Chem162 Kinetics Report

Page 1 of 36
Name:
ID Number:
Quiz Section:
Lab Partner:
Chem 162 Experiment #3: Chemical Kinetics

Part I: A Clock Reaction
Part II: Crystal Violet-Hydroxide Reaction
Note: All sections of this report must be typed.
By signing below, you certify that you have not falsified data, that you have not plagiarized any part of this lab
report, and that all calculations and responses other than the reporting of raw data are your own independent
work. Failure to sign this declaration will result in 5 points being deducted from your report score.
Signature:
Grading: 60 pts.
(Lab notebook pages are worth 5 pts - total for report and notebook is 65 pts)
Purpose and Method

Part I: Clock Reaction
(1) Identify the purpose, (2) provide the relevant equations, reactions, and rate law, and (3) provide a brief
description of how the rate law is determined (how do you figure out the orders for reach reactant?) and how the
rate law for one reaction is determined by observing a related reaction. (3 pts)
Part II: Crystal Violet-Hydroxide Reaction

(1) Identify the purpose, (2) provide the relevant equations, reactions, and rate law, and (3) provide a brief
description of how the rate law is determined (how do you figure out the orders for each reactant?). (3 pts)
Page 2 of 36
Data, Calculations and Graphs

Part I: A Clock Reaction
Stock Solutions
Soln.
S2O32-
Conc.
Units
IBrO3HCl
Table of Recorded Reagent Volumes, Temperature, Time of Reaction, and Calculated Rate
Experiment
Run
H2O
Test Tube #1
S2O32-
mL
mL
mL
Test Tube #2
BrO3H+
mL
1
2
3**
4
5
6
7**
8
9
10
11**
12
13
14*
15*
* Measurements made with a drop of 1.0 mM Ammonium Molybdate
** Repeated measurements for calculating k and Ea
A drop of 1% Starch indicator solution is included in each run.
Show your calculation for the "Rate" here using data for Run #1:
mL
Temp.
Celsius
Time
sec.
Page 3 of 36
Reaction Order Determination for IShow your calculation for the concentration of BrO 3- used in Runs 1-4:
Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Run #
Temp
Celsius
Initial Concentrations (M)

S2O32-
BrO3-
Time
Rate
sec
M/sec
X-axis
Y-axis
log(I )
log(Rate)
Run 1
Run 2
Run 3
Run 4
READ THIS BEFORE PROCEEDING:

Recall that since BrO3- and H+ are held constant, the rate law takes on the
following form:
Rate = B[I-]i
where "B" is the pseudo rate constant that includes k, [H+], and [BrO3-].
Therefore, a plot of log(Rate) vs. log([I-]) (y-axis vs x-axis) will yield a straight
line with a slope equal to i, the order of the reaction with respect to I-.
Place your plot relating to the reaction order for I - here, making it large enough to cover this box
(so that it is easy to read).
Refer to the text box above for hints about what to plot.
FOR FULL CREDIT:
- plot the correct data on each axis
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT need to
start at 0)
- appropriately title the plot
- use Excel to add a trendline for the data...be sure to choose the trendline options that "display equation on chart" and "display
R-squared on chart"

R-squared on chart"
Page 4 of 36
What is the order with respect to I- as determined from your data?

Round to the nearest whole number.
If no trendline equation is provided on the plot, no credit will be given for your answer to this question.
Reaction Order Determination for BrO3-
Page 5 of 36
Reaction Order Determination for BrO3Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Run #
Temp
Celsius

S2O32-
BrO3-
Time
Rate
sec
M/sec
X-axis
log(BrO3-)
Y-axis
Run 5
Run 6
Run 7
Run 8
log(Rate)
Place your plot relating to the reaction order for BrO 3- here, making it large enough to cover this
box (so that it is easy to read).
FOR FULL CREDIT:
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT need to
start at 0)
R-squared on chart"
What is the order with respect to BrO3- as determined from your data?
Page 6 of 36
Reaction Order Determination for H+

Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Run #
Temp
Celsius

S2O32-
BrO3-
Time
Rate
sec
M/sec
Run 9
Run 10
Run 11
Run 12
X-axis
Y-axis
log(H )
log(Rate)
Place your plot relating to the reaction order for H+ here, making it large enough to cover this
box (so that it is easy to read).
FOR FULL CREDIT:
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT need
to start at 0)
R-squared on chart"
What is the order with respect to H+ as determined from your data?

