Azeotrope (Data) - Wikipedia, The Free Encyclopedia

9/6/13
Azeotrope (data) - Wikipedia, the free encyclopedia
Azeotrope (data)
From Wikipedia, the free encyclopedia
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. Data includes composition of mixture by
weight (in binary azeotropes when only one fraction is given, it is the fraction of the second component), boiling point (b.p.) of
components, boiling point of mixture, and specific gravity of mixture. Boiling points are at 760 mm Hg unless otherwise stated. Where the
mixture separates into layers, values are shown for upper (U) and lower (L) layers.
Data is obtained from Lange's 10th edition[1] and CRC 44th edition[2] unless otherwise noted (see color code table).
A list of 15825 binary and ternary mixtures was collated and published by the ACS.[3]
Binary azeotropes
Data source color code
CRC & Lange's CRC only Lange's only other (see references)
Azeotropes of water, b.p.=100 C

2nd Component
b.p. of
b.p. of
% by
comp. (C) mixture (C) weight
Azeotropes of ethanol, b.p.=78.4 C

spef.
grav
with various alcohols

ethanol
78.4
78.1
95.5
0.804
methanol[4]
64.7
n-propanol
97.2
87.7
71.7
0.866
iso-propanol
82.5
80.4
87.9
0.818
n-butanol
117.8
92.4
55.5
U 79.9 U 0.849
L 7.7
L 0.990
sec-butanol
99.5
88.5
67.9
No azeotrope
0.863
iso-butanol
108.0
90.0
70.0
U 85.0 U 0.839
L 8.7
L 0.988
tert-butanol
82.8
79.9
88.3
allyl alcohol
97.0
88.2
72.9
benzyl alcohol
205.2
99.9
furfuryl alcohol
169.4
98.5
20
cyclohexanol[5]
161.1
97.8
20
benzyl alcohol[5]
205.4
99.9
0.905
with various organic acids

formic acid
acetic acid
100.8
[4][6]
107.3
118.1
77.5
No azeotrope
propionic acid
141.1
99.98
17.7
1.016
butyric acid
163.5
99.94
18.4
1.007
iso-butyric acid
154.5
99.3
21
with mineral acids

nitric acid
86.0
120.5
68
perchloric acid
110.0
203
71.6
hydrofluoric acid
19.9
120
37
en.wikipedia.org/wiki/Azeotrope_(data)
1.405
1/9
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hydrochloric acid
84
110
20.24
hydrobromic acid
73
126
47.5
hydroiodic acid
34
127
57
sulfuric acid
290
338
98
1.102
1.481
83.7
72
91.8
propylene chloride 96.8
78
89.4
53.3
97.0
U 0.8
L 99.8
chloroform
61.2
carbon tetrachloride 76.8
methylene chloride 40.0
b.p. of b.p. of
% by spef.
comp. mixture
weight grav
(C)
(C)
with various esters
with various alkyl halides

ethylene chloride
2nd Component
U 1.004
L 1.491
ethyl acetate
77.1
71.8
69.2
methyl acetate
57.0
56.9
97
ethyl nitrate
87.7
71.9
56
isopropyl acetate[5]
88.4
76.8
47
0.863
with various hydrocarbons

