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1
but first, an introduction...
Preliminary Chemistry Topic 3
WATER
What is this topic about?
To keep it as simple as possible, (K.I.S.S.) this topic involves the study of:
1. THE IMPORTANCE OF WATER
2. STRUCTURE, BONDING & PROPERTIES OF WATER
3. THE CHEMISTRY OF AQUEOUS SOLUTIONS
4. HEAT CAPACITY & CALORIMETRY
...all in the context of waters vital role in the natural world
Water... Amazing Stuff!
Its seems very strange to devote an entire topic
to just one simple compound.
But water is so important in so many ways...
WATER...
covers most of the Earth
controls weather and climate
carves landscapes
makes up 75% of all living things
dissolves things
absorbs heat
...and much more
all life on
Earth
depends on
WATER
WATER
is involved
in our
life &
leisure
Chemically...
You already know several different ways to
describe and visualise the water molecule...
H
2
O
H
H O
H
H
O
In this topic you will learn more about the
Chemical Bonding
within and between water molecules, and how
this is responsible for waters
many unique properties.
You will learn about the
Chemistry of Solubility
and how we measure concentrations, and
calculate with
Molarity of solutions.
Finally, as a lead-in to Topic 4, you will learn
about waters quite remarkable Heat Capacity,
and how we use it in the technique of
Calorimetry
for measuring energy changes
during chemical processes.
Usage & copying is permitted according to the
Site Licence Conditions only
Preliminary Chemistry Topic 3 Water
Copyright 2005-2009 keep it simple science
www.keepitsimplescience.com.au
keep it simple science
2
Temperature,
Heat Energy
&
Specific
Heat Capacity
Roles
of Water
on Earth
Basic Properties:
Density,
m.p. & b.p.
Polar
Covalent
Bonding
Calorimetry
& Calorimeters
Waters
Heat Capacity
& Life on Earth.
Endothermic
&
Exothermic
Changes
Heat
of
Solution
Measuring
Concentration;
Molarity
Ionic Solutions
&
Equations
How
Ionic & Polar
Substances
Dissolve
Bonding in Water
and Similar
Molecules
Dipoles
&
Hydrogen Bonds
Water as a
Solvent
Precipitation Reactions
WATER
Importance of
Water
Structure, Bonding
&
Properties
of Water
Chemistry of
Aqueous
Solutions
Heat Capacity
&
Calorimetry
CONCEPT DIAGRAM ( Mind Map ) OF TOPIC
Some students find that memorising the OUTLINE of a topic helps them learn and
remember the concepts and important facts. As you proceed through the topic,
come back to this page regularly to see how each bit fits the whole.
At the end of the notes you will find a blank version of this Mind Map to practise on.
Dynamic Equilibrium
in a
Saturated Solution
Water in the
Spheres of the Earth
In the Atmosphere, water is present as water
vapour, and as tiny liquid droplets in the clouds.
In percentage terms, water makes up between
1% and 5% of the air, varying with time, place
and weather.
In the Lithosphere, water makes up about 10%
of the solid Earth. Although solid rock and
minerals seem perfectly dry, there is often water
incorporated into the crystal lattice structure of
many minerals. When volcanoes erupt, a huge
amount of steam is released as the rocks are
melted.
The Hydrosphere is, of course, nearly all water.
Oceans contain about 3% dissolved salt, but the
ice caps, rivers and lakes are virtually 100%
water.
In Living Things, water makes up about 75% of
every life-form, but jellyfish or watermelons are
more like 95%
The Many Roles of Water on Earth
Water is essential in all living things because it is
a solvent for all the chemicals in a living cell, and
the medium in which all the chemical reactions occur.
a reactant or product in many biological reactions,
such as photosynthesis and cellular respiration.
a transport medium for carrying substances, such
as when food, oxygen, etc. are carried in the blood.
a shock-absorber and support structure. Many
plants and simple animals (e.g. worms) rely on water
pressure in their tissues to hold their body in shape.
Our brain and other body parts are cushioned by
water-based body fluids.
a habitat (place to live) for many species. Water
habitats have very stable temperatures because of
waters ability to absorb heat with little temperature
change.
