Page 1/5

Mat er i al Saf et y Dat a Sheet

acc. t o OSHA and ANSI
Printing date 12/19/2007 Reviewed on 01/24/2007
DR
1 I dent i f i cat i on of subst ance:
Pr oduct det ai l s:
Pr oduct name: Sodi umhydr ogen phosphat e
St ock number : 11592
Manuf act ur er / Suppl i er :
Alfa Aesar, A Johnson Matthey Company
Johnson Matthey Catalog Company, Inc.
30 Bond Street
Ward Hill, MA 01835-8099
Emergency Phone: (978) 521-6300
CHEMTREC: (800) 424-9300
Web Site: www.alfa.com
I nf or mat i on Depar t ment : Health, Safety and Environmental Department
Emer gency i nf or mat i on:
During normal hours the Health, Safety and Environmental Department.
After normal hours call Chemtrec at (800) 424-9300.
2 Composi t i on/ Dat a on component s:
Chemi cal char act er i zat i on:
Descr i pt i on: ( CAS#)
Sodium hydrogen phosphate, heptahydrate
(CAS# 7782-85-6), 100%
I dent i f i cat i on number ( s) :
EI NECS Number : 231-448-7
3 Hazar ds i dent i f i cat i on
Hazar d descr i pt i on:
Xi Irritant
I nf or mat i on per t ai ni ng t o par t i cul ar danger s f or man and envi r onment
R 36/37/38 Irritating to eyes, respiratory system and skin.
Cl assi f i cat i on syst em
HMI S r at i ngs ( scal e 0- 4)
( Hazar dous Mat er i al s I dent i f i cat i on Syst em)
HEALTH
FIRE
REACTIVITY
1
0
1
Health (acute effects) = 1
Flammability = 0
Reactivity = 1
4 Fi r st ai d measur es
Af t er i nhal at i on
Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
Af t er ski n cont act
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
Af t er eye cont act
Rinse opened eye for several minutes under running water. Then consult a
doctor.
(Contd. on page 2)
USA
Page 2/5
Mat er i al Saf et y Dat a Sheet
acc. t o OSHA and ANSI
Printing date 12/19/2007 Reviewed on 01/24/2007
Pr oduct name: Sodi umhydr ogen phosphat e
(Contd. of page 1)
DR
Af t er swal l owi ng Seek immediate medical advice.
I nf or mat i on f or doct or
The f ol l owi ng sympt oms may occur :
Nausea
Gastric or intestinal disorders.
5 Fi r e f i ght i ng measur es
Sui t abl e ext i ngui shi ng agent s
Product is not flammable. Use fire fighting measures that suit the
surrounding fire.
Speci al hazar ds caused by t he mat er i al , i t s pr oduct s of combust i on or
r esul t i ng gases:
In case of fire, the following can be released:
Phosphorus oxides
Pr ot ect i ve equi pment :
Wear self-contained respirator.
Wear fully protective impervious suit.
6 Acci dent al r el ease measur es
Per son- r el at ed saf et y pr ecaut i ons:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Measur es f or envi r onment al pr ot ect i on:
Do not allow material to be released to the environment without proper
governmental permits.
Measur es f or cl eani ng/ col l ect i ng: Ensure adequate ventilation.
Addi t i onal i nf or mat i on:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handl i ng and st or age
Handl i ng
I nf or mat i on f or saf e handl i ng:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
I nf or mat i on about pr ot ect i on agai nst expl osi ons and f i r es:
The product is not flammable
St or age
Requi r ement s t o be met by st or er ooms and r ecept acl es:
No special requirements.
I nf or mat i on about st or age i n one common st or age f aci l i t y:
Do not store together with acids.
Store away from water/moisture.
Fur t her i nf or mat i on about st or age condi t i ons:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
USA
(Contd. on page 3)
Page 3/5
Mat er i al Saf et y Dat a Sheet
acc. t o OSHA and ANSI
Printing date 12/19/2007 Reviewed on 01/24/2007
Pr oduct name: Sodi umhydr ogen phosphat e
(Contd. of page 2)
DR
8 Exposur e cont r ol s and per sonal pr ot ect i on
Addi t i onal i nf or mat i on about desi gn of t echni cal syst ems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Component s wi t h l i mi t val ues t hat r equi r e moni t or i ng at t he wor kpl ace:
Not required.
Addi t i onal i nf or mat i on: No data
Per sonal pr ot ect i ve equi pment
Gener al pr ot ect i ve and hygi eni c measur es
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Br eat hi ng equi pment :
Use suitable respirator when high concentrations are present.
