-resistant UV coatings for inmould labels or low-odour and lowmigration UV systems for food packaging. The printing and coating of plastic substrates places particular demands on all those contributing to the process: the press manufacturer, the film, ink and coating suppliers, and not least the printer at the end of the chain. It is thus indispensable for the user to maintain intensive dialogue with all partners, as only in this way is it truly feasible to become a successful player in this interesting and innovative market segment. Mark Fregin (ACTEGA Terra GmbH, Lehrte)
22 Process 5 | 2008
Applications | Examples
Film and plastics printing package for KBA sheetfed offset presses
Applications: Non-absorbent surfaces (glossy coated board, films/composites with board-like flexural rigidity) Infeed/feeder*: Antistatic systems, coatings (e.g. chrome), timed guide shaft with rollers, rollers above front lays, timed sheet guide with rollers, blower air support Printing units/coating units*: Sheet guiding with mechanical board guides and blower air support, sheet travel sensors, modified grippers, antistatic systems, preparations for UV (ink agitators, rollers, washing systems, UV interdeck drying, coating supply) Delivery*: Sheet guide plates with controlled air, switching between suction and blowing, sheet brake, antistatic systems, extraction system, extended delivery with UV final dryers *) The available features vary according to press type and format, and are matched to individual customer requirements.
The discs can be printed in optimum waterless offset quality with the machines CD-Print and Premius. The latter also handles mini-discs and digital business cards of deviating sizes and shapes. The KBA-Metronic OC200 is the worlds most widely used machine for direct printing on ISO-format plastic cards (both with and without cavities to accommodate a chip). A turning facility at the end of the print section permits immediate printing of the card reverse. Subsequently, it is possible to personalise the cards in an inkjet process on the KBA-Metronic universys, or to add scratch-off patches or labels. As an alternative minimalist solution, the scratch-off module UDA150-S can be combined
The waterless Rapida 74 at Roldn Grficas prints PVC, PETG and PS cards
Personalisation, labelling and scratch-off patches for plastic cards on the KBA-Metronic universys
Standard discs, mini-discs and digital business cards printed on the KBA-Metronic Premius
Process 5 | 2008 23
Applications | Examples All KBA presses and machines on which films and plastic substrates can be printed (subject to further changes)
Model
KBA-Metronic CD-Print KBA-Metronic Premius KBA-Metronic OC100/200 KBA-Metronic universys
Max. format
CD, DVD, Blu-ray CD, DVD, Blu-ray 8.6 x 5.4 cm x2 8.6 x 5.4 cm
Inks
Waterless UV Waterless UV
Finishing options
UV screen-printing or flexo primer UV screen-printing primer, UV coating UV primer, UV coating Scratch-off hot-foil stamping, labelling Scratch-off hot-foil stamping, labelling UV coating UV coating UV coating Dispersion coating (Tippl Tipadur P-1203 B3) UV coating UV coating UV coating UV coating UV coating UV coating UV coating UV coating UV coating UV coating UV coating UV coating
Corona option
no no no no no no no realised realised possible possible realised realised possible upon request upon request upon request upon request upon request upon request upon request
KBA-Metronic UDA150-S Scratch-off 8.6 x 5.4 cm KBA-Metronic Genius 52UV KBA Performa 74 UV KBA Rapida 74 UV KBA Rapida 74G KBA Rapida 74G UV NEW: KBA Rapida 75 UV KBA Rapida 105 NEW: KBA Rapida105 (previously universal) NEW: KBA Rapida106 KBA Rapida 130 KBA Rapida 130a KBA Rapida 142 KBA Rapida 162 KBA Rapida 162a KBA Rapida 185 KBA Rapida 205 36 x 52 cm 52 x 74 cm 52 x 74 cm 52 x 74 cm 52 x 74 cm 52/60.5 x 75 cm 74 x 105 cm 74 x 105 cm 74 x 106 cm 91 x 130 cm 96.5 x 130 cm 102 x 142 cm 112 x 162 cm 120 x 162 cm 130 x 185 cm 151 x 205 cm
ABS, PC, PET, PS, PVC cards up to 1.2 mm, Waterless UV with cavity Personalisation of ABS, PC, PET, PS, Inkjet inks PVC cards up to 0.8 mm Personalisation of ABS, PC, PET, PS, Inkjet inks PVC cards up to 0.8 mm Approx. 0.1 to 0.8 mm, depending on polymer Waterless UV Films from 0.05 to 0.6 mm UV Option for films up to 1.0 mm UV, waterless UV Option for ABS, PC, PET, PS, PVC films Waterless (Zeller+ up to 1.0 mm Gmelin Toracard TF) Option for films up to 1.0 mm Waterless UV Option for films up to 1.0 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV Option for films up to 1.2 mm UV, waterless UV
Tirol (Austria), whose five-colour Rapida 74 with coater, extended delivery, hybrid and UV equipment and plastics package was started up at the beginning of 2008. The first waterless Rapida 74 in Spain was delivered to Roldn Grficas, a member of the European Waterless Printing Association based in Terrasa near Barcelona, in 2007. It is equipped with four UV interdeck modules and UV final drying, and handles above all PVC, PETG
and PS cards. At Gse Verlag GmbH in Karben near Frankfurt am Main, the first Rapida 74G installed in Germany has been in use since November 2005. The waterless offset press with its keyless Gravuflow inking units is configured for alternating production with oxidatively dried and UV-cured inks. Specialities of the company are plastic markers, labels and tags for plant and gardening suppliers.