Water is a major
factor in global
climate, weather
and the shaping of
landforms.
The water-cycle produces all rain, hail and
snowfall.
Water is the main agent of erosion, carving out
the valleys and wearing down the mountains,
creating the landscapes.
Water can absorb, transport and release vast
amounts of heat energy. The ocean currents
largely control global climates by
re-distributing heat world-wide.
For humans & civilization, water is a major
resource:
for drinking, cooking, washing and recreation.
for crop irrigation and farming.
in industry as a solvent, cleaning and
cooling agent.
for transport by boat and ship.
for generating hydro-electricity.
3
1. THE IMPORTANCE OF WATER
keep it simple science
+
+
+
+
O, N or F atom
H atom
Polar Covalent Bond
Hydrogen Bond
Intra-molecular
Covalent Bonds
within molecules
Inter-molecular
Hydrogen Bonds
between
molecules
It is the
HYDROGEN BONDING
between water molecules
which explains all of waters
weird and unusual properties
9
As well as the Density Anomaly and the very
high m.p. and b.p., water has other properties
whi ch, compared to other si mi l ar si ze
molecules, are quite extraordinary.
You may have done simple practical work to
demonstrate these:
Surface Tension is a phenomenon where
a liquid acts as if it has a skin at the surface.
In most liquids the effect is small, but water has
a relatively strong surface tension.
Technically, the metal is NOT floating.
The explanation is, as usual, hydrogen bonding.
Water mol ecul es have a network of forces
attracting them to each other. At the surface,
this network of force resists penetration and
can support objects. They will sink if pushed
through the skin .
Surface tension is also the reason that water
forms droplets.
The surface tension network of forces tries to
pull the droplet into a spherical shape. Gravity
often squashes them to form the typi cal
teardrop shape.
Viscosity is another phenomenon you may
have experimented with.
Vi scosi ty i s a measure of how sti cky or
thick a liquid is. Technically it is measured as
the resistance of a liquid to flowing through a
thin tube, but it can be thought of as how easy
or difficult it is for things to move through the
liquid.
You may have dropped
marbles into various liquids
and compared the rates at
which they fell, as a way to
observe viscosity differences.
Liquids like oil are very
viscous, so you may get the
idea that water has a low
viscosity. Yes it has,
compared to oil, but thats not
really a fair comparison.
In fact, when the viscosity of
water is compared to liquids
with similar size molecules,
waters viscosity is very high.
Why?
Its that hydrogen bonding
again...
The hydrogen bonds between
water molecules cause them
to cling to each other, and
make it much more difficult
for a moving object to move
through the liquid.
The high viscosity of water has had a major
impact on the evolution of any aquatic animals
who need to move quickly to catch food or
escape predators.
Fast moving aquatic animals are always
streamlined in shape and equipped with
powerful tails or flippers for propulsion.
keep it simple science
10
Water has a number of unusual
a)............................... including abnormally high
m.p & b.p. and the density anomaly . These are
all due to the b)................................. between the
molecules.
When an atom has 4 pairs of electrons around it
(as is the case in most covalent molecules) each
pai r tri es to stay c)........................
...................................... as possible. The result is
that each pair lies at one of the points of a
d).................................. This is why methane is a
tetrahedral shaped molecule. In ammonia, the
central e)........................... atom is bonded to 3
f)............................. atoms but al so has an
g)............................ electron pair occupying one
poi nt of the tetrahedron. Therefore, the
molecule is a h)................................. shape. In
water, the oxygen atom has 2 pai rs of
i)........................................ occupying 2 points of
the tetrahedron. This results in the molecule
being j)........................ (shape)
In a pure covalent bond, the electrons are
shared k)............................... An i oni c bond
occurs when the sharing is totally uneven so
that ions form. In between these extremes there
are l ).............................. coval ent bonds i n
which the sharing is m).................................. The
result is that n)............................ electric charges
(denoted by the greek letter ) are produced
on the mol ecul e because of the uneven
distribution of electrons.
The molecule is said to be a o).............................
because it has 2 electric poles.
