AQAGloss X

Water it down and shine it up !

AQAGloss X
water it down and shine it up !

Legislation will Change the (European) World of Architectural Coatings

AQAGloss X
water it down and shine it up !

Europes lacquer market must and will change: From solvent based systems (mainly alkyds) to environmental friendly systems

AQAGloss X
water it down and shine it up !

VOC-limits for trim paints* January 2007 January 2010

Water borne Solvent borne (usually alkyd)

*EU directive 2004/42/CE

150 g/l

130 g/l

400 g/l

300 g/l

Conventional alternatives to solvent based alkyds: water based acrylics

Advantages alkyds Brushability Body, leveling Open time (Initial) gloss level Hardness Penetration/adhesion Stain blocking Resistance towards household chemicals Sandability (reparability) Advantages acrylics Safer handling and easier cleaning No siccatives Short drying time No/less yellowing Gloss retention Outdoor durability

Typical Alkyd Problem: Aging / Delamination

Quotations on new water based alkyd lacquers (introduced at Farbe 2005, Cologne) Die echte Alternative zum konventionellen Malerlack: Capalac Aqua PU-Alkyd Gloss Seit Jahren warten professionelle Anwender auf einen Lack, der das Zeug hat, die neue Maler-Qualitt zu werden. Die Zeit des Wartens ist vorbei. LackPerfect Hochglanz

(Meffert)
Zukunftslacke: Umweltschonender, PUverstrkter, wasserverdnnbarer Hochglanzlack (PU-Alkydemulsion): Rubbol BL Azura Umweltschonender, lsemittelreduzierter, hochglnzender Alkyd-PU Decklack Relius VOC Gloss
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AQAGloss X
water it down and shine it up !

Options for 2010

Alternatives to solvent based alkyds high solids (solvent based alkyds) z alkyd like (familiar) rheology z still significant solvent level needed (not really green) z difficult to achieve for tinted systems (coloured pigment distribution)

AQAGloss X
water it down and shine it up !

Options for 2010

Alternatives to solvent based alkyds z water based alkyds z no major change in chemistry (film properties) z no technical selling point vs. solvent based alkyds typical alkyd problems, such as yellowing, bad weathering performance

AQAGloss X
water it down and shine it up !

Options for 2010

Alternatives to solvent based alkyds z water based acrylics acrylic benefits (weatherability, whiteness) limited gloss level

10

AQAGloss X
water it down and shine it up !

Options for 2010

Alternatives to solvent based alkyds z water based PUs good surface characteristics (chemical resistance) expensive limitations in achievable gloss level

11

AQAGloss X
water it down and shine it up !

Options for 2010

Alternatives to solvent based alkyds z Polymer blends combine benefits and deficiencies of different systems need cobalt siccatives

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The Option for 2010

Alternatives to solvent based alkyds

water it down and shine it up:

AQAGloss X
better in gloss better performance better for our environment

13

AQAGloss X
Water it down and shine it up !

Water based Gloss Level as Conventional Alkyds No Heavy Metals/Siccatives

- more than passing EU 2004/42/EC

AQAGloss X - water it down and shine it up !

Basic properties

z Solid content: approx. 42 % z pH: 7-8.5 z Viskosity: approx. 70 mPas z MFT: <1 C z Water uptake (24 h): 10 % z Solvent content: 2.5%

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AQAGloss X
water it down and shine it up !

Alkyd-like features:
z z z z Gloss and haze Body and hiding power* Stain blocking Low Blistering
solvent based AQAGloss alkyd X 92 90 83 81 17 14 water based acrylic 81 57 159

Gloss 60 Gloss 20 Haze

*)Confirmed by professional painter!

without siccative and oxime

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AQAGloss X- water it down and shine it up !

good for our environment

Paints based on AQAGloss X already meet environmental standards of tomorrow (e.g. EU Directive 2004/42/EC): They contain only small amounts of film-forming auxiliaries, no heavy metals driers, no oximes and no formaldehyde.

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AQAGloss X- water it down and shine it up !

starting point formulation

AQAGloss X based High Gloss Paint z Water 70.3 z Byk 020 4.5 z Disperbyk 190 22.2 z Collacral LR 8990 11.6 z Kronos 2190 222.7 disperse at 3000 rpm for 15 min, then add z AQAGloss X 640.2 z Propylene glycol 20.5 z Tego Airex 902 W 5.0 z Tego Wet 270 3.0 1000.0
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AQAGloss X - water it down and shine it up !

gloss comparable to solvent born alkyds

100 90 80 70 60 50 40 30 20 10 0 AQAGloss Rubbol AZ gloss 24h 20 gloss 24h 60

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Glasurit EA HG

AQAGloss X- water it down and shine it up

superior gloss level especially at 20 !

