MSDS

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Material Safety Data Sheet
Ammonium sulfate MSDS
Section 1: Chemical Product and Company Identification
Product Name: Ammonium sulfate
Catalog Codes: SLA2851, SLA2011, SLA1168, SLA2674
CAS#: 7783-20-2
RTECS: BS4500000
TSCA: TSCA 8(b) inventory: Ammonium sulfate
CI#: Not available.
Synonym: Sulfluric Acid, Diammonium Salt
Chemical Name: Ammonium Sulfate
Chemical Formula: (NH4)2SO4
Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Ammonium sulfate 7783-20-2 100
Toxicological Data on Ingredients: Ammonium sulfate: ORAL (LD50): Acute: 2840 mg/kg [Rat]. 640 mg/kg [Mouse].
Section 3: Hazards Identification
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
p. 2
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: CLOSED CUP: Higher than 93.3C (200F).
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances:
Flammable in presence of oxidizing materials. Slightly flammable to flammable in presence of heat.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:
A mixture of ammonium sulfate and potassium chlorate decomposes with incandescence when heated. When a little
ammonium sulfate is added to fused potassium nitrite, a vigorous reaction occurs attended by flame. Non combustible. This
substance itself does not burn, but may decompose upon heating to produce corrosive and/or toxic fumes.
Special Remarks on Explosion Hazards:
If accidently mixed with oxidizers like potassium chlorate, potassium nitrate or potassium nitrite, there is an explosion hazard
during fire. A mixture of ammonium sulfate and ammonium nitrate can easily be exploded by potassium or sodium-potassium
alloy.
Section 6: Accidental Release Measures
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Section 7: Handling and Storage
Precautions:
p. 3
Keep away from heat. Keep away from sources of ignition. Do not ingest. Do not breathe dust. Wear suitable protective
clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately
and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing
agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid. (Crystals solid.)
Odor: Odorless.
Taste: Not available.
Molecular Weight: 132.14 g/mole
Color: brownish gray to white
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: 280C (536F)
Critical Temperature: Not available.
Specific Gravity: 1.77 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in cold water. Insoluble in acetone.
Section 10: Stability and Reactivity Data
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Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials.
Incompatibility with various substances:
Highly reactive with oxidizing agents. Reactive with alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with the following: Potassium + ammonium nitrate, potassium chlorate, potassium nitrate, potassium nitrite,
sodium hypochlorite, sodium/potassium alloy + ammonium nitrate. Substance should not contact either zinc or copper bearing
materials. Reacts with alkali to release ammonia.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 640 mg/kg [Mouse].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose/Conc: LDL [Domestic animal - Goat, Sheep) - Route: Oral; Dose: 3500 mg/kg
Special Remarks on Chronic Effects on Humans:
It may be a possible mutagen. It has been tested for mutagenicity, but so far tests have been inconclusive or test information
has not been made available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tract
irritation. Ingestion: When ingested, its osmolarity can draw water from the body into the bowel, acting as a laxative. However,
if enough is absorbed systemically it may produce Ammonia poisoning. Symptoms may include gastrointestinal (digestive)
tract irritation with nausea, vomiting, hypermotility, diarrhea. May also affect eyes (Mydriasis), behavior/central nervous system
(somnolence, tremor, convulsions, muscle contraction or spasticity), and respiratory system (respiratory stimulation, dyspnea).
Also, with ingestion of large doses of Ammonium Sulfate arises the possibility of sufficient absorption to produce diuresis, an
excessive discharge of urine, and kidney damage (renal tubular disorder, abnormal renal function). Chronic Potential Health
Effects: One Russian occupational standard study discussed chronic exposure effects which may include cardiac contraction,
neurotoxicity, and hypertension. This has not been confirmed in other ammonium sulfate exposed workers.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
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Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Section 15: Other Regulatory Information
Federal and State Regulations:
Rhode Island RTK hazardous substances: Ammonium sulfate Pennsylvania RTK: Ammonium sulfate Florida: Ammonium
sulfate Massachusetts RTK: Ammonium sulfate New Jersey: Ammonium sulfate TSCA 8(b) inventory: Ammonium sulfate
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R16- Explosive when mixed with oxidizing substances. R36/38- Irritating to eyes and skin. S24/25- Avoid contact with skin and
eyes.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/10/2005 08:14 PM
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
p. 6
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
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Barium Chloride TS MSDS
Product Name: Barium Chloride TS
Catalog Codes: SLB2362
CAS#: Mixture.
RTECS: Not applicable.
TSCA: TSCA 8(b) inventory: Barium chloride dihydrate;
Water
CI#: Not available.
Synonym: Barium Chloride Test Solution
Chemical Name: Not applicable.
Chemical Formula: Not applicable.
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Barium chloride dihydrate 10326-27-9 12
Water 7732-18-5 88
Toxicological Data on Ingredients: Barium chloride dihydrate: ORAL (LD50): Acute: 76 mg/kg [Guinea pig]. 118 mg/kg [Rat].
300 mg/kg [Rat].
Potential Acute Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Slightly hazardous in case of skin contact
(permeator).
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, the nervous system, peripheral nervous
system, cardiovascular system, upper respiratory tract, central nervous system (CNS). The substance may be toxic to liver.
Repeated or prolonged exposure to the substance can produce target organs damage.
p. 2
Eye Contact:
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
attention.
Ingestion:
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Fire Hazards in Presence of Various Substances: Not applicable.
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Be careful that the product is not
present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
p. 3
Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation,
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes.
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value.
Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or
equivalent.
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
product.
Exposure Limits:
Barium chloride dihydrate TWA: 0.5 (mg(Ba)/m) from ACGIH (TLV) [United States] Consult local authorities for acceptable
exposure limits.
Physical state and appearance: Liquid.
Odor: Odorless.
Molecular Weight: Not applicable.
Color: Clear Colorless.
pH (1% soln/water): Not available
Boiling Point: The lowest known value is 100C (212F) (Water).
Melting Point: Not available.
Vapor Pressure: The highest known value is 2.3 kPa (@ 20C) (Water).
Vapor Density: The highest known value is 0.62 (Air = 1) (Water).
Dispersion Properties: See solubility in water, methanol.
Solubility:
Easily soluble in cold water, hot water. Soluble in methanol. Insoluble in acetone.
p. 4
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Special Remarks on Reactivity: Not available.
Routes of Entry: Absorbed through skin. Eye contact. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects. May affect genetic material
(mutagenic) (Barium chloride dihydrate)
Special Remarks on other Toxic Effects on Humans: Not available.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Waste Disposal:
Special Provisions for Transport: Marine Pollutant
p. 5
Federal and State Regulations: TSCA 8(b) inventory: Water
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
DSCL (EEC):
R22- Harmful if swallowed. S2- Keep out of the reach of children. S46- If swallowed, seek medical advice immediately and
show this container or label.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: g
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Not applicable. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate
respirator when ventilation is inadequate. Safety glasses.
Created: 10/10/2005 12:51 AM
Last Updated: 11/01/2010 12:00 PM
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Borax Solution 1% (w/v) MSDS
Product Name: Borax Solution 1% (w/v)
Catalog Codes: SLB3373
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Sodium borate; Water
CI#: Not available.
Synonym:
Chemical Name: Borax Solution 1% (w/v)
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Sodium borate 1303-96-4 1
Water 7732-18-5 99
Toxicological Data on Ingredients: Sodium borate: ORAL (LD50): Acute: 2660 mg/kg [Rat.].
Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Non-
corrosive for skin.
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available.
p. 2
Eye Contact:
Skin Contact:
may be used.
Inhalation:
attention.
Ingestion:
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated
surface and dispose of according to local and regional authority requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue with a dilute
solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the
sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and
with local authorities.
p. 3
Precautions:
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label.
Personal Protection: Safety glasses. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or
equivalent.
product.
Exposure Limits:
Sodium borate TWA: 0.31 TWA: 5 from ACGIH (TLV) [United States] [1995] Consult local authorities for acceptable exposure
limits.
Odor: Not available.
Color: Not available.
pH (1% soln/water): Basic.
Specific Gravity: Weighted average: 1 (Water = 1)
Solubility:
Easily soluble in cold water, hot water. Insoluble in methanol.
p. 4
Incompatibility with various substances: Non-reactive with oxidizing agents.
Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 266000 mg/kg (Rat.) (Calculated value for the mixture).
Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Ingestion of 5-10 grams has produced severe vomiting, diarrhea,
shock and death. (Sodium borate)
Waste Disposal:
p. 5
Pennsylvania RTK: Sodium borate Massachusetts RTK: Sodium borate TSCA 8(b) inventory: Sodium borate; Water
Other Regulations: Not available. or of its ingredients
DSCL (EEC):
This product is not classified according to the EU regulations.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: g
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Not applicable. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.
Created: 10/10/2005 12:52 AM
Last Updated: 11/01/2010 12:00 PM
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Copper Sulfate solution MSDS
Product Name: Copper Sulfate solution
Catalog Codes: SLC1300
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: No products were found.
CI#: Not applicable.
Synonym: Copper Sulfate Solution
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Water 7732-18-5 91.8
Copper sulfate pentahydrate 7758-99-8 8.23
Toxicological Data on Ingredients: Copper sulfate pentahydrate: ORAL (LD50): Acute: 300 mg/kg [Rat.]. DERMAL (LD50):
Acute: >2000 mg/kg [Rat].
Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of ingestion, . Non-corrosive for
skin.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfate
pentahydrate]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may
be toxic to kidneys, liver. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated
exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.
p. 2
Eye Contact:
Skin Contact:
attention.