benzene
80.2
68.2
67.6
64.9
69.5
0.848
66.8
95.9
U 0.03 U 1.000
L 99.97 L 1.597
cyclohexane[8]
80.7
toluene
110.8 76.7
32
n-pentane
36.2
34.3
95
38.8
99.6
U 2.0
99.9
n-hexane
68.9
58.7
79
0.687
n-heptane
98.5
70.9
51
0.729
n-octane
125.6 77.0
22
U 1.009
L 1.328
with various esters
0.815
ethyl acetate
77.1
70.4
91.9
U 96.7 U 0.907
L 8.7
L 0.999
methyl acetate
57.0
56.1
95.0
n-propyl acetate[5] 101.6
82.4
86
carbon tetrachloride
76.8
65.1
84.2
ethyl nitrate
74.4
78
allyl chloride
45.7
44
95
n-propyl chloride
46.7
45.0
93
isopropyl chloride
36.3
35.6
97.2
n-propyl bromide
71.0
62.8
79.5
isopropyl bromide
59.8
55.6
89.5
n-propyl iodide
102.4 75.4
56
isopropyl iodide
89.4
71.5
73
methyl iodide
42.6
41.2
96.8
methylene chloride
40.1
39.85
95.0
ethyl bromide
38.0
37.0
97.0
trichloroethylene
87
70.9
73.0
1.197
43.8
96.2
1.517
87.7
0.940
with various other solvents

acetone [4][6]
56.5 C
No azeotrope
methyl ethyl ketone 79.6
73.5
89
0.834
pyridine
92.6
57
1.010
69.3
91.1
U 99.94 U 0.880
L 0.07 L 0.999
benzene
toluene
cyclohexane
115.5
80.2
110.8
80.7
84.1
79.8
U 99.95 U 0.868
L 0.06 L 1.000
69.8
91.5
U 99.99 U 0.780
L 0.01 L 1.00
diethyl ether
34.5
34.2
98.7
tetrahydrofuran[4]
66
65
95
anisole
153.9
95.5
59.5
acetonitrile
82.0
76.5
83.7
chloral
97.75
95.0
hydrazine[7]
113.5 C
120.3 C
0.720

ethylene chloride
83.7
70.5
63
chloroform
61.1
59.4
93
1.403
1.377
trichlorotrifluoroethane
47.7
(CFC 113)
tetrachloroethylene
121.0 76.75
37.0

methyl ethyl ketone
79.6
74.8
60
0.802
93.0
acetonitrile
82.0
72.9
43.0
0.788
68.5
nitromethane
101.3 75.95
26.8
tetrahydrofuran[9]
P = 100 kPa
65.6
65.4
3.3
thiophene[8]
84.1
70.0
55.0
carbon disulfide[5]
46.2
42.4
92
0.818
CRC 44th ed. lists azeotropes for acetic acid/water and acetone/water, Lange's
10th ed. as well as numerous web sources indicate no azeotrope for these pairs.
Azeotropes of allyl alcohol, b.p.=97.0 C
Azeotropes of methanol, b.p.=64.7 C

2/9
9/6/13
2nd Component
b.p. of
b.p. of
% by spef.
comp. (C) mixture (C) weight grav
with various solvents
methyl butyrate
102.7
93.8
45
n-propyl acetate
101.6
94.2
47
benzene
80.2
76.8
82.6
toluene
110.8
92.4
50
cyclohexane
80.8
74
80
72.3
88.5
ethylene chloride
79.9
82
83.7
2nd Component
b.p.
b.p. of
of
% by
mixture
comp.
weight
(C)
(C)
spef.
grav
with various esters

0.874
1.450
methyl acetate
57.0
53.8
81.3
0.908
ethyl acetate
77.1
62.3
56
0.846
ethyl formate
54.1
51.0
84

benzene
80.2
toluene
58.3
60.4
0.844
110.8 63.8
31
0.813
cyclohexane
80.8
54.2
62.8
U 97.0
L 39.0
n-pentane
36.2
30.8
91
n-hexane
68.9
50.6
72
n-heptane
98.5
59.1
48.5
n-octane
125.8 63.0
72.0

