MADRAS CHRISTIANCOLLEGE(AUTONOMOUS) B.Sc.

DEGREE -Nov z0r2 END oF SEMESTER EXAMINATTONS ' GENERALCOURSE 0 9l r l A N CHEMISTRYIN EVERYDAY LIFE TIME : 3 HOURS SEMESTER : ONE PART_ A AnswerALL the questions. I l0 x 2:20 | l. Defineair pollution. 2. Whatis hardwater? 3. Whatareantipyretics? Giveanexample. 4. Whatareceramics? 5. Whatis thecomposition of Portland cement? 6. Whatis PVC? Draw its structure. 7. Whatarebuildingblocksof proteins? Giveanytwo significances of proteins asfood constituents. 8. Whatis scurvy? 9. Givethe composition of super phosphate of lime. 10.What aresoaps? PART - B Answerany FIVE questions. I5 x g - 40 l I l. Explain thecauses andconsequences of air pollution. 12.Give an account of detergents. | 4+4) t g] MAX : 100rnarks

13.Write aboutthe general formulation andpreparation of shampoos and perfumes. t4+41 14.Differentiate between natural andsynthetic fertilizers. t g]

15.Describe thecladsification of explosives with suitable examples. t 8] 16.write two ekamples andtwo applications of a acid,basic, mordant andvatdyes. t at+2+21 17.Givethepreparation, structure anduses of bakelite. Continued in Paee 2 t g]

'
I

P,agp 2

B.Sc.Chemistry in Everyday Life .... 18.Discuss hazards of theuseof cosmetics. PART - C Answerany TWO questions.

12x20=40 1
t 5l

19.(a) Givethe principleanduses of fuel cells.

(b) Explainthe classification of fuelswith suitable examples. t r0 l (c) Write a noteon NPK ratio. t 5l

20. Givethe sources andphysiological importance of fat andwater solublevitamins. [10+10]

21. Write short noteson the following : (a) Photosynthesis (b) Tooth pastes (c) Analgesics (d) Polyesters

[4x5:20f

{.*{rl.rl*****

COLLEGq(AUTONOMOUS) MADRASCHzuSTIAN -NOV 2OI2 EXAMINATIONS END OF SEMESTER DEGREE B.SC. Gr,(iv)Chemistry
T 5I T i A N i
I

_I BASIC CHEMISTRY SEMESTER:ONE

PART _ A

TIME : 3 HOURS

MAX : 100marks [ 1 0x 2 = 2 0 1

Answer ALL the questions. 1. 2. 3. 4. 5. 6. 7. 8. g.

Define electronaffinitY. Calculatethe equivaleirtweight of sulphuricacid. What is photoelectriceffect? principle. StatePauli's exclusion r l $tateFajan'srules. Definehybridization. What is lattice energY? thanCsCl lattice. Why? NaCl latticeis more stable conductorand What is the differencebetweensemiconductor, insrilator? 10. Densityof solid statewater(ice) is lessthanthat in the liquid state.

lvhy?

PART _ B

I Answ$rany FIVE questions. [5x8:40 energ\ What arethe factorsthat affect the energy. ionization ine ionization 11. Define
ionizationenergy? ladii. in covaletrt trends t 2 . Write a shortnoteon periodic

r3.

Discussthe hybridizationand shapeof SFo.

on MO theory. bond orderof Oz*and02- based t 4 . ,Calculate 1 5 . Draw and explainBorn - Habercycle. bonding?Explainrvith hydrogen 1 6 . What is interand intraurolecular one examplefbr each. of Nz. Draw andexplainthe MO diagram in Page2 Continued

Page 2 - I B,Sc.(iv) Basic Chemistry 18. How arep andn - typesemiconductors prepared? PART - C
A4swer any TWO questions.
I

12x20-40 I
[ 1 0]

19.

' . i i

order. i , , " 1 , (b) ExplainSchottky andFrenkel defects with examples.

(a) Draw tlrc MO diagramol'CO rnolecule and determine the bond

tl0l
[ 10]

20. (a) Draw andexplain the crystalstructure of NaCl. VSEPRtheory.

(b) Explain the shapeand hybridizationof PCl5and IFz on the basisof

t 10l
t

2 r . (a) Discuss the significance of.fourquantum numbers.

, l

I l 0]

(b) Statethe postulates of VB theory.

tsl

(c) what aretlredifferences between vB theoryandMo theories? [5 ]

* * rF:F:l * t<{.:k:f

Page 2 - I B.Sc.(iv) Basic Chemistry 18. How arep andn - typesemiconductors prepared? PART - C
Ar1swer any TWO questions.
' e

12x20-40 1

19.

(a) Draw tlrc MO diagramol'CO moleculeand determine the bon<J

or{3r
-

1
I

(b) 'Explain Schottky andFrenkel defects with examples.

I

t l0 l

20. (a) Draw andexplain the crystal structure of NaCl. VSEPRtheory.

t

t10 l
[10]

(b) Explain the shapeand hybridizationof PCls and IFz on the basisof

2 t . (a)Discuss thesignificance of.fourquantum numbers.

. l

I t 0]

(b) Statethe postulates of VB theory.

tsl

(c) what aretfredifferences between vB theoryandMo theories? [5 ]

* **:f ******

cHRrsTr4,N coLLEGE (AuroNoMous) : ^ i'*y4pl4! B.Scl DEGREE END

ry lrl AN
TINp :3 HOURS
Gr.(iv) Chemistry _ II BASIC CFIEMISTRY SEMESTER:TWO I PART _ A Aniwer ALL the questidrns.
i

oF SEMESTFR -Nov 20t2 EXAMINATTONS

MAX I 100marks

[ 1 0x 2 = 2 0 1

is the kineticenergy l. At what temperature of the gasbecomes half of

i its valueat327oC.
I l

2. Themolarvolumeof a gasat latm. pressure and500K is ', -3,m3. 50.25 x l0 calcurate thecompressibility factorof thegas. 1 What areliquid crystals?Give an example. WhatareMiller indices? I
i

5. Mentionany two conditions for usinga metalion indicatorin complexometric titration, 6. Distinguish co - precipitation frompostprecipitation. of cyclohexane. l. Draw the conformers
i
I

q Givethe IUpAC names of thefollowing:

i i

cH3 r'3
_

i I r r ; (a) CHr-C-CH-CH2-CH3

cH3
l

(b)CH2-C-CH_CH3

H CH2_CHz, CH: iH, _ CHz_ CH: D-Jfferentiate tetween enantiomer anddiastereomer. !t 10.Write a noteon Waldeninversion. PART - B Answerany FIVE questions. [5x8=40] 11. State thepostulates of kinetictheoryof gases. Continued in Page 2

Page2 B.Sc.(iv)BasicChemistryII . . ... 12. Statethe law of corresponding states. Deducethe equationfor law of coffesponding state 13.Discussvarioustypesof symmetryin crystals. 14. Explain any one theory of indicators. 15. How will you get the following from benzene. (a) Xylene (b) diphenylmethane (c) Benzenehexachloride 16. Explain the mechanism of El andE2reactions. 17. Explainthe reactionof pyrolysison + (a) Propane (b) ethylacetate (c) [CH3CH2CH2N(CH3)3]OH18. (a) What is E - Z nomenclature? (b) Assign E - Z configurationfor the following : i

(i)clH2c\. = ,r"''
/ \

(ii) F
C:C H
\

Br

CHr C:C

cH2ct

H3CH2C

cH2cH3

CI

CH:

Answerany TWO questions.