Inhalation:
attention.
Ingestion:
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks,
of heat.
Special Remarks on Explosion Hazards: Nitromethanes and copper salts spontaneously form explosive materials (Copper
sulfate pentahydrate)
Small Spill:
requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
p. 3
Precautions:
contact with skin and eyes.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
product.
Exposure Limits:
Copper sulfate pentahydrate TWA: 1 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 0.1 (mg/m3) from OSHA
(PEL) [United States] Inhalation TWA: 1 (mg/m3) from NIOSH InhalationConsult local authorities for acceptable exposure
limits.
Color: Blue.
pH (1% soln/water): Not available
Solubility:
Easily soluble in cold water, hot water. Partially soluble in methanol.
p. 4
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Slightly reactive to reactive with metals, alkalis.
Corrosivity: Corrosive in presence of steel.
Air Sensitive. Solutions of hyprobromite are decomposed by powerful catalytic action of cupric ions, even as impurities.
Incompatible with finely powdered metals. (Copper sulfate pentahydrate)
Routes of Entry: Absorbed through skin. Eye contact.
Acute oral toxicity (LD50): 3641 mg/kg (Rat.) (Calculated value for the mixture). Acute dermal toxicity (LD50): 25485 mg/kg
(Rat) (Calculated value for the mixture).
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Copper sulfate pentahydrate]. Contains material which may
cause damage to the following organs: kidneys, liver.
Hazardous in case of skin contact (irritant). Slightly hazardous in case of ingestion, of inhalation.
Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 1088 mg/kg (Copper sulfate pentahydrate)
Special Remarks on Chronic Effects on Humans: May affect genetic material based on animal data (Copper sulfate
pentahydrate)
Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tract
irritation. Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea.
May affect metabolism, liver (jaundice), blood (Methemoglobin, hemalytic anemia), urinary system (kidneys), behavior/nervous
systems (somnolence, coma), cardiovascular system (lowering of blood pressure)
Special Remarks on the Products of Biodegradation:
If released to soil, copper sulfate may leach to groundwater, be partly oxidized, or bind to humic materials, clay, or hydrous
of iron and manganese. In water, it will bind to carbonates as well as humic materials, clay and hydrous oxides of iron and
manganese. Copper is accumulated by plants and animals, but it does not appear to biomagnify from plants to animals. This
p. 5
lack of biomagnification appears common with heavy metals. In air, copper aerosols (in general) have a residence time of 2 to
10 days in an unpolluted atmosphere and 0.1 to >4 in a polluted, urban areas. (Copper sulfate pentahydrate)
Waste Disposal:
TSCA 8(b) inventory: Water SARA 313 toxic chemical notification and release reporting: Copper compounds CERCLA:
Hazardous substances.: Copper sulfate pentahydrate: 10 lbs. (4.536 kg);
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: h
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
Created: 10/10/2005 01:00 AM
p. 6
Last Updated: 11/01/2010 12:00 PM
Material Safety Data Sheet Page 1 of 2
2008, Scholar Chemistry. All Rights Reserved. 9/19/2009
Glucose Monohydrate
MSDS # 308.10

Section 1: Product and Company Identification
Glucose Monohydrate
Synonyms/General Names: D-Glucose Monohydrate; Dextrose Monohydrate
Product Use: For educational use only
Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925.
24 Hour Emergency Information Telephone Numbers
CHEMTREC (USA): 800-424-9300 CANUTEC (Canada): 613-424-6666
ScholAR Chemistry; 5100 W. Henrietta Rd, Rochester, NY 14586; (866) 260-0501; www.Scholarchemistry.com
White crystalline powder; no odor. HMIS (0 to 4)

This material is not considered hazardous.
Target organs: None known.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Section 3: Composition / Information on Ingredients
Dextrose, monohydrate (5996-10-1), 100%

Always seek professional medical attention after first aid measures are provided.
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Poison Control immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink.
Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
Nonflammable solid. When heated to decomposition, emits acrid fumes. 0
Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire. 0 0
Firefighters should wear full fire fighting turn-out gear and respiratory protection (SCBA). Cool
container with water spray. Material is not sensitive to mechanical impact or static discharge.
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected
personnel. Sweep up spill and place in sealed bag or container for disposal. Wash spill area after pickup is complete. See Section
13 for disposal information.
Section 7: Handling and Storage Green
Handling: Use with adequate ventilation and do not breathe dust or vapor. Avoid contact with skin, eyes, or clothing. Wash
hands thoroughly after handling.
Storage: Store in General Storage Area [Green Storage] with other items with no specific storage hazards. Store in a cool, dry,
well-ventilated, locked store room away from incompatible materials.
Section 8: Exposure Controls / Personal Protection
Use ventilation to keep airborne concentrations below exposure limits. Have approved eyewash facility, safety shower, and fire
extinguishers readily available. Wear chemical splash goggles and chemical resistant clothing such as gloves and aprons. Wash
hands thoroughly after handling material and before eating or drinking. Use NIOSH-approved respirator with an dust cartridge.
Exposure guidelines: Dextrose: OSHA PEL: Not Available, ACGIH: TLV: Not Available, STEL: Not Available.
Health 0
Fire Hazard 0
Reactivity 0
Material Safety Data Sheet Page 2 of 2
2008, Scholar Chemistry. All Rights Reserved. 9/19/2009
MSDS # 308.10 Glucose Monohydrate Scholar Chemistry

Molecular formula C
6
H
12
O
6
H
2
O. Appearance White crystalline powder.
Molecular weight 198.17. Odor None.
Specific Gravity 1.5. Odor Threshold N/A.
Vapor Density (air=1) 6.3. Solubility Soluble in water.
Melting Point 146C (295F). Evaporation rate N/A. (Butyl acetate = 1).
Boiling Point/Range Decomposes. Partition Coefficient N/A. (log P
OW
).
Vapor Pressure (20C) Negligible.. pH N/A.
Flash Point: N/A. LEL N/A.
Autoignition Temp.: N/A. UEL N/A.
N/A =Not available or applicable
Section 10: Stability and Reactivity
Avoid heat and moisture.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Strong oxidizers.
Shelf life: Fair shelf life, store in a cool, dry environment.
Section 11: Toxicology Information
Acute Symptoms/Signs of exposure: Eyes: Redness, tearing, itching, burning, conjunctivitis. Skin: Redness, itching.
Ingestion: Irritation and burning sensations of mouth and throat, nausea, vomiting and abdominal pain. Inhalation: Irritation of
mucous membranes, coughing, wheezing, shortness of breath,
Chronic Effects: No information found.
Sensitization: none expected
Dextrose: LD50 [oral, rat]; N/A; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.
Ecotoxicity (aquatic and terrestrial): Not considered an environmental hazard.

Check with all applicable local, regional, and national laws and regulations. Local regulations may be more stringent than
regional or national regulations. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
DOT Shipping Name: Not regulated by DOT. Canada TDG: Not regulated by TDG.
DOT Hazard Class: Hazard Class:
Identification Number: UN Number:
Section 15: Regulatory Information
EINECS: Listed (200-333-3). WHMIS Canada: Not WHMIS Controlled.
TSCA: All components are listed or are exempt. California Proposition 65: Not listed.
The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products Regulations.
Current Issue Date: September 19, 2009
Disclaimer: Scholar Chemistry and Columbus Chemical Industries, Inc., (S&C) believes that the information herein is factual but is not intended to be all
inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any
particular process. Because safety standards and regulations are subject to change and because S&C has no continuing control over the material, those
handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored
or used and that the same is done in accordance with federal, state and local law. S&C makes no warranty, expressed or implied, including (without
limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein or with respect to fitness for any
particular use.
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Hydrochloric Acid, 5% (1+19) MSDS
Product Name: Hydrochloric Acid, 5% (1+19)
Catalog Codes: SLH1339
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Hydrochloric acid; Water
Synonym: Hydrochloric Acid, 5% (1+19) Solution
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Hydrogen chloride 7647-01-0 1.85
Water 7732-18-5 98.2
Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].
Very hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of ingestion. Slightly hazardous in
case of skin contact (corrosive, permeator), of eye contact (corrosive), of inhalation (lung sensitizer). Non-corrosive for lungs.
Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin
contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for
human.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper
respiratory tract, skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage.
p. 2
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Eye Contact:
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Inhalation:
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.
Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts with
hydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warm
hydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid is
used, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid produces
spontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact with
hydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas. (Hydrochloric Acid)
Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:
Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino
p. 3
ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesium
carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithium
disilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,
beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodium
hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon
tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.
Small Spill:
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers,
basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of
sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and
Precautions:
Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. If ingested, seek
medical advice immediately and show the container or the label. Avoid contact with skin and eyes.
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
product.
Exposure Limits:
Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States]
CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3)
from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.
Taste: Acid.
p. 4
pH (1% soln/water): Acidic.
Specific Gravity: Weighted average: 1 (Water = 1)
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether.
Incompatibility with various substances: Slightly reactive to reactive with oxidizing agents, organic materials, metals,
alkalis.
