*

Detailed Chemistry Key answer HSC March - 2014.

*



Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
*

PART - I
Q. No. Correct Answer
1
( d ) = h / mv
2 ( d ) sp
3
d
3

3 ( a ) Z* = Z S
4 ( c ) PH3
5 ( d ) Cu
+

6
( b ) 3d
5
4S
1

7 ( d ) + 4
8 ( b ) Lu
9 ( a ) Magnesium - Porphyrin
10 ( c ) 6 , 4
11 ( c ) Unit cell
12 ( b ) q = 0
13 ( b ) are state functions
14 ( b ) K
1
= 1 / K
2

15 ( b ) deactivates the catalyst
16 ( b ) mol litre
-1
sec
-1

17 ( a ) Protein
18 ( b ) Glycerine
19 ( c ) Dialysis
20 ( c ) 13
21
( a) CH
3
MgI reacts with alcohol
giving methane.
22 ( d ) Comparatively inert.
23 ( b ) Williamson synthesis
24 ( c ) Ammonical silver nitrate
25
( b ) Acid chloride > Acid
anhydride > Ester > Amide
26 ( c ) Functional
27 ( c ) Di methyl amine
28 ( b ) Diphenyl amine
29 ( d ) Waxes
30 ( b ) Cellulose




CHEMISTRY


Note :
The key answer published for paper
evaluation by the Directorate of Government
Examinations Chennai- 6 is the foremost one.
It is only a guidance material to the
teachers as well as students for better
understanding of distribution of mark to the key
points.
If the teacher highlight the key points
and make a note on distribution of marks in red
ink in this detailed key answer material from the
key answer given by DGE, then the evaluation
should beCORRECTION FREE EVALUATION.
The students are advised to understand
the key answer and not to miss the key points
while writing the examination in the upcoming
years.
If you find any inconsistencies kindly
correct it in accordance with DGE Key.



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*

Detailed Chemistry Key answer HSC March - 2014.

*



Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
*

PART - II
31.Significance of negative electron
energy
32.IE Boron is less than that of
Berllium

33.P
2
O
5
powerful dehydrating agent

34.Three uses of Helium

35.The reason for transition elements
form complexes

36. Gold reaction with auqaregia

37. Half-life period calculation
1/2
0.693
t
=

0.693
2.31min
=

1
0.3min

=
38. Vitreous state
39.Calculation of Entropy

540 /
18
( ) 373
vap
vap
b
H
cal mole
S X
T k K
A
A = =

vap
S A = 26.05898 = 26.06
1 1
calk mole


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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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40.Reaction Quotient (Q)

41.Consecutive reaction-example

42.Activation energy

43.Tyndall effect

44. Common ion effect - example

45.Recemisation

46.Victor Meyers test for tertiary
alchohol


47.Picric acid preparation from phenol

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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48.Urotropine and its use.

49.Trans-esterification reaction

50.


Compound
Molecular
formula
Name
A C6H7N Aniline
B C6H5N2Cl
Benzene diazonium
chloride
C C6H5OH Phenol

51.Antiacids and Example

PART III
Section -A
52. Formation of N
2
Molecule by MOT.

53. The extraction of Zinc

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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54. Extraction of lanthanides.

55.Write for the Coordination compound
[ Cr (en)
3
] Cl
3
(a) IUPAC NAME
Tris (ethylenediamine) Chromium (III) Chloride
(b) Name of the central metal ion - Cr
3+

(c) Ligand en - Ethylene diamine
(d) Coordination Number 6
(e) Structure of [ Cr (en)
3
] Cl
3

chandrachemistry Octahedral
56. Characteristics of Free energy G

57. Relationship between Kp and Kc.


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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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58. Rate constant for first order equation.


59. Half cell emf Calculation.

60.The isomerism in ethers.

61. Mechanism of aldol condensation.

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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62. Preparation of Oxalic acid.

63.


PART IV 4x10 = 40
64.a.Ionic radii determination.

64. b.Uses of silicones.

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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65 a.

65. b.Difference between chemical
bbbb reactions and nuclear reactions.


66 . a.Braggs spectrometer method.

66 . b. Repeated M 2012, M 2013
The preparation of colloides by
chemical methods.

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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67 .a.


67. b .

68.a. Difference between enantiomers
chanand diastereomers
5. Example d or l tartaric acid
d, l tartaric acid and meso tartaric acid.

68.b.Benzoic acid preparation from
1.Toluene
2.Phenyl cyanide
3.Carbon dioxide
69. a.Reduction of nitrobenzene in
chanalkaline medium.

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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
*

69. b. The structure of Glucose.


70.a.Hydroxy derivatives.

2 4
. /440
2 5 2 2 2
2
Con H SO K
C H OH CH CH H O = +
2 2 2 2 2
( ) CH CH H O O CH OH CH OH = + +
Compound
Molecular
formula
Name Structure
A C2H6O Ethanol

CH3 CH2OH

B C2H4 Ethylene
CH2= CH2
C C2H6O2
Ethylene
Glycol
CH2OH

CH2OH

70.b. d- block elements.

Compound
Chemical
formula
Name
A Ag Silver Metal
B AgNO3 Silver Nitrate
C AgNO2 Silver Nitrite
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Detailed Chemistry Key answer HSC March - 2014.

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Collected By: x+ V.CHANDRASEKARAN M.Sc., M.Ed.,(Mysore), M.Phil., Ph.D.*,(Che), PG Teacher in Chemistry,
Government Higher Secondary School, Athanur 636 301, Namakkal District.
*
: +9194444 98254 , : chandrache@gmail.com
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70.c. Carbonyl compounds.

Compound
Molecular
formula
Name Structure
A C7H6O
Benzaldehyde
C6H5CHO
B
Aldimine /
Shiffs base
C6H5CH=NC6H5
C

Benzoyl
chloride


70 . d .Electro chemistry I
The Ka of propionic acid is 1.34 x 10
-5
.
What is the P
H
of a solution containing 0.5 M
propionic acid and 0.5 M sodium
propionate?
Solution :
Ka = 1.34 x 10
5

P
Ka
= log Ka
= log (1.34 x 10
5
)
= 5 log10 10 log 1.34
= 4.87
P
H
= P
Ka
+ log
| |
| | acid
salt

= 4.87 + log
| |
| | 5 . 0
5 . 0

P
H
= 4.87

Space for rough work


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