Page 7 of 36
Calculation of Rate Constant, k
Page 8 of 36
Calculation of Rate Constant, k

Show your calculation of k using Run 3:
Table of Initial Concentrations, Time of Reaction, Calculated Rate, and Calculated k

Experiment

S2O32-
Run #
BrO3-
Time
Rate
sec
M/sec
Run 3
Run 7
Run 11
Average:
Std Deviation:
H
Units:
i
n
Determination of Activation Energy, Ea
t
:
:Show the calculation of Ea uncatalyzed using the average room temp data and 0C data
U
s
e
t
h
e
r
o
u
n
Table
of Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
d
Activation Energy: Uncatalyzed
e
Experiment
Temp
Time
Rate
d
v
a
l
u
e
s
Run #
Celsius
S2O32-
I-
H+
BrO3-
sec
M/sec
Ave *
Run 13
* Average value from runs # 3, 7, & 11
Ea of the uncatalyzed reaction:
Ea =
kJ/mol
Table of Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
f
Activation Energy: Catalyzed with Ammonium Molybdate
o
Experiment
Temp
r
Run #
t
h
e
r
x
n
Run 14
Celsius
S2O3
2-
BrO3
Time
Rate
sec
M/sec
f
o
r
t
h
e
Page 9 of 36
Run 15
r
x
Part
n
Ea =
Ea of the catalyzed reaction:
kJ/mol
II: Crystal Violet-Hydroxide Reaction
READ THIS BEFORE PROCEEDING WITH THE DATA ANALYSIS FOR PART II OF THIS
o EXPERIMENT:
r For Part II of the lab, you will first evaluate the data for the CV+ standards to obtain a value for molar absorptivity () that you will then
d use to convert Absorbance data to [CV+] (Remember: A=bc). You will then evaluate the concentration data as a function of time
e using the integrated rate law method of determining the orders with respecto to each reactant and the rate contant for the reaction at
r this temperature.
s You will plot all of the data for Run 1. However, for the calibration curve, the data in Runs 2-4, and the determination of the order
with respect to OH-, INSTEAD OF CREATING ADDITIONAL PLOTS, WE WILL USE A SHORTCUT THAT EMPLOYS FUNCTIONS
f WITHIN EXCEL TO DETERMINE THE SLOPE AND Y-INTERCEPT FOR A SET OF DATA. To use these functions, click on the cell
r in which you want the result to appear, G339 for the slope and G340 for the y-intercept, and enter the following:
o =SLOPE(D337:D340,C337:C340)
m
=INTERCEPT(D337:D340,C337:C340)
y
D337:D340 represent the cells that contain data for the y-axis (Absorbance) and C337:C340 represent data for the x-axis. This is a
o short cut to creating an actual plot of the data and generating the trendline equation of y = mx + b.
u
r You will create three plots on page 9, using the data from Run 1, to determine the order of the reaction with respect to CV +. Once
you know the order of the reaction with respect to CV+, you will perform the necessary "slope" functions for the other three runs to
c determine k' for each run. When you get to the section for determining the order of the reaction with respect to OH-, you will also
need to use the "intercept" function mentioned above.
o
n
c
l
u
s
i
o
n
s
a
n
d
n
o
t
t
h
e
l
i
n
e
a
r
r
e
g
r
e
s
s
Concentration of stock solutions

CV+
OH-
Volume of CV+ stock solution needed

to make 25 mL of 1.0 x 10-5 M CV+ is
Calibration Curve Data

Dilution Factor
[CV+] (M)
CV+
mL
max, CV+
nm
Absorbance
10.0
Slope and Y-intercept for

Absorbance vs. [CV+]
slope
y-int
4.0
2.0
1.0
What is the molar absorptivity for the CV+ at this wavelength?