Pr ot ect i on of hands: Impervious gloves
Eye pr ot ect i on: Safety glasses
Body pr ot ect i on: Protective work clothing.
9 Physi cal and chemi cal pr oper t i es:
Gener al I nf or mat i on
For m: Crystalline
Col or : White
Odor : Odorless
Change i n condi t i on
Mel t i ng poi nt / Mel t i ng r ange: 48.1C (119F) ((-5H2O))
Boi l i ng poi nt / Boi l i ng r ange: Not determined
Subl i mat i on t emper at ur e / st ar t : Not determined
Fl ash poi nt : Not applicable
I gni t i on t emper at ur e: Not determined
Decomposi t i on t emper at ur e: Not determined
Danger of expl osi on: Product does not present an
explosion hazard.
Expl osi on l i mi t s:
Lower : Not determined
Upper : Not determined
Vapor pr essur e: Not determined
Densi t y at 20C ( 68F) : 1.679 g/cm
Sol ubi l i t y i n / Mi sci bi l i t y wi t h
Wat er at 40C ( 104F) : 1040 g/l
10 St abi l i t y and r eact i vi t y
Ther mal decomposi t i on / condi t i ons t o be avoi ded:
Decomposition will not occur if used and stored according to
specifications.
(Contd. on page 4)
USA
Page 4/5
Mat er i al Saf et y Dat a Sheet
acc. t o OSHA and ANSI
Printing date 12/19/2007 Reviewed on 01/24/2007
Pr oduct name: Sodi umhydr ogen phosphat e
(Contd. of page 3)
DR
Mat er i al s t o be avoi ded: Acids
Danger ous r eact i ons No dangerous reactions known
Danger ous pr oduct s of decomposi t i on: Phosphorus oxides (e.g. P2O5)
11 Toxi col ogi cal i nf or mat i on
Acut e t oxi ci t y:
LD/ LC50 val ues t hat ar e r el evant f or cl assi f i cat i on:
Oral LD50 12930 mg/kg (rat)
Pr i mar y i r r i t ant ef f ect :
on t he ski n: Irritant to skin and mucous membranes.
on t he eye: Irritating effect.
Sensi t i zat i on: No sensitizing effects known.
Subacut e t o chr oni c t oxi ci t y:
Inorganic phosphorus compounds may cause irritation and hemorrhages in
the stomach as well as liver and kidney damage. Bone structure may be
attacked, especially the jaw and teeth.
Addi t i onal t oxi col ogi cal i nf or mat i on:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecol ogi cal i nf or mat i on:
Gener al not es:
Do not allow undiluted product or large quantities of it to reach ground
water, water course or sewage system.
Do not allow material to be released to the environment without proper
governmental permits.
13 Di sposal consi der at i ons
Pr oduct :
Recommendat i on
Consult state, local or national regulations to ensure proper disposal.
Uncl eaned packagi ngs:
Recommendat i on: Disposal must be made according to official regulations.
14 Tr anspor t i nf or mat i on
Not a hazardous material for transportation.
DOT r egul at i ons:
Hazar d cl ass: None
Land t r anspor t ADR/ RI D ( cr oss- bor der )
ADR/ RI D cl ass: None
Mar i t i me t r anspor t I MDG:
I MDG Cl ass: None
Ai r t r anspor t I CAO- TI and I ATA- DGR:
I CAO/ I ATA Cl ass: None
(Contd. on page 5)
USA
Page 5/5
Mat er i al Saf et y Dat a Sheet
acc. t o OSHA and ANSI
Printing date 12/19/2007 Reviewed on 01/24/2007
Pr oduct name: Sodi umhydr ogen phosphat e
(Contd. of page 4)
DR
Tr anspor t / Addi t i onal i nf or mat i on:
Not dangerous according to the above specifications.
15 Regul at i ons
Pr oduct r el at ed hazar d i nf or mat i ons:
Hazar d symbol s:
Xi Irritant
Ri sk phr ases:
36/37/38 Irritating to eyes, respiratory system and skin.
Saf et y phr ases:
26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
Nat i onal r egul at i ons
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
I nf or mat i on about l i mi t at i on of use:
For use only by technically qualified individuals.
16 Ot her i nf or mat i on:
Employers should use this information only as a supplement to other
information gathered by them, and should make independent judgement of
suitability of this information to ensure proper use and protect the
health and safety of employees. This information is furnished without
warranty, and any use of the product not in conformance with this
Material Safety Data Sheet, or in combination with any other product or
process, is the responsibility of the user.
Depar t ment i ssui ng MSDS: Health, Safety and Environmental Department.
Cont act : Paul V. Connolly
USA