ATOMIC STRUCTURE & GASEOUS STATE CHEMICAL BONDING

1. If in Hydrogen atom, an electron jumps form n

2
= 2 to n
1
= 1 Bohrs orbit, then the value of wave number of
the emitted photon will be (R= 109700 cm
-1
)
A) 54850 cm
-1
B) 82275 cm
-1
C) 62875 cm
-1
D) 10970 cm
-1


2. 1 = 3, then the value of magnetic quantum numbers are
A) 1, 2, 3 B) 0, 1 , 2, 3 C)- 1, - 2, - 3 D) 0, + 1, + 2, + 3

3. For a f-orbital, the values of m are
A) 1, 0, + 1 B) 0, + 1 , + 2 , + 2 C) - 2, -1. 0, +1, +2, D) -3, -2, -1, 0, +1, +2, + 3

4. The deBroglic wavelength associated with a particle of mass 10
-6
kg moving with a velocity of 10ms
-1
is
A) 6.63x 10
-7
B) 6.63x10
-6
C) 6.63x 10
-21
D) 6.63x 10
-29


5. The deBrogie equation treats an electron to be
A) a particle B) a wave C) ray D) both (1) and (2)

6. Bohrs theory is not applicable to
A) H B) He+

C) Li
2+
D) H
+


7. The Bohrs orbit radius for the hydrogen atom( n = 1 ) is approximately 0.530 A. The radius for the first
excited state ( n = 2) orbit is
A) 4.77 A B) 1.06A C) 0.13A D) 2.22A

8. Which of the following electronic configuration is a correct explanation of Aufbau principle
A) 1s
2
3s
2
4s
2
B) 1s
2
2p
2
3p
2
C) 1s
2
2s
2
3s
2
D) 1s
2
2s
2
2p
6


9. An e

has magnetic quantum number as 3. What is sits principal quantum number?

A) 3 B) 2 C) 1 D) 4

10. Ratio of masses of proton and electron is
A) 1.8 B) 1.8 x 10
+3
C) Infinite D) None of these

11. The configuration of 1s
2
2s
2
2p
5
3s
1
shows
A)Ground state of fluorine atom B) Excited state of fluorine atom
C) Excited state of neon atom D) Excited state of oxygen atom

12. Electronic configuration of chromium is
A) 3d
5
4s
1
B) 3d
4
4s
2
C) 3d
4
4s
1
D) 3d
5
4s
2


13. Electronic configuration of 1s
2
2s
2
2p
3
represent which of the following element
A) Nitrogen B) Fluorine C) Oxygen D) Carbon

14. Which of the following set of quantum number is not possible
n 1 m
1
m
2

A) 3 2 1 +1/2
B) 3 2 1 1/2
C) 3 2 1 0
D) 3 2 1 +1/2

15. The maximum number of electrons accommodated in 5f orbitals
A) 5 B) 10 C) 14 D) 18

16. A gas occupies a volume of 300 cc at 27C and 620 mm pressure. The volume of the gas at 47C and 640
mm pressure is
A) 2600cc B) 310cc C) 390cc D) 450cc

17. Volume of a gas N.T.R. is 1.12 x 10
-7
cc. The number of molecules in the gas is
A) 3.01 x 10
12
B) 3.01 x 10
20
C) 3.01 x 10
23
D) 3.01 x 10
24


18. At 2730C the volume of 2 mole of an ideal gas is 44.8 lit. Its pressure is
A) 1 atm B) 4 atm C) 2 atm D) 6 atm
JUNIOR

19. For the diffusion of a gas at pressure P, the rate of diffusion is expressed by
A)
M
P
r B)
M
P
r = C)
P
M
r D)
M
P
r =

20. The ratio between the root mean square velocity of H
2
at 50K and that of O
2
at 800K is
A) 2: 1 B) 4: 1 C) 1: 1 D) 1: 4