ethylene chloride
83.7
61.0
68
chloroform
61.1
53.5
87.4
1.342
carbon tetrachloride
76.8
55.7
79.4
1.322
ethyl bromide
38.4
35.0
95.5
n-propyl chloride
46.6
40.5
90.5
isopropyl chloride
36.4
33.4
94
n-propyl bromide
71.0
54.5
79
isopropyl bromide
59.8
48.6
85.0
isopropyl iodide
89.4
61.0
62
trichloroethylene[5]
87.2
60.2
64
tetrachloroethylene[9] 121.1 63.5
40.6
trichlorotrifluoroethane
47.7
(CFC 113)[5]
94
39.9
Azeotropes of n-propanol,
b.p.=97.2 C
nitromethane
101.2 64.6
acetone
56.5
55.7
87.9
acetonitrile
82.0
63.45
19.0
carbon disulfide
46.2
37.7
86.0
U 50.8 U 0.979
L 97.2 L 1.261
isopropanol[5]
82.5
64.0
20
tetrahydrofuran[10]
P = 984 mBar
65.6
60.7
69.0
0.796
Azeotropes of isopropanol, b.p.=82.5 C
3/9
9/6/13
b.p. of
comp.
(C)
2nd
Component
b.p. of
% by spef.
mixture
weight grav
(C)
2nd Component

methyl
butyrate
102.7
94.4
51
n-propyl
formate
80.8
80.65
97
n-propyl
acetate
101.6
benzene
80.2
77.1
83.1
toluene
110.8
92.4
47.5
n-hexane
68.9
65.7
96
carbon
tetrachloride
76.8
73.1
88.5
ethylene
chloride
83.7
80.7
81
n-propyl
bromide
71.0
69.7
91
b.p.
b.p. of
of
% by spef.
mixture
comp.
weight grav
(C)
(C)
with various esters

ethyl acetate
77.1
75.3
75
0.869
isopropyl acetate
91.0
81.3
40
0.822

94.7
49
0.833
0.836
1.437
benzene
80.2
toluene [8]
71.9
66.7
110.8 80.6
42
cyclohexane
81.0
68.6
67.0
n-pentane
36.2
35.5
94
n-hexane
68.9
62.7
77
n-heptane
98.5
76.3
46
0.838
0.777
Azeotropes of acetic acid,

b.p.=118.5 C
b.p.
b.p. of
of
% by spef.
2nd Component
mixture
comp.
weight grav
(C)
(C)
69.0
82
chloroform
61.1
60.8
95.8
ethylene chloride
83.7
74.7
56.5
ethyl iodide
83.7
67.1
85
n-propyl chloride
46.7
46.4
97.2
n-propyl bromide
71.0
66.8
79.5
isopropyl bromide
59.8
57.8
88
n-propyl iodide
102.4 79.8
58
isopropyl iodide
89.4
68
76.0
tetrachloroethylene[8] 121.1 81.7
1.344
19.0
benzene
80.2
80.05
98
cyclohexane[5]
80.8
79.7
98
toluene
110.8 105.0
72
0.905
m-xylene
139.0 115.4
27.5
0.908
n-heptane
98.5
70
n-octane
125.8 109.0
50
CRC and Lange's disagree on this azeotrope, but web source corroborates
isopropyl iodide
89.2
88.3
91
CRC
carbon
tetrachloride
76.8
76.6
97
92.3
tetrachloroethylene 121.0 107.4
61.5
ethylene bromide
131.7 114.4
45
1,1dibromoethane
109.5 103.7
75.0
methylene bromide 98.2

pyridine
94.8
115.3 139.7
0.882

methyl ethyl ketone
79.0
77.5
68
diisopropyl ether
69
66.2
85.9
nitromethane
101.0 79.3
0.800
70
84.0
65.0
1.024
4/9
9/6/13
Azeotropes of formic acid,

b.p.=100.8 C
b.p. of
comp.
(C)
2nd
Component
b.p. of
% by spef.
mixture
weight grav
(C)
Azeotropes of ethylene glycol,

