CHM2045 EXAM 3 (Gower, Mitchell, Korolev) FORM CODE A Fall 2013

Instructions: On your scantron sheet enter and bubble in your name, UF ID number, and Form Code.
Check your bubbling carefully bubbling errors will not be negotiated and will be penalized.
Potentially useful info: SC: r = a/2; BCC: r= a 3/4; FCC: r = a2/4

1. When the following reaction proceeds, what will be true? 2A(g) + 3B(g) 4C(g)
(1) The temperature will increase at constant P and V.
(2) The volume will increase at constant T and P. (3) The pressure will increase at constant T and V.
(4) The density will increase at constant T and P. (5) The moles will increase at constant T and V.

2. If a 1.0 L flask containing 0.400 atm of gas A is connected to a 3.0 L flask containing 0.400 atm of gas B,
what will be the total pressure of the gases if the valve between the flasks is opened so that the gases can
mix ? (assume no reaction between the gases takes place)
(1) 0.100 atm (2) 0.267 atm (3) 0.400 atm (4) 0.300 atm (5) 0.333 atm
3. When an evacuated 50.0 mL glass bulb is filled with a noble gas at 22C and 747 torr, the bulb gains
0.0409 g in mass. Which of the following is the noble gas? (1) Xe (2) Kr (3) Ar (4) Ne (5) He

4. If 5.0 mL of liquid chloroform (CHCl
3
, density = 1.48 g/mL ; molar mass = 119.4 g/mol) were placed in a
closed 5.0 L flask at 20C, what percentage (by mass) of the chloroform would remain as liquid in the flask
after equilibrium is established between liquid and vapor chloroform ? (the vapor pressure of chloroform at
20C is 0.208 atm) (1) 70% (2) 30% (3) 60% (4) 40% (5) none of the liquid would remain

5. A rigid vessel at constant temperature initially contains 0.500 atm of nitrogen gas and 0.500 atm of
hydrogen gas. If these gases react to form ammonia, and the reaction is assumed to go to completion, what
is the closest value to the final (total) pressure in the vessel after the reaction has gone to completion?
(1) 0.167 atm (2) 0.66 atm (3) 1.00 atm (4) 1.50 atm (5) 2.00 atm

6. A cylinder with a frictionless movable piston contains an ideal gas at 400K. After the temperature of the
cylinder is increased to 800K at constant barometric pressure, which of the following will not be true ?
(1) the volume of the gas in the cylinder at 800K will be twice the volume of the gas in the cylinder at 400K
(2) the average kinetic energy of the gas in the cylinder at 800K will be greater than it was at 400K
(3) the frequency and force of the gas particle collisions in the cylinder at 800K will be greater than at 400K
(4) the root-mean-square velocity (u
rms
) of the gas in the cylinder at 800K will be greater than at 400K
(5) the pressure of the gas inside the cylinder at 800K will be twice the pressure of the gas at 400K

7. A certain gaseous oxide of sulfur has an effusion rate that is 0.707 times the effusion rate of oxygen gas.
What is the most likely molecular formula of this oxide?
(1) SO (2) SO
2
(3) SO
3
(4) SO
4
(5) S
2
O

8. When considering the Ideal Gas equation of state, the molecules in the gas are assumed to have no
interaction with each other at all. In real gases, however, attractive intermolecular forces exist between the
molecules. The effect of these attractiveintermolecular in a real gas (which we compensate for) is to:
(1) Decrease the size of the molecules in the gas.
(2) Decrease the pressure in the gas relative to that of an Ideal Gas
(3) Increase the volume of the gas relative to that of an Ideal Gas.
(4) Sometimes increase and sometimes decrease the pressure of the gas relative to an Ideal Gas.
(5) Decrease the Temperature of the gas relative to that of an Ideal Gas.

9. A gas mixture consists of equal masses of methane (molecular weight 16.0) and argon (atomic
weight 40.0). If the partial pressure of argon is 200 mm Hg, what is the pressure of methane, in mmHg?
(1) 80.0 mm Hg (2) 200 mm Hg (3) 256 mm Hg (4) 500 mm Hg (5) 556 mm Hg

10. Which of the following substances exhibits hydrogen-bonding intermolecular forces in its liquid state?
(1) CH
3
NH
2
(2) CH
3
OCH
3
(3) CH
3
F (4) H
2
S (5) (CH
3
)
3
N
11. Which member in each pair has the highest vapor pressure at a given temperature?
A: C
2
H
6
or C
4
H
10
B: CH
3
CH
2
OH or CH
3
CH
2
F C: NH
3
or PH
3

(1) C
2
H
6
, CH
3
CH
2
OH, NH
3
(2) C
2
H
6
, CH
3
CH
2
F, PH
3
(3) C
4
H
10
, CH
3
CH
2
F, PH
3
(4) C
2
H
6
, CH
3
CH
2
F, NH
3
(5) C
4
H
10
, CH
3
CH
2
OH, NH
3