100

90

80

70

60

50

40 AQAGloss M1 M2 gloss 24h 20 M3 gloss 24h 60 M4 acrylic

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AQAGloss X- water it down and shine it up !

low initial gloss loss (14 d) indicates low shrinkage
100 90 80 70 60 50 40 30 20 10 0 AQAGloss Rubbol AZ Glasurit EA Solvent based HG M1 M2 M3 M4 acrylic
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1d 3d 14d

AQAGloss X - water it down and shine it up !

excellent gloss on contrast paper
100

90

gloss on contrast paper

80

70

gloss 20 gloss 60

60

50

40

AQAGloss

M1

M2

M3

acrylic
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AQAGloss X - water it down and shine it up !

high gloss on any surface (20)

90

80

70 PVC steel zinc aluminium gloss 20

60

50

40

30 AQAGloss M1 M2 M3 acrylic
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AQAGloss X - water it down and shine it up !

high gloss on any surface (60)

90

80

70

PVC steel zinc aluminium

gloss 60

60

50

40 AQAGloss M1 M2 M3 acrylic
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AQAGloss X - water it down and shine it up !

lowest haze of all water based systems
haze after 3d drying at RT
200 182 180 160 160 140 120 100 80 60 40 20 0
AQAGloss Rubbol AZ Glasurit EA solvent born HG M1 M2 M3 M4 acrylic
25

113 97 105

25 16 0

AQAGloss X - water it down and shine it up !

low initial haze level does not increase
250

200

150 haze 100 50 0 AQAGloss Rubbol AZ Glasurit EA HG M1 M2 M3 M4 acrylic

1d

3d

14d

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DOI: Distinctness of Image

Good

Poor

Contrast - Sharpness - Distinctness

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Measurement Principle: wave-scan DOI

Optical Profile

Mathematical Filters LW splitted Higher Resolution Expanded Range

0.1 mm 30 mm

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DOI: Distinctness of Image

100 80 60 40 20

< 0.1

0.1

0.3

10

30

100

Light scattering cause a contrast reduction Small structures cause a distortion of outlines
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DOI: Distinctness of Image

25 20 15 10 5 0

84

91

< 0.1 dullness

0.1-0.3 Wa

0.3-1 Wb

1-3 Wc

3 - 10 Wd

10 - 30 mm We

DOI = f (du, Wa, Wb)

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AQAGloss X - water it down and shine it up !

best of all systems if tested to automotive standards

Distinctness of Image (DOI)

72 70 68 66 64 62 60 AQAGloss Sikkens Rubbol BL solvent based M1 M2 M3 acrylic
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Surface Roughness

AQAGloss X
water it down and shine it up !

Acrylic gloss paint

Polymeric layer on top is decisive for high gloss!

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AQAGloss X - water it down and shine it up !

no yellowing in Xeno test

M1

M2

M3

Rubbol AZ

acrylic

M5

AQAGloss

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AQAGloss X - water it down and shine it up !

no yellowing in artificial weathering
Xeno-Test (delta b after 1000h)
2

1,5

1 delta b

0,5

0 AQAGloss -0,5 Rubbol AZ M1 M2 M3 acryl

-1
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AQAGloss X - water it down and shine it up !

Yellowing at elevated temperature
delta b 14d/50
1,5

0,5

0 AQAGloss -0,5 Rubbol AZ M1 M2 M3 acrylic

-1

-1,5

35

AQAGloss X - water it down and shine it up !

low yellowing by ammonia contamination
delta b after 20 min contamination with ammonia
7

delta b

0 AQAGloss Rubbol AZ M1 M2 M3 acryl

36

AQAGloss X - water it down and shine it up !

high brightness (next to acrylics)
brightness
96,00 94,00 92,00 brilghtness (L) 90,00 88,00 86,00 84,00 82,00 80,00 AQAGloss Rubbol AZ brightness 100 M1 M2 M3 brightness 600 acryl
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brightness 300

AQAGloss X - water it down and shine it up !

Hiding power
contrast ratio
100,00 98,00 96,00 94,00 contrast ratio 92,00 90,00 88,00 86,00 84,00 82,00 80,00 AQAGloss Rubbol AZ contrast ratio 100 M1 M2 M3 contrast ratio 600 acryl
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contrast ratio 300

AQAGloss X - water it down and shine it up !

very low water uptake of paint film
35

31,3
30

28,5

25

water uptake [%]

20

15,3
15

2h 24h
13,7 11,7

10

6,4
5

4,4 1,8
no thick film formation possible

3,6

3,2

AQAGloss

solvent based

Rubbol AZ

M1

M2

M3

acrylic

39

AQAGloss X - water it down and shine it up !

no blisters caused by water droplets
30

25 water blisters after h contamination

>24

>24

20

15

10 7 5 3,6 1,8 0,2 0 AQAGloss

solvent based

Rubbol AZ

M1

M2

M3

acrylic
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AQAGloss X - water it down and shine it up !

good dry adhesion on various substrates
100 90 80

0= zero adhesion; 100= perfect

70 60 50 40 30 20 10 0

AQAGloss

Rubbol AZ
solvent based

M1 PVC steel zinc

M2 aluminium

M3

acrylic
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AQAGloss X - water it down and shine it up !

