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Thermodynamic Properties
This section contains thermodynamic charts, correlations,
and calculation procedures.
The enthalpy correlation presents a rigorous method for calculation of enthalpy, followed by an example calculation illus-
FIG. 24-1
Nomenclature
hf
hg
hfg
sf
sg
sfg
vf
vg
vfg
xi
yi
Greek
Subscripts
Acentric factor: A factor frequently used in correlating thermodynamic properties defined by = log Pvr 1.00 where
Pvr = reduced vapor pressure at Tr = 0.7.
Corresponding states: The theory that proposes pure components and mixtures have the same relative thermodynamic
properties when at the same relative thermodynamic state.
Critical pressure: The vapor pressure at the critical temperature.
Critical temperature: The temperature at which vapor and
liquid properties become identical.
Datum: A reference point.
Density: Mass per unit volume of a substance.
Enthalpy: Heat content, H, composed of internal energy, E,
and PV. Usually expressed as H = E + PV.
Entropy: A thermodynamic quantity, S, defined by the equation dS = dQ/T where Q is the amount of heat entering or
leaving the system reversibly at absolute temperature, T.
Ideal gas: A gas which follows the equation PV = nRT where n
= number of moles, and V is volume per mole.
24-1
m = mixture property
i = any one component in a multicomponent mixture
ENTHALPY BEHAVIOR
The change of enthalpy with temperature and pressure is
complex. Predicting the enthalpy for a pure component or mixture is a multi-step procedure that requires information that
can only be obtained by experimental measurement. For pure
components, use of a P-H diagram like those shown in Figs. 2415 to 24-26 is recommended.
The enthalpy behavior of mixes can be predicted through
thermodynamic correlations. Use of a good contemporary equation of state is recommended for mixture enthalpy predictions.
Fig. 24-2 shows graphically the change in enthalpy of three gas
streams and two liquid streams as pressure is changed at constant temperature. Values for the plot were calculated by the
Soave10 version of the Redlich-Kwong equation of state11. The
curves in Fig. 24-2 are for no phase change and show typical
behavior of gas phase enthalpy decreasing and liquid phase enthalpy increasing with increasing pressure.
Enthalpies for mixtures of real gases and liquids can be predicted by hand calculation methods. The ones recommended for
use are based on an extension of the principle of corresponding
states and are shown graphically in Fig. 24-6 and 24-7.
by the enthalphy difference between the ideal gas state enthalpy and the enthalpy at the
desired pressure, both quantities at the specified temperature, kJ/kmole.
Since H00 is zero at the chosen datum, zero absolute temperature, Equation 24-1 can be written:
HTP = HT0 (HT0 HTP)
Which can be simplified to:
H = H0 (H0 H)
Eq 24-1
(H0 H) (0)
(H0 H) ()
+
(H
0 H) = RTc
RTc
RTc
Eq 24-4
where:
Figs. 24-6 and 24-7 can be used for gas and liquid mixtures.
If the mixture is a gas, use the lower chart in each figure. For
liquids read the value from the isotherms at the top of the chart.
The units of (H0 H) will depend on the units of the universal
gas constant, R, and Tc. For (H0 H) in kJ/mole, R = 8.3145
kJ/kmole K) and Tc is in K.
The reduced temperature and pressure are defined as Tr =
T/Tc and Pr = P/Pc, where absolute temperature and pressure
must be used. Values for pure component critical temperature,
pressure and acentric factor are in Section 23 Physical Properties. Section 23 also contains graphs relating ASTM distillation
temperature, molecular weight, specific gravity (relative density), critical temperature, and critical pressure for undefined
fractions. The fraction acentric factor can be estimated from Eq
23-17.
To use Figs. 24-6 and 24-7, the mixture composition must be
known. The mole fraction average (pseudo) critical temperature
and pressure are calculated using Kays Rule4 as illustrated in
Fig. 23-7 (TCm = yiTCi and PCm = yiPCi). The mole fraction average mixture enthalpy is calculated from:
Hm0 = yi H0i
Eq 24-5
where:
(HT0 H00) the ideal gas state enthalpy above the datum,
H0, at the desired temperature (subscript T),
kJ/kmole
Eq 24-3
Eq 24-2
m = yii
Eq 24-6
24-2
EXAMPLE CALCULATION
USING ENTHALPY CORRELATION
Caution: Some mixtures encountered in the calculations fell inside the phase envelopes of Figs. 24-6 and 24-7.
Rather than extrapolate into the phase envelopes of Figs.
24-6 and 24-7 for enthalpy pressure corrections, the total
enthalpies were first generated, plotted, and then extrapolated.
A current (2011) GPA Research Project, Project 042, is to measure physical properties (including heat capacity) in high pressure acid gas streams. H2S contents will range from 2080 mol%,
temperatures from 10176C, and pressures 350035 000 kPa
(abs).
Vapor enthalpies at 1000 kPa were extended to lower temperatures by assuming the relative enthalpy change with temperature to be the same as for the ideal gas.
ENTROPY CORRELATION
Entropy is most used as a guide for interpreting the behavior of gases and liquids in compression and expansion processes.
The entropy of a multicomponent mixture may be calculated by
combing ideal gas state entropies from API 441 with the Curl
and Pitzer2 tables of values for the change of entropy with pressure. Entropy equations for undefined mixtures (pseudo components) are not available but, for most uses where the pseudo
components are present in small concentration, they can satisfactorily be approximated by the nearest molecular weight paraffin hydrocarbon.
Physical properties of CO2 are discussed in more detail in Section 23. Note that the two examples copied here use the previous
GPSA Data Book chart version (12th Edition).
Another common use for a P-H chart is to plot refrigeration
cycles (using, say, the propane or ethylene charts). Such illustrations are frequently found in refrigeration text books.
Figures 24-13 and 24-14 show examples using a P-H diagram to display a process path.
24-3
REFERENCES
BIBLIOGRAPHY
Canjar, L. N. and Manning, F. S., Thermodynamic Properties and Reduced Correlations of Gases, Gulf Publishing Co., Houston, Texas,
1967.
Kesler, M. G. and Lee, B. I., Improve Prediction of Enthalpy of Fractions, Hydrocarbon Processing, 55, 1976, pp. 153-158.
Lee, M. C., Ratcliffe, A. E., Maddox, R. D., Parham, W. F. and Maddox,
R. N., Heat Capacity Determined for Crude Fractions, Hydrocarbon
Processing, June 1978, pp. 187-189.
Maddox, R. N. and L. Lilly, Gas Conditioning and Processing, Vol. 3,
Campbell Petroleum Series Inc., Norman, Oklahoma, 1990.
Properties for Light Petroleum Systems, Gulf Publishing Co., Houston, Texas, 1973.
16. Bailey, D.M., Liu, C.-H., Holste, P.T. and Eubank, P.T. Energy
Functions for H2S, Part 3: Near-equimolar Mixture with CO2,
Hydro. Process. Pet. Ref., Volume 67, Number 1, pp. 73-74,
1987.
17. Liu, C.H. Experimental Densities, Entropies and Energies for
Pure H2S and Equimolar Mixtures of H2S/CH4 and H2S/CO2 Between 300 and 500K, B Master of Science, Graduate College of
Texas A&M University, 1985.
18. Bailey, D.M., Liu, C.-H., Holste, J.C., Hall, K.R., Eubank, P.T.,
Marsh, K.M., Thermodynamic Properties of Pure Hydrogen Sulfide and Mixtures Containing Hydrogen Sulfide with Methane,
Carbon Dioxide, Methylcyclohexane and Toluene, GPA Research Report No. 107, 1987.
Technical Data Book Petroleum Refining, 3rd Ed., American Petroleum Institute, Washington, D.C., 1977.
