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I
Accessions
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UNIVERSITY OF CALIFORNIA
LIBRARY
OF THE
PEPfrttTMENT 'OP
Pll'I'JieS
Received
\ccessions No..../...3..&..
Hi
Book No
HEAT.
HEAT
BY
P. G.
Eonfcon
MACMILLAN AND
CO.
/rvPTtyc'
'
'OTi'T^
1892.
PREFACE.
IT was with considerable hesitation that I sanctioned the
number of copies
Some of my reasons
of the
first
be found
will
in the
work was
is,
ation
can reissue
find I
the
it
now
442.
make
I
these passages
difficulty
more
and
have endeavoured
clear.
theory.
in the
COLLEGE, EDINBURGH,
November 2nd,
1891.
673242
G.
TAIT.
large
it
in the
form of an elementary
portion of
part of which
was put
in type,
in
at the
In 1876
the
greater
Some
criticism.
when
an evening discourse
treatise.
the
had
of the earlier
British
Association Meeting
1876.
examination of the
leisure.
have
nearly as possible
at
Thermometers, interfered
writing by occupying most of my
Challenger
my
last
on the
managed
lines laid
to
finish
down
the book, as
at starting
but
it
it
PREFACE.
It
may be asked
subject which
vii
Why
is
Clerk-Maxwell's work
the Physical
opening
Laboratory
for a
expression
that of Stewart
scientific
or experimental, are
more prominent
accurately the
facts
In addition to
phenomena.
what is stated
been
way
and
in
it
may be
By
that
who, without
career,
whether
desirous of knowing
yet
remains an
still
is
rather for
is
Lecture Room.
to the
there
so that
work suited
mean a work
is
the Study
them an
in the
text
intelligent
n)
as to
of the subject in
division
which the
especially
treated.
Temperature is first introduced as a mere condition determining which of two bodies in contact shall part with
heat to the other
In
6).
this sense
made
to
52).
is less.
And
this is altogether
In
57
it is
When
is
compared
air
two
is
itself
to
being
it
the
air
greater to that in
passes
which
receivers.
is
an absolute method
PREFACE.
viii
method.
scientific
But
is
it
what
that
In
60 the reader
is
the
for
is
told
absolute
Thus
means of mixtures of
And
this is stated to
ice-cold water
is
defined by
boiling
water.
" accord so
closely with the absolute
scale,
and
is
even to show
required
the whole
to the absolute
pointed out
option in the
and
that
is
ordinary air-thermometer.
is
the
It is
leave a certain
still
so
possible
to
meter temperatures
it
his
of absolute temperature,
definition
Thomson found
definition (which
and
measurement of temperature.
formal
rapid resume of
Thomson's application of
Reversibility, with
principle of
them
first
Carnot's Cycles,
subject introduces
new
scale
frame his
make a very
and
that of
an
justified
by
their close
by
approximation
their comparative
PREFACE.
simplicity
and
and convenience,
they are
thenceforth
it
which follow
then shown, in
how
405,
employed
(by means of
has been fully pointed out what
until
is
ix
to
It is
by the air-thermometer.
be
set
practice to
And
average student.
it
is
if
they be found in
solely
on
this
ground that
He who
it
is,
be deservedly disappointed.
from real and great difficulties,
everywhere
No branch of science
even
is
either not
read at
free
in its elements.
all,
or
has confined
to
his reading
pseudo-science.
The
reader,
science of
who
wishes to
know more of
the general
book on Thermodynamics.
There he
will
it
COLLEGE, EDINBURGH,
December
isf,
1883.
in
my
also find
subject,
TAIT.
CONTENTS.
CHAPTER
I.
PAGE
FUNDAMENTAL PRINCIPLES
CHAPTER
II.
INTRODUCTORY
CHAPTER
III.
CHAPTER
13
IV.
CHAPTER
21
V.
DILATATION OF SOLIDS
71
CHAPTER
VI.
CHAPTER
88
VII.
THERMOMETERS
103
b
CONTENTS.
CHAPTER
VIII.
J'AC'.B
CHAPTER
IX.
......................
CHAPTER
CHANGE OF TEMPERATURE.
THERMO-ELECTRICITY
XI.
2O
XV.
.......................
CHAPTER
193
XIV.
...................
CHAPTER
182
XIII.
..............
CHAPTER
163
XII.
.................
CHAPTER
CONVECTION
...................
CHAPTER
CONDUCTION OF HEAT
X.
SPECIFIC
CHAPTER
131
230
XVI.
RADIATION
239
CHAPTER
RADIATION AND ABSORPTION
XVII.
250
CONTENTS.
xii
CHAPTER
XVIII.
I'AGE
RADIATION
276
CHAPTER
XIX.
2QO
CHAPTER XX.
WATT'S INDICATOR DIAGRAM
CHAPTER
298
XXI.
ELEMENTS OF THERMODYNAMICS
CHAPTER
NATURE OF HEAT
324
XXII.
3$2
HEAT.
CHAPTER
I.
FUNDAMENTAL PRINCIPLES.
IN dealing with any branch of physical science it is
absolutely necessary to keep well in view the fundamental
i.
and all-important
principle that
to the physical world save by
or
by mathematical deductions
experiment,
from data
and
so obtained.
On
each successive stage of his progress more and more profound conviction of its truth.
He must receive it, at starting,
as the
study
only
lute
the
and, as he gradually gains knowledge by this
method, he will see more and more clearly the abso-
impotence of
reasoning, to help
Man
all
him
has been
so-called
metaphysics, or a priori
HEAT.
and understand
to control
[CHAP.
to enable
him
their indications.
is
totally helpless in
such
The
matters.
preted by
r
l
His
<to
open
ithey
an
absolutely
This
&her'
that
is
new and
illimitable
prospect of
"na "resting-place
te
much
is
has but scant time to co-ordinate and consolidate his knowledge before he has additional materials poured into his
store.
3.
To
sight,
with light
opaque bodies.
filled
what we understand by brightness, &c., does not exist outIt shows us also that the sensation of
side our minds.
colour
between
To
be
different so-called
town seems
to
filled
of
dilatations.
pitch,
what
and
the
And
quality,
is
in the air-particles
is
objectively the
amount of com-
FUNDAMENTAL
i.J
PRINCIPLES.
less
light,
or
venience
the
and
is
terms
to
occasioned
light
if
we announce
and sound
effects
as
phenomena,
" luminous
"
"
or
noise," as the case may be. In this sense
impressions
us
is
there
outside
energy of motion of every kind, but in
of brightness and
&c.
&c.
noise
or
colour,
harmony, pain,
4. It would seem therefore that we must be extremely
the
cautious in our
own
of a thermometer, not by the sense of touch, and in all probability you will find little or no difference in what we call
their temperatures.
B 2
HEAT.
[CHAP.
is
The
of
And
heat.
process
it
is so,
reverse the
ingly
them
all
to
comparatively cool to the touch, while the metal paperweight may be much too hot to hold. The order of these
bodies, as to
reversed
warm and
and
this is so,
heat from
receives
Thus the
direct indications of
bodies.
FUNDAMENTAL
i.j
PRINCIPLES.
England, remained for nearly an hour in comparative comBut, though their clothes gave them no great inconvenience, they could not hold a metallic pencil-case without
fort.
On
Even from
is
conducted by
and temperature.
is
and
in
to take place.
In
tell
body
is
as closely
He must notice,
analogous to the elevation of the cistern.
that
does
not
however,
depend upon mere
water-power
quantity of water
must have
"
to
be capable of driving a
head/' or elevation.
But, in another
is
and quite
body
Heat
HEAT.
[CHAP.
level.
vice versa.
Two
7.
For
that, as will
all
has
not material
though
a sense as
matter has.
This
appear, at
may
first sight,
paradoxical
but we must
remember
others, already
When we
mean
that
understood in their
full significance.
something which
existence,
we
exists altogether
it
ception of
it,
something
very different
if
it
at
our
command
mainly upon
for all
is
based
we
FUNDAMENTAL
I.]
PRINCIPLES.
logic
admit
concession.
Heat,
therefore,
which
mutations
satisfies
we adopt
its effects.
There
9.
is
Under
the
We may
same physical
enunciate
it
conditions the
as follows
same physical
results
be
fully
strictest
on
and experiment) of the existence of definite
and unchanging laws to which all physical processes are
sense.
It
is,
observation
found to be subject.
CHAPTER
II.
INTRODUCTORY.
i o.
UNTIL all physical science is reduced to the deduction
of the innumerable mathematical consequences of a few
laws,
it
will
to avoid
arrangement of
its
be impossible completely
whatever be the
repetition,
we adopt
in bringing
When we
and
his trowel,
extract
in
the
following
knowledge
and
reasoning,
on
all
CHAP,
INTRODUCTORY.
ii.]
categories of quantity
and of
space-conditions, are
rendered
and
no admission
simplified
is
for
of philosophy.
is
to observe
and
classify
by no means
entitled.
it
were
complain of true
science,
merely mechanical.
It will
knowledge of causes, as
endue matter with mysterious
the
qualities
in
the
Thus
physical
all
subject know that the laws of motion, and the law of gravitation, contain absolutely all of Physical Astronomy, in the
sense in which that term is commonly employed
viz., the
:
number of masses
(usually
planets,
and
satellites.
p. 149.
we must
HEAT.
io
[CHAP.
move
is
problem
gone
much
So
in
it is
its
and
rigid,
difficulties
entirely mathematical,
it
falls
various
comes
from others
fully satisfactory
and uncom-
mode
we
shall find
it
of demarcation.
found to require
from another.
All that
for its
we can do under
may be
confessedly
somewhat
throughout,
when needed,
is
to
indefinite,
results
and
freely
to
of other parts
assume
of our
INTRODUCTORY.
n.]
The advantages
subject which we have not yet discussed.
of this method, at least in my own experience, have been
found much to outweigh its obvious but as yet inevitable
But, to reduce the latter as far as possible,
disadvantages.
out
its
outset fairly prepared to take up in turn each of our divisions of the subject with as much detail as is consistent with
And another
the dimensions of an elementary treatise.
follows
The
classification
is
as
1.
Nature of Heat.
2.
Effects of Heat.
3.
4.
Sources of Heat.
5.
Transference of Heat.
6.
Transformations of Heat.
As
ordinary
phenomena belong
in part to
Dynamical Theory of
commonly
called.
ffeafy or Thermodynamics, as
Hence
(i) will
be more
fully
it
is
developed
HEAT.
'12
its
in that of (4)
and
first
[CHAP. u.
farther
(6),
group
(2).
importance.
CHAPTER
III.
WE
13.
briefly
but before
absolutely essen-
is
and explanation of
a passage in Newton's Principia which, till very lately, seems
to have altogether escaped the notice of scientific men.
The
modern
science, will
Newton's Third
Law
" To
every action there
action; or,
equal
of Motion
is
always an equal and contrary rethe mutual actions of any two bodies are always
and oppositely
is
directed"
first
shows to hold
is,
what we com-
monly
call forces
is
true in
"
If the
acti'ity
of an agent be measured by
the
product of its
HEAT.
14
force into
its velocity ;
and
[CHAP.
p
if,
similarly
the counter-activity
of
the resistance be
into their
activity
and counter-activity,
and opposite"
The
now
called
duced the
it
lifts
which
it
will
not be capable of
power of doing work. On the other hand, the hundredweight was moved, work was done upon it, and that work
was stored up in it in its raised position, ready for use
at any future time.
Newton's statement implies that in
this case the work spent in raising the
hundredweight is
in.]
stored
in the
^15
mass when
raised.
15. Thus it appears that force is a mere name; but that
the product of a force into the displacement of its point of
application has an objective existence.
[Even those who
are so metaphysical as not to see that the product of a mere
name
may
and
to say
Force
is
the rate at
of length*
1 6.
we have
hundredweight or of a
* In
symbols
this is
at
ton.
When
resistance
merely
= fv = /
at
the
whence
dx
the
- /,
the second.
first
statement,
was
HEAT.
[CHAP.
power may
consist.
The
we
say,
or passive, form,
is
Excellent
Another example of it is suggested by the word "Cohesion" employed in Newton's statement ( 13), and which
must be taken to include what are called molecular forces in
general, such as for instance those
of a solid depends.
elasticity
to
Newton's words
3)
and we see
that
in.]
acceleration *
is
the product
-17
accele-
been applied.
As
kinetic
comes
to ilk
it
affect
our nerves of
depends, &c.
we can
part of
the
work is
and the
originally at rest,
is
Mv
1
.
HEAT.
[CHAP.
is
equivalent to the
work
so
spent.
bow
is spent against
or winding up a
Also it is stored
weight.
Hence
work
is
energy
it is
spent,
:
friction,
stored
up
Newton, whenever
Newton
is
it
expressly
friction)
energy
tells
is
indestructible
it
is
when
there
To make
requisite
this
is
to
beautiful
statement complete,
know what
becomes of
all
that
is
friction.
of course, experiment
is requisite.
Newton,
have
seems
to
forgotten that savage men had
unfortunately,
long since been in the habit of making it whenever they
19. Here,
wished to procure
sticks together, or
The
fire.
(still
produced.
In
by the expenditure of work.
has its equivalent in the heat
failed to see, and thus his grand
it is produced
friction
This Newton
generalization was
left,
The converse
plete.
transformation, that of heat into work,
dates back to the time of Hero at least. But the knowledge
produce a certain
result
does not
JJK]
as little
19
imagined that in
into work, as
heat.
totally different
One
title
the French
Academy
scheme pretending
to give
We
employ
it
to
show
one direction
is
it
return to
its
position,
Apply
ascent
frictionless constraint to
it
Aw
B, and
in
its
its
HEAT.
20
descent, along
From
A.
to
the
amount
of
work
[CHAP. in.
is
restored to
is
w of energy additional
to
what
it
with an amount
possessed at starting.
Every time the mass goes round the double course in the
same direction it gains the difference between the larger
quantity and the smaller one, and therefore at the end of
each complete cycle, that amount may be drained off to
to do useful work.
some machine
turn
We
be
fully
discussed
In general,
if
is
reversible.
This term
later.
if
the
reversible,
n, according
to the
CHAPTER
IV.
Nature of Heat.
21.
name
of
fire,
really or
as ordinary
called
composed.
The tendency
its first
great impulse,
of Colchester (circa 1570), was to regard heat, light, elecas forms of matter
excessively subtle and
tricity, &c.,
refined
capable of freely pervading and combining with
all
They were,
in fact, classed as
its
Phlogiston
Crum Brown,
HEAT.
22
[CHAP,
now
call
all
but universally
till
is
commonly
called popular.
One by one
from
their old
* "
And tryall hath taught me that there are liquors, in which the
bare admixture of milk, oyle, or other liquors nay, or of cold water,
will presently occasion a notable heat : and I sometimes imploy a
And
intense enough to be troublesome to him that holds the Glasse.
yet it seems not necessary that this should be ascrib'd to a true fermenwhich may rather proceed from the perturb'd motion of the
Corpuscles of the menstruum, which being by the adventitious liquor
or other body put out of their wonted motion, and into an inordinate
tation,
cause soever
Some
Philosophy.
By Robert
Boyle.
Part
II.,
Section
I, p. 4=5.
1663.
iv.]
23
of
W. Weber,
quite as
Easy
in
Reflection
certain sense, forms of imponderable matter, acting
on one
The
experiments,
which,
as
stated
in
22,
first
was simply
this
The body
in' its
massive
in other words,
with
its
it
required so
particles in order to
whole that
On
its
if by any process
capacity for heat, then, of
course,
friction
or abrasion
is
due to the
fact that
if it
retains
it,
it
effect
of the
HEAT.
24
heat more than
it
Now
temperature.
[CHAP.
this
reasoning
therefore rise in
so
is,
far,
perfectly
philosophical,
doubts about
the
and of
ca-:e,
it.
He
says
to try if possible to
modern
doctrines of
factory
is
The
final state.
they
iv.]
25
filings.
If there
be
by any
possibility
be matter
there
would
one
one
and
all
the process.
Here
is
" In
reasoning on this subject, we must not forget to consider that
most remarkable circumstance, that the source of heat generated by
friction in these experiments appeared evidently to be inexhaustible.
"It is hardly necessary to add, that anything which any insulated
HEAT.
26
[CHAP.
in the manner in
anything capable of being excited and communicated
which heat was excited and communicated in these experiments, except
it
be motion."
28.
When we make
if
it
in another form,
which
is
perhaps
still
more
striking.
In
down a cascade
the
fall
it
fall
were
when rubbed
them.
But
if
if it
To
was therefore
this possible
iv.]
27
objection, that the heat might have come from some external
He
source, so that he tried a second form of experiment.
surair-
upon
the subject is
" From
this
into water,
but
it is
experiment
it is
a well
known
by
its
friction is
capacity
is
converted
diminished
is
much
greater than that of ice ; and ice must have an absolute quantity of
heat added to it before it can be converted into water. Friction, conse-
And
this
there he stops.
to-
"
Heat, then, or that power which prevents the actual contact of the
corpuscles of bodies, and which is the cause of our own sensations of
heat and cold, may be defined as a peculiar motion, probably a vibration,
of the corpuscles of bodies tending to separate them. It may with
propriety be called the repulsive motion. Bodies exist in different states,
and these
states
power on
attraction
sive
and a
HEAT.
28
[CHAP.
will
be forced.
The
have two
particles adhering
together,
soon
In
to take
in a position to
it
make
that statement he
second interpretation
and the whole dynamical
in addition to the
18),
sort,
but
iv.J
as something
which
it
29
phers to consider ; and it was not until Joule's time, somewhere about 1840, that the subject was fairly taken up, and
that justice was rendered to their real value.
33. Notice, however, how distinctly these two
leaders were men who based their work directly
There
great
upon
no a
experiment.
is
these
exquisite
extended to
all
unquestionably due,
(especially those of Joule)
is
experiments
forms of energy, and therefore included
far,
these
however, as they bear upon our present quesresearches re-established the conclusions of
much more
is
exact
commonly but
In fact the extensive, and exceedingly accurate, experiments of Joule led, in 1843 and subsequent years, by
35.
HEAT.
30
[CHAP.
The number
in error
to
per cent.
by means of a very
accurate determination of the specific heats of air, and a
by anything approaching
In 1853 Joule
36. Direct
ways by Colding,
forms by
in 1843,
Him, Regnault,
1849) of Joule's
made
&c.,
various
in
in
many
final result.
in 1839,
was
first
effected
by
Him
in
1857-
menters.
The
kind
are, of
1843 an d subsequent
by means of magneto-electricity.
F.
UNIVERSITY OF CALIFORNI/
DEPARTMENT OF PHYSICS
PRELIMINARY SKETCH OF THE SUBJECT.
iv.]
31
And,
referring
generally that
nature
the
to
30, 31, it may be stated
as yet very little information about
internal heat-motions, &c., of the
again
we have
of the
collisions,
&c., of
we
here
De
+ Hydrodynamica, 1738.
HEAT.
32
those of Light
'(
(CHAP.
3).
sense-organs adapted
quite independent
pheno-
mena.
20 40.
Heat is now proved to be a
41. Resume of
form of energy. Hence the First Law of Thermodynamics,
which merely states the equivalence of heat to work, with
the requisite numerical
datum
have, as yet,
a.
b.
Change of Dimensions,
or of Stresses, in Solids,
and
c.
Change of Temperature.
d.
Electric Effects.
e.
Effects in starting
Chemical Changes,
it
will
may be
necessary,
it
is
on
suddenly or
iv.J
33
else
star.
seen to
"
rises
"
sag
notably in pitch
as the
rises.
through them
expansion by heat.
44
(a continuea).
The grand
on
in
the ocean
HEAT.
34
[CHAP.
stone
just as
only that
its
at
first,
more complex.
is
it
really
rock-salt or galena
is
somewhat
Suppose
the
all
sufficient heat to
ice.
It is still the
its
melting-point
is
considerably
point of view, its temperature is still that of the meltingpoint, but it is a liquid instead of a solid.
46 (b and c continued}. Apply more heat to the water.
Its effect is
now
to
make
the water
warmer
in scientific
Every fresh
language, the temperature of the water rises.
application of heat raises the temperature more and more
till it reaches what is called the boiling-point, but here the
of temperature again stops. Farther application of heat
produces a new alteration in the molecular state, and the
rise
been applied
the whole of the liquid has, without farther rise of temsaturated steam, as it
perature, been converted into vapour
.
till
is
technically called
raise the
is
this gas
production
iv.J
is
commonly
dissociation
its
35
the
constituents,
effects,
produced by continuous
>
2.
Water-substance
is
Melting.
3.
Heating.
4.
Evaporation.
5.
Heating.
6.
Dissociation.
7.
Heating.
familiar to
all,
and, as
we have
seen,
Few other
successive changes of state and of temperature.
substances offer, at least with our present very limited exOn the other
perimental facilities, so complete a series.
hand there are substances, such as carbon, which we cannot
even melt; others, such as uncombined hydrogen, which,
till the
very end of 1877, we knew only in the gaseous
form.
49
(d).
when heated
knowledge.
HEAT.
36
is
[CHAP.
commonly
called
Thermo-
already of immense practical as well as theoretical importance, as the reader will see when we come to
electricity is
is
of
is
the
following, discovered
electricity passes
round
the circuit
and
in intensity with
junctions.
The
now made
the hotter.
Let
A and B in
To
tions.
circuit in
from copper
passing from iron to copper, and at
iron, if he reversed the direction of his motion round
the circuit, these characteristics of the two junctions would
to
he
is
iv.]
be interchanged.
Now
suppose
37
down
Seebeck's discovery.
is
characteristic difference
50
need not
resist electricity
described.
and
lf
re -arranged.
B 1?
A B
2,
2,
&c.
/l'/f/l
Call
/I
/I
Then
HEAT.
round the
each
circuit in the
direction indicated
by the arrows
each
will at
[CHAP.
way round.
we had only one hot junction,
while we may have here as many as we please it is obvious
that by this arrangement we can increase the strength of the
all
But
is
the other
the hot
iv.]