PART _ C

1 2x 2 0- 4 0I

19. (a) Explain Maxwell'sdistributiori of molecular velocities. \ilhat is critical phenomenon? Deriveexpressio$for the critical ,(b) ; bonstants of a gasubing v4nder walls equation of state.
i

[10+10] Continued in Page 3

PAse?

B.Sc.(iv) BasicChemistry II ..,.. 20. (a)DeriveBragg'sequation. I (b) Explainthe following: (i) Specificandselective precipitants (ii) Sequestering agents (iii) Nucleation

[10]

t4l t3l I3l

conformational isomers of the followingand ?t.(") Explainvarious explaintheir stability. I (i) ethane t4l (ii) n - butane t6l (b) Explainthe mechanisms of (i) SNl reaction (ii) Sy2reaction
*{.rrrF*****

Is+s]

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) EXAMINATIONS-NOV 2012 B.Sc.DEGREEEND OF SEMESTER Gr.(iv) Chemistry 15IIIFN CFIEMISTRYOF NON METALS SEMESTER: THREE PART _ A AnswerALL the questions. 1. 2. 3. 4. 5. TIME : 3 HOURS MAX : 100marks [10x2=201

What is an ionic hydride?Give an example. Define : Permanent hardness of water. Describe the preparation of carbonsuboxide. Give the importance of siliconcarbides. base among the following?Why? Which is a strong (a) PH3 (b) NHs (c) AsH3 6. Write the structure of HzNzO+. 7. What arepolyphosphates? 8. Givetwo usesof bismuthates. 9. What arefreons? Give oneexample. 10.Whatarepseudo halogens? Givetwo examples. PART _ B Answerany FIVE questions. [5x8-40] resin. 11.Explainhow hardness of wateris removed by ion - exchange

12.Which is calledinorganicberzene?Why? Give its synthesis. 13. How aresilicates classified? for eachclass. Givean example
14. Give any four reactionsto illustrate that liquid ammonia can get as a solvent.

15. Write a note on any fwo oxy acids of phosphorus.

How are Caro's acid and Marshall's acid prepared? 16. Give two chemicalreactionfor each.

1 7 .Write any one preparation for eachof the oxidesof arsenic,

antimony and bismuth. in Paee2 Continued

Page2 . .. of Non Metals. B.Sc.(iv)Chemistry 18.Write a noteon inter halogencompounds. PART - C Answerany TWO questions. of water? the hardness 19.(a) How will you estimate of diborane. (b) Explainin detailthe structure

12 x20 = 40I [10] [10]

of nitrogen. on hydrides account 20.(a) Give a comparative of Phosphorus. (b) Discuss the following(i) Oxyhalides (ii) NitrogencYcle. the allotropicformsof phosphorus. 21.(a) Discuss of SeandTe. (b) Give a brief account nitrogen. (c) Discuss the fixation of atmospheric
,k ,F,* ,1.* * tS tF tk t& tl. ,F {

[10] [10]

tsl
t5l
[10]

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) B.Sc.DEGREE END oF SEMESTER EXAMINATIONS-Nov 2or2 " Gr.(iv)Chemistry t2lrlFN ORGANOOXYGEN CFIEMISTRY ' TIME :3 HOURS SEMESTER:THREE
PARTA Answerall questions: point of glycerol 1. Theboiling isvery high(290i'C).G ive reasor:. 2. How will you convert acetyl pyrwic chloride into acio ? 3. What is 4. 5. 1,. 7. 8 esterification?Give an example. . Explain the term metameris.r, r.rith a suitable example. How will you distinguish 2-pt:r tanoneand 3-pentanone? H. .riis a.ce:cpheroneprepared? y, .v is i';1:i-3p6snolcalled picricacidthoughit hasno carboxylic acidgroup? (10x2=lQ)

MAX : 100marks

N4esc iar:aricacid is opticallyinactive.Why? ?. l\/ha: is saponification? 1o- p-nitrobenzoic acidis moreacidic than benzoic acid.Give reason. PARTB

Answerany five questions: 1,1.How does glycerol reactraiith ] .t Oxalic acidat Z6OrC b)p2os c)Ht d)Conc.HNO, 2

(5x8=tf!)

1[. a)Whatis Hoffmannbromamidereactiorl?Give its mechanism.(6) i

I

b)Acetylchlorideis a better acetylating agentthan aceticanhydride.why?(2)

18.a)Explain the basecatalysed mechanism of hydrolysis of ester,(6) j b)How will you convertacetylchlorideto ethylacetate? (2) 14.V\lritenoteson a) Zeisel's method b) Waxesand fats.

1$. Discuss the mechanism of the followingrearrangements a ) P i n a c o l -p i n a c o l o n e b) Fries 1p.Arrangethe followingin the increasing order of acidityand givereason chloro aceticacid,fluoro aceticacid,aceticacidand formic acid

p _

:?'.
17. How are the followingsynthesized? a)citricacid b)salicylaldehyde c) catechol d)anisole

A tct,
18.a)phenol+ C.H:.COC| )A -------->B + C What are A, B and C.Give suitablereactions. (5) b)Howwiil you preparethe followingfrom aceticacid? {3) i)formic acid ii)acetone

PART C
Answerany two questions: l3.aic ve en er.:mpiefor the foilowingnamereactions. (5 x 3 = 15) ') ,{ra/1-f;ster:reaction _ Blancreduction ii) Bouveault 'i,) Rosenrn,ndreduction iv) Tischenko reaction v) HellVofhard Zelinsky reaction biHorv will you dis:inguish the following? i) acetaldehyde and acetone ii) 1_propanol and 2 _ propanol 2i'a)Fse1is sceto aceticester prepared.How will you synthesise the followingfrom it? i) succinic acid ii)y ketovaleric acid i;iiethyt methvlketone iv) crotonicacid (2*8) :i Somplete the following reactions. (5xl=161 (2x20=tCI)

) ;i) iii) ir,) v)

Zn + BrCH:COOC,H ______> C.H-CHO + phthaiicanhydride+ conc.H,SO,) Resorcinol Malonic + trrea) es,ter A c r o l e i r r .H g t ) A l l y l a l c o h o lO +:)

21' C.omplete the followingreactions indicating against eachnameof the reactionand suggest a suitable mechanism. (.4x 5 = 20) i) ii) i;i) iv) + aq.alc.KCN 2C*H.CHO ) (C;H5)2C=NOH + HrSOo )' + NaoH ) 2c"H_rcHo CoH5ONa + CO; )