The small charges on the o)..............................
are not as large as the charge on an ion, but do
create forces of p)............................. between
each mol ecul e and i ts nei ghbours. These
q)................. - .................... forces tend to hold
molecules together. These are the r)..............-
molecular forces which must be overcome for a
substance to change s)...........................
When hydrogen i s bonded to atoms of
t)......................., ....................... or ..........................
the forces are especially strong. These are
called u)................................ Bonds .
Water is such a molecule. The molecules are
strongl y attracted to each other by the
u)............................. bonds. This means that the
m.p. & b.p. are abnormal l y v)..................
compared to similar sized molecules.
Another result of the hydrogen bonding is that
water has a very strong
w)........................................ whi ch acts l i ke a
skin and can support small objects which will
x)............................. if placed under the surface.
Water al so has a rel ati vel y hi gh
y)........................... due to the way the molecules
cling to each other. Because of this, many
aquatic animals are z)........................................ to
allow easier movement through the water.
Worksheet 3 Structure & Bonding in Water
Fill in the blank spaces Student Name..........................................
Worksheet 4 Test Questions section 2
Student Name..........................................
Multiple Choice
1. The compound H
2
Se
can be represented by
the Lewis Formula shown.
The covalent molecule contains 2 unshared pairs of
electrons. You would expect its shape to be:
A. linear
B. tetrahedral
C. triangular pyramid
D. bent
2. Hydrogen Bonds are likely to occur within
substances i n whi ch hydrogen atoms are
bonded to atoms of:
A. oxygen, chlorine and carbon.
B. nitrogen, oxygen and fluorine.
C. sulfur, oxygen and chlorine.
D. fluorine, chlorine and bromine.
3. Water tends to form droplets because of its:
A. high viscosity.
B. high surface tension.
C. density anomaly
D. high boiling point.
H H Se
Longer Response Questions
Mark values shown are suggestions only, and are to
give you an idea of how detailed an answer is
appropriate. Answer on reverse if insufficient space.
4. (6 marks)
The diagram
represents 2 water
molecules.
a) Add labels to identify:
i) a covalent bond.
ii) a hydrogen bond.
iii) the partial charges (+ , -) on one molecule.
b) Explain what is meant by a polar covalent
bond .
c) Explain how the presence of hydrogen bonds
is responsible for waters relatively high m.p. &
b.p.
Usage & copying is permitted according to the
Site Licence Conditions only
Preliminary Chemistry Topic 3 Water
Copyright 2005-2009 keep it simple science
www.keepitsimplescience.com.au
keep it simple science
Water as a Solvent
Perhaps the mai n reason that water i s so
important to living things, and in the study of
Chemistry is that it is a great solvent.
This doesnt mean that everything will dissolve
in water... far from it. You may have done
experimental work to try to find any general
rules about which substances will, or will not,
dissolve in water. Generally, it all depends on
the type of bonding within the substance.
Ionic Compounds are (generally) soluble
in water, and all because water molecules are polar.
Ionic compounds are composed of a strong
i oni c crystal l atti ce. It requi res a hi gh
temperature to mel t thi s l atti ce, but water
mol ecul es can di ssol ve the crystal by
surrounding each ion and detaching it from the
lattice.
Notice how the the (+ve) ions are surrounded by
water molecules which are presenting the (-)
end of their dipole to the ion. The (-ve) ions are
surrounded by molecules presenting the (+)
end of the dipole.
With each ion surrounded by dozens of water
molecules, the attraction between the ions is
blanketed and the individual ions can no
longer get close enough to each other for their
charges to bond them together.
An ionic compound in solution is made up of
free moving, separate, hydrated ions.
Covalent Molecular Substances
may, or may not dissolve, in water depending on
their own polar nature, and on how large the
molecules are.
If the solute molecules are themselves polar,
they will generally dissolve, because the water
mol ecul es wi l l surround each mol ecul e,
attracted by dipole-dipole forces.
In the case of ethanol (CH
3
CH
2
OH) (alcohol) the
water molecules form hydrogen bonds with the
ethanol molecules which contain the highly
polar -OH chemical group.
