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Fracturing
g Fluid Composition
p
yp
Fluid Types
Water-based Fluids
Linear Polymer Solution
Crosslinked Gel
Viscoelastic Surfactants
Oil
Oil--based FFluids
luids
Acid-based Fluids
Multiphase Fluids
Emulsions
Foams
Energized
Additives
Gelling Agents
Crosslinkers
Breakers
Fluid Loss Additives
Biocid
Biocides
Thermal Stabilizers
Surfactants
Clay Control Additives
Additives
Gelling Agents
Increase Fluid Viscosity for Improved Proppant
Transport
Into perforations
Along fracture
Create/Maintain
/
Desired Fracture Geometryy
Reduce Friction Pressure Loss in Wellbore
Slick Water applications
(HPG)
Carboxymethyl Guar
Guar
(CMG)
Carboxymethyl
Hydroxypropyl Guar
Guar
(CMHPG)
Cellulose
Hydroxyethyl Cellulose
(HEC)
Carboxymethyl
Hydroxyethyl Cellulose
(CMHEC)
Synthetic Polymers
Polyacrylic
Poly
lyacrylic
acrylic Acid (PAc)
(PAc)
Poly
lyacrylamide
acrylamide (P
(PAm)
Am)
Partially Hydr
Hydrolyz
olyzed
ed
Pol
Polyac
yacrylami
amid
de (PHP
PHPA
A)
Acrylamido-meth
Acrylamido-methyyl-propane
l-propane
sulf
sulfonate
onate (AMPS
AMPS))
Viscoelastic Surfactants
Surfactants
Cationic
Anioni
Anionicc
Amphoteric
Agents
Polymer
oy e
Concentration
(by weight)
Guar
< 1%
HPG
< 1%
CMHPG
< 1%
HEC
< 1%
CMHEC
< 1%
Synthetic Polymers
Viscoelastic Surfactants
< 0.05%
< 2%
Crosslinkers
Increase Effective Molecular Weight by
on Polymers
Borate
Chelated Compounds
Compounds
Retard Oxide
Formation
Formation
Crosslinking Rate
Controlled by
Complex Stability and
and
Ligand Concentration
Non
Non-reversible
-reversible
reversible
Shear Degraded
Borax)
Slowly
Slowly
S
Soluble
oluble Salts
(Ca and Mg Salts)
Salts)
Borate Esters
Polyborates
Typical
yp
Usage
g Rate of Common
Crosslinker Compounds
General Class
Borate
Titanate
Zirconate
Concentration Range
< 150 ppm as Boron
< 150 ppm as Titanium
< 100 ppm as Zirconium
Breakers
Purpose
Improve Flowback &
Maximize Conductivity
Mechanism
Reduce Polymer
Molecular Weig
Weight
React with Specific
Sites in Polymer Chain
Reverse Crosslinking
(Borate Only)
Common Types
Oxidizer
Oxidizerss
Persulf
rsulfaate
Perbor
rborate
ate
Hypochlorite
Mg & Ca Peroxide
Enzymes
nzymes
Acids
Esters of
hydroxycarboxylic
acids
References
1. Chapter 7: Fracturing Fluids and Additives, Recent
Questions ?