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DRAFT
CHAPTER 6
Digestate
6.1
Introduction
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6.2
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6.3
6.3.1
6.3.2
6.3.3
6.3.4
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6.4
6.4.1
6.4.2
6.4.3
6.4.4
6.4.5
6.4.6
6.4.7
Separation techniques
Screw press
Belt press
Centrifuge
Bio-drying
Evaporation
Membrane filtration and reverse osmosis
Chemical separation
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6.5
6.5.1
6.5.2
6.5.3
6.5.4
6.5.5
6.5.6
6.5.7
Application of digestate
Bandspreading
Tankering
Trailing shoe
Dribble bars
Disc injectors
Tine injectors
Manure-type spreaders
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6.6
6.6.1
6.6.2
6.6.3
6.6.4
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6.7
6.7.1
6.7.2
6.7.3
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6.1 Introduction
The anaerobic digestion of biodegradable materials produces two key outputs,
namely biogas and a nutrient-rich biofertiliser known as digestate. Wet AD
systems produce digestate in a liquid form (whole digestate) that can be
separated to produce liquor and fibre/cake fractions, whilst dry AD systems may
produce digestate which is entirely fibre-based (although many will have a liquor
fraction as well).
The principle that what goes in must come out is common to all digestates,
in that the majority of plant nutrients present in the feedstock will transfer to
the resulting digestate, with the exception that some nitrogen may be lost as
ammonia and sulphur as hydrogen sulphide. While the digestion process renders
nitrogen in digestate more available for crop uptake, it is equally true that heavy
metals such as copper and zinc, and any non-degradable contamination such as
plastics, will pass through into the digestate. Therefore, the better the quality of
feedstock, the better the quality of digestate produced.
Requirements for both producers and users of digestate vary across the UK and
guidance is available from Defra, SEPA (Scottish Environment Protection Agency),
DARD (Northern Ireland Department of Agriculture and Rural Development) and
the Welsh Government.
Rules vary depending on the nature of the digestate and the level of control
in production. For example, high quality digestate made from approved
biodegradable materials, wastes and purpose-grown crops may be used outside
of Environmental Permitting Regulations if the relevant Quality Protocols
are followed. Conversely, other waste-derived digestates, for example from
mechanical biological treatment (MBT) facilities, should only be applied to land
under prior notification or permitting. It is also customary for digestate suppliers
to provide end-users with a recent analysis from an accredited laboratory, as
agronomic value will vary depending to some extent on the AD process and to a
considerable extent on the nature of the feedstock.
Compliance with standards such as PAS 110 may only partly meet the needs of
end-user farmers. This is because PAS 110 relates primarily to product safety rather
than to agronomic value and so farmers may require more information, particularly
regarding NPK (nitrogen, phosphorus and potassium) quantity and form. Producers
selling digestate may also have to comply with regulations concerning product
labelling and usability and should refer to the appropriate guidance.
DRAFT
As a general rule, the use of fertilisers, including digestate, must comply with
a range of legislative requirements both for agricultural best practice and
environmental protection (cross-compliance requirements can be complex and
cannot be defined in this publication).
There are multiple advantages to the application of digestate on agricultural land,
from increasing nutrient value to improving the physical structure of the soil.
These benefits have been widely recognised across continental Europe and North
America where on-farm use of digestate is well-established. British farmers are
also now being encouraged to consider whole farm issues, and so interest in
digestate spreading is increasing.
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Quality of digestate is not only dependent on feedstock but also upon the efficiency
of the digestion process. A well-digested material with high conversion of volatile
solids will be stabilised and should be low in odour. However, a poorly digested
product will retain readily degradable organic material and risks further degradation
(and therefore release of odour) during storage or after application to land.
Poor digestate risks being a source of odour, may self-heat due to continued
biological activity, and may have a high level of residual biomethane potential
(RBP), which reflects a potential to release unwelcome greenhouse gases, such
as methane and carbon dioxide, into the atmosphere. The following pictures
show similarly derived good and poor digestate resulting from a well-controlled
process and a failing process respectively.
Reduced weed seeds: Most weed seeds present in raw slurry are
killed during the AD process, particularly where that process includes a
pasteurisation step, saving on herbicide-related costs.