There are many covalent molecules like this,
wi th -NH or -OH groups on the mol ecul e,
including all the alcohols and the sugars
such as sucrose (table sugar).
Small, non-polar covalent molecules such as
iodine (I
2
), oxygen (O
2
) and nitrogen (N
2
) will
dissolve in water, but only in small amounts...
we say they are sparingly soluble . These
molecules do not have any dipole charges to
attract a water mol ecul e and become
hydrated , but they are so small and have such
small dispersion forces holding them to each
other, that they can simply spread out, in small
numbers, among the water molecules.
Larger non-polar molecules will NOT dissolve in
water. They are too large to simply disperse
among the water molecules, and there are no
dipoles for the water molecules to associate
with or form hydrogen bonds.
These substances i ncl ude petrol , oi l s and
waxes, and are often descri bed as
hydrophobic (= water hating/fearing) because
they will not mix with water.
11
3. THE CHEMISTRY OF AQUEOUS SOLUTIONS
Na
+
Na
+
Cl
-
Cl
-
Na
+
Na
+
Cl
-
Na
+
Na
+
Cl
-
Na
+
Cl
-
Cl
-
Cl
-
Na
+
Ionic
Lattice
Lattice
disintegrating
Ions hydrated
(surrounded by water
molecules) and taken
into solution
+
+
+
+
+
+
+
+
Ethanol CH
3
CH
2
OH
Water molecules form
hydrogen bonds and
hydrate the molecule
so it dissolves
Dispersion Forces
are extremely weak attractive forces that exist
within all substances. Among non-polar molecules
they are the only inter-molecular forces acting to
hold the molecules together. This is why such
substances have very low m.p. & b.p. Knowledge
of how and why these forces arise is
not required for this course.
12
A Special Case to Know About...
Hydrogen Chloride
In the pure state, the compound hydrogen chloride
(HCl) is composed of small polar molecules:
Despite the dipole-dipole attractions, the m.p. &
b.p. are quite low, so pure HCl is a gas at room
temperature.
You would expect that these molecules would
dissolve in water, but they do much more than
just dissolve... they interact so strongly with
water that the molecules ionise and become
separate H
+
and Cl
-
ions.
Hydrogen chloride dissolved in water is, of
course, hydrochloric acid. This is more than just
dissolving in water because the molecule has
ionised... what was a polar covalent bond has
become ionic, due the the influence of the polar
water molecule.
This equation describes the dissolving of HCl
gas to form hydrochloric acid.
Water as a Solvent (continued)
Covalent Network Substances
l i ke the el ements Si l i con and Carbon, and
compounds l i ke si l i con di oxi de Si O
2
(the
mineral silica), are crystal lattices of atoms
bonded together covalently.
Since the bonds are non-polar, or only slightly
polar, water molecules are not attracted, and the
substance will NOT dissolve.
Compounds with Very Large Molecules
Living cells produce many very large molecules,
each containing perhaps tens of thousands of
atoms. Some, like cellulose (in plant cell walls)
contai n many pol ar groups, and water
molecules will be attracted and form hydrogen
bonds. However, the cellulose molecules are
often linked together by their own hydrogen
bonding, and covalent cross-linking , and it is
impossible for the huge molecules to be taken
into solution.
Cellulose is therefore insoluble, but is described
as being hydrophilic (= water loving) because
water will cling to it, wet it and soak into it very
well.
Some protein molecules will dissolve if they
have a folded, globular shape that allows
water molecules to surround them. This is the
case with enzyme proteins, which are dissolved
in the water inside a cell, or in the blood.
Other proteins, like keratin (in hair and skin) are
in long chains that cross-link to others. They will
not dissolve, but are hydrophilic.
Plastics, such as polyethylene, are composed of
huge molecules too. Most are non-polar, and
may be cross-linked with each other. They tend
to be insoluble in water and are generally
hydrophobic.
keep it simple science
+
+
HCl
(g)
molecule
Separate, hydrated ions
Cl
-
(aq)
and H
+
(aq)
HCl
(g)
H
+
(aq)
+ Cl
-
(aq)
(aq) means aqueous.
This is Latin for in water.