Absorption of gaseous hydrogen chloride on mercuric sulfate becomes violent @ 125 deg. C. Sodium reacts very violently with
gaseous hydrogen chloride. Calcium phosphide and hydrochloric acid undergo very energetic reaction. It reacts with oxidizers
releasing chlorine gas. Incompatible with, alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides,
phosphides, cyanides, carbonates. Reacts with most metals to produce flammable Hydrogen gas. Isolate hydrogen chloride
from heat, direct, alkalies (reacts vigorously), organic materials(reacts vigorously with many organic materials), and oxidizers
(especially nitric acid and chlorates), amines, metals, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials),
lithium silicide (incandescence), sulfuric acid(increase in temperature and pressure) Hydrogen chloride gas is emitted when
this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction.
Hydrogen chloride causes aldehydes and epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contact
with the folloiwng can cause explosion or ignition on contact or other violent/vigorous reaction: Acetic anhydride, Alcohols +
hydrogen cyanide, Aluminum, Aluminum phosphide, Aluminum-titanium alloys (with HCl vapor), 2-Amino ethanol, Ammonium,
Ammonium hydroxide, 1,4-Benzoquinone diimine, Calcium acetylide (incandescence upon warming), Calcium carbide,
Calcium phosphide, Carbon tetrachloride + silver perchlorate (produce trichlormethyl perchlorate), Cesium acetylene carbide,
Cesium carbide, Cesium telluroacylates, Chlorine + dinitroanilines (evolves gas), Chloroacetaldehyde oxime, Chlorosulfonic
acid, Cyanogen chloride (when catalyzed by HCl), 1,1-Difluoroethylene, Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-
formylpropionate oxime (when generated by using HCl as a catalyst), Ethylene imine, Fluorine, HClO4, Hexalithium disilicide,
Hydrogen peroxide, Metal acetylides, carbides, Magnesium boride, Methyl vinyl ether, Mercuric sulfate, Nitric acid + glycerol,
Oleum, Perchloric acid, Potassium, Potassium permanganate, beta-Propiolactone, Propylene oxide, Rubidium acetylide,
Rubidium carbide, Rubidium a c e t y l e n e c a r b i d e , S i l i c o n d i o x i d e , S i l v e r c h l o r i t e , S o d i u m ( w i t h
a q u e o u s H C l ) , S o d i u m 2-allyloxy-6-nitrophenylpyruvate oxime, Sodium hydroxide, Sodium tetraselenium, Sulfonic
acid, Sulfuric acid, Tetraselenium tetranitride, 2,4,6-Tri(2-acetylhydrazino)-1,3,5-trinitrobenzene, Uranium phosphide, Vinyl
acetate. Hydrogen chloride gas can react with formaldehyde to form bis(chloromethyl)ether, a human carcinogen. Most
p. 5
metals, as well as certain coatings, plastics, and rubbers, are attacked by hydrogen chloride. Addition of hydrochloric acid to
the following results in an exothermic reaction: Cesium cyanotridecahydrodecarborate(2-), Potassium ferricyanide, Vinylidene
fluoride. Addition of hydrochloric acid to potassium ferrocyanide or ammonium hexacyanoferrate(II) results in an endothermic
reaction. Hydrochloric acid in the presence of alcohol and glycols results in dehydration reactions. (Hydrochloric Acid)
Special Remarks on Corrosivity:
This compound is highly corrosive when in solution (especially to most metals except: gold, mercury, platinum, silver, and
tantalum). The anhydrous gas is not corrosive . (Hydrogen chloride)
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. Contains material which
may cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth.
Very hazardous in case of skin contact (irritant). Hazardous in case of ingestion, of inhalation (lung corrosive). Slightly
hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive), .
Acute Potential Health Effects: Skin: Mildly Corrosive. Causes skin irritation and possible burns. Eyes: Mildly Corrosive.
Causes eye irritation possible burns. Inhalation: May cause irritation of the nose, throat, bronchi (upper respiratory
tract), coughing, sneezing, hoarseness. May affect the lungs/respiration. May affect the liver. Ingestion: Causes irritation
gastrointestinal tract with nausea, vomitting abdominal cramps, and diarrhea. May affect behavior, the cardiovascular system,
respiration and urinary system (kidneys). Chronic Potential Health Effects: Prolonged or repeated inhalation or ingestion
may affect liver, respiration(changes in pulmonary function, chronic bronchitis), teeth (yellowing of teethand erosion of tooth
enamel), kidneys, and behavior. Prolonged or repeated skin contact may cause dermatitis.
Waste Disposal:
p. 6
DOT Classification: Class 8: Corrosive material
Identification: : Hydrochloric Acid Solution UNNA: 1789 PG: III
Special Provisions for Transport: Not available.
Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric
acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK
hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts
RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:
Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8(b)
inventory: Hydrochloric acid; Water TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremely
hazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid 5%
CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg);
WHMIS (Canada): CLASS E: Corrosive liquid.
DSCL (EEC):
R34- Causes burns. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37/39- Wear
suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.
Created: 10/10/2005 10:32 AM
Last Updated: 11/01/2010 12:00 PM
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Hydrochloric acid, 20%(v/v) MSDS
Product Name: Hydrochloric acid, 20%(v/v)
Catalog Codes: SLH2932
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Hydrochloric acid; Water
Synonym:
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Hydrogen chloride 7647-01-0 4.8-9.12
Water 7732-18-5 90.9-95.2
Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact
(corrosive), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid
or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin
contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for
human.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper
respiratory tract, skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage.
p. 2
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Eye Contact:
Skin Contact:
Inhalation:
Serious Inhalation:
attention.
Ingestion:
Small Spill:
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
p. 3
Large Spill:
sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and
Precautions:
Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as alkalis, moisture. May corrode
metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package.
product.
Exposure Limits:
Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States]
CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3)
from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.
Odor: Disagreeable and choking. (Strong.)
Taste: Acid. (Strong.)
pH (1% soln/water): Acidic.
Specific Gravity: Weighted average: 1.01 (Water = 1)
p. 4
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether.
Reactive with alkalis. Slightly reactive to reactive with oxidizing agents, organic materials.
Corrosivity:
Extremely corrosive in presence of aluminum. Highly corrosive in presence of zinc. Corrosive in presence of steel, of copper.
Slightly corrosive in presence of stainless steel(304), of stainless steel(316). Non-corrosive in presence of glass.
Reacts violently (moderate reaction with heat of evolution) with water especially when water is added to the product. Isolate
hydrogen chloride from heat, direct, alkalies (reacts vigorously), organic materials, and oxidizers (especially nitric acid and
chlorates), amines, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence),
sulfuric acid(increase in temperature and pressure) Hydrogen chloride causes aldehydes and epoxides to violently polymerize.
It reacts with oxidizers releasing chlorine gas. Hydrogen chloride gas is emitted when this product is in contact with sulfuric
acid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes
and epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause
explosion or ignition on contact or other violent/vigorous reaction: Acetic anhydride, Alcohols + hydrogen cyanide, Aluminum,
Aluminum phosphide, Aluminum-titanium alloys (with HCl vapor), 2-Amino ethanol, Ammonium, Ammonium hydroxide, 1,4-
Benzoquinone diimine, Calcium acetylide (incandescence upon warming), Calcium carbide, Calcium phosphide, Carbon
tetrachloride + silver perchlorate (produce trichlormethyl perchlorate), Cesium acetylene carbide, Cesium carbide, Cesium
telluroacylates, Chlorine + dinitroanilines (evolves gas), Chloroacetaldehyde oxime, Chlorosulfonic acid, Cyanogen chloride
(when catalyzed by HCl), 1,1-Difluoroethylene, Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime
(when generated by using HCl as a catalyst), Ethylene imine, Fluorine, HClO4, Hexalithium disilicide, Hydrogen peroxide,
Lithium silicide, Metal acetylides, carbides, Magnesium boride, Methyl vinyl ether, Mercuric sulfate, Nitric acid + glycerol,
Oleum, Perchloric acid, Potassium, Potassium permanganate, beta-Propiolactone, Propylene oxide, Rubidium acetylide,
Rubidium carbide, Rubidium acetylene carbide, Silicon dioxide, Silver chlorite, Sodium (with aqueous HCl), Sodium 2-
allyloxy-6-nitrophenylpyruvate oxime, Sodium hydroxide, Sodium tetraselenium, Sulfonic acid, Sulfuric acid, Tetraselenium
tetranitride, 2,4,6-Tri(2-acetylhydrazino)-1,3,5-trinitrobenzene, Uranium phosphide, Vinyl acetate. Hydrogen chloride gas
can react with formaldehyde to form bis(chloromethyl)ether, a human carcinogen. Most metals, as well as certain coatings,
plastics, and rubbers, are attacked by hydrogen chloride. Addition of hydrochloric acid to the following results in an exothermic
reaction: Cesium cyanotridecahydrodecarborate(2-), Potassium ferricyanide, Vinylidene fluoride. Addition of hydrochloric acid
to potassium ferrocyanide or ammonium hexacyanoferrate(II) results in an endothermic reaction. Hydrochloric acid in the
presence of alcohol and glycols results in dehydration reactions. (Hydrogen chloride)
This compound is highly corrosive when in solution (especially to most metals except: gold, mercury, platinum, silver, and
tantalum). The anhydrous gas is not corrosive . (Hydrogen chloride) Will not occur.
Polymerization:
p. 5
Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity of
the vapor (LC50): 3124 ppm, 1 hours [Rat]. (Hydrochloric Acid)
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. Contains material which
may cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, , teeth.
Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact
(corrosive). Slightly hazardous in case of inhalation (lung sensitizer, lung corrosive).
Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300
ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M (Hydrochloric Acid)
May cause adverse reproductive effects (fetoxicity). May affect genetic material. (Hydrochloric Acid)
Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe eye
irritation and burns. May cause permanent damage to the eyes. Inhalation: Inhalation of vapor or mist may be destructive
to tissue of the mucous membranes and upper respiratory tract. It may affect the lungs/respiration. Inhalation of mist or
vapor may produce nose, throat, and laryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking
sensation, hoarseness, laryngeal spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations.
Inhalation of high concentrations may also cause chemical burns of the upper respiratory tract, constriction of the larynx and
bronchi, nasospetal perforation, glottal closure, dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also
occur, particularly if exposure is prolonged. It may affect the liver Ingestion: Causes irritation and burns of the mouth, throat,
esophagous (gastrointestinal tract) with nausea, vomitting abdominal cramps, diarrhea. It can also cause thirst, difficulty
swallowing, salivation, chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect
behavior (excitement), the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary
system (kidneys - renal failure, nephritis). Chronic Potential Health Effects: Prolonged or repeated inhalation or ingestion
may affect liver, respiration(changes in pulmonary function, chronic bronchitis), teeth (yellowing of teethand erosion of tooth
enamel), kidneys, and behavior. Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact
with vapor/mist may cause conjunctivitis
Waste Disposal:
p. 6
Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II
Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric
acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK
hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts
RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:
Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8(b)
inventory: Hydrochloric acid; Water TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremely
hazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid 24%
CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg);
WHMIS (Canada):
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R34- Causes burns. S24/25- Avoid contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of water. S36/37/39- Wear
suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Created: 10/10/2005 10:32 AM
Last Updated: 11/01/2010 12:00 PM
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E
Methyl orange MSDS
Product Name: Methyl orange
Catalog Codes: SLM2938, SLM4318
CAS#: 547-58-0
RTECS: DB6327000
TSCA: TSCA 8(b) inventory: Methyl orange
CI#: 13025
Synonym: Acid Orange 52; Sodium
Dimethylaminobenzenesulfonate; 4-
[Dimethylamino)pnenylazo]benzenesulfonic Acid, sodium
salt; Orange III; Tropaeolin D
Chemical Name: Methyl Orange
Chemical Formula: C14H14N3NaO3S
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Methyl orange 547-58-0 100
Toxicological Data on Ingredients: Methyl orange: ORAL (LD50): Acute: 60 mg/kg [Rat].
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposure can result
in death.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to a highly toxic material may
produce general deterioration of health by an accumulation in one or many human organs.
p. 2
Eye Contact:
minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact:
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek
medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.
Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks.
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal.
p. 3
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25C (77F).
product.
Physical state and appearance: Solid. (Powdered solid.)
Odor: Odorless.
Color: Orange-Yellow.
Melting Point: >300C (572F)
Specific Gravity: Not available.
Dispersion Properties: Not available.
Solubility:
Partially soluble in hot water. Very slightly soluble in cold water. Insoluble in diethyl ether. Practically insoluble in alcohol.
Soluble in Pyrimidine.
p. 4
Conditions of Instability: Excess heat, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents.
Toxicity to Animals: Acute oral toxicity (LD50): 60 mg/kg [Rat].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Chronic Effects on Humans: May affect genetic material
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Dust may cause eye irritation. This product contains
an anionic dye. Similar dyes have not caused injury to the cornea or conjunctiva in documented exposure cases with
human or rabbit eyes. Inhalation: Dust may cause respiratory tract irritation, Ingestion: Harmful is swallowed. May cause
gastrointestinal tract irritation with nausea, vomiting, and diarrhea. The toxicological properties of this substance have not been
fully investigated.
Waste Disposal:
DOT Classification: CLASS 6.1: Poisonous material.
p. 5
Identification: : Dye, solid, toxic, n.o.s. (Methyl orange) UNNA: 3143 PG: III
Federal and State Regulations: TSCA 8(b) inventory: Methyl orange
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
DSCL (EEC):
R25- Toxic if swallowed. S28- After contact with skin, wash immediately with plenty of water. S45- In case of accident or if you
feel unwell, seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Created: 10/10/2005 08:40 PM
Last Updated: 11/01/2010 12:00 PM
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Phenolphthalein TS MSDS
Product Name: Phenolphthalein TS
Catalog Codes: SLP1345
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Water; Ethyl alcohol 200
Proof; Phenolphthalein, powder
Synonym: Phenolphthalein TS
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Water 7732-18-5 5.0
Ethyl alcohol 200 Proof 64-17-5 94
Phenolphthalein, powder 77-09-8 1
Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse]. Phenolphthalein, powder LD50: Not available.
LC50: Not available.
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Slightly hazardous in case of skin contact
(permeator). Non-corrosive for skin. Non-corrosive to the eyes. Non-corrosive for lungs.
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN
p. 2
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. The substance is toxic to blood,
the reproductive system, liver, upper respiratory tract, skin, central nervous system (CNS). The substance may be toxic to
kidneys. Repeated or prolonged exposure to the substance can produce target organs damage.
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Get medical attention.
Skin Contact:
attention.
attention.
Inhalation:
attention if symptoms appear.
Serious Inhalation:
attention.
Ingestion:
Flammability of the Product: Flammable.
Auto-Ignition Temperature: The lowest known value is 363C (685.4F) (Ethyl alcohol 200 Proof).
Flash Points:
The lowest known value is CLOSED CUP: 12.78C (55F). OPEN CUP: 12.78C (55F). (Cleveland). (Ethyl alcohol 200 Proof)
Flammable Limits: The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 200 Proof)
Products of Combustion: These products are carbon oxides (CO, CO2).
Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing
materials. Non-flammable in presence of shocks, of reducing materials, of combustible materials, of organic materials, of
metals, of acids, of alkalis, of moisture.
Slightly explosive in presence of oxidizing materials, of acids. Non-explosive in presence of open flames and sparks, of
shocks.
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog.
p. 3
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable
distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Ethanol has an explosive reaction with the oxidized coating around potassium metal. Ethanol ignites and then explodes on
contact with acetic anhydride + sodium hydrosulfate (ignites and may explode), disulfuric acid + nitric acid, phosphorous(III)
oxide platinum, potassium-tert-butoxide+ acids. Ethanol forms explosive products in reaction with the following compound :
ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane iodide), magnesium
perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver fulminate) silver nitrate (forms ethyl
nitrate) silver(I) oxide + ammonia or hydrazine (forms silver nitride and silver fulminate), sodium (evolves hydrogen gas). (Ethyl
alcohol 200 Proof)
Small Spill:
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
product.
Exposure Limits:
Ethyl alcohol 200 Proof TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 1000 (ppm) from OSHA (PEL)
[United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000 (ppm) from NIOSH TWA: 1000 (ppm)
[United Kingdom (UK)] TWA: 1920 (mg/m3) [United Kingdom (UK)] TWA: 1000 STEL: 1250 (ppm) [Canada]Consult local
authorities for acceptable exposure limits.
p. 4
Color: Colorless.
pH (1% soln/water): Neutral.
Boiling Point: The lowest known value is 78.5C (173.3F) (Ethyl alcohol 200 Proof). Weighted average: 79.58C (175.2F)
Melting Point: May start to solidify at -114.1C (-173.4F) based on data for: Ethyl alcohol 200 Proof.
Critical Temperature: The lowest known value is 243C (469.4F) (Ethyl alcohol 200 Proof).
Vapor Pressure: The highest known value is 5.7 kPa (@ 20C) (Ethyl alcohol 200 Proof). Weighted average: 5.53 kPa (@
20C)
Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.54 (Air = 1)
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof)
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water, methanol, diethyl ether. Soluble in acetone.
Conditions of Instability: Incompatible materials, heat, sources of ignition. (Ethyl alcohol 200 Proof)
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Ethanol rapidly absorbs moisture from the air. Can react vigorously with oxiders. The following oxidants have been
demonstrated to undergo vigorous/explosive reaction with ethanol: barium perchlorate, bromine pentafluoride, calcium
hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride, dioxygen difluoride, disulfuryl difluoride, fluorine nitrate,
hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl perchlorate, perchloric acid permanganic acid, peroxodisulfuric
acid, potassium dioxide, potassium perchlorate, potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver
peroxide, uranium hexafluoride, uranyl perchlorate. Ethanol reacts violently/expodes with the following compounds: acetyl
bromide (evolves hydrogen bromide) acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver
oxide, chlorate, chromic anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen
peroxide + sulfuric acid, iodine + methanol + mercuric oxide, manganese perchlorate + 2,2-dimethoxy propane, perchlorates,
permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, silver & nitric acid, silver perchlorate, sodium
hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water. Ethanol is also incompatible with platinium, and
sodium. (Ethyl alcohol 200 Proof)
p. 5
Routes of Entry: Absorbed through skin. Eye contact. Inhalation.
Toxicity to Animals: Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. (Ethyl alcohol 200 Proof).
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. Contains material which may
cause damage to the following organs: kidneys.
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
May affect genetic material (mutagenic) Causes adverse reproductive effects and birth defects (teratogenic) , based on
moderate to heavy consumption. May cause cancer based on animal data. Human: passes through the placenta, excreted in
maternal milk. (Ethyl alcohol 200 Proof)
Acute potential health effects: Skin: causes skin irritation Eyes: causes eye irritation Ingestion: May affect behavior.
Moderately toxic and narcotic in high concentrations. May affect metabolism, gastrointestinal tract, blood, liver. May affect
respiratory tract, cardiovascular and urinary systems. Experimentaly tumorigen. Inhalation: May cause irritation of the
respiratory tract, headache, drowsiness, nausea, narcosis. (Ethyl alcohol 200 Proof)
Waste Disposal:
DOT Classification: CLASS 3: Flammable liquid.
