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9031-9422(94)00493-5
Phymchem~rry,
COMPILATION
Indian Institute of Chemical Biology, 4 Raja S.C. Mullick Road, Jadavpur, Calcutta 700032, India
(Received31 May 1994)
Key Word Inde~--~C NMR da&g pentacyclic triterpenoids; signal assigmnent techniques; substituent effects.
Abstract-A compilation of the C NMR data of a selected variety of naturally occurring pentacyclic triterpenoids,
arranged skeletonwise, is provided. A brief account
of the newer signal assignment techniques and a discussion on the
substituent effects on the i3C shieldings of the triterpenoids, are also included.
1518
S.
B. MAHATO and
2D-NMR Spectroscopy
The above mentioned techniques are found to be inadequate for unambiguous assignment of the 13C resonances of compounds possessing complex structural features. In such cases, 2D-NMR techniques provide a useful solution to the problem. ZD-NMR techniques have
been reviewed in several monographs [12-171. There are
many variants for the techniques of 2D-NMR and it is
rather difficult to keep abreast with the acronyms of so
many variants. However, it is perhaps pertinent to mention that no new interactions or parameters are involved
in the newer techniques and the increase in experimental
complexity stems rather from instrumental developments
and from the necessity to interpret the spectra of increasingly complex samples. Sensitivity problems are inherent
in NMR spectroscopy and acceptability of a technique
largely depends on its sensitivity and the minimum time
requirement. A few of the techniques e.g. J-resolved experiment [IS, 191, SECSY (spin echo correlated spectroscopy) [20] are now rarely used, because of their limited
sensitivity. The techniques and their applications which
are useful today and have the potential of being used
tomorrow are briefly dealt with in the following paragraphs.
Homonuclear correlation spectroscopy. Homonuclear
H-HCOSY [21] is now one of the most widely used
2D-NMR experiments for H assignment. Once the definitive H NMR assignments are achieved by homonuclear COSY or its variants, these can be correlated via
H-13C COSY spectrum to assign 13C signals. As such,
H-HCOSY not only provides information for unambiguous HNMR
assignments
but also helps in
13CNMR assignments. The phase sensitive COSY (PS-
A. P. KUNDU
1520
S. B. MAHATO
and A. P. KUNDU
The techniques of HMQC and HMBC were successfully used for elucidation of the structure of stelliferin A,
a new isomalabaricane triterpene by Tsuda et al. [31].
Fame et al. [58] employed HMQC and HMBC experiments for complete i3C signal assignments of isomultiflorenyl acetate (159). Carbon-hydrogen
pairings of the
methyl groups were readily determined from an HMQC
contour plot. The structure of abrisapogenol G (106),
a triterpenoid sapogenol isolated from Abrus precatorious, has been established by the use of HMBC specrroscopy [59]. The HMBC NMR spectroscopy was successfully used to elucidate the structure of chiratenol (364),
a novel triterpene possessing a rearranged hopane skeleton 160-J The two- and three-bond correlation between
methyl protons and carbon of the ketone of chiratenol
led to the elucidation of the structure 364. Three
friedelane triterpenes isolated from the stem-bark of
Caloncoba glauca were characterized as trichadonic acid
(195X caloncobalactone
(174) and 21/I-hydroxycaloncobalactone (175) by considerable use of long-range C-H
coupling studies [61]. For example, the methyl doublet
of trichadonic acid (195) was found by means of the
proton detected direct C-H coupling (HMQC) study, to
be highly shielded, which is typical for the 23-Me reson-
ance of a 3-oxo-friedelane. Assuming this resonance assignable to C23, the application of the HMBC technique
led to the elucidation of the structure and 13C assignments of the triterpene (1%) by identifying J and 3J
connectivities associated with the methyl proton resonances. Thus HMBC, using the protons from only the
seven methyl resonances, allows unambiguous assignment of C3, C4, C5, C6, C8, C9, ClO, Cll, C13, C14, C15,
C17, C18, C20 and C23 to C30 of the triterpene (195) and
assignment of C19/C21 and C16/C22 without distinguishing between these pairs. Parsons et al. [62] described the assignments of different H and C signals
using HMBC experiments for the elucidation of the
structure of D-friedoolean-14-ene-38,7a-diol (152).
The hybrid methods e.g. HMQC-COSY [63, 641,
HMQC-TOCSY
[65] and HMQC-NOESY
[66] are
powerful alternatives for obtaining further connectivity
information, specially when the H spectrum is highly
congested. The application of these techniques in the field
of triterpenoid is still very limited.
Ont dimensional analogues of proton detected ZD-NMR
experiments. The 2D-NMR experiments usually yield
some information which is not always required. In such
cases, selective 1D analogues of the 2D experiments
would be highly desirable. Two such techniques are selective inverse correlation (SELINCOR) reported by .Berger
1671 and selective one dimensional HMQC-TOCSY
[68]. A selective inverse multiple bond analysis (SIMBA)
which is a 1D analogue of the 2D HMBC experiment has
recently been described by Crouch and Martin [69]. The
authors are of the opinion that the future for application
of 1D analogues of ZD-NMR experiments is quite bright,
as they can provide vital structural information with
minimum investment in time, compared to the acquisition of full 2D-NMR experiments.
C NMBSHIELDINGDATAOF PENTACYCLIC
TEITEEPENES
ANDSUESTITUENTEFFECTS
13CNMR shielding data of a large number of pentacyclic triterpenes have been published. A compilation
of the 13CNMR data of selected varieties of naturally
occurring pentacyclic triterpenes is given in Table 1. The
triterpenes have been arranged skeletonwise and according to increasing number of hydroxy substituents. The
olean-12-enes have been listed first, followed *by oleanenes with other double bonds and more than one
double bond, friedooleananes, urs- 12-enes, Ursa-dienes,
taraxastanes, pseudotaraxastanes,
friedoursanes, gammaceranes, serratanes, swertanes, kairatane, stictanes,
flavicanes, lupanes, hopanes, fernanes, adiananes, arboranes, bicadinane, friedomadeiranes and pachanane.
Hydroxyl substituent eflects
Inspection of the C data of various mono- and polyhydroxy triterpenes (Table l), reveals that introduction
of a hydroxyl group results in downfield shifts of
34-50 ppm for cc-carbons and 2-10 ppm for p-carbons
and upfield shifts of O-9 ppm for y-carbons. These values
1521
1522
4P
38.7
27.3
79.0
38.8
55.3
18.5
32.8
38.8
47.7
37.6
23.6
121.8
145.1
41.8
26.2
27.0
32.5
47.4
46.9
31.1
34.8
37.2
28.2
15.5
15.6
16.9
26.0
28.4
33.3
23.7
[ 1131
38.5
27.4
78.1
38.7
55.2
18.3
32.6
39.3
47.6
37.0
23.1
122.1
143.4
41.6
27.7
23.4
46.6
41.3
45.8
30.6
33.8
32.3
28.1
15.6
15.3
16.8
26.0
181.0
33.1
23.6
39.1
34.1
217.6
47.4
55.3
19.6
32.2
39.3
46.0
36.7
23.0
122.1
143.8
41.8
21.7
23.5
46.7
41.4
45.8
30.6
33.8
32.3
26.4
21.4
14.9
16.7
25.8
33.0
23.6
36.Y
27.8
78.8
40.2
55.5
18.3
33.5
37.3
49.2
38.8
23.0
125.5
137.5
56.1
22.3
21.3
32.9
47.5
44.0
30.9
34.3
36.8
28.3
15.7
16.4
18.1
176.1
28.2
33.2
23.5
36.7
27.6
76.4
39.9
48.8
18.0
32.9
36.7
48.8
36.7
23.6
126.0
137.6
56.0
22.7
26.2
32.9
47.0
44.2
31.0
34.2
36.2
28.2
22.1
15.8
18.0
179.0
28.2
32.9
23.6
38.4
23.6
81.1
37.8
55.4
18.3
32.7
39.9
47.6
37.0
23.6
123.0
144.4
41.7
26.6
27.0
32.5
46.1
40.6
42.8
29.1
36.0
28.3
16.8
15.6
16.8
26.0
28.2
179.6
19.4
38.6
27.2
78.8
38.6
55.1
18.4
32.7
39.7
47.6
36.9
23.4
122.2
143.9
41.5
26.1
27.0
31.9
48.1
42.8
44.1
31.3
38.3
28.1
15.3
15.5
16.8
25.9
28.1
28.4
176.9
38.8
27.2
78.6
38.7
55.2
18.3
33.1
39.5
47.2
36.8
23.2
117.2
141.5
43.6
26.3
38.1
34.9
39.3
36.0
42.8
32.4
28.7
28.1
15.2
15.7
15.8
23.2
17.4
20.9
178.7
38.4
27.0
71.6
56.2
48.0
21.0
32.5
40.0
47.7
36.2
23.8
122.2
144.8
42.2
28.2
23.8
46.6
41.9
46.5
30.9
34.2
23.1
207.1
9.6
15.7
17.3
26.1
180.0
33.2
23.8
Cl141
Cl151
Cl161
Cl161
Cl171
C761
C761
Cl 181
1523
Table 1. Continued
10
11
12p
13
14p
15
16
17
18
19p
2op
21P
36.7
27.5
76.0
39.6
48.5
18.0
32.9
36.7
46.8
37.0
22.6
126.8
136.1
55.6
21.8
25.3
32.7
47.1
35.1
46.6
24.6
34.6
28.0
21.9
15.8
17:7
178.5
28.0
206.0
15.8
36.2
27.3
75.8
39.9
48.5
18.0
32.7
37.0
47.9
37.0
22.5
126.8
135.8
55.5
21.7
25.2
32.7
46.4
38.1
42.0
21.2
35.1
28.2
22.3
16.1
17.9
185.5
27.8
183.0
19.3
37.6
26.2
74.0
53.0
50.5
20.2
31.5
38.6
46.9
35.3
22.3
122.4
143.3
40.7
26.8
22.2
45.1
40.5
45.0
29.5
32.7
31.5
179.2
10.7
14.5
15.9
24.7
178.7
31.8
22.3
39.2
25.3
77.8
39.1
55.7
18.7
37.4
39.8
47.5
37.3
23.4
125.9
138.1
56.5
28.1
24.9
47.7
44.2
44.0
30.9
34.0
32.8
28.5
16.5
16.4
18.7
178.5
180.2
33.1
23.1
38.9
28.0
78.1
39.4
55.8
18.8
33.2
39.7
48.0
37.4
23.8
122.2
144.3
42.5
28.3
23.8
46.6
41.1
41.1
42.2
29.4
32.4
28.3
16.6
15.5
17.4
26.1
180.0
181.2
20.0
38.4
27.1
78.1
38.7
55.2
18.3
32.6
39.2
47.5
36.9
23.3
122.9
142.9
41.4
27.6
23.3
46.0
42.5
42.0
43.6
30.3
33.4
27.9
15.6
15.3
16.7
25.9
176.4
28.1
177.3
39.5
27.4
78.7
39.0
55.1
18.4
32.9
43.3
49.7
31.9
81.7
121.2
153.2
41.8
26.4
27.4
32.3
46.9
46.9
31.2
34.7
31.0
28.0
15.5
18.3
16.8
24.1
28.5
33.3
23.1
38.7
27.2
78.8
38.7
54.8
18.6
36.8
41.1
47.7
37.0
23.6
123.0
146.1
47.4
68.2
36.0
33.0
47.6
46.2
31.0
34.6
37.4
28.1
15.6
15.6
17.5
20.2
28.9
33.3
23.6
38.5
27.1
78.8
38.7
55.1
18.2
32.6
39.8
46.8
37.2
23.4
122.2
143.4
43.7
35.5
65.9
36.8
49.0
46.5
30.8
34.1
30.5
28.0
15.4
15.3
16.7
27.0
21.3
33.1
23.8
39.2
28.2
78.1
39.4
55.9
18.9
33.3
40.1
48.1
37.3
23.9
122.5
144.9
42.5
26.5
28.7
38.0
45.4
46.9
30.9
42.3
75.6
28.8
15.9
16.6
17.3
25.8
28.8
33.3
21.2
39.1
28.1
78.0
39.4
55.7
18.7
32.9
39.9
47.8
31.2
23.9
124.9
141.1
42.0
25.3
21.3
48.2
46.7
41.1
44.4
45.9
214.1
28.7
15.6
16.6
16.9
25.4
21.3
176.6
20.9
39.1
28.1
78.0
39.4
55.1
18.7
33.0
39.9
47.9
31.2
23.8
124.7
141.5
42.0
25.3
28.1
47.5
48.5
44.1
45.7
46.8
213.0
28.7
15.8
16.6
16.9
25.3
21.3
26.2
176.8
Cl161
Cl161
Cl191
cw
Cl211
Cl221
~1231
cl241
cl251
Cl261
~1271
~1271
PHYTO
37-6-D
1524
Table 1.
