Chemical Equilibrium Level 2 Multiple Choice 130.

The dynamic state in which two opposing processes take place at the same time with the same velocities is the state of 1) oxidation; 2) reduction; 3) thermodynamics; 4) complete ionization; 5) none of these. ANS: 5 131. A slightly soluble ionic solid can be made to dissolve 1) by stirring vigorously; 2) by increasing the pressure upon the solvent; 3) by evaporating the solvent; 4) by use of a catalyst; 5) by increasing its solubility product at constant temperature. ANS: 1 132. The rate law for a specified reaction 1) can be determined from the balanced overall reaction. 2) can never be higher than first order. 3) must be determined experimentally. 4) is never changed by the addition of a catalyst. 5) gives no information about the mechanism of the reaction. ANS: 3 133. A reaction in chemical equilibrium is characterized by 1) equal concentration of reaction components. 2) a continual change between reaction components. 3) much greater equilibrium concentrations than initial concentrations. 4) its resistance to change. 5) none of these. ANS: 2 134. Increasing the initial concentrations of reactants 1) has no effect on a reaction. 2) increases the energy produced. 4) increases the number of collisions per sec. 3) has no effect on the reverse reaction. 5) none of these possibilities occur. ANS: 4 135. Although neither gas is very soluble in water, methane (CH4) is about twice as soluble (in moles per liter) as hydrogen (H2) at all temperatures. Which of the following statements regarding the solubility of these gases is false? 1) Methane probably has a greater increase in randomness than does hydrogen as each gas dissolves. 2) The dissolving of each gas in water is an exothermic reaction. 3) Both gases will be less soluble at high temperature than low. 4) Either gas might have different solubility in another solvent. 5) Methane probably has a larger negative value for H of solution than does H2. ANS: 1 136. In order for a reaction to be spontaneous, the sum of the entropy changes of the system and its surroundings must be 1) equal to zero. 3) greater than zero. 5) greater than 2) less than zero. 4) smaller than the free energy change. the enthalpy.

ANS: 3 137. A chemical system in equilibrium will 1) have the same concentrations of all products and reactants. 2) form more products if the temperature is increased. 3) have a specific ratio of product to reactant concentrations. 4) not have any precipitates. 5) represent a spontaneous chemical process. ANS: 3 138. A solution is transferred to a 1 liter flask, some pure ice is added and a stopper is inserted to close the flask. After the system has reached constant temperature, there are still a few cubes of ice left in the flask, but no other solid. Which of the following statements is false relative to this system at equilibrium? 1) The system is a heterogeneous one. 2) There are four phases present in the system, not including the container & stopper. 3) The vapor pressure is constant. 4) The temperature of the system is below 00C. 5) none of these. ANS: 2 139. If methane, CH4, effused through an opening at a rate of 4.00 ml per sec., sulfur dioxide, SO2, would effuse through the same opening at the same temperature at a rate of: 1) 8.0 ml/sec. 2) 2.0 ml/sec. 3) 16.0 ml/sec. 4) 4.0 ml/sec. 5) none of these. ANS: 2 140. For all systems at equilibrium 1) temperature and pressure have equal effects; 2) no energy of activation is required; 3) no changes occur at a molecular level; 4) two opposing changes occur at the same mass per time; 5) none of these. ANS: 4 141. The use of a catalyst in a reaction that goes to equilibrium 1) displaces the equilibrium to form more of the product. 2) increases the energy released. 3) increases the rates of the forward and the reverse reactions. 4) decreases the rates of the forward and the reverse reactions. 5) none of these. ANS: 3 142. When a liquid in equilibrium with its vapor is heated 1) the rate of the reaction, vapor liquid, is increased. 2) the same equilibrium mixture is re-established. 3) a new equilibrium mixture with a higher vapor pressure is established. 4) a new equilibrium mixture is established in which the rate of evaporation is greater than the rate of condensation. 5) none of these. ANS: 3 143. Which is a characteristic of water solutions of gases? 1) They are heterogenous with respect to phase.