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) EXAMINATIONS -NOV 2012 B.Sc.DEGREEEND OF SEMESTER Gr.(iv) Chemistry 20ITlFN NUCLEAR CI{EMISTRY SEMESTER: THREE PART - A AnswerALL the questions. TIME :3 HOURS MAX : 100marks [10x2=201

l. Definepackingfraction. nuclei? 2. What area metastable 3. Give anytwo usesof isotopes. 4. What is nucleartransmutation? Give oneexample. 'critical mass'. 5. Define powerreactors. 6. Mentionthe typesof nuclear reactions? 7. What arethermonuclear elements? Why arethey calledso? 8. What aretransuranium dating. 9. Defineradiocarbon I 0.Differentiatebetween naturalandartificial radioactivity. PART - B Answerany FIVE questions. 11.Elaborate on the liquid dropmodel. : 12.Describe the followingwith examples (i) fissile andfertile material and (ii) nuclear isomerism
13. What are the ways in which fissionenergyis released?Explain using suitableexample. 14. Explain the fusion reactionin stars. 15. What is nip ratio and how doesit explainnuclearstability? 16. Write a note on scintillation counter. 17.How are radioisotopes usedin agriculture? in Pase2 Continued

[ 5 x 8 - 4 0I

Page2 Nuclear Chemis$ .... B.Sc.(iv) capture. 18.Explainorbital electron

PART- C
Answer any TWO questions.

12x20=401

wastes? How canthey be 19.(a) What arethe differenttypesof nuclear effectivelydisposed? [10] reactor. (b) Explain the working of a breedor

l t 0l

for the Derivean expression disintegration? 20.(a) What is radioactive material. of a radioactive rateof disintegration [10] (b) Explainthe working of a GM counter. [10]

of isotopes. of separation methods 2L. (a) Write noteon the different [10] particles? Explaintheir properties. (b) What aresubatomic tl0l

**rf ****

'l

MADRASCHRISTIANCOLLEGE(AUTONOMOUS) EXAMINATIONS_NOV 2OI2 END OF SEMESTER DEGREE B.SC. Gr.(iiD (va) (vi) $ltlFN ALLIED CHEMISTRY _ I

TIME : 3 HOI-]RS

SEMESTER:THREE
PART _ A

MAX : 100marks

Answer ALL the questions.

[ 1 0x 2 = 2 0 1

of chromiumandcopper' 1. write the electronicconfigurations of PClsandIF5? 2. What arethe geometries involvedin the extractionof metal 3. What arethreemajor operations from its ore? valencyof the metalin the complex' 4. Write the primary andsecondary
[Co(NH3)o]C1:. , 7--rit-^+. - r titrations' redox and base acid in employed indicators two any Give 5. of atomis b.c.c.andh'c'p' number 6. Whatis the co - ordination alTangements? of watergas' composition 7. Give the average is prepared?Givethe chemicalreaction' 8. How triple pho-sphate Give the with maleicanhydride? *lt.n furan is treated 9. Whathappens reaction. of tartaricacid' 10.Draw the enantiomers PART. B [5x8=40] AnsweranYFIVE questions'

principleandHund'srule of andexplainPauli'sexclusion 11.State maximummultiPlicitY. of steel' of heattreatment 12.Explainthe process theoryof M - L bond' of Pauling's 13.outline the salientfeatures of Portlandcement' 14.Explainthe manufacture complexes' in four co - ordinated isomerism the geometrical l5.Discuss
Continuedin Page2

Page2 I . ... (v) & (vi) . . .. Allied Chemistry B.Sc.(iii) the following ? 16.How will you prepare (3) (i) AmmoniumsulPhate (ii) AmmoniumNitrate (3) Nitrate (2) (iii) Potassium with suitable reaffangement of Beckmann 17. Explainthe mechanism example. of maleicacidandfumaricacid. the properties 18. Compare PART- C Answerany TWO questions.

1 2 x 2 0 = 41 0

of NaCl andCsClwith neatdiagrams. 19.(a) Explainthe structures of the following : (b) Draw the structure (i) CFI4 (ii) CzI{z (iii) BF3 (iv) HzO (v) IF5 ligandsand 20.(a) What is meantby chelation?Give anytwo chelating ligands. with chelating 12 + 2 + 3l threecomplexes of chelates. (b) Explainthe applications

t8l

of solubilityproductis qualitative (c) Write a noteon applications t 5l analysis. gas. of producer 21.(a) Givethe composition of glass. (b) Explatl rh" manufacture of pyridine' andproperties (c) Give the preparation and'nucleophile'' (d) Explaintheterms'electrophile'
******{<

t4l

tsl tsl
[3+3]

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) B.sc.DEGREE END oF SEMESTER EXAMINATIONS-Nov z0r2 Gr.(iv)Chemistry l2/lrFN ORGANOOXYGENCHEMISTRY TIME : 3 HOURS SEMESTER:THREE
PARTA
Answerall questions: ' (10x2=!Q|

MAX : 100marks

1. The boilingpoint of gryceror is very high(290i'c).Give reason. 2. How willyou convert.acetylchloride into pyrwic acid? esterification?Give an example. 4. Explain the terr,n metamerism with a suitable examole. 5. How will you distinguish 2-pentanone and 3_pentanone ? 6. How is acetophenone piepared? 7' Why is trinltrophenol called picricacidthoughit hasno carboxylic acidgroup? . 8 Meso tartaricacid is optically inactive.Why? 9. What is saponification? 10. p-nitro benzoic acid is more acidicthan benzoic acid.Give reason. PARTB | Answeranv five questions: . nsrrqns: 11. How doesglycerol reactwith a) Oxalicacidat 260'rC .
.1. '" il , i,

3. What is

, q c)Hl d)Conc.HNOl ? ' '

,

(Sxg={e}

b)lro, |
I

12. a)Jvhatis Hoffmannbfomamide'eaction?Give its mechanism.(6) biAietyl chlorirde is a better acetylating atent than aceticanhydride.why?(2) i '18'a)Explain the basecatalysed mechanism of hydrolysis of ester,(6) i b)How will you convertacetylchlorideto ethylacetate? (2)
I 14. Write notes on

method , a)Zeisel's

b)Waxesand fats.

15.Discuss the mechanisrn of thefollowing rearrangements

a)Pinaccil-pinacolone ; b) Fries

16. Arrangethe folloi,ving in the increasing order of acidityand give reason chloro acdticacid, fluoro aceticacid,a-cetic acid and formic acid l t
I

e.