24-4
FIG. 24-2
Influence of Pressure on Enthalpy for Typical Natural Gas Streams
24-5
FIG. 24-3
Ideal-Gas-State Enthalpy of Pure Components
24-6
FIG. 24-4
Ideal-Gas-State Enthalpy of Pure Components
24-7
FIG. 24-5
Ideal-Gas-State Enthalpy of Petroleum Fractions
24-8
FIG. 24-6
Effect of Pressure on Enthalpy (Simple Fluid)
24-9
FIG. 24-7
Effect of Pressure on Enthalpy (Correction for Real Fluids)
24-10
FIG. 24-8
Example Enthalpy Calculation
Mole Fraction
Molecular
Mass
Critical
Temp. K
Critical
Pressure kPa
Acentric Factor
Ideal Gas
Enthalpy kJ/kg
Methane
0.9010
16.04
190.6
4599.0
0.0108
682
Component
Carbon Dioxide
0.0106
44.01
304.1
7374.0
0.2667
234
Ethane
0.0499
30.07
305.4
4880.0
0.0972
442
Propane
0.0187
44.10
369.8
4240.0
0.1515
381
i-Butane
0.0065
58.12
407.8
3640.0
0.1852
357
n-Butane
0.0045
58.12
425.1
3784.0
0.1981
381
i-Pentane
0.0017
72.15
460.4
3381.0
0.2286
357
n-Pentane
0.0019
72.15
469.7
3365.0
0.2510
370
Hexane
0.0052
86.18
506.4
3030.0
0.2990
326
REDUCED TEMPERATURE
1.569
REDUCED PRESSURE
1.517
0.70
0.02
0.7005
1199.2
H, kJ/kmole
10220.6
NOTE: Ideal Gas Enthalpy for Hexane from the 12th Edition of the Data Book (Fig. 24-9).
Wichert and Aziz correction not applied to critical properties.
24-11
FIG. 24-9
Example Entropy Calculation
Component
Mole Fraction
Molecular
Weight
Critical
Temp. K
Critical
Pressure kPa
Acentric Factor
Ideal
Gas Entropy
kJ/(kg K)
Methane
0.9010
16.04
190.6
4599.0
0.0108
13.19
Carbon Dioxide
0.0106
44.01
304.1
7374.0
0.2667
4.90
Ethane
0.0499
30.07
305.4
4880.0
0.0972
8.50
Propane
0.0187
44.10
369.8
4240.0
0.1515
6.80
i-Butane
0.0065
58.12
407.8
3640.0
0.1852
5.83
n-Butane
0.0045
58.12
425.1
3784.0
0.1981
5.58
i-Pentane
0.0017
72.15
460.4
3381.0
0.2286
5.29
n-Pentane
0.0019
72.15
469.7
3365.0
0.2510
5.20
Hexane
0.0052
86.18
506.4
3030.0
0.2990
5.02
REDUCED TEMPERATURE
REDUCED PRESSURE
218.6
205.9
1.569
4613.3
1.517
0.02476
0.338
4.2353
(S0 S) (0)
(S0 S) ()
38.025
(S
0 S) = R
+w
+ ln P
R
R
R yi ln (yi)
3.935
Smo = ( yi Soi R yi ln yi )
222.5
184.5
NOTE:
24-12
FIG. 24-10
Ideal-gas-state Entropy of Pure Components
24-13
FIG. 24-11
Effect of Pressure on Entropy (Simple Fluid)
24-14
FIG. 24-12
Effect of Pressure on Entropy (Correction for Real Fluids)
24-15
24-16
CARBON DIOXIDE
Note that blowdown from higher temperatures, represented by the righthand path, remains within the vapor region, while blowdown from colder
temperatures, represented by the lefthand path, may cross the vapor-liquid envelope boundaries and generate liquid. Additionally, extending the lefthand
path below about 75 psia will result in the formation of solids (e.g., enters the vapor-solid equilibrium region).
FIG. 24-13
24-17
Last stage
recycle will form
liquid in
interstage
scrubber
CARBON DIOXIDE
FIG. 24-14
24-18
FIG. 24-15
24-19
FIG. 24-16
Span, R., Lemmon, E.W., Jacobsen, R.T, Wagner, W., and Yokozeki, A. A Reference Quality
Thermodynamic Property Formulation for Nitrogen, J. Phys. Chem. Ref. Data, 29(6):1361-1433,
2000.
24-20
NITROGEN
FIG. 24-17
Setzmann, U. and Wagner, W., A New Equation of State and Tables of Thermodynamic
Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to
1000 MPa, J. Phys. Chem. Ref. Data, 20(6):1061-1151, 1991.
24-21
METHANE
FIG. 24-18
24-22
ETHANE
FIG. 24-19
Smukala, J., Span, R. and Wagner, W. A New Equation of State for Ethylene Covering the Fluid
Region for Temperatures from the Melting Line to 450 K at Pressures up to 300 MPa, J. Phys.
Chem. Ref. Data, 29(5):1053-1122, 2000.
24-23
ETHYLENE
FIG. 24-20
Miyamoto, H., and Watanabe, K., A Thermodynamic Property Model for Fluid-phase Propane, Int.
J. Thermophys., 21(5):1045-1072, 2000.
24-24
PROPANE
FIG. 24-21
Angus, S., Armstrong, B., and de Reuck, K.M., International Thermodynamic Tables of the Fluid
State-7 Propylene, International Union of Pure and Applied Chemistry, Pergamon Press, Oxford,
1980..
24-25
PROPYLENE
FIG. 24-22
24-26
I-BUTANE
FIG. 24-23
Miyamoto, H. and Watanabe, K. A Thermodynamic Property Model for Fluid-Phase n-Butane, Int.
J. Thermophys., 22(2):459-475, 2001.
24-27
N-BUTANE
FIG. 24-24
24-28
I-PENTANE
FIG. 24-25
24-29
N-PENTANE
FIG. 24-26
Schmidt, R. and Wagner, W.,A New Form of the Equation of State for Pure Substances and its
Application to Oxygen, Fluid Phase Equilibria, 19:175-200, 1985.
24-30
OXYGEN
24-31
TPT
NBP
TC
PC
90.6941
90.352
85.48
113.56
134.87
112.65
143.47
103.986
87.95
63.151
54.361
216.592
TPT
K
NBP
K
4599.2
4871.8
4247.09
3640.0
3796.0
3396.0
3370.0
5041.8
4664.6
3395.8
5043.0
7377.3
PC
kPa
10.139
6.87
4.95514
3.860
3.920
3.271
3.2156
7.637
5.3086
11.1839
13.63
10.6249
182.80
182.46
210.00
56.56
169.16
187.67
173.15
159.59
138.28
159.90
129.68
218.79
Ethane
Methane
N2
CO2
Ethylene
Propane
Propylene
I-Butane
n-Butane
I-Pentane
n-Pentane
Oxygen
NIST
NIST
NIST
NIST
NIST
NIST
NIST
NIST
NIST
TRC
NIST
NIST
Reference Temperature
Value (C)
Database
TRC
TRC
TRC
TRC
TRC
TRC
TRC
TRC
TRC
TRC
TRC
TRC
Reference Pressure
Value (kPa) Database
1.131E03
1.170E+01
1.252E+01
5.187E+02
1.260E01
1.685E07
9.332E07
1.206E05
6.736E04
1.214E07
7.632E05
1.500E01
TMAX
K
90.6941
625
90.352
625
85.48
623
113.56
573
134.87
589
112.65
600
143.47
600
103.986
450
100.0
600
63.151
2000
54.361
1000
216.592
1100
TMIN
K
1000000
70000
103000
35000
69000
1000000
100000
260000
200000
2200000
82000
800000
PMAX
kPa
40.072
22.419
17.41
12.90
13.15
10.93
10.57
26.67
17.95
53.15
43.348
37.24
RHOMAX
Mol/L
PMAX
Maximum Recommended
Pressure
RHOMAX Maximum Recommended Density
.01142
.0993
.1524
.185
.2
.2296
.251
.0866
.1408
.0372
.0222
.22394
RHOC
ACEN
Mol/L
Critical Density
Acentric Factor
Minimum Recommended Temperature
Maximum Recommended Temperature
190.564
305.33
369.825
407.817
425.125
460.35
469.7
282.35
365.57
126.192
154.581
304.1282
TC
K
RHOC
ACEN
TMIN
TMAX
111.667
184.552
231.06
261.48
272.6
300.97
309.21
169.379
225.46
77.355
90.1878
194.75
Methane
Ethane
Propane
Isobutane
n-Butane
Isopentane
n-Pentane
Ethylene
Propylene
Nitrogen
Oxygen
Carbon Dioxide
Substance
Virtual Materials Group gratefully acknowledges the assistance provided by Dr. Eric Lemmon and Dr. Michael Frenkel from the National Institute
of Standards and Technology (NIST) for their assistance in the preparation of the P-H Diagrams presented in Fig. 24-15 through Fig. 24-26 and as the
basis for Figs. 24-13 and 24-14.