At Gse in Karben near Frankfurt, the Rapida 74 G is used to print plastic markers and tags for gardening suppliers in waterless UV
24 Process 5 | 2008
Applications | Examples
The worlds first inline corona tower for sheetfed offset at Etna in Nantua (France)
One of the two inert UV interdeck dryers on the six-colour Rapida 105 at Crea Crea Printing Industries recently received an RTE Award for Innovation in the category Printing & Packaging for a biodegradable lenticular presentation box. Further product examples from the company: 1 Advertising displays with flip-image effect; 2 Floor graphics; 3 PET presentation box for bottles; 4 Transparent inserts for books and magazines; 5 School utensils with advertising designs; 6 PET packaging for underwear; 7 Medical info posters; 8 Table-talkers; 9 Ring folders; 10 Place mats
The first sheetfed offset press with an inline corona tower went into production at Etna in Nantua (France) in April 2003. The sixcolour Rapida 74 is also able to pretreat films for later printing on other presses without corona facilities.
The first unit of the 30-metre Rapida 105 at Graf-Poz in Poznan (Poland) is a corona tower
high-gloss or effect coatings. The company Serigraph in West Bend, Illinois, is one of the largest film printing specialists in the USA. The screen printing activities which lent the company its name were already complemented with offset capabilities some years ago. Serigraph has owned a six-colour KBA Rapida 105 UV coater press since 2000. Crea Printing Industries in Roeselare near Bruges (Belgium) was in 2002 the first user in the world to install the inert UV technology in sheetfed offset. Two of the dryer modules developed by SID Leipzig in cooperation with Eltosch are provided as interdeck units on the sixcolour KBA Rapida 105 with coater. Crea is thus able to print also thin PVC films without curling, because the heat input can be significantly reduced.
Process 5 | 2008 25
Applications | Examples
Capital Print, London, uses a Rapida 205 for large-format plastic advertising materials
waterless UV press Genius 52UV. The most prominent user is the Swedish Inplastor Group, where bank cards are printed and laminated under strict security precautions. The press installed in Strngns possesses a separate coater and an extended delivery.
Ultimate quality is also the image of Kunstdrukkerij Mercurius in Zaanstad (Netherlands), who received a five-colour Genius 52UV at the end of 2006. The press is used primarily for printing on plastics. The fifth unit is required for coatings and varnishes. A separate UV
Mercurius in Zaanstad prints films in four and five colours on the Genius 52UV
26 Process 5 | 2008
Many of us remember them from our childhood days: Images of figures which appeared to wave a hand or blink an eye. It was usually just a simple image change (flip) which suggested the motion or action. In the past few years, however, the technology of lenticular printing has been revolutionised. The amazing multi-stage images can in the meantime comprise up to 16 phases. They trick the human eye perfectly and convey the impression of a film sequence or diorama. There are three factors which have made the recent progress possible and which are decisive for the quality of modern lenticular printing: The finely structured lens sheet Exact preparation of the digital image data with the aid of special software
A printing press capable of delivering a brilliant, highly precise image with perfect registration.
viewing angle, however, the blue image disappears and is replaced by the green image, and so on. This effect can be exploited to place several different images or image versions behind the individual lenses. To achieve an image sequence with four separate elements (Figure 3, line A), for instance, each element must be divided into stripes with exactly the same width as a single lens (Figure 3, line B). It is here important that each original image is divided into as many stripes as there are lenses in the array. This newly composed striped image is naturally four times wider than the actual sheet format. Consequently, it must be compressed to a quarter of its width, so that the each set of stripes fits exactly under one and the same lens (Figure 3, line C). All in all, this is a highly complex process, whose implementation has only become properly feasible with modern software, and furthermore demands the trained eye of an experienced printer.