2) Components can be separated by filtration. 3) Less entropy exists in the solution than exists in the pure components. 4) Components usually cannot be separated by simple or fractional distillation. 5) none of these statements above. ANS: 3 144. At equilibrium the relationship between the driving forces of energy change accompanying a reaction and that of the disorder change is: 1) that the energy change is always greater. 4) that they are sometimes balanced. 2) that the disorder change is always greater. 5) that the forces are unrelated to each 3) that they are always balanced. other. ANS: 3 145. In the reaction X2 + Y2 2 XY + heat, 1) the enthalpy of the system increases; 2) the system becomes more stable; 3) the bonds between like atoms are more stable than the bonds between unlike atoms; 4) the number of moles of molecules decreases; 5) the reaction is endothermic. ANS: 2 146. Water in a pressure cooker boils above 1000C because 1) the molecules of water form heavier units at high pressure. 2) the vapor molecules cannot move rapidly at high pressure. 3) a higher temperature is needed to produce a vapor pressure equal to the pressure in the cooker. 4) heat is needed for the decomposition of water. 5) none of these. ANS: 3 147. The mechanism for a certain reaction proceeds as follows: A + B D (1st step) D + A F (2nd step) F + 2B C (3rd step) 2A + 3B C (net overall) The energy diagram for the reaction is as shown above. Which is a correct conclusion about this system? 1) The rate law is R = k[A]3[B]2. 3) Step 3 is the most rapid. 2) The expression for the rate 4) A catalyst would affect all 3 steps equally. determining step is R = k[D][A]. 5) none of these ANS: 2 148. Which one of the following does this pair of equations best describe? NO(g) + O2(g) NO3(g) (fast); NO3(g) + NO(g) 2 NO2(g) (slow) 1) the mechanism 3) the catalysis 2) the randomness 4) the activation 5) the entropy ANS: 1 149. In the reaction PCl5(s) PCl3(l) + C12(g); H = 125.5 kJ/mole PC13(l), which would increase Rr ?

1) addition of a catalyst 2) increase in temperature ANS: 4

3) addition of PC15(s) 4) increase in pressure

5) removal of PC13(l)

150. If a bottle 1/2 full of H2O is tightly corked, equilibrium will be reached between H2O(g) and H2O(l) in the bottle. Which of the following is wrong? 1) Raising temperature favors formation of more H2O(g). 2) Lowering temperature will decrease pressure on inside walls. 3) Water vapor pressure will increase as temperature increases. 4) Decreasing volume by pushing the cork farther in favors formation of more H2O(g). 5) Raising temperature will decrease the amount of H2O(l) present in the bottle. ANS: 4 151. Consider the equilibrium reaction: 1/2 Br2(g) + 1/2 H2(g) HBr(g) + 217.6 kJ. Which statement is false? 1) The rate of HBr formation equals its rate of decomposition. 2) A temperature increase would cause less HBr to be present. 3) A catalyst would not change the equilibrium concentrations. 4) A pressure increase would shift the equilibrium so that more HBr would be present. 5) The [H2(g)] at equilibrium would decrease if the [Br2(g)] were increased. ANS: 4 152. Into a system which contained only A, a limited amount of B is injected. The equilibrium, A + B C is established. Which of the following statements applies? 1) The concentration of A is unchanged. 2) The concentration of B is zero at equilibrium. 3) The concentration of C increases until either A or B is exhausted. 4) The concentration of A decreases initially, then becomes constant. 5) The concentrations of A and B become equal. ANS: 4 153. Kp is 0.16 at 250C, and H = -343.1 kJ for the following reaction: 2 NOBr(g) 2 NO(g) + Br2(g). Which one of the following statements is false? 1) Kp for the reaction at 1000C will be less than 0.16. 2) If the equilibrium mixture is compressed, the number of moles of Br2 will decrease. 3) Addition of Br2 to the equilibrium mixture will result in an increase in NO. 4) Addition of NOBr to the equilibrium mixture will cause no change in Kp. 5) If the temperature is decreased, more Br2 is produced. ANS: 3 154. Which of the following changes would increase the molar concentration of the products in any chemical reaction at equilibrium? 1) increase the temperature 2) decrease the pressure 3) add a catalyst 4) decrease the temperature 5) increase molar concentrations of reactants ANS: 5 155. The equilibrium constant for the all gas equilibrium (at l000 K) 2 NO + O2 2 NO2 is Ke = 1.20. If you were to begin with 3.0 moles of NO, 2.0 moles of O2 and 7.0 moles of NO2, in a closed container at l000 K, and allow