Acknowledgments
FIG. 24-27
Thermodynamic Properties of Water
24-32
FIG. 24-28
Thermodynamic Properties of Water
24-33
FIG. 24-29
Saturated Steam: Temperature Table
Temp.
C
T
Press.
kPa
P
Specific Volume
Sat.
Sat.
Vapor
Liquid
vg
vf
Internal Energy
Sat.
Liquid
uf
Evap.
ufg
0.01
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
205
210
215
220
225
230
235
240
245
250
255
260
265
270
275
280
285
290
295
300
305
310
315
320
330
340
350
360
370
0.6113
0.8721
1.2276
1.7051
2.339
3.169
4.246
5.628
7.384
9.593
12.349
15.758
19.940
25.03
31.19
38.58
47.39
57.83
70.14
84.55
101.35
120.82
143.27
169.06
198.53
232.1
270.1
313.0
361.3
415.4
475.8
543.1
617.8
700.5
791.7
892.0
1002.1
1122.7
1254.4
1397.8
1553.8
1723.0
1906.2
2104.
2318.
2518.
2795.
3060.
3344.
3618.
3973.
4319.
4688.
5081.
5499.
5942.
6412.
6909.
7436.
7993.
8581.
9202.
9856.
10547.
11274.
12845.
14586.
16513.
18651.
21030.
0.001 000
0.001 000
0.001 000
0.001 001
0.001 002
0.001 003
0.001 004
0.001 006
0.001 008
0.001 010
0.001 012
0.001 015
0.001 017
0.001 020
0.001 023
0.001 026
0.001 029
0.001 033
0.001 036
0.001 040
0.001 044
0.001 048
0.001 052
0.001 056
0.001 060
0.001 065
0.001 070
0.001 075
0.001 080
0.001 085
0.001 091
0.001 096
0.001 102
0.001 108
0.001 114
0.001 121
0.001 127
0.001 134
0.001 141
0.001 149
0.001 157
0.001 164
0.001 173
0.001 181
0.001 190
0.001 199
0.001 209
0.001 219
0.001 229
0.001 240
0.001 251
0.001 263
0.001 276
0.001 289
0.001 302
0.001 317
0.001 332
0.001 348
0.001 366
0.001 384
0.001 404
0.001 425
0.001 447
0.001 472
0.001 499
0.001 561
0.001 638
0.001 740
0.001 893
0.002 213
206.14
147.12
106.38
77.93
57.79
43.36
32.89
25.22
19.52
15.26
12.03
9.568
7.671
6.197
5.042
4.131
3.407
2.828
2.361
1.982
1.6729
1.4194
1.2102
1.0366
0.8919
0.7706
0.6685
0.5822
0.5089
0.4463
0.3928
0.3468
0.3071
0.2727
0.2428
0.2168
0.194 05
0.174 09
0.156 54
0.141 05
0.127 36
0.115 21
0.104 41
0.094 79
0.086 19
0.078 49
0.071 58
0.065 37
0.059 76
0.054 71
0.050.13
0.045 98
0.042 21
0.038 77
0.035 64
0.032 79
0.030 17
0.027 77
0.025 57
0.023 54
0.021 67
0.019 948
0.018 350
0.016 867
0.015 488
0.012 996
0.010 797
0.008 813
0.006 945
0.004 925
.00
20.97
42.00
62.99
83.95
104.88
125.78
146.67
167.36
188.44
209.32
230.21
251.11
272.02
292.95
313.90
334.86
355.84
376.85
397.88
418.94
440.02
461.14
482.30
503.50
524.74
546.02
567.35
588.74
610.18
631.68
653.24
674.87
696.56
718.33
740.17
762.09
784.10
806.19
828.37
850.65
873.04
895.53
918.14
940.87
963.73
986.74
1009.89
1033.21
1056.71
1080.39
1104.28
1128.39
1152.74
1177.36
1202.25
1227.46
1253.00
1278.92
1305.2
1332.0
1359.3
1387.1
1415.5
1444.6
1505.3
1570.3
1641.9
1725.2
1844.0
2375.3
2361.3
2347.2
2333.1
2319.0
2304.9
2290.8
2276.7
2262.6
2248.4
2234.2
2219.9
2205.5
2191.1
2176.6
2162.0
2147.4
2132.6
2117.7
2102.7
2087.6
2072.3
2057.0
2041.4
2025.8
2009.9
1993.9
1977.7
1961.3
1944.7
1927.9
1910.8
1893.5
1876.0
1858.1
1840.0
1821.6
1802.9
1783.8
1764.4
1744.7
1724.5
1703.9
1682.9
1661.5
1639.6
1617.2
1594.2
1570.8
1546.7
1522.0
1496.7
1470.6
1443.9
1416.3
1387.9
1358.7
1328.4
1297.1
1264.7
1231.0
1195.9
1159.4
1121.1
1080.9
993.7
894.3
776.6
626.3
384.5
374.14
22090.
0.003 155
0.003 155
2029.6
Enthalpy
Sat.
Vapor
ug
2375.3
2382.3
2389.2
2396.1
2402.9
2409.8
2416.6
2423.4
2430.1
2436.8
2443.5
2450.1
2456.6
2463.1
2469.6
2475.9
2482.2
2488.4
2494.5
2500.6
2506.5
2512.4
2518.1
2523.7
2529.3
2534.6
2539.9
2545.0
2550.0
2554.9
2559.5
2564.1
2568.4
2572.5
2576.5
2580.2
2583.7
2587.0
2590.0
2592.8
2595.3
2597.5
2599.5
2601.1
2602.4
2603.3
2603.9
2604.1
2604.0
2603.4
2602.4
2600.9
2599.0
2596.6
2593.7
2590.2
2586.1
2581.4
2576.0
2569.9
2563.0
2555.2
2546.4
2536.6
2525.5
2498.9
2464.6
2418.4
2351.5
2228.5
2029.6
24-34
Sat.
Liquid
hf
.01
20.98
42.01
62.99
83.96
104.89
125.79
146.68
167.37
188.45
209.33
230.23
251.13
272.06
292.98
313.93
334.91
355.90
376.92
397.96
419.04
440.15
461.30
482.48
503.71
524.99
546.31
567.69
589.13
610.63
632.20
653.84
675.55
697.34
719.21
741.17
763.22
785.37
807.62
829.98
852.45
875.04
897.76
920.62
943.62
966.78
990.12
1013.62
1037.32
1061.23
1085.36
1109.73
1134.37
1159.28
1184.51
1210.07
1235.99
1262.31
1289.07
1316.3
1344.0
1372.4
1401.3
1431.0
1461.5
1525.3
1594.2
1670.6
1760.5
1890.5
2099.3
Entropy
Evap.
hfg
Sat.
Vapor
hg
Sat.
Liquid
sf
Evap.
sfg
Sat.