In an equation it means
dissolved and hydrated by
water molecules.
Molecules in the
gas state.
Like dissolves like ...
water is polar, so it dissolves:
ionic compounds
polar molecules (unless too large)
very small non-polar molecules (sparingly)
13
Ionic Solutions
When an ionic compound dissolves in water, the crystal
lattice disintegrates and the (+ve) and (-ve) ions become
separately hydrated to form the solution.
The positive (+ve) ions are collectively called
cations . Negative (-ve) ions are anions .
You need to be able to write an equation to
describe the dissolving of any ionic compound.
More examples:
Notice that the equation must balance in terms
of the ratio of the ions. In this case there are 2
nitrate ions for each magnesium ion. Notice
also that the total of (+ve) charges is the same
as the total of (-ve) charges.
Dilute, Concentrated, Saturated
If you dissolved a pinch of salt in a bucket of
water this is a dilute solution, meaning that it
contains very little solute compared to the
amount of solvent.
If you dissolved a heaped spoonful of salt in a glass
of water the solution is concentrated ... it has quite
a lot of solute compared to the amount of solvent.
There is a limit to how much solute can be dissolved
in a given amount of solvent. When this limit is
reached, and the solution contains as much solute as
it can hold, it is said to be saturated .
Different compounds have different solubilities,
and this can change with temperature, but as an
exampl e, at 25
o
C a sal t-water sol uti on i s
saturated when about 36g of salt have dissolved
in each 100mL of water. We say the solubility of
salt is 36 g/100mL, or simply 36 % m/v.
( % m/v means percentage mass to volume
and refers to the measurement of grams (mass)
in 100mL (volume).
This is not the only way we can measure the
concentration of a solution...
the Mole is Back!! (soon)
Dynamic Equilibrium
in a Saturated Solution
If you keep adding and stirring salt into water
until the solution is saturated, you reach a
dynamic equilibrium between the ions still in
an undissolved, solid, crystal lattice, and those
in the solution as separate, hydrated ions.
For si mpl i ci ty i n thi s di agram, the water
molecules have been left out.
Since dissolving and precipitating occur at the
same rate, the concentration of the solution
does not change, and the amount of
undissolved solid remains the same. At the
macroscopic level, it seems that nothing is
happening, but down at the atomic level things
are moving... ions constantly dissolving into
solution and precipitating back out of it again.
This is known as a Dynamic Equilibrium
This double-arrow symbol indicates that the
reaction is occurring in both directions, at the
same rate, in dynamic equilibrium.
Many chemical reactions
reach this state.
keep it simple science
17
Mass, Volume & Concentration in Precipitation Reactions
Armed with a knowledge of molarity you can now link calculations involving concentration of
solutions to masses and even gas volume quantities.
Example Problem 1
15.00mL of 0.3055 molL
-1
solution of lead(II) nitrate
was treated as follows:
An excess of potassium iodide solution was added,
causing a precipitate. The solid precipitate was
collected by filtration, dried and then weighed.
What substance, and what mass, was collected?
(Note: an excess of something means that the
quantity added was more than enough to ensure a
complete reaction)
Solution
Step 1: use the Solubility Rules to figure out what
substance preci pi tated, then wri te a bal anced
equation for the reaction.
Pb(NO
3
)
2(aq)
+ 2KI
(aq)
PbI
2(s)
+ 2KNO
3(aq)
Step 2: find how many moles of Pb(NO
3
)
2
were
present in the 15mL (0.015 L) of solution.
c = n/V, so n = cV = 0.3055 x 0.01500
n(Pb(NO
3
)
2
) = 4.5825 x 10
-3
mol
Step 3: fi nd how many mol es of PbI
2
were
precipitated.
The balanced equation shows the mole ratio is 1:1,
so n(PbI
2
) = 4.5825 x 10
-3
mol
Step 4: convert moles to mass. MM(PbI
2
) = 461.0g
n = m/MM, so m = n x MM
= 4.5825x10
-3
x 461.0
m(PbI
2
) = 2.113g
Note:
The working above assumes 100% precipitation of
the lead ions. Technically, a small fraction of the
lead ions would stay in the solution, so not quite all
of it would precipitate. However, the solubility of
PbI
2
is very low, so for simplicity (K.I.S.S.) were
assuming complete precipitation.