equilibrium to be established, 1) the concentration of NO2 would go up. 2) the equilibrium constant would change to some other value besides 1.20. 3) there would be more than 3.0 moles of NO present. 4) the amount of O2 would decrease. 5) all concentrations will decrease by the same amount. ANS: 3 156. Consider the reaction NO(g) + O3(g) NO2(g) + O2(g) + 182.0 kJ. If the reaction is in a closed vessel at a given temperature, consider the following possible changes: A. Decrease temperature C. Add a catalyst B. Add O3 D. Reduce the pressure on the equilibrium gas mixture. Which changes would increase the amount of NO2 present at the new equilibrium? 1) A and B only 3) B and D only 2) B and C only 4) C and D only 5) A and C only ANS: 1 157. The rate of a chemical reaction involving liquids only will not be influenced by the 1) temperature of the system; 2) number of reacting particles per liter; 3) stability of the bonds; 4) impact of molecular collisions; 5) pressure of the system. ANS: 5 158. Consider the equilibrium reaction: 2 A(g) + B(g) 2 C(g). At constant temperature and volume what is the effect of doubling the concentration of C? 1) The concentration of A increases more than that of B. 2) The concentration of A decreases more than that of B. 3) The concentrations of A and B remain the same. 4) The concentrations of A and B decrease equally. 5) The concentration of B decreases more than A. ANS: 1 159. Consider the reaction: 3 H2(g) + N2(g) 2 NH3(g) + 92.0 kJ. Raising the temperature without changing the volume in any of these cases will cause all of the following changes except: 1) a change in the value of the equilibrium constant for the reaction. 2) a decrease in percentage of collisions that result. 3) an increase in pressure. 4) an increase in the number of collisions that result. 5) an increase in the rate of both the forward and the reverse reactions. ANS: 2 160. Consider the reaction: 4FeS(s) + 7O2(g) 2Fe2O3(s) + 4SO2(g); H = -2543.9 kJ/m. When the above reaction is at equilibrium for any given pressure and temperature, which of the following will shift the position of equilibrium so that more product is formed? 1) increase the temperature of the system without changing the pressure 2) add an inert gas to increase the pressure of the system 3) add a catalyst specific for the forward reaction 4) remove the Fe2O3 as it is formed 5) remove the SO2 as it is formed ANS: 5 161. Which of the following does not necessarily produce more product in a chemical reaction?

1) increasing the temperature 2) increasing the amount of reactants 3) removing product as it is formed 4) decreasing the volume of a reaction where change of gas moles is negative 5) increasing the volume of a reaction where the change of gas moles is positive ANS: 1 162. The equilibrium constant, Kp, for the all-gas system SO3 + NO SO2 + NO2 is 0.012 at 4600C. Suppose you began with 6.0 moles SO3, 10 moles NO, 3.0 moles SO2 and 1.0 mole NO2 in a closed fixed volume vessel. Assuming a fast reaction can occur, after several days it would be true that 1) there will be more than 6.0 moles SO3. 2) there will be less than 6.0 moles SO3. 4) the concentration of NO2 will increase. 3) nothing will have changed. 5) the concentration of SO2 will increase. ANS: 1 163. For the reaction A + B C + D, G equals 200 kJ/mole. What can be concluded about the equilibrium concentrations of products and reactants? 1) Very little product forms and the reactants are nearly unaffected. 2) The reaction is virtually complete and only a little of the reactants remain. 3) Without values for entropy and enthalpy, free energy is insufficient basis for deciding. 4) The reaction is easily reversible and the concentration of reactants and products are equal. 5) The reaction mechanism is complex and long. ANS: 2 164. Consider the following reaction at 350 K: heat + NOBr(g) NO(g) + 0.5 Br(g). What would the value of the equilibrium constant be if the reaction were allowed to come to equilibrium at a temperature somewhat higher than 350 K? 1) less than the constant for 350 K 4) more data is necessary 2) greater than the constant for 350 K 5) It is impossible to predict the relative 3) the same value as the KE at 350 K values of equilibrium constants. ANS: 2 165. Consider the reaction: 3 H2 + N2 2 NH3 ; H = -92.0 kJ. Which one of the following statements is wrong? 1) Temperature tends to increase in each case as the reaction proceeds. 2) Chemical bonds must be broken for this reaction to occur. 3) At equilibriums concentrations of H2, N2 and NH3 are not changing. 4) If volume and temperature are same at equilibrium as they were initially, equilibrium pressure will always be greater than the initial pressure. 5) At equilibriums chemical reactions are taking place in the system. ANS: 4 166. The equation for the reaction in the figure below is: AB5(g) + heat AB3(g) + B2(g).