Identification: : Ethanol (Ethyl alcohol 200 Proof) UNNA: 1170 PG: II
p. 6
California prop. 65: This product contains the following ingredients for which the State of California has found to cause
cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl alcohol 200 Proof;
Phenolphthalein, powder California prop. 65: This product contains the following ingredients for which the State of California
has found to cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof California prop. 65:
This product contains the following ingredients for which the State of California has found to cause cancer which would require
a warning under the statute: Ethyl alcohol 200 Proof; Phenolphthalein, powder Rhode Island RTK hazardous substances:
Ethyl alcohol 200 Proof Pennsylvania RTK: Ethyl alcohol 200 Proof Florida: Ethyl alcohol 200 Proof Massachusetts RTK: Ethyl
alcohol 200 Proof New Jersey: Ethyl alcohol 200 Proof TSCA 8(b) inventory: Water; Ethyl alcohol 200 Proof; Phenolphthalein,
powder
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8C (100F). CLASS D-2A: Material causing other toxic effects
(VERY TOXIC).
DSCL (EEC):
R11- Highly flammable. R22- Harmful if swallowed. R45- May cause cancer. S2- Keep out of the reach of children. S46-
If swallowed, seek medical advice immediately and show this container or label. S53- Avoid exposure - obtain special
instructions before use.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
Health: 2
Flammability: 3
Reactivity: 0
Specific hazard:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.
Created: 10/10/2005 11:18 AM
Last Updated: 11/01/2010 12:00 PM
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Potassium dichromate MSDS
Product Name: Potassium dichromate
Catalog Codes: SLP5455, SLP2629
CAS#: 7778-50-9
RTECS: HX7680000
TSCA: TSCA 8(b) inventory: Potassium dichromate
CI#: Not available.
Synonym: Bichromate of potash; Dipotassium
Dichromate; Potassium bichromate; Potassium dichromate
(VI)
Chemical Name: Not available.
Chemical Formula: K2Cr2O7
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Potassium dichromate 7778-50-9 100
Toxicological Data on Ingredients: Potassium dichromate LD50: Not available. LC50: Not available.
Extremely hazardous in case of skin contact (permeator). Very hazardous in case of skin contact (irritant), of eye contact
(irritant), of ingestion, . Hazardous in case of skin contact (corrosive, sensitizer), of eye contact (corrosive), of inhalation (lung
irritant). Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory
irritation. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching.
Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.)
by ACGIH. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to
blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce
target organs damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.
p. 2
Eye Contact:
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Fire Hazards in Presence of Various Substances: combustible materials, organic materials
Dangerous in contact with organic materials. Contact with combustible or organic materials may cause fire. When heated to
decomposition it emits toxic fumes of potassium oxide
Special Remarks on Explosion Hazards: Reacts explosively with hydrazine, and anydrous hydroxylamine.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep
substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
p. 3
Precautions:
Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible
material Do not breathe dust. Never add water to this product In case of insufficient ventilation, wear suitable respiratory
equipment If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes Keep
away from incompatibles such as reducing agents, combustible materials, organic materials.
Storage: Oxidizing materials should be stored in a separate safety storage cabinet or room.
product.
Exposure Limits:
CEIL: 0.1 (mg(CrO3)/m ) from OSHA (PEL) [United States] TWA: 0.05 (mg(Cr)/m) from ACGIH (TLV) [United States]Consult
local authorities for acceptable exposure limits.
Physical state and appearance: Solid.
Odor: Odorless.
Taste: Bitter. metallic.
Color: Orange-Red.
pH (1% soln/water): 4 [Acidic.]
Boiling Point: Decomposition temperature: 500C (932F)
Melting Point: 398C (748.4F)
Specific Gravity:
2.676 @ 25 deg. C(Water = 1) Bulk Density: 1.6 g/m3 @ 20 deg. C
p. 4
Solubility:
Easily soluble in hot water. Soluble in cold water. Solubility in water: 4.9 g/100 ml water @ 0 deg. C Solubility in water: 10.5%
(w/w) @ 20 deg. C Solubility in water: 102 g/100 ml water @ 100 deg. C Insoluble in alcohol.
Incompatibility with various substances: Reactive with reducing agents, combustible materials, organic materials, metals,
acids, alkalis.
Reacts violently or ignites with ethylene glycol above 100 deg. C Other Incompatibles: combustible, organic, or other readily
oxidizable materials such as paper, wood, sulfur, aluminum, iron, tungsten, sulfuric acid + acetone, born, glycol, sulfur, plastics
Polymerization: No.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Acute oral toxicity (LD50): 25 mg/kg [Rat]. Acute dermal toxicity (LD50): 14 mg/kg [Rabbit].
CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.) by ACGIH. MUTAGENIC EFFECTS: Mutagenic for
mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood, kidneys,
lungs, liver, upper respiratory tract, skin, eyes.
Extremely hazardous in case of skin contact (permeator). Very hazardous in case of skin contact (irritant), of ingestion, .
Hazardous in case of skin contact (corrosive, sensitizer), of eye contact (corrosive), of inhalation (lung irritant).
Lowest Published Lethal Dose: LDL [Man] - Route: Oral; Dose: 143 mg/kg LDL [Child] - Route: Oral; Dose 26 mg/kg
Passes through the placental barrier in animal. May cause adverse reproductive effects and birth defects (teratogenic). May
affect genetic material (mutagenic)
Acute Potential Health Effects: Skin: It causes skin irritation and may cause skin burns. It can be absorbed by the skin and
cause systemic effects. Deep ulceration of the skin of the hands, resulting from occupational exposure can penetrate as
far as the bone in severe cases. Eyes: Causes eye irritation and may cause eye burns. It may cause severe damage with
possible loss of vision, transient corneal bulging, residual irregular astigmatism, and anesthesia of the area after bulging
resolves. Inhalation: Causes respiratory tract irritation. Inhalation of dust or mist can also cause irritation of the nose and
eyes. Symptoms may include sneezing, rhinorrhea, throat erythema, nasal septum lesions, or perforation with with bleeding,
disharge, or crusting Ingestion: Harmful if swallowed. When ingested in small amounts, it can cause burns of the esophagus,
with possible stricture formation and perforation of the stomach. Symptoms may include adbominal and esophageal pain,
nausea, vomiting, hypermotility, diarrhea, gastrointestinal tract irritation and bleeding, respiratory distress, cyanosis, coma, and
death. It may also affect the cardiovascular system (cardiovascular shock, peripheral vascular collapse, urinary system (kidney
p. 5
damage - nephritis with glycosuria, acute tubular necrosis, renal failure), liver (elevated liver enzyme levels, hepatits, hepatic
failure), behavior/central nervous system/nervous system (somnolence, ataxia, vertigo, muscle cramps). It may also affect
the blood and cause anemia, methemglobinemia (characterized by dizziness, drowsiness, headache, shortness of breath,
cyanosis with bluish skin, rapid heart
Ecotoxicity:
Ecotoxicity in water (LC50): 75 mg/l 96 hours [Fish (Striped bass)]. 1.5 mg/l 24 hours [Daphnia (daphnia)]. 17.3 mg/l 11 hours
[Fish (Fathead minnow)].
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation:
Dangerous to aquatic life in high concentrations. Chromium probably occurs as the insoluble (CrIII) oxide (Cr2O3.nH2O) in
the soil, as the organic matter in the soil is expected to reduce any soluble chromate to insoluble chromic oxide (Cr2O3).
Chromium in the soil can be transported to the atmosphere by way of aerosol formation. Chromium is also transported from
the soil through runoff and leaching of water. Most of the chromium in surface waters may be present in particulate from as
sediment. Some of the particulate chromium would remain as suspended matter and ultimately be deposited in the sediments.
Chromium present usually as (CrIII) in the soil and is characteriszed by its lack of mobility, except in cases where Cr(VI) is
involved. Chromium (VI) of natural origin is rarely found.
Waste Disposal:
DOT Classification:
CLASS 5.1: Oxidizing material. CLASS 6.1: Poisonous material.
Identification: : Toxic Solids, Oxidizing, n.o.s (Potassium Dichromate) UNNA: 3086 PG: I
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,
birth defects or other reproductive harm, which would require a warning under the statute: Potassium dichromate California
prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which
would require a warning under the statute: Potassium dichromate Pennsylvania RTK: Potassium dichromate Massachusetts
RTK: Potassium dichromate TSCA 8(b) inventory: Potassium dichromate SARA 313 toxic chemical notification and release
reporting: Potassium dichromate CERCLA: Hazardous substances.: Potassium dichromate
WHMIS (Canada):
p. 6
CLASS C: Oxidizing material. CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS
D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
R21- Harmful in contact with skin. R25- Toxic if swallowed. R26- Very toxic by inhalation. R37/38- Irritating to respiratory
system and skin. R41- Risk of serious damage to eyes. R43- May cause sensitization by skin contact. R46- May cause
heritable genetic damage. R49- May cause cancer by inhalation. R50/53- Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment. S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible). S53- Avoid exposure - obtain special instructions before use. S60- This
material and its container must be disposed of as hazardous waste. S61- Avoid release to the environment. Refer to special
instructions/Safety data sheets.
