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xy
x
y / n
x
(
x
(
/ n
.12
b =
/ na
/ n
.<2
n-the number o! given values " or y.
#! $e $ant to kno$ ho$ big is the derivative, it is necessary to state the value o!
agreement bet$een calculated and evaluated values y characterized by the 4uantity:
r
(
%
[
xy
/ n
]
(
[
x
(
x
(
/ n
] [
y
(
y
(
/ n
]
.+2
6he ro"imity o! r
(
to one means that our linear regression coordinates $ell $ith
e"erimental oints.
?et us !ind by the method o! selection the !unction y % a & b'" & c'"
(
describing the
deendence multilicity % !.?2 and E % !.?2 in best $ay, in general this !unction describes
this deendence !or any chemical bonds.
?et us make some trans!ormations !or the !unction y % a & b'" & c'"
(
, $e accet
L % ,'",
` %
yy
,
,/ x,/ x
,
, b
,
% b & c/ x
,
,
than $eall receive: ` % b
,
& cL, that is the simle line
e4uality, than
,B
c =
,/ xY
,/ x
Y / n
,/ x
(
,/ x
(
/ n
.D2
b
,
%
Y
/ nc
,/ x
/ n .32
nYthe number o! given value `.
?et us !ind a !rom the e4uality: by % na & bb.,'"2 & cb.,'"
(
2, .C2
$hen n % B.
?et us !ind no$ multilicity % !.?2 !or )c), )^), )d).
6able ,. )alculation o! ratios !or relation Tultilicity % !.?2.
,'" ,'"J
yy
,
,/ x,/ x
,
,/ x
yy
,
,/ x,/ x
,
yy
,
,/ x,/ x
,
b
,
% b & c'"
,
` % b
,
& cL
*s usual:
c =
,/ xY
,/ x
Y / n
,/ x
(
,/ x
(
/ n
.D2
,<
b
,
%
Y
/ nc
,/ x
/ n .32
nYthe number o! given value `.
?et us calculate a !rom the e4uation by % na & bb.,'"2 & cb.,'"
(
2, .C2
$hen n % B.
6able (. )alculation o! ratios !or relation E % !.?2.
,'" ,'"J
yy
,
,/ x,/ x
,
,/ x
yy
,
,/ x,/ x
,