At time imposed into the equilibrium? 1) Pressure was increased. 2) Temperature was increased. 3) AB3 was added to the system. ANS: 1

3 minutes, what change was 4) B2 was added to the system. 5) none of these.

167. The equation for the reaction in the figure below is: H2(g) + I2(g) + heat

2HI(g).

At time 3 minutes, what change was imposed into the equilibrium? 1) Pressure was increased. 2) Temperature was increased. 4) Iodine was added to the system. 3) Hydrogen was added to the system. 5) none of these. ANS: 5 168. The equation for the reaction in the figure below is: H2(g) + I2(g) + Heat

2HI(g).

At time 3 minutes, what change was imposed into the equilibrium? 1) Pressure was increased. 2) Temperature was increased. 4) Iodine was added to the system. 3) Hydrogen was added to the system. 5) none of these. ANS: 4 169. The equation for the reaction in figure below is: H2(g) + I2(g) + heat

2HI ( g).

At time 3 minutes, what change was imposed into the equilibrium? 1) Pressure was increased. 2) Temperature was increased. 4) Iodine was added to the system. 3) Hydrogen was added to the system. 5) none of these ANS: 3 170. The graph below shows the variation of concentration with time for the reaction 3 A(aq) B(aq) + 2 C(aq) at 250C.

What is the value of the equilibrium constant at time t2? 1)1.18 2) 0.845 3) 0.567 4) 0.222 ANS: 1

5) none of these

171. For any chemical reaction at equilibrium, which of the following will change the value of the equilibrium constant? 1) adding a catalyst 2) increasing the pressure 4) increasing concentration of the reactants 3) increasing temperature 5) increasing concentration of the products ANS: 3 172. The numerical value of the equilibrium constant for a given reaction in a closed system depends on the 1) pressure; 2) concentration; 3) temperature; 4) catalyst; 5) none of these. ANS: 3 173. For the reaction 2 HC1(g) H2(g) + Cl2(g) at 12000C, H = +184.6 kJ and KE = 4.0 x 10-5. The value of KE could be increased by 1) adding a catalyst. 3) increasing the temperature. 2) increasing the pressure. 4) increasing the HC1 concentration. 5) none of these. ANS: 3 174. An equilibrium constant will not remain constant if: 1) the temperature of the system changes. 2) the concentrations of the reactants are changed. 3) the concentrations of the products are changed. ANS: 1

4) a catalyst is used. 5) none of these.

175. If a certain reaction has the rate law rate = k[A]2, then when the initial concentration of A is doubled, the initial rate is 1) halved. 3) is tripled. 2) quadrupled. 4) is doubled. 5) remains the same. ANS: 2

176. 0.5 mole of H2(g) and 1.0 mole of HI(g) (but no I2) are added to a 1.0 liter vessel and

allowed to reach equilibrium according to the following reaction: H2 + I2 2 HI(g). If x is the equilibrium concentration of I2(g), the correct equilibrium expression is 1) x(0.5 - x) 2) _(2 - x)2_ 3) x(2 + x)2 4)_(1 - 2x)2 5) none of these (0.5 + x)2 (0.5 x) (0.5 + x)x