Vapor
sg
2501.3
2489.6
2477.7
2465.9
2454.1
2442.3
2430.5
2418.6
2406.7
2394.8
2382.7
2370.7
2358.5
2346.2
2333.8
2321.4
2308.8
2296.0
2283.2
2270.2
2257.0
2243.7
2230.2
2216.5
2202.6
2188.5
2174.2
2159.6
2144.7
2129.6
2114.3
2098.6
2082.6
2066.2
2049.5
2032.4
2015.0
1997.1
1978.8
1960.0
1940.7
1921.0
1900.7
1879.9
1858.5
1836.5
1813.8
1790.5
1766.5
1741.7
1716.2
1689.8
1662.5
1634.4
1605.2
1574.9
1543.6
1511.0
1477.1
1441.8
1404.9
1366.4
1326.0
1283.5
1238.6
1140.6
1027.9
893.4
720.5
441.6
2501.4
2510.6
2519.8
2528.9
2538.1
2547.2
2556.3
2565.3
2574.3
2583.2
2592.1
2600.9
2609.6
2618.3
2626.8
2635.3
2643.7
2651.9
2660.1
2668.1
2676.1
2683.8
2691.5
2699.0
2706.3
2713.5
2720.5
2727.3
2733.9
2740.3
2746.5
2752.4
2758.1
2763.5
2768.7
2773.6
2778.2
2782.4
2786.4
2790.0
2793.2
2796.0
2798.5
2800.5
2802.1
2803.3
2804.0
2804.2
2803.8
2803.0
2801.5
2799.5
2796.9
2793.6
2789.7
2785.0
2779.6
2773.3
2766.2
2758.1
2749.0
2738.7
2727.3
2714.5
2700.1
2665.9
2622.0
2563.9
2481.0
2332.1
.0000
.0761
.1510
.2245
.2966
.3674
.4369
.5053
.5725
.6387
.7038
.7679
.8312
.8935
.9549
1.0155
1.0753
1.1343
1.1925
1.2500
1.3069
1.3630
1.4185
1.4734
1.5276
1.5813
1.6344
1.6870
1.7391
1.7907
1.8418
1.8925
1.9427
1.9925
2.0419
2.0909
2.1396
2.1879
2.2359
2.2835
2.3309
2.3780
2.4248
2.4714
2.5178
2.5639
2.6099
2.6558
2.7015
2.7472
2.7927
2.8383
2.8838
2.9294
2.9751
3.0208
3.0668
3.1130
3.1594
3.2062
3.2534
3.3010
3.3493
3.3982
3.4480
3.5507
3.6594
3.7777
3.9147
4.1106
9.1562
8.9496
8.7498
8.5569
8.3706
8.1905
8.0164
7.8478
7.6845
7.5261
7.3725
7.2234
7.0784
6.9375
6.8004
6.6669
6.5369
6.4102
6.2866
6.1659
6.0480
5.9328
5.8202
5.7100
5.6020
5.4962
5.3925
5.2907
5.1908
5.0926
4.9960
4.9010
4.8075
4.7153
4.6244
4.5347
4.4461
4.3586
4.2720
4.1863
4.1014
4.0172
3.9337
3.8507
3.7683
3.6863
3.6047
3.5233
3.4422
3.3612
3.2802
3.1992
3.1181
3.0368
2.9551
2.8730
2.7903
2.7070
2.6227
2.5375
2.4511
2.3633
2.2737
2.1821
2.0882
1.8909
1.6763
1.4335
1.1379
.6865
9.1562
9.0257
8.9008
8.7814
8.6672
8.5580
8.4533
8.3531
8.2570
8.1648
8.0763
7.9913
7.9096
7.8310
7.7553
7.6824
7.6122
7.5445
7.4791
7.4159
7.3549
7.2958
7.2387
7.1833
7.1296
7.0775
7.0269
6.9777
6.9299
6.8833
6.8379
6.7935
6.7502
6.7078
6.6663
6.6256
6.5857
6.5465
6.5079
6.4698
6.4323
6.3952
6.3585
6.3221
6.2861
6.2503
6.2146
6.1791
6.1437
6.1083
6.0730
6.0375
6.0019
5.9662
5.9301
5.8938
5.8571
5.8199
5.7821
5.7437
5.7045
5.6643
5.6230
5.5804
5.5362
5.4417
5.3357
5.2112
5.0526
4.7971
2099.3
4.4298
4.4298
Temp.
C
T
0.01
6.98
13.03
17.50
21.08
24.08
28.96
32.88
40.29
45.81
53.97
60.05
64.97
69.10
75.87
81.33
91.78
99.63
105.99
111.37
116.06
120.23
124.00
127.44
130.60
133.55
136.30
138.88
141.32
143.63
147.93
151.86
155.48
158.85
162.01
164.97
167.78
170.43
172.96
175.38
177.69
179.91
184.09
187.99
191.64
195.07
198.32
205.76
212.42
218.45
223.99
233.90
242.60
250.40
263.99
275.64
285.88
295.06
303.40
311.06
318.15
324.75
330.93
336.75
342.24
347.44
352.37
357.06
361.54
365.81
369.89
373.80
374.14
Specific Volume
Sat.
Liquid
vf
0.001 000
0.001 000
0.001 001
0.001 001
0.001 002
0.001 003
0.001 004
0.001 005
0.001 008
0.001 010
0.001 014
0.001 017
0.001 020
0.001 022
0.001 027
0.001 030
0.001 037
0.001 043
0.001 048
0.001 053
0.001 057
0.001 061
0.001 064
0.001 067
0.001 070
0.001 073
0.001 076
0.001 079
0.001 081
0.001 084
0.001 088
0.001 093
0.001 097
0.001 101
0.001 104
0.001 108
0.001 112
0.001 115
0.001 118
0.001 121
0.001 124
0.001 127
0.001 133
0.001 139
0.001 144
0.001 149
0.001 154
0.001 166
0.001 177
0.001 187
0.001 197
0.001 217
0.001 235
0.001 252
0.001 286
0.001 319
0.001 351
0.001 384
0.001 418
0.001 452
0.001 489
0.001 527
0.001 567
0.001 611
0.001 658
0.001 711
0.001 770
0.001 840
0.001 924
0.002 036
0.002 207
0.002 742
0.003 155
Sat.
Vapor
vg
206.14
129.21
87.98
67.00
54.25
45.67
34.80
28.19
19.24
14.67
10.02
7.649
6.204
5.229
3.993
3.240
2.217
1.6940
1.3749
1.1593
1.0036
0.8857
0.7933
0.7187
0.6573
0.6058
0.5620
0.5243
0.4914
0.4625
0.4140
0.3749
0.3427
0.3157
0.2927
0.2729
0.2556
0.2404
0.2270
0.2150
0.2042
0.194 44
0.177 53
0.163 33
0.151 25
0.140 84
0.131 77
0.113 49
0.099 63
0.088 75
0.079 98
0.066 68
0.057 07
0.049 78
0.039 44
0.032 44
0.027 37
0.023 52
0.020 48
0.018 026
0.015 987
0.014 263
0.012 780
0.011 485
0.010 337
0.009 306
0.008 364
0.007 489
0.006 657
0.005 834
0.004 952
0.003 568
0.003 155
Internal Energy
Sat.
Liquid
uf
00
29.30
54.71
73.48
88.48
101.04
121.45
137.81
168.78
191.82
225.92
251.38
271.90
289.20
317.53
340.44
384.31
417.36
444.19
466.94
486.80
504.49
520.47
535.10
548.59
561.15
572.90
583.95
594.40
604.31
622.77
639.68
655.32
669.90
683.56
696.44
708.64
720.22
731.27
741.83
751.95
761.68
780.09
797.29
813.44
828.70
843.16
876.46
906.44
933.83
959.11
1004.78
1045.43
1082.31
1147.81
1205.44
1257.55
1305.57
1350.51
1393.04
1433.7
1473.0
1511.1
1548.6
1585.0
1622.7
1660.2
1698.9
1739.9
1785.6
1842.1
1961.9
2029.6
Evap.
ufg
2375.3
2355.7
2338.6
2326.0
2315.9
2307.5
2293.7
2282.7
2261.7
2246.1
2222.8
2205.4
2191.2
2179.2
2159.5
2143.4
2112.4
2088.7
2069.3
2052.7
2038.1
2025.0
2013.1
2002.1
1991.9
1982.4
1973.5
1965.0
1956.9
1949.3
1934.9
1921.6
1909.2
1897.5
1886.5
1876.1
1866.1
1856.6
1847.4
1838.6
1830.2
1822.0
1806.3
1791.5
1777.5
1764.1
1751.3
1721.4
1693.8
1668.2
1644.0
1599.3
1558.3
1520.0
1449.3
1384.3
1323.0
1264.2
1207.3
1151.4
1096.0
1040.7
985.0
928.2
869.8
809.0
744.8
675.4
598.1
507.5
388.5
125.2
0
Enthalpy
Sat.