39
together as closely as possible into what is called a Thermoso that all the A junctions are at one end and
electric Pile,
Nobili (1834).
51
by
"
(e).
friction
and
flint
steel
"
is
that
it is
particles of iron
used, just as
it
sets fire to
amorphous
modern
phosphorus
"
safety matches
"
;
In
poker causes
to
it
as dissociation
all
(47).
52.
Measurement
The
of
ment
if
is
A is
at the
HEAT.
40
B and
the
[CHAP.
i.e.
bodies which have
C, whatever be these bodies
same temperature as another body have themselves the same
:
temperature.
To refer to one of the analogies formerly employed, Heat
may be compared to the quantity of air in a receiver, tem-
that in which
with the other, and contain far less air ; it is the difference of
pressure alone which determines the direction of the transfer.
53. But, just as
another, so as to contain
one body may have more capacity for heat than another, and
more heat even when their temperatures
therefore contain
And
to
this difference
of capacity
(as
specific property
This
heat that mercury has.
the name of Specific Heat, a
known by
student as
54.
now
fairly
permanent, though as
is
system of
whole year
compared
v/ith
the
heat required
to
raise
the
average
iv.J
41
9, it is
clear that
in terms of
pound of
form of energy, we
it
may
equivalent
But the
it
is
37).
mode
is
to define a
to raise a
pound
metrical units,
these
Such questions
The
HEAT.
42
[CHAP.
devised to
The very
or submultiples.
consistency should have rendered it
impossible for any one who employs the decimal notation
to use any but a decimal system of multiplication and subwhen we come
to
lowest attempt
at
division of units.
with
its
Barbara
multiples
The measurement
have seen
52)
that the
may
perature
it
is
entirely inde-
It will at
that, since
IV.]
there
is
43
adopted in
of experiments
to apply
and
59.
in
though
it
it
Few
reduced.
delicate
necessary, even
if
it
a good,
its
step
i.e.
is
a uniform, screw
of no consequence.
:
What
is
necessary
is
When
for all,
becomes
Far from being a drawback to the use of such an instrument, the arbitrary scale is often of positive advantage to
the experimenter, for it prevents his being (as the most
honest and careful experimenter is very liable to be) unconsciously influenced by a knowledge of the reading that is
to be expected.
And the mere arithmetical difficulty of
passing from one scale to another is so trifling in comparison with the difficulties of experiment that it would
distinct
HEAT.
44
[CHAR
to reproduce,
and which
shall after-
it
is
(practically) to
be obtained
be found
It will
later
that
its
which
require to
pressure.
Hence we merely
For a
which pure
ice melts,
pure water
boils.
and another
temperature at
definite temperature at which
definite
The
is
boiling, the
If
we
call
Centigrade scale.
Now it is obvious
intermediate
that
temperature
portions
it
possible
of water
And we may
iv.]
45
define
10
the intermediate
water at 100
is
And
employ
it
for
The
effect of heat which is most commonly emof heat and temperature is the
measurements
ployed
of
volume
of
We may take for
liquids (
change
42).
that
has
some
little
reader
granted
every
familiarity with an
62.
for
ordinary
Thermometer.
mercury or alcohol.
is
usually
in
making
49).
In two respects
far, first, it is far
it is
more
vastly superior to
its
indications
HEAT.
46
of
the
current
electric
is
[CHAP.
directly
proportional
to
that
difference.
Here a
63.
is
digression
fact of Thermo-electricity
subject
entirely foreign
fact,
to
of
the
galvanometer
by the passage of an
depends,
is
it.
the position of
The
The fundamental
necessary.
The
the
same time
rk
elect
figure represents
all
is,
is
simply that
in general, altered
for illustration.
and
its
free
one with a
zinc, the
dry,
and not
iv.l
47
electric
which
is
may be
deflection
reversed.
The
rule
Suppose
we
are
looking at the coil from the west side, then the left-hand
end of the magnet is what is usually called its north pole.
current be so applied that positive electricity
If, then, the
which the
passes round the coils of wire in the direction in
hands of a watch move, the north end of the magnet will
move towards
coil,
i.e.
will
move away
is
is
smaller (provided
HEAT.
48
there be the
same number of
[CHAP.
coils
But
all
more
the
essential features
of galvanometers are
be made
to fall
on
it,
and
on a
nated spot on the screen. And the farther off the screen is
placed, the greater will be the motion of the spot for the
same
Thus
of the magnet.
as
to
so
be
magnified
may
deflections,
become
however
visible
small,
i.e.
This makes
method invaluable for lecture-illustration.
the thermo-electric
And
When
accurate measurement
is
little
mirror
made
index,
66.
The
iv.]
49
it,
need not
meter
the
of a great
number of
so small as to destroy
The
also
astatic principle
be
introduced
this
may
with
two
of
to each
other
with
their
and
their
di-
middle
by a fibre of unspun
Each magnet has
in a
vertical position
silk.
its
own
coil,
wires
HEAT.
50
[CHAP.
earth's
magnetism tend
in opposite directions.
we could make
fibre.
directive
force
of the
earth's
As an
be mentioned that
which
will
show the
it
is
it
may
a degree-
When
at a time.
If
Another device
is
magnetized
iv.]
51
continually
part of
it
is
means
in
Another, and by
cosity of the
air,
and
cell,
no
and mirror
pounce almost
upon
its
before it
ways
As heat
is
our disposal.
are mainly fuel.
at
potential energy
are included not
merely coal, wood, and so on, but also all that may properly
be called fuel
the zinc used in a galvanic battery, for
instance,
We
have also
Ordinary water-power.
Tidal water-power.
E
HEAT.
52
[CHAR
Winds.
Currents of water, especially ocean currents.
Hot springs and volcanoes.
named
those
And
every
The
first is
primitive chemical
affinity,
which we
may
sup-
If,
form the earth, did not combine, but still remain separate
from one another, the mutual chemical potential energy of
the iron and sulphur xemains to us as a portion of energy
primordially connected with the universe. But of that, so far
as we know, at least near the surface of the earth, there is
very
little.
interior
enormous
The second
abundant
source
source
we
is
far the
most
very
solar radiation,
have.
by
iv.]
instructive forms,
axis,
and
its
Now
70.
tJie
53
Our
due
to the sun.
it,
we
have
water-power
wave passes
we
us.
take
it
We
till
HEAT.
54
And
employed
for
mainly, at least,
partly,
[CHAP.
affinity.
71. It
is
of almost
all
count for more than a very small fraction of it ; and that the
only adequate known source is the potential energy which
parts
Transference of Heat.
Under
this
head
it
is
Conduction.
Radiation.
Convection.
As
will
be seen presently, this list involves some confucommonly understood it includes either too
sion, for as
much
73.
or too
By
little.
Conduction of
Heat we
usually
mean
that
com-
It is
the earth's internal heat reaches the surface, and that the
sun's heat penetrates into the crust.
The study of the laws
iv.]
55
power of one
is
of
very-
which heat
is
transferred from
velocity of light
what
that
is
It is entirely
by
radiation
unexpectedly an enormous extension. The practical process of Spectrum Analysis, to which they have recently led,
is
at our
command
for
By
Convection of
Heat
is
usually
Gulf-stream
is
meant the
locality to another
which
it is
carriage of
along with the
associated.
The
But
it
may
book
not be amiss to
make
while
That
it is
HEAT.
56
But
it
an
it
[CHAP,
electric
is
for,
call
though
a current of
heat:
that
i.e.
temperature
electricity
is
throughout,
to deposit
it
it
in the other.
ing to this
what
illogical
we have decided
assist the
difficulty also.
Transformations of Heat.
as
numerous
iv.]
57
thus
form ?
76.
Now
column of smoke
is
waste.
But there
waste.
It
if it
were theoretically
working
about one-fourth
one-fourth
and
somewhere
perfect,
that
is
determines this
The answer
just used.
When
is
$8
in
its
entirety
going up
but when
hill,
as
it
HEAT.
[CHAP.
comes
to be a question of reversal
it
were
then
it
is
only a fraction, in
up again
down
still
78.
In
all
transformations of energy
we
find experiment-
less
Thomson
into
full
79.
The
becoming
less
and
Thus, as long as
less transformable.
there
are
changes going on in
must
Its ultimate
.all
Whether
this
be a high
iv.J
59
it
is
in
it
cannot raise
on.
carried out ?
it
brilliant
82.
operations.
It has supplied not merely the legitimate mode of finding
the relation between the heat taken in and the work done
by an engine, but also the test of perfection for a heatengine, an absolute definition of temperature, the effect of
pressure on the melting-points of solids, and innumerable
important groups of associated properties of matter and
HEAT.
60
[CHAP.
To
Second
such that,
Law
when
of Thermodynamics. If an engine be
worked backwards, the physi:al and
it is
and
refrigerator,
heat.
said about the nature of the working substance ; the temperatures of source and refrigerator, and the quantity of heat
can be done.
The importance
work which
84. Garnet's
moment
the
full
merits of this
all
but
of Temperature.
first
time,
an absolute definition
his
own
work
which enables us
at
claims
first,
iv.]
61
and experimental basis; and, second, in the furmeans of reasoning upon it which was
absolutely new in physical mathematics, and which has
been, not merely in Carnot's hands, but in the hands of
physical
nishing us with a
a great
many
of his successors, as
fruitful in
new
discoveries
series
state
calls
steam or water
which
in
it
was
we
tion
is
at starting.
it
Carnot
entitled to reason
says, that
only
upon the
rela-
If a
which
it
was
at the beginning.
let
It
was saturated
and
to
assume that
amount of energy
as
it
it possesses
intrinsically the same
did in its former state. We have no
and ends
in another.
But if we can by any process bring
the working substance back to its initial state, then we are
entitled to assert that it must contain neither more nor less
HEAT.
62
than
it
did at
first,
[CHAP
also
entitled to reason
86.
The
the
for
all
purpose of reasoning on
this
subject
is,
like
In addition to
these suppose a
which, as regards
work
in pressing
down
will
be
liquefied.
become
Continue
this
fresh steam
process at any stage and transfer the cylinder to the nonIf we now allow the contents farther to
conducting body.
sinks.
may now be
gain of heat,
to
compress
it
it
transferred.
at the constant
iv.]
to the
first
63
the second operation, and heat was given to the cold body
Also it is evident that more work has
during the fourth.
been done during the second and third operations than was
spent in the first and fourth, for the temperature, and therefore the pressure, of the
may be
tion
is.
The
external bodies,
before
its
contents
is
all
is
be no
being taken
the
HEAT.
'64
[CHAP.
doing work
the time,
all
till
quantity of heat taken from the cold body ; but during the
first operations the piston was in contact with steam at
two
in the
in taking heat
hot body.
',
the
reverse
performed
in
heat
at
iv.]
65
way.
Now
90.
Carnot, considering heat as a material subit has done work in the direct
being
i.e.
in quantity.
of heat
is
fore lose
only
is
We now know
therefore unchangeable
its
required to render
and
One
it
subject.
we
it
involved
give the correct statement of the question here
of
Carnot's
account
brief
this
may be well to complete
engine
(as
UN ,VERSrTY OF CALIFORNIA
HEAT.
66
[CHAP.
quantity of useful
will
that heat
Reversibility is thus the sole necessary condition of equivalence between two heat-engines.
This is an enormous step in physical science. The
reasoning
is
Whether steam, or
particular substance.
air,
or ether, &c.,
in
scientific
sense
possible physically to
92.
that
make
it.
Carnot demonstrates
ad absurdum
this property
by a simple
is
20.
a perfect one
reductio
He
says
for, if not,
suppose there could be one more perfect, and let these two
Let the more perfect
engines be employed in conjunction.
engine be employed in taking a quantity of heat, conveying
it to the condenser from the boiler, and giving from it a
do.
it comes up,
and therefore the
double system necessarily gains more work than it spends.
Thus we have an engine which will not merely go for ever,
is
every time
iv.]
its
67
sources,
Such a consequence, as we have seen ( 20), is inconwith all experimental results, and therefore the
that there can be a more
supposition which led to it, viz.
sistent
is necessarily false.
perfect engine than a reversible one,
Such is Garnet's proof that (on the assumption that heat
is
is
a perfect engine.
It
indeed, as a
of heat.
93. We have now to consider the cycle in the light of the
conservation of energy ; so that, if work be produced from
heat at all, some of that heat must have disappeared in its
if
the
Therefore, under no circumstances
production.
boiler.
If
one.
Work
the two
work
to
be employed on
it,
when
reversed
of heat), than
while there
HEAT.
68
[CHAP.
heat
from the
result
it
boiler,
amounts
must obtain
to this, that
by
it
The
cannot be done
we have
94. Since all reversible engines are perfect, they are all
that is, they all give precisely the same
:
of equal efficiency
which
ployed.
iv.]
between the
new
thermometer, and
scale
and
therefore
to
of
that
make
this
reasons
for
explained.
quantities
localities
and
not allowed
to part
to the
Trans. R. S.
.,
May
1854.
HEAT.
70
[CHAP. iv.
for
374 taken
thermometer.
result, that
Hence
the
a body cooled
and very
curious
down 274
important
centigrade
degrees
This limit,
below zero is absolutely deprived of heat.
which is commonly called the absolute zero of temperature,
perhaps more correctly called the zero of absolute temAnd it is obvious that the temperature of a
perature.
is
much
Resume #/
dition of a
available.
body
41
97.
as regards Heat.
Second
Law
Cycles,
of Thermo-
CHAPTER
V.
DILATATION OF SOLIDS.
61 as a mode of
Taking the process explained in
oand
100
of
the Centigrade
between
defining temperatures
99.
as air
and
its
constituents, but as
we
solid
vessels,
simplicity
of process
requires
that
we
temperature.
Its
pure
changes of
a far higher
for
scientific interest is of
order.
ico.
is
same
it is
properties at
heterogeneous.
all
points
But even
HEAT.
72
The
in all directions.
[CHAP.
rocks,
familiarize us with
were
it
cut,
how
it
it
would be impossible
to tell
by any operation on
has, in fact, precisely
it
all directions.
taken as approximately isotropic as well as homogeneous. We commence our work with a rod or bar of such
may be
a material, and
The
we
define thus
ratio
101.
be raised
its
be put
in the
specific
property of the
and then
unit length,
DILATATION OF SOLIDS.
v.]
102.
As
this
work
is
73
sufficient to say
usually obtained
or of the distance
it is
is
may be made directly with a microscope and screw, or comparisons may be made between the lengths of the heated
bar and of another kept permanently in melting ice in a
second bath placed alongside of the first. Methods in
The
in lecture illustra-
tions.
principle
may
And
is
above
it.
Thus by
HEAT.
74
[CHAP.
is
used
so that
if
one be
fixed,
T/ie ratio
proportional
of temperature.
DILATATION OF SOLIDS.
v.]
75
where k
is
put /=i, we
the
coefficient
The
we
if
is
value of k
is
it
we must use a
considerable change of
Taking then the extreme temperatures of our
temperature.
temporary scale i.e. measuring the length of the same
bar,
first
and then
in melting ice
--=
have
/o
/.oo
-,
in
100
boiling water
we
k.
^o
The
oC.
crystals,
as glass,
is
rarely
much more
c.,
so that
is
The
as an
as a basis for
has discs of
quite sufficient
flint
subject,
but
HEAT.
76
[CHAP.
lens,
tables of results of former experimenters to find the refractive index, he has to measure with great care for himself
this particular constant for the material
and
for
The
And
by a determination of
its
specific
-0000085
Platinum
=r
-0000085
i~^3
Steel
-000012 1
Copper
-0000191
=:
-000029
Zinc
105.
The
results.
it
~^
-j~
-^~
^,000
law of
103,
tions of
two
it
appears that
we may by means
different materials
of combina-
produce compensation,
if
we
DILATATION OF SOLIDS.
v.j
77
The
condition
that the
dis-
remain constant at
all ordinary temsimply that the actual expansion shall be the same for each
bar.
But, as the Coefficients for zinc
peratures
is
be
at
as 29
once secured by
we can
construct a measur-
is
independent
of temperature.
This is, practically,
the same arrangement as that of
the Gridiron
Pendulum of Harrison.
But the reader who has mastered the simple case given
above can have little trouble with the more complex
cases.
HEAT.
[CHAP.
1 06.
The balance-wheel and its spring perform for a
watch or chronometer precisely the same function as the
pendulum, assisted by gravity, performs for a clock. But
we may
compensating
its
temperature.
How-
moment
of inertia of the
When
bent
it
is
the same.]
DILATATION OF SOLIDS.
v.J
79
would bend
itself if
its
mesial
heated,
Now
it is
is
cooled.
structed of two concentric layers, the outer the more expanAlso let it be cut into separate arcs sufficiently
sible.
removed from one another to prevent interference. Then
of two
HEAT.
8o
in a support at
[CHAP.
its
One
107.
fact of
same
for
that this
is
glass,
and
coefficient
is
nearly the
farther experiment
shows
wide range
of temperature.
may be
The
104.
platinum as for
"fused in
wire,
whose melting-point
thin be the wire
wire contracts
not
is
high,
it
almost certainly
however
;
or the
is
air-tight.
fails
on cooling
08.
little
is
practically infusible in
employment
The
bar
is
The bar
plumbago, whose dilatation is exceedingly small.
rests against the bottom of the hole and is kept there by a
DILATATION OF SOLIDS.
v.j
baked
81
clay.
As the
maximum thermometer.
109. When a body is
properties are not the
the circumstances are
aeolotropic,
same
now
i.e.,
non-isotropic,
its
in all directions.
But, though
less simple than in the case of
For
in
right angles to
ascertained, and
(as
show
that,
follows
An
ellipsoid
may be
regarded
tions
it
becomes a sphere.
Thus when
the amounts of
HEAT.
82
compression or extension
diameters
revolution
parallel
[CHAP.
to
are
;
sphere.
line
the axis.
same
in all directions.
to that.
right angles to
one another.
DILATATION OF SOLIDS.
v.]
83
measures of length.
It
was, in
fact,
almost entirely by
As a simple
no.
sarily
as in the cut,
For
if
the diagonals
be i + kit
half
of
and
the
the
measured
kj
tC,
tangent
of
the
rhombus
is
angle
were of unit length at o C, their lengths
and
will
at
-f
+ kj
T^
*,/
-j-
,
,
which
is
practically
(k2
#,)/,
because
heating.
The upper
surface will
HEAT.
84
[CHAP.
-directions
made up
of two parts
polished slab of
112.
By
"arrow-headed
the optical
"
selenite
method the
is
slightly
differences
warmed.
between the
principal dilatation coefficients are very accurately determined. All that remains to be done is to measure one of
them
Here
advantage.
an
all
directions
number
pendulum.
But the apparent anomaly of contraction by heating is
not confined to crystalline bodies. We shall presently have
to discuss
instance
is
it
as
shown by
furnished by india-rubber.
instructive
DILATATION OF SOLIDS.
v.]
85.
india-rubber gas-pipe,
vertically,
some specimens by
tracts (in
its
and
length)
it
through
it
con-
the weight,
raises
from a
lower end,
to its
five
little
boiler.
of expansion.
113. The experimental result of
consequence, the farther statement:
The
coefficient
of cubical dilatation
is
103 involves, as a
in all cases tht
sum of
This
by supposing a body
easily seen
is
to
be divided
number of
into a
in the ratios
i
or,
what comes
&/,
/,
to the
same
original,
k are
This
is
precisely the
When
and the
of
the
body
same formula
as (a) of
103,
and thus
is verified.
is
linear
dilatation.
HEAT.
86
determination (whichever
may be
[CHAP.
the easier, or the
more
In aeolotropic bodies there may be expansion, conor no change of volume, as a result of rise of
traction,
temperature.
change of form, we
change of volume.
without
without
we
shall
suppose
first
a non-
any
is to
Then
let it
expansion of the
solid.
weighed.
the expansion (if any) of the solid will drive out some of
the liquid. Let it cool, and weigh it again. The difference
of weight is the weight of the liquid driven out by the
The
correction for
material of which
substance,
where k
is,
is its
by
is
the
usually glass or
some other
the
isotropic
113,
The
greater part of what precedes is only approximately true, even for the small range of temperature (o
to iooC.) to which our statements have been, in the
115.
main, confined.
DILATATION OF SOLIDS.
v.j
at
much
87
higher temperatures
zero.
has been tacitly assumed, in what precedes, that heating has not permanently altered the molecular state of the
So long as this is the case the dimensolid operated on.
It
sions of the
"
process of annealing," as it is called, is devised essentially
for the purpose of preventing such physical changes.
The
whole of this subject, with the exception of a few rules
instance,
different
parts
Think, for
stress,
&c.,
causing
116.
it
Resume of
solid rod
perature.
is
Hence,
rise
of tem-
aeolotropic
compensation
bodies.
balances
Breguet's metallic
Applications
and
to jneasuring-rods,
pyrometers,
pendulums,
thermometers.
Irregularities due to
CHAPTER
VI.
solids,
liquids
we have
for
first,
we
is
cubical dilatation
only.
Taking
find that in general their cubical dilatation
is,
been devoted to
common
this
two
ranges of
anomaly
tion.
is
We
1 1 8.
Let, as in
W W
,
CH. vr.l
89
is
W.-w,
it
would hold
at temperature t
(i
3 &)
is
w\
It actually holds
provided mercury were not expansible.
an amount whose weight is only
w.
The ratio of
t
(i
from which
To
AT/)
K may
at
w) =
3&)
Ww\
once be calculated.
i.e.
K=&
then
we have
at
once
filled
at
all
tem-
peratures.
119. This process is a simple and effective one, although
involves the determination of the expansion of the vessel
as well as of the liquid ; and it is so because the expansion
it
of mercury
is
much
But a very
liquid,
skill
common
surface
HEAT.
[CHAP.