Reduced pathogens: AD kills bacteria such as salmonella, e-coli and
parasites including tapeworm, which are potentially present in untreated
waste and cause infections to farm animals where untreated manure is
spread. Digestate from processes with a pasteurisation step will have a very
high and demonstrable level of biosecurity.
Greater availability of nutrients: During anaerobic conditions, organic
forms of N are converted into ammonium-N (NH4). Plant uptake of N from
digestate is comparable to uptake from commercial fertiliser and can be
a more predictable source of N than raw slurry. It should be noted that,
depending on the temperature and pH of the digestion process, NH4 can be
altered into free ammonia (NH3) which will volatilise. Spreading digestate
with high ammonia concentrations can lead to odour release and loss of
nutrients. In order to avoid risk of nuisance, good practice such as sub-soil
application of liquid digestates is advised.
DRAFT
Digestate can either be applied to land whole or separated into solids and
liquids, generally referred to as fibre and liquor. Separating the digestate using
mechanical, biological or thermal equipment can have a number of benefits that
can justify the cost of the additional equipment, including:
Selective storage of flowable and stackable materials;
Improved pumpability of separated liquor;
Partition of nutrients at different ratios in the liquid/solid phases; and
Reduced storage volume of liquids compared to whole digestate.
Separation is usually carried out at the AD facility as the two products may be
sent to different outlets. As wet AD systems receive predominantly sludges and
slurries, dewatering may generate relatively little solid material, with a typical
ratio of >5:1 liquor:solid.
Facilities handling purpose-grown crops such as maize silage will generate
a significant amount of solids that can be separated, while dry AD systems
handling comparatively coarse and woody input material may predominantly
generate solids with little or no liquid, with ratios closer to <1:3 liquor:solid.
In summary, digestate from different AD technologies can have quite different
characteristics. Changes in inputs can have a significant impact on the mass
balance of the process which, in turn, can have a significant positive or negative
impact on the business.
PAS 110 defines three types of digestate fraction: whole digestate, fibre fraction
and liquor. There is another type of digestate fraction called cake, a term that
comes from the water industry which has a subtle nuance in definition. These
terms are explored in more detail below.
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6.3.1 Whole digestate
Whole digestate is the digested liquid that comes out of the digester without any
form of separation. Typically this will be between 2% dry solids and 6% dry
solids in a wet digester and 18% to 23% in a dry, with varying concentrations
of N, P and K.
6.3.2 Liquor
Liquid digestate, known as liquor, contains a diverse range of nutrients and can
be used as a liquid fertiliser or, due to its high water content (low DS content),
for fertigation on agricultural land. This generally means application to land
by tanker or irrigation system, respectively. Liquor containing particles or
coagulants would need to be pre-filtered for fertigation, while liquor used as
a liquid fertiliser via greenhouse microbore irrigation systems may need to be
fine-filtered to prevent blockage of feeder pipes.
As with any fertiliser containing N and other plant nutrients, the liquor should only
be used when there is agronomic demand, in certain locations and on certain
types of soil. It should be applied in accordance with good agricultural practice
and as part of an integrated fertiliser programme, to ensure that the optimum
nutrient requirements for the crop
are supplied. It is good practice for
the farmer or operator to regularly
analyse the soil and the liquor, to
assess the appropriate application
rate and to quantify the amount of
chemical fertiliser to be applied
to crops and grassland, as overapplication causes vegetation
scorching. Many areas in the
UK are Nitrate Vulnerable Zones
(NVZ) which require applications
Picture 3. Salad leaf production using
hydroponics with AD-derived liquid fertiliser
of N to be limited and recorded.
Liquor is generally used on the farm on which it was produced although a potentially
wider market is developing through AD operations working in partnership with the
agricultural industry. The liquid fraction from dry AD facilities tends to be relatively
high value. Fertiliser value depends on the feedstock but generally, NPK is likely
to be in the order of 35:15:35 (kg/t) as freely available N:P2O5:K2O. In continental
Europe, some sites have been certificated as producers of organic liquid fertiliser.
