---

: , 2007.

No.

Date

10/1~10/5

2
3
4
5
6
7
8
9
10
11
12
13
14

10/8~10/12
10/15~10/19
10/22~10/26
10/29~11/2
11/5~11/9
11/12~11/16
11/19~11/23
11/26~11/30
12/3~12/7
12/10~12/14
12/17~12/21
12/24~12/28
12/30~1/4

Topic
Check in &
(exp.1)
-(exp.2)
(exp.7)
(exp.9)
&(exp.10)

(exp.17)
(exp.18)
-(exp.29)
(exp.30)
(exp.39)
Check out
final exam.

Prototype:

( A):

(?)

Results 1:
(1a)

(one-pot reaction)

()

one-pot reaction

20mL
4mL
(0.1M)
(0.1M)
50mL
20mL
(0.1M)
(0.1M)

40th IChO
(0.1M)
(0.1M)
(0.1M)
(6M)

(0.1M)
(250mL)

20mL
20mL
20mL
50mL

50mL
1
1
1

50mL

1 2

1. *1 0.1M 20mL

Ag+

2. 01.M 4mL

Ag2CO3

Ag2CO3
2Ag+ + HCO3- Ag2CO3(s) + H+
Ag2CO3Ksp= 8.1x10-12
3. 2 300mL
0.1M 20mL
Ag2O

2Ag+ + 2OH-

Ag2O(s) + H2O
Ag2OKsp = 2x10-8

4. 0.1M 50mL

AgCl

Ag2O(s) + 2Cl- + H2O AgCl(s) + 2OH AgClKsp=1.8x1010

5. 6M 50mL

[Ag(NH3)2]+
2

40th IChO

AgCl(s) + 2NH3 [Ag(NH3)2]+ + Cl [Ag(NH3)2]+ =6.2x108

6. 0.1M 20mL
*2AgBr

[Ag(NH3)2]+ + Br- AgBr(s) + 2NH3

AgBrKsp=4.9x1013
7. 0.1M 50mL

[Ag(S2O3)2]3 AgBr(s)+2S2O32 [Ag(S2O3)2]3+Br

8. 0.1M 20mL

*3AgI

[Ag(S2O3)2]3- + I- AgI(s) + 2S2O32 AgIKsp=8.3x1017

9. 0.1M 20mL

Ag2S
AgI(s) + S2- Ag2S (s) + 2I Ag2SKsp=7.1x1050

(0.1M)
(2M)

75mL
25mL
0.2mL

(2.0M)
(6M)

0.3mL
5mL
50g

40th IChO

10. 300mL 75mL 0.1M 25mL

*4Cu2+

11. 2M 5 0.2mL

Cu(OH)2

Cu2+ + 2OH- Cu(OH)2(s)

12. 2M 7 0.3mL

Cu2+

Cu(OH)2(s) + 2HNO3

13. 50g*5

Cu2+ + 2 NO3- + 2H2O

[CuCl4]2
Cu2+ + 4NaCl (s) [CuCl4]2- + 4Na+

14. 6M 5mL*6

[Cu(NH3)4]2+

[CuCl4]2- + 4NH3

[Cu(NH3)4]2+ + 4Cl-

*1 20mL

*2 AgBr
4

40th IChO

*3 KCN AgI one-pot reaction

KCN
*4 (CuSO4)
*5
*6 Cu2+
NH3 > Cl- > H2O
NH3

Results 2: 246
(+)()
( 26 )
1. 17.

Total

64
129
46
6
1
246

48
86
29
3
0
166

0.75
0.67
0.63
0.50
0.00

16
43
17
3
1
80

0.25
0.33
0.37
0.50
1.00

2. 13.

Total

64
129
46
6
1
246

48
86
28
3
1
166

0.75
0.67
0.61
0.50
1.00

16
43
18
3
0
80

0.25
0.33
0.39
0.50
0.00

3. 5.

Total

62
113
47
16
8
246

46
80
23
11
6
166

0.74
0.71
0.49
0.69
0.75

16
33
24
5
2
80

0.26
0.29
0.51
0.31
0.25

4. 14.