The
tube
is
now
and
and
b',
and
at
in
b,
measured number.
120. Here are a few of Regnault's numbers for merThe second column contains numbers derived
cury
the third is cal.directly from the experiment described
culated from the second for a special purpose
:
vj.]
91
DILATATION OF MERCURY.
CO
Temperature C.
.
50
IOO
150
200
250
300
350
We
Thus
be 250
if /
A"250
0*0001791
-00000005 1.
0*0001791 4-0-0000125=0*0001916,
As
this
be employed
will
coefficient
all
the
to calculate
of dilatation
This is found
increases steadily with rise of temperature.
to be the case with the great majority of liquids, through
the whole range of temperature in which we can experiment
But the rate of increase of the coefficient is
upon them.
generally
towards
greater as
its
the
boiling point.
rises
HEAT.
92
The
column
last
[CHAP
true coefficient
of dilatation
volume
not (as
is
ance with
common
two
With
usage) to the volume at zero C.
solids, in general, the dilatation is so small that this distinction is of little importance
but a comparison of the
last
cannot
be
The formula
for
it
K = O'OOOiyQI
H-
In
this
abandon
case,
for
into details.
a perfectly
same
The
definite
not
which
in
that
conditions,
places
and
O'OOOO0002/.
different
reason
is
that
we
are
now
dealing with
substance
specimens
like
glass
or
may
differ
brass,
&c.,
of
another.
121.
The behaviour
iooCis
From o upwards it
contracts, more and more slowly, till it reaches its maximum
From 4 upwards it exdensity almost exactly at 4C.
very different from that of mercury.
as Hope's experiment.
static
law
that,
fluid
vi.]
sufficient) to the
93
middle of a cylindrical
Thermometers were
fixed
The
first effect
is
to
reaches 4C, for then it ceases to descend; very soon afterwards the temperature indicated by the higher thermometer
begins to sink in its turn. But it does not stop at 4 C. It shows
lower and lower temperatures till the water towards the top
of the vessel begins to freeze,
and
is
therefore at o.
Thus
proved to be denser than at any other temperature from o to 100, because it remains persistently at
the bottom of the vessel whatever be the temperature of the
water at 4
water above
is
it.
for the
experi-
HEAT.
94
this
[CHAP,
temperature
DILATATION OF
:
4
6
00169
30
'00420
40
1-00766
50
60
1*01672
-00003
1*00011
70
80
1-02871
1-00025
1-00082
90
1*03553
ioo
1*04312
-ooooo
15
The numbers
with a
fair
Vol. of Water.
1-00003
i-ooooi
i-ooooi
PRESSURE.
C.
20
Temp.
-00012
10
WATER AT ORDINARY
Vol. of Water.
Temp. C.
1-01189
1*02237
144,000*
Hence
the
these limits)
coefficient
is
of
dilatation
of water
(between
approximately
72,000.
Pierre,
without freezing,
vi.]
It
95
of water
is
density
freezing
point also
122.
is
The most
expansible of
all
known
The
liquid state.
in the
acid, or carbonic
Thus
is
the
30
vapour
at
Density.
2O C.
o C
-i-
its
O'QO
0-83
mean expansion
for
between
6o.
oC and 30
0*013 nearly.
As a rough
of dilatation
is
c
0-00105 at o C.)
is
considerably
HEAT.
96
solids
have notfound
it
[CHAP.
necessary to take
In fact a
discussing the expansion of such substances.
solid or a liquid will expand very much as we have already
described, even
if it
a gas kept
The
first
indicated that the quantities just defined are not only the
gas, but have the same common numerical
value for all gases, at least for the range from o to 100 C.
Though these results are only approximately true, they are
sufficiently exact for
many
now
called
BOYLE'S LAW.
vi.]
Along with
we may
this
97
is
called
CHARLES' LAW.
increases by
temperature.
The two
laws together
may be
stated
in
the
simple
form
pv =
where
C is
in fact
upon
of
its
C(i
a/),
cubical dilatation.
a =: 0-003665.
125.
statement of
at this stage,
be made on the
last section.
First.
dilatation
to
is
a gas-thermometer
is
one.
Second.
124),
Note
that the
123,
because
/ and
in
it.
We have stated Charles' law as holding for all temperatures intermediate to o and 100 C.
Practically this is
have
been
to
seems
it
tacitly assumed.
true, though
n
HEAT.
98
Third.
we assume
If
[CHAP.
the formula of
124 to hold
for
tf//
same
i.e. if
to the particular
temperature
*=
= -
0^665
-f
:
or
^73 nearly,
it
//
i.e.
It
may be well
does
exist,
gives a
and
satisfactory notion of
fairly
If
we would
shift
is
61)
we must put
for
^and
124) becomes
pv
where
is
= Xf,
As already
it
will
VI.]
The
its
99
temperature,
is
is rarefied.
particles
The experiments
Thomson show
of Joule and
that,
Hence
the air-thermometer,
is
(
strictly identical
96)
with
by the help of
But
is
does not at
all
denned
in
95.
he employed
are, in all
the
more
by Balfour Stewart.
II
HEAT.
Two
vertical
[CHAP.
glass tubes,
full
The
of mercury.
capacity of this
or unscrewing,
One of the tubes
a plug
in,
is
open
by screwing
or
piston.
at the top,
A,
mented on.
much
This
of the stem as
balloon,
is
and
as
necessary, are
atmosphere
When
is
volume
at con-
be measured, the
screwed in or withdrawn till the
stant pressure
plug
134).
the change of
is
to
The pressure of
peratures selected.
the gas in A is then exactly that of the
atmosphere for the time being, and the volume of the gas
in A and its stem must be accurately measured at each
correction (small in comparison with the
temperature.
change of volume of the gas) must of course be made for
is
to
be
column of mercury
in the
barometer
vi.]
by heat, there
101
also to be applied
is
its
dilatation
by
Thus the
Then,
filling
it
100
C,
was thus
air
to seal
128.
The
obtained
by the
first-
first
00 to
iooC. when
taken at a pressure
without change of
o
and
heated
at
C.
atmosphere
the pressure at
of
those
with
agreed satisfactorily
described apparatus.
The
it
rarefied
volume
the gas
is
....
Hydrogen
Air
.
Nitrogen
Carbonic Oxide
1*3667
1-3661
..
1-3670
1-3665
1*3668
1*3688
1-3670
...
-3669
Carbonic Acid
1-3710
Sulphurous Acid
-3903
.*
...
-3667
'3845
It is to
the
second.
as the four
first in
all
such
nearly equal
easily liquifiable
is
the gas.
The
HEAT
102
[CHAP.
greater
Pressure in
Any
;
j
i.
at
0-1444
.
:'
Ratio of increase of
pressure from o to 100
o.
.
'36482
'
<
pressures
Atm ^spheres
initial
\i.
.GarlMnic Acid,
<
-O3OO
'36650
4'8i
'3709 1
0*998
'36856
4722
-38598
Air
...
Pressure in
Atmospheres.
i
3-447
Hydrogen
3-349
Carbonic Acid
3 '3i6
We
Thermodynamic
in the
...
.
same range
Ratio of volumes
at o" and 100 C.
....
....
1*36706
1-36964
1-36613
1-36616
when we come
"37099
to consider
of matter.
130.
esumtof<
117
129.
Dilatation of Liquids;
Dilatation
Carbonic Acid.
especially Mercury and Water.
of Gases. Laws of Boyle and Charles.
Another hint of an
Absolute Zero of Temperature.
Regnault's results as to
of
volume
under
constant
pressure, and change of
change
CHAPTER
VII.
THERMOMETERS.
131. IT seems now certain that the first inventor of the
thermometer was Galileo, before 1597 (see Memoire sur la
Determination de VEcheUe du Thermometre de V Academic del
His
Cimento, par G. Libri, Ann. de C/iimie, xlv. 1830).
thermometer was an air-thermometer, consisting of a bulb
dipping into a vessel of liquid.
use to which it was applied was to
with a tube
The
first
The
the
air,
down
the
similar instrument
for
changes
HEAT.
104
[CHAP.
counted
for,
in glass,
were
first
in the
Memoirs of
to
the
Academy
have
lost
long supposed
themselves could not be compared with our present ther-
mometric
scale.
One
Academy employed
The
made by Newton,
for
first
constructed
graduation
is
countries.
ice
is
The Centigrade
Upsala.
In
it
scale
the freezing-point
The obvious
simplicity of this
mode
of
THERMOMETERS.
vn.l
the
points
105
of reference has
caused
to
it
marked o, and the boiling point 80, is still used for some
medical and domestic purposes on the Continent of Europe.
The
furnishes an
uniformity in
into
in imitation
of the division of a
fact that
The
its
and
For, if/,
it is
f
that c
and
^,
obvious that
;-
bears
to
bears
to
32 or) 180,
J
oo,
So.
HEAT.
io6
[CHAP.
Hence
32
180
[So
__ _
= 100
r_
80
But, in this
legitimate and also necessary.
of the ipth century, the progress of science (!)
far, all is
latter half
seems to demand
To prepare
we append
/ -:-A2
__
180
so that
is
f-
Again, to find
sum of its
the
JL
100'
-_ 4 o.
the temperature whose Centigrade reading
Fahrenheit and Reaumur readings, take
c
=/
r,
and we have
c
= 32 + -180-
80-
IOO
IOO
4,
f,
whence
c
We
-20.
Also,
;-
1 6.
may
at
desirable appointments.]
133. The glass tubes for liquid thermometers are drawn,
not bored, and it is therefore necessary to go through the
THERMOMETERS.
VII.]
107
of calibrating them
first, roughly, in order to
are not nearly uniform in bore throughout ;
then more carefully, so as to discover and tabulate the
process
This
a
little
by
is
It consists in
to point,
it
introducing
in length
to slide
and,
from point
and measuring
tion.
The narrower
a dividing engine.
The
is
The
to
expel
little
air,
is
now made
to boil
its
HEAT.
loS
[CHAP.
The
bulb.
sealed.
lies
pressure of
134.
curial
its
own vapour
only.
always desirable to have the range of a merthermometer made long enough to include both
It is
instru-
ment.
When
the range
is
is
left for
some
time.
THERMOMETERS.
VIL]
109
till
carefully
if
the zero-point
is
Boiling point.
carefully observed
The instrument
and
is
registered.
now
to
be immersed,
cut shows fully the arrangement usually adopted, and requires no explanation ; but we must show how to define
accurately what is meant by a pressure of
6 1, footnote.)
(See
The
atmosphere.
The
when
C.,
The change
stands at
2 9 '90 5
London.
HEAT.
~_L
[CHAP,
(5
"^^ 1 ^
1
;=
" ^
:: - :
^;
THERMOMETERS.
VI,.]
in
than 100 C., and rather more for temperatures above that
point.
The
till
we
heat.
165.)
(See below,
The mercurial thermometer is useful through a range
of temperature from a little above the melting point
40 C.) of mercury, to a few degrees below its boiling
(
135.
When we
much
its
mometer
40
C., alcohol
freezing-point
is
is
about
air- ther-
or, for
sensitiveness
is
carbonic acid
is
The
mum
thermometers
little
maximum
or mini-
ployed in a
i.e.
it
maximum thermometer
HEAT.
ii2
[CHAP.
panding, it passes freely but as soon as it begins to conthe column breaks at the narrow neck, and remains
:
tract
136.
But
all
so simple,
graphic process
time so instructive, that
we
an explanation of
and
it,
and
will
of
valuable, and
The
photo-
at the
same
some of
its
elementary
consequences.
It is
by an instrument
THERMOMETERS.
VII.]
made on
its
When
it
fixed,
below
stem,
may
easily
be recorded photographically.
off, developed, and
somewhat
To
find then
h
say 4 .4i
the line
m
,
all
we have
D E which
at that
The
slit.
maxima and
HEAT.
ii4
C in
[CHAP.
the sketch
is
obviously neither
maximum
zontal.
nor a minimum, although the tangent is horiAt one side of C it is above, at the other below,
the curve.
Another way
fact quite
itself, is
in
which
this
may be
put,
and which
is
in
maximum
(in
or
point of
time) are these equal values, the more nearly does either
coincide (in time, and also in magnitude) with the maximum
or
minimum
sought.
consideration
[This simple
enables
us to solve
many
problems which are usually thought to require the Differential Calculus, or even the Calculus of Variations, for their
proper treatment. Thus it suffices not merely for the investigation
that light takes the least time possible to pass from one
point to another, but also for the investigation of brachisto-
The
on which air-thermometers
apprehended from the sketch of
Balfour Stewart's apparatus in
127. If a metal ball be employed, as in fact must be done if very high temperatures are
to be measured, the gas must be preserved at atmospheric
138.
general
are constructed,
is
principle
easily
had on hand.
THERMOMETERS.
ML]
The
H5
and Rumford
is
really a
air,
is obviously unaffected by changes of barometric pressure ; it can be made very sensitive, and it is
Leslie made all his experiments
therefore of great use.
made, he converted
it
aethrioscope, &c.
I
HEAT.
[CHAP.
The Mean
Another method, originally suggested by Moseley's obseron the way in which, in consequence of alterations
vations
The
teeth
and grooves
are so
shaped as to
offer
very
ture
THERMOMETERS.
vii.]
117
the fluctuations
140.
How
of temperature.
Resume of
131
139.
its
it acquires
the
elevated position, is
mometer.
Celsius, and Reaumur.
Scales of Fahrenheit,
Ranges
Thermometers.
mum
meters.
Properties of a
Maximum- Minimum.
aging Thermometers.
Differential
The
Creeper.
Thermometer.
Aver-
CHAPTER
VIII.
MELTING AND
SOLIDIFICATION.
141. IN sections 45 and 48 above we have given a general
sketch of the part of the subject to which this chapter is
devoted.
The student is recommended to re-read these
When
it
will
a similar recom-
."
',
till
melted.
This
Heat.
is
that heat
is
This
will
CHANGE OF MOLECULAR
CH. VIIL]
if
STATE.
to reduce a
119
mass to
fine
and
experimentally by
Sir
W. Thomson
Hopkins, Bunsen, and others, have experimentally determined the elevation by pressure of the melting-points
of substances which expand on becoming liquid.
As an
143.
instance showing the nature of the experithis statement rests, we refer again
to the process of determining the zero-point of the thermometer ( 134). There nothing is said about the rate at
i.e. about the
which the ice is melting
quantity of heat
See also
131.
supplied in a given time.
:
104) only a
MELTING-POINTS.
Ice
....,..,.
Mercury
Sulphur
Lead
Wrought Iron
Some
.,...-
Temperature C.
..>.;>,
40
in
335
1500
(?)
(which
metal "), melt at temperatures considerably under 100 C.
The recently discovered metal, gallium, melts at about
in
30 C. On the other hand, platinum cannot be fused
HEAT.
120
[CHAP.
As already
melting-point of a body
The
is
reason of
its
probably to
be
effect
even
when
may mention
the
145.
The
experiment,
for
theoretical result
is
for ice,
and vice
versa.
exactly verified
by
may be
of one ton weight per square inch, ice melts at one degree
Centigrade under its ordinary melting-point.
[Along with this we have to remark that the density of
ice is only about 0^92 of that of water, so that water-substance contracts by eight per cent, in the act of melting.]
Many of the consequences of this important fact were
Ons form
in
which
hundreds of years
is
it
But,
if
the
warmed
nearly to
its
melting-point,
it
in the
hands to be
MIL]
iii
"
"
making," or rather of
being made." Every time we see
a wheel-track in snow we see the snow is crushed, and even
after one loaded cart has passed over it,
certainly after
The same
people enough
pavement; and in all these cases
this
minute lowering of
is
especially
in
summer
freely
percolated
throughout by water,
its
but
it
wherever there
is
ice
it
melts,
from which
it
instantly
glacier
is
becomes
melted
ice again.
for
an instant
The only
at the place
where there
is
precisely as
HEAT.
122
[CHAP.
In
ment did not succeed.
he
with his Bramah press,
fact,
as
could
we now
not
apply
see,
even
pressure
enough.
hole in the end of a cylinder in which snow
compressed by a Bramah press, we obtain a cylinder or
wire of solid ice gradually squeezed through the hole, just
By opening a
is
as wires
are
made
of
soft
is
or
crystalline
metals.
The
through the ice, which melts before the wire and is immeso that the wire passes entirely
diately re-formed behind it
:
as strong as ever.
such as that of
is observed in lava-lakes
"
Hawaii, where the crust cracks in different directions, and
first one half of the lake and then the other is covered with
phenomenon
Yin.]
123
temperatures
above
far
and therefore
though at
solid,
doubt
is
if
at
once
we suppose
to be such as,
immense
pressure to which they are subjected from superincumbent strata is probably sufficient to raise their melting-
remain
present
temperature.
But
by the cooling
and shrinking of the lower strata within the solid crust
this pressure 'should be anywhere considerably relieved,
the mass affected would (almost explosively) melt with
solid,
if
and of uniform density equal to its predensity, the pressure within a few hundred miles
liquid throughout,
sent
mean
*
J.
W.
Nichol, Prcc. R. S.
.,
1875-6,
p.
117.
HEAT.
124
[CHAP.
800 atmospheres
We
142.
experimental statement of
That the temperature of the mixture of solid and liquid
should remain at the melting-point, however much heat be
supplied,
till
is
Thus
caloric.
chemical combination
As
caloric.
of the
body by
this admixture,
this
solidified
in
amount of heat
molecular
state
alteration of
its
is
of a
substance even
temperature.
to
when
change the
is no
there
vni j
We
148.
in
are, as
which energy
yet,
125
"
Until
heat.
of the internal
we know,
particles of matter,
it is
it,
friable of
tained
supplied
to
a body without
producing
alteration
of
its
temperature.
[The student should carefully notice the words in italics,
for the same amount of energy can be given to the ice in
many
temperature
gravity, or
Thus
HEAT.
126
[CHAP.
be
communicated
atmosphere.
The
sists in
effects of
equal amounts
ordinary lecture-room form of the experiment conpouring over a pound of ice at o C. a pound of
it is
of the ice
still
just
melted
o C.
from o to 80
C.,
it is
has lost 80 units of heat, which must have gone to the pound
of ice with the result of melting it without raising its temperaHence it follows that (in accordance with the definiture.
tion of latent heat,
150),
80
is
mode
upon
from ice
we may form
some extent
vin.]
127
in temperature.
The
paraffin, as they are gradually raised
welding of iron and of platinum, at high temperatures, is
another case in point. And several excellent authorities
What
farther
profitably deferred
thermodynamic
we have
till we
principles.
of specific heat, just below the melting-point, might, if undetected, lead to an over-estimate of the latent heat as we
have defined
it.
only be valid
but
its
But
if ice,
it is
is
trickling, is (all
C.
found to be a
153.
Phosphate of Soda
(crystallised)
Zinc
It is to
....
79 '25
67*0
28' i
Sulphur
9 '4
Lead
5 '4
Mercury
2 '8
We
the change
is
of the nature of expansion ; but water, castand some other bodies, contract. As the
iron, type-metal,
HEAT.
128
process of solidification
is
[CHAP.
and
crevice in a mould.
we
will
In
fact,
show when
treating of the
dynamical
lowering of the
freezing-point by pressure, we have pointed out ( 145)
that a pressure of a ton weight per square inch is re-
theory.
while
discussing
the
zero.
at a
temperature
viii.]
129
in the
form of heat.
Thus
solution of a solid in a liquid is usually accompanied by cooling. This is, in some cases, partially or wholly
One
results
may
yet
be obtained
When
salt,
or of salt
and pounded
ice
132).
HEAT.
130
[CHAP. via.
157. Conversely,
out,
we have
when a substance
in general a
in solution crystallises
development of
heat.
This
is
is
of crystallisation.
141-157.
158. Resume of
Pressure.
Melting-points of
Ice and Lava.
of Melting.
Solids.
Effect of
Behaviour of
Latent Heat in
Mixtures.
Law
some
Crust.
different
Heat developed
Liquids.
Solution.
in Solidification.
Freezing
CHAPTER
IX.
VAPORISATION AND
We
perature
called
There
is
no
very slowly.
state in
Whether
it
distillation of liquids is
example.
All but a very small fraction of the vapour conair, has been raised from the surface of
stantly in the
132
1
60. BOILING.
phenomenon
HEAT.
[CHAP.
Experiment enables us to
142, viz.
The pressure remaining the same, there is a definite boilingpoint for the free surface of every liquid ; and (provided the
mass be stirred] however much heat be applied, the temperature of the whole remains at the boiling-point
till
the last
particle is evaporated.
The
of pressure upon the boiling-point can be calwas that of pressure upon the melting-point but
as we do not know of a substance which (at the same
temperature and pressure) occupies less bulk in the form
effect
culated, as
So
far as
water
is
concerned,
we have
already
We
will
and
in a
now
treat the
manner
60) given
this subject.
similar to that
The
first
behaviour
even
is
due
cision,
and
ix.J
133
pushed in
volume,
HEAT.
134
for fresh
and part
[CHAP.
is
This
diminished.
is
by
intro-
with mercury, as
the tube is inverted
filled
When
of mercury, there is a definite amount of depression of the mercury column (as compared with the
barometer), which is not altered by plunging the tube
in a vessel
while b
is
The second
The same
if
air
that in
many
old
and almost
IX.]
"135
fast as it is formed.
Then, obviously,
furnished very rapidly from the liquid
and
observed to come not merely from its surface, but in
air-pump almost as
fresh vapour
it is
is
And we
is
what
is
called boiling.
is subjected.
PRESSURE OF SATURATED
Temperature C.
in
Atmo-
spheres.
1-962
10
2O
30
4712
6*120
50
60
70
80
90
7 -844
9'929
12-425
i5-38o
18-848
22-882
TOO
110
at p.
made.
(a.)
We
see
water-vapour
how
rises as the
temperature
is
raised.
Thus
twenty-three atmospheres.
Compare this with the behaviour of a gas such as air
HEAT.