HMIS (U.S.A.):
Health Hazard: 4
Fire Hazard: 0
Reactivity: 0
Health: 4
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
Created: 10/10/2005 08:49 PM
Last Updated: 11/01/2010 12:00 PM
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Potassium Hydroxide, 45% MSDS
Product Name: Potassium Hydroxide, 45%
Catalog Codes: SLP3880
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Potassium hydroxide; Water
Synonym:
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Potassium hydroxide 1310-58-3 45
Water 7732-18-5 55
Toxicological Data on Ingredients: Potassium hydroxide: ORAL (LD50): Acute: 273 mg/kg [Rat]. 365 mg/kg [Rat]. 388 mg/
kg [Rat].
Extremely hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant), of ingestion, of inhalation. Liquid or
spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact
may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing,
choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation
is characterized by itching, scaling, reddening, or, occasionally, blistering.
Extremely hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant), of ingestion, of inhalation. Non-
sensitizer for skin. Non-permeator by skin. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs,
mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated
p. 2
or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged
exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated or
prolonged inhalation of vapors may lead to chronic respiratory irritation.
Eye Contact:
open. Finish by rinsing thoroughly with running water to avoid a possible infection. Cold water may be used.
Skin Contact:
If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting
your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such
as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly
careful to clean folds, crevices, creases and groin. Cold water may be used. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.
attention.
Serious Inhalation:
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that
the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,
tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
p. 3
Small Spill:
necessary: Neutralize the residue with a dilute solution of acetic acid.
Large Spill:
acetic acid. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
local authorities.
Precautions:
Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case of
insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as acids, moisture.
Storage:
Alkalis may be stored in heavy duty gauge steel containers. Corrosive materials should be stored in a separate safety storage
cabinet or room.
product.
Exposure Limits:
Potassium hydroxide CEIL: 2 (mg/m3) from ACGIH Consult local authorities for acceptable exposure limits.
Taste: Alkaline. (Strong.)
pH (1% soln/water): Basic.
p. 4
Vapor Pressure: The highest known value is 17.535 mm of Hg (@ 20C) (Water).
Solubility:
Easily soluble in cold water, hot water. Soluble in methanol.
Incompatibility with various substances: Extremely reactive or incompatible with acids.
Corrosivity:
Extremely corrosive in presence of aluminum. Slightly corrosive to corrosive in presence of glass.
Polymerization: No.
Routes of Entry: Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 607 mg/kg (Rat) (Calculated value for the mixture).
Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.
Other Toxic Effects on Humans: Extremely hazardous in case of skin contact (corrosive, irritant), of ingestion, of inhalation.
Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.
p. 5
Waste Disposal:
DOT Classification: CLASS 8: Corrosive liquid.
Identification: : Potassium hydroxide, solution (Potassium hydroxide) : UN1814 PG: II
Pennsylvania RTK: Potassium hydroxide Massachusetts RTK: Potassium hydroxide TSCA 8(b) inventory: Potassium
hydroxide; Water CERCLA: Hazardous substances.: Potassium hydroxide;
WHMIS (Canada):
CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC): R35- Causes severe burns.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Created: 10/09/2005 06:09 PM
Last Updated: 11/01/2010 12:00 PM
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Potassium hydroxide MSDS
Product Name: Potassium hydroxide
Catalog Codes: SLP4096, SLP3085, SLP4900, SLP2071
CAS#: 1310-58-3
RTECS: TT2100000
TSCA: TSCA 8(b) inventory: Potassium hydroxide
CI#: Not available.
Synonym:
Chemical Name: Potassium Hydroxide
Chemical Formula: KOH
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Potassium hydroxide 1310-58-3 100
Toxicological Data on Ingredients: Potassium hydroxide: ORAL (LD50): Acute: 273 mg/kg [Rat].
Very hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant, corrosive), of ingestion, of inhalation.
The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin
contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory
tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,
unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to
upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage.
Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.
p. 2
Eye Contact:
Skin Contact:
attention.
Inhalation:
Serious Inhalation:
Ingestion:
Fire Hazards in Presence of Various Substances: metals, acids
Violent reaction or ignition under appropriate conditions with acids, alcohols, p-bis(1,3-dibromoethyl) benzene,
cyclopentadiene, germanium, hyponitrous acid, maleic anhydride, nitroalkanes, 2-nitrophenol, potassium peroxodisulfate,
sugars, 2,2,3,3-tetrafluoropropanol, thorium dicarbide. Molten ortho -nitrophenol reacts violently with potassium hydroxide.
When potassium hydroxide and tetrachloroethane are heated, a spontaneously flammable gas, chloroacetylene, is formed.
When phosphorus is boiled in a solution of potassium hydroxide, phosphine gas is evolved which is spontaneously flammable.
1,2-Dichloroethylene and Potassium hydroxide reaction produces chloroacetylene which is spontaneously flammable in air.
Potassium Persulfate and a little Potassium hydroxide and water will ignite. When wet, attacks metals such as aluminum, tin,
lead, and zinc, producing flammable hydrogen gas.
p. 3
Potentially explosive reaction with bromoform + crown ethers, chlorine dioxide, nitrobenzene, nitromethane, nitrogen
trichloride, peroxidized tetrahydrofuran, 2,4,6-trinitrotoluene. Reaction with ammonium hexachloroplatiate(2-) + heat forms
heat sensitive explosive product. Potassium hydroxide will cause explosive decomposition of maleic anhydride. Detonation will
occur when potassiuim hydroxide is mixed with n-methyl-nitroso urea and methylene chloride. Nitrogen trichloride explodes on
contact with potassium hydroxide.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation,
contact with skin and eyes. Keep away from incompatibles such as organic materials, metals, acids, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23C (73.4F).
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from ACGIH (TLV) [United States] Consult local
authorities for acceptable exposure limits.
Physical state and appearance: Solid. (Solid pellets.)
Odor: Odorless.
p. 4
Color: White.
pH (1% soln/water): 13 [Basic.]
Boiling Point: Decomposition temperature: 1384C (2523.2F)
Melting Point: 380C (716F)
Solubility:
Easily soluble in cold water, hot water. Insoluble in diethyl ether.
Conditions of Instability: Incompatible materials, dust generation, exposure to moist air or water.
Highly reactive with acids. Reactive with organic materials, metals, moisture.
Corrosivity:
Extremely corrosive in presence of aluminum, brass, and zinc. Slightly corrosive in presence of copper, of stainless steel(304).
Non-corrosive in presence of stainless steel(316).
Hygroscopic (absorbs moisture from air). When dissolved in water or alcohol or when the solution is treated with acid, much
heat is generated. Reacts violently with acids, halogens, halogenated hydrocarbons, maleic anhydride, organic anhydrides,
isocyanates, alkylene oxides, epichlorhydrin, aldehydes, alcohols, gylcols, phenols, cresols, caprolactum solution. Also
incompatible with nitro compounds (nitrobenzene, nitromethane, nitrogen trichloride), organic materials, acid anhydrides, acid
chlorides, magnesium, peroxidized tetrahydrofuran, chlorine dioxide, maleic dicarbide, sugars. When wet attacks metals such
as aluminum, tin, lead, and zinc.
When wet, attacks metals such as aluminum, tin, lead, and zinc, producing flammable hydrogen gas. Severe corrosive effect
on brass and bronze.
Routes of Entry: Absorbed through skin. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 273 mg/kg [Rat].
p. 5
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: upper
respiratory tract, skin, eyes.
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant), of eye
contact (corrosive), of ingestion, .
Special Remarks on Chronic Effects on Humans: May affect genetic material based on animal data.
Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Eyes: Causes severe eye irritation and
burns. May cause irreversible eye injury. Inhalation: Causes severe irritation and burns of the respiratory tract and mucous
membranes. Irritation may lead to chemical pneumonitis Ingestion: Harmful if swallowed. May cause severe and permanent
damage to the digestive tract. Causes severe irritation and burns of the gastrointestinal (digestive) tract with abdominal pain,
vomiting and possible death. May cause perforation of the digestive tract. Chronic Potential Health Effects: Chronic contact
with dilute solutions of potassium hydroxide can cause dermatitis. Inhalation can produce chronic productive cough, and
shortness of breath.
Ecotoxicity: Ecotoxicity in water (LC50): 80 mg/l 24 hours [Mosquito Fish].
Waste Disposal:
Identification: : Potassium hydroxide, solid UNNA: 1813 PG: II
New York release reporting list: Potassium hydroxide Pennsylvania RTK: Potassium hydroxide Florida: Potassium hydroxide
Minnesota: Potassium hydroxide Massachusetts RTK: Potassium hydroxide New Jersey: Potassium hydroxide California
Director's List of Hazardous Substances: Potassium hydroxide TSCA 8(b) inventory: Potassium hydroxide CERCLA:
Hazardous substances.: Potassium hydroxide: 1000 lbs. (453.6 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
p. 6
WHMIS (Canada):
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS E: Corrosive solid.
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
Personal Protection: j
Health: 3
Flammability: 0
Reactivity: 1
Specific hazard:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.
Created: 10/10/2005 08:23 PM
Last Updated: 11/01/2010 12:00 PM
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Potassium Iodide MSDS
Product Name: Potassium Iodide
Catalog Codes: SLP2050, SLP1042, SLP2854
CAS#: 7681-11-0
RTECS: TT2975000
TSCA: TSCA 8(b) inventory: Potassium Iodide
CI#: Not available.
Synonym:
Chemical Name: Potassium Iodide
Chemical Formula: KI
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Potassium Iodide 7681-11-0 100
Toxicological Data on Ingredients: Potassium Iodide LD50: Not available. LC50: Not available. Lowest Published Lethal
Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL [Rabbit] - Route: Oral; Dose: 916 mg/kg
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE]. The substance may be toxic to thyroid. Repeated or prolonged exposure to the substance
can produce target organs damage.