Example Problem 2
To measure the concentration of salt in a
40.0mL seawater sample, an excess of silver
nitrate solution was added to precipitate all
the chl ori de i ons. The preci pi tate was
collected by filtration, dried and weighed. Its
mass was 2.76g
a) What substance was precipitated?
b) Write a net ionic equation for the reaction.
c) Write a full ionic equation for the reaction.
d) Calculate the number of moles of
precipitate collected.
e) How many moles of chloride ions must
have been in the seawater sample?
f) Calculate the molar concentration of salt in
the seawater.
Solution
a) From Solubility Rules : Silver chloride, AgCl
b) Ag
+
(aq)
+ Cl
-
(aq)
AgCl
(s)
c) Ag
+
(aq)
+ NO
3
-
(aq)
+ Na
+
(aq)
+ Cl
-
(aq)
AgCl
(s)
+ NO
3
-
(aq)
+ Na
+
(aq)
d) n = m/MM MM(AgCl) = 143.35g
= 2.76 / 143.35
n(AgCl) = 0.0193 mol
e) Mole ratio in equation is 1:1
n(Cl
-
) = 0.0193 mol
f) c = n/V
= 0.0193 / 0.040 (40mL = 0.040 L)
c(NaCl) = 0.481 molL
-1
Example Problem 3 A little revision of Topic 2
What volume of hydrogen gas (measured at SLC)
could be produced from the complete reaction of
50.0mL of 1.50 mol L
-1
hydrochl ori c aci d wi th
magnesium?
Solution
As usual, start with a balanced equation:
Mg
(s)
+ 2HCl
(aq)
H
2(g)
+ MgCl
2(aq)
Moles of HCl present in the solution:
c = n/V, so n(HCl) = cV = 1.50 x 0.050 = 0.075 mol
Moles of H
2
: equation shows mole ratio = 2:1
n(H
2
) = 0.075/2 = 0.0375 mol
Volume of H
2
: (remember 1 mole = 24.8 L at SLC)
vol(H
2
) = 0.0375 x 24.8 = 0.930 L (930 mL)
WORKSHEET at end of section
Usage & copying is permitted according to the
Site Licence Conditions only
Write ionic equations (showing states) for the
dissolving of each compound in water.
a) potassium bromide
b) calcium sulfate
c) lithium nitrate
d) magnesium iodide
18
keep it simple science
23
Calorimetry
Calorimetry is a technique used to measure the
energy change occurri ng duri ng chemi cal
processes. The word i s deri ved from the
calorie , a unit for heat energy no longer in
use. The equi pment used to make energy
measurements is called a calorimeter .
(Since we now use joules for our energy unit,
maybe we should call it a joulemeter )
Since many chemical processes occur in water,
and because water has such a high Specific
Heat Capacity (i.e. it can absorb lots of energy
with little temperature change) calorimetry often
uses water as the working fluid or medium
used to absorb the heat energy.
Exothermic Reactions ( Exo = to go out)
are the reactions that produce and release
energy.
The amount of energy involved is the delta-H
for the process, and is measured per mole of the
substance(s) involved. When the chemicals lose
energy, the temperature in a calorimeter rises,
because the energy release heats up the water
i n the cal ori meter. Thi s i s why, when the
temperature ri ses, the energy quanti ty i s
considered negative... the chemicals involved
have LOST this amount of heat energy.
Endothermic Reactions ( Endo = to go in)
are the reactions that absorb energy... those
where you must suppl y energy to make i t
happen.
The delta-H for this change is considered
positive because the chemicals have gained
energy. The temp. change is negative, because
the calorimeter temp. drops.
Simple Laboratory
Calorimeter
Thermometer
measures
temperature change
Copper Beaker
reaction container
Polystyrene body
and lid prevents heat
loss/gain with the
surroundings
Prac. Work: Heat of Solution
You may have carri ed out experi ments to
measure the energy change that occurs when
ionic compounds dissolve in water.