(l + 2x)2 ANS: 4

177. For a reaction involving homogeneous gas phase equilibrium, the equilibrium constant can be expressed either in terms of concentration (Kc) or in terms of partial pressures (Kp). Which statement is correct? 1) Kp and Kc are equal only if the moles of reactants are equal to the moles of product. 2) The numerical value of Kc must be greater than that for Kp. 3) The numerical value of Kp must be greater than that for Kc. 4) Kp and Kc must be numerically equal. 5) None of these statements apply. ANS: 1 178. In the reaction 2 A + B C + 3 D, the molar concentrations at equilibrium are: A = 1; B = 4; C = 8; and D = 2. What is the value of the equilibrium constant? 1) 1/16 2) 1/6 3) 16 4) 64 5) none of these ANS: 3 179. For a given system at equilibrium, the addition of heat 1) always favors the endothermic reaction; 2) sometimes favors the endothermic reaction; 3) has no affect on the equilibrium; 4) increases the value of the equilibrium constant; 5) always favors the exothermic reaction. ANS: 1 180. If a certain reaction has the rate law rate = k[A]3, then when the initial concentration of A is doubled, the initial rate is 1) doubled. 3) increased six times. 2) tripled. 4) increased five times. 5) none of these. ANS: 5 181. In a reaction between A and B, the rate of reaction was doubled by doubling the initial concentration of A when B was fixed. If B concentration was doubled with A fixed, the rate increased by a factor of 4. What is the rate law expression? 1) Rate = k[A][B] 3) Rate = k[A]2[B] 2 2) Rate = k[B] 4) Rate = k[A]2 5) Rate = k[A][B]2 ANS: 5 182. N2O4 dissociates into two NO2 molecules. When 0.50 mole of N2O4 is placed in a 2.0 liter flask and allowed to come to equilibrium, the final concentration of N2O4 is 0.10 mole per liter. What is the equilibrium constant for the dissociation of N2O4 under these conditions? 1) 0.20 2) 0.90 3) 0.23 4) 4.44 5) 1.11 ANS: 2

183. The data given in the table were collected for the reaction A + B D + E. [A] [B] INITIAL RATE (mol/L) (mol/L) (mol/L-min) ---------------------------------------------------------0.10 0.20 200 0.10 0.10 50 0.30 0.10 150 ---------------------------------------------------------What is the overall reaction order? 1) First 2) Second 3) Third 4) Fourth 5) Zero ANS: 3 184. SO2C12 decomposes according to SO2Cl2 SO2 + Cl2. Use the following data to determine the reaction order with respect to SO2C12. [SO2C12] Initial Rate (M/s) -------------------------------------------------0.1 M 2.2 x 10-6 0.3 M 6.6 x 10-6 0.4 M 8.8 x 10-6
-----------------------------------------------------------------------------

1) First ANS: 1

2) Second

3) Third

4) Fourth

5) Zero

185. The rate of a reaction is given by Rate = k[A]x[B]y[C]z . If [A] is doubled while [B] and [C] are held constant, the observed rate is 8 times the original rate. If [B] is doubled while [A] and [C] are held constant, the rate is 2 times the original. If [A] and [B] are held constant and [C] is doubled, the new rate is 4 times the original. The exponents x, y and z are: 1) 1, 0 and 2. 3) 3, 1 and 2. 2) 2, 1 and 2. 4) 4, 1 and 2. 5) more info is needed. ANS: 3 186. If a reactants concentration is doubled and the reaction rate increases by a factor of 8, the exponent for that reactant in the rate law should be: 1) 1; 2) 2; 3) 3; 4) 4; 5) . ANS: 3 187. The gas-phase reaction H2(g) + X2(g) 2 HX(g) proceeds by bimolecular collisions between H2 and X2 molecules. If the concentrations of both H2 and X2 are doubled, while keeping all other conditions unchanged, the reaction rate will be increased by a factor of 1) 1; 2) 2; 3) 3; 4) 4; 5) 16. ANS: 4 188. The equilibrium law K = [A]2[B] represents which of the following reactions? [C][D]2 1) A + B C + D 3) 2 A + B C + 2 D 2) C + 2 D 2 A + B 4) C + D A + B 5) A2 + B C + D2 ANS: 2