Eye Contact:
p. 2
Skin Contact:
may be used.
Inhalation:
attention.
Ingestion:
Products of Combustion: Some hazardous decomposition products are: Hydrogen Iodide, Oxides of potassium , iodine
Special Remarks on Explosion Hazards: Potassium iodide + Fluorine Perchlorate will explode on contact.
Small Spill:
Large Spill:
Precautions:
Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when
possible. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, moisture.
p. 3
Storage:
Moisture Sensitive. Light Sensitive. Air SensitiveKeep container tightly closed in light-resistant containers. Keep container in a
cool, well-ventilated area.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
product.
Physical state and appearance: Solid. (Deliquescent crystals solid.)
Odor: Odorless.
Taste: Bitter. Saline. (Strong.)
Molecular Weight: 166 g/mole
Color: White.
Boiling Point: 1330C (2426F)
Dispersion Properties: See solubility in water, methanol, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in methanol. Partially soluble in acetone.
p. 4
Conditions of Instability:
Light, moisture, incompatible materials. It is stable under ordinary conditions of use and storage. On long exposure to air, it
becomes yellow due to release of iodine.
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, organic materials, metals, acids.
Corrosivity:
Corrosive in presence of steel, of aluminum, of zinc. Non-corrosive in presence of glass, of copper, of stainless steel(304), of
stainless steel(316).
Moisture Sensitive. Light Sensitive. Air Sensitive. Air causes decomposition to iodine. Reacts violently with strong oxidizers,
bromotrifluorides, chlorotrifluorides, fluorine perchlorate, metallic salts. Attacks metals in moist environments. Also
incompatible with salts of alkaloids, chloral hydrate, calomel (mercurous chloride), potassium chlorate, tartaric and other
acids, oxidants, diazonium salts, charcoal, ozone, strong reducers, alkali metals, metals (brass, aluminum magnesium, zinc,
cadmium, copper, tin, nickel, steel), metallic salts, organic materials, light.
Incompatible with water, producing a corrosive. Corrosive in all concentrations to most metals, except stainless steel, titanium,
and tantalum.
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. DEVELOPMENTAL TOXICITY: Classified Reproductive
system/toxin/female, Development toxin [POSSIBLE]. May cause damage to the following organs: thyroid.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Lowest Published Lethal Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL[Rabbit] - Route: Oral; Dose: 916 mg/kg
Can cause adverse reproductive efects and birth defects based on animal data. May affect genetic material based on animal
data
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause
respiratory tract and mucous membrane irritation and a productive cough. May cause pulmonary edema and inflammation
of the tonsils. Ingestion: Causes gastrointestinal tract irritation with nausea, vomiting and diarrhea. May affect behavior
(somnolence, muscle weakness), respiration (dyspnea). Serum-sickness type of hypersensitivity such as fever, arthralgia,
lymph node enlargement , and eosinophilia may appear. Thrombotic thrombocytopenic purpura, and fatal periarteritis nodosa
attributed to hypersensitivity to iodide has been described. Chronic Potential Health Effects: Can lead to iodism characterized
by salivation, nasal discharge, sneezing, conjunctivitis, fever, headache, laryngitis, bronchitis, stomatits, parotitis, anemia, and
skin rashes. Chronic ingestion may also affect metabolism (anorexia), and thyroid gland (hypothyroidism, goiter). Furthermore,
chronic ingestion of iodides (in animals) during pregnancy has resulted in fetal deaths, severe goiter and cretinoid appearance
of the newborn.
p. 5
Waste Disposal:
Federal and State Regulations: TSCA 8(b) inventory: Potassium Iodide
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
Not available Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
when ventilation is inadequate. Safety glasses.
p. 6
Created: 10/11/2005 12:21 PM
Last Updated: 11/01/2010 12:00 PM
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Silver Nitrate, 10% MSDS
Product Name: Silver Nitrate, 10%
Catalog Codes: SLS2698
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Silver nitrate; Water
CI#: Not available.
Synonym:
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Silver nitrate 7761-88-8 10
Water 7732-18-5 90
Toxicological Data on Ingredients: Silver nitrate: ORAL (LD50): Acute: 1173 mg/kg [Rat]. 50 mg/kg [Mouse].
Hazardous in case of skin contact (irritant), of ingestion. Slightly hazardous in case of skin contact (permeator), of eye contact
(irritant), of inhalation. Non-corrosive for skin. Non-sensitizer for skin. Liquid or spray mist may produce tissue damage
particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the
spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can
produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe
skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks
of bronchial infection.
p. 2
Eye Contact:
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
attention.
Serious Inhalation:
Ingestion:
Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that
the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,
tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Small Spill:
Large Spill:
p. 3
basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Avoid contact with skin Never add water to this
product Wear suitable protective clothing If ingested, seek medical advice immediately and show the container or the label.
Storage: Corrosive materials should be stored in a separate safety storage cabinet or room.
Personal Protection: Face shield. Full suit. Gloves. Boots.
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits:
Silver nitrate TWA: 0.01 (mg/m3) from ACGIH [1995] Consult local authorities for acceptable exposure limits.
Color: Not available.
Vapor Pressure: The highest known value is 17.535 mm of Hg (@ 20C) (Water).
Solubility:
p. 4
Easily soluble in cold water. Soluble in hot water.
Polymerization: No.
Routes of Entry: Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 500 mg/kg (Mouse) (Calculated value for the mixture).
Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.
Hazardous in case of skin contact (irritant), of ingestion. Slightly hazardous in case of skin contact (permeator), of inhalation.
Non-corrosive for skin. Non-sensitizer for skin.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Waste Disposal:
DOT Classification: CLASS 8: Corrosive liquid.
p. 5
Identification: : Corrosive liquid, n.o.s. (Silver nitrate, solution) : UN1760 PG: III
Special Provisions for Transport: Marine Pollutant
Pennsylvania RTK: Silver nitrate Massachusetts RTK: Silver nitrate TSCA 8(b) inventory: Silver nitrate; Water SARA 313 toxic
chemical notification and release reporting: Silver nitrate CERCLA: Hazardous substances.: Silver nitrate;
WHMIS (Canada):
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2A: Material causing other toxic effects
(VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC): R35- Causes severe burns.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Full suit. Wear appropriate respirator when ventilation is inadequate. Face shield.
Created: 10/10/2005 11:58 AM
Last Updated: 11/01/2010 12:00 PM
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Sodium carbonate MSDS
Product Name: Sodium carbonate
Catalog Codes: SLS3481, SLS1264, SLS4105, SLS1894,
SLS3316
CAS#: 497-19-8
RTECS: VZ4050000
TSCA: TSCA 8(b) inventory: Sodium carbonate
CI#: Not available.
Synonym: Crystal Carbonate, Disodium Carbonate, Sal
Soda, Soda Asha, Washing Soda
Chemical Name: Sodium Carbonate, Anhydrous
Chemical Formula: Na2-C-O3
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Sodium carbonate 497-19-8 100
Toxicological Data on Ingredients: Sodium carbonate: ORAL (LD50): Acute: 4090 mg/kg [Rat]. 6600 mg/kg [Mouse]. DUST
(LC50): Acute: 2300 mg/m 2 hours [Rat]. 1200 mg/m 2 hours [Mouse].
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation
(lung irritant).
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:
Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may
be toxic to upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs
damage.
p. 2
Eye Contact:
Skin Contact:
attention.
attention.
Inhalation:
attention.
Ingestion:
Products of Combustion: Emits Na2O fumes when heated to decompositon.
Sodium carbonate can ignite and burn fiercely in contact with fluoride. Sodium Carbonate in contact with fluorine decomposed
at ordinary temperature with incandescence.
Reacts explosively with red-hot aluminum metal. Sodium carbonate + ammonia in arabic gum solution will explode.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution
of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system.
p. 3
Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes. Keep away from incompatibles such as acids.
Storage:
Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24C (75.2F).
Hygroscopic
product.
Physical state and appearance: Solid. (Solid powder.)
Odor: Odorless.
Taste: Alkaline.
Color: White.
pH (1% soln/water): 11.5 [Basic.]
Specific Gravity: Density: 2.532 (Water = 1)
Solubility:
p. 4
Soluble in hot water, glycerol. Partially soluble in cold water. Insoluble in acetone, alcohol.
Conditions of Instability: Incompatible materials, moisture
Reactive with acids. Slightly reactive to reactive with moisture.
Hygroscopic. Combines with water with evolution of heat. Incompatible with phosphorus pentoxide, lithium, fluorine, fluoride,
ammonia + silver nitrate, 2,4,6-trinitrotoluene, ammonia, acids, sodium sulfide + water, hydrogen peroxide, red hot alumium
metal, sodium sulfide, zinc, calcium hydroxide. Sodium Carbonate is decomposed by acids with effervescence. Reacts
violently with F2, Lithium, and 2,4,6-trinitrotoluene. Sodium begins to decompose at 400 C to evolve CO2.
Special Remarks on Corrosivity: Hot concentrated solutions of sodium carbonate are mildly corrosive to steel.
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 4090 mg/kg [Rat]. Acute toxicity of the dust (LC50): 1200 mg/m3 2 hours [Mouse].
Chronic Effects on Humans: May cause damage to the following organs: upper respiratory tract, skin, eyes.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).