21. The gas molecules have r.m.s velocity of its molecules as 1000 m/s. What is its average velocity?
A) 546 M/S B) 921.58 m/s C) 1012 m/s D) 960 m/s

22. If two moles of an ideal gas at 546k occupies a volume of 44.8 litres, the pressure must be
A) 4 atmospheres B) 3 atmospheres C) 2 atmospheres D) 1 atmosphere

23. The volume of gas measured at 27C and 1 atm pressure is 10 litres. To reduce the volume to 5 liters at 1
atm pressure, the temperature required is
A) 75K B) 150K C) 225 K D) 300K

24. Partial pressure of hydrogen in a flask containing 2 gm hydrogen,16 g oxygen and 14 g nitrogen is
A) Half of the total pressure B) 1/8
th
of the total pressure
C) Equal to the total pressure D) 1/3
rd
of the total pressure

25. A certain mass of gas occupies a volume of 300 cc at 27C and 620 mm pressure. Th e volume of this gas at
47C and 640 mm pressure will be
A) 400 cc B) 350 cc C) 310 cc D) 510 cc

26. Which one of the following statements is wrong
A) Confined gas exerts uniform pressure on the wall of its container in all directions
B) Volume of the gas is equal, to volume of container in all directions
C) Gases do not have a definite shape and volume
D) Mass of the gas cannot be determined by weighing a container in which g as its enclosed

27. Two separate bulbs contain ideal gases A and B. The density of gas A is twice that of B. The molecular
weight A is half that of B. The two gases are at the same temperature. The ratio of pressure A to that of B
gas is
A) 2 B) 1/2 C) 4 D)

28. Partial pressure is directly proportional to the mole fraction of the solute. This is a statement of
A) Charleslaw B) Boyles law C) Raoults law D) Avogadros law

29. At what temperature will be RMS velocity of SO
2
be the same as that of O
2
at 303 K?
A) 2 J B) 4 J C) 8 J D) zero

30. The density f CH
4
at 2 atm and 27C is
A) Half of the total pressure B) 1/8
th
of the total pressure
C) Equal to the total pressure D) 1/3 of the total pressure

31. The one having highest bond energy is
A) N N B) F F C) C C D) O O

32. The highest dipolemoment is of
A) CF
4
B) CH
3
OH C) CO
2
D) CH
3
F

33. Born - Haber cycle is used to determine
A) Electron affinity B) Lattice energy C) Crystal energy D) All the above

34. Chemical bond implies
A) Attraction and repulsion B) Attraction and repulsion balanced at a particular distance
C) Attraction D) Repulsion

35. The correct order of N O bond length in NO, NO
-
2
, NO
-
3
and N
2
O
4
will be
A) NO > N
2
O
4
> NO
2
> NO
3
-
B) NO> NO
-
3
> N
2
O
4
> NO
2
-

C) NO
3
- > NO
2
-
> N
2
O
4
> NO D) N
2
O
4
> NO
2
-
> NO
3
-
> NO

36. The compound having highest dipole moment is


C I
C
C H
3 C I
C
C H
3
=
H
C
C H
3
=
H
C
C H
3
A )
B )
C )
C = O
H
H
C
C H
3
=
C H
3
H
C
H
D )


37. Both BF
3
and NF
3
are covalent but BF
3
molecule is non- polar while NF
3
is polar because
A) Atomic size of boron is smaller than that of nitro gen B) BF
3
is planar but NF
3
is pyramidal
C) Boron is a metal while nitrogen is a gas
D) BF bonds have no dipole moment while NF bonds have dipole moment

38. BF
3
molecule has planar structure Correct explanation for this is
A) B is sp
3
hybridised B) B is sp
2
hybridised C) B is sp hybridized D) B is sp
3
d hybridized

39. Which of the following molecule contains one lone pair of electrons on the central atom?
A) NH
3
B) CH
4
C) CHCI
3
D) CI
2


40. Which one of the following contains both covalent and ionic bonds?
A) NH
4
CI B) H
2
O C) CCI
4
D) CaCI
2