7.67.7
c.2.5
DRAFT
Dry solids (DS)
43.257.9
Organic matter
41.056.6
Total-N
kgt-1DS
8.813.0
Available-N
kgt-1DS
1.01.5
Phosphate (P2O5)
kgt-1DS
6.38.7
Potassium (K20)
kgt-1DS
7.212.0
Calcium
kgt-1DS
12.6131.6
Magnesium
kgt-1DS
4.56.1
Sulphate
kgt-1DS
<0.053.7
Parameter
Unit
Cadmium
gt-1DS
0.10.2
Dry substance
% FS
1215%
Copper
gt-1DS
24.249.9
Organic DM
% TS
5065%
Nickel
gt-1DS
6.613.4
Total Nitrogen
mg/l
4,000 6,000
Lead
gt-1DS
23.036.4
NH4-N
mg/l
1,000 3,500
Zinc
gt-1DS
42.483.1
BOD
mg/l
7,500 10,000
Chromium
gt-1DS
COD
mg/l
90,000 115,000
Mercury
gt-1DS
7.5 8.5
pH Value
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6.3.3 Fibre
Fibre refers to the coarse screened material from whole digestate and will
typically represent 10% to 40% of the total solids material in digestate. Because
it tends to be primarily long fibre material, the most useful application is as a soil
conditioner. Fibre has the advantage of being stackable and can be transported
by lorry rather than tankers and easily stored on site or on fields.
6.3.4 Cake
The term cake is generally used in the water industry, whereas in the waste
industry the term fibre is more commonly encountered. That said, when sourceseparated food waste is anaerobically digested the output is more cake than
fibre, and so the expression is becoming more frequently used in the waste
sector.
DRAFT
Picture 4. Solids fraction (fibre)
following the pressing of digestate
derived from the AD of maize
It is common to further treat fibre with post aeration and this is usually required
for crop-based systems due to the very slow break down of lignin. Digestate from
dry digestion is also usually referred to as fibre and is often further treated by an
aerobic composting stage post digestion.
Dry AD digestate can not only in be used agriculture but can also qualify as
finished compost, as defined by UK PAS100 or Rottegrade 4-5 (commonly
accepted standards of usability and stability). Examples include horticultural
growing media, turf and landscape products, as well as soil blends.
This is not just a semantic difference; when referring to fibre we usually mean
the large indigestible fibres (usually lignin) that are separated out by a relatively
coarse screen following digestion. Fibre tends to have a low agronomic value as
most of the nitrogen and phosphorus are retained within the liquor fraction.
When talking about cake, we are referring to the solids fraction of the whole
digestate, including the fine particulates and cell mater. Cake is usually produced
by centrifuge or gravity thickening belts (see below) that can capture >95% of the
solids material. In this way the majority of the N and P are retained in the cake
fraction. Fibre fractions are usually a by-product of removing large particles that
would clog up irrigation systems, whereas cake is a desired end-product. A good
cake product should be well stabilised, black in colour, friable and resemble
soil.
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6.4.1 Screw press
A screw press compresses the digestate into a gradually decreasing screw
channel between a screw shaft and screen mantle, squeezing out the liquid.
Different screens and operational pressure can be used to alter the efficiency of
the separation process. This method can achieve 3038% DS. It is worth noting
that screw presses tend to have a solids-capture efficiency between 10% and
40% depending on the feed characteristics.
6.4.5 Evaporation
A relatively new technology in the UK but one that has been operational in
continental Europe for a number of years, evaporation systems generally rely on
two effects: first the digestate is heated using either hot water or steam; second,
low pressure steam is flashed off using a cyclone separator and a vacuum pump.
By subjecting the heated liquid to a vacuum (the pressure is reduced to below
atmospheric), the boiling point of water is reduced and steam can be generated
at low temperature.
DRAFT
6.4.4 Bio-drying
Bio-drying uses aerobic bacteria which occur at the beginning of the classic
composting process. These bacteria heat the digestate and remove the water
content. This process may be inefficient unless supplemented with auxiliary
heat, such as exhaust heat from a combined heat and power unit (CHP), or may
require an agitation process due to the high thermal inertia of moist, fine particle
digestate.
Picture 7. Dewatering of
sludge-derived digestate
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Equipment used to apply raw slurry and separated liquid onto land can also
be used to apply digestate. Similarly, equipment used for spreading solid
farmyard manure can also be used to spread separated solids. The application
of digestate to land can be carried out by several different methods, including
tractor and tanker, self-propelled tankers or umbilical cord spreading. Whichever
method is used, it is good practice to inject whole digestate as odours from NH3
volatilisation can cause nuisance.