189. Use the equilibrium constant expression for W + 3 X Y + 2 Z to set up the concentration for Y. What is the molarity of Y? 1) KE[X]3 2) [W]KE 3) [Z]2[W] 4) KE[W]2[X] 5) none of these [W][Z]2 [X]3[Z]2 KE[X]3 [Z]3 ANS: 5 190. Use the equilibrium constant expression for 2 C + D 3 E to express the concentration of D. The molarity of D is equal to: 1) [C]2KE 2) [E]3KE 3) [E]3[F] 4) [C]2[F] 5) none of these 3[F] 2[F] 2K 3K [E] [C] [C] E [E] E ANS: 3 191. Use the equilibrium constant expression for 3 A + 2 B 2 C + D to express the concentration of D. The molarity of D is equal to: 1) [A]3[B]2 2) [C]2KE 3) KE[A]3[C]2 4) KE[A]3[B]2 5) none of these 2 3[B]2 2 2 KE[C] [A] [B] [C] ANS: 4 192. Use the equilibrium constant expression for 3 K + L M + 2 N to set up the concentration for L. What is the molarity of L? 1) [M] N]2 2) [K]3KE 3) KE[N]2 4) [M]3[N] 5) none of these 3 2 3 2K KE[K] [M][N] [M][K] [K] E ANS: 1 193. Consider the reaction: NaI(aq) + H2SO4(aq) NaHSO4(aq) + HI(aq). The equilibrium constant is 7.3 x 10-4. If the equilibrium concentrations of H2SO4, NaHSO4 and HI are 2.1 x l0-l M, 3.2 x 10-2 M and 4.6 x l0-4 M respectively, what is the molarity of NaI? 1) 3.2 x 102 M 3) 7.2 x 10-1 M 1 M 2) 1.0 x 10 4) 9.6 x 10-2 M 5) 5.1 x 10-8 M ANS: 4 194. Consider the reaction: 2 SO3(g) 2 SO2(g) + O2(g). If the equilibrium concentrations of SO3, SO2 and O2 are 2.2 M, 1.7 M and 5.1 M respectively, what is the KE? 1) 0.31 2) 0.34 3) 3.05 4) 3.94 5) none of these ANS: 3 195. In the equilibrium reaction, 2 NO2(g) N2O4(g), KE = 8.81. What is the molar concentration of nitrogen tetroxide at equilibrium if the nitrogen dioxjde concentration is 0.20 molest liter? 1) 4.53 x l0-3 M 3) 1.76 x 10-1 M 2) 2.27 x 10-2 M 4) 3.52 x 10-1 M 5) 7.63 x 103 M ANS: 4 196. Consider the reaction: NaHCO3(aq) + HBr(g) NaBr(aq) + H2CO3(aq). The equilibrium constant is 3.3 x 10-5. If the equilibrium concentrations of NaHCO3, HBr and NaBr are 3.0 M, 4.0 M and 2.0 M respectively, what is the molarity of H2CO3? 1) 5.5 x 10-6 M 3) 4.6 x 102 M