b.p.=197.4 C
2nd
Component
b.p. of
comp.
(C)
b.p. of
mixture
(C)
% by spef.
weight grav
benzene
80.2
71.7
69
ethyl benzoate 212.6
186.1
53.5
toluene
110.8
85.8
50
diphenyl
254.9
192.0
36
m-xylene
139.0
94.2
29.8
mesitylene
164.6
156.0
87
n-pentane
36.2
34.2
90
naphthalene
218.1
183.9
49
n-hexane
68.9
60.6
72
toluene
110.8
110.2
93.5
n-heptane
98.5
78.2
56.5
m-xylene
139.0
135.6
85
n-octane
125.8
90.5
37
o-xylene
144.4
139.6
84.0
ethylene
bromide
131.7
129.8
96
nitrobenzene
210.9
185.9
41
chlorobenzene 132.0
130.1
5.6

chloroform
61.2
59.2
85
carbon
tetrachloride
76.8
66.7
81.5
methyl iodide
42.6
42.1
94
benzyl chloride 179.3
167.0
70
ethyl bromide
38.4
38.2
97
benzyl alcohol 205.1
193.1
44
ethylene
chloride
83.6
77.4
86
anisole
153.9
150.5
89.5
acetophenone
202.1
185.7
48
ethylene
bromide
131.7
94.7
48.5
aniline
184.4
180.6
76
n-propyl
chloride
o-cresol
191.1
189.6
73
46.7
45.6
92
isopropyl
chloride
34.8
34.7
98.5
n-propyl
bromide
71.0
64.7
73
isopropyl
bromide
59.4
56.0
86

carbon
disulfide
46.3
42.6
Azeotropes of glycerol, b.p.=291.0 C

2nd
Component
b.p. of
comp.
(C)
b.p. of
mixture
(C)
% by spef.
weight grav
diphenyl
254.9
243.8
45
naphthalene
218.1
215.2
90
Azeotropes of acetone, b.p.=56.5 C
83
Azeotropes of benzene, b.p.=80.1 C
5/9
9/6/13
2nd
Component
b.p. of
comp.
(C)
b.p. of
% by spef.
mixture
weight grav
(C)
cyclohexane
81.4
77.8
45.0
ethyl nitrate
88.7
80.03
12.0
methyl ethyl
ketone
79.6
78.4
37.5
nitromethane
101.0
79.15
14.0
acetonitrile
82.0
73.0
34.0
n-heptane[5]
98.5
80.0
b.p. of
2nd Component comp.
(C)
0.834
0.853
b.p. of
% by spef.
mixture
weight grav
(C)
carbon disulfide
46.3
39.3
67.0
1.04
chloroform
61.2
64.7
80.0
1.268
cyclohexane
81.4
53.0
33.0
n-hexane
68.8
49.8
41
ethyl iodide
56.5
55.0
40.0
carbon
tetrachloride[8]
76.8
56.2
11.9
Miscellaneous azeotrope pairs