136
[CHAP.
(
124), where the pressure (at constant volume) rises approximately in proportion to the absolute temperature ; and
we see how very much less dangerous, so far as the chances
high temperature.
(b.)
Water
at ordinary temperatures
may be made
to boil
it
atmosphere
mercury).
the water
in the receiver of
(or,
more
accurately, to
9-16
millimetres of
And
is
ix.J
to
This
when we
subsequent section,
137
be explained
will
in
Heat of steam.
flask, it
it
on, at
im-
once
mountains.
portability,
to breakage.
calculated
The
from
Relation, etc.)
Temperature C.
99
r.
Inches.
Atmospheres.
0'9647
0*0348
T.
28*87
I<04 T -
much exceeding
accurate
values within
must be consulted.]
this
range,
Regnault's
full
table
HEAT.
138
[CHAP.
8 4 4 C.
(d.}
We
see
why
solvent and
used
temperatures
far
above
its
ordinary boiling-point.
TX.]
139
But the
temperatures were given by Watt and others.
doubtful
until
remained
cleared
it up.
subject
Regnault
He
gives for
temperature
what he
tC.
of steam, at any
606 '5
0*305
/.
out 606*5
30*5 (or 637 units) in passing to water at o.
In the next chapter the (very small) variation of specific
from
606 *5
to
536'5 at
and
The
latent heat at
to
oC.,
at
464*3 at
100,
200.
any temperature
is
For most
pound of water
same temperature.
may be
taken as indi-
and amounting
hundred
pound of water
i.e.,
at o C. into
true the
sums of the
of numbers should be
HEAT.
140
[CHAP.
approximately equal. They are not so, and they show that
Watt's statement involves an error in defect amounting to
When we
for every
hundred degrees
this question
more
we
shall
fully.
of
ATMOSPHERE PRESSURE.
Water
536-0
Alcohol
2O2'4
Ether
90*5
Bromine
45-6
68.
its
consequences.
steam
is
condensed as soon as
it
but as the
As soon
as the water
is
is
steadily
going
ix.]
141
The
is
utilised in
is
many
kept
a glass vessel
and placed
is
is
employed,
if it
in a current of air.
rice-straw.
in
shallow unglazed
More
saucers,
upon
is greater as
the temperature of the air is higher. The cooling of water,
when it is made to boil at low temperatures (by reducing
the pressure, as in
165 (b) ) is due to the same cause.
This process, with a quantity of dry oatmeal or a large surface of sulphuric acid (to absorb the vapour as it is formed)
HEAT.
42
core of the
jet,
which
in a proper
collected
is
[CHAP.
receiver
as
snow-like mass.
It
is
is
213).
in
If the dish
fails.
experiment
Faraday succeeded
in freezing
platinum
crucible.
170.
The
reader will
now
easily
understand why
it
is
an exhausted receiver.
in
171.
We
In
We may
saturation.
viz. that
ture falls
is
another form,
in
Regnault's table.
And it
164, to the pressure of the water-vapour present.
found by experiment that the pressure of air or other gas
Hence,
solid
if
this result
we present
ix.J
will
43
take place
become
thicker, until,
in
pressure.
film freezes as
Hoar
it
is
is
C. the
called
Frost.
In Hope's experiment
the freezing mixture
frost,
it
is
however warm
contains a moderate
172.
The
is
It is
meant by the meteorological term, the Dew-point.
the temperature at which saturated water-vapour would have
the same pressure as that of the vapour present in the
air at the time ; and it could therefore be found directly
164)
air.
if
we knew the
quantity of
is
that
at
any time.
a body
is
show
at
The instrument-maker
boils
HEAT.
144
[CHAP.
this ether ; and hermetically seals the second bulb when the
ether-vapour has expelled the air from the whole apparatus
To use the instrument, pour a few drops
165 (b) ).
(as in
bulb.
black bulb
is
instant of the
first
again read at the instant that the dew disappears, when the
.apparatus begins to be heated again to the temperature of
the air.
It is usual to assume the mean of these readings
as the dew-point.
Cryophorus ( 169).
Another method of finding the dew-point
Two
by the Wet
thermometers
bulb covered with
is
similar
The thermometer
water, so as to be kept constantly moist.
with the naked bulb shows the temperature of the air, the
other shows a lower temperature, which differs from the first
consequence of the evaporation constantly going on from
in
temperature small.
But
if
if
ix.]
145
48
30
barometer in inches.
To a
as yet, empirical.
The full treatment of the question
theory remains to be discovered.
is,
by
The
the air
What
HEAT.
146
[CHAP.
pressure
But
is
it
it
not liquid), by
them .under
It was Andrews,
great pressure.
first
cleared
the
whole
who
however,
up
subject by showing
the nature of the distinction between what may now be
heating
The
this
critical
substance
great*
is
high,
and
3o.9C, and
That
for carbonic
it
On
ix.]
147
Carbonic Oxide
plished.
is
Cailletet
effected in the
and
end of 1877
this
complete verification of
Andrews' s law.
175.
When
a gaseous substance
is
at
a temperature higher
than
its critical
it
a true gas
The
when
distinction
is
was reached.
till
At 3i'iC., which
now reduced
to
7 |^- of
L 2
its
HEAT.
148
[CHAP.
ix.
original
rapid
became
fall
less manifest,
and
at
48
it
could no
longer be observed. [This question will be more fully discussed in Chapter XX. below.]
176. For the formation of liquid water from ordinary
vapour a nucleus of some kind must be present, else the
vapour
may remain
in a state of saturation,
of supersaturation, without
condensing.
sometimes even
This
has
quite
of dust in the
air.
These dust
particles are
found to be
would
fall,
and the
air
would get
rid of its
superfluous
it.
Resume of
177.
Law.
159-176.
Vaporisation.
Dalton's
tinction
Point.
Condensation.
Dew-point.
DisHygrometers.
Andrews's Critical
CHAPTER
CHANGE OF TEMPERATURE.
178. Refer
again
to
45-48.
X.
SPECIFIC HEAT.
In these sections we
of temperature of water
as
heat
is
substance,
steadily applied to it, in the solid
and
liquid,
gaseous forms, and the question immediately
rise
define, as a property of
The
is
called
its
Specific
Heat, as
specific
ditions, is the
heat of a substance, under any specified conunits of heat required, under these
number of
HEAT.
150
by
[CHAP.
C.
We
and
F.
32
80.
for deter-
We commence
;
with
a process, in fact,
know
that
its
be the same
at
by radiation will
be the subwhatever
one
temperature
any
CHANGE OF TEMPERATURE.
x.J
'151
Now
pose.
water
is
specific
heat of mercury
8 1. .The process
is
found
we have
The most
in this
way
just described
to
be about
is
liable
to
loss of heat
by
is
in
Although from
great accuracy,
its
it
it cannot
pretend to any
always free from large error ; and is
very nature
is
HEAT.
152
therefore an
calculation, in
[CHAP.
serious mistakes.
CHANGE OF TEMPERATURE.
x.]
reduced
'153
data of part of an
actual experiment
is
intervals
Then
136.
1
if
rate of cooling at
86, be required,
zontal line
all
that has to be
where
Hence the
rate of cooling at
186
is
73
in
i7
m>
6,
or
4'i5
per minute.
Even the best mercury thermometers, when the column
is rising or falling otherwise than very slowly, are found
to
move
the
for
sticking
column
the bulb
Hence
to pressure or tension.
recovers by starts from
state
of dilatation.
readings
and
of the successive
midway between
interval in question.
'
HEAT.
154
inserted
now
on the right
[CHAP.
Its
numbers are
We
it
impossible to
any
former method.
preferred.]
182.
Another
case, as to
method of determining
specific
heat
is
which
it
is
amount of
ice
melts.
specific heat
from
CHANGE OF TEMPERATURE.
X.]
155
forces.
necessarily retained
by capillary
others, the
with,
is
HEAT.
156
The
result of
[CHAP.
By dividing
passing from a known temperature to o C.
the number of units of heat lost by the number of pounds
of the substance and by the number of degrees of change
of temperature, we obtain the Average Specific Ifeat of the
other,
183.
determine the
it,
when
perature,
acquires.
results, are
easy.
if
we
exceedingly troublesome
Suppose
pounds of one substance, at temperature
C., to be mixed with ;;/ pounds of another substance at
and suppose the mixture (all
a lower temperature, t C.
the
have
to
corrections made)
temperature T C., which must
Then the
and /.
obviously be intermediate between
If the
heat lost by the one substance has gone to the other.
s respectively,
two
substances
be
*Sand
heats
of
the
specific
the loss of the
first
(in units
of heat)
M S(T
T).
is
CHANGE OF TEMPERATURE.
x.]
The
is
(in the
same
/)
///
(T
'157
units)
S
s
m (r /)
-~M(TT)'
or, if the
second
J/from Tto
T, s
It is well to
if
no heat be
that of
from
r to /.]
lost
by radiation or evaporation,
MS T +
vi
is
sf
extent,
[And we
is
given
and
same
as
inertia
that
numerical value
is
(See
249).
HEAT.
153
[CHAP.
We
184.
of such
however,
determinations,
if
they be
in their circumstances,
it
of the temperature.
at o C. requires
it
it
to
units to
to 200 C.
H
which
/
0*000,02
/'-'
0*000,000,3
^ 35
any temperature,
+ o'ooo,o4
+ o'ooo,ooo,9
/2
Thus
The
that of water.
at
oC.
is
is
That of platinum
assumed
as
about
is
0*2.
slightly
c.
for
iooC.
subject, as different
results.
But we have
CHANGE OF TEMPERATURE.
X.]
SPECIFIC
HEAT OF ELEMENTARY
Lead
Tin
0x31
Copper
0-095
0-056
....
Iron
Sodium ....
Lithium ....
The
118
63-5
0*293
56
23
...
0-941
59
SOLIDS.
207
...
0-114
...
...
.
...
.
6'4
6*6
6-0
6-4
67
6'6
column of the
the
different bodies
all at
compared are
much more
183)
we put
it
in the
form
is
solids.
been found
to
In general, as
we have
HEAT.
160
is
[CHAP.
greater than in the solid
state.
SPECIFIC HEATS OF
ELEMENTARY LIQUIDS.
Lead
Tin
0*040
400 C.
0-064
Mercury
0*033
C.
3C.
in
1 86.
of specific heat is not only more difficult, from the experimental point of view, than in the case of a solid or of a
but
liquid,
of view.
gases,
also
theoretical point
of
the
consequence
great expansibility of
have to specify the conditions under which the
it is
For, in
we
is to be made.
Thus the gas may be maintained at the same volume, or at the same pressure, throughAnd we therefore
out the range of temperature employed.
measurement
speak of the
Specific
Heat at
Heat at
constant pressure.
Thermo-dynamics gives
us a simple relation between these quantities for the ideal
perfect gas ( 126); and therefore for gases such as Air,
Specific
Hydrogen, &c.,
one of the two
it
is
specific heats.
cumstance, because the experimental difficulties of determining the specific heat at constant volume are extremely
The mass of a gas at ordinary pressures is small
great.
make
the
proportion.
vessel
strong
(and
therefore
massive)
in
CHANGE OF TEMPERATURE.
x.]
161
The measurement
is
its
up
but
theoretical
of
point
view,
must
be
deferred
for
the
present.
air,
this
class,
at the
specific heats.
Air
Nitrogen
It will
inverse
2 37
0-244
Oxygen
Hydrogen
....
....
0*217
3'4CQ
of the
densities
of the various
in the
gases
(see
184).
HEAT.
62
The
dition
[CHAP. x.
0-48, a
little less
than that of
Hence
184).
Resume of
178-187.
Change of temperature cf
mass by a given quantity of heat. Specific Heal.
Method of Cooling. [Digression on Graphic Methods.]
Method of Mixtures. Water EquivaIce Calorimeter.
Thermal Capacity. Relation between Specific Heat
lent.
iSS.
unit
Specific
Heat of Gases
Specific
(a)
at
Heat of
CHAPTER
XI.
THERMO-ELECTRICITY.
189.
We
in
by Seebeck ; and
examine the subject more closely from
For this purpose we must
the experimental point of view.
use the term Electro-motive Force.
So far as we* require its
as
be
enunciated
follows
properties they may
we now propose
to
The
lowing figure
Jour
where the
circuit is
supposed
to consist
of
wires, alternately of
See. again,
fol-
HEAT.
164
[CHAP.
it
at the
temperature
and
with
and
together
Hence
e.
the assumptions
made
(in brackets)
as the figure
e',
provided
Iron
Iron
wire
AB
and
Hence the
whole E.M.F. of such a
produces no
effect.
circuit
depends
E.M.F.
in
viz.
to
.,
a simple circuit
THERMO-ELECTRICITY
XI.]
are at
and
tn will
be the sum of
its
/,
and
'165
separate values
/,,
tl
and
/2,
when
&c, and
and 4.
We
The
as.
is
E.M.F.
for
any
t\vo
assigned temperatures
of
the June-
HEAT.
66
[CHAP.
tions)
result
than that in
sum of the
p and y, is
At
189.
thermo-electric
Then
and
(if
B and C had
the
same temperature)
Iron,
'Cold
would give E.
temperatures
J/. F.
/<,,
/;
B and C
JE.
M.
F. due to a copper-gold
It
is
190, we form the lines representing the positions of iron and of gold, each with regard
to copper taken as the standard, the lines so drawn will
Thus
if,
by the process of
of
iron
and gold
relatively to
one
THERMO-ELECTRICITY.
XI.]
Hence
another.
167
electric
Diagram
The idea of such a representation was suggested by
W. Thomson in 1855, and he gave a rough preliminary
A "first approximation"
it.
was given by Tait in 1873.
an accurate
sketch of
to
diagram
This
duced on a small
198, but
scale in
it
is
repro-
cannot be
fully
much more
simple
formerly possible.
192.
The
electric
current
in a
thermo-electric
circuit
When a
current
of
electricity
two
from an external
metals, it
causes
source
an ab-
same as that of
the
absorption
and vice
versa.
Two
their
This
is
one of the
free
HEAT.
168
is
maintained in connection
end
with
[CHAP.
in connection with
is
circuit
circuit
of the galvanometer
the iron-
And
is
it
reversed.
The
which
is
sought.
When
The
direct quantitative
measurement of the
Peltier effect,
difficulties.
yet,
The
stated below.
is
for
current employed.
193.
It
phenomenon
first
remarked
THERMO-ELECTRICITY.
XL]
of a thermo-electric current
may
whose
circuits
will
and
be pairs of metals
there
it
is
it
is
'169
(more probably
alloys) for
[This
be seen in
199 below.]
But a phenomenon, noticed by dimming very soon after
the publication of Seebeck's discovery, shows that the
Peltier effect
follows
is
This discovery of
current.
Cu mining's may be
stated as
if one junction be kept at ordinary temperathe temperature of the other be steadily raised, the
iron-gold,
etc.,
and
E.M.F. increases more and more slowly till it reaches a
maximum, then gradually diminishes, and finally is
tures,
reversed.
At that
Sir W. Thomson explained this effect as follows
temperature of the hot junction for which the E.M.F. is a
maximum (in Cumming's experiment), the two metals are
:
neutral
to
vanishes,
one another,
and
their
i.e.
thermo-electric
power
figure in
which the
which the hot junction is at the neutral temperature, and the other at any lower temperature: we
cannot suppose the energy of the current to come from the
circuit,
heat
in
of the
neutral
to
hot junction
for,
Peltier effect
must be
there
nil.
and
it
HEAT.
i;o
in
[CHAP.
The assumption
that
the
Peltier effect
vanishes at the
We
this to
show
is
is
with
consistent
electric diagram.
It
is
that
may be
experimentally established.
An
it
When
is
absorption of
heat,
and
from
In iron
vice versa.
the opposite.
This
"Thomson
effect"
is
Convection of Heat.
As
will
above statement, so
far
as
be seen
iron
is
later
concerned,
199),
the
requires
a special expres-
THERMO-ELECTRICITY.
xi.]
in terms of temperature.
In
fact,
171
Peltier effect
two metals,
the junctions have the same temperature (as in
190), but also when their temperatures
When one
are equidistant from that of their neutral point.
that the thermo-electric current, in a circuit of
of the metals
is
when
named.
Nature,
86 and 122.
HEAT.
172
LCHAP.
Hence,
if
electricity at
directly
proportional
Le Roux,
in
1867,
measurements of the
showed
that
it
is
is
in general
null,
made a
valuable
electric
convection
series of
of
direct
and
heat,
in
lead.
196.
We
are
now
of the thermo-electric diagram, and to use it for the calculation of the Peltier and Thomson effects, showing fully
is
derived.
the figure
circuit
is
N.
Then
E.M.F. of
the copper-iron
I' /; and, as
C
area
the
190) represented by
a
current
it
going round the
drawn,
produces
neutral point
in the positive
the
direction as
shown by the
arrows,
[The
THERMO-ELECTRICITY.
XL]
reason
why
being positive
the amount of energy of the current, if
properly adjusting the resistance of the
it
be made unit by
circuit.
Now
(by
DICE
condition.
And therefore
the area B!
Both of these represent absorption, for the current passes from cold to hot in copper, and
from hot to cold in iron. It will be easily seen (by Euclid)
that
G C is the
(positive) while
K I (negative)
BC
in, in
is
C' I'
copper at
C.
that in iron.
HEAT.
174
DICB
[CHAP.
The
represents energy given out in that form.
C C' 1' f, remains for the production of the
difference,
thermo-electric
current.
Thus
the
In order to
first
law of
thermo-
make
dynamics
is
satisfied.
in the circuit.
To show
of
all
[It will
BD
+ BB' + D' D =
be good practice
o,
which proves
are
corresponding diagrams, when one or both junctions
THERMO-ELECTRICITY.
xi]
'175
Here
tive,
A
C
and
at
The
negative.
and A, B,
We
junction B, C, is at / C, A, at /2
and the area bounded by the doubled
,
now
197. Let us
consider
the^.J/!/!]
how
CCI'I
Of
i.e. it is
Hence
When one
at a
is
neutral point.
HEAT.
i;6
[CHAP.
upon
circuit of
1
and shortly afterwards by
given by Akin in I863,
2
As this explanation has already found its way
Avenarius.
into some text -books, it is necessary to direct the reader's
other
Among
the
Thomson
defects
effect,
it
it
cannot possibly be
ignores entirely
the
correct.
existence of
as a vera causa
198.
R.
by independent experimenters.]
thermo-electric diagram opposite (from Trans.
1873) contains the lines of a number of common
The
S.
.,
be shown
in
limits, that
195) the line for lead has been adopted as the axis of
along which temperatures are measured.
abscissae
An auxiliary circuit
num was employed
The
plati-
is
range of
alloys
for
of a circuit of these
xii.,
THERMO-ELECTRICITY.
XL]
100
Pl>
200
3pQ
177
^X.
40QC
HEAT.
178
The
remark
[CHAP.
is
veniently studied
(as,
indeed,
is
N (one
If
we
"
little, if
any,
Thomson
effect.
On the other hand, in the circuit of the two alloys, whatever the temperatures of its junctions, the current is due
almost entirely to the Peltier effect.
It is
for
them
at a
still
200. In practice
THERMO-ELECTRICITY.
XT.]
179
when
large in themselves,
the whole
quantity measured,
and may
thus to a con-
But
what
it
is
is
For
This
by a very simple
whose line
of two given metals.
process, to procure
possible,
virtually a metal
shall lie
anywhere
this
is
thermo-electric position.
between them
is
much
the calculation
Then if
when
Ia
be
(different)
the current
when
constant temperatures.
is cut, Tb the current
when
all
the
wires
are
continuous will be
(b
+ c) Ia + b(c+a] I
bc+ca + ab
In practice the resistance c includes that of the galvanois usually large compared with either a or b;
meter, which
HEAT.
i8o
[CHAP.
sufficiently approxi-
a+b
By
we can
fill
up
all
the gaps in
the diagram.
201. To conclude this part of the subject, we give a
brief table of approximate thermo-electric data for some
common
metals.
SPECIFIC
Fe.
Pt
(soft)
Ir
Mg
Arg
Cd
Zn
Ag
Ru
-00247
-
'00056
'OOOOO
- -00048
- '00260
+ -00218
+ -00122
+ '00076
--00106
Sb
Co
--00585
The
of course, temperatures.,]
not,
HEAT OF ELECTRICITY.
'01140
Au
+
+
Cu
Pb
Sn
Pd
-00052
-00048
-OOOGO
-00028
- -00182
.--00260
Ni (to i/5C.)
Ni(25o
3ioC.) .-f -01225
Ni (from 340 C.) - -coiSo
- -00058
Rd
Bi
.
-0055
Al
+ '0002
absolute temperature C.
THERMO-ELECTRICITY.
XI.]
E.M.F.
because
adopted
181
enables the
it
The mode
rents in general.
be given
will
when we
later,
discuss
same
be each of the
[This
any parts of
circuit, or in
it,
had no
when
is
material
effect
on the E.M.F.
is
But
and
it
when
it
irregularly heated.
circuit
behave
to the
metal.
different
is
Resume of
produced.
189-202.
perties of thermo-electric
electric
power
Thomson
denned.
Effect.
Consequences. Thermo-
circuits.
Peltier
Effect.
Neutral
Point.
Thermo-electric diagram.
the Peltier and Thomson
How
it
effects.
Anomalous behaviour of
diagram experimentally.
Nickel and Iron. Circuits in which there is (a) no Thomson
the
effect, (b)
of wires.
no
Peltier effect.
Null
effect of
and
unequal thickness
strain in a wire.
CHAPTER
XII.
204.
this
chapter
we propose
to
effects of heat,
collect a few
odd
the discussion of
is
afforded by what
is
commonly called
placed that
two bodies have acquired almost the same temperaof this phenomenon, given by
Leslie and confirmed by Faraday, depends merely upon the
until the
ture.