' 9

'

17.How are the follciwing synthesized? a)citricacid b) salicylaldehyde c) catechol d)anisole

A tct.
18.a)phenol+ C,.H:.COC| +A -------> B + C What are A, E and C.Give suitablereactions. (5) blHow willyou preparethe followingfromaceticacid? (3) i) formic acid ii) acetone PARTC Answer any two questions: 19-a)Give an exarnple for the foliowingname reactions. (5 x I = 15y i) Arndt-Eisterr reaction " ii) Bouveault - Blancreduction iii)Rosenmundreduction iv)Tischenkoreaction v) Hell VoihardZelin_sky reacrion b)Hoiv will you distinguish the following? i) ecetaldehyde and acetone ii) 1_propanol and 2 _ propanol . 20.alHciw is acetoac:eric esterprepared.How will you synthesise t h e f o l l o w i n g f rc i r r i t ? i) succinic acid ii)y ketovaleric acid iii)ethylmerhyl ketone iv) crotonicacid (2+8) b) Complete the following reactions. 7n C,H.CHO + BrCH;COOC;H: -----> Resorcinol + phthalicanhydride+ conc.H2SOo ) Malonicester + urea ) 'Acrolein + HBr) i ',

(2x20=40)

i5xl=161

:i) ii) iii)l ivi

"ir iirrii'."i.iif,r
a'su,itable mechanism. (4x 5= 20) i)
ii) iti) iv)

,j

'

21' c':nipletethe following reactions indicating against eachnameof the reaction andsuggest

2C6H:CHO + aq.alc.KCN )
(C*H5)2C=NOH:r HzSOo ) + .2C^H_qCHONaOH ) C,,H..ONa + COr )

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) B.Sc.DEGREEEND OF SEMESTER EXAMINATIONS -NOV 2012 INTERDISCPLINARY COURSE 09IIlFN BIOLOGICAL CI{EMISTRY

TIME :3 HOURS

SEMESTER: THREE
PART _ A

MAX : 100marks

AnswerALL the questions.

[10x2:207

1. Write the Haworthring structure of sucrose. 2. How do you convertglucose into ozasone? point. 3. Defineisoelectric 4. How areaminoacids classified? 5. Defineiodinenumber. 6. Whatis saponification reaction? 7. Write the structure of two pyrimidinebases of DNA. 'Genetic 8. Define: Code'. 9. What arevitamins? How arethey classified? lO.Enzymes aremore specificin catalyticactivity. Justiff. PART - B AnsweranyFIVE questions. t 5 x 8 :40 ] 11.Writethe structure andproperties of maltose. 12.How areproteins classified on the basis of composition? 13.Whatarelipids? Explainthetypesof lipids with suitable examples. 14. Differentiate nucleosides from nucleotides. 15.Explainthe biologicalfunctions of DNA. 16.Givean account on ureacycle.
17. What are enzymes?Mention their sources.How are the enzymes classified? ContinuedrnPage2

Page2 B.Sc.(iv) Biological Chemistry. . .. 18.ExplainEdman's methodin N - terminal aminoacidanalysis of proteins. PART _ C AnsweranyTWO questions.

- 40l 12x20

19. (i) Give an account on glycolysis of carbohydrates. (ii) Bring out the similaritiesanddifferences between starchand cellulose. [10+10] 20. (i) Differentiate RNA from DNA. (ii) Explainthebiologicalfunctions of RNA. (iii) Write a methodof determination of the C - terminalof proteins.

[6+6i-dt
21. (i) Explain the various factorsthat affect enrymeactivity. (ii) Write the sources and diseases caused by deficiencyof vitamin 41, 81,B2, C andD.
* * ****{< *

MADRAS CHRTSTTAN (AUTONOMOUS) COLLEGE -SN O V E M B E2 B , S c .D E G R E E E N DO F S E M E S T EE RX A M I N A T I O N R0 1 2 Gr (iv) CHEMISTRY SEMESTER FOUR CLASSICAL THERMODYNAM ICS

T i me :3 h o u rs ob l tt A h l
I

M a x :1 0 0m a r k s PARTA

Answer ALL the questions 1 Define intensive and extensive variables. 2 3 4 5 6 7 8 9 Statethe zerothlaw of thermodynamics. Whatis standard state? Wh a ti s e n th a l p y o f n e u tralization? Wri ted o w nth e Gi b b s-Duhem equation. Writedownthe unitsfor AG. Whatis a homogeneous system?

(10X2=20marks)

Givethe expression for Kofor the dissociation of pCls. law, StateRaoult's

10 Whatis van't Hofffactor?

PART B Answer anv FIVE questions

(5X8=40marks)

11 State and explain the first law of thermodynamics. L2 a) Derive the relationbetweenCo and Cufor an ideal gas. b) Write a note on inversiontemperature.

( 4+ 4)

........contd.

Page I of /

BSc(iv)

13 a) Derive Kirchhoff equation. o) Writea note.orplring"Oilr,"

CLASSTCAL THERMODYNAMTCS ..... solutions with gaseous systems.

(4+4)

14 How does entropychange on isothermal rnixingof ideal gases? 15 How does chemicar potentiaf vary with temperature and pressure? 16 Derivethe van,t Hoffeguation.

17. Calculate AG

on the spontan rB Howis osmor: c pressure

I00. commr:j 1995for anequitibrium whose

,"",";:T;;;#

is #'ff:uilibrium constant

PART c
lY

.,oon'Yu'unu or"r'on, (a) Derive "o ec

dU and dH ror f,il::,:l""fi,o*,0, (b) "" ifi:tTi:fii,,?;:: t"rpuiJt?u'Ju" energy vary with pressure,
vorumeand

27

20 ,t;i fl:.T,': n:fi:ffiil!,,.,";,.,, heat surnmation

- Br ,';i SfJ;::Il^:.: cha'ier 0

(1s+s)
(10+10)

ii?i:i::ilft:, hT!,'i 3' i;,",h e, p sinth "i".,i, e "1?[

X ---- X

Page 2 of

MAPRAS

CH RISTIAN COLI.ECDE CAUTDNOVOUS)

B.sc' DE&REE- END oF SEMESTERExAMtNATloNs NovarqBER_ 2Dt2 Gnoop lV cHEtvtfsrRy

PHYSICAL METHODS 4 CTTEMICAL CONSTITOTION

rJ D r r e : 1 6 l r4
Ttq e: B Houva

sav'srER

: l=ot-:R'

SugTecr

4.oDE : Bcog

lvla:c : loo, Marks

panr- A
'lhz.dipo\annornan\dt p-drh6d..*A

tt ox2=.2o1

Ansr^rov ALL tho iuoafio,..,a

q P-dich\orcbenane. is hrctrrrhe.ra aa tbot_ ga6za\1L is I .64 D . Erephr n .

2 . Ee=p\ain qnq twro c.h".rac-\-.n ah es 6\ d,o-o6no}i.

7

Arrbaf,e neoA

Defina bi.l.u"F i. conaf.nF'.

4 - frtznfion th,e-dr15c-r-t\tica inlhr- rr6a $neuhrrsrr drSracficn Fo.hnilrra 5 . trhaF is maXneFicpermco,U'\i+l ? 6 . \NbaFinf--XHo" can 5- oblaineJ b1 -DTAthaF ratnrroF b. obhainzd bE T614? 1 . ca\c.trlah. th;.*yt a't:ocio.F,.d t r\tt^,phohon q trAhF t^nvin6 q

6oooA Lh =A.62A*risf kA#a' ] 1u1ua\a-n6tn 8 . 'In$ro

q . Exp\ain th" onqtn q Ese spadnd$c6\%.

rod and Rannanapec-hra oyz- .*npl.rn"rrF^r1 +" e-a.h cth"v. Exp\oin.

lo. Hrato nn^l.A Feaka a:r.l_ 4ecY4 {or SlAn 6\DacFrclm$ -th* acothte.I ?rcdi& tt^. {.ela.huc\n\znai\ro'a5th.- pe-aka.