component 1
acetaldehyde
acetamide
b.p.
comp. 1 (C)
21.0
222.0
b.p.
comp. 2 (C)
b.p.
% wt % wt spec.
azeo. (C) comp. 1 comp. 2 grav.
diethyl ether
34.6
20.5
76.0
24.0
n-butane[8]
0.5
7.0
16.0
84.0
benzaldehyde
179.5
178.6
6.5
93.5
nitrobenzene
210.9
202.0
24.0
76.0
o-xylene
144.1
142.6
11.0
89.0
ethyl acetate
77.15
74.8
23.0
77.0
toluene[9]
110.6
81.1
25.0
75.0
component 2
0.762
acetonitrile
82.0
acetylene
86.6
ethane
88.3
94.5
40.7
59.3
aniline
184.4
o-cresol
191.5
191.3
8.0
92.0
diethyl ether
34.6
34.4
1.0
99.0
1,1-dichloroethane
57.2
46.0
94.0
6.0
methyl ethyl ketone
79.6
45.9
84.7
15.3
ethyl acetate[5]
77.1
46.1
97
methyl acetate[5]
57.0
40.2
73
27
methyl ethyl ketone
79.6
79.9
17.0
83.0
0.877
n-hexane
68.7
60.0
72.0
28.0
1.101
methyl ethyl ketone
79.9
73.8
71.0
29.0
1.247
ethylene dichloride
84.0
75.3
78.0
22.0
1.500
ethyl acetate
77.1
74.8
57.0
43.0
1.202
ethyl acetate
77.15
72.8
46.0
54.0
ethyl nitrate
88.7
74.5
64.0
36.0
methyl formate
31.50
28.2
44.0
56.0
methylene chloride[4] 40
40.8
30
70
toluene
110.8
96.5
55.0
45.0
chloroform
61.2
72.5
34.5
65.5
n-hexane
69
63.0
46.5
53.5
pyridine
115.3
110.2
78.0
22.0
aniline
184.4
179.5
43
57
o-xylene
144.4
135.8
10
90
toluene
110.6
110.5
1.5
98.5
carbon disulfide
chloroform
46.2
61.2
cyclohexane
81.4
diethyl ether
34.6
nitromethane
101.0
tetrahydrofuran[10] 65.6
toluene
propylene glycol[11]
110.63
188.2
0.719
1.157
6/9
9/6/13
Ternary azeotropes
Tables of various ternary azeotropes (that is azeotropes consisting of three components). Fraction percentages are given by weight.
Data source color code
CRC & Lange's CRC only Lange's only other (see references)
Ternary azeotropes of water, b.p.=100 C

2nd component
b.p.
2nd comp. (C)
b.p.
3rd comp. (C)
b.p.
% wt % wt % wt
azeo. (C) 1st
2nd
3rd
ethyl acetate
77.1
70.3 C
7.8
9.0
83.2
cyclohexane
80.8
62.1
17
76
benzene
80.2
64.9
7.4
18.5 74.1
U 1.3 U 12.7 U 86.0 U 0.866
L 43.1 L 52.1 L 4.8 L 0.892
chloroform
61.2
55.5
3.5
4.0
92.5
U 80.8 U 18.2 U 1.0 U 0.976
L 0.5 L 3.7 L 95.8 L 1.441
3rd component
4.3
ethanol
n-propanol
78.4
97.2
86.0
61.8
3.4
10.3 86.3
U 44.5 U 48.5 U 7.0 U 0.935
L <0.1 L 5.2 L 94.8 L 1.519
ethylene chloride
83.7
66.7
17
78
acetonitrile
82.0
72.9
1.0
55.0
44.0
toluene
110.6
74.4
12.0 37.0 51.0

U 3.1 U 15.6 U 81.3 U 0.849
L 20.7 L 54.8 L 24.5 L 0.855
73.2
11.0
n-hexane
69.0
56.0
3.0
12.0 85.0
U 0.5 U 3.0 U 96.5 U 0.672
L 19.0 L 75.0 L 6.0 L 0.833
n-heptane
98.4
68.8
6.1
33.0 60.9
U 0.2 U 5.0 U 94.8 U 0.686
L 15.0 L 75.9 L 9.1 L 0.801
carbon disulfide
46.2
41.3
1.6
5.0
93.4
cyclohexane
80.8
66.6
8.5
10.0
81.5
benzene
80.2
68.5
8.6
9.0
82.4
65.4
5
84
11
U 84.9 U 15.0 U 0.1 U 0.979
L 1.0 L 11.0 L 88.0 L 1.436
diethyl ketone
102.2
81.2
20
20
60
n-propyl acetate
101.6
82.2
21.0
19.5
59.5
cyclohexane
80.8
64.3
7.5
18.5
74.0
66.1
7.5
21.5
71.0
66.5
7.5
18.7
73.8
65.7 C
8.2
19.8 72.0
U 2.3 U 20.2 U 77.5 U 0.855
L 85.1 L 14.4 L 0.5 L 0.966
73.4
11.0
80.2 C
82.5
0.901
benzene
isopropanol
9.7
spec.
grav
14.0
1.0
75.0
88.0
0.832
0.834
7/9
9/6/13
allyl alcohol
benzene
97.0
80.1
110.6
76.3
n-hexane
69.0
59.7
5
5
90
U 0.5 U 3.6 U 95.9 U 0.668
L 64.4 L 34.8 L 0.8 L 0.964
benzene
80.2
68.2
8.6
9.2
82.2
U 0.6 U 8.7 U 90.7 U 0.877
L 80.9 L 17.7 L 0.4 L 0.985
cyclohexane
80.8
66.2
65.2
5
11
84
U 71.7 U 25.6 U 2.7 U 0.777
L 0.8 L 10.1 L 89.1 L 1.464
acetonitrile
66.0
8.2
68.2
8.8
65.1 26.1
U 0.6 U 71.3 U 28.1 U 0.858
L 94.7 L 0.1 L 5.2 L 0.992
65.7
3.0
22.2 74.8
U 94.4 U 5.5 U 0.1 U 0.993
L 0.1 L 22.6 L 77.3 L 1.313
cyclohexane
63.6
5.0
60.0 35.0
U 0.6 U 37.0 U 62.4 U 0.769
L 89.9 L 10.0 L 0.1 L 0.98
82.0
chloroform
61.2
13.1 38.2 48.7