Continued
22
23
24
25
26p
27
28
29
30
31
38.3
21.6
80.7
42.1
55.8
18.4
32.9
39.8
47.7
36.7
23.8
121.6
-145.2
41.7
26.9
26.1
32.5
47.2
46.8
31.1
34.7
37.1
22.4
64.4
16.1
16.7
26.0
28.4
33.3
23.1
38.6
27.2
79.0
38.8
55.2
18.4
32.6
39.8
47.6
36.9
23.6
122.3
144.2
41.7
25.6
22.0
36.9
42.3
46.5
31.0
34.1
31.0
28.1
15.5
15.5
16.7
25.9
69.7
33.2
23.6
38.5
27.2
78.8
38.7
55.1
18.4
32.7
39.7
47.6
36.8
23.5
122.1
144.4
41.7
26.1
27.3
32.4
46.7
41.9
35.5
29.6
36.5
28.1
15.5
15.5
16.8
25.9
28.1
29.6
66.6
38.2
27.3
78.8
38.7
55.2
18.3
34.1
39.5
47.2
36.8
23.1
116.9
141.9
43.6
26.3
38.8
35.0
39.6
36.3
36.2
32.3
28.5
28.1
15.2
15.7
15.8
23.1
17.4
20.6
74.9
38.9
28.4
80.1
43.2
56.4
19.1
33.6
39.8
48.1
37.1
24.1
123.7
142.8
42.8
25.7
26.5
38.6
45.2
46.1
40.0
39.3
85.8
23.6
64.6
16.2
17.0
25.1
23.5
72.6
76.4
72.8
35.9
71.9
40.1
48.6
17.4
33.0
39.8
38.4
42.7
23.8
123.7
144.7
41.7
26.7
27.5
33.0
46.8
41.8
43.0
30.0
36.7
28.6
16.8
16.6
16.6
26.3
29.0
181.4
18.9
46.4
68.8
83.8
39.1
55.3
18.3
32.6
39.1
47.5
38.3
23.1
122.0
143.6
41.7
27.6
23.5
46.6
41.3
45.8
30.7
33.8
32.3
28.6
16.8
16.8
16.8
26.0
178.0
33.1
23.5
41.7
66.5
78.9
38.5
48.1
18.1
32.5
39.7
47.4
38.3
23.2
122.1
143.8
41.9
27.7
23.2
46.8
41.3
46.0
30.7
34.0
32.5
28.5
21.9
16.4
17.0
26.2
178.1
33.2
23.6
40.6
27.4
79.1
39.5
55.6
68.7
40.7
38.6
47.9
36.5
23.3
122.7
142.9
42.2
27.7
23.0
46.7
41.3
45.8
30.7
33.9
32.4
27.9
17.0
16.8
18.2
26.0
178.2
33.1
23.6
35.2
25.1
77.4
38.1
49.1
68.9
40.5
38.5
47.5
36.6
23.1
122.7
142.8
42.2
27.5
23.0
46.7
41.2
45.8
30.7
33.8
32.3
28.3
24.4
16.5
18.1
26.1
178.3
33.1
23.6
cl241
WI
C761
cl291
Cl301
Cl311
cl321
I91
c501
C761
1525
Table 1. Continued
32
33p
38.9
28.0
78.0
39.3
55.8
18.8
33.3
39.8
47.2
37.3
23.7
122.4
144.9
42.0
36.0
74.6
48.8
41.3
47.2
30.9
36.0
32.7
28.7
16.5
15.6
17.4
27.1
179.8
33.5
24.7
38.8
28.1
78.2
39.4
56.0
19.0
33.3
40.0
48.3
37.5
24.1
123.8
144.3
42.0
29.0
28.1
46.4
44.7
81.0
35.6
29.0
33.3
28.8
16.5
15.5
17.3
24.7
178.7
28.8
24.9
Cl341
Cl311
41
35
36p
37
3&v
39e
40
38.6
27.1
77.8
38.6
55.3
18.3
32.8
39.1
47.5
36.9
23.3
122.1
143.8
41.8
27.9
26.4
46.6
41.2
40.8
35.0
72.9
39.0
28.3
15.9
15.3
16.8
27.6
177.6
25.3
24.8
38.4
27.0
76.9
38.4
54.9
18.0
32.3
38.9
47.2
36.6
23.0
122.1
142.7
41.3
27.3
24.0
47.9
40.6
46.2
35.7
70.8
40.6
28.2
16.0
15.1
16.6
25.5
176.1
29.1
17.1
39.2
28.8
78.1
39.4
55.8
18.8
33.2
40.1
48.1
37.3
23.9
123.0
144.1
42.4
26.4
28.5
37.9
44.3
41.1
42.7
37.3
75.0
28.2
15.9
16.6
17.2
25.7
21.0
18.8
38.9
27.6
73.7
42.9
48.8
18.7
33.6
39.8
48.2
37.3
23.8
122.7
145.0
42.2
28.4
23.8
46.7
42.0
46.5
31.0
34.3
33.3
68.2
13.1
16.0
17.5
26.2
180.4
33.3
23.8
38.8
28.5
80.3
43.3
56.5
19.1
33.6
39.8
48.3
37.3
24.1
122.7
145.1
42.2
28.5
23.8
46.8
42.1
46.6
31.0
34.3
33.3
23.7
64.6
16.0
17.3
26.2
180.4
33.3
23.8
33.9
26.4
70.0
43.9
50.1
19.1
33.6
39.9
48.1
37.5
24.0
123.0
144.1
42.0
28.1
23.5
47.0
41.9
46.1
30.8
34.0
32.8
23.4
65.8
15.9
17.1
26.1
177.9
33.1
23.7
33.6
27.5
78.8
38.5
55.1
17.8
32.7
39.3
48.2
41.1
22.9
122.7
143.3
41.6
28.0
24.8
46.5
41.1
45.7
30.4
33.1
32.2
28.6
15.6
61.0
17.0
26.1
178.1
32.9
23.3
38.1
27.1
78.8
38.7
54.8
18.2
32.4
39.7
48.3
37.1
24.1
129.7
137.7
47.5
24.5
22.4
46.0
40.4
44.9
30.7
33.4
32.3
28.0
15.7
15.5
18.5
63.0
183.0
33.0
23.8
Cl351
Cl361
Cl371
Cl381
Cl381
Cl391
Cl361
Cl141
34
S. B. MAHATO and A. P.
1526
KIJNDU
Table 1. Continued
SOD
51p
52
53p
39.0
27.7
74.0
43.0
49.1
18.8
33.2
40.0
48.4
37.4
24.0
123.4
144.6
42.3
28.6
24.0
46.4
43.5
43.0
44.3
31.1
34.6
68.4
13.1
16.1
17.6
26.3
179.8
28.6
177.3
33.2
25.3
70.6
42.7
49.6
18.7
33.0
40.0
47.1
36.9
23.7
122.4
143.9
41.2
27.8
23.2
45.9
42.7
41.3
44.0
30.6
33.6
21.7
66.5
15.6
16.7
25.4
178.9
27.9
176.5
38.6
28.0
78.0
39.4
55.9
18.9
32.8
39.8
47.8
37.6
23.8
122.4
141.1
42.2
24.0
26.6
44.1
40.2
30.2
38.6
80.4
36.6
28.6
16.4
15.6
16.3
23.5
181.9
22.1
68.0
33.0
27.4
78.2
39.0
48.3
18.5
30.5
46.9
79.0
44.8
67.2
123.2
149.0
43.3
27.7
26.8
32.9
46.8
45.3
31.0
34.8
36.9
28.2
15.5
20.2
19.6
27.6
28.7
33.3
23.6
39.1
28.5
80.2
43.2
56.2
19.5
37.2
41.6
48.3
37.1
24.3
123.7
146.9
48.2
66.9
37.1
33.3
48.3
46.7
31.2
34.9
38.7
23.8
64.7
16.4
17.7
20.9
21.3
33.5
23.6
Cl451
Cl391
Cl461
Cl471
El241
42p
43
44
45
46
41P
48p
49p
38.9
28.1
78.1
39.4
55.9
18.8
33.3
39.8
48.2
37.4
23.8
122.5
144.9
42.2
28.2
23.8
47.2
41.4
41.4
36.6
29.1
32.1
28.8
16.5
15.5
17.4
26.2
180.2
73.9
19.8
35.7
27.6
73.6
39.3
48.0
18.0
32.9
36.7
48.0
36.8
23.6
124.8
137.5
55.3
22.7
26.2
32.9
46.3
40.5
35.7
29.0
38.7
28.0
22.2
15.9
17.7
176.9
28.5
73.1
19.0
38.7
27.0
78.9
38.7
55.3
18.5
32.8
39.3
47.7
37.2
23.4
122.8
143.2
41.7
27.7
23.4
46.8
40.3
40.3
35.2
32.8
32.1
28.1
15.7
15.4
16.9
26.0
178.5
28.9
65.8
38.9
27.2
78.0
39.3
56.0
18.7
32.6
40.4
47.4
37.3
23.8
124.6
140.2
43.4
38.0
66.6
49.9
41.7
42.8
34.1
83.4
28.0
28.6
15.7
16.3
16.4
28.6
181.0
28.7
24.3
38.1
26.0
71.7
55.2
48.1
20.7
32.3
39.7
46.7
35.9
23.2
122.2
142.8
41.7
35.4
74.7
48.7
40.5
46.4
30.3
35.4
30.3
207.0
9.0
15.7
16.9
27.0
177.2
32.7
24.6
39.0
27.9
75.1
52.2
54.6
21.9
33.3
40.5
48.7
37.1
24.3
123.4
145.0
42.2
28.4
29.3
46.1
44.9
81.4
35.5
29.2
33.7
181.0
12.3
16.0
17.5
25.0
180.7
29.0
25.0
38.7
27.6
73.5
42.7
48.6
18.6
32.9
39.7
48.1
37.2
23.8
123.2
144.4
42.1
28.4
23.8
46.1
43.3
42.7
44.2
30.8
34.5
68.0
13.1
15.9
17.4
26.1
179.1
177.1
28.4
Cl403
Cl161
Cl411
~1421
I3411
Cl431
Cl441
1527
Table 1. Continued
54p
sp
38.8
26.8
78.8
38.9
55.2
18.3
32.6
39.8
46.9
37.0
23.5
122.3
143.2
43.7
36.0
67.5
40.2
44.7
46.9
30.7
33.8
26.2
28.0
16.0
15.6
16.7
26.8
70.8
33.0
23.9
39.2
28.1
78.1
39.4
55.8
18.8
33.3
40.1
47.2
37.3
23.9
122.4
145.2
42.1
34.7
74.2
40.9
42.5
48.3
30.5
37.1
31.3
28.7
16.6
15.9
17.2
27.3
70.2
33.4
24.9
Cl481
Cl491
fsp
s7p
58p
59p
60
61
62
63p
64p
39.2
28.1
78.1
39.4
55.7
18.8
32.9
40.3
48.0
37.3
23.9
122.6
144.5
42.1
26.6
27.5
39.2
44.0
47.3
36.6
74.6
79.6
28.8
15.8
16.5
17.1
26.7
22.3
31.5
21.3
39.0
28.2
80.1
43.1
56.5
19.1
33.6
40.6
48.2
37.1
24.2
122.4
145.4
42.4
26.7
31.0
33.3
47.6
42.9
36.0
74.5
44.6
23.5
64.5
16.2
17.1
25.6
28.8
28.1
25.5
38.9
28.4
80.1
43.2
56.3
19.1
33.3
40.1
48.1
37.0
24.1
122.7
144.3
41.9
26.5
28.6
35.1
47.2
46.5
36.9
72.8
47.7
23.5
64.5
16.2
16.9
26.0
28.7
29.9
17.7
39.2
28.5
80.4
43.4
56.5
19.3
33.8
40.3
48.4
37.3
24.2
122.6
144.7
42.5
26.6
28.8
38.0
45.6
47.0
30.8
42.7
75.8
23.6
64.6
16.2
17.0
25.8
28.8
33.2
21.0
39.9
27.0
78.8
39.0
55.6
18.6
32.8
40.2
47.9
37.1
23.8
123.0
143.2
41.5
25.3
14.7
43.0
42.4
46.0
31.5
42.2
75.8
28.2
15.6
15.6
16.7
26.4
70.1
33.4
24.8
38.3
26.0
76.7
41.8
49.8
18.5
32.4
39.8
47.6
36.9
23.6
122.3
144.2
41.8
25.6
22.0
36.9
42.4
46.5
31.0
34.1
31.0
72.0
11.4
15.9
16.8
26.8
69.7
33.2
23.6
47.1
67.2
82.2
38.8
54.8
16.9
32.4
38.9
47.2
38.5
23.0
122.6
143.4
41.9
28.4
24.0
46.6
43.1
80.0
36.9
28.4
34.8
27.1
16.8
16.1
16.9
28.7
179.0
28.7
24.4
47.1
68.9
78.7
43.5
48.4
18.6
33.1
40.1
48.5
38.5
23.8
123.5
144.1
42.4
28.3
23.9
47.0
43.5
46.3
30.7
34.2
33.0
67.2
14.0
17.6
17.2
26.1
178.6
32.9
23.7
41.1
28.3
73.3
44.0
49.3
67.5
41.1
39.2
48.7
36.9
23.7
122.9
144.2
42.7
28.3
23.9
46.6
42.0
46.4
30.9
34.2
33.2
67.1
14.7
17.4
18.6
26.2
180.2
23.7
33.2
L-1261
Cl501
Cl261
Cl511
Cl411
cl521
Cl531
Cl541
Cl551
S. B. MAHATOand A. P. KUNDU
1528
Table 1. Continued
65
66
67
68
44.8
71.5
73.1
42.3
48.5
18.3
33.0
39.9
48.2
37.2
23.9
122.7
144.8
42.3
28.2
23.7
46.6
42.0
46.4
30.9
34.2
33.1
67.8
14.4
17.2
17.5
26.2
180.1
33.1
23.7
41.7
66.7
78.8
41.1
42.6
18.0
32.6
39.7
47.7
38.2
23.2
122.4
144.4
42.0
27.9
23.6
47.0
41.6
46.2
30.8
34.1
32.4
71.5
17.5
16.8
17.1
26.2
178.7
33.2
23.8
41.4
66.2
73.3
41.4
48.6
18.2
32.7
39.3
47.4
38.0
23.4
121.9
143.7
41.6
27.5
22.9
46.6
41.1
45.7
30.6
33.7
32.2
22.0
65.5
16.6
16.6
25.9
178.2
33.0
23.5
38.9
27.5
77.8
38.9
55.4
18.3
32.8
39.6
47.0
36.8
23.4
122.5
144.0
41.4
34.3
73.3
40.0
43.2
30.7
46.7
29.5
27.5
28.3
15.4
16.1
16.6
27.2
69.7
23.8
207.6
Cl561
Cl571
Cl581
Cl591
7op
71P
72
73p
7@
75p
38.9
28.4
80.1
43.2
56.3
19.1
33.4
39.9
48.0
37.1
24.1
124.0
142.2
42.1
25.5
27.4
47.8
47.5
43.0
38.9
47.0
216.0
23.6
64.6
16.2
16.9
25.4
21.3
27.0
68.3
45.0
71.6
75.8
54.0
52.3
21.6
34.1
40.9
49.5
37.1
24.0
127.6
139.7
46.5
24.7
24.1
46.5
41.8
45.5
31.0
33.5
33.2
180.2
13.7
17.5
18.8
64.4
180.6
33.2
23.2
44.8
71.5
73.0
42.4
48.1
18.2
33.0
39.8
48.5
37.2
23.9
123.3
144.4
42.2
28.4
23.9
46.1
43.3
42.7
44.1
30.8
34.5
67.7
14.5
17.4
17.2
26.2
179.7
28.4
177.1
39.4
28.0
78.0
39.4
55.8
18.5
33.8
40.5
48.6
37.4
23.6
127.9
138.2
45.9
80.1
34.6
46.5
41.7
42.5
41.0
74.5
36.7
28.7
16.5
16.3
19.8
25.3
179.5
25.1
63.2
38.9
28.4
80.1
43.2
56.3
19.1
33.2
40.3
48.1
37.0
24.2
122.5
144.5
42.1
26.6
27.5
39.2
44.0
47.3
36.6
74.6
79.6
23.6
64.6
16.2
17.0
26.7
22.3
31.5
21.3
44.8
71.8
73.4
42.9
50.5
18.9
32.2
40.8
48.9
37.6
24.5
124.1
142.1
42.3
35.9
66.3
73.5
50.2
49.3
31.4
36.8
81.8
67.2
14.5
18.1
17.5
27.1
33.1
24.6
38.8
28.3
80.0
43.1
56.3
19.0
33.2
39.9
47.9
37.0
24.0
123.9
142.0
41.9
25.4
27.2
48.1
47.4
41.4
39.7
46.3
216.2
23.5
64.5
16.2
16.8
25.4
21.2
71.9
21.1
cl291
cw
Cl211
Cl611
Cl261
Cl621
cl271
1529
Table 1. Continued
76
77p
78p
79p
80
81
82
83
SIM
85
8ap
87
38.4
26.5
76.5
41.9
49.2
18.5
32.6
40.0
47.1
37.0
23.6
122.6
143.2
43.8
36.3
67.5
40.5
44.6
47.0
30.9
33.8
26.0
71.3
11.4
16.0
16.7
26.8
70.0
33.1
24.1
38.9
27.4
74.1
42.7
48.9
18.6
33.0
40.1
47.2
37.1
23.8
122.3
145.2
42.0
34.7
73.9
40.9
42.6
48.2
31.1
37.1
30.2
68.6
12.9
16.2
17.1
27.3
70.2
33.3
24.9
39.0
28.4
80.0
43.1
56.3
19.1
33.5
39.9
48.1
37.0
24.0
122.4
144.9
42.3
26.4
28.9
38.2
44.8
41.5
36.5
37.3
75.6
23.5
64.5
16.3
17.1
25.5
21.1
73.0
24.4
39.0
28.5
80.2
43.2
56.4
19.2
33.6
40.1
48.2
37.1
24.1
122.8
144.7
42.4
26.5
28.7
38.1
45.2
42.2
35.9
38.8
75.2
23.6
64.6
16.3
17.1
25.9
21.3
28.6
70.3
48.9
67.4
75.6
43.1
47.4
66.0
39.6
38.1
46.7
36.9
22.6
121.7
143.3
41.8
27.1
22.9
45.5
40.9
45.7
30.4
33.3
32.1
63.7
14.9
17.8
18.1
25.7
178.6
32.9
23.3
48.5
68.9
78.9
43.0
48.8
28.1
67.4
39.5
50.1
38.2
24.2
123.3
144.1
41.9
28.3
23.8
46.0
44.7
46.8
31.0
34.3
32.3
66.0
15.7
19.1
18.7
26.3
180.1
33.3
23.6
47.4
71.8
73.0
43.6
49.1
67.0
41.0
39.3
49.0
37.1
24.1
123.1
144.2
42.9
28.2
23.8
46.7
42.1
46.5
31.0
34.2
33.3
67.5
16.2
18.5
19.0
26.4
180.2
33.3
23.8
41.3
28.6
73.4
43.9
49.7
67.9
40.8
39.3
49.0
37.1
24.7
123.8