The explanation
CH.
xn]
cold metal
'183
it
the
The
effectiveness
of
the
arrangement
is
much
oiten
character,
sometimes
almost
are
vocal,
produced.
206. An interesting example of the effect of heat, upon
what are usually called "molecular" forces, is supplied by
the modifications produced on capillary phenomena.
is
to
becomes
less
temperature rises.
The former phenomenon
spection,
is
becomes
easily seen
by
less
the
as
careful
latter is established
in-
by a
UNIVERSITY OF CALIFORNIA
DEPARTMENT OF PHYSICS
HEAT.
84
[CHAP.
applied under the middle of the plate, the effect of the lamp
of exactly the same kind as that which it would produce
is
on a
The
tension
of
water overcomes
colder
the
surface tension of
hotter
the
we
the
surface
diminished
water,
get
little
is
one
In
dragged away on
case, as
it
is
in
all
the
other case from the point at which the alcohol was applied.
Thus we see why a drop of solder seems to be repelled
this
water surface
ture
is
surface
is
is
in
greater.
more
raised.
bottom, with a
it.
its
curva-
less as
the
is
is
is
little
when
first
the
W. Thomson, who
phenomenon, considers
that
it
xn.J
'185
subject of boiling.
Water
than in one
made of
glass.
air, it is
its
it
boiling, just as
176)
it is
The phenomena
HEAT.
186
[CHAP.
into
the basin
there was violent boiling, blowing out the upper part of the
column of water and thus relieving the lower part from
;
pressure, so that
it
also
Then
boiled explosively.
colder
water, from the geyser basin, ran back into the shaft, and
the gradual heating from below recommenced.
It is easy to exhibit the phenomena on a small scale, by
artificially
and thus
210. In
60, 134, while denning the fixed points of
the Newtonian thermometer scale, we used the terms pure
ice &c\&pure water. This implies, of course, that the freezing
and
of water (and
boiling points
affected
by impurities held
of other
in solution.
liquids),
are
[Mere mechanical
muddy
water,
It is
is
then
below 28'5 F.
salt is
He
froze
it,
water.
the process.
The
1*0025 to
1*002.
He
ty
converse process, removing in succession the various iceformed at lower and lower temperatures from a tub
crusts
full
thus be procured.
211. Very extensive
and
how
careful
measurements
have
In all
of different degrees of concentration.
is above 100
C., and the amount of
salts,
rise is
in solution
Such
solutions,
when
salt
dif-
boiling, give
off
the vapour
But
just before
it
it is
to
is
certainly superheated
and
The temperature
water
is
of the bulb
is
at
a temperature
above 100 C.
212.
solution
The
is
HEAT.
88
[CHAP.
tion
point.
its
(with
on
until
accompanying disengagement of
the mixture rises to
iooC. such
its
solutions
boiling-
maybe
What
is
shall see
which, in
one
phenomenon
been known from remote
to test
we
whether a
how
is
at least of its
times.
flat-iron is
When
finger in
fall
When
iooC.
in temperature,
the drop spreads over the surface, and rapidly boils away.
But if it be considerably hotter, the drop glides off from the
surface without wetting it, and without suffering much evapor[See Phil. Mag. 1850, I. 319, and 1832, II. 378.]
The phenomenon is easily studied by dropping water
ation.
The
water
is,
made
temperature of water
about 95 C. only.
is
found to be
xn.J
i3y
thirty-three
Hence
when we
momentum
come
move
acquired by
air
and vapour
in directions
more
and
which have
On
leaving it they
nearly perpendicular to the surface
particles
i.e.
more nearly
verti-
To
pressure in a vertical than in a horizontal direction.
in
the
a
thicker
or
a
similar
result
vapour
layer
gas
produce
mean free path (Chap. XXII.)
increased in length.
214. This simple consideration gives the explanation of
the chief phenomena shown by the Radiometer. This instru-
must be
may be
ment
to
much
an
axle,
each vane
side
is
When
is
polished.
The whole
is
fixed in a partial
vacuum.
is
on
Dewar and
HEAT.
190
[CHAP.
Another
216.
striking
The
ball is seen
to
glow
in
the middle of
more rapidly
when suddenly the water
than
it
comes
in contact with
it,
in air),
all
dark.
217. Brewster long ago discovered that in many specicrystals there are cavities, usually
Sang
microscopic, which are partially filled with liquid.
observed that little bubbles of gas in the liquid in the
cavities of Iceland spar seem to move towards the side of
the cavity at which the temperature of the crystal is slightly
If part of the walls of the bubble be formed by the
raised.
seem
that the
motion
is
distilling
known
facts.
Very
similar
is
He
merely an ordinary
found by trial that
XII.]
what
whose meshes are not too wide, over the flame of a Bunsen
lamp, the flame
is
arrested
HEAT.
192
match
lighted
unlit,
when
it
to
will
it.
[CH. xii.
be found
that the
the lamp
mixed gases can be
ture.
this temperature.
on molecular
curved surface of
tions.
liquid.
bubbles.
further remarks
forces.
Trevelyan
experiment.
Geysers.
solutions.
Our
in next chapter.
Safety-lamp.
CHAPTER
XIII.
As we have
7.
47, 51, 155
again to
we
know
almost
remarked
nothing as to the
(
38),
already
We can measure, in
state in which energy exists in a body.
general, the amount which goes in, or which comes out ; and
220.
we can
REFER
tell in
what forms
it
does
so.
work done
This
is,
however, as to
We
phenomena
fit
The
view.
producing heat.
HEAT.
194
[CHAP.
combine
we may mix
and
all,
in the
proper proportions,
The one
process
may be made
to
vessel
is
ac-
when
slow combustion
of heat
it
is
become
And
the quantity of heat thus proin the two cases, when the products
final state.
ultimately
heat.
So
far, well.
But suppose
mixed
that the
We
xiii.j
'195
We
69,
when
gases
the rest
is
be accounted
to
for
it is
is
evolution of
at the
mixture
is
about
stituents
greater than the sum of those of the conin the latter case the excess is- only
On the other hand, the volume of the first
\\\\
while
about TVth.
mixture is 3-6 per cent, less than the sum of the component
volumes
with the second mixture it is 17 per cent.
;
greater.
The
first
tell
complexity, and
We may
HEAT.
196
carried out with
various
[CHAP.
(common)
And
temperatures.
it
appears
The
37? 82 ) to chemical
combination
is,
in
its
elements at
The experimental
least, a matter of no great difficulty.
with
the
has
been
carried
out
of
work
great ability by
part
prominent among whom are Andrews,
and (more recently) Berthelot,
We must confine ourDeville, Thomsen, and Stohmann.
many
Favre
investigators,
and
selves to the
Silbermann,
more
It follows
from the
no way upon
one respect, a
great gain ; for it much simplifies the reasoning from the
results of experiment
but it is also a great loss, inasmuch
and final states of the system,
the intermediate transformations. This
the initial
and
is,
in
in
prevents our obtaining (by this means alone) any information as to the nature and order of the successive
as
it
steps of a
complex
reaction.
this
restriction
statement]
will
appear
at
once from
the
next
xin.]
its
197
of hydro-
nearly 50
per cent, greater for the former product than for the latter.
is
is
gas
statements of
223,
if
we wished
to
cause water to be
that of
pound.
hydrogen
The energy
is
essentially
find,
an unstable com-
compounds
is
and
We
is
essentially stable.
To decompose
it,
external energy
HEAT.
198
is
peroxide of barium
essentially stable, for heat is
required.
[CHAP.
cited,
of
elements
is
Here
developed.
Thus heat
effective
itself,
may be
it
can be
in
Light also
the decom-
alkaline
their
hydrated oxides.
On
transformation, in
heat
and
its
electrical
therefore, so far as
it
not chemical,
it
belongs
more properly
Although
accordance with
XIIL]
laws alone do
these
not enable
We
case.
any particular
1*99
us
must
have special data with reference to each pair of the substances involved.
These, of course, can be found only by
is
general results of
given by
will quote, as
one branch of
a specimen, a few
this extensive
subject as
Berthelot.
bases,
when made
to
combine
in
acids.
The
salts
less
as there
is
The
HEAT.
200
To
227.
remarks,
values of
illustrate
we
give
[CHAP.
further,
of roughly approximate
table
HEAT OF COMBINATION.
H
H
with
O2
C with O
C with O 2
CO with O
The
first
with
column
68,000
34,000
45,ooj
22,500
30,000
2,500
97>coo
8,100
67,000
2,400
and
Here H, O, C,
the proportions in which they combine.
stand for "atoms" (not "molecules") of hydrogen, oxygen,
and carbon, in the chemical sense of the term ; so that their
relative
masses are as
i,
16,
and
12.
Ib.
The
processes
of temperature.
is
Hence, to
effect the
If
it
could be
And we
xni.]
formation of carbonic
oxide,
and
its
ioi
subsequent farther
oxidation.
228.
Many
plosive mixture of one volume of oxygen with two of hydrogen requires a start, as it were. If the smallest portion of
combination
the
platinum.
is
may be due
to the heat
phenomena
as
it
An
excellent
and
We
will
typical instance,
HEAT.
202
[CHAP.
221
) is
To
any
such
way
diameter) in
its
water was
that
small hole
T|^th of a inch
in
made
orifice
of the jet.
The
cold
This was
led, after
analysed.
unignited
mixture
this
combustion
product
had
been
A
this
xiii.J
263
uncombined
tion
is
sociation
231.
to
On
assimilate
somewhat surprising, but its explanaWe must take account of the dis-
its
later.
that a liquid, at
any
definite
temperature,
we intend
its
We
is
have seen
in
kinetic
own vapour
common
at a
boundary,
disengagement and absorption of heat, the heat of combinaThe percentage of the whole, which is dissociated,
tion.
from zero at the lower limit of temperature (at, and
below, which there is no dissociation) faster and faster till
about half way, and then slower and slower till the upper
rises
limit
(at,
is
dissociated)
is
sociation.
When
begin to
yet ascertained),
HEAT.
204
mixture
(228)
requires a "start."
[CH. xill.
And,
if the
constituents be
such as to combine directly with evolution of heat, this commencement of combination is sufficient of itself to raise
the temperature, with the effect of producing farther and
This goes on (provided the gas lose
farther combination.
no energy to external bodies) until kinetic equilibrium is
established,
is
in the
i.e.
combined
which
the gases be
limit,
Stability of
sequences of the Laws of Thermodynamics.
Heat
of
combination.
Comcompounds. Displacement.
bustion.
Composition of flame.
Dissociation.
CHAPTER
XIV.
CONDUCTION OF HEAT.
We have already seen that
4, 73.
233. REFER to
bodies in contact ultimately acquire the same temperature.
This experimental fact is the necessary basis of almost all
our methods of measuring temperature. The same must, of
course, be true of contiguous parts of the same body. This
these
is
of energy
power
for heat,
is
matter of
common
observation.
We
HEAT.
20b
glass,
flame.
No
one would
try the
[CHAP.
is
melting in a blowpipe
similar piece of
wood
the body of a metal tea-pot owe their presence to a recognition of the same fact.
So does the packing of the interior
of a Norwegian cooking-stove.
Two of the ordinary forms of lecture experiment
also
may
be mentioned here.
First, that of
it
is
limits of the
thermometric
The temperature
at
is
between them.
impartially
much
CONDUCTION OF HEAT.
xiv]
faster
107
And
here
it
Fourier.
English at
The
least, conductibility
entire subject
or conducibility) was
developments may be said to have been suggested, or rendered possible, by Fourier's work. Its exquisitely original
methods have been the source of inspiration of some of the
greatest mathematicians
of
its
Ohm
work of
Fourier's,
attention
was
first
specially called to
Chapter XIX.]
236. Conducting power must,
sured
HEAT.
208
[CHAP.
from part to part of any one body, and what are the circumstances which have influence on it. We can then place
two different bodies under precisely the same determining
circumstances, and thus compare their conductivities by
comparing the quantities of heat transferred.
237. The simplest mode of passage is that in which the
transfer of heat takes place, throughout a body, in parallel
lines.
Thus, for instance, when a lake is covered with a
uniform sheet of ice, the ice grows gradually thicker if the
layers,
it is
Hence we choose,
solid,
is
vertically upwards.
a plate of
as our
typical
uniform thickness
form of conducting
and of
whose
(practically)
sides are kept permanently at two
different temperatures.
infinite surface,
infinite
of distribution of temperature
slab,
it
receives.
If,
To
conducting power.
is
the
The thermal
number of
con-
units
CONDUCTION OF HEAT.
xiv.J
269
at temperatures respectively
half a degree above, and half a degree below, that temperature.
The units which we employ are, as hitherto, the foot, the
the
minute,
pound, and
chapter we
special
will
show how
to pass to
In a
any other
system of units.
so
as
far
later.]
it
effects of
we
directly
ductivity
capacity.
itself,
it
and of
to the thermal
is
its ratio
[This ratio
Conductivity,
Thus
And, because it
temperature from those adjacent to it.
on
same
amount
across
each
to
the
goes
(thin) layer, the
p
HEAT.
210
[CHAP.
or
as a single layer.]
with
facts,
because conductivity
is
though directly based on the splendid work of Fourier) involves the same assumption, but here we can much more
CONDUCTION OF HEAT.
xiv.]
easily verify
and the
it,
verification
211
Chrystal.~|
realise experimentally
241. It is practically impossible to
the simple conditions which are assumed in the above
Hence, in order to measure
definition of conductivity.
the value of this quantity in different substances, experimental arrangements of a somewhat more complex character
must be adopted.
Two
The
of
requires a variable, but essentially periodic, state of temperature, maintained by external causes in one part of a
In
as a species of wave.
tion.
The
first
in
an
determination
of conductivity of any
real
value.
p 2
The
HEAT.
212
[CHAP.
principle
A
to,
the rest
inserted thermometer,
The
is
first.
us say, in the
have been left
night,
then be of the
will
no
heat
being applied. They
laboratory,
same temperature throughout, viz., that of the air, and all
bars
all
let
CONDUCTION OF HEAT.
313
faster
and
faster.
which
final
air
bar.
ing
The others showed each a rise of temperature, increasmore and more rapidly as they were placed nearer the
is
experiment, repeated
tures of the source, it
if
is
obvious that
accurate determination of
the
is
practically
the same throughout any cross section of the bar, unless the
section be very great, or the conductivity of the material
very small.]
243.
only
So
far,
we must now
HEAT.
214
[CHAP.
temperature
course, be
calculated
Hence,
temperature, and the area of the section is known.
the heat passing is expressed by a definite multiple of the
unknown conductivity. But that heat does not raise the
temperature of the part of the bar to which it passes, for we
have supposed that the stationary state has been reached.
Hence
must
lose
determination of the conductivity of the bar at the temperature of the particular cross section considered.
[The words in
italics are of special importance, as they indicate one of the
to
244. Starting afresh, we once for all heat the short bar to
a high temperature, insert its thermometer, and leave it to
cool in the neighbourhood of the long bar (which is, in
this
experiment,
left at
and
this
is
said
above
it
will
be obvious
by the short
that,
how much
bar,
CONDUCTION OF HEAT.
xiv.J
calculate
what was
^15
former
lost in the
experiment
along
it.
The
245.
But it also
the two bars in each part of the experiment.
some
the
actual
to
extent, upon
temperature and
depends,
246.
is
is
The
experi-
at the
242, 244,
given by direct comparison of the results of
of course that which raises by i C. the temperature of
unit
The
bar.
iron, in
results of
terms of this
unit,
Temperature C.
0*01506
Thus
would
it
at
first
100
.
sight
0*01140
200*
.
appear that
0*00987
the
conduc-
tivity
to find
it
so,
as conductors of heat
The
HEAT.
216
units,
[CHAP.
of Forbes's experiments.
of Forbes.
THERMOMETRIC CONDUCTIVITY.
o
100
0*0149
o'oi28
Temperature C.
Iron
.................................
German
In
in
Silver
this
..................
list,
all
...0-079
...0-057
o "0088
...
300
0*009
...
52-9(1+0-0014*)
53-4(1+0-000880
52-5(1+0-0009*)
0*0094
46-6(1+0-0009*)
seem
To
200
...
to improve
of temperature.
convert these numbers into thermal conductivities
rise
as defined
column of the
table.
indicated
Copper.
0-835 (l-:O*COI47/)
..............
Forbes.
'
0796
(,
-o.oo.870.
0-666(1-0-000230.
0-677 (I-0-002/)
0-6,9 (,+0-00070
.*,
.2-88(1+0-000040.
2-04 (1+0-00570
.
Lorenz.
Kirchhoff.
.Mitche,,.
247. It
final
CONDUCTION OF HEAT.
xiv.]
^17
order
in
electric
conductivity,
exist.
The diminution
tric
The whole
operated on differed
but also physically,
having been
cast, rolled,
drawn,
annealed, &c.
in
HEAT.
2i8
[CHAP.
strictly periodic,
to
ranges of the successive thermometers, and the postponement of their dates of maximum temperature, per unit of
length along the bar ; altogether independently of the rate
of loss of heat by the surface (provided this loss be everywhere proportional to the excess of temperature over that of
the
air).
The
cannot be given
Two
extremely important practical questions connected with this part of our subject are
249.
How
The
us
very
simple
instances
of the
application
of
earth's crust,
CONDUCTION OF HEAT.
xiv.J
219
(vertical) lines.
x under
This
the earth's
Then
this
becomes
d
dx
The
dx
The
rate at
which
its
temperature
S_v.
rises is dv-dt\
whence,
ness 8x,
;
\.:'v
:.'.
.,,
same quantity of
dr
r </?'\
dt
dx
dxl
is
full
HEAT.
220
When
251.
there
is
[CHAP.
we
have
dv
7/
'
whence
L
dx
Here A is the surface temperature, and J3jk is the rate at
which temperature rises per foot as we descend.
This
might have been obtained at once from the statements of
239.
Hence a
of the
If the conducting
power be
localities,
CONDUCTION OF HEAT.
xiv.J
221
heat.
This
feet in thickness.
252. Particular stationary periodic solutions of the equation, such as are due to surface conditions (any number of
which
solutions
equation
where
range
T
at
may
exist
is
is
the
the surface.
equation of
i.e.
To
introduce temperature changes of these quantities is unnecessary, because the range of temperature in any of these
And the problem
periodic solutions is usually small.
supposed
and capacity.
for
to vary
when
The
factor for
HEAT.
222
[CHAP.
provided their
The
travels
It is
rate at
is
and inversely
thermal capacity.
place in this case
may be
sea to
that
their heights
shall
tions are
CONDUCTION OF HEAT.
xiv.]
223
we should expect
in general character:
thermo-
that nearest
periodical
separate simple harmonic elements.
By the aid of this
method we can separate from the recorded indications of
strictly
its
attention.
We
The mean
42.
is
temperature
thermometer, and
about
rises steadily to
-5
C. at the highest
(251). The ranges of the annual wave are, for the various
instruments in order
8- 2
-6,
-7,
and o 7 C.
HEAT.
224
The epochs
maximum
of
[CHAP,
Multiplying together the right hand sides, and the left hand
sides, of these two equations, we have, as a test of their
accordance,
2
TT
= 6-302
some
The
is
27-4 =
-*~
238 nearly.
0-115
about 0*528.
125*6.
To
And,
0-017,
CONDUCTION OF HEAT.
XIV.]
235
underground temperature at two other stations near Edinburgh, where the materials of the crust are very different.
The
We may
roughest way, that the heat lost at present per annum from
the interior of the earth is capable of raising the temperature of its whole mass somewhere about one ten-millionth
of a degree centigrade.
The
Edinburgh Observations.
Heat conduction is essentially a dissipation of
energy for, whatever be the actual mechanism of the
233 again), and however short be its duraprocess (see
17, of the
257.
tion, there is
by
a lower temperature.
It would lead us far beyond the scope of such a work
this
to treat of the
as
HEAT.
226
[CHAP.
is
to
made.
discontinuity of temperature
a conducting body,
Hence
heat.
if,
if
is
impossible in
no sudden generation of
back by the help of Fourier's
there be
in tracing
arise
at that
De Senarmont, who
A
to
is
its
The
surfaces of
CONDUCTION OF HEAT.
xiv.j
this plate are
227
wax
centre) which
increases
plate.
when
the plate
is
of quartz
cut (i) perpendicular, (2) parallel, to the axis of the hexagonal prism ; along which the conductivity is the greatest.
If the substance (as in this case) be
homogeneous, the
thermal capacity
results of this
is
the same at
all
of
directions,
the
points,
this
ellipse
By measuring
and observing
we can
various orientations,
the
their
HEAT.
228
[CHAP.
When
the plate
is
the two surfaces are usually ovoid rather than elliptical, the
smaller ends being turned opposite ways on the two. This
arises
from the
When
of
the
conduction-ellipsoid
on the two
the hole.
261.
The
We know
made
that the
in general extremely
is
small.
may be
than o'oi.
The
very
to boil,
conductivity of gases
difficult to
measure.
is still
But
it
smaller,
and therefore
CONDUCTION OF HEAT.
Xiv.]
kinetic theory
the present.
262. Resume of
233-261.
its
2*29
consideration for
Mechanism of Conduction.
method
perimental
of crust,
Forbes.
Results
Angstrom's method.
of
Forbes,
Effects of
heat,
earth's crust.
and
of
in gases.
CHAPTER
XV.
CONVECTION.
263. Refer
above
now
it
will
to
so that
advisable
mately
73,
From what
74.
be clear that a
Convection,
as being
precedence
of
Radiation,
which
involves
more
inti-
should take
somewhat
also,
It
is
a subject
except in its
and
empirics,
far
too
little
in
those of
strictly scientific
men.
Of
its
importance,
it
it
includes,
directly or indirectly,
as well as
difficulties
CONVECTION.
en. xv.]
more than
far
subject,
natural philosophy,
most
in
and unimportant
trifling
231
first
sight the
place entirely
by means of
produced by
heat.
of water tends to
body
due to differences
is
how such
differences can be
when
This is well shown by an ordinary firewhose gaseous contents are considerably rarefied
by a flame applied at the lower end of the bag, which is
if
that be lowered.
balloon,
open.
as
If
it
may be
of
266.