molar absorptivity,
M-1cm-1
Table of Volumes and Final Concentrations During Solution Preparation for Runs 1-4
Run Number
NaOH (mL)
DI water (mL)
CV+ (mL)
mLTotal
[CV+]f, M
[NaOH]f, M
0.5
0.5
5.00E-06
0.0667
i
n
e
a
r
r
e
g
r
e
s
s
i
o
n
v
a
l
u
e
s
w
h
e
n
d
e
t
e
r
m
i
n
i
n
g
k
.
Page 10 of 36
1.5
0.5
5.00E-06
0.0500
1.5
0.5
5.00E-06
0.0333
5.00E-06
0.0167
4
0.5
2
0.5
3
*[CV+]f and [NaOH]f are the final concentrations after all reagents are mixed
and the initial concentration for the start of the reactions
r
e
g
r
Page 11 of 36
e
s
s
i
+
oShow your calculation of the [CV ] at the first timepoint in Run #1:
n
v
a
l
u
e
s
READ THIS BEFORE PROCEEDING
w For evaluating the data for Run 1, enter your time and absorbance values, as recorded in your lab notebook
h during lab, in columns A and B, respectively. In column C, convert the aborbance values to concentration
according to the example you provided at the top of this page. In column D, convert the [CV+] values from
e column C to ln [CV+]. In column E, convert the [CV+] values from column C to 1/[CV+] . Insert the plots used to
n determine the order with respect to [CV+] on the next page, then come back and provide the summary
information as requested.
d
e
t
e
r Run 1
m Time (s)
i
n
i
n
g
Absorbance
[CV+]t
ln[CV+]t
1/[CV+]t
k
.
Which plot on the next page is the most linear?

Based on the plots you created on the next page, what is the order of this reaction with respect to CV+?
RUN #1
What is the value of the slope for the most linear plot?
Page 12 of 36
What is the psuedo-rate constant (k') for this reaction?
Page 13 of 36
Place your plot of [CV+] vs time here, making it large enough to cover this box (so that it is easy
.to read)
FOR FULL CREDIT:
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT
need to start at 0)
- use Excel to add a trendline for the data...be sure to choose the trendline options that "display equation on chart" and
"display R-squared on chart"
Place your plot of ln[CV+] vs time here, making it large enough to cover this box (so that it is
.easy to read)
FOR FULL CREDIT:
need to start at 0)
Place your plot of 1/[CV+] vs time here, making it large enough to cover this box (so that it is
.easy to read)
FOR FULL CREDIT:
need to start at 0)
.

.
Page 14 of 36
Page 15 of 36
Note: in row 462 of columns D and I, provide the correct column title based on what data you are entering.
Run 2
Time (s)
Run 3
Absorbance
[CV+]t
Time (s)
Absorbance
[CV+]t
RUN #2
RUN #3
Page 16 of 36
Note: in row 513 of column D, provide the correct column title based on what data you are entering.
Run 4
Time (s)
Absorbance
[CV+]t
RUN #4
Reaction Order Determination for OHConsult the "Helpful Information" section in the introductory pages for this experiment in the lab manual for help
with this last section of data analysis. As you did in the previous secion for the slope and y-intercept calculations,
you will again use the functions in Excel rather than creating a plot.
Run #
[OH-]
k'
ln[OH-]
ln(k')
1
2
3
4
Show your calculation of the rate constant for the overall reaction.
ln(k') vs. ln([OH-])

slope
y-int
Show your calculation of the rate constant for the overall reaction.
Page 17 of 36
Order of the reaction with respect to [OH-]:

Rate constant for the overall reaction, k:
Units for k:
Results and Discussion

Part I
1. Based on your data and the average value for the rate constant at room temperature for the
uncatalyzed, write the complete rate law, including the value and units for the rate constant. (1 pt)
2. The literature values for the reaction orders are 1 for BrO 3- and I- and 2 for H+. Calculate the % error
for the experimental value for the order with respect to [I -].
(1 pt)
3. Discuss your most likely sources of error in Part I.
(1 pt)
4. How do the activation energies for the catalyzed and uncatalyzed reaction compare to each other? Is
this in line with what is expected? Explain.
(2 pts)
Part II
(1 pt)
1. Based on your data, write the complete rate law, including value and units for the rate constant.
2. The literature values of the orders with respect to CV+ are and OH - are 1 and 1 respectively. Calculate
the % error for the experimental value for the order with respect to [OH -].
(1pt)
3. Discuss your largest source of error in Part II.
(1 pt)
Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, thrown in
the garbage, collected in a container for disposal by the UW Environmental Health & Safety department, or released into the
environment. Based on the written lab procedure and your actions during the lab, list the identity and approximate amount
(mass or volume) of waste that you generated while performing this experiment.
Laboratory Waste Evaluation (1 pt)
Page 18 of 36
Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, thrown in
the garbage, collected in a container for disposal by the UW Environmental Health & Safety department, or released into the
environment. Based on the written lab procedure and your actions during the lab, list the identity and approximate amount
(mass or volume) of waste that you generated while performing this experiment.
d any part of this lab

