Oil Treating (I) Ltd.

Revision date-06/10/2009

BACTRON SK-5085

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME PRODUCT NO. APPLICATION SUPPLIER Bactron SK-5085 SK5085 BIOCIDE Basic Oil Treating (I) LTD E-16 MIDC, JEJURI Tal- Purandar, Dist Pune-412303 Tel- +91-2115-253226/ 28 Fax No. +91-2115-253225 +91-2115-253226/ 28

EMERGENCY TELEPHONE

2 HAZARDS IDENTIFICATION
Harmful by inhalation and if swallowed. Irritating to respiratory system. Causes burns. May cause sensitisation by inhalation and skin contact. May cause harm to the unborn child. Very toxic to aquatic organisms. CLASSIFICATION Repr. Cat. 2;R61. Xn;R20/22. R42/43. C;R34. Xi;R37. N;R50.

3 COMPOSITION/INFORMATION ON INGREDIENTS
Name WATER GLUTARAL Quaternary ammonium compound TETRAKISHYDROXYMETHYLPHOSPHONIUM SULPHATE ETHANEDIOL 259-709-0 203-473-3 EC No. 231-791-2 203-856-5 CAS-No. 7732-18-5 111-30-8 61789-71-7 55566-30-8 107-21-1 Content 30-60% 10-30% 10-30% 1-10% 1-10% Classification T;R23/25 C;R34 R42/43 N;R50 Xn;R22. C;R34. N;R50. T;R23. Repr. Cat. 2;R61. Xn;R22. Xi;R41. N;R50. R43. Xn;R22

The Full Text for all R-Phrases are Displayed in Section 16

4 FIRST-AID MEASURES
INHALATION Move the exposed person to fresh air at once. Rinse nose and mouth with water. If respiratory problems, artificial respiration/oxygen. Get medical attention. INGESTION NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention immediately. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Immediately transport to hospital or eye specialist.

5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA Use: Water spray, fog or mist. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. SPECIAL FIRE FIGHTING PROCEDURES Use special protective clothing. Regular protection may not be safe. Keep up-wind to avoid fumes. Cool containers exposed to flames with water until well after the fire is out. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water sources. Dike for water control. 1/ 5

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Bactron SK-5085
UNUSUAL FIRE & EXPLOSION HAZARDS May develop highly toxic or corrosive fumes if heated. SPECIFIC HAZARDS Oxides of: Carbon. Nitrogen. Sulphur. PROTECTIVE MEASURES IN FIRE Wear full protective clothing. Use air-supplied respirator during fire fighting.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. Avoid discharge to the aquatic environment. SPILL CLEAN UP METHODS Stop leak if possible without risk. DO NOT touch spilled material! Clean-up personnel should use respiratory and/or liquid contact protection. Absorb with inert, damp, non-combustible material, then flush area with water. Shovel into dry containers. Cover and move the containers. Flush the area with water. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Ventilate well.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Avoid acids, moisture, and combustible materials. Wear full protective clothing for prolonged exposure and/or high concentrations. Eye wash facilities and emergency shower must be available when handling this product. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Store away from Oxidising material. Use container made of: Suitable plastic material. Carbon steel. Stainless steel.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Std WEL WEL 0,05 ppm TWA - 8 hrs 10 mg/m3 0,2 mg/m3 0,05 ppm STEL - 15 min 104 mg/m3 0,2 mg/m3 Notes Sk Sen

Name ETHANEDIOL GLUTARAL WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin. Sen = Capable of causing occupational asthma. INGREDIENT COMMENTS WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT

PROCESS CONDITIONS Use engineering controls to reduce air contamination to permissible exposure level. ENGINEERING MEASURES Provide adequate general and local exhaust ventilation. RESPIRATORY EQUIPMENT Respiratory protection must be used if air contamination exceeds acceptable level. Use chemical cartridge protection with appropriate cartridge. Chemical respirator with organic vapour cartridge. HAND PROTECTION Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.