144.7
42.6
28.7
27.9
46.3
45.0
81.6
35.7
29.2
33.9
67.3
14.6
17.3
18.4
24.8
180.0
25.0
28.8
45.6
72.6
73.9
43.2
48.2
19.2
34.1
41.0
48.5
38.1
24.9
123.8
145.5
43.0
36.5
75.6
48.8
42.4
48.0
31.7
36.9
33.0
67.9
14.4
18.2
17.8
27.7
181.6
33.8
25.3
47.7
68.8
78.3
43.5
48.0
18.5
33.0
39.9
48.0
38.3
25.2
126.5
139.5
42.5
28.2
24.0
48.5
49.5
75.0
35.7
32.7
35.0
66.7
14.2
17.5
17.3
24.8
179.2
30.6
17.8
47.4
68.9
78.4
43.6
48.2
18.8
33.6
40.1
48.5
38.6
28.8
123.5
144.9
42.2
29.2
24.3
46.0
44.8
81.3
35.7
28.4
33.1
66.8
14.2
17.7
17.3
24.9
180.8
29.2
24.9
39.0
27.6
73.6
42.9
48.8
18.9
33.4
40.5
47.9
37.3
24.2
128.6
140.2
42.3
29.6
27.4
49.2
54.6
74.9
50.6
67.6
48.0
68.0
13.2
16.1
17.4
24.7
180.4
27.8
11.5
Cl481
Cl631
Cl641
Cl291
Cl541
Cl651
Cl661
Cl551
Cl671
PO1
Cl681
Cl431
1530
Table 1. Continued
88
90
91P
92
93
94
95
%p
97
!w
47.9
69.0
80.0
41.7
48.4
19.3
33.2
40.0
48.9
38.3
24.3
122.4
144.9
42.4
28.4
23.9
46.7
42.1
46.7
31.0
34.4
33.2
64.1
63.8
17.4
17.2
26.2
180.0
33.5
23.9
38.6
27.6
73.7
42.7
49.0
18.7
33.4
40.4
48.8
37.4
24.1
127.7
140.1
48.0
24.4
23.8
46.9
41.2
40.4
36.6
28.9
32.7
68.8
12.9
16.3
18.8
64.4
180.3
74.0
19.8
38.9
28.4
80.1
43.2
56.3
19.1
33.1
40.3
48.0
37.0
24.2
123.8
143.6
42.0
26.5
27.4
38.9
42.7
42.4
49.9
70.5
79.1
23.5
64.5
16.2
16.9
26.5
22.1
178.7
16.5
39.4
28.0
78.0
37.2
55.9
18.5
33.8
40.6
48.7
37.2
23.6
128.1
138.1
46.5
80.2
27.8
52.4
41.6
42.0
41.4
79.6
69.7
28.7
16.5
16.3
19.8
25.4
178.9
25.3
63.8
38.4
26.4
78.3
38.4
55.0
18.0
32.4
39.3
46.9
36.5
23.1
123.0
141.6
41.0
32.7
66.7
45.9
40.6
46.3
35.1
78.2
77.4
27.5
15.2
15.1
16.2
26.4
69.5
28.9
17.9
38.5
26.3
76.0
41.8
49.3
18.4
32.6
39.8
46.7
36.9
23.5
122.9
142.7
41.8
33.4
67.9
43.9
42.4
47.2
31.4
44.8
75.5
70.8
11.7
16.0
16.8
27.0
71.1
33.2
24.9
38.6
28.4
80.1
43.2
56.3
19.1
33.2
40.3
48.1
37.0
24.1
122.5
144.6
42.0
26.6
27.4
39.0
43.2
41.1
41.0
70.5
79.7
23.5
64.5
16.2
17.0
26.7
22.3
71.7
17.5
38.9
28.4
80.0
43.2
56.3
19.1
33.4
39.9
48.0
37.0
24.0
124.0
142.3
42.1
25.5
27.0
48.1
47.1
37.6
44.1
42.4
216.8
23.6
64.6
16.2
16.9
25.3
21.6
68.3
65.0
47.9
69.0
79.8
47.9
48.7
19.5
33.3
40.1
48.2
38.1
24.3
123.4
144.8
41.9
29.0
28.0
46.1
44.9
80.8
35.6
28.5
33.2
64.3
63.2
17.5
17.2
24.9
180.9
28.9
24.8
47.5
71.9
73.4
43.5
49.1
67.9
41.4
39.5
48.3
37.2
24.2
123.0
144.6
42.9
36.3
74.9
49.5
41.7
47.4
31.0
36.2
32.7
67.8
16.0
19.0
18.7
27.5
180.1
33.3
24.9
39.3
28.2
78.1
39.4
55.7
19.2
36.8
41.5
47.5
37.4
24.1
124.5
144.7
47.5
67.5
72.4
48.2
42.1
47.9
36.4
78.4
77.2
28.8
16.6
16.0
17.7
21.1
67.8
30.6
19.4
Cl681
Cl691
Cl261
Cl611
Cl701
~1521
W61
cl271
Cl651
[I711
~1721
1531
Table 1. Continued
100
101
10ZP
103
104
105
106
38.8
28.2
80.1
43.0
56.3
18.9
33.4
39.9
41.1
36.8
23.9
123.1
144.1
41.8
34.1
67.8
47.2
41.0
48.1
36.3
18.6
77.1
23.3
64.5
16.0
16.6
21.2
66.2
30.4
19.3
38.5
21.4
79.0
39.0
55.1
18.3
34.7
40.8
51.3
31.3
21.2
26.2
39.0
43.4
27.6
31.7
34.4
142.8
129.8
32.3
33.4
37.4
28.0
15.4
16.1
16.7
14.6
25.3
31.3
29.2
38.8
21.3
78.3
38.8
55.4
18.2
34.5
40.6
51.1
37.1
20.9
25.9
41.2
42.5
29.3
33.5
48.1
136.9
132.3
32.0
33.5
33.5
27.9
16.6
15.4
15.9
14.9
176.8
30.3
29.1
75.7
39.0
79.5
38.4
53.4
18.0
34.6
41.4
52.4
43.8
23.9
26.2
38.1
43.5
27.5
37.8
34.4
142.7
129.7
32.4
33.5
31.5
28.0
15.1
12.5
16.5
14.5
25.4
31.3
29.3
39.0
21.3
78.9
38.9
56.4
18.5
36.3
41.2
53.4
38.4
67.4
36.3
32.8
43.3
21.6
31.6
34.5
142.5
130.0
32.4
33.3
37.4
28.2
15.5
20.0
18.1
14.7
25.2
31.3
29.2
38.5
27.4
79.1
39.0
55.7
18.4
34.5
40.8
51.3
37.4
21.3
26.7
39.1
42.8
34.1
76.7
39.6
141.7
129.4
31.9
33.7
37.4
28.1
15.5
16.3
16.9
14.8
21.4
31.9
30.0
38.1
23.8
81.1
37.7
55.4
18.4
34.8
41.0
50.6
37.2
21.7
26.5
134.2
44.7
25.0
36.7
34.6
133.3
39.4
33.4
35.4
38.5
28.0
17.7
16.4
16.6
21.3
24.1
32.4
23.8
77.7
38.9
54.9
33.2
42.7
63.4
36.9
132.8
43.8
25.4
33.3
40.2
133.5
31.9
32.2
43.5
78.8
28.1
15.6
16.3
18.8
20.4
16.7
32.2
25.1
Cl731
Cl741
Cl751
Cl741
Cl741
Cl761
Cl771
c591
107
108
109
38.8
21.2
78.9
38.8
55.2
18.2
32.9
41.0
50.3
37.4
20.7
25.1
123.5
42.1
26.9
20.7
43.0
139.7
34.8
81.0
31.2
37.5
28.1
16.3
15.5
17.9
25.9
175.9
25.3
38.4
26.3
70.9
55.4
47.2
20.7
33.7
44.3
50.3
36.2
22.0
25.1
126.3
42.2
35.9
69.3
52.8
135.6
41.5
32.5
35.5
27.0
206.8
8.8
16.6
18.2
24.6
177.3
33.0
24.6
38.0
27.1
18.9
38.9
54.2
18.4
32.4
40.2
54.8
36.7
125.3
125.8
138.1
42.4
35.3
24.4
34.7
133.4
38.9
33.1
36.1
38.0
27.8
15.1
16.6
17.9
20.2
25.3
24.1
32.5
Cl781
II781
Cl791
1532
S. B. MAHATOand A. P. KUNDU
Table 1. Continued
llop
lllP
112p
l13p
l14p
1lSP
116
117p
l18p
119
38.6
28.1
78.2
39.5
55.4
18.8
32.7
40.5
54.6
37.1
127.6
126.1
136.1
42.3
24.7
36.6
48.5
136.0
38.3
41.2
43.6
74.3
29.6
15.8
18.3
17.0
26.8
20.5
25.0
177.8
37.8
28.0
78.5
39.7
55.6
18.9
33.0
40.2
54.5
37.0
127.1
125.8
136.6
44.4
35.1
76.3
44.4
133.4
38.7
32.6
35.3
30.2
27.8
15.9
18.3
17.2
22.1
64.0
25.0
32.3
39.0
28.1
78.0
39.5
55.4
18.9
32.6
41.1
53.9
37.0
126.2
126.2
136.1
41.9
31.9
67.7
45.3
133.1
38.6
32.6
35.5
24.5
28.5
16.0
18.4
17.3
21.9
64.7
25.1
32.6
38.9
29.0
80.1
39.8
56.4
19.6
34.0
40.7
54.8
39.8
127.3
126.3
138.3
40.8
25.0
35.6
42.0
135.0
38.4
43.2
43.3
75.6
23.3
64.5
18.3
16.9
25.4
23.6
25.0
29.1
38.4
27.6
73.1
43.1
48.2
18.6
32.4
40.5
54.5
36.8
127.1
125.7
136.4
44.4
34.8
76.5
44.4
133.3
38.4
32.7
35.1
29.9
67.4
12.6
18.6
17.1
22.0
64.0
24.8
32.3
38.4
27.6
73.3
43.0
48.4
18.7
31.9
41.0
54.0
36.8
126.2
126.2
136.0
41.9
32.8
67.6
45.3
133.0
39.0
326
35.4
24.4
64.7
12.6
18.7
17.3
21.9
64.4
25.1
32.4
38.8
27.9
78.6
38.9
51.2
18.4
32.2
37.0
154.3
40.7
115.8
120.8
147.1
42.8
25.7
27.3
32.2
45.6
46.9
31.1
34.7
37.2
28.8
15.1
20.1
21.0
25.3
28.3
23.7
33.2
37.8
28.7
77.8
39.6
51.8
18.6
32.6
43.1
154.9
39.0
116.1
121.2
145.3
43.2
36.1
668
40.6
42.6
47.0
31.0
34.1
26.2
28.8
16.6
21.0
21.3
25.5
69.4
33.2
24.0
37.6
28.4
73.0
43.2
44.6
18.5
32.2
43.2
155.0
39.0
116.1
121.2
145.4
43.2
36.2
66.8
40.6
42.7
47.0
31.0
34.2
26.1
67.7
13.2
21.1
21.3
26.1
69.4
33.2
24.1
39.1
28.1
78.2
39.5
56.0
19.0
33.5
40.4
47.9
37.8
23.7
123.0
141.7
44.8
129.9
134.9
44.0
42.9
47.9
30.8
35.2
33.5
28.9
16.4
15.5
17.9
25.1
178.4
33.5
23.5
Cl491
c791
Cl801
Cl491
Cl811
Cl811
Cl801
c791
Cl811
C801
1533
Table 1. Continued
1w
121P
122p
lUP
124
125
12Cip
127
41.7
67.4
68.4
40.3
140.8
115.6
34.6
40.5
47.6
41.4
20.9
117.6
144.4
41.9
28.2
21.5
35.8
42.8
43.1
31.8
34.8
36.3
71.2
16.8
16.8
19.5
22.3
22.3
31.0
21.3
43.2
70.8
73.0
45.5
148.7
120.9
33.2
37.5
46.0
38.5
24.1
123.4
145.1
43.1
27.7
23.6
47.0
42.5
45.8
31.0
34.2
33.1
69.4
21.3
23.0
23.8
26.2
180.2
33.3
23.8
38.8
28.0
78.0
39.5
55.3
18.3
31.3
41.9
52.9
36.8
131.9
131.9
84.9
43.6
36.8
77.1
45.4
51.4
38.5
31.9
36.8
31.9
28.4
15.9
18.2
19.5
18.2
77.8
33.8
24.4
38.5
26.6
78.5
39.1
54.4
17.9
31.7
41.8
52.7
36.3
132.5
130.1
84.0
45.9
35.7
64.3
46.2
51.8
37.9
31.5
34.2
25.2
27.6
15.7
17.8
19.5
20.6
72.3
33.8
23.7
38.0
26.2
75.9
41.9
49.3
17.7
31.1
41.6
53.3
36.3
132.5
130.7
85.2
43.9
25.7
25.3
41.6
51.1
37.2
31.7
34.9
30.9
70.7
11.1
18.2
19.3
19.3
77.1
33.7
23.6
38.0
26.1
75.6
42.0
49.2
17.7
31.1
41.4
52.5
36.3
132.6
130.5
85.1
43.0
34.7
77.3
44.9
50.6
38.0
31.7
36.5
30.5
70.3
11.1
18.3
19.0
17.9
77.3
33.4
24.2
38.3
25.8
75.3
42.1
48.8
17.6
31.4
41.9
52.8
36.2
133.0
129.8
84.2
45.3
35.3
64.5
46.4
52.0
37.5
31.5
34.5
25.3
69.8
11.3
18.4
19.5
20.7
72.6
33.5
23.8
38.2
26.2
75.2
42.2
49.0
17.8
321.2
41.8
52.8
36.4
133.2
130.3
85.5
43.8
34.3
70.5
47.5
50.4
37.4
33.2
45.7
74.3
69.6
11.3
18.4
19.1
18.1
16.9
33.2
25.2
CW
rwl
IT301
Cl481
~1521
~1521
Cl481
cl521
1W
39.9
28.8
78.1
39.6
55.8
18.3
31.9
42.6
50.7
37.3
19.3
34.6
86.5
44.7
37.0
77.2
44.7
51.6
39.1
31.9
36.9
33.0
28.7
16.6
16.4
18.7
19.6
78.0
33.8
24.8
Cl831
1W
39.1
28.3
78.0
39.5
55.7
18.6
32.9
42.5
47.8
37.3
19.3
31.8
86.4
44.7
34.6
77.2
44.7
50.6
37.0
48.0
37.0
33.8
28.7
16.6
16.6
18.2
19.6
78.0
24.8
207.2
Cl841
1534
S. B. MAHATOand A. P. KUND~J
Table 1. Continued
130p
38.0
28.3
78.2
39.6
55.8
18.3
32.7
42.9
47.6
37.3
19.2
31.8
86.1
44.6
34.4
73.2
46.5
50.6
36.8
47.6
30.1
74.1
28.8
16.6
16.4
18.7
20.1
70.3
24.2
205.3
Cl841
131
38.8
27.2
76.2
42.8
49.5
18.5
33.3
42.0
50.1
36.8
18.5
32.8
86.4
44.4
34.4
77.4
44.7
51.4
39.4
31.7
36.8
29.8
69.2
13.1
16.9
17.6
18.6
77.8
24.6
33.5
Cl851
132
38.7
27.0
76.2
42.7
49.6
18.6
33.4
42.0
50.0
36.6
17.8
31.6
86.2
49.7
45.4
213.3
56.1
54.5
40.0
31.6
35.2
24.8
71.6
11.3
16.3
17.8
21.7
75.1
23.6
33.3
Cl851
133
39.3
26.6
79.1
39.8
55.8
18.0
33.0
42.7
50.5
37.0
19.3
34.5
86.4
45.1
36.7
70.7
48.9
51.4
38.1
33.3
42.2
75.8
28.2
16.7
16.5
18.6
19.8
76.8
33.4
25.6
CW
134p
39.6
28.4
78.2
39.6
55.7
18.3
34.5
42.8
50.6
33.2
19.4
33.5
87.5
44.2
36.8
69.8
52.9
47.4
38.7
37.3
46.7
68.1
28.7
16.4
16.6
18.8
19.8
98.6
33.8
26.0
Cl871
139
136
45.5
68.1
79.0
42.6
47.6
17.3
34.1
40.4
50.4
33.0
27.5
75.1
37.0
48.6
17.3
31.5
40.9
49.8
37.0
52.9
57.4
88.0
41.9
27.0
21.7
44.1
51.1
38.0
31.6
34.4
27.7
29.1
22.2
17.3
18.8
20.5
180.0
33.6
23.5
52.4
56.9
87.4
41.2
26.5
21.1
43.7
49.4
37.6
30.6
26.8
37.3
68.1
12.3
18.6
18.7
19.9
179.3
33.0
23.4
cl231
w31
137
39.8
21.5
36.6
30.6
54.4
21.0
33.1
40.5
48.6
37.1
21.2
25.0
43.0
41.6
31.1
29.7
43.8
37.9
43.9
31.1
39.2
30.4
20.5
__
14.1
15.8
14.9
25.4
33.7
Cl891
138
13M
140
141
39.1
34.1
217.9
47.4
55.3
19.7
32.5
39.1
47.0
36.8
23.4
120.8
146.0
42.5
26.5
21.5
15.1
17.4
24.9
-
39.0
28.1
78.2
39.4
55.9
18.9
33.5
40.0
48.3
37.5
24.0
122.7
145.7
42.1
28.1
26.4
71.0
48.8
49.0
31.2
37.1
38.8
28.9
16.6
15.6
17.9
25.8
._
38.1
23.7
80.8
31.7
55.4
18.2
32.6
39.9
47.2
37.0
23.7
125.4
140.7
47.2
43.0
213.3
76.5
52.5
47.2
30.8
32.3
37.7
28.1
15.4
16.7
17.3
27.0
37.7
23.0
74.5
40.7
48.3
18.1
32.4
39.2
47.1
37.0
23.3
118.3
143.0
42.4
33.3
74.6
39.8
35.8
44.8
34.7
78.2
32.8
65.5
12.9
15.8
16.8
26.2
__
33.6
23.8
33.0
24.0
32.6
23.7
18.9
19.3
31.2
__
tml
~1231
Cl911
C781
1535
Table 1. Continued
142
143
144p
145o
146
147p
14V
149
l!W
151
152
37.6
22.4
73.3
54.1
48.0
20.5
32.3
39.0
47.1
36.1
23.2
118.1
141.5
42.6
43.7
212.1
38.7
27.1
78.7
38.7
55.3
18.2
33.4
38.7
46.1
36.8
24.1
126.8
139.1
44.9
40.4
200.4
128.9
146.8
44.1
29.2
33.4
20.6
28.1
15.6
15.6
17.9
28.1
-
45.1
71.6
72.8
42.5
48.2
18.1
33.5
39.1
46.8
37.0
24.6
127.5
139.3
45.2
40.3
199.2
129.1
146.2
44.4
29.2
34.6
21.2
67.5
14.6
17.4
18.0
28.1
38.1
26.9
78.1
41.9
55.1
19.6
32.7
39.3