Figure 2 Behind each cylindrical lens of width m, n image stripes are printed at the focal plane (sheet reverse). The example here is a lenticular image comprising n = 4 phases or elements. Depending on the viewing angle, the observer sees only the light beams depicting one of the image stripe sets 1 (here red), 2 (blue), 3 (green) or 4 (yellow) demonstrated above for a switch between the blue and green phases
Process 5 | 2008 27
footprint of just 12 m2, promises costeffective waterless offset printing with UV-cured inks, for outstanding print quality on the most varied nonabsorbent substrates in thicknesses from 0.1 to 0.8 mm.
Figure 3 For an image sequence with four elements (line A; here, as in Figure 2, coloured red, blue, green and yellow to aid understanding), each element is divided into stripes which are exactly the width of a single lens (line B). There must be exactly the same number of stripes as there are lenses in the array. As our sequence comprises four elements, the combined image is now four times the width of the lens array. Consequently, the overall image must be compressed to a quarter of its original width (line C), so that one stripe of each image element fits under each lens. All figures KBA-Metronic AG/Peter Schmitt
day practice: For lenticular printing, absolute precision is decisive. As there are no ink keys in the inking units of the Genius 52UV, the inking is consistently stable. On top of that, the register system guaran-
tees exact automatic plate mounting. As a result, the start-up waste is minimal. And that is an important argument when using expensive materials such as lenticular film. As runs are often particularly short
in the small-format sector, low consumption and fast makeready are imperative. On the Genius 52UV, a single operator can complete a job changeover in only seven minutes. The compact Genius 52UV, with a
With its waterless and keyless offset process, the Genius 52UV from KBA-Metronic sets new standards in respect of quality and cost-effectiveness for the printing of flexible and rigid films (e.g. PVC, PET, ABS) in substrate-dependent thicknesses between 0.1 and 0.8 mm
28 Process 5 | 2008
Glossary
ABS: Acrylonitrile-butadiene styrene; films suitable for printing with UV-cured and waterless offset inks Acrylic glass: see PMMA APET, A-PET, PET-A: Amorphous PET; for highly transparent, highly glossy printable PET films and thin plastic card laminations BOPET: Biaxially oriented APET film (i.e. stretched in both lengthwise and crosswise directions), e.g. DuPont Mylar BOPP: Biaxially oriented polypropylene film CA: Cellulose acetate; highly transparent, highly glossy and highly rigid natural polymer CAP: Cellulose acetopropionate COC: Cyclic olefin copolymer, Topas Coextruded film: Film composite produced by extruding melts of two identical or different polymers Composites: Print substrates and packing materials in which several identical or different material layers are bonded or welded together. CPET, C-PET: Semi-crystalline PET CPO: Cyclic polyolefins
Extruder
EVOH, EVAL: Ethylene vinyl alcohol Extrusion: Manufacturing process in which a plastic film is produced by forcing one or more polymer melts through nozzles (dies) GAG-PET: Coextruded PET composite (PETGAPETPETG); for blister and deep-drawn packaging components GPPS: General-purpose polystyrene HDPE: High-density polyethylene HIPS, PS-I: High-impact polystyrene HTR, PHEMA: Hard tissue replacement, polyhydroxylethylmethacrylate; extremely tear- and UV-resistant films for flexo and offset printing; good deep-drawing and lamination properties IML: In-mould label; usually oriented multilayer PP films, integrated into the surface of a plastic package as pre-printed labels during the moulding process LDPE: Low-density polyethylene Lenticular film: Plastic film comprising a fine array of parallel, cylindrical lenses LLDPE: Isotactically linear LDPE Monofilm: Plastic film produced from a single polymer; compare: Coextruded film. Mylar: Trademark of DuPont; synonym for oriented PET films OLED: Organic light-emitting diode; printable, electrically conducting polymer which emits light when a voltage is applied OPET-A: Oriented (i.e. stretched) PET-A film; high transparency, high glossiness, high rigidity OPP: Oriented (i.e. stretched) polypropylene OPV: Organic photovoltaic; photocell comprising a printable, electrically conducting polymer