Vapor
ufg
2375.3
2385.0
2393.3
2399.5
2404.4
2408.5
2415.2
2420.5
2430.5
2437.9
2448.7
2456.7
2463.1
2468.4
2477.0
2483.9
2496.7
2506.1
2513.5
2519.7
2524.9
2529.5
2533.6
2537.2
2540.5
2543.6
2546.4
2548.9
2551.3
2553.6
2557.6
2561.2
2564.5
2567.4
2570.1
2572.5
2574.7
2576.8
2578.7
2580.5
2582.1
2583.6
2586.4
2588.8
2591.0
2592.8
2594.5
2597.8
2600.3
2602.0
2603.1
2604.1
2603.7
2602.3
2597.1
2589.7
2580.5
2569.8
2557.8
2544.4
2529.8
2513.7
2496.1
2476.8
2455.5
2431.7
2405.0
2374.3
2338.1
2293.0
2230.6
2087.1
2029.6
24-35
Sat.
Liquid
hfg
01.
29.30
54.71
73.48
88.49
101.05
121.46
137.82
168.79
191.83
225.94
251.40
271.93
289.23
317.58
340.49
384.39
417.46
444.32
467.11
486.99
504.70
520.72
535.37
548.89
561.47
573.25
584.33
594.81
604.74
623.25
640.23
655.93
670.56
684.28
697.22
709.47
721.11
732.22
742.83
753.02
762.81
781.34
798.65
814.93
830.30
844.89
878.50
908.79
936.49
962.11
1008.42
1049.75
1087.31
1154.23
1213.35
1267.00
1316.64
1363.26
1407.56
1450.1
1491.3
1531.5
1571.1
1610.5
1650.1
1690.3
1732.0
1776.5
1826.3
1888.4
2022.2
2099.3
Evap.
hfg
2501.3
2484.9
2470.6
2460.0
2451.6
2444.5
2432.9
2423.7
2406.0
2392.8
2373.1
2358.3
2346.3
2336.1
2319.2
2305.4
2278.6
2258.0
2241.0
2226.5
2213.6
2201.9
2191.3
2181.5
2172.4
2163.8
2155.8
2148.1
2140.8
2133.8
2120.7
2108.5
2097.0
2086.3
2076.0
2066.3
2057.0
2048.0
2039.4
2031.1
2023.1
2015.3
2000.4
1986.2
1972.7
1959.7
1947.3
1917.9
1890.7
1865.2
1841.0
1795.7
1753.7
1714.1
1640.1
1571.0
1505.1
1441.3
1378.9
1317.1
1255.5
1193.6
1130.7
1066.5
1000.0
930.6
856.9
777.1
688.0
583.4
446.2
143.4
0
Entropy
Sat.
Vapor
hg
2501.4
2514.2
2525.3
2533.5
2540.0
2545.5
2554.4
2561.5
2574.8
2584.7
2599.1
2609.7
2618.2
2625.3
2636.8
2645.9
2663.0
2675.5
2685.4
2693.6
2700.6
2706.7
2712.1
2716.9
2721.3
2725.3
2729.0
2732.4
2735.6
2738.6
2743.9
2748.7
2753.0
2756.8
2760.3
2763.5
2766.4
2769.1
2771.6
2773.9
2776.1
2778.1
2781.7
2784.8
2787.6
2790.0
2792.2
2796.4
2799.5
2801.7
2803.1
2804.2
2804.2
2801.4
2794.3
2784.3
2772.1
2758.0
2742.1
2724.7
2705.6
2684.9
2662.2
2637.6
2610.5
2580.6
2547.2
2509.1
2464.5
2409.7
2334.6
2165.6
2099.3
Sat.
Liquid
sf
.0000
.1059
.1957
.2607
.3120
.3545
.4226
.4764
.5764
.6493
.7549
.8320
.8931
.9439
1.0259
1.0910
1.2130
1.3026
1.3740
1.4336
1.4849
1.5301
1.5706
1.6072
1.6408
1.6718
1.7006
1.7275
1.7528
1.7766
1.8207
1.8607
1.8973
1.9312
1.9627
1.9922
2.0200
2.0462
2.0710
2.0946
2.1172
2.1387
2.1792
2.2166
2.2515
2.2842
2.3150
2.3851
2.4474
2.5035
2.5547
2.6457
2.7253
2.7964
3.9202
3.0267
3.1211
3.2068
3.2858
3.3596
3.4295
3.4962
3.5606
3.6232
3.6848
3.7461
3.8079
3.8715
3.9388
4.0139
4.1075
4.3110
4.4298
Evap.
sfg
9.1562
8.8697
8.6322
8.4629
8.3311
8.2231
8.0520
7.9187
7.6750
7.5009
7.2536
7.0766
6.9383
6.8247
6.6441
6.5029
6.2434
6.0368
5.9104
5.7897
5.6868
5.5970
5.5173
5.4455
5.3801
5.3201
5.2646
5.2130
5.1647
5.1193
5.0359
4.9606
4.8920
4.8288
4.7703
4.7158
4.6647
4.6166
4.5711
4.5280
4.4869
4.4478
4.3744
4.3067
4.2438
4.1850
4.1298
4.0044
3.8935
3.7937
3.7028
3.5412
3.4000
3.2737
3.0532
2.8625
2.6922
2.5364
2.3915
2.2544
2.1233
1.9962
1.8718
1.7485
1.6249
1.4994
1.3698
1.2329
1.0839
.9130
.6938
.2216
0
Sat.
Vapor
sg
9.1562
8.9756
8.8279
8.7237
8.6432
8.5776
8.4746
8.3951
8.2515
8.1502
8.0085
7.9085
7.8314
7.7686
7.6700
7.5939
7.4564
7.3594
7.2844
7.2233
7.1717
7.1271
7.0878
7.0527
7.0209
6.9919
6.9652
6.9405
6.9175
6.8959
6.8565
6.8213
6.7893
6.7600
6.7331
6.7080
6.6847
6.6628
6.6421
6.6226
6.6041
6.5865
6.5536
6.5233
6.4953
6.4693
6.4448
6.3896
6.3409
6.2972
6.2575
6.1869
6.1253
6.0701
5.9734
5.8892
5.8133
5.7432
5.6772
5.6141
5.5527
5.4924
5.4323
5.3717
5.3098
5.2455
5.1777
5.1044
5.0228
4.9269
4.8013
5.5327
4.4298
FIG. 24-30
Superheated Vapor
P = 10 kPa (45.81C)
T
Sat.
50
100
150
200
250
300
400
500
600
700
800
900
1000
1100
1200
1300
v
14.674
14.869
17.196
19.512
21.825
24.136
26.445
31.063
35.679
40.295
44.911
49.526
54.141
58.757
63.372
67.987
72.602
Sat.
