CrackingtheGRESUBChemistry

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Chromium Cr
Epimer

exo 1)2)
endo 1)2)
FC FC
KOH HCl
pH pKA
KE=0.5mv2=0.5Iw2
(intensiveproperties)(extensiveproperties)
BO
(FrankCondonPrinciple)

Electromagneticradiation
Anode Cathode
A N A*(N)0.5

keto halo hydroxy

hemiketal
NBS (acyllicposition)
Geminalic Vicinylic Vinylic Allylic Acetylinic

spinelstructure MIMII2O4
18e
Interferometer
Gouybalance

JT
hypercloso, closo, nido, arachno, hypho, conjuncto, klado
BnHnBnHn+2

(aldolcondensation)Dickmann

HartreeFock

SternGerlachexperiment
VanHoff GHS

38.
39. London

40.
41. C H
42. LiAlH4 0.5 LiAlH4

43. Acylation Alkylation

44. cope
45. Neon Ne
46. MA3B3 facmer
47. Normalvibration
48.
49.

50.
51.

52. Nitrile ambient entropy

53.
54. []=/(l*c)[] l dmc
g/mL
55. acidchloride
56. +3
57.
58.
59.
60.
61.
62.
63. (Haworthprojection)

64. Heat of Hydrogenation

65. Regioselective
66. Deuterate
67. TsOCl OTs
68. Calcite NaCl
69.
70. VSEPR
71. GammaRay

PracticingtoGREChemistrySubjectTest
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Ka
Ignition Oxalicacid
potassiumpermanganate
hydrolysis

Diamagnetism paramagnetic
200
Molybdenum tungsten vanadiumNiobiumtantalum

Propanol
+
Aldehyde acetal amide nitrobenzene
Neopentane chlorination
Ortho para meta
Mutarotation
Dimerization cyclopentadiene
Enol
Benzoate /Benzoyl chloride Benzaldehyde
Benzamide

thionylchloride
pheromone ZERS
styrene Cyclohexanediol
Claisen Fisher
Eutectic
Translational
Inertia extrema
Maxwell

Extrapolation partitionfunction

Nucleon
meanfreepath
=kT/(2d2*P)
limitingmolarconductivities reciprocal
microwavespectroscopy
collisionnumber

PracticeBookGR9527
1. 1HNMR 13CNMR
2. RMgBrRLiR2CuLi
1,4
1,2 1,2
3. Tb=Tb
Tb=KbmBTf=TfTf=KfmB mB P=cBRTcB B

4. raoult
pAp*xAHenry's law

5. CarbonylGroup Amide primaryamine

6.
7. Hemoglobin porphyrin
8. Doubletstate:Aquantumstatewithspinof1/2
9.
10. tertbutylmethylether thionylchlorideSOCl2
11. CH3COOCOOCH3
COOCH3
12. KC8 K MoS2 Mg3(OH)2Si4O10

13. ammonia retentiontime

14.
15. hydroxide thiosulfate carbonate oxalate
phthalate NaOH
16. HPLC GC HPLC
17. Dnh Dnd
18. A=A0ktlnA0lnA=kt1/A1/A0=kt
19. a e
20. silicates siliconpolymers silica
21.
22. diastereoisomer
23.
24. Cv,m=1.5RCv,m=2.5R
Cv,m>=3RCp,m=Cv,m+R Cv,m=3.5R
25.

26. tautomer
27. He
28. endothermic exothermic
29. carbene
30. osmoticpressure sucrose

07
1. propylbenzonate
2. H+
H+

3.
dU=dQ+dWQ W
dSQ/T0K
0
4. f=K+2=+2
K=2
5. NuclearBindingEnergy
6.
7. H N
OH C
8. LindemanChristianenA
M A A M
A K[M][A] M A
M=A A K[A] A
9. Raman spectra
. ,
,
10.
d

11.
12. osazone 1
4 1
13.
14. E1E2
E2 H
X HX E1X
H SN1 SN1

15. a b 1
b=NAb' a

PracticeBookGR0027
1. identical enantiomer diastereomer constitutional
isomer
2.
3. pKa
4. ppm=Parts Per Million ppt =parts per thousand ppb= part per
billion
5. primitive cubic orthorhombic tetragonal triclinic
monoclinic rhombohedral hexagonal
6. triglyceride trinucleotide tripeptide trisaccharide
triterpene 6
30 C
7.
8.
9. G A
10.
11.
12. eddydiffusion longitudinaldiffusion

13.
14.
15. HD N2 CH4
16. Ev=(v+1/2)hcv0v0 m1m2/(m1+m2)
17. J=1v=1
18. linkageisomer

19. S=0L=01L=1
20.
21. Williamson RONa RCl R3COR R3CONa
RX R3CX RONa E2

22.
23. Qrev/T Qrev
24. ,
25. 1V=1J/C nFEo=RTlnKo E VR 8.314T K
26. pH
27.
N Negative
n
P P

28.

08
1. chelate
2.

3.

H 3000 H 3000 OHNH 32003400

17001750

11
1. molarity molality
2. Fe3+/Fe2+ Fe2+/Fe Fe3+/Fe =(n11+n22)/(n1+n2)
3. DeybyHukellaw

4. X=C/(TQ)
(Q)
5. 10 2~4
6. Chitin 1422D
7.
8. P(<X+)=68.3%P(2<X+2)=95.4%P(3<X+3)=99.7%
9. denaturation hydration
10. Fischer L D
11. acetalgroup Immunoassay
12. detectionlimit3
13. =/
14. MichaelisMentenequation

15.

/ Stark Zeeman
16. A,B,C*
17. n anharmonicity
18. lipid seesaw
19. PIPK1+PK2/2
20. pyroracemicacid/Pyruvicacid lactate/Lacticacid
21. ,,,,,
,Na+
22. QTest


1. Na/NH3 Lindlar H2 PdCaCO3PbOPdBaSO4

Birch C

2.
3.
4.

5.
6. F=IF/Ia=kF/(kF+ki)
7.

8.
9.
10.
11.

12.
13.
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15.

epoxide
LDA H enolate
XSPNCN
C
COCO2 NSPX SP
3n6 3 3 3n5

3n6
* 0*
a+bi abi
Pqh
OsO4H2O

16. lactam quinone

17.

18. S

19.
20.
21.
22.

B12 Co
F CaF2

HMO

23.


24.

(salteffect)
25.

26. H TMS

Hz

27. HClO4 HClO3 HClO2 HClO

28. polarimetry
29.
30. B12 CoCa
31. Hg sensitizer
32.

GR0627
1. HBr Geminalic C
2.
0C 100 97.03
[1] 97.03 p
0 f=p 1
3. G 0S 0 H 0
4. RCO H
RCOCl HCl

5. He

6. LCAO

LCAOMO
7. F=IF/Ia=kF/(kF+ki)F=1/(kF+ki)
1/e
ki=0 0
8.


1.

2. H H H2 VB MO
VSEPR Huckle HMO

3.

4. SN1SN2E1E2

5. Maxwell

6.

7.