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Bactron SK-5085
EYE PROTECTION Use approved safety goggles or face shield. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. DO NOT SMOKE IN WORK AREA! When using do not eat, drink or smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE COLOUR BOILING POINT (C) pH-VALUE, CONC. SOLUTION FLASH POINT (C) Clear liquid Colourless to pale yellow 212 3-5 > 110 PM Closed cup. RELATIVE DENSITY VISCOSITY 0.998 - 1.098 C 8 - 15 cps 25 @ 25 Deg

10 STABILITY AND REACTIVITY

STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid excessive heat for prolonged periods of time. HAZARDOUS POLYMERISATION Will not polymerise. MATERIALS TO AVOID Strong alkalis. HAZARDOUS DECOMPOSITION PRODUCTS Oxides of: Carbon. Sulphur. Phosphorus. Formaldehyde.

11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50 TOXIC DOSE 2 - LD 50 INHALATION May cause sensitisation by inhalation. May cause respiratory allergy. Vapour may affect central nervous system and cause headache, discomfort, vomiting or intoxication. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Irritating to respiratory system. Harmful by inhalation. INGESTION Causes burns. May cause chemical burns in mouth, oesophagus and stomach. SKIN CONTACT Causes burns. May cause sensitisation by skin contact. Corrosive. Prolonged contact causes serious tissue damage. EYE CONTACT Causes burns. ROUTE OF ENTRY Inhalation. Skin absorption. Ingestion. Skin and/or eye contact. TARGET ORGANS Eyes. Respiratory system, lungs. Skin. MEDICAL SYMPTOMS Extreme irritation of eyes and mucous membranes, including burning and tearing. Upper respiratory irritation. Severe skin irritation. MEDICAL CONSIDERATIONS Splash in eye requires examination by eye specialist. SPECIFIC EFFECTS Contains a substance/a group of substances which may cause harm to the unborn child. Name
Quaternary ammonium compound 400 (analogy) mg/kg (oral rat) 3300(analogy) mg/kg (oral-rbt)

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Bactron SK-5085
12 ECOLOGICAL INFORMATION
ECOTOXICITY Very toxic to aquatic organisms. BIOACCUMULATION The product does not contain any substances expected to be bioaccumulating. DEGRADABILITY There are no data on the degradability of this product.

13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION Recover and reclaim or recycle, if practical. DISPOSAL METHODS Absorb in vermiculite or dry sand, dispose in licensed hazardous waste. Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.

14 TRANSPORT INFORMATION

PROPER SHIPPING NAME AIR TRANSPORT NOTES UN NO. ROAD ADR CLASS HAZCHEM CODE IMDG CLASS EMS AIR CLASS

CORROSIVE LIQUID, ACIDIC, ORGANIC, n.o.s. (Contains Glutaraldehyde) PACKING INSTRUCTION (PASSENGER) 818 - 5 LITRES PACKING INSTRUCTION (CARGO) 820 - 60 LITRES 3265 Class 8: Corrosive substances. 2X 8 F-A S-B 8 ADR CLASS NO. ADR PACK GROUP UN NO. SEA IMDG PACK GR. UN NO. AIR AIR PACK GR. 8 III 3265 III 3265 III

15 REGULATORY INFORMATION
LABELLING

Toxic

Corrosive

Dangerous for the environment

CONTAINS

GLUTARAL Quaternary ammonium compound TETRAKISHYDROXYMETHYLPHOSPHONIUM SULPHATE

RISK PHRASES

R20/22 R34 R37 R42/43 R50

Harmful by inhalation and if swallowed. Causes burns. Irritating to respiratory system. May cause sensitisation by inhalation and skin contact. Very toxic to aquatic organisms.

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Bactron SK-5085
R61 SAFETY PHRASES S23 S25 S26 S36/37/39 S38 S45 S53 S57 S60 S61 P11 UK REGULATORY REFERENCES Approved Supply List. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply. Do not breathe vapour/spray. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Avoid exposure - obtain special instructions before use. Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Restricted to professional users. May cause harm to the unborn child.

16 OTHER INFORMATION
REVISION COMMENTS Revision to Section 2 Revision of classification ISSUED BY KH REVISION DATE REV. NO./REPL. SDS GENERATED RISK PHRASES IN FULL NC R22 R23 R23/25 R34 R37 R41 R42/43 R43 R50 R61 Not classified. Harmful if swallowed. Toxic by inhalation. Toxic by inhalation and if swallowed. Causes burns. Irritating to respiratory system. Risk of serious damage to eyes. May cause sensitisation by inhalation and skin contact. May cause sensitisation by skin contact. Very toxic to aquatic organisms. May cause harm to the unborn child. 06/10/2009 1

DISCLAIMER The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process unless specified in the text. 5/5