40th IChO

59
44
0.75
15
0.25

142
92
0.65
50
0.35

39
24
0.62
15
0.38

5
5
1.00
0
0.00

5. 24.

Total
245
165
80

58
43
0.74
15
0.26

146
96
0.66
50
0.34

37
23
0.62
14
0.38

3
2
0.67
1
0.33

6. 9.

0
0
#DIV/0!
0
#DIV/0!

1
1
1.00
0
0.00

Total
245
165
80

47
38
0.81
9
0.19

118
84
0.71
34
0.29

69
37
0.54
32
0.46

10
5
0.50
5
0.50

1
1
1.00
0
0.00

Total
245
165
80

7. 8.

41
123
66
15
1

37
84
36
8
1

0.90
0.68
0.55
0.53
1.00

4
39
30
7
0

0.10
0.32
0.45
0.47
0.00

8. 1.

Total
246
166
80

45

119

65

13

Total
246

40th IChO

35
0.78
10
0.22

78
0.66
41
0.34

41
0.63
24
0.37

8
0.62
5
0.38

4
1.00
0
0.00

166
80

9. 7.

41
122
68
13
1

34
75
46
9
1

0.83
0.61
0.68
0.69
1.00

7
47
22
4
0

0.17
0.39
0.32
0.31
0.00

Total
245
165
80

10. 15.

Total

41
152
47
5
1
246

31
94
36
4
1
166

0.76
0.62
0.77
0.80
1.00

10
58
11
1
0
80

0.24
0.38
0.23
0.20
0.00

11. 3.

Total

37
133
61
14
1
246

31
83
40
11
1
166

0.84
0.62
0.66
0.79
1.00

6
50
21
3
0
80

0.16
0.38
0.34
0.21
0.00

12. 26.

43
29
0.67
14
0.33

112
81
0.72
31
0.28

76
43
0.57
33
0.43

10
8
0.80
2
0.20

4
4
1.00
0
0.00

Total
245
165
80

40th IChO

13. 2.

Total

25
112
79
27
2
245

20
77
45
21
2
165

0.80
0.69
0.57
0.78
1.00

5
35
34
6
0
80

0.20
0.31
0.43
0.22
0.00

14. 20.

Total

23
118
78
22
3
244

20
76
50
16
3
165

0.87
0.64
0.64
0.73
1.00

3
42
28
6
0
79

0.13
0.36
0.36
0.27
0.00

15. 18.

Total

26
74
100
38
8
246

16
47
67
28
7
165

0.62
0.64
0.67
0.74
0.88

9
27
33
10
1
80

0.35
0.36
0.33
0.26
0.13

----------------------------------------------------------------------------16. 4.

Total

3
14
37
145
47
246

3
9
25
93
36
166

1.00
0.64
0.68
0.64
0.77

0
5
12
52
11
80

0.00
0.36
0.32
0.36
0.23
8

40th IChO

17. 19.

Total

1
27
79
95
43
245

1
19
48
59
38
165

1.00
0.70
0.61
0.62
0.88

0
8
31
36
5
80

0.00
0.30
0.39
0.38
0.12

18. 6.

2
7
74
108
55

2
5
47
73
39

1.00
0.71
0.64
0.68
0.71

0
2
27
35
16

0.00
0.29
0.36
0.32
0.29

Total
246
166
80

19. 16.

Total

0
4
26
161
55
246

0
3
21
101
41
166
#DIV/0!
0.75
0.81
0.63
0.75

0
1
5
60
14
80
#DIV/0!
0.25
0.19
0.37
0.25

20. 25.

Total

3
19
54
109
60
245

3
15
34
70
43
165

1.00
0.79
0.63
0.64
0.72

0
4
20
39
17
80

0.00
0.21
0.37
0.36
0.28

40th IChO

21. 10.

0
13
39
138
55

0
11
25
85
44
#DIV/0!
0.85
0.64
0.62
0.80

0
2
14
53
11
#DIV/0!
0.15
0.36
0.38
0.20

Total
245
165
80

22. 23.

Total

2
21
43
108
71
245

2
18
29
63
53
165

1.00
0.86
0.67
0.58
0.75

0
3
14
45
18
80

0.00
0.14
0.33
0.42
0.25

23. 21.