PART-B ls x8 =4o J Anorre-v anH FtVe 1t'-oHcrra Expla.\n tt. pXn.*p\" inuo\u.d in tl* d.Forrnino.ficr, 6t
dipo\e-rr,oroe",F bX t 2 " Descrrba

\r b>sPehrcc$cn '

q) th. tern\c.ra,t^r.e- rnatHod

t rr',pol-,tful^e{apond.nF qnd h.- pat.'h-tr- inJepndon h paro.naqna\rsrn , e-n frco& &*i..srl $1+rlrib'' S''r=t\l-.r;a E-xp\c.\

t4 . sk"l-ch qnd
6a CaO4. HeO

arptain tF- TGIA cuyue .=F.t-"d

6n heahn:

in a.ir

'rnth,. *"ff

3o- tooi.

1 5 . toha.F ayz- th. advan*ffo

t6
l7'

SFond4xd 2

q uaing TMs aa a.ninl-ov.ol

ilffi.,iil:|t1*f'*'oA

-t.R ap.hrrs"{"6 inttr-.f.^{ q

e nltaf ft\. rra.riHu applic-a{rcqa q th. narrhrarrdi,$\rachon

rnelhod t6' rr,.ShqFis moonF bg tho torrn c.hernico-\,s\if ? DeEcrrba th. $a-chora us,t.h in{turancp-lf-tz ahamical shi}+ vatr.ro. Anstrra PART- c

tq a) ,*j^,:aJ:r
tt yT).eq,6uy^e tt^4

1''"HdnE
**E

= 40 rna'rka) czxso
m'e-\bod u'6e^d

c) Exp\crin th. p"""ifl\.

brExplar\n rno* ayc_ \n corrtir-,"ilT:*iffiI"?-" ahruchurzs % c-oom4inqliooc.crnpogda. .helPt.I %.

Frauhnsrr Ji.6.,-chon td["r1*.

2b a) Diacum th. .F.hora thop q{F+ rh"rTJA";!?;"

b2 Diacuao tu*- app\icatr.na db l?arnan lp.r.o4X
e) D\bc'66 varr6u6 F":aibl<- .l-rzanai{rorraocc-urina in th"

2I Lffit*-; l*:H, t]flatah. tb,.

"?.srt'

U'v'

cs+ ro+,.)

*ffii c'a: ^ffi

intt,- Te \*hJoro*,f,J \*r*nt -{.v c=@afro-t"hti vlbt='lior ,_A Pti*, ,.Ai.Y.,

tft : r2,5 *,[!aqnaD.-, J

c) )ibcur,rtr^- p*Yap\-

Nr,4 R ,bp.cF66cspa [ + +a + + l

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) _NOV 2OI2 DEGREEEND OF SEMESTEREXAMINATIONS B.SC. Gr.(iv) Chemistry T 9I T l A N INTRODUCTIONTO NANO CHEMISTRY

TIME:3 HOURS

SEMESTER:FOUR PART - A

MAX : 100marks

Answer ALL the questions. 1. 2. 3. 4. 5. 6. 7. 8.

[ 1 0x 2 = 2 0 1

in nanochemistry. technique of lithographic Mentionthe significance How is SAM prepared? of titania. Mentionany onemethodof preparation of gold nanoparticle. Give anyonemethodof preparation Definenanosensors. sensors. chemical of electro Mentionthe significance theprincipleof field on microscopy. State usedto view the morphology techniques Nameanytwo experimental of thenanomaterials. of nanomaterials. 9. Mentionany two applications prepared for SEM analysis? 10.Howis the sample PART - B Answer any FIVE questions. I [5x8=40 11. Write a shortnoteon MEMS. of iron oxide. for thepreparation I2.Explain anytwo methods on opticalproperties. based the principleof nanosensors 13.Discuss process? adsorption usingsequential 14.How is polyionfilm prepared of nanoparticles? usedfor thepreparation technique 15.How is reduction Givean example. of SEM. the principleandapplications 16. Discuss
in Page2 Continued

Page 2 to NanoChemistry. . .. Introduction B.Sc.(iv) of sol - gel method.Mentiontheprincipleandadvantages 17. Describe sol gel method. nanowires. the principleof polypeptide 18.Discuss PART- C Answerany TWO questions.

1 2 x 2 0 - 4 0I

of TEM. andusefulness the principle,instrumentation 19.Describe

of the following: the importance 20.Discuss (i) proteinnanoparticles. (ii) multilayerfilms. (iii) Goldnanoparticles.

21. Write shortnoteson (a) Workingprinciple of STM. [ 10] for the (b) Evaporation andsputtering technique preparation of nanoparticles [ 10 ]
********

MADRAS CHRISTIAN COLLEGE(AUTONOMOUS) B.sc.DEGREEEND oF SEMESTER EXAMINATTONS -Nov z0r2 (iv) Chemistry 08/11FN ORGANONITROGENCHEMISTRY TIME :3 HOTJRS SEMESTER:FIVE PART_ A I l0 x 2 = 20 ] MAX : 100marks

Answer ALL thequestions.

.

l. Nitroalkanes aresoluble in sodium hydroxide. Why? 2. predict theproduct

i) AlkylNitrile on catalytic hydrogenation ii) Alkyt iso nitrile on catalyic hyjrogenation What is Benzidine rearangement? Define isoelectric point. Pyridine is more basicthan pyrole. Whv? What is transcription? Arrangethe following compounds in the decreasing orderof basicityandexprain. NH3,CH rNHz (CH:)r N, (CH3)2 NH r What is carbylarnine reaction? What is denaturation of protein? Give two colour reactionsfor identifichtion of proteins.

PART- B Answerany FIVE euestions

[5X8=40]

I l. How will youdistinguish the following compounds Nitrous acid [4+4] i) Aniline, N-methyl Aniline,N,N_dimethylAniline ii) Primary,Secondary and Tertiary nitro co_pounds 12.a) what is H.fmann' Bromamide reaction? Give iis mechanism. t 5] b) what doesthe secondary structure ofprotein dearwith? [3] 13. How will you convert Anilineto 14x2: gl Benzonitrile i Flourobenzene Iodobenzene \ . lv) , Bromobenzene 14' (iive onemethodfdr the deteiminatign of N- terminalandc- terminalendof a p r b t e i n1 . 4+ql 15' Describe the structure of DNA. what is its function? a + 4 [ ) i) ii) iii)

.,-. p,.. .

