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Article history:
Received 28 December 2013
Received in revised form 4 May 2014
Accepted 6 May 2014
Available online xxx
In this work, two commercial ultraltration (UF) membranes, i.e. UF PES-10 kDa and UF PVDF-100 kDa
and two nanoltration (NF) membranes, i.e. NF-90 and NF-270 were used to treat restaurant wastewater
discharged from local medium-sized restaurant which served typical Malay halal foods. The wastewater
which was subject to membrane treatment process was collected at the point of discharge without
undergoing any pre-treatment process. The separation performances of membranes were characterized
with respect to BOD5, COD, turbidity and conductivity removal while the membrane sustainability was
evaluated based on the water ux recovery. Promising results of COD and turbidity removal (between
97.8 and 99.9%) were able to achieve regardless of membrane type, indicating the size of pollutants
contributing to COD and turbidity values are signicantly larger than 100 kDa. Removal rates of BOD5
and conductivity were found to be strongly dependent on the membrane pore size. As NF-90 exhibited
the smallest pore structure among the membranes studied, it showed the highest BOD5 (86.8%) and
conductivity removal (82.3%). In terms of sustainability, it is found that the original water ux of NF-90
was able to be retrieved by >50% compared to between 15 and 38% reported in the UF membranes, after
only a simple rinsing process. This indicated that NF-90 is less susceptible to fouling and is more suitable
and reliable to be employed for restaurant wastewater treatment.
2014 Elsevier Ltd. All rights reserved.
Keywords:
Ultraltration
Nanoltration
Restaurant wastewater
BOD5
COD
1. Introduction
Over the past thirty years, membrane-based separation process
has emerged as one of the most promising techniques in the water
and wastewater treatment eld owing to the signicant evolution
of the membrane technology [1,2]. However, the potential of
membrane as treatment process has not been examined for all
types of wastewaters. For instance, the exploration of using
membrane for restaurant wastewater is paid little attention and
this can be reected by the limited number of technical papers
available in the literature [3,4].
Restaurant wastewater is water that has been used for cleaning
meats and vegetables, washing dishes and cooking utensils, or
cleaning the oor. The efuent is usually heavily loaded with
organic matters from the leftovers of food and soup which are
made of oily avorings such as soy sauce, seasoning, spice, etc.
Unlike most of the developed countries where the restaurant
efuent is discharged into foul sewers leading to public sewage
http://dx.doi.org/10.1016/j.jwpe.2014.05.001
2214-7144/ 2014 Elsevier Ltd. All rights reserved.
Please cite this article in press as: S. Zulaikha, et al., Treatment of restaurant wastewater using ultraltration and nanoltration
membranes, J. Water Process Eng. (2014), http://dx.doi.org/10.1016/j.jwpe.2014.05.001
G Model
Table 1
Typical local restaurant efuent characteristics and parameter limits of efuent
(Standard B) of environmental quality (Sewage and Industrial Efuents) regulation
1978.
Parametera
pH
BOD5 (mg/L)
COD (mg/L)
Turbidity (NTU)
Conductivity
(mS/m)
Restaurant
Limits of
efuent
(bStandard B)
Zam-Zam Corner
Restaurant
Nor Cafe
4.496.15
816.171097.25
10,356.6716,443.33
402.671208
915.332830
4.865.19
928.581076.50
837.331574.67
865.671199.33
6266.6715,940
5.59.0
50
100
N/A
N/A
a
The range of value shown is obtained from four different measurements at
different periods.
b
Standard B is the standard parameter limits discharge into all inland waters,
except inland waters within catchment areas.
Q
At
(1)
Table 2
UF and NF membranes used in this work.
Membrane
Manufacturer
Polymer
Type
UF PES-10 kDa
UF PVDF-100 kDa
NF-90
NF-270
Alfa Laval
Amfor Inc.