2) 2.0 x 10-4 M ANS: 1

4) 5.1 x 103 M

5) 2.0 x 105 M

197. Nitrogen reacts with hydrogen to form ammonia, NH3. Calculate the concentration of nitrogen present when the reaction reaches equilibrium if 1.8 x 10-4 m/l. of hydrogen is present and the concentration of ammonia is 8.9 x 10-6 m/l. The equilibrium constant is 1.11x 10-2. 1) 3.96 x 10-5 M 2) 8.17 x 10-4 M 3) 4.45 M 4) 1.22 x 103 M 5) 1.69 x 104 M ANS: 4 198. In the reaction 2X(s) + 3Y2(g) X2Y6(g), determine the equilibrium constant when X2Y6 has 4.85 x 102 moles/liter, X has 3 x 102 moles/liter and Y2 has 2 x 10-1 moles per liter. 1) 1.65 x 10-5 2) 6.74 x 10-1 3) 1.48 4) 2.43 x 103 5) 6.06 x 104 ANS: 5 199. One mole of X and one mole of Y are allowed to react in a 2-liter container. When equilibrium is reached, the following reaction occurs: 2 X + Y Z. If the concentration of Z is 0.2 M, calculate the equilibrium constant for this closed system. 1) 0.015 2) 2.22 3) 6.70 4) 7.41 5) 66.7 ANS: 5 200. If a 0.3 M solution of HNO2 has a [H+] = 9 x l0-3 M, what is the [NO2-] in this reaction? The equilibrium constant is 6 x 10-4. 1) 2.0 x 10-2 M 3) 4.5 M 2) 1.8 x 10-5 M 4) 5.0 x 101 M 5) none of these ANS: 1 201. Consider the equilibrium reaction: H2O2(g) H+(aq) + HO2-(aq). The acid has a concentration of 0.02 M and the KE = 8 x 10-2. What is the concentration of H+ and HO2- at equilibrium? 1) 1.6 x 10-3 M 3) 8.0 x 10-1 M -2 M 2) 4.0 x 10 4) 2.5 x 101 M 5) 6.25 x 102 M ANS: 2 202. Calculate the concentration of hydrogen at equilibrium for the reaction: H2(g) + Br2(g) 2 HBr when [Br2] = 0.05 M, [HBr] = 0.5 M and KE = 33.0. 1) 6.60 M 3) 3.03 x 10-1 M -1 M 2) 1.52 x 10 4) 6.60 x 101M 5) none of these ANS: 2 203. Consider the reversible reaction: O3(g) O2(g). At equilibrium the concentration of oxygen is 4.0 moles per liter. The equilibrium constant is equal to 16.0. What is the concentration of ozone, O3? 1) 0.25 M 2) 0.50 M 3) 2.00 M 4) 3.20 M 5) 4.00 M ANS: 3 204. Consider he reaction: 2 SO2(g) + O2(g) 2 SO3(g). The equilibrium constant is 8.6 x 10-2. If the equilibrium concentrations of SO2 and SO3 are 4.2 x 10-1 M and

6.4 x l03 M respectively, what is the molarity of O2? 1) 4.1 x 10-5 M 3) 1.3 x 10-2 M -3 M 2) 2.7 x 10 4) 1.8 x 10-1 M 5) 3.6 x l01 M ANS: 2 205. Consider the all-gas equilibrium H2O + CO H2 + CO2 for which KE = 4.0 at a certain temperature. If you were to begin with 1.5 moles of H2O and 1.5 moles of CO in a 1.0 liter vessel, what would be the equilibrium concentration of CO2? 1) 0.5 M 2) 0.8 M 3) 1.0 M 4) 1.2 M 5) 2.0 M ANS: 3 206. If the equilibrium concentrations for X2, Y2 and XY are 1.2 x 103 M, 5.83 x 11-12 M and 8.9 x 102 M respectively, what was the initial concentration X2 before the reaction occurred to form XY? 1) 8.83 x 10-1 M 3) 1.65 x 103 M 3 M 2) 1.16 x 10 4) 2.09 x 103 M 5) 1.13 x 1014 M ANS: 3 207. It has been found that the rate of the reaction A + B C doubles when the concentration of A is doubled, and goes up by a factor of four when the concentrations of both A and B are doubled. What is the overall reaction order? 1) First 2) Second 3) Third 4) Fourth 5) Zero ANS: 2 208. For the all gas reaction at l000 K: 2 HI H2 + I2, KE = 0.0344. If you were to begin with 8.0 M of HI in a fixed volume container, what would be the equilibrium concentration of H2? 1) 7.9 M 2) 0.48 M 3) 5.8 M 4) 2.92 M 5) 1.10 M ANS: 5 209. Consider the reaction: 2 CO2(aq) 2 CO(g) + O2(g). The equilibrium constant is 5.5 x 10-7. If the equilibrium concentrations of CO2 and CO are 1.8 x 10-3 M and 4.9 x 10-2 M respectively, what is the molarity of O2? 1) 5.2 x 10-12 M 3) 7.4 x10-10 M 2) 3.6 x 10-11 M 4) 2.0 x 10-8 M 5) 1.3 x 109 M ANS: 3 210. Consider the reaction: NaHCO3(aq) + HBr(g) NaBr(aq) + H2CO3(aq). The equilibrium constant is 4.8 x 10-8. If the equilibrium concentrations of HBr, NaBr and H2CO3 3.1 x 10-1 M, 2.6 x l02 M and 5.2 x 103 M respectively, what is the molarity of NaHCO3? 1) 9.1 x 103 M 3) 1.1 x 10-4 M -1 M 2) 4.9 x 10 4) 6.6 x 10-7 M 5) 3.1 x 10-8 M ANS: 1