12. Select the pair of substances in which the one with the lowest normal boiling point is listed first.
(1) C
7
H
16
, C
5
H
12
(2) Xe, Kr (3) H
2
O, H
2
S (4) CH
3
CH
2
OH, CH
3
-O-CH
3
(5) CF
4,
CCl
4


13. Sweating is the bodys natural process of cooling your body. By how many degrees will your body cool
(assume 100kg person and that a body is mostly water) if you evaporate away 10g of water? Possibly useful
information: Cp(liquid) = 4.18 J/gC Cp(gas) = 2.00 J/gC Hvap = 40.7 kJ/mol Hfus = 6.03kJ/mol
(1) 0.054 C (2) 0.97 C (3) 0.11C (4) 0.0080 C (5) 0.017 C
14. Consider a liquid with a vapor pressure of 200. torr at 20.0
o
C and a vapor pressure of 400. torr at
50.0 C. What is the closest value to the normal boiling point of this liquid?
(1) 18.2
o
C (2) 22.0
o
C (3) 83.8
o
C (4) 295.
o
C (5) 357.
o
C

Consider the phase diagram to the right for problems 16 -17
15. On the given phase diagram, what phase(s) are present at
equilibrium at point E?
(1) vapor (2) liquid (3) solid
(4) liquid and vapor (5) solid and liquid

16. Select the correct statement for the given phase diagram:
(1) The solid has a lower density than the liquid.
(2) The triple point is higher than the normal melting point.
(3) As one follows the line from C to D the substance changes from a solid to a liquid.
(4) As one follows the line from C to D the substance changes from a liquid to a gas.
(5) The temperature corresponding to Point E is the normal boiling point.

17. Which of the following properties of water is not related to hydrogen-bonding intermolecular forces in
water ? (1) relatively high surface tension (2) relatively low vapor pressure (3) relatively high H
vap

(4) relatively high molecular polarity (5) solid water is less dense than liquid water

18. Nickel crystallizes in a face-centered cubic structure with an edge length a = 352 pm. Based on this
information, calculate the appoximate density of nickel.
(1) 7.75 g/cm
3
(2) 8.94 g/cm
3
(3) 8.03 g/cm
3
(4) 9.84 g/cm
3
(5) 10.6 g/cm
3


19. What is the molality of a 3.00 M NaCl (58.44 g/mol) solution with a density of 1.10 g/mL ?
(1) 3.24 m (2) 2.88 m (3) 2.14 m (4) 3.14 m (5) 3.88 m
20. For which of the following is the H
solution
predicted to be the most endothermic?
(1) Dissolving NaCl in HCl (2) Dissolving CH
3
OH in H
2
O (3) Dissolving NaCl in C
6
H
14

(4) Dissolving CH
3
CH
2
OH in C
6
H
14
(5) Dissolving CH
3
CH
2
OH in CH
3
OH

21. If air (N
2
and O
2
only) contains 22% oxygen by volume, what is the solubility of nitrogen in water at
25.0 C and 1 atmosphere (k
H
for N
2
in water at 25.0 C = 7 x 10
- 4
mol/L atm)?
(1) 5.5 x 10
- 4
mol/L (2) 1.5 x 10
- 4
mol/L (3) 7.0 x 10
- 4
mol/L (4) 3.2 x 10
- 2
mol/L (5) 9.0 x 10
- 4
mol/L

22. Calculate the vapor pressure lowering of the solution of 2.00 grams of aspirin, (180.15 g/mol) in 50.0 g
of methanol (CH
3
OH) at 21.2C. Pure methanol has a vapor pressure of 101 torr at this temperature.
(1) 0.713 torr (2) 2.88 torr (3) 0.993 torr (4) 7.18 torr (5) 3.27 torr

23. Which pair of aqueous solutions is given in order of increasing freezing point?
(1) 0.010M Na
3
PO
4
< 0.030M NaCl (2) 0.010M CaCl
2
< 0.020M KCl
(3) 0.010M Na
3
PO
4
< 0.020M Na
3
PO
4
(4) 0.020M glucose < 0.010M CaCl
2

(5) 0.020M NaCl < 0.030M glucose

24. Which of the following aqueous solutions has the highest normal boiling point? Assume ideal solutions
where ionic compounds dissociate completely into ions in water.
(1) 0.20 mglucose (2) 0.12 mNa
2
SO
4
(3) 0.10 mCaCl
2
(4) 0.12 mKF (5) 0.10 mNaCl
25. The osmotic pressure at 25C is 1.79 atm for a solution prepared by dissolving 2.50 g of sucrose (table
sugar) in enough water to give a solution volume of 100. mL. Which of the following is the molar mass of
sucrose ? (1) 34.2 g/mol (2) 68.3 g/mol (3) 342 g/mol (4) 683 g/mol (5) 171 g/mol