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Thermodynamics
Closed System
So far
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Q (heat)
W (work)
E (Energy)
Recall
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Recall
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Recall
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Experience 1: W= 0
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Experience 2: W=0
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Experience 3: Q=0
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Experience 4: Q=0
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If we do a 10 kJ of boundary
work on a system,
the systems internal energy
will increase by 10 kJ.
This is because (in the
absence of any heat transfer (Q
= 0), the entire boundary work
will be stored in the air as part
of its total energy.
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If we do 6 kJ of shaft
work on system and
Transfer 15 kJ of heat
in.
Loose 3 kJ of heat
out.
Doing 4 kJ of Work
out.
Then the system
internal energy will
increase by 14 kJ.
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E in E out = E sys
Rate of net energy transfer
by heat, work and mass
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E = U + KE + PE
Usually the KE and PE are small
E = U = mu
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Ein Eout = E
Eout
Ein
0
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Q W = E
Q W = E
q w = e
q w = de
differential form
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KEY CONCEPT
Q W
E
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Q-W =U
But U = U2-U1=0
(initial state and final
states are the same)
Hence : Q=W
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Example (4-1):
Cooling of a Hot fluid in a Tank
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Example (4-2):
Electric Heating of a Gas at Constant Pressure
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Example (4-3):
Unrestrained Expansion
of water into an
Evacuated Tank
A rigid tank is divided into two equal parts
by a partition. Initially, one side of the tank
contains 5 kg of water at 200 kPa and 25oC,
and the other side is evacuated. The
partition is then removed, and the water
expands into the entire tank. The water is
allowed to exchange heat with its
surroundings until the temperature in the
tank returns to the initial value of 25oC.
Determine a) the volume of the tank, b) the
final pressure, and c) the heat transfer for
this process.
Example (4-6):
Heating of a
Gas at
Constant
Pressure
A piston-cylinder device initially contains air at 150 kPa
and 27oC. At this state, the piston is resting on a pair of
stops, as shown in the figure above, and the enclosed
volume is 400 L. The mass of the piston is such that a
350-kPa pressure is required to move it. The air now
heated until its volume has doubled. Determine (a) the
final temperature, (b) the work done by the air, and c)
the total heat transferred to the air. <Answers: a) 1400 K, b)
140 kJ, c) 766.9 kJ>
Sol:
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