Page2 ''" NitrogenChemistry B.Sc.(iv)Organo undergo of Quinoline.Why doesQuinoline sytil'esis 16.ExpiainSkraup 16 + 2l at 5,8positions? suUstitution Electrophilic whenUreais, 17.WhathaPPens gentlY, (i) heated at 170oC, (ii) heated HCHO' with excess (iii) treated and with hYPohalite (iv) treated (v) treatedwithmalonicester.

t1+1+ 2+2+21 ester' How doesit react of diazoacetic of preparation 18. ^" Givea method

;il1iis;"r.ti.^

a"d (ii)Acetvlene?
PART _ C

14+2+21

:40f t 2 x 20 Answer any TWO questions. when 19. (a) What haPPens pyiiditt. is treatedwith peracid (i) quinoline is treatedwith soda- amidein liquid ammonia (ii) fututt is treatedwith maleic anhydride iiiil hydroxideand py*ol. is treatedwith chloroformand potassium (iv) quinoline is treatedwith alkalineKMnOa' (v) [5x2=10] and explain Give its mechanism (b) what is BeckmanreIlrangement? [ 1 0] its stereochemistry. a ,20. (a)How will the peptideala-gly ? you synthesize t 6l

of aminoacid. synthesis phthalimide culerprainGabriel , ,

t 4l

with anexample' Explain methylation? Exhaustive (c) what is Hofinann

t6l

the stabilityof the helical (d) what arethe factorsthat influence structuieof Proteins? of Diazomethane. of thepreparation 2L. (a)Write a method of diazomethane. applications any five synthetic (b) Discuss

t4l

tsl

F0l
[2+3]

Whyit is Guanidine? (c)What

ir_?J:fl

base? strong

MADRAS CHRISTIAN C O L L E G( E AUTONOMOUS) B . S c .D E G R E E N DO F S E M E S T E -S R E XAMINATION N O V E M B E2 R 012 Gr (iv)CHEMISTRY S E M E S T EF RI V E C O M P U T EA R I D E DC H E M I S T R(Y CBCS) Time:3 hours

2tk't
PART A AnswerALL the questions

Max: 100 marks

(10X2=2Omarks)

I 2
1

Name two input devices.

Givetwo examples of operating system. Whatis an algorithm? Whatare controlstatements? Writethe BASIC expression for y = mX + c. Howare stringsrepresented in BASIC? Writea noteon the hierarchy of operations in BASIC. write a BASICprogram to calculate the pH of a solution whose[H+] ion concentration is 0.01 N. Howmany bytesare required to storeintegers in the computer? Writea noteon libraryfunctions.

4 5 6 7 8 9 l0

PART B

Answer any FfVE questions il

(5X8=40marks)

Explain the variouspartsof the CpUof a computer.

l 2 Drawa ffow:chart to calcurate the molecular weightor acetic acio. l 3 Explain briefly any two languages usedfor scientific work.

Page I of L

B S c( i v )

CBCS).. A I D E DC H E M I S T R(Y COMPUTE R

u s e di n a B A S I Cp r o g r a m ? 14 Howare subroutines l5 p r o d u c tf r o m s o l u b i l i t y . the solubility W r i t e a B A S I Cp r o g r a mt o c a l c u l a t e

16 Explaindata storageand retrieval. experiments? u s e f u li n d e m o n s t r a t i n g 17 Howare computers l8 teaching? helpfulin classroom How is PowerPoint

PART C

Answea r n vT WO q u e sti o ns
l9

( 2 X 20 = 40 m ar ks)

field. in scientific sf c o m p u t e r s t h e a p p l i c a t i o no Discuss

20 Write a BASIC program to generate a table showing the variation of for a first-order reactionas the time is varied from reactant concentration 1 0 t o 1 0 0 m i n i n s t e P so f 1 0 m i n : a, = 0 . 0 1 m o l / l i t I n i t i a lc o n c e n t r a t i o n k = 0.001min-l R a t ec o n s t a n t , i n headings yourtable: H a v et h e f o l l o w i n g S. No. 1

time 10 20

(a-x)

10

100
* lk=2.303/t log(a/(a-x)) l

Zl

the names of (a) - - Explain how MS Word is used to create a table to list and their molecularmass. How is list arrangedaccording carbohydrates molecularmass? to increasing the rate constantand computeits (b) How would you use Excelto calculate m e a n ?A l s o e x p l a i nh o w a g r a p h c a n b e p l o t t e d a n d t h e r a t e c o n s t a n t (5 + 15) from the slopefor a first-orderreaction. calculated

x x ---) nf

Daao

MADRA s cHRr srrq B'sc.DE g-!(AuroNoMo GREE us) eNo bisreffi g ".g1r: rr _ oNs 1en-Eiaifria No v 20r2 Gr.(iv)Chemistry 14,,/,
FN

APPLIED CHEMISTRY-I rntaE:3 HOURS SEMESTER: FIVE

MAX : 100marks [ 1 0 x2 = 2 0 ]

AnswerALL the questions. PART - A ]. _What 2. What ismeant bi r.fi"il;i6fp.rot.um? ----..^o

vJ by soundness in cement?

is meantby ,knockins,?

y-h" are safety gtu#J*"" li trvhat o1

is glazing?

3,. What is coal? ' 4t, What do you meal

;;edon the photographic nrm ins'ver : i ,Urj;f"ffii"Hlt;H: >.-twnat are fuel

cells? I0l, How do anodic inhibitorspreventcorrosion?

1 I l_tg*is nitrogtfcerine prepared?

AnswfranyFrvE questions.PART- B
arethe advaritages anddisadvantages of usingleaded petror? ]] l_T"
,*;.;;*"""'"

.- |

[5x8=40 I

I3' lvrite a briefaccount on

naturar andartificiarabrasives.

14' Explainthepreparation ofphotosensitive emulsions. l5' Exprain the cheriicar principre invorved in corour photography. l6',Describe H, - oz fuel cell with a neatdiagram.

tz' Dpscribe theproduction of gobar gasand'mention __ _-v its uses. sevD

I
! l .

vuntinued in page2
cc
, 1

Page 2 B.Sc.(iv) AppliedChemistry I . ;.. 'galvanization,. ' 18.(a) what arealloys? (b) Describe Answerany TWO questions.