U 8.5 U 38.2 U 53.3 U 0.845
L 61.0 L 38.0 L 1.0 L 0.930
toluene
81.0
11
68.5
81
23.3
methanol
64.65
52.6
81.0 15.0
4.0
U 27.0 U 32.0 U 41.0 U 1.022
L 3.0 L 83.0 L 14.0 L 1.399
acetone
56.5
60.4
4.0
57.6
38.4
Saddle azeotrope
Ternary azeotropes of methanol, b.p.=64.65 C

2nd component
acetone
methyl acetate
b.p.
b.p.
3rd component
2nd comp. (C)
3rd comp. (C)
56.5
57.1
b.p.
% wt % wt % wt spec.
azeo. (C) 1st 2nd 3rd grav
chloroform
61.2
57.5
23.0
30.0
47.0
methyl acetate
57.0
53.7
17.4
5.8
76.8
cyclohexane
81.4
51.5
16.0
43.5
40.5
carbon disulfide 46.2
37.0
cyclohexane
81.4
50.8
17.8
48.6
33.6
n-hexane
69.0
45.0
14.0
27.0
59.0
0.898
0.73
Saddle azeotrope
References
1. ^ Lange's Handbook of Chemistry, 10th ed. pp1496-1505
2. ^ CRC Handbook of Chemistry and Physics, 44th ed. pp 2143-2184
3. ^ Lee H. Horsley, ed. (1 June 1973). Azeotropic DataIII (http://pubs.acs.org/isbn/9780841201668). Advances in Chemistry Series No.
166. AMERICAN CHEMICAL SOCIETY. ISBN 9780841201668.
4. ^ a b c d e "What is an Azeotrope?" (http://www.solvent--recycling.com/azeotrope_1.html). B/R Corporation. Archived
(http://web.archive.org/web/20070424141816/http://www.solvent--recycling.com/azeotrope_1.html) from the original on 24 April 2007.
Retrieved 24 March 2007.
5. ^ a b c d e f g h i j k l John Durkee (November 2000). "Binary Organic Azeotropes Useful for Solvent Cleaning"
(http://www.metalfinishing.com/_virtual/article-downloads/Table%201_a2648.pdf). metalfinishing.com. Retrieved 13 February 2011.
8/9
9/6/13
6. ^ a b Hilmen, Eva-Katrine (November 2000). "Separation of Azeotropic Mixtures: Tools for Analysis and Studies on Batch Distillation
Operation" (http://www.chemeng.ntnu.no/thesis/download/2000/hilmen/Thesis_Hilmen.pdf). Norwegian University of Science and
Technology, dept. of Chemical Engineering. Retrieved 24 March 2007.
7. ^ Merck Index of Chemicals and Drugs, 9th ed. monograph 4653
8. ^ a b c d e f Ponton, Jack (September 2001). "Azeotrope Databank" (http://eweb.chemeng.ed.ac.uk/chem_eng/azeotrope_bank.html)
(Queriable database). The Edinburgh Collection of Open Software for Simulation and Education, Edinburgh University. Archived
(http://web.archive.org/web/20070424062750/http://eweb.chemeng.ed.ac.uk/chem_eng/azeotrope_bank.html) from the original on 24 April
2007. Retrieved 24 March 2007.
9. ^ a b c "Binary Vapor-Liquid Equilibrium Data" (http://www.cheric.org/research/kdb/hcvle/hcvle.php) (Queriable database). Chemical
Engineering Research Information Center.
10. ^ a b "Tetrahydrafuran (THF) Storage and Handling" (http://www.basf.com/diols/pdfs/thf_brochure.pdf). BASF. Retrieved 24 May 2007.
11. ^ "1,2-Propanediol" (http://chemindustry.ru/1,2-Propanediol.php). ChemIndustry.ru. Archived
(http://web.archive.org/web/20071221191626/http://chemindustry.ru/1,2-Propanediol.php) from the original on 21 December 2007.
Retrieved 2007-12-28.
Retrieved from "http://en.wikipedia.org/w/index.php?title=Azeotrope_(data)&oldid=561964023"