ur own independent
t score.
ebook is 65 pts)
rovide a brief
actant?) and how the
rovide a brief
ctant?). (3 pts)
Page 19 of 36
Page 20 of 36
(3 pts)
Rate
M/s
(2 pts)
Page 21 of 36
(1 pts)
alculated Rate
over this box
s do NOT need to
rt" and "display
(5 pts)
rt" and "display
Page 22 of 36
(1 pt)
Page 23 of 36
alculated Rate
o cover this
do NOT need to
" and "display
(1 pt)
Page 24 of 36
alculated Rate
(1 pt)
Page 25 of 36
Page 26 of 36
(2 pts)
(1 pt)
(3 pts)
Page 27 of 36
(2 pts)
PART II OF THIS
rptivity () that you will then

ta as a function of time
e contant for the reaction at
ermination of the order

EMPLOYS FUNCTIONS
functions, click on the cell
ollowing:
ata for the x-axis. This is a
th respect to CV +. Once
r the other three runs to
ect to OH-, you will also
(3 pts)
(1 pt)
(1 pt)
on for Runs 1-4
Page 28 of 36
Page 29 of 36
(2 pts)
(1 pt)
pect to CV+?
(1 pt)
(1 pt)
Page 30 of 36
(1 pt)
Page 31 of 36
(5 pts)
Page 32 of 36
Page 33 of 36
ou are entering.
(1 pt)
st linear plot?
this reaction?
(1 pt)
Page 34 of 36
st linear plot?
this reaction?
(1 pt)
ual for help

calculations,
(2 pts)
Page 35 of 36
(2 pts)
ure for the

onstant. (1 pt)
culate the % error

(1 pt)
(1 pt)
re to each other? Is
(2 pts)
rate constant.
pectively. Calculate
e sewer drain, thrown in

ent, or released into the
d approximate amount
e sewer drain, thrown in

ent, or released into the
d approximate amount
Page 36 of 36

Chem162 Kinetics Report

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chem162 Kinetics Report

Uploaded by

Copyright:

Available Formats

Page 1 of 36

Chem 162 Experiment #3: Chemical Kinetics

Purpose and Method

Part II: Crystal Violet-Hydroxide Reaction

Data, Calculations and Graphs

Initial Concentrations (M)

READ THIS BEFORE PROCEEDING:

- appropriately title the plot

What is the order with respect to I- as determined from your data?

Reaction Order Determination for BrO3-

Initial Concentrations (M)

Reaction Order Determination for H+

Initial Concentrations (M)

What is the order with respect to H+ as determined from your data?

Calculation of Rate Constant, k

Calculation of Rate Constant, k

Table of Initial Concentrations, Time of Reaction, Calculated Rate, and Calculated k

Initial Concentrations (M)

Table of Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate

Ea of the catalyzed reaction:

II: Crystal Violet-Hydroxide Reaction

Concentration of stock solutions

Volume of CV+ stock solution needed

Calibration Curve Data

Slope and Y-intercept for

What is the molar absorptivity for the CV+ at this wavelength?

READ THIS BEFORE PROCEEDING

Which plot on the next page is the most linear?

What is the psuedo-rate constant (k') for this reaction?

- appropriately title the plot

What is the psuedo-rate constant (k') for this reaction?

What is the psuedo-rate constant (k') for this reaction?

What is the psuedo-rate constant (k') for this reaction?

ln(k') vs. ln([OH-])

Order of the reaction with respect to [OH-]:

Results and Discussion

3. Discuss your most likely sources of error in Part I.

3. Discuss your largest source of error in Part II.

Laboratory Waste Evaluation (1 pt)

Laboratory Waste Evaluation (1 pt)

d any part of this lab

over this box

rt" and "display

rt" and "display

" and "display

rptivity () that you will then

ermination of the order

ata for the x-axis. This is a

on for Runs 1-4

ual for help

ure for the

culate the % error

e sewer drain, thrown in

e sewer drain, thrown in

You might also like