150
200
250
300
400
500
600
700
800
900
1000
1100
1200
1300
.8857
.9596
1.0803
1.1988
1.3162
1.5493
1.7814
2.013
2.244
2.475
2.706
2.937
3.168
3.399
3.630
Sat
200
250
300
350
400
500
600
700
800
900
1000
1100
1200
1300
.3749
.4249
.4744
.5226
.5701
.6173
.7109
.8041
.8969
.9896
1.0822
1.1747
1.2672
1.3596
1.4521
Sat
200
250
300
350
400
500
600
700
800
900
1000
1100
1200
1300
.194 44
.2060
.2327
.2579
.2825
.3066
.3541
.4011
.4478
.4943
.5407
.5871
.6335
.6798
.7261
u
2437.9
2443.9
2515.5
2587.9
2661.3
2736.0
2812.1
2968.9
3132.3
3302.5
3479.6
3663.8
3855.0
4053.0
4257.5
4467.9
4683.7
h
2584.7
2592.6
2687.5
2783.0
2879.5
2977.3
3076.5
3279.6
3489.1
3705.4
3928.7
4159.0
4396.4
4640.6
4891.2
5147.8
5409.7
P = 50 kPa (81.33C)
v
3.240
u
2483.9
h
2645.9
s
7.5939
v
1.6940
u
2506.1
h
2675.5
s
7.3594
3.418
3.889
4.356
4.820
5.284
6.209
7.134
8.057
8.981
9.904
10.828
11.751
12.674
13.597
14.521
2511.6
2585.6
2659.9
2735.0
2811.3
2968.5
3132.0
3302.2
3479.4
3663.6
3854.9
4052.9
4257.4
4467.8
4683.6
2682.5
2780.1
2877.7
2976.0
3075.5
3278.9
3488.7
3705.1
3928.5
4158.9
4396.3
4640.5
4891.1
5147.7
5409.6
7.6958
7.9401
8.1580
8.3556
8.5373
8.8642
9.1546
9.4178
9.6599
9.8852
10.0967
10.2964
10.4859
10.6662
10.8382
1.6958
1.9364
2.172
2.406
2.639
3.103
3.565
4.028
4.490
4.952
5.414
5.875
6.337
6.799
7.260
2506.7
2582.8
2658.1
2733.7
2810.4
2967.9
3131.6
3301.9
3479.2
3663.5
3854.8
4052.8
4257.3
4467.7
4683.5
2676.2
2776.4
2875.3
2974.3
3074.3
3278.2
3488.1
3704.7
3928.2
4158.6
4396.1
4640.3
4891.0
5147.6
5409.5
7.3614
7.6134
7.8343
8.0333
8.2158
8.5435
8.8342
9.0976
9.3398
9.5652
9.7767
9.9764
10.1659
10.3463
10.5183
7.1272
7.2795
7.5066
7.7086
7.8926
8.2218
8.5133
8.7770
9.0194
9.2449
9.4566
9.6563
9.8458
10.0262
10.1982
.6058
.6339
.7163
.7964
.8753
1.0315
1.1867
1.3414
1.4957
1.6499
1.8041
1.9581
2.1121
2.2661
2.4201
6.9919
7.0778
7.3115
7.5166
7.7022
8.0330
8.3251
8.5892
8.8319
9.0576
9.2692
9.4690
9.6585
9.8389
10.0110
.4625
.4708
.5342
.5951
.6548
.7726
.8893
1.0055
1.1215
1.2372
1.3529
1.4685
1.5840
1.6996
1.8151
6.8213
7.0592
7.2709
7.4599
7.6329
7.7938
8.0873
7.3522
8.5952
8.8211
9.0329
9.2328
9.4224
9.6029
9.7749
.3157
.3520
.3938
.4344
.4742
.5137
.5920
.6697
.7472
.8245
.9017
.9788
1.0559
1.1330
1.2101
6.7600
6.9665
7.1816
7.3724
7.5464
7.7079
8.0021
8.2674
8.5107
8.7367
8.9486
9.1485
9.3381
9.5185
9.6906
.2404
.2608
.2931
.3241
.3544
.3843
.4433
.5018
.5601
.6181
.6761
.7340
.7919
.8497
.9076
6.5865
6.6940
6.9247
7.1229
7.3011
7.4651
7.7622
8.0290
8.2731
8.4996
8.7118
8.9119
9.1017
9.2822
9.4543
.163 33
.169 30
.192 34
.2138
.2345
.2548
.2946
.3339
.3729
.4118
.4505
.4892
.5278
.5665
.6051
6.5233
6.5898
6.8294
7.0317
7.2121
7.3774
7.6959
7.9435
8.1881
8.4148
8.6272
8.8274
9.0172
9.1977
9.3698
.140 84
.143 02
.163 50
.182 28
.2003
.2178
.2521
.2860
.3195
.3528
.3861
.4192
.4524
.4855
.5186
2706.7
2768.8
2870.5
2971.0
3071.8
3276.6
3487.1
3704.0
3927.6
4158.2
4395.8
4640.0
4890.7
5147.3
5409.3
2748.7
2855.4
2960.7
3064.2
3167.7
3271.9
3483.9
3701.7
3925.9
4156.9
4394.7
4639.1
4889.9
5146.6
5408.6
2778.1
2827.9
2942.6
3051.2
3157.7
3263.9
3478.5
3697.9
3923.1
4154.7
4392.9
4637.6
4888.6
5145.4
5407.4
2543.6
2570.8
2650.7
2728.7
2806.7
2965.6
3130.0
3300.8
3478.4
3662.9
3854.2
4052.3
4256.8
4467.2
4683.0
2725.3
2761.0
2865.6
2967.6
3069.3
3275.0
3486.0
3703.2
3927.1
4157.8
4395.4
4639.7
4890.4
5147.1
5409.0
s
8.1502
8.1749
8.4479
8.6882
8.9038
9.1002
9.2813
9.6077
9.8978
10.1608
10.4028
10.6281
10.8396
11.0393
11.2287
11.4091
11.5811
2567.4
2638.9
2720.9
2801.0
2881.2
2962.1
3127.6
3299.1
3477.0
3661.8
3853.4
4051.5
4256.1
4466.5
4682.3
2756.8
2850.1
2957.2
3061.6
3165.7
3270.3
3482.8
3700.9
3925.3
4156.5
4394.4
4638.8
4889.6
5146.3
5408.3
2784.8
2815.9
2935.0
3045.8
3153.6
3260.7
3476.3
3696.3
3922.0
4153.8
4392.2
4637.0
4888.0
5144.9
5407.0
2738.6
2752.8
2860.5
2964.2
3066.8
3273.4
3484.9
3702.4
3926.5
4157.3
4395.1
4639.4
4890.2
5146.8
5408.8
6.8959
6.9299
7.1706
7.3789
7.5662
7.8985
8.1913
8.4558
8.6987
8.9244
9.1362
9.3360
9.5256
9.7060
9.8780
2553.6
2564.5
2646.8
2726.1
2804.8
2964.4
3129.2
3300.2
3477.9
3662.4
3853.9
4052.0
4256.5
4467.0
4682.8
2576.8
2630.6
2715.5
2797.2
2878.2
2959.7
3126.0
3297.9
3476.2
3661.1
3852.8
4051.0
4255.6
4466.1
4681.8
2769.1
2839.3
2950.0
3056.5
3161.7
3267.1
3480.6
3699.4
3924.2
4155.6
4393.7
4638.2
4889.1
5145.9
5407.9
6.6628
6.8158
7.0384
7.2328
7.4089
7.5716
7.8673
8.1333
8.3770
8.6033
8.8153
9.0153
9.2050
9.3855
9.5575
2790.0
2803.3
2927.2
3040.4
3149.5
3257.5
3474.1
3694.8
3920.8
4153.0
4391.5
4636.4
4887.5
5144.4
5606.5
6.4693
6.4975
6.7467
6.9534
7.1360
7.3026
7.6027
7.8710
8.1160
8.3431
8.5556
8.7559
8.9457
9.1262
9.2984
Symbols Used in Steam Tables: Ppressure, kPa (abs); Tthermodynamic temperature, C; vspecific volume, m3/kg; uspecific internal energy, kJ/kg; hspecific enthalpy, kJ/kg
sspecific entropy, kJ/(kgK) Adapted from Joseph H. Keenan, Frederick G. Keyes, Philip G. Hill, and Joan G. Moore, Steam Tables, (New York: John Wiley & sons, Inc., 1969).
24-36
.123 80
.132 87
.141 84
.158 62
.174 56
.190 05
.2203
.2500
.2794
.3086
.3377
.3668
.3958
.4248
.4538
Sat.
225
250
300
350
400
450
500
600
700
800
900
1000
1100
1200
1300
.079 98
.080 27
.087 00
.098 90
.109 76
.120 10
.130 14
.139 98
.159 30
.178 32
.197 16
.215 90
.2346
.2532
.2718
.2905
Sat.
275
300
350
400
450
500
600
700
800
900
1000
1100
1200
1300
.049 78
.054 57
.058 84
.066 45
.073 41
.080 02
.086 43
.098 85
.110 95
.122 87
.134 69
.146 45
.158 17
.169 87
.181 56
Sat.