The
all
sides towards
the
lower
end of a
shaft or
chimney with an
HEAT.
232
[CHAF.
open fire at the bottom. As already stated, the actual calculation of the effect even in this simple way, except to a
rough estimate, is an exceedingly difficult problem
which, having hitherto defied rigorous treatment, has been
solved approximately with the aid of hypotheses suggested
first
by experiment.
In fine
the
sea
coast
we have
above
horizontal
When
it,
which
inrush
rises,
and has
of colder
air.
it
heats the
place supplied by a
This is the Sea-breeze.
its
grows cold by
its
place,
Land-breeze.
267.
is
well
in a
flask
4.
When
CONVECTION.
xv.]
the
235
application of
culation, in
thus produced
density point
till
pressure
perature will
the ice
121).
will
Continuing the
be arrived at which
however,
These,
is all
start
will
afresh
if
prevent currents.
the pressure be
relaxed.
show
it
temperature
268.
We
influence
is
and
and
its
consequences on
air,
cloud.
like
to one
who knew
all
HEAT.
234
[CHAP,
work out
trial
cases,
It is
found, however, by
that,
values
results
as in
this
Such
special
problems.
Another
"
"
capriciousness of such
phenomena will occur to any one who thinks of two strata
of liquids of different densities, and which do not mix, in
269.
illustration of the
As long
is
stable,
is
the lower
is
(small as
it
is)
CONVECTION.
XV.J
usually a
But the
235
is
therefore
temperature effects
are
and
sphere.
Hence,
upper
atmo-
if
we should expect
air,
sides towards
column of hot
flow in from
would have,
air
would
rise
from
it
and colder
air
would
all sides.
and
HEAT.
236
but
its
direction of rotation
cyclone)
wards,
it
(anti-
and, because it takes place from above downshould usually be a less violent phenomenon.
in
direction in
of an
extensive disturbance.
from waterspouts,
dust-pillars,
and with
this
we
c.,
owe
are not
up
Smaller vortices,
some forms of
to
now concerned,
farther
of
aqueous
contains
atmosphere usually
vapour, though
It is the effective agent in
considerable amount.
it
many
in
of
It
it reflects or scatters
them), and thus indirectly
Thus the cloud,
heating the air in which it is suspended.
instead of the earth's surface, becomes the intermediary by
in so far as
rain
CONVECTION.
XV.
237
An inch of
0*25, so that its thermal capacity is about 90.
rain corresponds to about 5 Ibs. of water per square foot,
giving out about 3,000 units of heat when condensed from
Hence, if all the vapour were condensed at once,
vapour.
the lower air would be raised in temperature by somewhere
about
33C.
We
get a
still
more
one horse
for
atmosphere
two hours
would
this
fifty
correspond
hours.
to
[If this
the work of a
number of horses
air,
And
We
-cools as
it
expands on
by precipitation
is not a
very simple
almost
question, though
incomparably easier than that of
Nor can we do more than mention the
its motions.
1
methods.
1
Memoirs, 1862).
it
by Sir
W. Thomson
(Ma)uhester
HEAT.
238
273.
|CH. xv.
to determine the
also to
fluid.
274. Resume of
two
Mechanism of Convection.
Land and Sea breezes.
Causes of
and
circulation.
and
AntiOcean
Atmospheric
Cyclones
263-273.
Basis of Ventilation.
Effects of
Waterspouts and Dust-pillars.
in
Currents
Convective
Equilibrium.
Aqueous Vapour.
Convection
the Sun's atmosphere.
Apparatus.
Joule's
cyclones.
CHAPTER
XVI.
RADIATION.
as applied to Heat,
Radiations, like
Sounds, are
The
following passage
is
all
Heat
is
simply Light.
Newton's Optics:
"If in two large cylindrical vessels of glass inverted,
two little thermometers be suspended so as not to touch
the vessels, and the air be drawn out of one of these
vessels, and these vessels, thus prepared, be carried out
carried
vacua will grow cold almost as soon as the other therIs not the heat of the warm room conveyed
mometer.
remained
in the
vacuum
And
is
not this
medium
the
HEAT.
240
same by which
[CHAP.
and by whose
do not the
is
put
And
of this
by the
vibrations of this
medium
And
is
pro-
not this
medium
all
bodies
And
is
it
not (by
its
"
expanded through the heavens ?
know by actual trial that there are sounds which,
elastic force)
We
276.
while painfully affecting certain people, are absolutely inaudible to others whose ordinary hearing is quite as good,
and who are as favourably situated with regard to the source
is
In other words,
a continuous range of
majority of individuals this
is,
for
each human
audible sounds.
With the
shrill.
ear,
therefore,
jective
depend
to
organs of hearing.
RADIATION.
xvi. ]
241
man,
whose coarser audition-mechanism would enable them to
continuous sounds, periodic disturbances of air
occurring twice or thrice per second. Again, we might conceive of insects whose range of hearing should lie entirely
hear, as
among sounds
body, such as a hammer, the sound produced is at first extremely harsh and unmusical ; but, as it gradually dies away,
The
another.
shriller
farther.
Very low
notes, such as
engine-shops,
effect
where a
singularly
is
which
277.
\ve
experience
Analogy
at
when
it
relief
stops.
is
plausible.
The
existence in
all civilised
HEAT.
242
to our
own
[CHAP.
red-hot,
striking of these.
It
When we
luminosity.
fundamental
warmer
think of
this, in
to colder bodies,
we
When
hotter,
low
or
length,
it
refrangibility,
then,
only;
gives out
as
rays,
it
becomes
along with
i.e.
until
like
it
the
same
something
which they come to us from the
sun.
If the current be
now
interrupted, the wire presents exactly the same continuous series of appearances in the reverse order.
But,
even when
it
it is still
rate,
has ceased to be
it,
heat.
Bearing in
RADIATION.
xvi.j
compare
it
343
Thanks
of the visible.
we can now
treat
galvanometer (
50, 62),
tions with an amount of accuracy which, though
in
many
to
respects
that
usually
and the
obscure radia-
attainable
far inferior
in
optical
We
same
is
as that of light.
we must place it a
we wished to obtain the
if
But the
fact that
it
little
farther
from
sharpest luminous
is so affords a still
distance for red rays is greater than that for blue rays (unless
the lens be achromatic for these two sets of rays), and we
244
HEAT.
distance
[CHAR
to be
still
greater
for
pile,
is
',
is
absorbed
by the way.
A luminous
surface appears of the same brightness whatdistance from the eye (provided there be no
Similarly,.
absorption of light by the intervening medium).
ever be
its
s'
when
RADIATION.
xvi.]
245
This, again,
may be
its
inclinations at
various
aperture,
the
not altered by
is
from
altering the orientation of the surface, so long as (seen
Hence
the pile) it appears completely to fill the aperture.
it follows that the intensity of radiation, whether luminous
or obscure, from a hot surface, in any direction, is proportioned to the cosine of the angle which that direction
to
the surface.
[We
shall
is
amount of
light
and
practically
opaque
transparent to light
to obscure radiations,
and
vice versd.
lamp-black
it
becomes
practically
of alum
its
heat.
which permits
without suffering
plate as a fire-screen,
fire
HEAT.
246
[CHAP.
less
So
if,
second
plate,
283. All
now be
and so
the
much
sifted is
on.
facts
above described
279-282) can
by the use of
extended
Leslie.
is
in
subjoined.
We
various
directions
the
valuable
work
of
no explanation.
xvi.
RADIATION.
come
to others
identity of
in
which
mechanism
247
fact,
They
the
are,
Undulatory
We
will
content ourselves
by luminous
to the eye
groped for, as
rays,
were, in darkness
it
electric pile.
285.
of
the
means of proving
glass or in water,
ference of energy
particles.
But
all
of the wave-motion.
of a ray,
It
proved merely
that,
is
exactly
or
it
water.
HEAT.
248
[CHAP.
they
enabled Fresnel
to
give
consistent
theory
of
Elliptical Polari-
zation.
the position.
286. Fizeau
ordinary
interference experiments, such as that with Fresnel's inclined mirrors and that of ordinary diffraction, succeed
with obscure rays ; and, as was to be expected, indicate
he employed
is still
It
by cautious
films.
This
is
pile, it is
found
if
This
RADIATION.
xvi.j
249
We
of the
also.
it
Radia-
But to
tion generally is an electromagnetic phenomenon.
discuss his theory, or even to describe the ingenious experi-
discursive volume.
287.
Resume of
275-286.
Radiant Heat
is
merely
magnetic Theory.
CHAPTER
XVII.
entitle
Different
modes of experimenting
pile,
being inde-
pendent of particular nerves, or particular chemical compounds (on which sight and photographic processes depend),
are obviously fitted, in a special manner, to give us informaall species of radiation alike.
289. If
a hot wire
body
gives off
longest up
perature.
limit,
we
and
radiations
of
to a certain limit,
The
phenomena presented by
may now
all
state that
wave-lengths,
its
such a
from
amount radiated
the
tem-
is
the
corres-
itself
alone
(i.e.
upon
its
constitution, its
CH. XVIL]
its
surface, &c.),
251
and therefore
of heat
4), is
arrived
at,
once attained,
called the
Prevost
is
and temperature.
last century.
He
was led to
it
in trying to explain
its
bulb.
result,
by Stokes
we
will
which
is
us from
chapter
we
will
and convection.]
291. It was well known
amount of radiation from
tion
to
Leslie
filled
it
HEAT.
-252
[CHAP.
was very little radiation from the polished surface, considerably more from the scratched one, but very much more from
either of the others, which (in spite of their contrast of
The amounts of radiation
colour) behaved nearly alike.
from the polished and the black surfaces are so different
made by
and
the
fully
De
Desains,
of
groups
obscure
reflecting
rays
from
sides in
la Provostaye
determinations
powers of bodies
each of many
different sources.
great
exactness
reflecting
but
power diminishes
simultaneously increase.
viour of
some
as
The
the
powers
for
at
from
this principle,
of view.
it
And
or not,
all
same
limitations.
It is
xvii.]
253
present state of science, to look for a truly rigorous invesof the relation between radiating, absorbing, and
reflecting powers. In all the professedly rigorous investigatigation
tions
process of averages.
begin by assuming
its validity,
Why
will detect
justified only
by the
is
branches of physics.
in elementary dynamics, we consider the
of
a
lever under various forces, we simplify the
equilibrium
mathematical treatment of the question in a very marked
When,
293.
for
we
of
Friction,
great,
such a
Law,
is
sufficient,
Coulomb's
Laws
find
&c.,
are
all
mere
Law.
No
HEAT.
254
[CHAP.
all
(2.)
its
falls
No
ing surface.
z.
perfectly reflect-
them) absolutely
A thick
(4.)
identical.
Certain
one
conception of a body
definite
ray
and
perfectly
And,
now used
gests
finally,
silver,
such as
is
to
a certain
definite
may
xvji.]
but
named above
those
^55
object.
temperature
4),
we
is altogether
of them may be
Any number
But
if it,
and
its
Hence
either
way,
passing perpen-
body
of an
infinite
This
is
the aggregate
to a
definite wave-length.
make
its
attention
consequences more
clear,
we must now
only.
fix
To
our
In front of a
But
UNIVERSITY OF CALIFORNIA
HEAT.
256
[CHAP.
Hence what
impervious.
it
all,
in
which to express
define as follows
From
We
it.
The
The
wave-length which
is absorbed at a given
temperature, the
being reflected, scattered, or transmitted. [Strictly, the
radiation here referred to is that from a black body at the
rest
The
emissivity,
perature,
another.
and
concerned,
is
apparently
much more
xvii.]
just given,
more
Still
257
1
chiefly to obscure radiations.
that given by Kirchhoffin 1859, and
others with the help of an imposing array
since developed
by
is
them
297.
The dynamical
was called
the
first
by
modern
hint of the
cess,
line in
the
electric
arc,
he examined the
spectrum
,of
He
then,
by means of a mirror,
from one of the incan-
others.
But when
it
was
analysed,
through the arc, it was found to
have dark lines exactly where the arc itself gave bright
after passing
ones.
1
in Phil.
Mag.
1863,
i.
354.
S
HEAT.
258
[CHAP.
were placed
was played
so far as
would be given
out.
But
if
a listener
at
at
mere obstruction
is
note,
Now
all
radiation depends.
#11
Fraunhofer in a candle-flame
Hence
this substance.
it
is
due
followed
to
sea,
the. presence
of
in the
ing that the production of the double dark line
solar spectrum must be due to salt, or rather to metallic
sodium
in a
the sun
and the
earth.
close consideration of
it
on Spectrum Analysis.
however, one part of the question to
which, though it may easily be deduced from Stokes's
specially to those
300. There
is,
xvn.J
dynamical
attention.
259
277).
of
theory
in our inclosure, both of the same material, of the species
294, but originally at different temperatures.
(5) of
KirchhofFs investigation was direct, and specially limited
to single, definite wave-lengths.
And it was experimentally
verified by the fact that when the source was an incandes-
when
it
was obtained
length.
he might
He
colour in the
fire
coal behind
it,
and green
(the
behind
it is
light,
have done) to one particular waveshowed that red glass, for instance, loses all
easily
when
it is
appears red
at the
same temperature
when a
hotter coal
is
as the
behind
not so hot as
it,
coal
it is.
But,
if
we now revert
to the
HEAT.
260
some by
transmission, as
[CHAP.
may
by
reflection,
light-rays.
polarise
But the radiation must be throughout of the identical character of that from a black body, and thus cannot be polar(If this were not so, the
ized.
into a
body
new
position would
And
first.
It does so because it
which polarizes by transmission.
absorbs one of the polarized rays produced by its double
refraction ; and, absorbing, it must also radiate, that
nected with
We take only a
we
If
foil,
few
common
foil in
a dark ground.
It
foil
now shows
on a
we
light
find,
ground,
are
strongly
on examining them
in a
xvn.]
reversed.
them
It is
261
at intervals,
very hot
The
When we
rays.
its
surfaces
HEAT.
262
smoked
[CHAP.
are
its
be heated.
it
But there
always degraded.
phenomenon we have
Of
course
is
to
is
we
it
is
just described
phenomenon,
for
it
is
essentially con-
all that
that emission
scattering.
is
upon
as a netv surface.
And
we have
to fluorescence.
But the
xvii.J
263
transparent)
same
effect of thickness
Let
on the
from a
direct radiation
when
as small as
power
plate.
definite kind,
may be chosen
we please), and a
same
for the
Then
same substance,
same temperature, placed in front of the first, and
so close as to be virtually one with it, radiates also R,
ture.
at the
but stops
aR
R(l +
(I
first.
The whole
-a)).
and stops
aR
three plates
(i
-f (i
a)
).
Hence
is
(i
-a)
).
series,
However
vanish,
(i
small
may be
the value of
a)" vanishes
when n
is
a,
provided it do not
This gives
infinite.
the utmost
emit,
R_
a
of course, equal to its absorptive power for the
corresponding radiation from a black body of the same
This
is,
HEAT.
264
Hence
we have
if
temperature.
quantity,
a stand
[CHAP.
for this perfectly definite
= aa;
The
following
consequences of
(i
little
(i
- a)
-)-
this
the
quantity
being in the upper line of the table (i.e. the values of the
expression for
=i), and those of ;/ in the left-hand
The numbers
column.
in the table
may
Their defects
of the plate.
corresponding transmissions
nesses
of course be taken
different thick-
by
305.
One
is
expression
will,
if
only
R,
a,
emits
RSx
a8x
of that of the
if <>(jr)
be the whole
Then,
=R
)=(!--*
f(*)=(l--*
a
we have
).
at
a<f)(x'),
once
and
XV! i]
265
above
materials at
its
all
events being
and sharply
is
whose
that a body,
stop a
large percentage of the incident radiation from a black
body very early in its career, while the rest may pass
absorption
is
specially
selective,
may
selective,
even though
it
be nearly transparent
it is
is
not
such a
clear that
when
indirectly
it
it
is
easy when
the radiation
one insuperable
is visible,
difficulty, viz.,
is
This, however,
brightness of light of different wave-lengths.
a
to
branch
of
Photometry
practical Optics.
belongs properly
We may merely mention that the principle usually employed
r
is
increase
The two
adjusted
till
HEAT.
266
[CHAP.
The same
these,
like
is
has
the eye,
above, sometimes
in,
its
particular
Each of
range (sometimes
favours.
is
In
fact,
The
own doctrine of
parallel beam of white
of his
Interference.
He
it
by the
showed that
h'elp
if
the
screen
The amount
xvn
267
after
employed.
The
be
now
by means of a thermo-electric
pile,
studied
directly
all
The
proportional to the breadth of the face of the pile.
can be made to travel, keeping its length parallel to
the wires of the grating, all along the spectrum, by means
pile
of a screw motion.
308.
(i.)
is
we cannot
if
well have
the
slit
HEAT.
268
[CHAP.
by passage through
As
(3.)
of
radiation
half that
wave-length
from
the
The
(4.)
statements
whose length
is
considerably less
wires.
With longer
waves
the
of a different character.
phenomenon
(5.) The comparison,
ought
to
ratio in
When we
diffraction one,
try a refraction
we
are
spectrum, instead of a
different, but
met by a somewhat
Some of these
quite as formidable, array of difficulties.
over
the
recent
be
improvements in
got
by
may probably
photography, which enable us to utilise the obscure rays of
longer wave-lengths than red, just as the old methods
employed chiefly obscure rays of wave-lengths shorter than
violet.
xvii.]
-^69
spectrum.
formula
where X
is
and
are special conthe wave-length, and
medium. If this law holds, even approx-
which the
refractive
index
is
practically the
same
and
no
which p = A.
worked
is
leaving
it.
Thus,
all its
and
to a
specified
are sufficient.
310.
The remarks
just
the
HEAT.
270
[CHAP.
intensity
These are
all,
difficulty
maximum
somewhere
is
expected) not
much
in the yellow,
farther agreement.
W. Herschel was
is
of rock-salt.
The reason
is
some of the
viz.
at
200
C.,
400
C,
&c., a
lamp, a white-hot
such observations are seen to
Locatelli
we look
by the
at
them
behaviour of
xvii.]
be
There can
radiations.
extends,
to
at
least
as
little
doubt that
formidable an
-27*
this
effect
amount, to the
what
in
fact
we
And
by
an
artificial
product.
substances can be obtained chemically pure,
naturally expect a much closer agreement between the
312.
we
When
Thus all
and aqueous
singularly opaque
to
agree
that
water,
ment
is
some
(as
dry
air for
is
in
not
There can be no
so definitely answered.
doubt that even a small amount of water-substance in air
by any means
know how
is
slight a
HEAT.
272
[CHAP.
the glare of the sun, while stopping his heat as well as his
This can be accounted for, to some extent, by the
light.
mere
reflection, &c.,
we were
to attempt a
of a cloud in
full
on
Wollaston) as about
The
direct heat-radiation
air
appears to
is felt
powerfully
as in the intervals
after
shining
condensation
saturated
176); and
air, if
it
little
dust,
would
at
once become practically opaque to sun-heat by the formation of mist or clouds. Still, we must also bear in mind that
a rain-cloud
is
warm, moist
air,
clouds
is
in great part a
The
air.
xvii.]
unsettled.
273
on the subject
is
is
certainly
possibly
gas,
Its
and is
main
absorption
dew
and, if the air were moist, there would be material for dew
but little cooling to precipitate it.
Practically, the results
of Wells are independent of the absorption due to true
1
The great difference between the effects of
water-vapour.
true water- vapour and cloud or mist is seen at once by any
when
treated in works
Fluorescence
varieties of
on Light.
and therefore
This
and Phosphorescence,
more properly
designated by the terms
which are probably mere
is
is
one phenomenon.
W. Thomson,
HEAT.
274
dried
fish.
[CHAP.
other chemical combination, and therefore belong to combustion ; though, in some special cases, they are known tx>
But
it
was known
to the
horse-chestnut-bark
(esculine),
and a
slightly
acidulated
in fact,
the
title
On
the
Change of
is
must
xvii.]
275
here,
especially from
general proposition
the
295).
We
Spectrum Analysis.
Internal Radiation.
Absorption by
Distribution of Energy in
plates of different thickness.
the Spectrum.
Absorption by gases and vapours. Fluorescence and Phosphorescence. Defects in the Theory.
T 2
CHAPTER
XVIII.
RADIATION.
relations
considerations.
one
particular wave-length.
is
in this connection,
is
All
that a rise
Whether
or not,
we have had
as yet
RADIATION.
CH. xvili.]
inclosure.
and
first
is
it
277
this is
For simplicity we
partly reflection.
will, therefore,
And,
for
at
comparison
suspended within
it.
This
is
nearly
and exhausted of
To
carried out.
air
avoid the
the blackened
body
we may suppose
made of a good
it
containing mercury,
inclosure.
If the inclosure
metal,
we may suppose
rature
by immersion
in
it
to
is
as speedily as possible.
ings of the thermometer are then taken (as in
The
read-
180) at
of
the
The water-equivalent
intervals of a minute.
ball,
mercury, and thermometer-bulb together are found by the
proper methods, and enable us to calculate the number
of units of heat lost for the fall of temperature observed.
This number, divided by the number of square units in the
surface of the ball, gives the loss of heat by emission per
unit of surface, per minute, at each temperature.
HEAT.
2?S
[CHAP.
thus
/,
the quantities
calculated
successive values of
all
where
made
(even
and
temperatures,
are constants.
when convection
This
also
is
comes
the assumption
into play) in all
And it is found to be
the theoretical writings of Fourier.
approximately true so long as the temperature-differences
are not above a few degrees.
322. Dulong and Petit, by a very careful series of experiments, found that this approximation errs in defect,
even for moderate temperature-differences, and that the
increase.