General Method:
Use a calorimeter to measure the temperature
change in a measured mass of water, when a
measured mass of a solid dissolves.
You can then calculate:
the energy change occurring
(for the quantities used) and then
the energy change per gram of solute
and then
the energy change per mole of solute.
Typical Results for dissolving Potassium hydroxide.
Mass of water placed in calorimeter = 100g
Mass of potassium hydroxide dissolved = 4.50g
Initial temperature of water = 21
o
C
Final temperature of solution, after dissolving = 28
o
C
Temperature change, T = 7.0
o
C
Calculations:
H = - mCT
= - (100 + 4.5) x 4.18 x 7.0
= - 3, 058 J for the dissolving of 4.50g
Energy per gram: H = - 3,058/4.50 = -679 J per gram
Energy per mole: MM(KOH) = 56.1g
H = -679 x 56.1 = - 38,100 J per mole
Heat of Solution = - 38.1 kJmol
-1
(exothermic)
Total mass in calorimeter
Solution is mostly water
Reactants
Energy Level
E
n
e
r
g
y
C
o
n
t
e
n
t
Products have
MORE energy
Energy
absorbed by
chemicals
during
reaction
Reactants
Energy Level
E
n
e
r
g
y
C
o
n
t
e
n
t
Products have
LESS energy
Energy
released by
chemicals
during
reaction
= H
negative
= H
positive
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Preliminary Chemistry Topic 3 Water
Copyright 2005-2009 keep it simple science
www.keepitsimplescience.com.au
keep it simple science
24
Thermal Pollution
Some i ndustri es, especi al l y coal -burni ng or
nuclear power stations produce large amounts
of waste heat.
In some places, these plants are situated beside
lakes or the sea so that the water can be used
for cooling the equipment. Typically, lake water
is pumped through the equipment, then hot
water discharged back into the lake.
This is
thermal
pollution,
and is very
destructive
to aquatic
habitats.
Effect of Extra Heat on Aquatic Life
The main problem is a matter of solubility.
Oxygen, and other gases, are only slightly
soluble in water. Aquatic organisms are totally
dependent on thi s l ow concentrati on of
dissolved gases for their survival.
The problem is, that the solubility of gases
decreases as the temperature rises. If the water
temperature ri ses by as l i ttl e as 5
o
C, the
dissolved oxygen concentration drops by 20%
and fish begin to suffocate.
Not only that, but increased temperatures can
interfer with the normal breeding cycles and
alter the delicate balance between populations
of food plants, disease microbes, parasites, etc.
Habitat destroyed!
Heat of Solution is the common name
for the energy change that occurs when 1 mole
of a solute dissolves in water.
H
sol
is negative if energy is released.
(exothermic: the calorimeter temperature rises)
Examples: soluble hydroxides (e.g. NaOH, KOH)
H
sol
is positive if energy is absorbed.
(endothermic: the calorimeter temperature falls)
Examples: ammonium nitrate (NH
4
NO
3
),
ammonium chloride (NH
4
Cl)
Limitations of Calorimetry
When you use a simple calorimeter to measure an
energy change in the laboratory, there are a number
of assumptions and approximations involved.
It is assumed that the calorimeter itself does not
absorb a significant amount of the heat energy of the
reaction. This source of error is minimised by using
a copper reaction vessel, since the very low Specific
Heat Capacity of copper means it absorbs little
energy.
It is assumed that there is no heat lost or gained
between the calorimeter and the surroundings. This
source of error can be minimised by good heat
insulation of the calorimeter.
It is assumed that the Specific Heat Capacity of the
solution reacting in the calorimeter is the same as
water. i.e. C = 4.18 J/
o
C/g. For many solutions this is
not quite true, but (generally) the error this causes is
very small.
A serious limitation of many calorimetry experiments
in school laboratories is the poor precision of the
usual lab. thermometers. Usually these can only be
read to the nearest 0.5
o
C, and if the temperature
change is only a few degrees, the % error is huge.
Seri ous cal ori metry needs thermometers wi th a
precision of at least 0.1
o
C.
Waters Heat Capacity
& Life on Earth
The fact that water has a remarkably high Specific
Heat Capacity is of enormous significance to weather,
climate and life on Earth.
