TECHNICAL DATA SHEET

TDS-737 Edition: December 29, 2009 Previous Edition: February, 2009

Carbopol 676 Polymer

A High Efficiency Rheology Modifier for Household and I&I Applications
Introduction
Carbopol 676 polymer is a crosslinked polyacrylate powder designed to impart thickening, stabilization and suspension properties to a wide range of HI&I applications. It provides proven high performance in formulations where oxidative stability and cost effectiveness are key requirements.

Product Efficiency
Carbopol 676 polymer is a highly efficient thickener and suspension agent. The following chart illustrates the viscosity values obtained for mucilages containing various levels of polymer.
Carbopol 676 Polymer Viscosity vs. Concentration The graph below shows the effect of Carbopol 676 polymer concentration on viscosity.
Viscosity vs. Concentration Carbopol 676 Polymer

Benefits
Carbopol 676 polymer provides numerous benefits when formulating a wide range of HI&I products: High efficiency thickening (0.2 to 1.0 wt% typical use levels) for very cost-effective formulations. Suspension and stabilization of insoluble materials and particulates. Improved vertical cling which minimizes dripping and increases surface contact times. Shear thinning rheology suitable for non aerosol sprayable or pumpable product formulations. Excellent stability in oxidizing systems such as those containing chlorine bleach or peroxides.

100,000 90,000 80,000 70,000 60,000 50,000 40,000 30,000 20,000 10,000 0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Viscosity (mPas)

Polymer Concentration (wt% TS)

Application Suggestions
The features and benefits of Carbopol 676 polymer make it an ideal candidate for use in formulating products such as: Automatic dishwashing liquids General sanitizing applications Laundry pre-spotters and treatments Hard surface cleaners Toilet bowl cleaners Mold and mildew cleaners Oven cleaners Gelled fuels
Data obtained at pH of 7.5, polymer neutralized with NaOH using Brookfield RVT at 20 rpm @ 25C

Broad Suitable pH Range

Carbopol 676 polymer is effective across a broad range of pH giving formulators maximum flexibility for a wide range of applications.

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The information contained herein is being furnished for informational purposes only, upon the express condition that the User makes its own assessment of the appropriate use of such information. While the information contained herein is believed to be reliable, no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for a particular application or the results to be obtained herefrom. Lubrizol Advanced Materials, Inc. ("Lubrizol") cannot guarantee how any products associated with this information will perform in combination with other substances or in the Users process. Due to variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the information or products for the applications disclosed. Lubrizol shall not be liable and the User assumes all risk and responsibility for any use or handling of any material beyond Lubrizol's direct control. LUBRIZOL MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. It is the Users sole responsibility to determine if there are any issues relating to patent infringement of any component or combination of components relating to the supplied information. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without permission of the patent owner.

For further information, please visit: www.lubrizol.com/homecare

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TDS-737 Carbopol 676 Polymer

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Carbopol 676 Polymer Viscosity vs. pH The graph below shows the effect of pH on the viscosity of Carbopol 676 polymer at 0.5 wt%.
Viscosity vs. pH Carbopol 676 Polymer
80,000 70,000

60,000 50,000 40,000 30,000 20,000 10,000 0 3 4 5 6 7 8 9 10 11 12 13 14

Order of Addition To ensure maximum benefit and efficiency from the polymer, we recommend the following order of addition: 1. Water (deionized). 2. Carbopol 676 polymer. 3. Surfactants. 4. Builders (e.g., soda ash, phosphate). 5. Oils, waxes, etc. 6. Neutralizers and other high pH materials. 7. Chlorine bleach (>pH 12.5). 8. Hydrogen peroxide bleach (after neutralizing to desired product pH). 9. Abrasives, aesthetics, etc.
Order of addition will depend on the nature of the formulation ingredients.

Viscosity (mPas)

pH
Viscosity data obtained using Brookfield RVT at 20 rpm @ 25C with

Processing Guidelines
Dispersions can be prepared by slowly sifting the polymer into the vortex of a rapidly mixing solution. Techniques or devices which sprinkle the powder as discrete particles at a controlled rate are the most effective. This allows each particle to completely wet out in the water vortex. Conventional impellers such as propellers or turbines are recommended. High shear rates will disperse the polymer very rapidly; however, extremely high shear mixers or homogenizers should be carefully employed because they can break down the polymer resulting in permanent viscosity loss. For faster dispersion, break up soft agglomerates of dry powder formed by static electricity or humid conditions. The wetting time required is dependent upon the amount of Carbopol 676 polymer added, vessel geometry and water temperature. Some producers choose to make a stock dispersion of Carbopol 676 polymer in water and then add this dispersion to their formulation mix tank. For easier processing of a 2-5 wt% dispersion, 400 ppm of an inorganic acid can be added to the water prior to dispersion of the polymer. Under high shear agitation, dispersions of Carbopol 676 polymer can stabilize entrapped air. Antifoam, at use levels of 0.02 - 0.05 wt%, can be added to the water prior to the Carbopol 676 polymer in order to minimize or eliminate foaming.

NaOH as the neutralizer

Ingredient Compatibilities
Carbopol 676 polymer is compatible with many materials including nonionic surfactants, alcohols, waxes and abrasives. In addition, Carbopol 676 polymer is stable with oxidizers such as chlorine bleach and hydrogen peroxide and is stable at high alkaline pH. The viscosity and yield value provided by Carbopol 676 polymer can be influenced by the ionic strength of the system. Deionized or soft water is therefore recommended in product applications. Carbopol 676 polymer in the powder form does not support bacterial or fungal growth, but it does not inhibit such growth either. Typical use of preservatives is recommended as appropriate when using the polymer in formulated systems.

Physical Properties
Carbopol 676 polymer has the following typical physical properties: Product Description Appearance Odor Total Solids (wt%) pH (unneutralized aqueous dispersion) Viscosity, 0.5 wt% mucilage Brookfield RVT, mPas
(20 rpm @ 25C)
Formal product specifications are available upon request.

Handling and Storage

White powder Mildly acrylic 100 2.5 - 3.5 45,000 - 80,000 Packaging: 20 kg cardboard boxes. Shelf-Life: 2 years. Storage: Store in cool, dry, well-ventilated area. Consult the Carbopol 676 polymer MSDS for additional pertinent information.

Additional Literature
Please visit www.lubrizol.com/homecare for other Technical Data Sheets as well as Specifications, Formulations, TSE-GMO Certificates and Toxicology Studies.