Special Remarks on Toxicity to Animals: LDL (Lowest Published Lethal Dose) [Man] - Route: Oral; Dose: 714 mg/kg
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects based on animal test data
Acute Potential Health Effects: Skin: Causes skin irritation with possible burns depending on the concentration, site (abraded
or intact skin), and duration of exposure. Eyes: Causes eye irritation and possible burns. Concentrated solutions may cause
permanent corneal injury (permanent corneal opacity). Ingestion: Sodium carbonate ingestion may cause irritation of the
digestive tract resulting in nausea, vomiting, diarrhea, thirst, abdominal pain depending on concentration and amount ingested.
May also affect the cardiovascular system . Inhalation: Dust may cause respiratory tract and mucous membrane irritation
with coughing and shortness of breath (dyspnea), pulmonary edema. Chronic Potential Health Effects: Chronic inhalation
may result in decreased pulmonary function, nasal congestion, nosebleeds, perforation of the nasal septum. Other effects
of chronic exposure are skin (dermatitis and ulceration), and gastrointestinal complaints. However, the effects of chronic
exposure seem to be reversible if exposure is decreased.
p. 5
Waste Disposal:
Federal and State Regulations: TSCA 8(b) inventory: Sodium carbonate
WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R36/37/38- Irritating to eyes, respiratory system and skin. S22- Do not breathe dust. S26- In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 1
Health: 2
Flammability: 0
Reactivity: 1
Specific hazard:
p. 6
Created: 10/10/2005 08:26 PM
Last Updated: 11/01/2010 12:00 PM
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Sodium chloride MSDS
Product Name: Sodium chloride
Catalog Codes: SLS3262, SLS1045, SLS3889, SLS1669,
SLS3091
CAS#: 7647-14-5
RTECS: VZ4725000
TSCA: TSCA 8(b) inventory: Sodium chloride
Synonym: Salt; Sea Salt
Chemical Name: Sodium chloride
Chemical Formula: NaCl
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Sodium chloride 7647-14-5 100
Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].
DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >42000 mg/m 1 hours [Rat].
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.
Eye Contact:
p. 2
Skin Contact:
may be used.
Inhalation:
attention if symptoms appear.
Ingestion:
Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes.
Electrolysis of sodium chloride in presence of nitrogenous compounds to produce chlorine may lead to formation of explosive
nitrogen trichloride. Potentially explosive reaction with dichloromaleic anhydride + urea.
Small Spill:
Large Spill:
Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,
seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing
agents, acids.
p. 3
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic
product.
Physical state and appearance: Solid. (Solid crystalline powder.)
Odor: Slight.
Taste: Saline.
Color: White.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 1413C (2575.4F)
Solubility:
Easily soluble in cold water, hot water. Soluble in glycerol, and ammonia. Very slightly soluble in alcohol. Insoluble in
Hydrochloric Acid.
p. 4
Conditions of Instability: Incompatible materials, high temperatures.
Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.
Corrosivity: Not considered to be corrosive for metals and glass.
Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride is
rapidly attacked by bromine trifluoride. Violent reaction with lithium.
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 3000 mg/kg [Rat.]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):
>42000 mg/m3 1 hours [Rat].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/
or yeast.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose (LDL) [Man] - Route: Oral; Dose: 1000 mg/kg
Causes adverse reproductive effects in humans (fetotoxicity, abortion, ) by intraplacental route. High intake of sodium chloride,
whether from occupational exposure or in the diet, may increase risk of TOXEMIA OF PREGNANCY in susceptible women
(Bishop, 1978). Hypertonic sodium chloride solutions have been used to induce abortion in late pregnancy by direct infusion
into the uterus (Brown et al, 1972), but this route of administration is not relevant to occupational exposures. May cause
adverse reproductive effects and birth defects in animals, particularly rats and mice (fetotoxicity, abortion, musculoskeletal
abnormalities, and maternal effects (effects on ovaries, fallopian tubes) by oral, intraperitoneal, intraplacental, intrauterine,
parenteral, and subcutaneous routes. While sodium chloride has been used as a negative control n some reproductive
studies, it has also been used as an example that almost any chemical can cause birth defects in experimental animals
if studied under the right conditions (Nishimura & Miyamoto, 1969). In experimental animals, sodium chloride has caused
delayed effects on newborns, has been fetotoxic, and has caused birth defects and abortions in rats and mice (RTECS, 1997).
May affect genetic material (mutagenic)
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Ingestion: Ingestion of large
quantities can irritate the stomach (as in overuse of salt tablets) with nausea and vomiting. May affect behavior (muscle
spasicity/contraction, somnolence), sense organs, metabolism, and cardiovascular system. Continued exposure may
produce dehydration, internal organ congestion, and coma. Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
p. 5
Waste Disposal:
Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride
DSCL (EEC):
R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Created: 10/11/2005 12:33 PM
p. 6
Last Updated: 11/01/2010 12:00 PM
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Sodium Thiosulfate, 0.100N MSDS
Product Name: Sodium Thiosulfate, 0.100N
Catalog Codes: SLS2623
CAS#: Mixture.
TSCA: TSCA 8(b) inventory: Sodium carbonate; Water
CI#: Not available.
Synonym: Sodium Thiosulfate, 0.100N, Aqueous
Solution, APHA
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Sodium thiosulfate pentahydrate 10102-17-7 2.48
Sodium carbonate 497-19-8 0.02
Water 7732-18-5 97.5
Toxicological Data on Ingredients: Sodium thiosulfate pentahydrate LD50: Not available. LC50: Not available.
Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Non-corrosive for skin. Non-
permeator by skin. Non-corrosive to the eyes. Non-corrosive for lungs.
Slightly hazardous in case of skin contact (irritant, sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC
EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.
p. 2
Eye Contact:
Skin Contact:
may be used.
Inhalation:
attention.
Ingestion:
Special Remarks on Explosion Hazards: An explosion may occur if triturated with nitrates, chlorates, or permanganates.
(Sodium thiosulfate pentahydrate)
Small Spill:
requirements.
Large Spill:
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
Precautions: No specific safety phrase has been found applicable for this product.
p. 3
Personal Protection: Safety glasses. Lab coat.
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Solubility:
Easily soluble in cold water, hot water. Insoluble in acetone.
Conditions of Instability: Incompatible materials, light
Incompatibility with various substances: Slightly reactive to reactive with oxidizing agents, acids, alkalis.
p. 4
Special Remarks on Reactivity: Sodium Thiosulfate may be unstable to light.
Routes of Entry: Skin. Eye contact.
Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Non-permeator by skin.
Special Remarks on Toxicity to Animals: LDL (Lowest Published Lethal Dose) [Man] - Route: Oral; Dose: 714 mg/kg
(Sodium carbonate)
Acute Potenial Health Effects: Skin: It may cause mild skin irritation. Eyes: Can cause mechanical eye irritation. Inhalation:
May cause upper respiratory tract and mucous membrane irritation. Ingestion: Sodium Thiosulfate is an agent with a low
order of toxicity. Ingestion of large doses may cause gastrointestinal irritation disturbances with nausea, vomiting, addominal
cramping, diarrhea, metabolic acidosis, and hypernatremia. May also affect respiration (cyanosis, respiratory stimulation),
cardiovascular(hypotension), behavior (ataxia, convulsions) Chronic Potential Health Effects: Skin: Prolonged or repeated skin
contact may allergic dermatitis, and irritation. The toxicological preperties of this substance have not been fully investigated.
(Sodium thiosulfate pentahydrate)
Toxicity of the Products of Biodegradation: Not available.
Waste Disposal:
p. 5
Federal and State Regulations: TSCA 8(b) inventory: Sodium carbonate; Water
Other Regulations: Not available. or of its ingredients
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Not applicable. Lab coat. Not applicable. Safety glasses.
Created: 10/10/2005 12:09 PM
Last Updated: 11/01/2010 12:00 PM
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Water MSDS
Product Name: Water
Catalog Codes: SLW1063
CAS#: 7732-18-5
RTECS: ZC0110000
TSCA: TSCA 8(b) inventory: Water
CI#: Not available.
Synonym: Dihydrogen oxide
Chemical Name: Water
Chemical Formula: H2O
14025 Smith Rd.
US Sales: 1-800-901-7247
1-800-424-9300
Composition:
Water 7732-18-5 100
Toxicological Data on Ingredients: Not applicable.
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes. Non-
hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-
corrosive to the eyes. Non-corrosive for lungs.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.
DEVELOPMENTAL TOXICITY: Not available.
Eye Contact: Not applicable.
p. 2
Skin Contact: Not applicable.
Inhalation: Not applicable.
Ingestion: Not Applicable
Explosion Hazards in Presence of Various Substances: Not Applicable
Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.
Engineering Controls: Not Applicable
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Not Applicable
p. 3
Odor: Odorless.
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100C (212F)
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20C)
Vapor Density: 0.62 (Air = 1)
Dispersion Properties: Not applicable
Solubility: Not Applicable
Corrosivity: Not available.
Routes of Entry: Absorbed through skin. Eye contact.
LD50: [Rat] - Route: oral; Dose: > 90 ml/kg LC50: Not available.
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-hazardous in case of
ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-
corrosive for lungs.
p. 4
Waste Disposal:
Federal and State Regulations: TSCA 8(b) inventory: Water
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
Health: 0
Flammability: 0
Reactivity: 0
Specific hazard:
p. 5
Not applicable. Lab coat. Not applicable. Safety glasses.
Created: 10/10/2005 08:33 PM
Last Updated: 11/01/2010 12:00 PM

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