It means that, on a hot day, the ocean or a lake
can absorb a large amount of energy from the
Sun without much temperature change. The air
and the land may get very hot, but the water
temperature changes very little. In cold weather,
the air and land can get really cold, but the water
changes only a little.
This means that water habitats have very stable
temperatures and do not change much from day
to night, or even summer to winter.
Aquatic
organisms do
not need
complex
temperature
control
mechanisms
because their
habitat remains
quite stable.
More i mportantl y, the oceans absorb and
transport (via ocean currents) huge quantities of
heat from the tropics towards the poles. This
has the effect of cooling the tropical areas and
warming the temperate regions, and generally
evening-out the Earths temperature.
Without water, very little of the Earth would
have l i veabl e temperatures. Wi thout the
moderating effect of water, the tropics would
be too hot for life, and the temperate regions
would be too cold.
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Temperature i s a measure of the
average a)........................... energy of the
particles within a substance. When heat
is added, the particles b)....................
....................
However, some substances requi re
more heat energy than others for the
same temperature change. Thi s
difference is measured by the property
of c)...........................................................
which has units of d)...............................
Water has a very e).............................
(high/low) value.
The amount of heat energy involved in
any change is given by the formula
f).......................................
A g).............................. is a device for
measuring energy changes. Water is
often used as the worki ng fl ui d
because of i ts hi gh h).................
.................... Capacity.
i )............-thermi c changes rel ease
energy, so the temperature i n the
cal ori meter j ).......................... The
chemi cal s i n the reacti on have
k).......................... energy, so the energy
value is considered l)........................ (+/-)
m)..........-thermi c changes absorb
energy, so the temperature i n the
cal ori meter n).......................... The
chemi cal s i n the reacti on have
o)........................ energy, so the energy
value is considered p)...................... (+/-)
The energy change i nvol ved i n
di ssol vi ng a sol uti on i s cal l ed the
q).............................................................
25
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28
CONCEPT DIAGRAM ( Mind Map ) OF TOPIC
Some students find that memorising the OUTLINE of a topic helps them learn and
remember the concepts and important facts. Practise on this blank version.
WATER
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29
Answer Section
Worksheet 1
a) water vapour b) clouds
c) 10% d) crystal
e) hydrosphere f) oceans
g) ice caps h) 75%
i) solvent j) biological chemical reactions
k) transports l) supports and cushions
m) habitat n) stable
o) absorb a lot of heat p) climate
q) erosion r) cooking
s) recreation t) irrigation
u) solvent v) hydro-electricity
w) 0
o
C x) 100
o
C
y) 1.00 g/mL z) less
aa) closer ab) lattice
Worksheet 2
1.a) 8.8 g/cm
3
b) 1.2 g/cm
3
c) 4.8 cm
3
d) 0.72 g/cm
3
e) 264g f) 5.7 cm
3
2.
a) Substances B & F, because they have the same
density.
b) Substance D, because density is less than water.
3. D 4. C
5.
a) It is the solvent for life chemicals.
It transports substances in blood.
b) Main agent of erosion.
Ocean currents distribute heat... controls climate.
c) Crop irrigation
Making hydro-electricity
6.
a) For most substances, the solid has a higher
density than the liquid. Water is the opposite.
b) Water ice is a molecular lattice in which the
molecules are held in a regular array by hydrogen
bonding. When ice melts, the molecules can move
around, but the strong hydrogen bonds still act.
Mol ecul es are attracted so strongl y that they
wriggle in even closer to each other than in the
solid lattice arrangement. This results in a smaller
volume, and a higher density.
Worksheet 3
a) properties b) forces/bonding/H-bonds
c) as far apart d) tetrahedron
e) nitrogen f) hydrogen
g) unshared h) pyramid
i) unshared electrons j) bent
k) evenly l) polar
m) uneven n) partial
o) dipole p) attraction
q) dipole-dipole r) inter-
s) state
t) oxygen, nitrogen or fluorine
u) Hydrogen v) high
w) surface tension x) sink
y) viscosity z) streamlined
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