OPVC-P: Oriented (i.e. stretched) plasticised PVC film PA: Polyamide; condensation polymer with low transparency, but good glossiness and rigidity; thermoplastic whose rigid variant is also processed into films for offset printing; often found in composites with PE for food bags; as PA 6.6 fibres for synthetic papers PAN: Polyacrylonitrile; highly transparent, highly glossy and highly rigid polymer PBN: Polybutylene naphthalate PBT: Polybutylene terephthalate; polyester for heat- and wear-resistant injection-moulded parts, sheathings and nano-fillers PC: Polycarbonate; the most expensive polyester; highly transparent, highly glossy and highly rigid condensation polymer used for CDs, DVDs, Blu-ray Discs and transparent device housings PE: Polyethylene, polythene; polyolefin polymer with average to good transparency, wax-like, low gloss, average rigidity PEDOT:PSS: Copolymer of polyethylene dioxythiophene and polystyrene sulfonate; printable, electrically conducting copolymer PEEK: Polyetheretherketone PEN: Polyethylene naphthalate; condensation polymer with good transparency and high glossiness and rigidity; replacement for PET in many applications PET, PETB: Polyethylene terephthalate; most important polyester material; highly crease-resistant condensation polymer PET-A: APET, amorphous PET PETB: PET PETG, PET-G: Glycol-modified PET; rigid film with good transparency as base carrier for lenticular films and
shrink-sleeve labels PETIP: Coextrusion of APET with a PET modified with isophthalic acid; for sealable films in metallised composites PHEMA: Polyhydroxylethylmethacrylate; see HTR PK: Polyketone PLA: Polylactic acid; degradable bio-polyester produced from renewable raw materials; can also be printed in offset as a rigid film with high gloss and high strength Plastic: Trivial designation for synthetic and semi-synthetic polymers; distinction is made between thermoplastics (can be formed when heated, e.g. PVC, PP), thermoset plastics (cannot be re-formed, e.g. PUR, hardened epoxides) and elastomers (all cold-formed rubbers); generally speaking, only films produced from thermoplastics are suitable for printing; also processed into blow-moulded packing materials. Plastic films: Polymer webs produced by way of injection moulding or extrusion, processed into substrates and composites with thicknesses between 20 and 150 m (typically 50 to 100 m) and sold in sheet or reel form; available in cleartransparent to opaque white and coloured grades, with glossy, semimatt and matt surfaces, or alternatively structured with patterns or as lenticular film; effectively any plastic film can be printed using UV-cured inks; conventional and waterless inks can also be used in sheetfed offset, or solvent- and water-based inks in flexo and gravure applications; processed for use as folding boxes, flexible packaging, cards and advertising materials Plexiglas: PMMA PMMA: Polymethyl methacrylate,
Process 5 | 2008 29
polymethacrylate; known as Plexiglas or acrylic glass, usually only processed in screen printing Polyester: Ethyl acetate; polymers with the ester functional group, e.g. PET, PEN, PC Polymer: Organic macromolecule on the basis of simple hydrocarbon molecules (monomers), whose high strength and other properties are determined by the chaining, branching or cross-linking of these
monomers; homopolymers (comprising a single monomer type): PE, PP, PVC; copolymers (comprising different monomers): ABS POM: Polyoxymethylene, polyacetal resin, polyformaldehyde PP: Polypropylene, polypropene; average to good transparency, glossy, wax-like, rigid PS: Polystyrene; clear-transparent, rigid; can be foamed (then no longer suitable for printing)
PSU: Polysulphone PTT: Polytrimethylene naphthalate PUR: Polyurethane; basis for moulded parts and adhesives PVC: Polyvinyl chloride; average to good transparency, rigid PVC-P: Plasticised PVC PVC-U: Unplasticised PVC PVDC: Polyvinylidene chloride, a polyolefin polymer PVOH: Polyvinyl alcohol; antistatic, weldable, water-soluble, bio-degrad-
