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Volume 12 Issue 3 Version 1.0 Year 2012
Type: Double Blind Peer Reviewed International Research Journal
Publisher: Global Journals Inc. (USA)
Online ISSN: 2249-4596 & Print ISSN: 0975-5861
Keywords : copper, NCRH, breakthrough curve, adsorption rate coefficient, adsorption capacity
coefficient.
GJRE-C Classification : FOR Code: 030504
Fixed Bed Column Study for the Removal of Copper from Aquatic Environment by NCRH
2012 Upendra Kumar & Jyotikusum Acharya. This is a research/review paper, distributed under the terms of the Creative
Commons Attribution-Noncommercial 3.0 Unported License http://creativecommons.org/licenses/by-nc/3.0/), permitting all non
commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
I.
Introduction
Year 2012
Fixed Bed Column Study for the Removal of Copper from Aquatic Environment by NCRH
Year 2012
b) Preparation of adsorbent
c) Experimental Studies
tz =
V E VB
Qw
(1)
Fixed Bed Column Study for the Removal of Copper from Aquatic Environment by NCRH
Where,
C0 = initial solute concentration (mg/l)
Sz = amount of solute that has been removed by
the adsorption zone from breakthrough to exhaustion
Smax = amount of solute removed by the adsorption
zone if completely exhausted
The percentage of the total column saturated at
breakthrough is
0.8
0.7
C/Co
0.6
0.5
0.4
0.3
% saturation =
0.2
0.1
0.0
0
9 10 11 12 13 14
Time (h)
tE =
VE
Qw
(2)
Uz =
hz
h
=
tz tE t f
(3)
Where,
h = height of exchange zone (cm)
h = total bed depth (cm)
tf = time required for the initially form (h)
Rearranging Eq. 3 provides an expression for
the height of the exchange zone as given below.
hz =
h(t z )
tE t f
(4)
t f = (1 F )t z
(5)
V (Co C )dV
Sz
F=
= B
S max
C o (V E VB )
h + (F 1)hz
100
h
(7)
C / Co
KN o X
ln
=
+ KCo t
V
1 C / Co
(8)
Where,
C = concentration at any time t
Co = initial Cu(II) concentration (10 mg/l)
V = approach velocity (210 cm/h)
X = bed depth (10 cm)
K = adsorption rate constant (l/mg-h)
No = adsorption capacity constant (mg/l)
Rearranging Eq. 8
C
KN o X
ln
=
+ KCo t
V
Co C
(9)
(6)
Year 2012
0.9
1.0
Fixed Bed Column Study for the Removal of Copper from Aquatic Environment by NCRH
2.5
2.0
1.5
5.
ln[C/(Co - C)]
1.0
0.5
0.0
-0.5
6.
-1.0
-1.5
y = 0.560x - 4.382
-2.0
R = 0.957
Year 2012
-2.5
7.
-3.0
0
9 10 11 12 13 14
Time (h)
8.
IV.
Conclusions
9.
10.
11.
12.
13.
14.
15.
Table 1 : Volume of effluent treated and the mass of NCRH required up to breakthrough
Bed depth
(cm)
10
10% Breakthrough
time (hr)
3.583
Treated volume
(lts)
2.15
Total mass of
NCRH (gm)
8.39
Table 2 : Cost for volume of metal effluent treated up to breakpoint per kg of NCRH
Metal
Cu(II)
2012 Global Journals Inc. (US)