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1-bromo-3,5-difluorobenzene
290165 601-073-00-7 461-96-1 Laboratory chemicals, Manufacture of substances
1.2 2. 2.1
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 3) Acute toxicity, Oral (Category 4) Specific target organ toxicity - repeated exposure (Category 2) Skin irritation (Category 2) Skin sensitization (Category 1) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1)
2.2
Hazard statement(s) H226 H302 H315 - 290165H317 H373 H410 Precautionary statement(s) P273 P280 P501 Supplemental Hazard Statements Hazard symbol(s) R-phrase(s) R10 R22 R38 R43 R48/22 R50/53 S-phrase(s) S24
Flammable. Harmful if swallowed. Irritating to skin. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid contact with skin.
Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets.
2.3 3. 3.1
1-Bromo-3,5-difluorobenzene
CAS-No. EC-No. Index-No.
4. 4.1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
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If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
4.3 5. 5.1
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
6.4 7.
7.1
7.2
7.3
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8. 8.1 8.2
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) Appearance b) Odour c) Odour Threshold d) pH e) Melting point/freezing point f) Initial boiling point and boiling range g) Flash point h) Evaporation rate i) j) Form: liquid Colour: colourless no data available no data available no data available no data available 140 C - lit. 44 C - closed cup no data available
no data available no data available 1,676 g/cm3 at 25 C no data available log Pow: 5 no data available no data available no data available no data available no data available
m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties
9.2
Skin corrosion/irritation
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Aspiration hazard
no data available
May be harmful if inhaled. Causes respiratory tract irritation. Harmful if swallowed. May be harmful if absorbed through skin. Causes skin irritation.
Additional Information
RTECS: Not available
Contaminated packaging
Dispose of as unused product.
no data available
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
16.