Total

0
5
28
142
70
245

0
5
18
88
54
165
#DIV/0!
1.00
0.64
0.62
0.77

0
0
10
54
16
80
#DIV/0!
0.00
0.36
0.38
0.23

24. 22.

Total

2
12
25
134
72
245

2
10
15
81
57
165

1.00
0.83
0.60
0.60
0.79

0
2
10
53
15
80

0.00
0.17
0.40
0.40
0.21

25. 11.

Total
10

40th IChO

0
0
#DIV/0!
0
#DIV/0!

4
2
0.50
2
0.50

22
15
0.68
7
0.32

136
90
0.66
46
0.34

84
59
0.70
25
0.30

246
166
80

26. 12.

Total

4
18
26
110
87
245

4
12
18
70
61
165

1.00
0.67
0.69
0.64
0.70

0
6
8
40
26
80

0.00
0.33
0.31
0.36
0.30

:
(B):: (1b) : 4 0

th

2008 IChO 3

5 0 0 C

(Pumice stone)

:
H+, NH4+, Li+, Na+, Mg2+, Al3+, K+, Ca2+, Cr3+, Mn2+, Fe2+, Fe3+,
Co2+, Ni2+, Cu2+, Zn2+, Sr2+, Ag+, Sn2+, Sn4+, Sb3+, Ba2+, Pb2+, Bi3+
OH, CO32, HCO3, CH3COO, C2O42, NO2, NO3, F, PO43,
HPO42, H2PO4, SO42, HSO4, S2, HS, Cl, ClO4, MnO4, Br, I
pH

11

40th IChO

1-8

:
5%

1-2

12

40th IChO

25 C
CH3

N Li N M A K C C M F F C N C Z S A S S S B P B
H
1.

CO
C2O

NO2

0.

4 R

NO3

0.

4. 1.

SO42PO4

HP

( (
H

0.
2

1. H H

O
H2P

O
ClO4

1. 2 1.

0 R R

0.
8

0.
1

(Y

(Y
H

R (Y

Mn

H R

0. R

R R

R
0.

((
1.

(Y 0

O
Br
I

H R
( )
( B ) = ( P ) =
(W) = ((Y)) = (Y) =

Solution
8

Country

7
13

40th IChO

colour
Blue

AgNO3

KHCO3

NH4ClO4

NaOH

NaHS

Pb(OAc)2

BaI2

MgSO4

Green

Pb(OAc)2

NH4ClO4

NaOH

NaHS

MgSO4

KHCO3

AgNO3

BaI2

Ivory

NH4ClO4

Pb(OAc)2

KHCO3

BaI2

AgNO3

MgSO4

NaHS

NaOH

NaHS

MgSO4

BaI2

NH4ClO4

Pb(OAc)2

AgNO3

NaOH

KHCO3

BaI2

NaHS

MgSO4

AgNO3

NaOH

NH4ClO4

KHCO3

Pb(OAc)2

Pink

MgSO4

NaOH

AgNO3

Pb(OAc)2

KHCO3

BaI2

NH4ClO4

NaHS

Red

NaOH

BaI2

Pb(OAc)2

KHCO3

NH4ClO4

NaHS

MgSO4

AgNO3

Yellow

KHCO3

AgNO3

NaHS

MgSO4

BaI2

NaOH

Pb(OAc)2

NH4ClO4

L.Blue
L.Green

NaHS
1367 8 pH 5-6
2 pH9 4 5 pH11
Cr3+Fe2+Fe3+Co2+Ni2+
Cu2+ MnO4 Mn2+

H+Sn2+Sn4+Sb3+Bi3+ HSO4

NH4+Li+Na+Mg2+Al3+K+Ca2+Mn2+Zn2+Sr2+Ag
Ba2+Pb2+
OHCO32HCO3CH3COOC2O42NO2NO3F
PO43HPO42H2PO4SO42S2HSClClO4Br
I

14

40th IChO

= = no change

AgNO3

KHCO3

3
NH4ClO

NaOH NaHS

Pb(OAc
MgSO
BaI2
)2
4

white
crystals
(*)

black

AgNO3
light
yellow

2
KHCO3

3
NH4ClO

neutral,
odourles
s
no
change

boiling:

4
NaOH

5
NaHS

brownblack

basic,
no
odour of
change
ammoni
a

black

boiling:

solution
turns
acidic

no
basic,
no
odour of chang
change
NH3,
e
H2S
white

no
white

Pb(OAc crystals neutral, change

)2
odourles
s

white

15

40th IChO

white

yellow

BaI2

8
MgSO4

white
crystals

(**)

no
change
(***)

no
no
no
chang chang yellow
change
e
e
no
change

no
chang

white
white
e
(****)

whit
e

(*): pH NH3
(**): 2
(***):
(****): H2S
2 Ag+ + 2 HCO3 = Ag2CO3 + CO2 + H2O
Pb2+ + 2 HCO3 = PbCO3 + CO2 + H2O
Ba2+ + 2 HCO3 = BaCO3 + CO2 + H2O
Mg2+ + 2 HCO3 = MgCO3 + CO2 + H2O

Ag+ + I = AgI;
CH3COOAg

2 Ag+ + SO42 = Ag2SO4;

Pb2+ + 2 OH = Pb(OH)2; Pb2+ + 2 I = PbI2;

K+ + ClO4 = KClO4;
Mg(OH)2

Ag+ + CH3COO =
Pb2+ + SO42 = PbSO4

Ba2+ + SO42 = BaSO4;

Mg2+ + 2 OH =

2 Ag+ + 2 OH = Ag2O + H2O

2 Ag+ + HS = Ag2S + H+; Pb2+ + HS = PbS + H+;
CH3COOH

CH3COO + H+ =

NH4+ + OH = NH3 + H2O

NH4+ + HCO3 = NH3 + CO2 + H2O

2 CO2 2
CO32 HCO3

16

40th IChO

3 Ag2OAg2S PbS pH
1 Ag+6 Pb2+4 OH5

5 5 1 6
pH 1 5
HS
2 Ag+ Pb2+ CO2 HCO3

3 4 4 NH3 3 NH4+
2+4 2 4 Na+ K+
2+5 5
3 Ag+3
2 3
ClO42 K+
4 NH4ClO4 4 Na+
5 NH4ClO4 (K+) KHCO3 NaOH (Li+) 5
Na+
7 NaOH KHCO3 7
1 6 7 7
Ba2+ I
8 OH HS 2A
8 BaI2 Ba2+ 8
8 SO42HCO3 H2PO4
8 Ag+
8 HCO3 H2PO4 8 SO42
Mg2+
6 CH3COONO2NO3 ClO4
6 6 HS
1 6 6
Ag+ NH4ClO4
N2 HS
6 CH3COO
NO3F ClO4 NaOH
1 Ag2O
17

40th IChO

1 BaI2
F KClO4 KHCO3
1
NO3 ClO4

-------------------------------------------------------------------------------------------------

:
1. -
(

2010

460 2010/11 //2010 // )-----

-2010 2010/11/17

-2010 2010/11/17

2010 2010/11/16

18

40th IChO

------------------------------------------------------ 2010
9
19 67

19

40th IChO

20

40th IChO

21

40th IChO

3,200 2,654 83

----------------------------------------------------------------------------------22

40th IChO

2.

!!!

109> 108> 106> 105

1. 109
2., 107
3.,, 106
4. 106
5., 105
6. 105
7. 105
11. 103
16. 100

107
105
105
104
21

http://en.wikipedia.org/wiki/IQ_and_Global_Inequality

23

40th IChO

http://www.isteve.com/IQ_Table.htm
http://www.v-weiss.de/calibration.html
.( 106)
15 . 15 .
5 . 105 . 106. 1
5 . 108..
1 . 13 . 10%. 120.
1.3 = +=
21
?. 82 ? 60~70

82 ?
:
105.
108!/.

97. 87. 82
.18 ..

..
.==>:
20 . 2030
!
3 .. 2 ..
3 ..
.==> CHAIWAN

3..

? ,
,

, ,
?
,

24

40th IChO

10
: 2010-9-20 11:45 | : - | : |

60 ""

;
.

25

40th IChO

""

""
.

26

40th IChO

27

40th IChO

:
" "" " " "

28

40th IChO

!
29

40th IChO

30