46.1
41.1
22.1
19.8
38.8
43.2
22.2
125.6
140.2
42.1
66.9
35.2
133.2
123.2
65.2
16.9
18.2
16.9
27.1
28.6
23.1
28.6
23.3
62.1
16.1
39.4
26.5
78.1
39.4
55.9
18.7
34.0
39.4
48.1
37.4
23.7
122.9
143.4
43.2
28.2
23.4
46.2
45.6
129.5
130.4
33.2
39.2
28.8
16.6
15.9
17.7
23.6
179.9
23.0
39.1
28.2
78.2
39.5
55.9
18.9
33.4
39.9
47.5
37.4
24.0
122.8
143.8
44.6
38.6
64.9
50.4
43.5
46.2
68.2
34.2
27.2
28.9
16.7
15.7
17.8
27.2
181.3
32.3
38.3
24.0
80.7
38.2
55.6
18.3
31.8
42.8
46.5
37.5
39.2
210.3
83.1
45.4
23.1
34.0
34.2
51.3
35.5
30.0
34.7
39.7
28.1
16.7
15.9
20.1
18.4
31.5
32.1
25.9
38.4
24.0
80.6
38.0
55.2
18.6
38.2
44.9
46.2
37.9
39.2
210.4
85.8
51.1
66.7
44.0
35.1
51.6
35.2
31.8
34.5
39.6
28.0
16.7
15.9
20.4
14.4
32.0
32.3
24.8
38.1
24.1
80.9
37.9
55.7
18.7
33.7
40.0
48.2
37.4
23.9
123.2
144.9
42.2
28.4
29.2
46.1
44.8
81.3
35.7
29.2
33.2
28.2
16.9
15.3
17.5
24.9
180.9
28.8
24.9
38.1
27.3
79.2
39.1
55.7
19.0
35.3
38.9
48.9
37.9
17.7
35.9
37.9
158.1
117.0
36.9
38.1
49.4
41.4
29.0
33.9
33.2
28.1
15.6
15.6
30.1
26.0
30.1
33.5
21.5
37.7
27.4
79.1
38.5
46.5
23.9
71.6
45.7
42.1
38.6
17.1
34.1
37.5
155.2
118.7
36.9
36.0
49.0
37.2
29.3
33.2
35.2
27.9
15.8
15.6
26.7
21.1
29.6
33.1
29.8
Cl911
Cl911
~1921
[l?s]
Cl931
Cl941
Cl941
Cl941
C811
48.0
36.1
42.8
34.5
78.1
27.7
203.9
9.4
15.4
16.8
25.7
28.8
19.3
C781
C621
1536
Table 1. Conti~d
153
154
155
156
157
158
159
160
161
162
163
144
37.8
28.0
78.2
41.4
56.0
19.2
36.3
39.3
45.6b
37.8
17.9
31.2
38.3
158.7
116.8
33.2
38.3
49.6b
41.7
28.8
33.8
28.7
28.4
16.5
15.7
30.1
26.2
64.6
33.8
22.0
32.6
25.0
76.2
37.5
48.8
18.7
41.2
40.3
49.2
37.3
17.3
32.2
38.0
159.3
115.5
30.8
39.2
44.7
35.8
28.6
33.5
27.9
28.2
22.2
15.2
29.9
26.2
65.5
21.5
33.5
38.3
34.0
217.2
47.5
55.7
19.9
35.8
39.0
48.6
37.5
17.3
30.7b
37.7
158.5
116.0
32.6b
40.3
44.9
40.6
28.5
33.3
27.9
26. I
21.6
14.8
29.8
25.7
65.4
33.5
21.4
38.4
34.1
217.3
47.5
55.7
21.5
35.41
38.9
48.6
37.3
17.3
31.3
37.8
162.1
117.1
30.7
51.5
41.4
40.38
29.3
33.7
31.9
26.1
20.0
15.0
28.7
25.9
184.7
33.2
22.6
37.4
23.4
80.8
37.6
55.5
18.7
40.7
39.0
49.0
37.9
17.2
33.2
37.2
160.5
116.8
31.3
51.4
41.3
35.2
29.2
33.6
30.6
27.9
16.5
15.6
26.1
22.4
184.2
31.8
28.6
36.6
24.2
81.1
37.7
50.2
24.0
117.5
147.6
48.7
35.1
17.1
34.6
37.0
41.6
31.7
36.1
30.9
46.9
36.1
28.2
33.9
36.8
27.6
16.0
13.2
27.1
26.1
31.7
34.1
33.7
34.9
24.4
81.1
37.9
51.1
19.3
27.5
135.4
133.6
37.7
20.9
31.0
37.5
41.1
26.6
37.1
31.0
44.3
34.3
28.4
43.0
36.9
28.1
16.8
20.0
18.9
25.0
31.6
34.7
33.2
36.9
19.2
41.8
33.3
51.7
19.6
21.2
135.0
134.2
37.9
20.8
30.9
37.6
40.1
26.8
36.4
31.2
43.1
28.8
33.3
29.1
37.6
33.3
21.8
19.9
25.9
18.0
31.4
72.9
27.6
36.9
19.3
41.8
33.3
51.5
19.5
27.8
133.3
134.8
37.9
20.8
30.2
36.9
42.1
25.6
37.1
31.0
44.7
30.5
40.5
29.6
34.3
33.0
21.9
19.9
21.8
18.0
31.3
185.3
32.7
34.7
24.2
80.9
37.7
50.8
19.1
27.3
135.4
133.2
37.5
20.8
30.7
37.6
40.6
26.7
36.3
31.1
43.0
28.0
33.1
28.9
37.6
28.0
16.7
19.8
25.9
17.9
31.3
12.6
27.6
35.0
27.9
78.9
38.8
50.5
19.2
27.6
133.9
134.2
37.5
20.7
30.3
37.1
41.8
25.0
37.0
30.9
44.7
30.8
40.5
29.9
34.4
28.0
15.6
19.9
22.1
17.1
31.2
179.2
32.9
21.6
38.1
215.4
50.0
142.4
121.3
23.6
47.0
35.1
50.7
34.1
30.3
39.3
37.9
31.9
35.9
30.1
43.1
35.1
28.2
33.1
38.9
24.4
28.5
15.6
19.3
18.4
32.0
34.5
32.4
1811
Cl951
fl961
Dll
PI
II821
L581
Cl11
Cl11
WI
Cl01
cw
1537
Table 1. Continued
165
166
167
168
169
31.9
24.7
84.4
43.3
53.1
19.8
20.0
41.9
36.7
93.6
30.6
30.0
39.2
39.3
31.8
35.9
30.1
43.6
35.0
28.3
33.4
38.7
24.4
23.0
m.5
19.3
18.5
31.9
34.1
328
31.9
24.8
84.0
43.5
51.8
31.5
68.4
48.0
36.9
93.3
31.1
30.0
39.3
40.4
31.8
36.0
29.8
44.2
34.6
28.3
33.9
38.1
23.9
228
21.7
19.8
18.8
33.5
34.0
324
31.9
24.7
84.4
43.4
53.1
19.8
20.0
423
36.6
93.5
30.3
30.9
38.9
39.4
31.2
32.0
41.6
45.2
34.5
34.7
41.5
75.4
24.4
23.0
20.4
20.0
18.7
23.3
34.9
31.9
17.8
35.0
72.7
49.0
37.3
41.4
15.8
53.2
37.9
61.2
37.9
27.8
54.8
39.3
32.8
35.6
36.7
43.3
35.7
28.5
32.5
38.2
11.6
16.4
18.8
22.5
179.4
31.1
30.6
35.3
20.8
27.4
36.9
46.0
37.7
42.6
M.6
53.1
37.1
61.2
35.4
23.7
42.2
39.8
30.1
35.7
30.4
43.5
35.4
28.3
32.9
39.1
13.4
15.1
19.6
18.0
64.1
31.7
-
D51
C851
C851
Cl971
im
171
172
173
174
175
176
21.1
27.0
30.2
46.3
44.1
58.0
212.4
63.9
43.5
60.6
35.7
32.2
39.4
37.6
30.7
36.2
30.2
42.0
35.1
28.1
33.0
38.9
13.8
15.1
19.6
18.4
19.6
32.3
31.7
20.7
27.4
30.9
46.1
37.6
41.5
18.1
53.5
37.0
60.7
35.5
30.7
39.9
38.3
32.6
35.9
30.5
41.8
29.1
33.1
27.8
39.5
15.1
13.5
18.1
18.4
20.7
321
74.8
25.8
20.7
27.4
30.9
46.1
37.5
41.5
18.1
53.1
37.0
60.8
35.4
30.7
39.7
38.4
32.1
36.0
30.0
42.7
29.3
33.4
28.2
38.1
15.1
13.5
18.2
18.6*
19.9
321
28.9
72.0
22.3
41.5
213.2
58.2
421
41.3
18.2
53.1
37.4
59.4
35.6
30.5
39.1
38.3
32.4
36.0
30.0
42.8
35.3
28.1
32.7
39.2
6.8
14.6
17.9
20.2
18.6
32.1
35.0
31.8
22.1
41.3
212.5
57.8
41.9
40.0
19.9
47.9
36.6
58.2
35.7
21.6
50.9
46.7
81.0
39.7
31.4
44.7
30.8
145.3
29.2
36.8
6.8
14.6
16.3
13.3
179.3
30.1
109.1
22.1
41.3
212.4
57.8
41.9
40.0
19.9
47.9
36.6
58.2
35.6
21.4
51.0
46.6
81.0
39.8
31.6
44.8
28.3
141.1
70.1
45.9
6.8
14.6
16.3
13.3
179.3
32.6
110.0
31.9
20.7
21.4
30.9
46.1
37.5
41.4
18.1
525
37.1
60.7
35.3
30.2
39.3
38.2
31.2
29.2
34.2
39.5
34.5
28.1
328
33.4
15.1
13.5
18.3
19.2
19.0
68.0
31.3
35.1
Cl981
C871
C871
C871
c461
c611
c611
1538
S. B. MAHATOand A. P. KUNDU
Table 1. Continued
177
178
179
180
22.8
41.5
213.0
58.1
42.0
39.5
21.5
46.6
40.5
57.1
37.0
34.9
39.0
142.3
116.1
30.9
33.7
46.1
39.6
31.0
34.4
37.9
6.8
14.4
14.7
16.5
35.3
72.7
49.0
37.8
39.9
20.9
46.8
40.4
59.1
36.8
35.1
39.0
143.0
115.5
30.9
33.8
46.2
39.6
31.0
34.4
37.9
11.6
16.0
14.8
24.1
31.8
33.7
24.4
24.1
31.8
33.8
24.5
20.8
27.5
31.1
46.3
37.6
41.5
18.2
51.9
37.2
61.0
35.6
30.2
38.7
39.6
30.4
27.2
45.1
48.1
34.8
31.4
49.7
217.3
13.6
15.1
18.0
18.4
18.5
34.0
31.1
35.1
22.2
27.5
30.6
47.0
38.8
41.4
18.1
53.1
48.3
60.0
32.5
31.4
37.6
39.8
33.3
36.1
30.0
42.8
35.5
28.1
32.8
39.4
15.1
11.9
173.9
20.5
18.9
31.7
35.1
32.1
26.6
69.6
73.2
45.6
37.8
41.0
17.8
52.9
36.4
51.3
35.2
30.5
39.6
38.2
32.3
35.9
29.9
42.7
35.2
28.0
32.7
39.2
9.6
13.4
17.8
18.6
20.1
32.0
31.6
34.9
PW
C871
Cl991
cw
C861
181
182
183
184
185
186
187
188
16.8
34.7
72.0
48.8
43.4
58.2
210.3
63.9
43.4
61.1
35.6
30.1
38.8
37.6
31.6
36.3
30.1
41.9
35.0
28.1
32.9
39.4
11.6
16.3
18.3
19.5
19.5
32.1
31.9
34.9
22.4
41.5
213.1
58.2
42.0
41.3
20.0
53.5
37.8
59.4
35.8
31.2
40.6
44.1
74.6
48.4
30.2
41.6
35.6
28.2
31.9
38.9
6.8
14.5
18.0
14.1
18.8
32.6
30.9
35.7
22.3
41.6
212.5
58.3
42.3
41.4
18.6
53.5
37.6
59.7
35.8
30.8
39.3
40.1
44.4
75.6
32.1
44.8
35.8
28.0
32.1
36.0
6.8
14.7
18.2
20.1
21.5
24.9
30.8
35.5
22.1
41.3
212.6
57.8
41.9
41.0
18.1
52.2
37.3
59.1
35.3
29.9
39.1
38.0
31.3
29.0
35.1
39.2
34.4
27.9
31.4
33.2
6.7
14.5
18.0
18.9
19.1
67.0
32.9
34.2
22.4
41.6
212.9
58.3
42.2
41.3
18.0
49.9
37.8
59.7
34.5
27.8
39.8
22.3
41.6
212.2
58.3
42.2
41.4
18.3
53.5
37.5
59.6
35.7
29.8
40.0
38.3
32.8
36.0
29.8
42.0
30.6
33.2
27.9
39.6
6.8
14.7
17.9
18.4
20.8
32.1
25.9
74.8
22.1
41.3
212.5
57.7
41.9
39.9
19.9
48.0
36.6
58.2
35.6
22.4
51.0
47.9
80.7
40.3
30.5
44.2
34.3
28.2
34.2
35.8
6.8
14.5
16.4
13.6
180.1
29.6
34.3
31.1
C871
c511
C871
C871
27.8
33.2
82.8
43.4
32.1
30.8
27.2
35.7
6.8
14.6
16.5
15.5
19.5
33.4
25.4
C871
C871
WI
1539
Table 1. Continued
189
17.8
32.8
75.1
50.0
38.3
41.3
17.8
52.1
37.0
59.9
35.3
30.4
39.2
38.5
31.1
36.4
31.9
43.3
35.8
33.5
76.4
43.7
9.9
14.5
18.2
18.8
19.0
32.8
30.8
26.2
IPll
1%
15.7
34.9
72.5
49.0
37.7
41.6
17.4
522
37.0
61.2
35.2
30.3
39.1
38.5
31.0
36.2
31.8
43.2
35.8
33.4
76.6
43.6
11.5
16.2
18.3
18.6
18.9
32.5
30.7
26.1
WI
PHYTO 37-6-E
191
192
193
194
1%
1%
197
1%
199
21.6
40.8
210.6
57.8
47.0
56.9
210.2
63.4
42.4
59.0
35.5
29.8
39.4
37.5
31.6
36.3
30.1
41.8
34.9
28.0
32.8
38.6
6.8
15.1
18.2
19.2
19.4
32.1
31.8
34.6
223
41.4
213.1
58.2
42.0
40.5
21.3
45.3
37.2
59.3
34.4
29.4
42.4
54.2
214.1
54.0
33.5
44.0
34.9
27.9
33.8
38.6
6.8
15.0
17.4
14.7
18.9
32.2
33.3
33.4
22.2
41.4
212.5
58.2
42.1
41.0
18.6
52.4
37.7
59.4
35.4
29.1
39.2
40.5
50.2
218.8
45.3
44.0
35.5
27.6
31.7
30.8
6.8
14.7
17.3
20.3
16.2
27.4
31.1
35.2
22.3
41.5
212.6
58.3
42.1
41.3
18.1
51.8
37.6
59.7
35.7
30.2
38.6
39.7
30.4
27.1
45.0
48.1
34.8
31.5
49.5
217.3
6.8
14.7
18.1
18.3
18.5
34.0
31.1
35.1
22.3
41.4
213.0
58.1
42.2
40.9
18.5
53.0
38.3
59.4
37.6
27.8
54.8
39.2
33.0
35.9
30.7
43.3
35.7
28.4
32.4
37.6
6.8
14.7
18.4
22.7
181.1
31.0
30.5
35.4
22.2
42.1
213.3
58.2
44.7
41.5
18.0
53.0
37.8
59.2
35.9
31.0
41.1
38.9
29.3
326
37.6
37.6
35.4
28.4
34.8
32.6
6.8
14.6
17.5
20.6
18.5
185.0
29.7
34.5
22.2
41.5
213.3
58.2
42.1
41.3
18.2
50.7
37.4
59.8
35.3
30.2
39.1
39.2
29.7
36.1
30.1
44.2
29.5
40.4
29.5
36.6
6.2
14.6
18.0
18.4
16.3
31.8
184.5
31.6
22.3
44.5
212.6
58.3
42.1
41.3
18.2
53.2
37.5
59.5
35.5
30.3
39.7
38.1
32.8
35.5
29.5
42.5
31.4
40.5
28.6
38.3
6.8
14.6
17.6
17.6=
20.Y
31.9
179.4
31.8
22.3
41.4
213.0
58.1
42.2
42.4
20.7
51.2
37.5
59.9
35.4
30.0
39.6
42.7
23.4
36.3
32.9
44.9
36.0
34.5
74.3
46.6
6.7
14.4
17.9
63.2
20.2
32.7
24.9
32.0
22.4
41.6
211.8
58.0
42.1
41.2
18.4
53.2
37.5
59.2
35.7
30.5
40.1
38.3
29.5
32.6
36.6
39.0
29.8
33.6
29.2
33.0
7.2
14.7
18.0
20.1
19.0
67.1
73.6
27.5
WI
WI
c200)
PW
C871
C87l
I371
c511
C871
P321
S. B. MAHATOand A. P. KUNDU
1540
Table 1. Continued
201
202
203
204
2osp
20@
207
208
209
210
22.3
41.5
212.9
58.3
42.1
41.4
18.3
52.5
37.5
59.7
35.5
30.0
39.6
38.4
31.1
29.2
35.2
38.9
31.5
33.3
30.2
28.3
6.8
14.7
18.2
18.7
19.1
69.0
73.4
28.6
202.1
60.7
204.1
59.1
37.7
40.7
19.7
52.6
37.6
71.9
34.7
30.8
40.6
44.0
74.7
48.6
30.2
41.6
35.5
28.2
31.9
38.9
7.3
15.8
18.1
14.1
18.9
32.7
31.0
35.6
22.6
41.3
211.6
57.9
42.2
40.9
18.9
54.1
43.7
59.3
56.1
211.4
62.3
43.7
33.1
37.2
30.4
37.6
36.3
28.7
33.3
40.4
7.3
14.6
18.3
223
62.5
30.6
35.6
31.9
202.6
60.5
203.7
59.2
37.5
38.5
17.0
45.2
37.1
69.0
35.8
26.5
38.1
40.0
34.7
36.8
30.8
44.0
35.4
28.3
32.5
38.9
6.8
15.7
67.1
19.3
69.9
30.0
31.4
35.1
29.4
68.5
74.7
46.6
41.1
31.0
30.3
39.4
133.7
133.7
29.0
121.7
144.7
41.6
27.6
24.0
47.0
41.5
47.3
31.0
34.3
33.1
67.3
16.0
27.9
24.0
26.2
179.9
33.1
23.8
24.9
61.3
78.0
43.8
50.2
32.1
29.0
40.3
149.1
85.0
120.7
120.3
139.8
41.2
27.8
23.8
45.7
40.6
46.6
30.7
34.6
33.8
73.4
14.2
18.6
20.3
21.4
178.3
33.0
23.6
38.7
27.2
78.3
38.7
55.2