PART- C
[2x20=40]

19. (a) what are the ingredients of portland cement? Explain their

functions

t l0 l
cement. [10]

(b) Describethe wet process of manufacture of portland

20-(a) write noteson the followingwith suitable examples. [ 5 + 5 ] (i) Low explosives anAlii; highexplosives , (b) what is theprincipleinvolvedin electrodeposition of a metal? Illustrateelectrodepositionofcopper [5 +5 ] . (a) what arethe conditions for 'two - metarcorrosion' to takeplace? How canit be minimized? ; (b) what arephotovoltaic cells?How aretheyconstructed?

i,':

,l.rF{r * {a*,t,F

.tl0+t0l

MADRA S CHRr S TrAN (AUroNoMous) ^C_O_L_L!GE B.SC. DEGREE ENDOFSI'IVFSTER EXAT,NiNATIONS _NOV 2012
t0 / 11FN TIME :3 HOI]RS Gr'(iv)Chemistry PI{ASE RULE AND ELECTROCIIEMISTRY SEMESTER:FIVE MAX : 100marks

2' Definethe. term 'component' wiih theillustration of the of,CaCO3. i ^ _{e=comnosition 3,. Whatarethe limitation,of dirt ibution law? do you mean by eutectic point? 1. If" 5' How doesspecificconductance varywith dilution? 6. Definetransport number. by electrochemical 1, _!3* do you unders,tand series? 8; Whatareredoxindicatorsi 9r calculate thepH andpoH of 0.05Msorution of HCI at25oc. Ip'Distinguish strongelectroryte frqm weak.t."t oryt.. PART - B AnsweranyFrvlrQuestionso [5xg=40J I l' Draw andexplain thephase diagram of watersystem.
i

I Answer ALL thequ.rlions. ' ' l. Siate ,ulr. fhase

-A PART ,

, [l 0 x Z = Z 0 l

l2' Explaintheprincipleinvolved in fractional distillation of miscible liquid pair andr.uion out why anhydrous ethanor ----- cannotby obtained by fractional distillation of rectified spirii. 13.Discuss fractionalcrystallization. 14' statedistribution law. How is it modifiedwhenthe soluteundergoes (a) association (b) dissociation il i;j'.o-pr.* formation. 15.Discuss ostward'sdilutionlaw andits limitations. tu'#io; wouldyou measure theconductance at infinitedilutionof aceric Continued in page2

Page 2

phase B.Sc.(iv) Ruleand Electrochemistry .... 17'De:finelthe ofhydrolysis. carculate Talegree thedegree of hydtolysis of 0.05Msolution of sbdium *.iu,. at2'oc.Given that K: 1.85 x 10-sand K* = 1.0 f O:iul ii;C i "
181 Derivean expression for the 'v vrr pH when wrrsll soqlUm sodiur aCetate UndCtgOeS hydrOlySiS.
,

- c PART Answer anyTWo questions. , t 2x20=40J 19'(a)Describe fteezing mixtures andtheirapplications. t r0 l (b) Explain theprinciple underlyirlg theprocess of steam distillation.

tr0l
20' (a) Describea methodof the determination ---- of -' the 'rv transport Lr.rrspurt numbers nul of ions in a solutionof AgNol. I r0 l (b) Explain the titrations. {o]tgwing potentiometric

(i) Strong acid Vs Sirongbase

(ti);iCt Vs AgNo3

I l0 l

2l' (a)Describe theconstruction andworkingof a calomer erectrode.[r0] (b) How would you determine the sorubilityproductof a sparingry soluble salt? Discuss its application lr'nlJnrtive anarysis..

Is+s]
,F***:F***,F,F*

MADRASCHRISTIAN COLLEGE (AUTONOMOUS) B.Sc. DEGREE END oF SEMESTER EXAMINATTONS ocrarov-2012 Gr.(iv)CHEMISTRY
APPLIED CHEMISTRY II Semester: SIX PART - A AnswerALL the questions. 1. 2. 3. 4. 5. 6. 7. 8. 9. What are insectrepellants? What is Bordeauxmixture? Define hydrogenation of vegetable oil. Differentiatebetween a soapanddetergent. What arepigments? Give the useof a vehiclein perfumes. How is PVC prepared? Whatis SBR? What are food additives? Max: 100marks

o6ftt 4f\l TIME:3 Hours

[I0x 2:2a]

10. Defineeutrophication. PART _ B Answerany FIVE questions. I l. Whatareherbicides? How is 2,4-D prepared? [5 x 8 :40]

12. How arepesticides classified? Give examples for each. 13. How are detergents classified? Explain usingsuitable examplep. 14. Write note'.:n the following a) transparent soapb) laundrysoap. 15. What are syntheticfixatives?How arethey usefulin maintainingthe fragrance of perfumes?

16. What are varnishes and lacquers? 1 7 . Explain vulcanizationof rubber. 1 8 . What are COD and BOD?

LP-T-O

'

PART- C Answer anyTWOquestions. 19. a) Writenoteonpollution caused by fuelindustries. b) Whatarefoodadditives? methods. Writenoteonfoodpreservation process? 20. a) Howis soap manufactured by continuous b) Givethepreparation anduses of nylonanddecron. 21. a) Writenoteonthemanufacture of paper. andapplication of thefollowing. b) Givethesynthesis
i) orlon ii) celluloseacetate

[2 x 20: 40] [10] [0] [10] [10] [10]

ll0l

* * *:f,l:1.

MADRASCHzuSTTAN COLLEGE (AUTONOMOUS) B.Sc. DEGREE END oF SEMESTER -Nov zltz EXAMINATTONS Gr.(iv)Chemistry 23IT1FN
CI{EMICAL KINETICS A}iD SURFACECIIEMISTRY

TIME:3 HOURS

SEMESTER: SIX PART - A

MAX : 100marks

AnswerALL the questions.

[10x2=201

1. Definethe termrate constant. 2. IVhatis Arrheniusfactor? 3. Whatis zeroorderreaction? Give an example. 4. Whatis transmission coefficient? 5. Whatis homogenous catalysis?Give an example. t. what 6. Therateconstant of a first orderreaction is 0.6-93sis its half - life ? 7. statestark - Einstein'slaw of photochemical equivalence. 8. Whatis c.m.c.?Mentionits significance. 9. Definethe term chemisorption. 10.What arethe typesof colloids? PART _ B Answerany FIVE questions. [5x8=40] 11. (a)Discuss anytwo methods of determination of orderof a chemical reaction. (b) Give the characteristics of the first orderrateconstant. 12.Exprainthe effectof ionic strength on reaction rates. 13.Outline the characteristics of enzyme catalysis. 14.Discuss thekineticsof photochemical decomposition of cH3cHo. 15.Explainthe Freundlich adsorption isotherm. Whatareits limitations? 16.Explain thephotosensitization process. Givean example. Cor-rtinued in pase2

Page 2 B.Sc.(iv)Chemical KineticsandSurface Chemistry .... 17. Discuss Lindeman's theoryof unimolecularreactions. 18. Write an account of stabilityandeleckicaldoublelayermodelwith respect to colloids.

Answerany TWO questions.

PART - C

[2x20=40J

19. (a) Derive an expression for the rateconstant of a second order reactionA+B-+C+D. (b) Thevelocityconstant of a first orderkinetics at 25ocis 2.8 x 10-3min-r, andtheactivation energy is l l.9Kcalmol -r . Find the velocityconstant at 35oC. (c) Explainthe absolute reaction ratetheorv. [8+4+8] - Menten 20' (a) DeriveMichaelis relationship for the enzyme catalysis. (b) Explainthe fluorescence andphosphorescence. [10+10] 21.(a)How is the surface area of a catalyst determined usingBET equation? t l0l (b) Explainthe following: (i) electrophoresis (ii) consecutive reaction (iii) parallelreaction [ 10]
********

^C9_LLE ) B.sc. DEGREE END oF SEMESTER exavnNarroNs _Nov z0r2

Lg/ tt fiN TIME : 3 HOIIRS Gr'(iv) Chemistry CI{EMISTRY OF METALS SEMESTER : SIX PART - A I l0 x 2 = 20 | MAX : 100marks

MADRAS CHzu STrA{

GE(AUTONOMOUS

AnswerALL the questions.