Categories: Chemistry-related lists Thermodynamics Science-related lists Phase transitions Separation processes
This page was last modified on 28 June 2013 at 13:27.
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Azeotrope (data) - Wikipedia, the free encyclopedia

Azeotropes of water, b.p.=100 C

Azeotropes of ethanol, b.p.=78.4 C

with various alcohols

with various organic acids

with mineral acids

Azeotrope (data) - Wikipedia, the free encyclopedia

propylene chloride 96.8

carbon tetrachloride 76.8

methylene chloride 40.0

with various esters

with various alkyl halides

with various hydrocarbons

with various esters

n-propyl acetate[5] 101.6

with various other solvents

methyl ethyl ketone 79.6

with various alkyl halides

with various other solvents

Azeotropes of allyl alcohol, b.p.=97.0 C

Azeotropes of methanol, b.p.=64.7 C

Azeotrope (data) - Wikipedia, the free encyclopedia

carbon tetrachloride 76.8

with various esters

with various hydrocarbons

with various alkyl halides

tetrachloroethylene[9] 121.1 63.5

with various other solvents

Azeotropes of isopropanol, b.p.=82.5 C

Azeotrope (data) - Wikipedia, the free encyclopedia

with various solvents

with various esters

with various hydrocarbons

with various alkyl halides

Azeotropes of acetic acid,

tetrachloroethylene[8] 121.1 81.7

tetrachloroethylene 121.0 107.4

methylene bromide 98.2

carbon tetrachloride 76.8

with various other solvents

Azeotrope (data) - Wikipedia, the free encyclopedia

Azeotropes of formic acid,

Azeotropes of ethylene glycol,

with various hydrocarbons

with various solvents

ethyl benzoate 212.6

with various alkyl halides

benzyl chloride 179.3

benzyl alcohol 205.1

with various other solvents

Azeotropes of glycerol, b.p.=291.0 C

Azeotropes of acetone, b.p.=56.5 C

Azeotropes of benzene, b.p.=80.1 C

Azeotrope (data) - Wikipedia, the free encyclopedia

Miscellaneous azeotrope pairs

methyl ethyl ketone

methyl ethyl ketone

methyl ethyl ketone

carbon tetrachloride 76.8

Azeotrope (data) - Wikipedia, the free encyclopedia

Ternary azeotropes of water, b.p.=100 C

12.0 37.0 51.0

methyl ethyl ketone 79.6