18.3
32.9
40.0
47.7
36.9
23.3
124.3
139.3
42.0
28.7
26.6
33.7
58.9
39.6
39.6
31.2
41.5
28.1
15.6
15.6
16.8
23.3
28.1
17.4
21.3
40.1
35.6
207.8
56.6
57.2
19.6
32.0
38.9
45.6
36.2
22.7
123.1
138.9
41.3
25.6
27.1
32.8
58.2
38.7
38.6
30.2
40.5
20.0
173.2
12.4
15.9
22.1
27.8
16.5
20.3
38.8
27.3
78.8
38.8
55.4
18.4
33.0
39.6
47.5
37.0
23.3
125.5
138.0
42.0
28.2
24.3
48.1
52.8
39.1
38.8
30.7
36.7
28.2
15.5
15.7
16.9
23.6
177.7
16.9
21.2
39.4
34.2
217.8
47.4
55.4
19.7
32.6
39.1
46.8
36.6
23.6
125.4
138.4
42.2
28.1
24.3
48.2
53.0
39.0
38.9
30.7
36.7
26.6
21.5
15.2
16.9
23.5
178.0
17.1
21.2
1511
cm31
WI
Pw
PO41
c2051
c391
cl321
Cl151
II871
1541
Table 1. Continued
211
212
213
214
215
216
217
218
219
22v
39.4
26.5
78.1
39.4
55.9
19.0
37.7
40.2
47.4
37.5
23.5
129.1
134.2
56.9
28.3
25.6
48.9
55.1
39.5
37.8
30.7
37.2
28.7
16.8
16.8
18.4
178.2
180.2
19.1
21.7
33.5
25.4
76.0
37.5
48.8
18.2
35.2
43.5
55.8
38.2
68.4
128.7
142.9
42.2
27.9
27.7
33.6
58.1
39.4
39.3
31.1
41.3
28.7
22.4
16.6
18.0
23.3
28.6
17.5
21.3
38.8
27.3
79.0
38.8
55.4
18.4
32.9
39.4
47.8
37.2
23.4
125.0
138.0
42.8
29.2
22.6
36.8
54.1
38.9
39.4
30.7
30.6
28.1
15.4
15.6
16.9
23.4
69.7
16.2
21.3
46.8
68.9
83.8
39.1
55.4
18.4
32.9
39.6
47.5
38.3
23.4
125.3
138.1
42.1
28.0
24.3
48.1
52.8
39.1
38.9
30.7
36.7
28.7
17.0
17.0
17.0
23.7
177.9
17.0
21.2
47.2
68.9
78.2
37.5
51.0
19.8
32.4
39.7
48.2
37.3
23.3
125.6
138.1
42.2
27.9
24.2
48.2
53.0
39.0
38.8
30.7
36.6
23.8
23.2
21.1
16.7
23.6
178.1
17.0
21.1
42.2
66.7
79.2
39.3
48.3
18.2
33.0
40.0
47.6
38.4
23.4
125.8
138.7
42.2
28.2
24.4
48.3
53.2
39.1
38.5
30.8
36.8
28.6
22.0
16.5
17.1
23.9
178.4
17.1
21.2
44.3
71.0
78.4
38.0
55.2
18.1
32.9
39.6
47.9
36.6
23.4
125.6
138.1
42.1
27.9
24.2
48.1
52.9
39.0
38.8
30.6
36.6
29.7
17.3
16.4
16.9
23.6
178.0
17.0
21.1
38.7
28.0
78.2
39.3
55.8
18.9
33.6
40.3
47.7
37.3
24.0
128.1
139.9
42.1
29.2
26.6
48.2
54.5
72.7
42.3
27.0
37.4
28.7
16.7
15.5
17.1
24.6
180.6
26.8
16.4
38.8
27.3
79.0
38.8
55.4
18.4
33.2
39.5
47.7
37.1
23.4
125.9
137.9
423
28.5
27.1
48.2
53.7
32.0
42.8
71.8
428
28.2
15.5
15.7
16.8
23.2
177.6
17.0
17.2
38.5
26.9
77.4
38.5
54.8
18.2
32.3
39.6
47.2
38.4
23.0
124.8
138.0
42.2
25.5
20.3
36.4
57.2
33.6
49.7
33.1
76.7
28.0
15.4
15.7
16.4
23.1
24.3
18.0
177.0
WI
VW
12071
~1321
c731
Cl571
c731
PO81
Cl351
P-3
1542
S. B. MAHATOand A. P. KUNDU
Table 1. Continued
221P
222
223
2rMp
225
22iiM
227
228
229
230
39.0
26.3
74.2
43.8
48.0
18.3
33.0
40.0
48.5
37.1
24.2
125.5
139.2
43.0
27.3
24.0
47.5
52.2
39.2
30.9
37.0
33.0
64.6
12.7
15.6
17.5
24.2
179.7
17.1
21.1
38.2
27.5
80.7
42.5
55.7
18.3
33.0
39.3
47.4
36.5
23.4
125.2
137.6
41.8
29.9
24.0
47.9
52.7
38.9
38.7
30.5
36.5
22.4
64.4
15.8
16.7
23.4
177.9
16.9
21.1
38.5
26.9
73.3
52.2
49.6
19.5
34.5
39.8
45.9
36.8
24.1
125.6
137.6
40.0
31.1
25.4
45.7
52.3
70.4
39.8
24.8
36.1
178.2
9.8
13.8
14.4
24.6
178.3
26.9
14.8
39.8
29.1
78.3
49.2
56.9
20.9
33.9
40.2
47.2
37.9
24.5
128.1
139.9
42.2
29.1
26.5
48.3
54.7
72.7
42.2
27.0
38.4
24.2
180.6
13.9
17.1
24.5
180.6
27.0
16.8
42.9
66.1
79.3
38.7
48.8
18.6
33.5
40.6
47.6
38.8
24.1
128.0
139.9
42.9
29.2
26.4
48.3
54.6
72.7
42.4
26.9
38.5
29.4
22.3
16.6
17.3
24.7
180.1
27.1
16.8
39.4
27.4
80.2
41.4
55.3
67.3
42.7
42.9
47.8
38.3
24.4
129.5
140.2
42.9
28.0
26.6
47.8
55.3
73.9
43.1
26.8
39.0
17.6
29.1
16.8
22.4
24.9
179.2
27.3
16.5
41.7
28.4
78.8
39.7
56.4
67.8
41.3
40.5
48.3
37.1
24.1
128.4
139.3
42.6
29.3
26.5
48.5
54.7
72.8
42.4
27.0
38.5
17.1
28.6
16.8
18.0
24.7
180.7
27.2
16.8
46.7
69.0
79.9
42.9
48.8
18.4
32.8
39.8
47.7
38.3
23.5
125.7
138.7
42.3
28.2
24.4
48.3
53.1
39.3
39.1
30.9
36.8
69.3
13.1
17.1
17.1
23.9
178.4
17.3
21.2
41.6
66.6
78.6
41.1
42.1
17.8
32.4
39.6
47.9
37.9
23.3
125.2
138.4
42.1
28.0
24.2
48.1
52.9
39.0
38.9
30.6
36.6
71.3
17.5
16.8
16.9
23.7
178.1
17.0
21.2
41.8
66.2
73.3
43.8
48.5
18.2
33.0
39.5
47.3
37.9
23.3
125.1
138.1
41.9
27.8
24.1
47.9
52.7
38.9
38.7
30.5
36.5
22.0
65.5
16.7
16.7
23.6
178.0
16.9
21.1
Pm
c2111
c-w
cw
c2131
c2141
c2151
Cl571
c731
Cl581
1543
Table 1. Continued
UP
232p
233
234p
usM
236
237
2w
239
241P
38.9
27.1
73.1
42.9
48.8
18.9
33.4
40.4
47.9
31.3
24.1
128.1
140.0
42.2
29.4
26.5
48.3
54.7
12.1
42.4
21.0
38.5
68.2
l3.1
17.3
16.8
24.9
180.7
21.2
16.0
38.8
28.5
80.3
43.2
56.5
19.3
34.0
40.4
41.9
31.2
24.3
127.9
140.0
42.1
29.1
26.5
48.4
54.7
728
424
27.0
38.6
23.7
64.6
17.2
16.8
24.1
180.8
21.2
16.1
33.1
25.2
70.6
42.1
49.5
18.7
32.9
40.0
47.1
36.8
23.7
129.1
137.9
41.1
28.2
25.5
41.9
53.2
73.1
41.1
26.0
37.4
21.6
65.5
15.6
16.5
24.6
178.2
27.4
16.1
48.1
68.6
80.9
54.1
52.2
21.4
33.3
40.5
48.1
38.5
24.2
121.1
139.9
42.0
29.1
26.3
48.6
54.1
72.1
42.0
27.1
38.5
180.6
13.4
17.3
17.1
24.1
180.0
27.1
16.8
40.5
26.2
121
56.4
49.6
70.8
40.5
39.1
41.1
35.9
23.1
128.6
137.8
42.0
28.4
25.6
41.9
53.6
73.2
41.5
26.2
31.7
209.3
10.1
17.0
11.1
24.5
181.2
27.1
16.1
14.6
14.9
19.9
40.6
53.2
17.9
32.8
41.8
48.0
37.4
24.5
130.0
137.3
41.8
29.8
26.1
48.5
52.6
13.2
42.9
21.0
38.1
28.3
16.1
11.4
16.9
25.6
178.3
21.4
17.1
14.7
11.0
19.9
40.6
53.2
17.9
32.8
41.8
48.0
31.4
24.6
130.1
137.2
41.8
29.8
26.1
48.5
52.6
13.2
42.9
26.9
38.1
28.3
16.1
11.4
16.9
25.6
178.4
21.4
17.1
50.3
69.6
84.7
38.8
51.4
68.8
41.8
41.2
49.1
40.3
24.1
129.6
139.4
421
29.5
27.8
49.1
55.1
13.6
43.1
26.6
39.0
29.0
16.6
18.5
18.8
24.8
182.2
27.1
18.5
48.4
61.7
82.9
41.2
53.3
21.7
66.9
39.2
41.4
38.4
22.8
127.6
137.5
41.2
28.7
25.4
41.9
55.3
71.8
41.1
24.8
37.1
25.2
16.6
16.8
16.6
21.0
180.6
22.9
14.6
48.2
69.0
78.5
43.1
48.6
67.6
39.0
39.5
48.9
38.0
25.0
126.0
138.6
44.3
28.7
26.0
48.0
53.3
38.1
39.1
31.0
37.5
66.6
15.5
17.2
18.6
23.8
179.8
24.0
21.3
47.8
68.6
78.2
43.6
48.2
18.6
33.0
40.3
48.2
38.2
24.1
128.1
139.4
42.1
28.9
26.8
48.2
54.4
725
42.1
21.2
38.2
66.5
14.3
17.3
17.3
24.6
178.4
21.2
16.6
WI
cm
CM
C2l7l
C2181
~2191
~2191
c2201
cm
I?221
C2l7-l
1544
Table 1. Continued
242p
243
SUP
245
246
247
248P
249
250
zslP
zszp
47.8
68.7
85.8
44.0
56.6
19.4
33.8
40.4
47.9
38.3
24.4
127.9
140.0
42.1
29.3
26.9
48.3
54.6
72.7
42.4
26.4
38.5
24.2
65.7
17.3
17.1
24.6
180.7
27.1
16.8
32.7
24.6
67.0
45.3
46.4
18.4
32.7
39.8
46.9
36.6
23.8
128.9
138.0
41.2
28.2
25.5
47.9
53.3
73.1
41.1
26.0
37.5
70.3
66.0
14.9
16.6
24.6
178.5
27.4
16.1
48.1
69.0
78.4
43.7
48.1
18.7
33.0
41.0
48.1
38.2
24.4
127.6
140.2
42.0
27.6
25.7
38.8
55.7
73.5
42.8
27.1
36.3
66.7
14.4
17.6
17.1
24.4
69.4
27.1
17.1
48.2
67.8
76.6
42.8
47.2
27.9
67.0
38.3
47.1
36.7
23.8
126.7
138.5
41.4
28.7
25.5
47.9
54.0
72.4
41.1
25.3
37.7
64.5
17.1
22.3
14.8
25.9
178.4
23.0
13.3
528
87.5
177.2
48.5
61.9
18.9
33.0
40.9
46.8
43.3
25.4
129.4
137.9
42.0
28.0
18.6
58.8
53.5
72.8
38.9
33.4
73.6
27.3
21.0
16.0
16.9
25.1
177.3
27.0
15.8
528
87.4
177.2
48.5
61.8
19.0
35.8
41.9
46.7
43.3
25.4
130.3
139.2
46.9
68.2
35.4
47.0
53.7
73.0
41.0
25.8
37.0
27.3
21.0
15.6
17.4
19.2
177.8
27.2
16.0
68.8
156.7
134.0
42.1
63.7
17.7
34.7
42.1
42.4
51.0
26.9
128.3
140.2
42.3
29.7
27.0
48.3
54.8
72.8
43.7
26.4
38.4
30.1
21.7
18.9
16.6
25.3
180.5
27.2
16.6
62.8
148.9
137.5
42.6
63.0
17.2
37.4
47.9
42.9
41.3
26.5
129.2
138.4
41.7
28.7
25.5
50.8
53.3
73.1
41.2
26.1
33.9
21.3
29.6
18.6
18.6
25.2
25.2
27.4
16.1
37.0
24.3
80.6
38.6
51.2
18.2
32.0
40.7
154.2
37.9
115.1
123.0
141.4
43.1
28.2
26.1
33.7
57.3
39.0
39.5
31.2
41.4
28.2
17.4
17.6
22.2
25.5
28.7
16.8
21.5
48.5
68.7
83.8
39.4
56.1
18.8
35.1
39.9
48.4
38.4
23.6
125.9
139.5
45.1
29.2
27.1
49.8
134.7
-
48.9
68.3
78.9
41.6
49.4
24.0
34.5
39.5
47.7
38.4
23.5
125.8
139.5
45.1
29.1
27.1
49.8
134.7
34.8
31.9
35.6
29.4
17.8
17.7
18.4
22.1
178.7
19.7
18.9
34.8
31.9
35.6
11.1
18.1
18.4
22.2
178.7
19.7
18.9
c2231
CW
c217l
iwl
P241
c2241
r2251
l-2261
~2271
i?W
C-W
1545
Table 1. Continued
259
254
25s
256
251
258
259
41.9
71.9
82.3
31.5
52.2
21.0
34.2
39.2
46.1
31.9
24.0
126.1
139.7
45.2
29.0
27.1
49.8
134.7
-
15.9
18.5
22.1
178.7
19.7
18.9
42.0
66.4
78.8
38.2
48.0
17.9
32.6
39.5
47.2
38.1
23.2
125.7
137.8
41.8
27.8
24.2
48.1
54.1
37.2
152.8
321
38.6
28.4
21.7
16.3
16.8
23.6
177.2
16.0
105.0
41.6
66.1
13.2
43.8
48.5
18.1
32.9
39.5
47.3
37.9
23.3
125.5
137.8
41.9
27.7
24.1
48.1
54.6
37.1
152.7
32.1
38.6
22.0
65.7
16.7
16.6
23.5
177.2
16.0
105.0
38.8
27.4
79.0
38.8
55.4
18.3
34.1
40.9
50.5
37.1
21.4
26.2
39.2
42.0
26.6
38.3
34.5
48.7
39.4
154.6
25.6
38.9
28.0
15.4
16.8
15.9
14.8
19.5
25.5
107.2
38.8
27.4
79.0
38.9
55.3
18.3
34.3
41.1
50.4
37.1
21.6
21.6
39.2
42.3
27.0
36.7
34.4
48.7
36.3
139.8
118.9
42.2
28.0
15.4
16.3
16.1
14.8
17.7
22.5
21.7
36.5
24.2
81.1
37.8
50.0
24.0
116.2
145.4
48.2
35.1
16.9
32.5
37.8
41.3
28.9
31.5
32.1
55.0
35.4
38.0
29.2
37.8
21.5
15.8
13.0
23.6
22.7
32.1
25.6
22.5
34.8
24.2
80.9
37.8
50.6
19.0
25.3
134.0
134.5
37.4
20.5
33.1
38.2
41.1
27.3
29.6
31.8
52.4
35.9
38.2
29.1
37.8
21.9
15.6
19.9
22.1
16.2
32.0
25.2
22.4
12281
Cl581
Cl561
34.8
31.9
35.6
15.9
-
II441
[441
c911
c911
260
38.7
27.3
79.0
38.8
55.2
18.7
33.1
41.9
50.2
37.1
21.1
21.3
50.3
41.7
33.1
18.7
56.3
37.3
40.3
18.7
42.1
33.2
28.0
15.4
15.9
16.5
15.9
15.9
21.5
33.4
E931
Ml
262
38.3
25.4
76.0
37.5
49.0
18.7
33.4
41.5
50.2
31.2
21.2
227
46.5
39.5
33.4
117.9
147.7
37.6
41.5
18.1
41.8
36.1
28.3
22.2
16.0
16.9
17.7
29.9
20.7
33.5
38.7
27.4
79.1
38.9
55.3
18.7
33.5
41.3
50.5
37.1
21.4
22.7
46.5
39.4
33.4
117.8
147.7
37.1
41.5
18.2
41.8
36.1
28.1
15.5
16.2
16.9
17.6
29.9
20.6
33.5
38.7
27.4
79.0
38.8
55.1
18.4
33.1
41.7
50.2
37.0
21.2
21.2
50.2
41.7
33.1
18.4
55.1
37.0
38.7
21.4
79.0
38.8
28.0
15.4
16.0
16.5
16.5
16.0
15.4
28.0
38.6
25.2
78.8
38.2
55.7
18.9
45.1
39.0
57.1
36.1
25.4
27.6
62.8
138.2
122.2
24.0
49.5
38.9
29.2
27.2
19.2
37.1
15.7
19.8
28.1
15.4
56.0
13.4
27.5
14.6
c931
1931
r941
[951
263
264
1546
Table 1. Continued
MS
266
267
268
2459
270
271
272
273
274
275
38.6
25.2
78.8
38.2
55.7
18.9
45.2
39.0
56.8
36.0
25.4
27.2
62.9
138.5
122.0
24.0
43.4
37.1
31.2
27.5
76.2
37.4
15.7
19.8
28.1
15.4
56.2
13.3
27.7
21.8
38.6
25.2
76.1
37.7
49.4
18.8
44.9
38.2
56.9
35.9
25.4
28.4
62.7
138.6
122.0
24.0
43.4
37.3
31.2
27.1
76.2
37.4
15.6
19.8
30.0
13.5
56.3
13.3
21.8
27.7
38.5
22.4
88.5
38.2
56.3
18.8
45.2
38.9
57.2
36.1
25.3
27.7
62.9
138.3
122.1
24.1
49.5
38.9
29.7
27.2
79.2
37.1
15.7
19.8
28.1
16.2
56.1
13.4
27.5
14.6
38.4
22.3
88.4
38.2
56.2
18.7
45.1
38.9
55.0
36.6
25.7