pendulum hardness
70

60

50

40

30

1d 3d 7d 14d

20

10

0 AQAGloss Rubbol AZ
Solvent based
42

M1

M2

M3

acrylic

AQAGloss X - water it down and shine it up !

block resistance (force of separation)
blocking after 4d
5 4,5 4
blocking (0 = perfect; 5 = worst)

3,5 3 2,5 2 1,5 1 0,5 0

AQAGloss

solvent based

Rubbol AZ

M1

M2

M3

acrylic
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AQAGloss X - water it down and shine it up !

elongation at break
elongation at break
300

250

200

150

100

50

no thick film formation possible

AQAGloss Rubbol AZ M1 M2 M3 acrylic

Solvent based
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AQAGloss X - water it down and shine it up !

Stain blocking on Meranti and Merbao (5d in water)
dE
14 12

10

0 AQAGloss M1 M2 delta E (Meranti) delta E (Merbao) M3 acrylic

45

AQAGloss X - water it down and shine it up !

increasing PVC causes little gloss change - reduces formulation cost
100 90 80 70 gloss/haze 60 50 40 30 20 10 0 gloss 20/24h gloss 60/24h haze

PVC 20

PVC 25
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AQAGloss X
water it down and shine it up ! transparent lacquers

Clear Lacquer / Tinting Base z Water z Byk 020 z Disperbyk 190 z Collacral LR 8990 z Propyleneglycol z X-Fast yellow/red/blue/green (or Luconyl z AQAGloss

9.0 0.6 2.8 1.5 2.6 1.5/1.8/2.1/1.9 2.8) 82.0

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AQAGloss X
water it down and shine it up ! transparent lacquers
gloss 20 gloss 60

Tinting with X-Fast

120 100
84

haze
92 82 90 88

94

99 100

80
Gloss level

60 40 20 0
yellow red

53 40 31

52

blue

green
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AQAGloss X
water it down and shine it up ! transparent lacquers

gloss 20

Tinting with Luconyl

gloss 60 haze
91 91 83 82 89

100 90 80 70 60 50 40 30 20 10 0
84

35 26 28

yellow

red

black

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AQAGloss X - water it down and shine it up !

360 h salt spray on Acronal S 760 primed steel Sikkens Rubbol
(solvent based )

AQAGloss

50

flow curve
5.000 Pa 4.500

Flie- und Viskosittskurve

05Schw33/2 1 Z 7.1

4.000

05Schw33/3 1

Sikkens Rubbol
3.500

Z 7.1 05Schw33/4 1 Z 7.1

solvent based alkyd

3.000

05Schw33/6 1

2.500 2.000

AQAGloss M5 M3

Z 7.1 05Schw33/5 1 Z 7.1 05schw33/7 1 Z 7.1

1.500

1.000

05Schw33/8 1

500

M2 M1
0 500 1.000 1.500 2.000 2.500
.

Z 7.1

0 3.000 3.500 4.000 4.500 1/s 5.000 Schergeschw indigkeit

Copyright (C) 1998 Physica Metechnik GmbH

51

AQAGloss X - water it down and shine it up !

high thickener response
Fliesskurve
1 .500 Pa 1 .300 1 .200 1 .1 00 1 .000 900 800 7 00 600 500 400 300 200 1 00 0 0 500 1 .000 1 .500 2.000 2.500 3.000 3.500 4.000 1/s Geschwindigkeitsgeflle D 1

Identical formulation; binder exchange only

0,9 0,8 0,7

AQAGloss

0,6 0,5 0,4

acrylic binder

0,3 0,2 0,1 0 5.000

52

AQAGloss X - water it down and shine it up !

resistant to household chemicals

Resistant to contamination by z Handcreme z Coffee z Red wine z Beetroot z Ketchup z Mustard z Lip stick z Butter z Margarine z Iron oxide
53

AQAGloss X - water it down and shine it up !

resistant to household chemicals
solvent based

M1

M2

M3

Rubbol AZ

Acrylic

AQAGloss

Coffee

Red wine

beetroot Ketchup Lip stick

mustard handcreme

54

AQAGloss X - water it down and shine it up !

AQAGloss X more than gloss and weathering resistance:

New benchmarks for the professional painter - excellent body - superior brush drag - high film build - easy application by PU-foam applicator - no foaming tendency - safe working hygiene - easy cleanability
55

AQAGloss X - water it down and shine it up !

AQAGloss X more than gloss and weathering resistance

The easy way for the DIY market water based - low solvents - no heavy metal siccatives - no oximes - easy application - water cleanable - high resistance to household chemicals
56

AQAGloss X - water it down and shine it up !

Laboratory tested proven in daily use by professionals

The professionals are convinced. As master painter Witte says: In my business water-based paints used to be just a last resort. But paints based on the new AQAGloss X binder more than meet my expectations and make it possible to do a highly professional job.

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