= A
a<
B.
but should
RADIATION.
XVIIL]
be equal to
De
if this
down to absolute
radiation when t
o.]
tures
279
all
tempera-
can be no
la
it is
no longer
applicable.
The
especially as a
was
base a theory.
324. Accepting
it,
experimental results
however, as a
between the
fair
approximation to
we
/(/)-/(/=)==
.4
a'o(a'-'o-l).
rate of surface
loss is proportional to
(1-0077)*
where
is
the difference
For a given
is
difference
of temperatures in degrees C.
of temperatures the rate of surface
loss
proportional to
where
It
t<>
is the
increments of temperature.
325. The first of these results shows that the rate of
cooling, for
tional to
+0-0038 6/-&C.).
is
propor-
HEAT.
23o
[CHAP.
oC.
among
same throughout
be the same
We
RADIATION.
XVIIL]
Chapter XVII.
may be
281
amount of emis-
being
first
temperature
as
it is still
is
body increases,
more and more rapidly as the
thenceforward more and more slowly
perceptible,
raised,
farther raised.
pile.
Such a
series, for
each of
a well-selected
set of
If a periodic disturbance of
c., propagated at
water-waves, sound-waves, light-waves,
a uniform rate), take place at a centre, the number of these
disturbances which reach a spectator in a given time
We
are
not,
HEAT.
:282
[CHAP.
But experiments on musical sounds produced by a trumpeter on a passing train have verified the principle for sound
.and
it
in the solar
-east or
us,
150,001 of the same species from the east side, and 149,999
from the west. Thus, if the spectra of these two sources
of light be formed side by side by the same prism, the
The
relative
them.
330. Assuming, then, the principle to be accurate (as
is at least partially verified
if
in
it
our inclo-
by experiment)
295) one of the bodies is moving relatively to the
others, the only way in which we could conceive equality of
temperature to be maintained would be by supposing the
sure
energy corresponding to
each of the
infinite
variety
of
RADIATION.
XVIIL]
283
it
indosure
is
motion
of radiating bodies in an
amongst them.
Now
Motivity
(see
Kence
it
on the
[Other trains of
Thus,
if
thought
there be resistance
ordinary matter,
it is
lead
to similar conclusions.
by the ether
to the
motion of
motion
lost
be given off
in
is
It
could be
for
HEAT.
284
Pouillet
answer
altered
was the
first
this question
by
instrument
farther
he
[CHAP.
who made
and
a successful attempt to
have not been much
his results
The
research.
devised for
the
purpose
Pyrheliometer.
This
is
filled
is
with water
the bulb of a
RADIATION.
A viii.]
285
When
is
the instrument
The
determined.
of temperature, say /
turn the instrument towards the sun for five minutes,
fall
Now
let
The thermometer
us say.
rises
through
shaded as before,
/.
Turn it imme-
The
through t
temperature
During the time of its exposure to the sun, its temperature was steadily rising by solar radiation, but as steadily
falls
falling
by
its
mately that
In
fact,
after
own
exposure
full
radiation.
lost in
we take
exposure.
Thus the
five
it
the
to
Hence we conclude
approxi-
mean
the
it
in
minutes by
From this, and the numerical data for the instrument (which
we have specified above), we calculate at once how many
HEAT.
[CHAP.
286
From
a great
due to
where
to day.
these facts warranted his
as-
simply.
Thus he calculated from the data of his instrument that
the
in
grammes of water by
C.
334.
e in his
From
RADIATION.
xviii.]
vertical
cent,
earth
of the
;
and
entire ;heat
solar
clear,
heat
287"
is
is
radiation
almost
must be looked
on
as mere approximations.
336. The great majority of the experimental determinations of absolute rate of loss of heat have been made in
air,
the
effect.
and
is
the
same
at the
same
temperature
It depends, of course, upon the
polished or blackened.
nature of the surrounding gas, and upon its pressure (p) as
well as upon the temperature excess of the body.
This
.
HEAT.
2 88
[CHAR
form
A p'(t **,)***.
A
is a special constant ;
Here
to another, being about 0-45 for
and
ft
varies
air.
is
small.
337. Determinations of absolute amount of loss by radiation and convection together are not numerous.
We
may
Loss
due
Lright Copper
Blackened.
to Nicol
2*03
0*51
1-46
0*42
1*35
respectively.
and the
air
The agreement
is
very satisfactory,
since
there
can
much
larger
discrepancies.
RADIATION.
xviii.]
289
338. Experiments with the short bars as in Forbes's conduction method ( 244), give us valuable information of this
The
]ron smoked
C.
50 C.
100.
150.
1*13
2*76
4 76
7^33
1^40
364
6*75
H'25
200.
250.
IO'55
i~'2i
C.
And we
series.
body
Resume of
318-338.
temperatures.
Dulong and Petit's Law.
measures of absorption.
Pouillet on Solar
at different
Melloni's
Radiation.
convection
Pyrheliometer.
jointly.
CHAPTER
XIX.
really involved
lent in centimetres.
how
to transform
said
all
that
is
simultaneously changed,
the
operation
is
(numerically)
that
is,
i.e.
36,000
Or we might put
feet,
it
as
600
feet
difficulty of principle.
CH. xix.]
is
somewhat
The
less
easy
291
when we
intensity of gravity
take such
is
represented
in miles and hours ?
how
the various
is
result
We
by 5,280.
hours,
^ 79^36
That
in
is,
nearly.
hour.
-42.
view.
greater,
Look on
is
Speed
and less as the time employed
is
Hence
greater.
HEAT.
292
[CHAP.
or as
it
is
is
greater
thus
"
M -CM*}
;:
,
Now, when a unit is increased in any proportion, a concrete quantity, expressed in terms of it has its numerical
value diminished in the same proportion.
[Thus when we
increase the unit twentyfold,
we
to pounds,
quantity
it
find 480^.
as in passing
Here
and
and a
24!.]
for the
space described
bt
-f
ct
we have
2
.
b,
a speed,
c^
an acceleration
--=
shillings
Every definite
terms of each fundamental unit
-f^ 480!.
homogeneous in
Thus in the expression
is
involves.
from
is
'
the value of s
is,
L
I
-jfi
like s itself,
of the
[L].
xix.]
293
Thus we may employ, as we have hitherto done, a footpound-minute system; we might adopt a mile-ton-day system ;
or, what seems to be in a fair way towards adoption in
science, a centimetre-gramme-second (C. G. S.) system.
The student must remember that the choice of units
no way whatever of
is
in
scientific
mainly of convenience
a general system, even if it be inconvenient for mere business purposes.
(See again,
56.)
:
344. But the question of dimensions is of the utmost scienimportance, and is too apt to be lost sight of in the
tific
composition
best of "hands."
C. G.
lute
S.
And
Units,
is
If a pro-
HEAT.
294
have come into use.
[CHAP.
is
meant by
"
In
of five feet eight, who " scales
twelve stone.
the C. G. S. system this advantage is wholly sacrificed for
the sake of another advantage (felt especially in electrical
man
Thus
strictly
scientific purposes.
common
in
ieft
imbedded
in
and thus
Swedish, &c.,
of those to whom
Italian,
Russian,
it
might be of the utmost importance.
wise conservatism of the botanists, much as it is ridi"
culed by " advanced
science, has preserved to them this
The
evident
are
self-
Volume
[v]
[f].
Speed [V]
=[
].
TUT
Density
[p]
Force [F ]
[p]'
"TWTT
Momentum
[^]
=
|
J.
XIX.]
Pressure [p]
295
LT
|->J
346.
We now come
to
temperature [0],
but we
scale
may
take
it
is
And
here a
required.
for illustration
new fundamental
This, again,
as
is
optional,
C. on the absolute
96).
few instances,
are simply
[e-].
Heat, [H], as we have seen, may be measured in many
If it be measured in dynamical units, its dimensions
ways.
are those of [E] above.
If
it
be measured
in
thermal units,
i.e.
by the
rise
of
mass and
and
its
dimensions are
therefore
[M0].
But
if it
the order
be measured
in
thermometric units
246)
it is
of
HEAT.
296
Now
we
is
by the
definition
[CHAP.
of thermal conductivity
237),
see that
[L
[k]
[T]
[H],
or
w = [ft]
ML m
.
=r=
2
= rI l
I
^j-j
Similarly
we
in
energy
'
thermal units,
thermometric
in
units.
find that
Rate of Emission
m
as energy,
=
I
7901
f~ J
n thermal
in
units,
thermometric
units.
\ix.j
297
But
is
453-6
60
30-48
nearly.
4-03
Thus
about
0-2,
Again
and
for rate
to 0-5.
of emission, as in
337,
we have
as
rM0
~i
Ll2 TJ
Here [0] is a centigrade degree in both systems, so that
the requisite factor is
-
60 x (30-48)-
nearly.
123
The
Change of
real
units
difficulty
is
lies
a
in
Objection
ascertaining how the various units are involved.
Dimensions of Volume,
to the term Absolute Units.
CHAPTER
XX.
many
capital
steam
separate condenser or the expansive action, being applications of physical knowledge, others, such as the parallel
him what
is
we owe
Diagram, which
is
of
for the
engine
poses.
and
But
of Rankine,
that
we can
it
is
in the
employed for that and similar purhands of Clapeyron, and more recently
still
of which
CH. xx.]
299
this
and
the
first,
such that
its
displacement in the
new
direction
is,
same
the
mode
of
attainment
being
mere matter of
ingenuity or convenience.]
351.
The
figure
PP 'Q'Q
OM
MP
its
pressure.
through a space
//,
move under
the
the action
work done
fS. h
or
is
/.
S/i.
13)
of this
force
HEAT.
3 co
[CHAP.
But
parallel to Ov,
OM to
OM'
MPP' M'
rectangle
When
We
corresponding to an infinitesimal change of volume.
thus obtain (as in 190) a number of narrow rectangles,
the
sum of whose
MPP'M*
to
xx.]
Bearing
this in
figure
PP'QQ be
301
sents the
work
is
positive
direction.
itself, some parts of its area will
others
;
positive,
negative but the statement above applies
separately to each of the parts.
If the
diagram intersect
be
352.
Were
^great as
this
it is)
designed
it
its
value
originally
it
from a
We
does not leave the cylinder also that it has, through(at each instant), the same temperature and also the
same hydrostatic pressure. By this last consideration our
that
it
out
whether they be
or
even
a
or
arrangement
complex
liquids, vapours,
gases,
such as a liquid in the presence of its saturated vapour.
In the last of these cases there is, between the limits of
practically restricted to fluids,
reasoning
is
volume
at
is
liquid, or the
whole
is
vapour,
how much
of the
substance
is
in the liquid
state.
But
(
in
the
first
three
is
of these cases
we have seen
HEAT.
302
[CHAP.
is
This corresponds
so long as its temperature is unchanged.
to the second &&& fourth of the operations in Carnot's Cycle
(which, as
From any
we have
body) we may
relation between pressure and volume under this new
Thus the whole diagram may be covered with
limitation.
In
a new set of curves, called by Rankine Adiabatic lines.
PQ
and
the rough diagram above,
Q' represent portions
of two such lines.
Any other definite condition will, in
xx.]
303
but
general, give rise to its own particular class of lines
the two classes we have mentioned are by far the most
;
We
far,
must discuss
their
temperature
measured on any
scale,
class of lines
Thus
would be a
sure
and temperature
selves
may
in
fact
volume
as co-ordinates.
in terms of pres-
The
surfaces them-
be regarded as portions of a
hilly
country, while the parallel sections play the part of contour lines. And all the properties of contour lines find here
new and
interesting applications.
Any .number
of section can
is
made
to
go to and
fro
in
the cylinder.
HEAT.
304
We may
i
for
C, such
the
as
moment assume
we have
tiple or fraction of
such a degree.
irt view
ment of temperature.
[CHAP.
is
When we have
secured
this,
we
shall
for
and volume
PP
QQ',
curves are
is
in the
all similar,
and
similarly situated,
and the
linear
dimensions of each are as the square root of the correspondThus, if drawn at successive
ing absolute temperature.
intervals
of
equal
temperature, they approach more and
more
closely to
The
one another
as the temperature
is
higher.
air
known.
In
fact,
if
is
not cer-
strict
out.
XX.]
305
cross the hyperbolas, and for 'higher presshow volumes in constantly increasing ratio to those
of the ideal gas under the same pressure.
air isothermals
sures
They appear,
line of
in fact, to
no volume (Op
in the
fig.
of
distance from
This, of course, we are prepared to
we
have
for
absolutely no reason to think that any
expect
finite portion of matter can be deprived altogether of volume
it.
The
it
may.
results are of
very great value, but they are only remotely connected with
the main features of our present inquiry.
360. The distinction between a true^ gas and a vapour
appears very clearly from the isothermals of carbonic acid,
obtained by Andrews in the classical investigation already
mentioned
174).
Andrews' diagram
is
reproduced on
is, it
CH. xx.]
307
air,
respectively, at
For the
this chapter.
its
changes
left.
Thus,
volume
at which the carbonic acid is wholly vaporous becomes
less, while the greatest volume at which it is wholly liquid
becomes greater.
Close to the critical temperature (but
as the temperature
under
is
Also, as
less
and
liquid
less as
(when
the temperature
is
greater.
Thus
in
HEAT.
3o8
[CHAP.
at
is
as is also
its
critical
obvious
Another
of this line, the carbonic acid is wholly liquid.
line, consisting of the right- hand branch of the
dotted curve and the same portion of the critical isothermal,
left
broken
it
(twice).
state to the
undoubtedly non-
This, however,
made
is
on
we have
for
the
indicator
xx.]
309
seen
The
361.
and
57
its
:
relative densities
as great.
relative
Thus
there
is
no
volumes graphically.
of
densities
is
at
any
(roughly)
must take
the
i.e.,
ture, increase of
is
all
or
This
increase of pressure implies diminution of volume.
known
in
it
that
whatever
state
fluid,
merely signifies
every
be,
is
its
is
necessarily violated.
the case of saturated vapour in
presence of the liquid, for here the pressure remains unchanged as the volume varies, whether by diminution or by
real exception
is
in
UNIVERSITY OF CALIFORNIA
HEAT.
3io
increase.
This, of course,
due
is
[CHAP.
to the fact that part of the
The
363.
for
is,
out.
Now
If the
Let the piston be forced inwards.
cylinder conduct, the heat developed is at once removed ;
but for all that the pressure in general rises, as we saw in
compression.
362.
But,
be the same
if
the cylinder
increased by (isothermal)
its
compression,
effect will
pressure already
farther heat
had
XX.]
311
Thus
still
line
through any
point of the
is
diagram
is
the adiabatic
more inclined
to the
The
a
statement
liquid,
another.
and
sets
is
still
true
when we
its
latent heat.
When
this
is
allowed to
escape as
it is
pressure, as
happens
own
action."
HEAT.
312
[CHAP.
adiabatics
when
the state of a
is
straint
then
if
other respects,
all
any one point of the diagram corone perfectly definite state of the working
substance, and therefore there can be drawn through it
The adiabatic (as
only one isothermal and one adiabatic
crosses
the
isothermal
from above
we see by
365, 366)
368. In general,
responds to
the substance.
and
that
its
own
adiabatic
one another.
is
to look
on them
one another.
(See, again,
355.)
appear clearly enough if we consider the relation between volume and temperature in water at the
This
will
Thus
ordinary atmospheric pressure.
that the volume of water is the same at
6 C.
Hence
121)
we know
and at about
C. and at 6 C.
C.
XX.]
313
volume 1-00003.
we
But
if
it
upwards
to
3, 2,
c.,
for diminution of
And
same
We
have
of the substance
same
is
The
know-
is
considerably less complete because less direct.
But we must presently consider the area (which will be
proved to be finite), included between a finite portion of one
ledge
HEAT.
[CHAP.
to be employed.
Clerk- Maxwell suggests the following
method which, while convenient and sufficient for our
solitary object,
RR'R"
Let
is
risk of
of
374 below) be the isothermal
whose form we know, QR, QR*',
Draw any line SS S" and call
adiabatic lines.
the
(in
fig.
of lowest temperature
Q'R",
it
(for
any assignable
371.
that we
the two
Let
finite values.
We now
temperature
/r ,
batics of the
first
QQ'
QP and P'Q'
and
Also
xx.l
315
let HI,
be the quantities of heat taken in and given out
Then, by
respectively in the direct working of the cycle.
As the
is
cycle
these,
equivalent of the
source over that
95),
we have
t*
t,
place except
excess of the
given
out to
lent."
degree.]
Hence, with
of
we have
351,
this
372.
now
the foot-pound)
The
HI =
A-
^ = 4;
so that, in our present system of units
/,
we have
temperature.
HEAT.
3i6
[CHAP.
PP'
&c., so that
P"
ti
diagram
,
P to
/>'.
Then
the
in
mark
<2<2'
<2",
<?'":
&c
is
it
And
this
Hence,
that
if
we assume
i,
to
/x ,
so
PP'Q'Q, P'P"Q'Q',
unit.
And a third isothermal, two degrees
be one degree under / and will thus cut off
a new set of unit areas from the series of adiabatics.
The whole explored part of the field may thus be divided
c.,
be one
will
under
will
and a
just described,
ture.
far,
is
temperaperfectly
arbitrary,
the scale
374.
The
is
is
that of absolute
a finite quantity representing the whole heat supThus if RRR'R". ... be the lowest isothermal
XX.]
317
several
the areas
is
represented by QQ'Q"Q'",
two isotliermals
also
be
Thus
PP and
SR Q
two
boiling,
pressure,
and
is
HEAT.
318
[CHAP.
The
and Thomson
be nearly i'365
i.
(Phil. Trans. 1854.)
the
centigrade scale, but merely
375. Hence,
in so far as to divide the interval between the freezing and
to
if
we adopt
A + 100
will
x+ 100
Thus we have,
as already stated,
so that
1*365
i.
#=274
very nearly.
Or, to introduce a practical term, Efficiency, whose meais the fraction of the whole heat taken in which is
sure
The
efficiency
of a perfect engine,
it
work
at
this.
good high-
Ibs.
uo
F. nearly.
l
+
-274
32
efficiency
is
461
F. nearly.
Hence even
the theo-
The actual
only y|~J, very nearly \.
rarely more than about half as much.
retical efficiency is
XX.]
To
377.
319
our diagram,
The absolute
374.
completely defines a particular isothermal,
the working substance.
Let, now, <j> be the
recur to
temperature,
/,
when we know
which
which
is
<
batics,
<
to part with.
dynamics,
For
origin.
we measure
(as, in
from
some
assumed
potential)
Practically, however,
we measure
it
with
is
a
its
<f>
its
we
isothermal, say /
which
<
is
to
>
HEAT.
320
[CHAP.
contract adiabatically
Here //"may be
It follows that if
a substance change
at temperature /, from
heat denoted by
to <,
<
If
it
be restored to
<
state isothermally
takes in an
it
/(4>-<
also negative.
is
<
its
amount of
).
it
gives out
(4>
- &)
379.
The changes
also be exhibited
in the total
/,
i.e.
</>,
the
<
the excess of
energy of a substance
may
on the diagram.
energy in a substance is
of ascertaining. We can
tell
220)
in,
P in the diagram
PM the
line of
volume,
PQ
corresponding to P.
Then,
if
MP
XX.]
if
P'
lie
little
quired
below PQ.
if
volume
line
is
to the left of
MP,
or above
PQ.]
Draw
PM', and
the
QQ be
PQQP
Hence
the area
PQQ'P'M'M represents
M
P
work done, and the heat given out, has in general a value
which depends on the form of the path. This consideration
one of the utmost importance, as it enables us to
represent graphically the amounts of heat which are either
necessarily, or needlessly, wasted in any particular course.
If. for instance, we
suppose that no heat is supplied to the
is
HEAT.
322
above
PQ.
if
Again,
[CHAP.
available tempera-
in passing
isothermal
PR.
can be obtained,
will
correspond
PRP'
380.
We
much
Clerk-Maxwell,
develop
These are
a substance.
all
elementary parallelogram formed by two consecutive adiabatics and two consecutive isothermals, as defined in
373.
that,
elegant,
simple,
and
more
No
difficult to follow
who
one
wishes
safely
will
xx.]
and be
the
at
looking
elements of the
if
323
he begins by
theory from
a simple
is
something
terribly profound.
When one
of this class, as sometimes happens, can be persuaded to listen, he is made conscious in a very short time
many
simply an
none
here.
382.
Resume of
How it
Diagram.
batic Lines.
surface.
Regarded as successive
Isothermals of
diagram.
expresses work.
parallel sections of a
Absolute temperature.
Thermodynamic Function.
Efficiency of an engine.
En'tropy.
Total Energy.
CHAPTER
XXI.
ELEMENTS OF THERMODYNAMICS.
IN the preceding chapter we have exhibited, by
383.
means of the
indicator diagram,
many
Then we saw
function, or entropy).
v and
p and
and
And we also saw that (E) the whole energy (to a constant
pres) could be expressed in terms of p and v, and therefore
v and
/,
in terms of
</>,
/,
or p
<f>.
Hence
ELEMENTS OF THERMODYNAMICS.
CH.
XXL]
we
325
among
the
five quantities
/,
v, /,
<,
E,
and
We
of
results
mentary
to
proceed
Thermodynamics
and we
will
pair,
We commence
change from v
so
much
to v
dv, the
loss of energy) is
pdv.
If at the same time the substance, at mean
temperature /,
to the proximate one <f> + d <,
pass from the adiabatic
it must take in (i.e.
gain in energy by) the amount of heat
<
represented
Thus we have,
dE =
Hence
td<$>
may be
-pdv
regarded
as
<f>,
(i)
function
such that
>
its
of the
partial
HEAT.
326
These equations
385.
The
(a)
loss of
[CHAP.
respectively, that
tell us,
From
386.
equations
(2),
by
partial differentiation,
we
find
'
^</>\
To
=
dv \ d$)\
dv
\ dv
)'
hand member by
temperature.