DOWFILMTECTM
DOWFILMTECTM
Polyethersulfone
Polyvinylidene diuoride
Polyamide (aMPD-TMC)
Polyamide (bPIP-TMC)
Tight UF
Loose UF
NF
NF
a
b
Please cite this article in press as: S. Zulaikha, et al., Treatment of restaurant wastewater using ultraltration and nanoltration
membranes, J. Water Process Eng. (2014), http://dx.doi.org/10.1016/j.jwpe.2014.05.001
G Model
MWCOa
(Da)
Pure water
uxb (L/m2 h)
Mean contact
angle (8C)
UF PES-10 kDa
UF PVDF-100 kDa
NF-90
NF-270
10,000
100,000
100
200300
43.7
208.0
19.0
54.6
66.2
81.2
80.3
14.1
(0.8)
(8.0)
(1.4)
(2.4)
(1.4)
(2.1)
(3.2)
(5.9)
Please cite this article in press as: S. Zulaikha, et al., Treatment of restaurant wastewater using ultraltration and nanoltration
membranes, J. Water Process Eng. (2014), http://dx.doi.org/10.1016/j.jwpe.2014.05.001
G Model
Please cite this article in press as: S. Zulaikha, et al., Treatment of restaurant wastewater using ultraltration and nanoltration
membranes, J. Water Process Eng. (2014), http://dx.doi.org/10.1016/j.jwpe.2014.05.001
G Model
Fig. 4. Water ux recovery and pure water uxes of membranes before and after
treatment process using wastewater sample collected from Zam-Zam Corner
Restaurant.
that all the membranes studied provided very similar COD and
turbidity removal (97.899.4% and 99.9%, respectively), but
different BOD5 and conductivity removal. The excellent separation
efciency of membranes for COD and turbidity could be explained
by the fact that those pollutants contributing to COD and turbidity
values were having particle sizes that were larger than the pore
size of membranes used. With respect to BOD5 and conductivity
removal, it is found that NF membranes demonstrated better
results than those of UF membranes and the smaller the pore size
of membrane, the higher the removal rates for BOD5 and
conductivity, resulting in higher quality of treated efuent.
Because of this, NF-90 achieved 86.8% BOD5 removal and 82.3%
conductivity removal in comparison to 82.2% and 8%, respectively
shown by NF-270. Besides showing higher separation rates for
pollutants, NF-90 is also reported to be less susceptible to fouling
owing to its high water ux recovery rate upon a simple rinsing
process without using any chemical cleaning agent. The research
ndings showed that the small footprint membrane technology
could be potentially implemented in local restaurants, treating not
only the efuent heavily loaded with organic matters but also
offering benets to restaurants owner to reuse the treated efuent
for non-potable purposes.
References
[1] N. Hilal, M. Khayet, C.J. Wright (Eds.), Membrane Modication: Technology and
Applications, CRC Press, Boca Raton, 2012.
[2] N.N. Li, A.G. Fane, W.S.W. Ho, T. Matsuura (Eds.), Advanced Membrane Technology
and Applications, John Wiley & Sons Inc., Hoboken, NJ, 2008.
[3] B. Yang, G. Chen, G. Chen, Submerged membrane bioreactor in treatment of
simulated restaurant wastewater, Sep. Purif. Technol. 88 (2012) 184190.
[4] X. Yu, Z. Zhong, W. Xing, Treatment of vegetable oily wastewater using an
integrated microltration-reverse osmosis system, Water Sci. Technol. 61 (2)
(2010) 455462.
[5] W. Chu, W. Hsu, Pollution source identication and waste loading reduction at
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[10] M. Manttari, L. Puro, J. Nuortila-Jokinen, M. Nystrom, Fouling effects of polysaccharides and humic acid in nanoltration, J. Membr. Sci. 165 (2000) 117.
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[13] C.S. Ong, W.J. Lau, A.F. Ismail, Treatment of dyeing solution by NF membrane for
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[14] Y. Kwon, K. Shih, C. Tang, J.O. Leckie, Adsorption of peruorinated compounds on
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4. Conclusions
The effectiveness of two different commercially available UF
membranes UF PES-10 kDa and UF PVDF-100 kDa, and two
different NF membranes NF-90 and NF-270, were evaluated in
this study for treating restaurant wastewater discharged from a
medium-sized Malay restaurant. The preliminary results showed
Please cite this article in press as: S. Zulaikha, et al., Treatment of restaurant wastewater using ultraltration and nanoltration
membranes, J. Water Process Eng. (2014), http://dx.doi.org/10.1016/j.jwpe.2014.05.001