27.2
62.6
138.6
120.8
24.6
53.6
37.1
38.7
37.1
209.4
63.2
15.7
19.8
28.1
16.2
55.8
12.7
16.3
201.9
38.9
22.4
88.4
38.5
56.4
18.8
37.1
38.9
57.4
36.1
25.7
27.3
62.8
138.6
121.6
29.5
45.7
56.1
38.3
37.9
212.9
49.4
15.7
19.8
28.2
16.2
45.2
11.5
11.0
-
38.6
22.5
88.6
38.3
56.1
18.9
37.0
41.1
57.1
35.9
24.5
27.3
63.0
138.3
121.8
25.6
50.6
56.4
37.2
21.8
80.3
39.0
15.8
19.9
28.2
16.2
45.3
13.8
24.3
64.0
36.9
27.8
79.3
39.0
50.7
24.2
116.2
145.0
47.9
35.3
16.7
34.1
36.5
41.0
29.1
27.9
38.2
43.4
23.3
21.3
27.2
39.0
27.6
14.6
12.9
23.8
22.2
16.1
25.3
23.0
38.3
34.8
216.5
47.8
52.3
24.5
116.1
145.1
47.4
35.3
16.8
33.9
36.5
41.0
29.1
27.9
38.1
43.4
23.2
21.5
37.0
39.0
24.5
21.4
12.5
23.8
22.2
16.0
25.3
22.9
31.7
23.0
78.3
36.6
45.6
24.0
116.1
145.3
47.5
35.0
16.6
34.0
36.5
41.1
29.1
27.9
38.2
43.4
23.2
21.6
37.1
39.0
27.2
21.3
12.8
23.7
22.2
16.1
25.3
23.0
37.2
24.7
81.1
37.6
44.6
17.4
19.0
40.3
150.2
37.3
116.7
39.1
37.2
38.2
28.1
27.9
38.2
41.2
23.3
21.8
37.6
39.3
27.4
16.2
25.3
15.2
16.5
16.4
25.3
23.0
37.9
27.2
79.1
38.8
55.7
18.7
32.4
39.4
48.4
36.6
23.2
117.5
146.7
41.8
24.6
29.2
37.4
41.7
23.9
21.9
36.2
37.7
28.0
15.3
15.4
16.3
21.5
21.3
25.5
22.2
c951
c951
c951
c951
~2291
c2291
c911
c911
c2301
c911
WI
1547
Table 1. Continued
276
277
278
34.6
20.2
41.5
33.7
49.1
19.5
34.5
42.0
46.0
37.2
22.7
21.8
48.6
43.3
32.1
25.9
42.8
36.6
34.8
36.0
30.6
42.1
33.9
22.0
23.1
22.6
17.2
12.1
33.5
23.0
34.4
20.2
41.5
33.8
49.2
19.4
34.4
421
45.9
37.2
22.6
22.2
48.6
43.5
30.4
17.7
55.1
42.5
35.7
36.9
43.8
217.7
33.9
22.0
23.1
22.5
16.8
13.7
25.6
26.5
33.2
29.2
79.3
39.2
48.0
19.1
34.5
41.9
45.8
36.9
22.6
21.5
48.6
42.8
31.8
19.4
49.0
38.5
34.9
35.0
35.8
76.5
29.1
16.1
22.7
22.7
17.3
13.5
29.9
18.6
ml1
[loll
Poll
279
33.2
29.2
79.3
39.2
48.0
19.1
34.6
41.9
46.2
36.9
22.5
21.3
49.8
43.4
32.6
23.5
45.9
36.5
35.6
30.2
34.8
81.3
29.1
16.1
22.7
22.5
17.3
15.9
27.8
26.0
cw
280
281
31.7
33.9
220.5
47.0
43.4
20.6
33.9
42.0
47.5
36.1
22.1
21.3
48.6
42.3
31.7
19.3
48.9
38.6
34.8
35.0
35.8
76.5
29.4
19.6
23.4
221
17.2
13.6
29.9
18.5
31.6
33.8
220.1
47.2
43.3
20.6
33.8
42.0
47.4
36.2
220
22.2
48.6
43.3
30.4
17.6
55.0
42.2
35.6
36.8
43.8
217.3
29.3
19.6
23.3
22.0
16.5
13.7
25.5
26.4
WI
cw
282
41.4
70.8
84.3
38.7
47.9
18.8
34.3
41.7
46.1
37.4
22.7
21.4
48.7
42.5
31.4
19.6
46.5
38.9
34.8
34.8
35.2
78.4
29.6
17.2
23.8
22.5
17.1
13.4
29.3
19.6
cw
283
41.6
71.2
84.7
39.1
48.0
19.0
34.3
41.9
46.5
37.7
22.9
21.6
48.9
426
31.9
19.4
48.7
38.5
35.1
35.1
35.9
76.6
29.8
17.3
24.0
22.6
17.2
13.6
29.8
18.6
WI
284
39.0
71.8
81.0
38.7
47.5
18.7
34.0
41.7
46.1
37.3
22.7
21.4
48.6
42.5
31.6
19.5
46.5
39.0
34.8
34.8
35.2
78.3
29.4
17.9
23.6
22.4
17.0
13.3
29.4
19.5
cw
285
286
23.9
25.7
82.5
38.3
33.4
20.2
32.7
40.3
46.7
44.9
20.8
21.7
48.5
42.8
31.6
19.2
49.0
38.5
34.9
35.0
35.8
76.5
26.4
20.2
178.2
22.1
17.1
13.5
29.8
18.5
39.2
71.9
81.0
39.1
47.6
18.9
34.4
41.6
46.5
37.5
227
24.1
48.9
43.3
32.7
20.6
54.2
44.2
40.0
27.4
47.9
148.1
29.4
18.0
23.7
22.6
17.1
15.1
109.3
19.6
Wll
cw
1548
Table 1. Contimred
287
288
289
290
291
292
293
294
295
296
39.0
71.8
81.8
39.0
47.6
18.7
34.4
41.4
46.6
37.5
22.8
24.0
49.4
43.0
31.8
19.5
139.7
49.8
41.4
27.4
136.2
26.3
29.3
17.9
23.6
22.5
15.0
18.7
21.2
21.8
40.3
18.7
42.1
33.2
56.3
18.7
34.3
41.0
50.5
37.5
20.8
25.2
38.0
42.8
27.4
35.6
43.0
48.3
47.9
150.6
29.9
40.0
33.4
21.6
16.1
16.1
14.6
18.0
109.2
19.3
38.7
27.4
78.9
38.8
55.3
18.3
34.2
40.8
50.4
37.1
20.9
25.1
38.0
42.8
27.4
35.5
43.0
48.2
47.9
150.9
29.8
40.0
28.0
15.4
16.1
15.9
14.5
18.0
109.3
19.3
40.2
18.6
42.1
33.2
56.3
18.6
34.2
41.1
50.4
37.4
20.7
25.3
37.2
42.7
27.0
29.2
47.7
48.7
47.7
150.2
29.8
33.9
33.3
21.5
16.0
16.0
14.8
60.4
109.4
19.1
40.2
18.6
42.0
33.2
56.3
18.6
34.2
40.8
50.6
37.4
20.7
25.5
38.2
42.3
29.6
32.1
56.5
49.4
46.9
150.3
30.6
36.9
33.3
21.5
16.0
16.0
14.7
176.3
109.4
19.3
38.7
27.4
78.9
38.8
55.3
18.3
34.3
40.7
50.5
37.2
20.8
25.5
38.4
42.4
30.5
32.1
56.3
46.8
49.2
150.3
29.7
37.0
27.9
15.3
16.0
16.1
14.7
180.5
109.6
19.4
34.0
23.2
75.5
j9.0
49.3
18.6
34.8
41.2
50.7
37.7
21.0
26.1
38.5
42.9
31.2
32.8
56.6
47.7
49.7
151.2
29.9
37.5
29.2
22.5
16.4
16.4
14.9
178.7
109.8
19.4
39.5
27.3
77.9
38.4
55.2
17.9
33.9
40.3
51.0
37.1
20.3
27.0
38.4
59.5
25.8
37.5
55.8
51.7
46.5
149.3
30.0
36.5
27.7
15.3
16.4
16.8
175.3
176.1
109.5
18.6
38.7
27.3
78.9
38.8
55.5
18.2
34.3
40.8
50.4
37.1
20.7
25.5
38.7
42.5
29.2
28.8
59.3
48.0
47.5
149.7
29.8
33.2
27.9
15.4
15.9
16.1
14.2
205.6
110.1
19.0
33.6
25.9
76.4
37.5
49.9
18.4
34.4
41.0
50.5
37.3
20.8
25.6
38.7
42.6
29.5
28.8
59.3
48.0
47.5
149.8
30.0
33.2
28.2
222
15.9
16.1
14.2
205.6
110.1
19.0
WI
c1021
PO21
PO21
c2311
~2321
Iwl
PW
WI
Cal
1549
Table 1. Continued
297
298
299
300
301
302
303
304
305
306
307p
39.0
27.5
78.6
39.4
55.6
18.1
35.3
41.1
55.7
37.7
70.5
27.7
37.7
42.6
27.5
35.5
43.0
47.7
47.7
150.2
29.9
39.9
28.3
15.6
16.1
17.3
14.5
18.1
109.8
19.4
38.9
27.4
78.9
38.8
54.9
18.5
37.8
42.5
51.0
37.4
21.0
25.2
37.6
47.9
69.7
46.5
43.0
48.1
47.4
150.4
30.1
39.7
27.9
15.4
16.1
16.6
8.0
19.2
109.7
19.4
38.9
27.4
78.8
38.9
55.4
18.3
34.3
41.0
50.0
37.1
20.9
24.9
37.3
44.1
36.9
76.9
48.6
47.7
47.6
149.8
30.0
37.8
28.0
15.4
16.1
16.1
16.1
11.8
109.6
19.4
38.5
27.8
80.9
42.8
55.9
18.4
34.9
40.9
50.5
38.0
21.2
25.1
36.9
42.8
27.4
35.6
43.0
48.0
48.3
150.9
29.9
40.0
224
64.5
15.9
16.7
14.6
18.0
109.4
19.3
38.8
27.2
78.9
38.9
55.3
18.3
34.3
40.9
50.4
37.2
20.9
25.3
37.3
427
27.0
29.2
47.8
48.8
47.8
150.6
29.8
34.0
28.0
15.4
16.1
16.0
14.8
60.2
109.6
19.1
39.6
34.1
218.3
47.3
54.9
19.7
33.6
40.8
49.7
36.9
21.6
26.7
38.1
42.9
27.4
35.4
43.0
48.8
43.8
154.7
31.8
39.8
26.7
21.0
16.0
15.8
14.5
17.7
106.8
65.0
421
66.6
78.9
38.3
51.2
17.9
34.0
40.8
49.4
38.5
20.8
25.8
38.1
42.4
29.6
32.1
56.6
48.1
46.9
150.5
30.5
36.9
28.4
21.6
17.1
15.9
14.7
176.6
109.6
19.3
39.2
27.9
73.6
42.9
48.9
18.6
34.6
41.2
49.8
37.6
21.3
26.2
38.7
42.9
30.3
32.9
56.7
47.8
49.7
151.4
31.8
37.6
68.2
12.9
16.5
19.5
14.9
178.9
109.9
19.5
~2371
C2381
Cl021
cl241
c491
c491
P391
c2401
79.0
37.5
75.7
38.9
53.1
18.0
34.1
41.3
51.4
43.5
23.8
25.0
38.0
42.8
27.4
35.5
42.9
48.3
47.9
150.8
29.7
39.9
27.8
14.9
11.9
16.2
14.4
18.0
109.4
19.2
55.7
49.1
46.8
150.4
30.4
37.0
15.6
27.3
16.0
15.9
14.5
177.6
109.3
19.2
38.7
27.5
78.9
37.3
52.5
27.5
74.7
46.9
50.5
37.3
20.9
25.3
38.7
42.8
29.4
36.1
42.8
48.3
48.2
151.0
30.0
40.2
28.0
15.4
15.1
10.2
15.8
17.9
109.3
19.4
CW
PW
I2361
39.0
28.1
78.5
38.7
55.2
18.1
34.2
40.5
50.4
37.9
20.7
25.4
79.0
42.2
29.5
1550
Table
I. Continued
308
309
31op
311P
312
313p
314
31sp
316
317p
39.2
25.5
77.9
39.2
55.9
18.6
35.8
41.8
50.2
37.6
21.3
27.7
39.4
46.6
28.0
33.7
56.3
50.0
47.5
151.1
31.0
37.6
28.3
15.4
16.6
17.0
59.9
178.8
109.5
19.3
35.4
26.6
72.8
52.8
45.2
22.1
35.9
42.9
56.6
39.6
69.9
38.5
37.7
43.4
30.2
32.9
56.6
49.5
47.6
150.9
31.3
37.5
179.7
18.1
18.3
17.2
14.8
178.8
110.1
19.6
35.4
27.1
73.1
53.0
44.2
21.3
35.5
42.8
56.0
39.0
69.8
38.3
37.6
43.3
30.1
32.8
56.5
49.5
47.5
150.8
31.3
37.4
209.9
17.8
15.0
16.8
14.8
178.8
110.0
19.5
41.5
28.9
78.7
40.6
56.7
67.8
42.6
40.7
51.4
37.3
21.6
25.7
37.1
44.5
37.7
76.3
49.4
48.4
48.3
150.9
30.5
38.5
27.9
17.3
17.9
16.8
16.7
12.0
109.9
19.4
39.9
34.1
218.3
47.2
54.5
19.8
36.9
42.4
50.3
37.1
21.5
25.2
37.0
47.8
69.0
40.3
47.9
48.3
47.2
149.9
30.0
33.9
26.6
21.0
16.1
16.3
8.1
61.5
110.0
19.1
66.6
36.2
75.1
40.0
58.2
18.8
35.9
42.7
53.5
46.3
76.5
35.1
36.2
43.1
30.2
38.0
43.2
48.7
48.2
150.6
28.0
40.1
28.7
14.4
15.7
17.8
14.3
18.3
110.3
19.4
38.2
30.6
82.3
40.9
59.5
22.0
37.5
42.7
54.5
32.2
24.7
30.8
41.3
44.8
33.0
38.0
46.4
53.3
47.4
150.7
35.4
33.1
31.2
19.3
18.6
19.2
17.8
62.9
109.8
67.8
66.7
37.7
75.2
42.8
58.3
18.8
35.8
43.0
53.5
46.4
76.6
35.1
36.3
43.3
32.4
38.1
43.3
49.1
44.0
156.3
28.1
40.0
28.7
14.4
15.7
17.8
14.3
18.1
106.6
64.4
38.6
28.0
78.0
39.4
55.9
18.9
32.8
39.8
47.8
37.6
23.8
122.4
141.1
42.2
24.0
26.6
44.1
40.2
30.0
38.6
80.4
36.6
28.6
16.4
15.6
16.3
23.5
181.9
22.1
39.2
28.2
78.0
39.4
55.7
18.6
34.9
41.5
50.3
37.3
21.3
28.5
40.1
44.7
37.0
68.2
59.0
42.5
56.4
69.2
81.6
42.5
28.6
16.3
16.3
16.4
15.6
177.0
30.7
31.0
c2421
C2431
P441
C2451
c2441
c351
~2411
c491
Cl461
318
40.5
18.8
42.3
33.3
56.5
18.8
34.6
41.3
50.4
37.6
21.0
27.1
38.1
43.2
27.5
35.8
43.2
47.8
44.9
29.5
22.0
40.5
33.4
21.7
16.1
16.2
14.6
18.2
15.2
23.0
cw
1551
Table 1. Continued
319
38.7
27.4
78.8
38.8
55.2
18.3
34.4
40.8
50.1
37.1
20.9
26.8
37.8
43.0
27.4
35.5
43.1
47.5
44.6
29.3
21.9
40.4
28.0
15.4
16.0
16.0
14.4
18.0
15.1
23.0
rP1
320
40.2
18.6
42.0
33.2
56.1
18.6
34.5
41.5
50.2
37.4
21.2
29.1
37.4
43.5
27.5
35.5
44.6
48.2
49.9
73.3
28.7
40.2
33.3
21.5
16.1
16.2
14.8
19.2
24.8
31.4
IN21
321
322
40.5
18.6
42.1
33.3
56.5
18.7
35.0
41.0
51.2
37.5
21.5
28.4
40.3
43.7
28.3
37.7
48.4
139.0
138.7
26.4
28.7
39.2
33.3
21.5
16.6
16.7
15.4
23.7
21.4
21.9
40.5
18.7
42.1
33.3
56.6
18.7
34.8
40.9
51.3
37.5
21.2
28.2
39.5
43.5
27.0
39.7
48.3
141.4
135.7
145.3
37.4
36.8
33.3
21.5
16.0
16.3
15.4
16.7
111.7
23.6
Cl021
Cl021
323
38.7
27.3
78.7
38.8
55.2
18.2
34.4
41.0
49.1
37.1
21.0
26.6
38.1
43.1
34.2
74.2
47.4
40.4
43.8
29.3
21.3
33.2
27.9
15.4
16.0
16.0
17.2
19.1
15.2
22.9
WI
324
325
326
327
328
329
38.8
27.3
79.1
38.0
55.2
18.4
32.9
40.1
47.7
36.9
23.4
125.1
138.8
421
23.4
26.0
38.8
54.4
39.5
39.4
30.7
35.2
28.2
16.8
15.6
15.7
69.9
23.3
21.3
17.3
40.7
38.9
37.8
61.6
18.8
34.7
41.4
50.0
45.6
23.6
25.1
38.3
43.0
27.8
35.7
42.9
48.4
48.0
150.7
29.9
40.1
32.7
26.2
16.1
16.3
14.7
18.0
109.2
19.4
55.4
224.5
45.7
59.2
18.1
33.8
41.2
48.7
41.6
23.7
24.8
38.1
42.9
27.5
35.5
429
48.2
47.9
150.4
29.8
39.9
27.7
21.0
17.5
16.2
14.6
18.0
109.3
19.3
51.5
82.3
44.4
61.8
18.6
34.4
41.4
49.9
43.4
23.6
24.9
38.2
42.9
27.6
35.6
428
48.3
47.9
150.5
29.8
40.0
31.8
19.0
17.2
16.1
14.6
18.0
109.2
19.3
51.3
81.2
41.9
61.1
19.0
34.4
41.4
49.7
40.9
23.6
24.9
38.2
42.9
27.6
32.1
42.8
48.3
47.9
150.5
29.8
40.0
25.4
25.2
17.4
16.2
14.6
18.0
109.2
19.3
65.3
84.6
43.2
56.4
19.4
33.9
41.6
44.5
49.3
23.5
25.4
38.5
42.8
29.8
32.1
56.5
49.3
46.8
150.1
30.6
36.8
30.7
18.4
18.4
16.5
14.7
176.4
109.4
19.1
c2461
Cl021
cw
w21
c1021
c1021
330
40.4
18.8
42.2
33.3
56.2
18.8
33.4
41.9
50.5
37.5
21.0
24.0
49.4
41.8
33.7
22.7
54.7
44.4
41.7
27.7
48.0
32.0
33.4
21.6