300
350
400
450
500
550
600
700
800
900
1000
1100
1200
1300
.032 44
.036 16
.042 23
.047 39
.052 14
.056 65
.061 01
.065 25
.073 52
.081 60
.089 58
.097 49
.105 36
.113 21
.121 06
2596.0
2644.7
2692.3
2781.1
2866.1
2950.1
3119.5
3293.3
3472.7
3658.3
3850.5
4049.0
4253.7
4464.2
4679.9
2794.0
2857.3
2919.2
3034.8
3145.4
3254.2
3472.0
3693.2
3919.7
4152.1
4390.8
4635.8
4887.0
5143.9
5406.0
.110 42
.116 73
.124 97
.140 21
.154 57
.168 47
.195 50
.2220
.2482
.2742
.3001
.3260
.3518
.3776
.4034
6.2575
6.2639
6.4085
6.6438
6.8403
7.0148
7.1746
7.3234
7.5960
7.8435
8.0720
8.2853
8.4861
8.6762
8.8569
9.0291
.066 68
2604.1
.070 58
.081 14
.090 53
.099 36
.107 87
.116 19
.132 43
.148 38
.164 14
.179 80
.195 41
.210 98
.226 52
.242 06
2644.0
2750.1
2843.7
2932.8
3020.4
3108.0
3285.0
3466.5
3653.5
3846.5
4045.4
4250.3
4460.9
4676.6
6.0701
6.2285
6.3615
6.5821
6.7690
6.9363
7.0901
7.3688
7.6198
7.8502
8.0647
8.2662
8.4567
8.6376
8.8100
.044 06
.047 30
.051 35
.058 40
.064 75
.070 74
.076 51
.087 65
.098 47
.109 11
.119 65
.130 13
.140 56
.150 98
.161 39
5.8892
6.0674
6.3335
6.5408
6.7193
6.8803
7.0288
7.1677
7.4234
7.6566
7.8727
8.0751
8.2661
8.4474
8.6199
.027 37
.029 47
.035 24
.039 93
.044 16
.048 14
.051 95
.055 65
.062 83
.069 81
.076.69
.083 50
.090 27
.097 03
.103 77
2803.1
2806.3
2880.1
3008.8
3126.3
3239.3
3350.8
3462.1
3686.3
3914.5
4148.2
4387.6
4633.1
4884.6
5141.7
5404.0
2801.4
2886.2
2960.7
3092.5
3213.6
3330.3
3445.3
3674.4
3905.9
4141.5
4382.3
4628.7
4880.6
5138.1
5400.5
2784.3
2884.2
3043.0
3177.2
3301.8
3422.2
3540.6
3658.4
3894.2
4132.7
4375.3
4622.7
4875.4
5133.3
5396.0
.099 63
.103 77
.111 44
.125 47
.138 57
.151 20
.175 68
.199 60
.2232
.2467
.2700
.2933
.3166
.3398
.3631
2804.2
6.1869
.057 07
2600.1
2650.3
2712.0
2817.8
2913.3
3005.0
3095.3
3276.0
3459.9
3648.3
3842.2
4041.6
4246.8
4457.5
4673.1
2603.7
2803.4
6.1253
2855.8
2993.5
3115.3
3230.9
3344.0
3456.5
3682.3
3911.7
4145.9
4385.9
4631.6
4883.3
5140.5
5402.8
6.2872
6.5390
6.7428
6.9212
7.0834
7.2338
7.5085
7.7511
7.9862
8.1999
8.4009
8.5912
8.7720
8.9442
.058 72
.068 42
.076 78
.084 53
.091 96
.099 18
.113 24
.126 99
.140 56
.154.02
.167 43
.180 80
.194 15
.207.49
2623.7
2738.0
2835.3
2926.4
3015.3
3103.0
3282.1
3464.3
3651.8
3845.0
4044.1
4249.2
4459.8
4675.5
2829.2
2977.5
3104.0
3222.3
3337.2
3450.9
3678.4
3908.8
4143.7
4384.1
4630.1
4881.9
5139.3
5401.7
6.1749
6.4461
6.6579
6.8405
7.0052
7.1572
7.4339
7.6837
7.9134
8.1276
8.3288
8.5192
8.7000
8.8723
6.0198
6.1401
6.2828
6.5131
6.7047
6.8746
7.0301
7.3110
7.5631
7.7942
8.0091
8.2108
8.4015
8.5825
8.7549
.039 44
.041 41
.045 32
.051 94
.057 81
.063 30
.068 57
.078 69
.088 49
.098 11
.107 62
.117 07
.126 48
.135 87
.145 26
5.8133
5.9305
6.2283
6.4478
6.6327
6.7975
6.9486
7.0894
7.3476
7.5822
7.7991
8.0020
8.1933
8.3747
8.5473
.023 52
.024 26
.029 95
.034 32
.038 17
.041 75
.045 16
.048 45
.054 81
.060 97
.067 02
.073 01
.078 96
.084 89
.090 80
2793.3
2863.2
2943.1
3080.6
3204.7
3323.3
3439.6
3670.5
3903.0
4139.3
4380.6
4627.2
4879.3
5136.9
5399.4
2772.1
2838.4
3016.0
3158.1
3287.1
3410.3
3530.9
3650.3
3888.3
4128.2
4371.8
4619.8
4872.8
5130.9
5393.7
2799.5
2835.8
2902.5
3023.5
3137.0
3247.6
3467.6
3690.1
3917.4
4150.3
4389.4
4634.6
4885.9
5142.9
5405.1
6.3409
6.4147
6.5453
6.7664
6.9563
7.1271
7.4317
7.7024
7.9487
8.1765
8.3895
8.5901
8.7800
8.9607
9.1329
2600.3
2628.3
2679.6
2772.6
2859.8
2945.2
3116.2
3290.9
3470.9
3657.0
3849.3
4048.0
4252.7
4463.3
4679.0
2797.1
2846.7
2911.0
3029.2
3141.2
3250.9
3469.8
3691.7
3918.5
4151.2
4390.1
4635.2
4886.4
5143.4
5405.6
2598.4
2636.6
2686.0
2776.9
2863.0
2947.7
3117.9
3292.1
3471.8
3657.6
3849.9
4048.5
4253.2
4463.7
4679.5
2597.1
2631.3
2698.0
2808.7
2906.6
2999.7
3091.0
3273.0
3457.6
3646.6
3840.7
4040.4
4245.6
4456.3
4672.0
2794.3
2838.3
2924.5
3068.4
3195.7
3316.2
3433.8
3665.5
3900.1
4137.1
4378.8
4625.7
4878.0
5135.7
5398.2
5.9734
6.0544
6.2084
6.4493
6.6459
6.8186
6.9759
7.2589
7.5122
7.7440
7.9593
8.1612
8.3520
8.5331
8.7055
2758.0
2785.0
2987.3
3138.3
3272.0
3398.3
3521.0
3642.0
3882.4
4123.8
4368.3
4616.9
4870.3
5128.5
5391.5
5.7432
5.7906
6.1301
6.3634
6.5551
6.7240
6.8778
7.0206
7.2812
7.5173
7.7351
7.9384
8.1300
8.3115
8.4842
Symbols Used in Steam Tables: Ppressure, kPa (abs); Tthermodynamic temperature, C; vspecific volume, m3/kg; uspecific internal energy, kJ/kg; hspecific enthalpy, kJ/kg
sspecific entropy, kJ/(kgK) Adapted from Joseph H. Keenan, Frederick G. Keyes, Philip G. Hill, and Joan G. Moore, Steam Tables, (New York: John Wiley & sons, Inc., 1969).
24-37
.020 48
.023 27
.025 80
.029 93
.033 50
.036 77
.039 87
.042 85
.045 74
.048 57
.054 09
.059 50
.064 85
.070 16
.075 44
.080 72
2557.8
2646.6
2724.4
2848.4
2955.2
3055.2
3152.2
3248.1
3343.6
3439.3
3632.5
3829.2
4030.3
4236.3
4447.2
4662.7
Sat.