I Whut is hydrometallurgy? 2. Definecupellation 3. Whatarethe uses of vanadium? is [MCl(PPh:)s]prepared? Mentionirs use. 1. !o* 5. Complete the equation. +9, looo-1400'c TiCl4 , , 6. Mention any two differences between Hg and Zn. List any two differences between lanthanides 1. andactinides. 8. Distinguish oresfrom minerals. 9. How is FI2WOa prepared? l0.Whatarethe uses of ammonium molybdate? PART - B Answerany FIVE questions. [5x8=40] 11. Write a noteon thermite process. 12.what arethe generar characteristic of cr grouperements? 13.what arepolyacids?How aretheyclassified? Give two exampres for eachclass. 14' Describe the foilowingcitingappropriate reactions. (i) roasting (ii) calcinations (iii) smelting 15.How is titaniummetalpurified?what areits properties? Continued in pase2

Page 2 B.Sc.(iv) Chemistry of Metals.... 16.what is lanthanide contraction? Discuss its consequences.

17' Describe the methods of concentration of ores. 18.Write a noteon reverberatory furnace. Answer any TWO questions. PART- C

[2x20=40J

19' (a) Describe the chemistry of innertransition elements with reference to their (i) positionin theperiodictable. (ii) occurence (iii) oxidationstates

[12]
(b) Discuss the chemistry of pu.

t8l

20. How arethe following compounds prepared? Explaintheir structures andmentiontheir uses. [4x5:20] (i) Li2co3 (ii) [Ru(bipy)3] (iii) OsO+ (iv) [ptOIH3)Cl2] 21. (a) Write a comparative account of coinage metals. [10]

(b) Give an account of heteropoly molybdates andtungstats. [ 1 0 ]

{<*******

MADRASCHRISTTAN COLLEGE(AUTONOMOUS) - NovEMBER2}rz B.sc. DEGREE END oF SEMESTER EXAMINATIONS B.Sc., Br (tV) Chemistry C oordination chemistrv

Duration:3hrs

: Part-A

'

06lup P
Answer all Questions 1. \\kite ttreIUPAC names of

MaximumMarks:100 (10x 2:20 Marks)

a) [Co (NH3)5C1] S04 b) tNi (Co)al. 2. 3. 4. 5. 6. 7. 8. 9. Write the relationbetween stepwise andover all formationconstants. Nameany four structural isomers foundin coordination complexes. Find the hybridization in [Fe F6]+. Whatis specto chemicalseries? Whatis CFSE? What areinert andlabile complexes? Give examples. What is ligandsubstitution reaction? Give an example. What is iron chlorosis disease?

10. How is Co2(CO)6prepared? Part -B Answer any Five Questions 11. Discuss Wemer'scoordination theory. 1,2. Explainthe factorsthataffectthe stabiiityof complexes. 13. What is spin only magnetic moment?Calculate the spin only magneticmoment of the following complexes (5x8=40Marks)

i) tM"clol"

ii) [Fe(Hro)u]t* iii) tNi (cN)ol2-iv) [coF6]+

t4. Describe thevariousfactorsthat affectthe magnitude of Aevalues. 1 5 . How ared orbitalssplit in an octahedral complex? t 6 . How arecis andnans[Pt (NH3)(NO:) Clz] synthesized from [Pt CL]2-? 1 7 . Describe the various applicationsof coordinationcomplexesin Analytical
chemistry. 1 8 . Discuss thepreparation andstructure of Fe (CO)r.

P-i" O

Page 2 B.Sc.(iv) Coordination Chemistry ...... PART - C Answerany TWO questions. [ 2 x 2 0 : 4 0] 19.(a) State effectiveatomicnumber rule. Apply EAN rule to tNr (CO)ol 'andI M" (C].D of *dexplain. t 10l (b) Explainstereoisomerism in complexes. 20.(a) Write noteon the following : (i) Jahn- Tellerdistortion (ii) Postulates of crystalfield theory

t10 l

[5+s]
(b) What are metal carbonyls? Explain any two metal carbonyls preparationand its structure. [10 ]

21. (a) Discussthe applicationsof coordinationcomplexesin medicinal

chemistry.

U0 l t 6l | 4l

(b) (i) ExplainSNt CB mechanism (ii) Discuss Anationreaction with an example.

**t(*{.***:f***

MADRAS CH RrsTrAN COLLEGE (AUTONOMOUS) B .S CD . E GR EE EN DOFS EM ESTER _ NOVEMBER EXAMINATIONS 2012

Gr (i, iii, v, vi) SEMESTER ANCILLARY CHEMISTRY II Max:100marks PART A

Time: 3 hours

An sw e A r L L th e q u e sti o n s ( lO X 2 = ZOm ar ks) 1 Givetwo examplgs of addition polymerization.

2 3 4 5 6 |7 8
t ' .

What is isoelectric point? G i v et h e u s e o f c h l o r o m y c e t i a nnd Whatare disaccharides? W h a t a r e t h e .c o n s e q u e n c eo sf o z o n ed e p l e t i o n ? What is biomagnification? Defineorder of a reaction.
i

streptomycin.

W h a t i s q u a n t u my i e l d ?
: , .

i
i '

e'

tbw. ltlte kohtrausch

, i

1 0 W h a t i s a b u f f e rs o l u t i o n ?

PARTB anv FfVE questions . Answer (5 X g = 40 marks) 11 Listthe differences between thermosetting porymers and thermoprastics. U , E xp l a i n th e p re p a ra ti oa nn d useloftsulphanilam ide.

Page I of 2

B S c( i , i i i , v , v i )

A N C I L L A RC Y H E M I S T RIY I.....

1 3 Writea noteon natural toxinsand foodadditives.

t4

E x pl a i n th e l a w so f p h o to chem istr y.

15 What is electroplating?

16 Howis a dipept[de synthesized?

L7 How are carbohydrates classified?

18 Writea noteon pollution by plastics.

PART C A n s w e ra n y T W O q u e s t i o n s
19

(2X20=4m 0 arks)
( 1 0 +1 0 )

( a ) E xp l a i n e n d g ro u pa n alysis of pr oteins. ( b ) D i scu ss th e so u rce a s nddeficiencies of vitam ins.

2 0 ( a ) Discuss the Green Houseeffect. (b) Explain the photochemica clh l o r i n a t i o n of methane. (c) Calculate t h e p H o f 0 . 0 0 1 N s o d i u mh y d r o x i d e solution.

(1 0 + 5 + s )

2L (a) Discuss t w o e x p e r i m e n t am l e t h o d sf o r t h e d e t e r m i n a t i o n ( 1 0 + 1 0 ) of the order of a reaction. ( b ) Write a note on conductometric titrations.

x ---- x

Page 2 o f 2