15.9
16.6
16.7
15.9
22.9
23.9
Wl
1552
Table 1. Continued
331
40.4
18.8
42.2
33.3
56.5
18.8
33.2
42.2
51.1
37.6
21.7
23.8
39.1
41.5
26.8
222
49.4
44.2
41.7
25.0
47.7
31.0
33.5
21.7
16.1
16.4
16.7
22.1
18.4
24.1
C2471
332
40.4
18.8
42.2
33.3
56.2
18.8
33.4
42.0
50.5
37.5
21.0
22.8
48.6
42.4
32.8
21.6
53.3
44.5
39.9
23.9
45.5
28.9
33.4
21.6
15.9
16.8
16.8
15.2
17.5
221
P481
333
40.4
18.9
42.2
33.3
56.6
18.6
33.0
42.4
51.2
37.5
21.6
24.3
43.1
40.7
33.0
20.1
51.2
44.4
44.4
26.7
48.3
28.9
33.5
21.7
16.0
22.0
16.6
227
21.7
26.7
CW
334
40.2
18.6
42.0
33.0
56.0
18.6
32.9
41.6
50.4
37.2
20.8
23.8
49.5
41.8
34.2
21.7
53.8
43.9
43.4
26.5
50.9
73.9
33.2
21.4
15.6
16.4
16.5
22.7
28.7
30.8
PW
335
40.4
18.7
42.2
33.2
56.2
18.7
33.4
41.9
50.5
37.5
21.0
24.0
493
41.8
33.6
22.0
54.2
44.5
41.6
26.3
41.0
38.7
33.4
21.6
15.8
16.7
16.2
15.9
68.1
21.6
C2491
336
337
40.5
18.7
42.2
33.2
56.3
18.8
33.4
41.9
50.6
37.5
21.1
24.1
49.5
41.9
33.8
22.6
54.4
44.5
41.8
27.2
42.8
39.6
33.4
21.6
15.7
16.6
16.5
15.9
18.1
67.7
40.4
18.5
43.8
33.6
61.1
69.3
45.5
42.9
49.5
39.4
21.1
24.0
49.8
41.9
34.3
21.9
54.0
44.0
41.3
26.6
51.1
73.9
36.8
22.1
17.1
18.3
17.1
16.1
28.7
30.9
C2491
c2501
338
339
39.6
34.2
218.1
47.3
54.9
19.8
32.7
41.7
49.6
36.8
21.6
24.1
50.0
41.9
34.4
21.9
54.0
44.1
41.3
26.6
51.0
73.9
26.6
21.1
15.7
16.5
16.9
16.2
28.7
41.1
18.6
42.8
32.6
66.5
214.0
51.7
48.5
50.9
44.1
21.6
24.0
49.8
42.4
34.5
22.0
54.2
44.1
41.5
26.8
51.2
73.8
32.7
22.0
17.2
17.0
17.8
16.3
29.0
31.2
c271
340
40.2
18.4
43.5
33.2
58.5
72.0
41.0
42.8
49.4
39.6
21.1
24.0
49.9
42.1
34.3
21.9
54.0
44.0
41.3
26.6
51.1
73.8
36.3
22.2
17.1
18.1
17.1
16.1
28.9
31.0
c271
341
40.2
18.6
41.8
33.0
53.1
29.6
73.3
47.6
50.5
37.4
20.7
24.1
50.0
43.4
38.3
22.2
53.5
44.1
41.4
26.5
51.5
73.8
33.2
21.4
15.5
11.2
17.7
16.2
28.6
1553
Table 1. Continued
342
40.4
18.7
420
33.2
55.8
18.9
36.8
43.5
50.5
37.6
20.8
24.1
48.9
47.1
74.8
32.6
50.5
44.2
40.9
26.9
50.5
73.7
33.3
21.6
15.8
17.4
11.8
15.8
28.7
343
39.3
17.7
36.7
47.7
51.1
21.6
32.8
42.3
50.5
36.7
20.6
23.5
49.0
44.0
41.5
66.8
60.6
45.8
43.7
27.8
49.8
74.1
179.3
16.6
16.1
16.3
18.3
17.1
26.6
34P
73.1
25.8
36.7
33.8
48.4
19.1
35.6
43.3
47.7
43.3
68.6
33.8
49.2
42.4
34.7
22.4
54.7
44.2
41.6
27.0
51.5
72.4
33.7
21.7
18.1
17.4
17.5
16.2
29.9
31.5
Wl
345
73.4
25.5
36.3
33.6
47.7
18.8
35.0
43.0
47.0
43.3
69.9
33.5
48.8
42.1
33.8
22.7
54.5
44.3
41.6
27.3
42.8
39.7
33.4
21.5
17.8
17.2
16.8
15.6
18.2
67.8
Wl
346
40.7
18.4
38.6
38.6
56.6
19.2
35.7
43.6
50.9
37.6
21.2
24.2
492
47.2
74.9
32.8
50.6
44.3
41.0
26.9
50.6
73.8
26.9
65.5
16.4
17.3
11.7
15.8
28.7
31.0
~2511
347
40.3
18.5
43.8
33.7
61.0
68.7
44.7
43.0
49.1
39.5
21.2
23.7
49.4
41.8
33.7
21.5
53.0
43.9
47.7
78.1
56.9
72.8
36.8
21.8
17.1
18.9
16.9
17.4
28.3
348
349
350
351
38.5
26.8
80.8
37.1
54.6
21.2
34.9
43.1
50.2
37.6
20.8
23.6
49.0
45.8
76.7
28.5
50.1
43.9
40.8
23.6
50.4
73.4
28.5
21.9
15.7
15.8
12.7
16.4
27.9
31.0
40.6
20.5
38.0
43.7
56.3
19.2
35.1
43.1
50.4
37.8
21.1
23.9
49.1
45.9
76.9
28.6
49.7
43.9
40.8
26.8
50.2
73.5
28.6
178.0
13.6
17.1
12.7
15.8
28.6
31.0
38.4
19.4
42.5
33.7
57.9
71.5
40.2
42.2
49.2
51.2
21.9
24.1
49.9
42.2
34.8
21.9
53.9
44.0
41.3
26.6
50.9
73.6
35.7
23.5
175.5
15.7
16.7
16.3
28.8
31.0
38.5
26.7
78.2
39.0
60.1
67.8
42.7
42.6
49.1
38.9
20.6
23.0
47.2
43.4
45.4
67.3
57.3
46.5
39.5
25.9
51.9
70.9
30.0
16.1
15.9
16.7
17.5
17.9
30.8
22.6
c2521
~2511
[571
C2531
1554
Table 1. Continued
352
353
354
355
356
357
358
359
360
361
45.4
24.6
49.9
32.5
51.3
20.0
32.1
42.1
50.5
38.0
22.1
24.6
49.0
42.2.
34.6
22.1
54.2
44.3
41.5
26.6
51.1
73.9
31.1
21.8
17.0
16.3
16.3
23.2
29.0
30.9
40.4
18.8
77.2
33.4
56.2
18.8
34.4
41.9
50.5
37.5
21.0
24.0
49.4
41.8
33.7
22.1
54.7
44.4
43.3
81.8
48.8
32.1
33.5
21.7
63.2
16.6
16.7
16.0
21.6
23.7
40.3
18.7
42.1
33.2
56.1
18.5
33.5
41.4
50.6
37.4
20.9
24.2
44.8
40.5
34.0
119.4
147.6
43.6
43.2
27.0
51.3
35.0
33.4
21.6
16.0
16.9
18.0
19.3
21.5
22.0
40.4
18.7
42.2
33.3
56.2
18.8
33.3
41.9
50.5
37.4
21.0
23.8
48.1
41.5
32.9
23.3
56.0
44.4
39.1
28.4
135.6
120.6
33.4
21.6
15.9
16.7
16.6
14.7
19.4
22.8
40.4
18.8
42.2
33.3
56.6
18.6
33.2
41.7
51.0
31.6
21.5
24.6
42.8
42.1
32.2
25.8
49.4
44.3
41.4
28.4
140.4
122.7
33.5
21.7
16.1
20.7
16.6
23.0
21.0
21.5
40.4
18.7
42.1
33.2
56.2
18.7
33.3
41.8
50.9
37.4
21.2
24.0
49.2
41.9
31.8
19.8
135.7
49.7
41.6
27.4
139.8
26.3
33.3
21.6
16.2
16.3
14.9
19.1
21.2
21.9
40.4
18.7
42.2
33.3
56.2
18.7
33.3
41.9
50.4
37.4
21.0
24.0
49.5
42.1
33.7
21.7
54.9
44.8
41.9
27.4
46.5
148.7
33.4
21.6
15.9
16.7
16.8
16.1
110.7
25.0
39.6
34.2
218.1
47.4
54.9
19.7
32.6
41.6
49.7
36.8
21.5
23.9
48.7
42.3
32.6
20.8
53.8
44.2
40.2
21.3
47.9
148.1
26.6
21.3
15.8
16.5
16.5
15.2
109.6
19.7
40.4
18.8
42.2
33.3
56.2
18.7
33.4
42.3
50.5
37.5
21.0
24.0
48.7
42.0
32.7
20.9
53.9
44.3
40.2
27.4
48.0
148.2
33.4
21.6
15.9
16.7
16.8
15.1
109.4
19.7
40.3
18.7
42.1
33.2
56.1
18.7
33.2
41.9
50.3
37.4
20.8
24.8
49.2
42.0
33.2
20.2
54.4
45.3
41.7
26.1
39.1
144.0
33.4
21.6
15.6
15.8
16.1
16.7
122.3
169.7
c2541
I2551
C2481
c2481
WV
C2481
C2481
Cl961
C2481
C2561
1555
Table 1. Continued
362
363
364
365
366
361
368
369
370
371
372
39.5
18.2
40.7
33.0
58.2
71.9
40.0
42.5
49.1
39.3
20.7
23.2
49.6
41.9
33.3
20.2
64.1
44.4
43.3
37.0
83.5
149.1
36.1
22.0
16.9
17.7
16.4
15.2
112.0
38.5
27.0
78.7
39.4
60.8
68.9
40.2
42.5
50.0
39.2
21.6
222
46.7
46.0
119.8
134.5
138.7
47.9
45.7
28.2
140.8
26.5
30.9
16.7
15.5
18.8
17.5
20.4
21.6
21.3
38.8
27.4
79.0
38.8
55.3
18.2
33.7
40.4
50.7
36.8
21.4
23.3
45.2
41.0
32.1
120.0
139.2
37.1
38.3
35.2
32.5
46.2
28.1
15.4
16.2
16.8
17.5
16.3
32.4
24.6
38.7
19.1
42.5
33.2
48.1
24.6
116.3
145.4
51.6
35.6
16.1
32.5
36.1
41.6
30.4
36.4
42.9
54.2
20.1
28.3
59.7
30.7
32.9
21.2
12.9
24.1
21.1
14.1
22.1
23.0
38.7
19.2
42.5
33.2
48.1
24.7
116.9
144.9
51.6
35.6
16.3
31.8
36.5
41.6
29.8
33.1
54.1
56.3
21.7
30.9
60.2
31.7
33.0
21.3
13.0
24.5
19.5
176.2
22.2
23.0
37.3
19.3
41.8
33.3
51.1
18.9
27.0
134.9
133.7
37.8
20.4
27.0
36.7
41.1
30.4
36.0
43.0
52.8
19.4
28.4
59.8
30.8
33.3
21.8
20.3
22.1
15.8
14.6
22.1
23.0
35.5
28.0
79.0
38.9
50.5
20.4
27.2
134.3
134.3
37.6
19.1
30.3
41.1
36.7
27.0
35.9
42.9
52.8
18.9
28.4
59.8
30.8
28.1
15.5
22.1
22.1
15.8
14.6
22.8
22.1
37.2
19.3
41.8
33.4
51.2
19.3
26.8
134.7
133.4
37.8
22.2
28.4
37.0
41.0
29.1
32.7
54.1
54.6
22.1
30.0
60.3
31.8
33.3
21.8
20.2
19.4
14.0
176.5
22.1
22.9
34.1
27.9
78.6
38.4
45.2
28.6
64.2
158.0
142.6
38.6
199.9
50.8
43.3
37.5
27.3
35.8
42.7
51.9
20.3
28.0
59.5
30.7
28.2
16.1
18.0
23.9
19.7
13.9
22.9
22.1
33.7
27.2
78.3
39.0
48.0
36.9
200.7
142.2
160.2
39.5
65.9
42.1
39.4
40.5
25.6
35.7
42.3
51.1
20.2
28.0
59.6
30.6
27.4
15.0
20.0
23.7
16.9
14.6
22.8
21.9
34.4
27.4
78.1
38.6
48.0
36.7
199.9
151.9
156.0
38.2
201.1
51.1
38.5
41.6
26.4
35.8
42.6
50.8
20.4
28.9
59.5
30.7
27.5
14.9
17.9
21.8
20.8
14.0
22.9
22.0
CW
c591
C2581
C2581
C2581
Wl
C2581
C2591
II2591
C2591
PHYTO 37-6-F
1556
Table 1. Continued
373
374
375
376
377
378
379
380
381
382
41.5
19.6
42.5
33.6
44.9
18.0
19.6
40.0
151.7
37.7
115.7
36.8
36.8
38.1
29.4
36.3
43.0
52.1
20.2
28.3
59.7
30.8
32.8
21.7
25.1
15.9
15.4
14.0
22.2
23.0
40.5
20.6
42.2
34.1
45.9
20.7
18.9
39.5
142.9
48.5
121.2
36.6
36.7
38.0
29.3
36.0
42.9
51.9
20.1
28.2
59.6
30.8
31.4
19.8
176.1
15.6
15.5
14.0
22.1
23.0
41.5
19.6
42.5
33.7
44.9
18.1
19.6
40.2
151.6
31.7
115.5
35.5
37.1
38.1
29.7
33.2
54.2
54.0
21.9
31.1
60.3
31.7
32.8
21.7
25.0
15.5
14.1
171.0
22.1
22.9
39.1
28.0
79.0
39.3
44.1
19.0
17.8
39.8
153.4
40.6
120.9
75.9
42.2
37.6
29.5
35.9
43.6
51.4
23.6
28.7
58.9
30.8
27.5
15.7
25.1
15.1
11.3
14.2
22.2
23.1
36.3
28.0
71.4
36.9
52.0
36.4
75.1
47.9
117.0
39.2
121.1
24.5
43.9
57.0
33.0
31.9
40.9
39.4
74.5
30.3
57.3
27.8
21.9
15.4
22.9
15.5
21.7
16.8
16.1
16.5
46.9
68.7
79.9
53.0
41.8
20.2
17.6
39.6
149.6
39.3
117.3
36.7
36.8
37.8
29.3
36.2
43.0
52.0
20.2
28.2
59.7
30.8
177.1
11.8
26.6
16.0
15.4
14.0
22.2
23.0
23.8
21.9
40.9
34.8
145.6
117.6
34.3
51.8
35.7
44.3
25.9
29.2
38.7
39.4
29.2
35.5
42.9
51.9
20.0
28.4
60.1
30.8
30.0
29.8
16.1
17.9
15.1
15.8
22.0
22.9
23.8
21.8
40.8
34.9
145.4
117.4
34.6
51.5
35.7
44.3
26.0
28.2
38.8
39.3
29.9
30.9
54.1
54.0
21.8
31.8
60.7
31.7
29.8
29.7
16.2
17.6
13.6
176.8
221
22.9
36.6
34.8
217.1
47.6
53.2
26.3
22.6
41.0
147.4
39.3
115.6
36.1
36.7
38.2
29.6
35.8
42.8
52.0
20.1
28.2
59.6
30.7
22.v
25.5
21.6
16.9
15.3
13.9
22.1
23.0
42.5
74.1
79.5
40.2
48.9
33.8
71.9
49.1
146.6
41.0
117.5
37.2
38.3
39.9
32.1
37.2
43.8
59.2
70.3
41.9
57.8
30.7
29.0
17.4
22.6
17.1
17.0
15.9
22.2
23.2
66.9
84.8
39.4
48.7
33.6
71.8
49.2
146.7
40.8
117.6
37.3
38.3
39.9
32.1
37.2
43.8
59.2
70.4
41.9
57.8
30.7
28.7
18.0
23.0
17.1
17.0
15.9
22.2
23.2
C2581
mu
C2581
WI
C2471
C2581
P581
E2621
iI
~271
1451
383
46.6
1557
Table 1. Continued
3w
38!F
3w
387p
388
389
390
31.0
28.8
78.0
39.5
49.1
33.9
12.2
49.5
147.6
39.9
117.1
31.3
38.3
39.9
32.1
31.2
43.8
59.3
70.4
41.9
57.8
30.7
28.1
16.4
22.1
17.1
17.0
16.0
22.2
23.2
46.0
69.2
83.6
39.7
49.1
33.9
721
49.2
147.2
41.0
117.3
31.3
38.4
40.0
32.1
31.2
43.8
59.3
70.4
41.9
57.8
30.7
29.3
17.5
23.1
17.1
17.0
15.9
22.2
23.2
31.0
28.7
78.0
39.4
48.5
33.9
72.1
49.4
147.7
39.8
117.3
37.6
38.4
40.2
33.0
33.3
49.0
60.0
10.1
43.4
58.1
30.7
28.7
16.4
22.0
17.2
16.7
62.9
23.4
23.4
46.0
69.2
83.6
39.1
49.1
33.9
72.1
49.3
147.4
41.0
117.5
31.1
38.5
40.3
33.1
33.4
49.1
60.1
70.1
43.5
58.2
30.8
29.3
17.5
23.2
17.3
16.6
63.0
23.5
23.6
33.4
29.3
79.3
39.2
46.5
22.1
30.5
41.5
48.2
37.2
19.0
26.4
130.8
42.6
26.5
35.0
42.7
142.0
27.5
37.6
59.2
29.8
29.1
16.1
18.0
23.0
26.1
25.1
23.0
37.1
33.8
220.0
46.9
44.1
22.3
30.4
41.6
47.1
36.4
20.4
26.2
131.3
42.3
26.4
34.4
42.8
141.8
21.5
31.1
59.1
29.7
29.3
19.7
17.9
23.5
26.1
23.5
23.0
23.0
30.8
28.8
76.6
41.4
140.6
121.5
22.1
44.5
34.5
37.2
30.6
30.7
39.3
39.6
29.4
32.1
39.9
54.5
48.2
36.0
21.9
424
21.3
25.4
28.8
15.4
16.8
33.4
21.3
23.4
C2621
w21
P521
W21
C2631
iF41
391
39.4
31.3
39.4
49.4
19.0
421
50.3
37.9
41.9
24.3
36.1
37.9
33.9
23.3
26.4
15.2
21.6
18.7
26.4
15.2
21.5
20.4
37.O(C3a)
33.7(C6a)
37.3(C7a)
44.1 (C8a)
49.7(C12a)
49.5(C13a)
40.3(C13b)
54.1(C13c)
Me
CHz
CH
v-w
*The data are for CDCl, solns unless indicated by supercripts D@MSO-d,&
a, b, c within a vertical column may be reversed.