387.
The
expression for
parts, neither of
tial,
which
is
dE [(i) of
is
necessarily so.
Com-
Both
pare
379, where the reason is made obvious.
the work done, and the heat supplied, depend on the
form of the path (i.e. on the succession of states through
which the substance passes) and this is wholly arbitrary.
The change of energy, on the other hand, depends only
on the initial and final states of the substance.
388.
sides of (i),
we
relations
can, as before,
<,
p and
/.
And from
definite conclusions
the
as to
ELEMENTS OF THERMODYNAMICS.
xxi.J
and
d (E
3^7
as independent variables,
tty]
dt - pdr.
<
386,
/
/ d$ \
dp \
\di) ~\av)'
if
is
e the ratio in
made up
which the
of these forms,
Hence
dp\ _=
(p\
V
The
first
dt '
member
is
i
z'
v, \
de
shall
be no change
The
for the
dt
HEAT.
328
[CHAP.
ture, this
,,
-- 8/,
t(v
z
z',
Thus, when v
>
z\ (as with
is
a function
of
<
v^
perature
by increase of pressure but when v
with
water
and
of
mixture
the
the
temperature
ice),
(as
raised
is
falls
above expression.
Term
for
345) of the
[FL]
390.
J.
result.
is
for
we
We
of a formidable character
lie
in the
way of the
ELEMENTS OF THERMODYNAMICS.
xxi.]
329
from
166,
8/ and S/ from Regnault's table ( 164), and
we may use the formula to calculate the volume of one
saturated steam at any temperature.
pound of
But a curious
may
be the
result,
be deduced.
easily
specific heats of
due
Rankine and
to
Let r
ct
Clausius,
(functions of / alone)
any substance
in its
two
states of
stance
have
e
fully characterised
is
by the quantities
change these to
and
/ 4-
e,
df,
we
and
de, respectively,
td$
(c e
<r x
(i
- e))dt+ Lde
(i).
d*<>
dL
*--*-?
Now
as
by
d =
values 2 '2,
166,
for water,
i '4,
(roughly)
07
so that
0-3.
To
is
C. respectively.
CQ is negative.
adiabatic compression on
presence of water, note that (
393) the
mixture is heated, so that dt does not vanish, but has a
Now the left-hand member of (i) is zero.
positive value.
investigate the results of
steam
in
Hence
in order that de
the
may
vanish,
[Since c
is
is
i.e.
that there
may be
we must have
a proper fraction.]
HEAT.
330
If the
steam be in excess of
[CHAP.
de
is
if in
defect,
(See, again,
is
present,
86.)
becomes
fearful
thus
burns.
mechanical
effect,
td$
equation,
vdp,
whence, as before,
*L
dp
The
Introducing t as a divisor of each side, we read
of increase of volume, per unit of heat supplied at
constant pressure, is the ratio of the adiabatic rate of
:
rate
change of temperature
with
pressure
to
temperature.
393. Finally
d(E
t$
+ pv) = - $dt +
vdp,
the
absolute
ELEMENTS OF THERMODYNAMICS.
xxi.]
whence
\dt,
^dpJ
The heat
Introducing / as a factor on both sides, we have
given out per unit increase of pressure at constant tempera:
ture
Ldv _
v dt
Hence,
for
developed
278
72,000
in
temperature)
is,
in
390),
/(/- 278).
62*5 x 72,000
and
it
/(/-
2117
278)
'
62-5 x 1390
72,000
= /(/-
278)
2,950,000
nearly.
at
- o'o 5 5
C.
HEAT.
332
This
however,
result,
[CHAP.
is
is
i
- tdv\
( -7v \dt)
and
i
idv\
v \dp)
(
once that
\dtr
\dp)
dp
or
The
raised
its
Thus Canton's
case
may
early result
under pressure.
Now
changed
is
By means
given by
we
may be
'
Q'000052
O'OOOOOO^
T.
ELEMENTS OF THERMODYNAMICS.
xxi.]
333
is
is
for the
dv
+ 0'02/
278
v dt
72,000
and we
150 atmospheres
150
water at o
274(4
C.
is
only
x o'oi)
15
'o
C.
In the case of
spheres
is
\vater at
150 atmo-
degree.
395.
If/'
pressure,
we have
kdt
at constant
mass
td$
dp
If
we choose,
as
is
o.
usually done, v
may be
and
written
M = &# + &&
dv
dt
dp
dt
dp
-
dv.
/ as
independent
HEAT.
334
Now
-5*
is
at
[CHAP.
c,
by our condition,
<
dp
k.^--*#^.*
dv dp
dp
dv
dv
which (since by
362,
is
-f-
dv
negative)
is
obviously always
396.
gas
and form
at
least
fair
approximations
(within
perfect
simple
ordinary
pv =
To
find the
.._
dv
We
fit.
dp
R
v
dt
have also
dt= - t
dv
so that
'
(395)
389)
ELEMENTS OF THERMODYNAMICS.
xxi.]
335
Hence, as
we have
v
<Ldp
p*
-dv.
v
Thus
gives,
397.
As Laplace
dilatations of
air,
first
lc
constant,
instead of
pv =
constant,
for the
- Rt
\/~Rt
(Laplace).
(Newton).
HEAT.
336
[CHAP.
<r,
as calculated
c,
395.
improvement of one of
interesting and instructive
Joule's
in
its
methods)
is
most
the
consequences.
We
will
tion, the
to,
definiair
at
399.
proved
be described, Joule
developed
work
By
in the
compression of
air is the
equivalent of the
spent.
This
is
And
the following
This
is
salutary lesson
by no means a
self-evident proposition.
In
fact,
ELEMENTS OF THERMODYNAMICS.
xxi. J
337
more imperfect
Hence the calculation of
gases
the dynamical equivalent of heat, which Mayer founded on
this proposition, at a time when its truth had not been
gaseous
it
state,
and even
in
truth.
by
it
its
exhausted of
might have expected, that the vessel from which the air had
been forcibly extruded fell in temperature in consequence of
It had expended some of its energy in
that operation.
forcing the air into the other vessel.
But that
air,
being
Thus
hotter than
vacuum became
had been
HEAT.
338
[CHAP.
till
as
it
then,
before,
common
tem-
change
in temperature.
at
him
least as nearly as so
to test
it
the other.
401.
Now
It
first
a certain capa-
not so
had
much
available working
There was,
before.
power stored up
therefore, dissipation
in
it
as
it
of part of
lost to the
The
was done.
its
air
bulk
available.
it
The
air
had seized
of dissipating part of
as far as
its
was compatible
arrangement.
at
ELEMENTS OF THERMODYNAMICS.
XXI.]
402.
this
is,
339
that in order to
of doing as
much
to get
enough to force back the air into the first vessel from the
second has been expended, the amount of heat which is
given out during the process which can be measured with
is almost precisely equivalent to the work
great exactness
which
is
Work
must be degraded.
instead
its
certain
amount of energy, or
energy in place of
it,
it
we have
got
must waste a
and which
We
it
possessed originally,
its
sudden
expansion.
in
1 86.
The gas to be experimented on is made to pass, as
uniformly and noiselessly as possible, through a tube in
which there is an obstruction, in the form of a porous plug,
such as a pellet of cotton-wool or the like. The temperature of the stream is carefully measured on each side of the
plug,
and
at
local irregularities
produced by
it.
HEAT.
34o
[CHAP.
Let the pressures before and after passing the plug be/ and
p' t the corresponding volumes of unit mass v and v.
Then pv
is
work done on
the
unit
as
it
leaving
the
Their difference
plug.
the gain of
is
E' -
=/
v -
p'v',
E
is
+p
constant.
Therefore
taking /
or,
392),
and
/ as
o,
independent variables,
dt
Now
pressure,
is
which
395) we called
d<$>
_
'
dv
Also
k.
(393) we have
~di
~dp
With these
kt
Here
= -
v (i
et)
S/
(i)
To compare
T be the tern-
ELEMENTS OF THERMODYNAMICS.
xxi.J
34*
pV = C(l
+ aT)
dv
and
vdT ^
a.
+ af
therefore
Thus,
finally,
variation of /
ture be
0.
a
404.
The
(log./
two terms of
log./')'
sult
of
third term
at
first
A'
HEAT.
342
gases
and considerably
[CHAP.
All the true
2737
on
at
ELEMENTS OF THERMODYNAMK.t
XXI.]
..
Sft
Tj-r
r* F*IJ
vaUie of the
quantities,
and
may be estimated
/,
407. In
78-81 a first notion was given as to the dissipation of energy.
Closely connected with this is the
Restoration of energy, a question also first treated by W.
Thomson. The tendency of heat (whether by conduction,
radiation, or convection) towards equalisation
ture,
i.e.
tion
or
to loss of availability,
degradation.
problem to seek what
It
becomes,
of tempera-
first
hint of dissipa-
then,
an interesting
gave the
HEAT.
344
[CHAP.
/r-ftf.
Suppose that we operate upon a number of bodies at
some being used to supply heat,
;
others to have heat supplied to them
then the work will
different temperatures
be simply
the excess of the heat taken from
This must always, except when perfect engines are employed, be less than the realisable
that given to others.
value
S (O) Hence we
t,
(f).
is
when
its
when
no
The
repre-
difficulty.
Thomson
called dissipation."
May
1879.
ELEMENTS OF THERMODYNAMICS
xxi.]
545
temperatures of
is
surrounded.
In the
latter case
it is
the utmost
amount
the
work which
of
temperatures of the
*m
where
is
ical
its
c its specific
heat in dynam/
the final
and
absolute
units,
temperature,
temperature to which the whole system is to be reduced.
For mcdt is an element of heat, in a body at temperature
Of
/.
this,
the
amount me
Y^
sign
dt can be realised
.
is
The
integration
cooled to
by a
sums
And
the
masses of
the system.
When
the system
is
this
This condition
is
expressed by
o.
HEAT.
346
[For,
when
the
higher than
/ ff
in
the
temperature,
the quantity
body
at /
of one
/,
mass
at /.
of the masses
leaving that
But when
to the
supply of
/
[CHAP.
/ is
mass
is
deposits
lower than
the
the taking of
at / necessitates
J-T
'
same
the
therefore
in
The form
either case;
is
of the expression
and
provided
the
for
is
distinction
by the
fixed
From
latter.]
for
specific heat to
common
entirely realised
is
V'/t/a,
itself is
Thus the
in foot-pounds,
'39
(i9'339
ELEMENTS OF THERMODYNAMICS.
xxi.]
The
when
is
347
reduced,
of
water
1390
raised
x 7-76
3'88,
obtained in
i.e.
the
we can
about
1390
0-048 foot-pounds.
The entropy
When
ture
/,,
its
motivity
is (as
we have
A-/o
is
in a
body
at tempera-
seen)
rr
~7T
where
H of heat
passes from
first
HEAT.
348
[CHAP.
TJ
to the
amount
TT
to the
amount -_
378)
need be
(theoretically)
no
loss of motivity,
i.e.
no dissipation
Thus we
the universe
tical with,
tends to
though
it
a
is
"
The entropy of
no
means idenby
Thomson's
connected
with,
closely
theorem,
maximum"
is
can now do
Let
Then
ELEMENTS OF THERMODYNAMICS.
XXI.]
from
349
t to
be
dt
it
is
$(
which
dE
dt
[Hence we see
point, for then
at
(
once that
193)
is
'
II vanishes
at
maximum, and
the
neutral
therefore
This equation shows that the value of II may be completely determined from measurements of the current in
the circuit as depending on the temperature of the hotter
junction, the colder being kept at constant temperature.
Conversely the comparison of the observed currents with
effect,
would enable
HEAT.
350
us
to
test
[CHAP.
we have
made.
But if
415. So far, we have been following Thomson.
we now introduce the experimental result ( 197) that the
specific
heat of electricity
temperature,
is
we have
dE
d
-'
dt
The second
~d
gives
3= c
=
because
With
(k,
(*,
k,)t,
- ka
) (T
/).
the
first
gives finally
ELEMENTS OF THERMODYNAMICS.
XXL]
The measurement
effect
in
therefore
351
Thomson
be carried out
directly.
electric current
will
among
circuit.
CHAPTER
XXII.
NATURE OF HEAT.
417. EVERY ONE has heard of the celebrated phrase
" Ohne
Phosphor, kein Gedanke" Be what there may of
truth in this, the facts stated in the preceding chapters
" Without
But just
entitle us to say
motion, no heat."
as from the first statement, even if it were proved to be
absolutely true,
"
is
we should
not be
entitled
"
so the second by
Thought phosphorus
" Heat is motion."
It is therefore
that
plies
:
to
say that
no means im-
much
to
be
regretted that
subject,
form in which
it
was
originally
mode
two
referring
scientific,
course, in
to
NATURE OF HEAT.
CH. xxil.]
353
would not
In the posthumous
MSS. of Sadi Carnot, published for the first time in 1878,
we find that he carefully guards himself in his statements
on this matter. Thus he says: Un mouvement (celui de
be merely slipshod,
it
would be untrue.
Alors
il
be able to recognise
it
again,
dis-
much
is
how much
it ; what it
That some of it,
energy we know from the
leaves
at least, is in the
form of kinetic
facts of radiation.
i.e.
a whole.
And we
for the
moment, we mean
Hence
is
not confined
all
literally
may have
motion of each
and motion of the
A A
HEAT.
354
[CHAP,
parts of a particle relative to its centre of inertia. This consideration, as we shall see later, leads to some very important
consequences.
How much
419.
of the
motions of
energy in a
body
is
that of
necessary that
its
we should
briefly consider
what
is
known as
grainedness or heterogeneity, is
Thus, as water
variety of facts.
made
is
certain
by a great
compound body,
it is-
are
to be portions of water.
still
This,
it
must be remarked,,
is
i.e.
to
ment, however,
is
into
physics.
bubble
(3)
and
NATURE OF HEAT.
xxii.]
355
these, as
The atomic
422.
which
sophers,
have
thought
a gas.
if,
for the
We
particles,
we
square.]
Boyle's
Law can be
For, suppose a
by
elementary hypothesis.
be inclosed in a cylinder, and suppose that we could,
arrived at
gas to
mean
this
Then
the
number of
AA
HEAT.
356
[CHAP.
reduced to
the same.
whose
of
Let
side
is
M be
/,
may be made
as
Then,
particles.
Thus the
if
we suppose
one-third of
them
to
be
second on a face
is
nuj6l.
square of the
approximate investigation,
pv =
\Mu
z
,
An
easy
is
extension
we assume
shows
how
to
estimate
the
that the
due to
assume
NATURE OF HEAT.
xxn.]
425.
work
is
italics
in
in part
we must
so
in
special remarks,
357
recur to them.
is
is
heated, and
365) that
must be removed as it
spent, and its equivalent
to compression
Thus work
is
is
communicated.
in heat
communi-
In other words,
cated to the surroundings of the cylinder.
But if the italicised statethere is dissipation of energy.
ment could be
its
particles
426. It
would not be
is
to
altered.
Clausius
that
we
are
earliest
He
the particles, and to show that these did not alter the preHe has also the great credit of
viously obtained results.
introducing the statistical methods of the theory of probabilities, and of thus giving at least approximate ideas as to
the probable length of the mean free path, i.e. the average
distance travelled over by a particle before
another, and thus has its course changed.
it
impinges on
He
thus ex-
all
moved
friction,
and
HEAT.
358
determination
definite
of
the
[CHAP.
length
of
the
mean
free
path.
These
mann and
have since
others,
still
theory.
give a general
This
will
be
by
this,
we can
427.
Assuming
that
the
slight
expressed as follows
Here the
left-hand side
sum of
is
The
pressure on the containing walls (supposed uniform).
second term, which Clausius names Virial, depends on the
NATURE OF HEAT.
xxii.]
359
particles.
we suppose
If
for a
moment
particle.
when they
depends
common
When
is
small in
multiplied
by the
negligible
to the
term
is
form
S(/
This
this
is,
in
a
)
=pv.
by
and, as already stated, it leads us (by comparison with the Law of Boyle and Charles) to regard the
absolute temperature of a gas in this condition as directly
Joule
423)
is
where
ft is
four-fold the
For a given
sum
total kinetic
energy
(i.e.
for
an isothermal) the
HEAT.
360
gas
and
now shows
[CHAP.
The equation
shows a
just written
volume
fair
is
diminished.
and pressures
be accounted for
In this case
A
r
where Afv
J 2 (mu
is
12
by endeavouring
viz.
=
;
(p +
who seems
Though
objections
it
due to
may be
NATURE OF HEAT.
xxii.]
361
new and
among/, z\ and
Laws of Boyle and
/,
which
Charles.
"
diaphragm
among
systems,
its particles.
an elementary
treatise
and
it
molecular forces
was
Hence
it
follows that
when masses
of different
the
number
Ampere
He
in 1814).
also
demonstrated
that,
in
a mixture of gases in
HEAT.
362
[CHAP.
remarkable
relation,
any one
particle, the
same
ratio as
approximately the size of a particle from the relative denThus it is found that the
sities of the gas and the liquid.
number of
particles of gas
in a cubic
inch, at ordinary
20
temperature and pressure, is somewhere about 3 x io
while if it be oxygen, the mean free path is about - Tfaru
inch, and the velocity of mean square about 1550 feet per
It follows that, on the average, each particle has
second.
;
If
or two of particles,
Even then
this state of
NATURE OF HEAT.
xxii.]
363
cubic
moment)
becomes
Spaces
than
less
the trillionth part of a cubic inch will, however, occasionally (but only for periods less than the billionth part of a
second) contain oxygen or nitrogen particles alone. [These
all
that
we
require
magnitudes involved.]
432. The following experiment, due to Graham, is one of
the most beautiful and suggestive in the whole range of
while it requires, for its successful
physical science
:
of
full
The
air,
and
difference
due
to capillary forces,
[Had
made
This state of
depression of the level of the inner surface.]
things is maintained by the absolute equality of the numbers
of particles continually passing opposite ways through the
fine pores of the clay.
Unfortunately we cannot mark the
particles, so as to be able to see directly that the contents
if
fewer
HEAT.
364
Now
[CHAP.
this is precisely
the tube.
be continued
for a little,
(collected
the ball.
what
in
an
The
the contents
case
for
to give an additional
sizes
of
it
may
the theory
NATURE OF HEAT.
XXII.J
enabled us to arrive at
actual size
much more
365
31oUailes
Oxygen.
6190
386
1550
1656
1320
224
7646
193
9489
9720
3-5
3*7
Velocity of mean-square at o C.
Mean path
Collisions
1775
Diameter
The
2-3
second
the
Carbonic Carbonic
Oxide.
Acid.
Hydrogen.
c
the
151
is
for
sliding over
viscosity,
among
the numerical
and heat-conduction
in
a gas.
But these could not easily be made intelligible
without a more careful examination of the theory than our
limits
permit
it
HEAT.
3 66
[CHAP..
moving
ot the
tears itself
it
rest in spite
molecular forces.
is
particle
436.
We
saw
in
418
motions of the
are at least in
medium
in the
communicated
part
to
the luminiferous
Of
for the main loss of energy in the radiant form.
however, we cannot be absolutely certain, for we are
account
this,
altogether ignorant of the mode in which energy is transferred from ordinary matter to the luminiferous medium
and it is possible that there may be a direct transfer even
:
when
the particle
is
moving merely
as a whole.
In such a
thus transferred
luminiferous
would be
stored
or
propagated in the
we are prepared to
when their temperature is sufficiently
raised, give out one or more radiations each of perfectly
This corresponds to one or more
definite wave-length.
if
all
all
some
NATURE OF HEAT
xxn.J
3^7
receding from him, with velocities not negligible in comHence, from this cause, which
parison with that of light.
tells
more
finite
as the temperature
the vibrating
body
is
The
necessarily altered.
is
At the
we saw
in
305)
it
make
the
And
whole.
constrained
438. Another point of importance, in which also experiprevisions of theory, is that the
number
of
pages, entered with any detail into the methods and results
of spectrum analysis.
(See Nature, xxiv. 582.)
more
obtain
Second
Law
we gave
light
of Thermodynamics
in passing, in
82).
HEAT.
368
(which
is
essentially that of
[CHAP.
W. Thomson)
that
we cannot
that
at the
it
is
it
410,
impossible to
we employ.
As
will
And
thermo-electric
current,
from a
sufficient
pile
of
higher temperature
This form is
interpreted into "without compensation."
not liable to the thermo-electric objection above.
Clausius'
thus ultimately becomes, " In all uncompensated
transformations there is increase of entropy."
440. The true basis of the second law is to be found in
basis
matter
NATURE OF HEAT.
xxii.]
369
move
in, bit
upon which
unaltered,
its
itself
This
the second law of thermodynamics, and it is undoubtedly true as long as we can deal with bodies only in
is
B B
HEAT.
37
[CHAP.
able to
still
do what
at present impossible to
is
temperature
are
moving with
For we
us.
full
of
velocities
air
at
by no
which we have drawn from our experience of bodies conan immense number of molecules, may be found
sisting of
far
will
NATURE OF HEAT.
xxii.]
37 1
that (so far as it has yet been developed) it has not been
reconciled with the observed values of the specific heats of
is
motion.
Thus the
energy of translation shall be made larger.
calculated values of the specific heats are as a rule much
But
too large.
it
would appear
been
This
is
not
likely,
so far at
are,
unconnected
facts.
438.)
(See, again,
444. In the present state of science we are not likely to
take the course of Clairaut, D'Alembert, and others who,
to differ considerably from that given by observation, proposed to modify the gravitation law of the inverse square of
which
it
had already so
it
fully
adapted
itself.
purposes
HEAT.
372
[CH. xxii.
would sink
which we had
body.
Resume of
417-445.
Calculation
methods.
Nature of heat in
Virial.
Law
Temperature.
of collisions.
>,
FORM NO.
<B>s
Id
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