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6.5.1 Bandspreading
Bandspreading involves a flexible supply pipe connected to a tractor and
applicator which drags the pipe across the field applying the digestate. It is a
fast, efficient method of application with reduced compaction of land compared
to tanker spreaders, and achievable work rates of 100 m3 to 130 m3 or more
per hour. Distance from the store can be overcome by adding booster pumps.
Umbilicals can be used to pump directly out of the AD plant/storage site, or
out of a headland nurse-tank if transportation by road is required. The main
drawback of using umbilicals is a reduction in consistency of the digestate. Band
applicators are the preferred method of application, as they dramatically reduce
nutrient losses.
DRAFT
6.5.2 Tankering
Tankering is useful when it is not possible to access the land with an umbilical.
Tankering can be costly due to the limited quantity being moved per load, and
ground compaction may also be an issue from the weight of the tractor and
loaded tanker. Low ground pressure equipment is advisable.
Picture 11. Purpose-built tanker used for
field spreading of AD liquor
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Total N
(nitrogen)
NH4N
(ammonium nitrate)
P2O5
(phosphate)
K2O
(potassium)
Units
Kg/m3
Kg/m3
Kg/m3
Kg/m3
Range
4.66.7
2.75.0
1.43.4
2.85.3
%DM
(dry matter)
5.88.5
Source: www.scotland.gov.uk/Resource/Doc/1057/0053041.pdf
Food waste typically results in digestate with different levels of NPK compared to
agricultural materials. This will depend on the protein content in food waste, for
example digestate from meat residues will have NPK ratios of around 12:1:4.
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Initiatives such as the Safe Sludge Matrix, together with legislation covering
the application of sewage sludge (Sludge Use in Agriculture Regulations), have
been critical in developing a secure and mutually beneficial recycling route for
digestate in the UK. The Matrix is often regarded as the benchmark for use of
digestates on land in the UK, but must be read in conjunction with other crosssector guidance.
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6.6.4 Digestate from mixed waste
If feedstock comes from a non source-segregated supply then the digestate
is considered a waste material. Generally speaking, digestate from black bag
collections are heavily contaminated and are suitable only for landfill cover and
limited forms of land reclamation. Nonetheless, there are European examples of
AD facilities producing MBT-derived digestates with net benefit when applied to
land and having an acceptably low level of contamination.
DRAFT
Like manure, when whole digestate is stored in open tanks, H2S, NH3 and CH4
gases can be released. The regulatory requirements of the IPPC (Integrated
Pollution Prevention and Control) Directive and the voluntary requirements of the
Biofertiliser Certification Scheme both require that digestate stores be covered,
but this may not be the case for on-farm storage of the finished product.
When stored, operators should be aware that sediment in the digestate will
settle out and will need to be stirred or agitated to ensure homogeneity before
application or transporting. Due to the impermeable nature of roof structures and
flexible covers, specialist design may be required to allow access for agitation
equipment. With flexible covers, care needs to be taken to avoid mechanical
damage during agitation.
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Economics of transport are crucial and can determine the success or failure of
a project. The financial implications of transportation are likely to be significant,
and will be determined by a range of factors including:
The form of the digestate whole or separated liquids and solids;
Transformation of digestate (for example by drying) before or after
transport;
Certification of material for disposal as a waste or use as a product; and
Destination of digestate distributed or centralised deliveries.
DRAFT
Liquid digestate
If bulk transport is needed from AD plants, it may be possible to use the same
tankers which have delivered feedstock to export digestate, providing that input
material is not an animal by-product. Cleaning the vehicles between feedstock
delivery and digestate transportation, to avoid cross-contamination, would have
energy and cost implications and care would need to be taken over the disposal
of any wash water.
Solid digestate
Solid digestate can be transported by truck and stored on fields under a rainproof
cover prior to application. As a rule of thumb, dewatered cake from wet AD
systems will require only 15% to 20% of the vehicle movements required for
liquid digestate.
Final considerations
The AD plant management, the landowner, the recycling team and the transport
company should be regarded as equal partners in any digestate-to-land
programme. All are ultimately accountable to national and regional regulators
and the acknowledgment of this fact is vital to the success of the operation.
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Notes
DRAFT
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