Q1. A 22.4 L vessel contains 2 mole of H2 and 1 mole of N2 at Tn.

What are the mole fractions and the partial pressures of the components in the vessel? Molar Fractions: Total no. of moles = 3, x(H2) = 2/3 , x(N2) = 1/3 Partial Pressures: For H2, p = nRT/V = 2026 mbar, For N2, p = nRT/V = 1013 mbar, p (Total) = 3039 mbar Q2. A 0.5 L vessel contains H2/N2 at 500 mbar & Tn. If partial pressures of H2 is 200 mbar, what are the mole fractions of H2 & N2? Use pV = nRT as n = pV/RT nH2 = 4.41 X 10-3 mole nN2 = 6.61 X 10-3 mole n (Total) = 11.02 X 10-3 mole x (H2) = 0.4 x (N2) = 0.6 Q1. A 4 L of N2 has a pressure of 500 mbar at 20C. What is the mass of the gas? Q2. The composition of dry air in % volume is as follows : N2=78.1, O2=20.9, Ar=0.9, CO2=0.03 and other 0.07.Find the partial pressure of each at Tn when total pressure is pn. Q3. The interior of a spherical vessel of radii 0.5 m is covered with monolayer of a gas particles each having cross sectional area of 10-19 m2. Find the increase in the pressure if all the particles are desorbed at 300C. Q4. Calculate the mean free path of N2 (molecular diameter = 3.7A ) at 1 torr and 293 K.

Mercury: 13.58 times heavier than water: Column is 13.58 x shorter : 10321 mm/13.58=760 mm (= 760 Torr) Q1. What is the average velocity of gas molecules in terms of its molecular weight and temperature ? Fine this for nitrogen molecule at 20C Q2. What is mean free path? What is the relationship between pressure and mean free path of a molecule. At 25C for nitrogen find number of molecules/cm3 and the mean free path at following pressures (in torr) a) 760 b) 1 c) 10-6 Q3. Find the relationship between following units Torr, mtorr, Pascal, atmosphere, mmHg and bar Q4. Describe basic fluid flow regimes. How does it depends on characteristic dimension of the system.

Q1. For a system with gas load of 110-5 torr l/sec, required ultimate vacuum is 110-7 torr. System is connected with a pump by a cylindrical 4 long tube of diameter 2.5. Find a suitable pump for this system. Can you improve on this system? Q2. How can one determine the pumping speed of a pump experimentally? Q1. A chamber is connected with a 3 m long tube of 20 mm radius to a pump of speed of 25 l/s. a) Find the conductance of the tube and effective pumping speed at the chamber. Assume molecular flow. b) What can be done to increase the effective pumping speed of the system? c) If pump is replaced with 1000 l/s pump OR connecting tube with 1m long tube having 40 mm diameter, which of more effective for increasing the Q2. Explain the differential pumping. Q3. At what temperature 4He atoms will have mean velocity of 150 ms-1? effective pumping speed. is replaced

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