P(C,DsN)
392
394
3w
15.3
15.5
16.8
19.0
19.6
24.4
25.2
28.0
17.2
18.8
27.2
30.4
32.5
33.4
37.8
38.5
41.8
34.1
34.5
49.5
55.5
63.5
79.1
118.3
29.7
38.0
38.8
39.1
50.3
157.5
13.1
14.7
17.0
17.3
23.0
24.2
25.8
27.6
16.8
22.2
24.2
27.1
28.5
31.1
35.3
35.9
37.0
33.6
35.2
48.6
50.3
56.7
19.3
116.9
35.2
37.0
38.5
40.5
46.8
145.4
39.1
28.3
71.9
39.2
54.5
19.5
41.1
40.4
55.4
38.1
22.9
124.0
1320
140.0
125.4
42.4
45.2
39.3
29.0
38.7
80.2
33.0
28.6
16.4
16.6
19.0
23.8
180.3
21.8
68.9
Cl051
Cl051
[X51
and M(CDsOD).
S.
1558
B. MAHATO and A. P.
3&OH, p-amyrin
36-OH. 28-COOH. oleanolic acid
310x0.iS_COQG
3p-OH. 27-COOMe
3a-OH. 27-COOH
3fSOAc. 29-COOMe
3p-OH. 30-COOMe
3@-OH, 30-COOMe. 18a-H
3fhOH. 23-CHO. 28-COOH
30
31
32
33
gypsogenin
10
11
12
acid
38-OH, 27, 28-COOH. cincholic
40
acid
41
14 3&OH. 28,29-COOH, serratagenic
42
acid
43
15 38-OH.28. 30-COOMe, methylserjanate
44
16 38, lla-OH
17 3&15a-OH
45
18 38, 16fkOH. maniladiol
19 38,22@OH, sophoradiol
203B-OH, 2%oxo.29-COOMe, subprogenin 046
213B-OH, 22-oxo,3O-COOMe, snbprogenin C
22 38.24-08
47
23 38,28-OH, erythrodiol
24 38.30-OH
48
25 38.30-OH. 18a-H
49
26 38.24-OH, 228: 30 epoxy
50
27 la, 38-OH. 29-COOH, imberic acid
51
28 2a, 38-OH, 28-COOMe, methylmaslinate 52
29 2a, 3a-OH, 28-COOMe,
53
methylepimaslinate
54
55
13
Acetylation
shifts
KUNDU
3/3,6fbOH, 28-COOMe.
methylsumaresinolate
3a. 68-OH, 28-COOMe.
methyl-3-episumaresinolate
38. 16a-OH. 28-COOH. echinocystic
acid
38, 19a-OH. 28-COOMe, methylsiaresinolate
38,21a-OH, 28-COOMe
38.21 f&OH, 28-COOMe. methylmachaerinate
3&22@-OH, 29-COOMe
38,23-OH, 28-COOH, hederagenin
38.24-OH, 28-COOH, epihedaragenin
3a, 24-OH. 28-COOMe
38.25OH. 28-COOMe
38,27-OH, 28-COOH
38.29-OH. 28-COOH
3;; 29-OH; 27-COOH
38,30-OH, 28-COOMe. methylqueretaroate
38, 16fSOH, 28 --w
218lactone,
acacic acid lactone
38. 16a-OH. 23-CHO, 28-COOMe,
methylquillalate
38, 19c+OH, 23, 28-COOH, ilexolic
acid B
38.23-OH, 28-COOH, 29-COOMe
38,23-OH, 28.3~COOH
3a, 24OH, 28.3~COOMe
3f4,30-OH, 28 +
218lactone. macherogenin
38,9a, 1 la-OH
38, 15a, 24-OH
38, 168, 28-OH, longispinogenin
38, 16o. 28-OH, primulagenin A
Cl8 Conjiguration
The configuration at Cl8 in an oleanene triterpene,
namely whether the oleanene triterpene belongs to the
18cr- or 18/Gseries, can be recognized by inspecting the
chemical shift of some characteristic carbons [76]. The
geometry of the D/E ring junction does not cause a significant alteration in the shielding of carbons in the
A and B rings. In ring C (cf. triterpenes 7,8,24,25), Cl2
and Cl3 of the 18a-series exhibit diagnostically valuable
upfield shifts of about 5 and 2.5 ppm, respectively, with
respect to the corresponding carbons of the 18B-series.
For C12, the upfield shift is attributed to the strong steric
interaction with C19. In ring D, Cl6 exhibits a significant
92
93
94
95
96
97
98
!J9
100
101
102
103
104
3p-OH. germanicol
3@OH. 28-COOMe, methylmorolate
1p, S@-Oq anagadiol
38, 1l&OH
3&16@OH
86
87
88
89
90
91
1559
S. B. MAHATOand A. P. KUNDU
109
110
111
112
113
114
115
119
3g-OH. 28-COOH
120
121
28.3@,23-OH,
28.38,23-OH,
butyraceol
28-COOH, bassic acid
3fl-OH
3&228-OH, 29-COOH. yunganogcninF
38, 16&28-OH. saikogeninC
38,16a, 28-OH
3&22~.24_OH. yuaganogeninD
38. 168,23,28-OH. saikogenia A
38. 16a. 23.28-OH
\ /
116
117
118
3f3-OH
38.168.28-OH.
saikogenio B
38, N&23.28-OH
13B,28-Epoxy oleanenes
There are some triterpenes which contain a 13/?,28epoxy-ll-ene
system (triterpenes 122-127) and some
others which possess the 13&28-epoxy oleanane skeleton
(triterpenes 128-134). The discernible C resonances for
the former are those of olefinic Cl 1 ( N 133.0 ppm) and
Cl2 (- 130.0 ppm) and quatemary Cl3 (~85.0 ppm),
attached to an oxygen atom. The fingerprint resonance of
the latter type of triterpenes is exhibited by the quaternary Cl3 at about 86.5 ppm.
Taraxeranes (D-fiiedooleananes)
D: C-Friedooleananes
Some triterpenes of this series, all containing an 8 : 9
double bond, have been assigned C resonances. The
13C values of a few representatives (159-163) are shown
in Table 1. Although multiflorenol (3B-hydroxy D: Cfriedooleanane-7-ene), a triterpene of this series containing a 7 : 8 double bond, has been isolated long ago [83],
1561
S.
1562
B. MAHATO and A. P.
K~JNDU
152 38,7a-OH
153 38.28-OH.
154 3;; 28-OH;
mvricadiol
is~myricadiol
155 3-0x0.28-OH
156 3-0x0,28-COOH
157 3p-OAc, 28-OH.
aeetyl aleuritolic
acid
135 3a-OH,
136
137
138
139
140
141
142
143
144
145
146
147
pfameric acid
methylbryonolatc
164
165
166
167
151
3-0~0.As, glutinone
3: lo-epoxy. delldrqmoxide
3: 10 epoxy. 7a-OH
3: 10 epoxy, 22p-OH
3p-OH. taraxerol
Friedoursanes
The 13C resonances of two friedoursanes e.g. 3/?acetoxy-D : C-friedours-7-ene (bauerenyl acetate) (258)
and 3B-acetoxy-D : C-friedours-8-ene (isobauerenyl acetate) (259) have recently been assigned [91] (Table 1).
Ursa-dienes
Gammaceranes
Triterpenes containing Ursa-9(11),12-,12,18- and 12,20diene systems have been isolated and rheir 13C resonantes assigned. The presence of such systems is indicated
by the characteristic olefinic 13C resonances (cf. triterpenes 250, 251 and 254).
Gammacerane
triterpenoids occur very rarely in
plants. Tetrahymanol (260) was first reported from the
Protozoan Tetrahymena pyrijbrmis [92]. Recently, some
gammacerane derivatives have been isolated from the
roots of Picris hieracioides subsp. japonica by Shiojima et
1563
3-oxo,21a,
26-OH
3-0x0,28,29-OH
3-0x0,28,30-OH,
maytenfoliol
1,3-dioxo, 15~OH
3. 12-dioxo, 27-OH. pristimeronol
1, Jdioxo. 25:26 epoxy
23
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
1%
191
192
193
194
195
1%
197
1%
mimusapic acid
28.3 -OH, 23:lO epoxy, 28-COOMe,
6901 f 12 ti
usopsic acid
.
M
3&OI-& a-amyrin
3ixo. 24-cohe
Z
211
212
213
214
215
216
217
ii
3a-Ol-i
28-COOMe
28.313-oH. 28-COOMe
and kairaterwl
Four swertane(l7,18-friedogammacerane)
triterpenes
have so far been isolated and their 13C resonances assigned. Some of the discrepancies in the assigned reson-
S. B. MAHATOand A. P. KUNDU
1564
218
219
228
221
222
223
224
225
226
227
228
229
238
231
232
233
234
235
236
237
238
239
248
241
242
243
244
245
246
247
23
24
248
249
250
38-OH
antes [97,98), have recently been revised by Chakravarty et al. [91]. The structure of kairatenol(275), the
first representative of a new class of migrated gammacerane triterpenoid, has been established with assignment of its r3C resonances [99] (Table 1).
Stictane
and flavicanes
231
253
goleishicacidII
2u. 3pOK 28400~
~Qor,
goreishicacidxII
260
261
262
263
3fbOH, tetrahymmol
3a-OH, Al6
3fbOH. Al6
3$,21a-OH
264
265
266
267
268
269
270
3fL21a-OH
3&21&oH
3a,21&oH
3@-OMe, 21a-OH
3fbOMe. Ila-OAc. 3SCHO
3fWMe, 21a.3bOAc
3p-OMe, 21-oxo. 30-m
256
Tamxasterol
i
HO
257
Pseudocaraxasterol
1565
1.566
271
272
273
274
3~4.JH.A. swertenol
3-0~0. A, swertanonc
3a-OAc, A*episwettextylacetate
Jg-oAc, A9( 1,pichieenyl
xetatc
275
Kairatenol
276
277
278
279
280
281
282
283
284
285
Hydmcarbon
22-0x0
38,224~OH
3fS,22/3-OH
3-oxo,22a-OH
3,22-dioxo
2a, 3@OH, 22a-OAc
2a, 38.22a-OH
2a, 3@22a-OAc
3g. lactone
22a-OH, 25 --_)
286
287
248
289
290
291
292
293
294
295
2%
297
298
299
300
301
302
303
304
305
306
307
308
Hydmarbon
3P-OKlupad
28-OH
28-COOMe
3&OH, 28-COOH. be.tulinicacid
3a-OH. 28-COOH
3fbOH. 27.2II-COOMe
3&OH, 28-CHO. betulinaldehyde
3a-06 28-CHO
1&3fbOH
38,13p-OH, 28-COOH, term& acid
3fS,7@OH
38.1 la-OH, nepiticin
3fJ.l5a-OH
3&16~-OH
3fS.24-OH
38.28-OH. bctldm
3-oxo,3O-OH
2u. 3a-tx-L 28-COOMe
38.23-OH. 2%COOH
38,27-OH, 28-COOH. cykodiscic
acid
318
319
Hydrocakm
3p-OH
320
321
322
323
324
2oB,-oH
A
AIs+@)
38,16@-OH
3&27-OH, Atz, obtusalin
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
325
326
327
328
329
Hydrocarbon
17a-H, hopane
21a-H hopane
17a-H, 2la-H hopane
22-OH, diploterol
29-OH
3O-OH,drycerassol
pauciflorol acetate
A6
d
17a-H. A*
A17 (21)
Aa@) di letene
3-oxo. AJ@)
Hydmcarbn
3-0x0
3&OH
3a-OH
3$-O& 1.28-cOOMe
cm
1567
S. B. MAHATO
and A. P. KUNDU
1568
379 Hydmcarben
380 28-COOMe
381
382
383
384
385
386
387
365
366
369
370
371
372
373
374
375
376
377
378
A
28-COOMe..A
As
313-0H As
2gcoOMe. A8
38.7~OH, 11-0x0,As. supinenolone A
38.11 B-OH, 7-0~0,A*.supiaenolone B
3fSOH, 7.11 -dioxo, As, supinewlone C
A901)
2%COOH A901)
28-COOh;e, A9()
38, 12a-OH A9(r)
3f3,7a, l%-OH, A9(), rubiatricl
2a, 3fGOH,23-COOMe,A9(I)
3-0~0,arborinoae
2a-OAc. 3&19a-oH, Nhiil
C
2a, l%-OH, 3$-OAc. rubiarbonel D
3g,7f3,1%-OH, rubiol
B
2a.3&7$, 19a_OH,ruhiiol
E
3$,7$.19a. 28-OH. rubiarbonofA
Za, 3g,7fS,19a, 28-OH rubiarbonol
F
Bicadinane
Friedomadeiranes
This structure of a representative triterpene of a completely new family of Csc pentacyclic triterpenoids has
been reported [103]. The structure has been established
as 2,6a,12-trimethyl-4,9-diisopropylperhydrobenzo[de]
naphthacene, or bicadinane (391), by the application of
MS, NMR and X-ray diffraction techniques. Two-dimensional H and C shift correlated NMR experiments
have been used for the unambiguous assignment of all
protons and carbon chemical shifts [104]. The 13C assignments of this novel bicadinane (391) are shown in
Table 1.
The pentacyclic triterpenes (392-395) have been isolated from extracts of Euphorbia mellfera AlT and their
structures determined by X-ray crystallography [105].
The skeleton of these triterpenes differs from that of
representatives of the lupane or hopane class by (i) an
unusual arrangement of the substituents in the cyclopentane ring E, the Me group being on Cl9 and the isopropyl group in an angular position Cl7 and (ii) a cis
D/E ring junction. The name of the unknown pentacyclic
parent skeleton has been proposed to be madeirane.
Thus 392 and 393 are o-friedomadeir-l4-ene and 394 and
1569
394 3p-OH
395 3-0x0
16
2i
ie
391 Bicadinane
3%
392
393
Pachannol A
3p-OH
34x0
SHIFTS
1570
BEFEUENCES
York.
14. Bax, A. (1982) Two-Dimensional Nuclear Magnetic
Resonance in Liquids. Delft University Press, Delft,
The Netherlands.
43.
44.
45.
46.
47.
501.
Reynolds, W. F., Hughes, D. W., Pe~ick~~umount,
M. and Enriquez, R. G, (1985) J, &fag@.&son, 63_
413.
Reynolds, W. F., McLean, S., Popiawski, J., Enriquez, R. G., Escobar, L. I, and Leon, 1. (1986)
Te~a~~o~ 42, 3419.
Kessler, H., Griesinger, C., Zarbock, J. and Loo&,
H. R. (1984) .Z. Nagn. Reson, 57, 331.
Akihisa, T., Yamamoto, K., Tamura, T,, Kumura,
Y., Iida, T., Nambara, T, and Chang, F. C. (1992)
&hem. Pharm. Bull. 40, 789.
Reynolds, W. F., McLean, S., Pe~i~k-Dumount~
M. and Enriquez, R. G. (1989) Map. Reson. Chem.
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74.
75.
76.
27, 162.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
1571
S. B. MAHATOand
1572
A. P. KUNDU
120. Rumbero-Sanchez,
A. and
Vazquez,
P. (1991)
127.
128.
129.
130.
338.
146. Koyama, K., Yama, T., Kinoshita, K., Takahashi,
K., Kondo, N. and Yuasa, H. (1983) J. Nat. Prod.
56,220l.
147. Tanaka, R. and Matsunaga, S. (1989) Phytochemistry 28, 1699.
148. Mahato, S. B. and Pal, B. C. (1987) J. Chem. Sot.
Perkin Trans I 629.
149. Akai, E., Takeda, T., Kobayashi, Y., Chen, Y. and
Ogihara, Y. (1985) Chem. Pharm. Bull. 33, 4685.
179.
180.
181.
182.
183.
184.
185.
186.
187.
188.
189.
190.
191.
192.
193.
194.
195.
196.
197.
198.
199.
1573
1574
S. B. MAHATO and
A. P.
KUNDU
1575