350
400
450
500
550
600
650
700
800
900
1000
1100
1200
1300
.010 337
.011 470
.015 649
.018 445
.020 80
.022 93
.024 91
.026 80
.028 61
.032 10
.035 46
.038 75
.042 00
.045 23
.048 45
2455.5
2520.4
2740.7
2879.5
2996.6
3104.7
3208.6
3310.3
3410.9
3610.9
3811.9
4015.4
4222.6
4433.8
4649.1
375
400
425
450
500
550
600
650
700
800
900
1000
1100
1200
1300
.001 973 1
.006 004
.007 881
.009 162
.011 123
.012 724
.014 137
.015 433
.016 646
.018 912
.021 045
.023 10
.025 12
.027 11
.029 10
1798.1
2430.1
2609.2
2720.7
2884.3
3017.5
3137.9
3251.6
3361.3
3574.3
3783.0
3990.9
4200.4
4412.0
4626.9
375
400
425
450
500
550
600
650
700
800
900
1000
1100
1200
1300
.001 640 7
.001 907 7
.002 532
.003 693
.005 622
.006 984
.008 094
.009 063
.009 941
.011 523
.012 962
.014 324
.015 642
.016 940
.018 229
1677.1
1854.6
2096.9
2365.1
2678.4
2869.7
3022.6
3158.0
3283.6
3517.8
3739.4
3954.6
4167.4
4380.1
4594.3
2742.1
2856.0
2956.6
3117.8
3256.6
3386.1
3511.0
3633.7
3755.3
3876.5
4119.3
4364.8
4614.0
4867.7
5126.2
5389.2
.018 026
.019 861
.022 42
.026 41
.029 75
.032 79
.035 64
.038 37
.041 01
.043 58
.048 59
.053 49
.058 32
.063 12
.067 89
.072 65
5.3098
5.4421
5.8811
6.1404
6.3443
6.5199
6.6776
6.8224
6.9572
7.2040
7.4279
7.6348
7.8283
8.0108
8.1840
.007 920
2390.2
.012 447
.015 174
.017 358
.019 288
.021 06
.022 74
.024 34
.027 38
.030 31
.033 16
.035 97
.038 76
.041 54
2685.0
2844.2
2970.3
3083.9
3191.5
3296.0
3398.7
3601.8
3804.7
4009.3
4216.9
4428.3
4643.5
4.0320
5.1418
5.4723
5.6744
5.9592
6.1765
6.3602
6.5229
6.6707
6.9345
7.1680
7.3802
7.5765
7.7605
7.9342
.001 789
.002 790
.005 303
.006 735
.008 678
.010 168
.011 446
.012 596
.013 661
.015 623
.017 448
.019 196
.020 903
.022 589
.024 266
1737.8
2067.4
2455.1
2619.3
2820.7
2970.3
3100.5
3221.0
3335.8
3555.5
3768.5
3978.8
4189.2
4401.3
4616.0
3.8290
4.1135
4.5029
4.9459
5.4700
5.7785
6.0114
6.2054
6.3750
6.6662
6.9150
7.1356
7.3364
7.5224
7.6969
.001 559 4
.001 730 9
.002 007
.002 486
.003 892
.005 118
.006 112
.006 966
.007 727
.009 076
.010 283
.011 411
.012 496
.013 561
.014 616
1638.6
1788.1
1959.7
2159.6
2525.5
2763.6
2942.0
3093.5
3230.5
3479.8
3710.3
3930.5
4145.7
4359.1
4572.8
.013 495
2505.1
2673.8
5.4624
5.9443
6.2120
6.4190
6.5966
6.7561
6.9029
7.0398
7.1687
7.4077
7.6272
7.8315
8.0237
8.2055
8.3783
.016 126
.020 00
.022 99
.025 60
.028 01
.030 29
.032 48
.034 60
.038 69
.042 67
.046 58
.050 45
.054 30
.058 13
2624.2
2789.3
2912.5
3021.7
3125.0
3225.4
3324.4
3422.9
3620.0
3819.1
4021.6
4228.2
4439.3
4654.8
5711.8
3039.3
3199.8
3341.8
3475.2
3604.0
3730.4
3855.3
4103.6
4352.5
4603.8
4858.8
5118.0
5381.4
6.0417
6.2719
6.4618
6.6290
6.7810
6.9218
7.0536
7.2965
7.5182
7.7237
7.9165
8.0987
8.2717
2528.8
5.1419
.005 834
2293.0
2409.7
4.9269
2902.9
3109.7
3274.1
3421.4
3560.1
3693.9
3824.6
4081.1
4335.1
4589.5
4846.4
5106.6
5370.5
5.7213
6.0184
6.2383
6.4230
6.5866
6.7357
6.8736
7.1244
7.3507
7.5589
7.7531
7.9360
8.1093
.009 942
.012 695
.014 768
.016 555
.018 178
.019 693
.021 13
.023 85
.026 45
.028 97
.031 45
.033 91
.036 36
2619.3
2806.2
2942.9
3062.4
3174.0
3281.4
3386.4
3592.7
3797.5
4003.1
4211.3
4422.8
4638.0
2818.1
3060.1
3238.2
3393.5
3537.6
3675.3
3809.0
4069.7
4326.4
4582.5
4840.2
5101.0
5365.1
5.5540
5.9017
6.1401
6.3348
6.5048
6.6582
6.7993
7.0544
7.2830
7.4925
7.6874
7.8707
8.0442
3.9305
4.4728
5.1504
5.4424
5.7905
6.0342
6.2331
6.4058
6.5605
6.8332
7.0718
7.2867
7.4845
7.6692
7.8432
.001 700 3
.002 100
.003 428
.004 961
.006 927
.008 345
.009 527
.010 575
.011 533
.013 278
.014 883
.016 410
.017 895
.019 360
.020 815
1702.9
1914.1
2253.4
2498.7
2751.9
2921.0
3062.0
3189.8
3309.8
3536.7
3754.0
3966.7
4178.3
4390.7
4605.1
3.7639
4.0031
4.2734
4.5884
5.1726
5.5485
5.8178
6.0342
6.2189
6.5290
6.7882
7.0146
7.2184
7.4058
7.5808
.001 502 8
.001 633 5
.001 816 5
.002 085
.002 956
.003 956
.004 834
.005 595
.006 272
.007 459
.008 508
.009 480
.010 409
.011 317
.012 215
1609.4
1745.4
1892.7
2053.9
2390.6
2658.8
2861.1
3028.8
3177.2
3441.5
3681.0
3906.4
4124.1
4338.2
4551.4
P = 30 000 kPa
P = 40 000 kPa
1742.8
1930.9
2198.1
2512.8
2903.3
3149.1
3346.4
3520.6
3681.2
3978.7
4257.9
4527.6
4793.1
5057.7
5323.5
2724.7
5756.8
2923.4
3096.5
3240.9
3373.7
3500.9
3625.3
3748.2
3870.5
4114.8
4361.2
4611.0
4865.1
5123.8
5387.0
P = 25 000 kPa
1848.0
2580.2
2806.3
2949.7
3162.4
3335.6
3491.4
3637.4
3777.5
4047.1
4309.1
4568.5
4828.2
5089.9
5354.4
2544.4
2610.4
2699.2
2832.4
2943.4
3045.8
3144.6
3241.7
3338.2
3434.7
3628.9
3826.3
4027.8
4234.0
4444.9
4460.5
1791.5
2151.1
2614.2
2821.4
3081.1
3275.4
3443.9
3598.9
3745.6
4024.2
4291.9
4554.7
4816.3
5079.0
5344.0
P = 35 000 kPa
P = 50 000 kPa
1716.6
1874.6
2060.0
2284.0
2720.1
3019.5
3247.6
3441.8
3616.8
3933.6
4224.4
4501.1
4770.5
5037.2
5303.6
1762.4
1987.6
2373.4
2672.4
2994.4
3213.0
3395.5
3559.9
3713.5
4001.5
4274.9
4541.1
4804.6
5068.3
5333.6
3.8722
4.2126
4.7747
5.1962
5.6282
5.9026
6.1179
6.3010
6.4631
6.7450
6.9886
7.2064
7.4057
7.5910
7.7653
P = 60 000kPa
1699.5
1843.4
2001.7
2179.0
2567.9
2896.2
3151.2
3364.5
3553.5
3889.1
4191.5
4475.2
4748.6
5017.2
5284.3
3.7141
3.9318
4.1626
4.4121
4.9321
5.3441
5.6452
5.8829
6.0824
6.4109
6.6805
6.9127
7.1195
7.3083
7.4837
Symbols Used in Steam Tables: Ppressure, kPa (abs); Tthermodynamic temperature, C; vspecific volume, m3/kg; uspecific internal energy, kJ/kg; hspecific enthalpy, kJ/kg
sspecific entropy, kJ/(kgK) Adapted from Joseph H. Keenan, Frederick G. Keyes, Philip G. Hill, and Joan G. Moore, Steam Tables, (New York: John Wiley & sons, Inc., 1969).
24-38