able, high-strength barrier film Tacticity: Preferred alignment of polymer molecules; isotactic polymers (i.e. polymers with identically aligned molecules, e.g. PP) are particularly easy to stretch TPE: Thermoplastic elastomers Dieter Kleeberg
Dryer systems
Adphos Vertriebs GmbH, Hamburg (www.adphos.de, www.eltosch.de) Grafix GmbH Zerstubungstechnik, Stuttgart (www.grafix-online.de) Heraeus Noblelight GmbH, Hanau (www.heraeus-noblelight.com) Khnast Strahlungstechnik GmbH, Wchtersbach (www.uv-technology.de) Dr. Hnle AG UV Technology, Grfelfing (www.hoenle.de) IST Metz GmbH, Nrtingen (www.ist-uv.com) RadTech Europe, Den Haag/Netherlands (www.radtech-europe.com) Schsisches Institut fr die Druckindustrie (SID), Leipzig (www.sidleipzig.de)
Advice, certification
Berufsgenossenschaft Druck und Papierverarbeitung, Wiesbaden (www.bgdp.de) Druck & Beratung D. Braun, Mlheim/Ruhr (www.wluv.de) fogra Forschungsgesellschaft Druck e.V., Munich (www.fogra.org)
3D software
Digi-Art Neue Visuelle Medien Elmar Spreer, Apen (www.lenticularsoftware.de) HumanEyes Technologies Ltd, The Hebrew University, Jerusalem (www.humaneyes.com, www.dispro.at)
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Koenig & Bauer AG Wrzburg Facility Friedrich-Koenig-Str. 4 97080 Wrzburg Germany Tel.: +49 931 909-0 Fax: +49 931 909-4101 Web: www.kba.com E-mail: kba-wuerzburg@kba.com Koenig & Bauer AG Radebeul Facility Friedrich-List-Str. 47 01445 Radebeul Germany Tel.: +49 351 833-0 Fax: +49 351 833-1001 Web: www.kba.com E-mail: kba-radebeul@kba.com KBA-Metronic AG Benzstr. 11 97209 Veitshchheim Germany Tel.: +49 931 9085-0 Fax: +49 931 9085-100 Web: www.kba-metronic.com E-mail: info@kba-metronic.com
KBA Process is a technically oriented publication created to facilitate strategic investment planning by providing detailed, practical information on the current status and future prospects of new technologies and advances. Publications to date: KBA Process No. 1 Focus: Direct Offset Printing on Corrugated Board (2002) KBA Process No. 2 Waterless and Keyless (2005) KBA Process No. 3 Quality Enhancement with Hybrid Production (2006) KBA Process No. 4 Inline Coating (2007) Publisher: Koenig & Bauer Group (www.kba.com) Editors: Jrgen Veil Klaus Schmidt Dieter Kleeberg
KBA, head of sheetfed offset marketing, responsible for the content, juergen.veil@kba.com KBA, marketing director, klaus.schmidt@kba.com Trade journalist/PR service provider to the print industry, dieter.kleeberg@t-online.de
Authors and contributors: Walter J.Bolliger Siegwerk Backnang GmbH, Backnang Martin Dhnhardt KBA Radebeul Olivier Deage Siegwerk France S.A., Annemasse Klaus Fischer Papier Union GmbH, Hamburg Mark Fregin ACTEGA Terra GmbH, Lehrte Beatrix Genest SID Schsisches Institut fr die Druckindustrie GmbH, Leipzig Anne-Kathrin Gerlach KBA Radebeul Birgit Grosse KBA-Metronic AG, Veitshchheim Dieter Kleeberg Dipl.-Ing. D. Kleeberg, Nidderau Izabella Kwiatkowska European Media Group, Poznan Matthias Lange KBA Radebeul Marc Lavor Siegwerk France S.A., Annemasse Cornelia Lillelund Freelance journalist (for Papier Union) Peter Psotta Siegwerk Backnang GmbH, Backnang Peter Schmidt KBA-Metronic AG, Veitshchheim Wilfrid Tews Treofan GmbH, Neunkirchen and Raunheim Jrgen Veil KBA Radebeul Frank Wamann Klckner Pentaplast GmbH, Montabaur Wolfgang Zierhut KERSTEN Elektrostatik GmbH, Freiburg im Breisgau Layout: Katrin Jeroch
If you wish to receive our free customer magazine KBA-Report, but are not yet a subscriber, please contact Anja Enders in our marketing department: E-mail: anja.enders@kba.com Tel.: +49 931 909-4518 Fax: +49 931 909-6015
KBA Radebeul
Product specifications and features may be changed without prior notice. No part of this publication may be reproduced in any way without the publishers permission and without source data. Although registered trademarks and copyrighted or patented products are not specified as such, this does not mean that they are or may be treated as public domain. Printed in the Federal Republic of Germany
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Koenig & Bauer AG, Sheetfed Offset Presses, Radebeul phone: +49 351 833-0, kba-radebeul@kba.com, www.kba.com