Professional Documents
Culture Documents
W. Nelson
Carbon Division
New York, N. Y.
INTRODUCTION
s o m e foam occurs.
This foam s u b s i d e s d u r i n g t h e
I t i s i m p o r t a n t i n f i l l i n g t h e coke
steaming and c o o l i n g c y c l e .
drum t o avoid any c a r r y over o f foam o r p i t c h y m a t e r i a l i n t o t h e
vapor l i n e s . Foam d e p r e s s a n t s a r e used t o minimize t h e amount o f
foam (1). Level i n d i c a t o r s a r e used t o e s t a b l i s h t h e p o s i t i o n o f
t h e l i q u i d o r foam i n t h e drum (2). These are o p e r a t e d by t r a n s m i t t i n g a beam from a r a d i o a c t i v e s o u r c e t o an instrument mounted
near t h e t o p o f t h e drum. When t h e l i q u i d r e a c h e s a predetermined
l e v e l t h e feed t o t h e drum i s switched t o an empty drum. A t t h i s
t i m e t h e f u l l drum i s steamed t o remove l i g h t hydrocarbons and
f i n a l l y cooled by i n t r o d u c i n g water a t t h e bottom o f t h e drum.
F a c t o r s a f f e c t i n q S i z i n q o f Coke
The coke i s removed from t h e drum b y means o f high p r e s s u r e
water j e t s which o p e r a t e on t h e p r i n c i p l e used i n h y d r a u l i c mining
o f c o a l ( 3 ) . The p r o c e d u r e used i n c u t t i n g t h e coke from t h e drum
i s extremely i m p o r t a n t . I f it i s n o t c a r r i e d o u t p r o p e r l y t h e
p h y s i c a l s t r u c t u r e o f t h e coke w i l l be d e s t r o y e d and t h e u l t i m a t e
consumer would n o t have enough c o a r s e p a r t i c l e s t o b a l a n c e o u t t h e i r
carbon aggregate f o r m u l a t i o n . The recommended procedure f o r c u t t i n g
t h e coke is i l l u s t r a t e d i n F i g u r e 2 .
T h i s series o f diagrams shows
t h e s t e p s which s h o u l d b e taken i n o r d e r t o g e t t h e maximum amount
of lump coke needed for f u r t h e r p r o c e s s i n g .
The f i r s t s t e p i s t o b o r e a p i l o t h o l e . During t h i s o p e r a t i o n
t h e f i n e c u t t i n g s a r e h e l d i n t h e upper s e c t i o n of t h e drum u n t i l t h e
h o l e i s completely through t h e bottom. A t t h i s t i m e , a l l o f t h e
c e n t e r c u t t i n g s f a l l o u t o f t h e drum t o g e t h e r w i t h t h e water used i n
cutting.
The d r i l l s t e m i s r a i s e d t o t h e t o p and t h e b i t i s changed t o
a c u t t i n g head which has n o z z l e s d i r e c t e d i n a h o r i z o n t a l manner.
The p i l o t h o l e is e n l a r g e d so t h a t lumps o f d i s l o d g e d coke can f a l l
f r e e l y through t h e opening.
T h i s a v o i d s t h e danger o f a coke b u i l d
up around t h e d r i l l s t e m which would p r e v e n t t h e r o t a t i o n o f t h e
c u t t ing head.
Once t h e p i l o t h o l e i s e n l a r g e d t h e s t e m i s r a i s e d t o t h e
l e v e l o f t h e coke i n t h e drum. The o p e r a t o r can t e l l by t h e sound
of t h e water h i t t i n g t h e metal w a l l s when t h e t o p i s reached. A t
t h i s t i m e t h e stem i s lowered 3 - 4 f e e t b e l o w the. t o p . I t i s h e l d
i n t h i s p o s i t i o n f o r s e v e r a l minutes u n t i l the coke i s undercut.
Then t h e stem is r a i s e d and lowered r a p i d l y w i t h i n t h i s s e c t i o n u n t i l
t h e coke i s a l l c u t from t h i s l a y e r .
T h i s a c t i o n causes t h e coke to
c o l l a p s e from t h e d r u m w a l l s r e s u l t i n g i n l a r g e p i e c e s which fal.1
through t h e p i l o t h o l e . This o p e r a t i o n i s r e p e a t e d u n t i l t h e drum
is completely empty.
I n g e n e r a l , t h e decoking o p e r a t i o n r e q u i r e s
about 3 t o 4 h o u r s depending on t h e hardness o f t h e coke. The h a r d e r
I
I
123
t h e coke t h e more t i m e r e q u i r e d .
B.
C.
124
c e r t a i n wind c o n d i t i o n s .
Magnetic s e p a r a t o r s a r e used a t t h e c a l c i n i n g p l a n t s .
These w i l l remove s c r a p i r o n from g r e e n coke, b u t w i l l n o t remove
i r o n r u s t , s i n c e t h e l a t t e r i s non-magnetic.
During c a l c i n i n g any
i r o n o x i d e ( r u s t ) w i l l be reduced t o i r o n which can be removed from
t h e c a l c i n e d petroleum coke w i t h magnets.
Chemical Composition o f Petroleum Coke
Green petroleum coke from t h e delayed coking process i s
e s s e n t i a l l y a hydrocarbon.
The chemical composition a s o b t a i n e d
by an u l t i m a t e a n a l y s i s i s given i n Table I. Before it can b e used
a s a carbon a g g r e g a t e i t i s n e c e s s a r y t o c o n v e r t t h e green coke i n t o
e l e m e n t a l carbon by a petrochemical p r o c e s s . This i s c a r r i e d o u t
0
by a p y r o l y t i c t r e a t m e n t a t temperatures around 2300 F.
In t h i s
o p e r a t i o n t h e carbon i s n o t developed u n t i l hydrogen is chemically
I n t h e t r a d e t h i s process is reremoved b y thermal decomposition.
f e r r e d to a s c a l c i n a t i o n , b u t it is e s s e n t i a l l y a dehydrogenation
r e a c t i o n which c o n v e r t s a hydrocarbon i n t o e l e m e n t a l carbon as i n d i c a t e d i n Table I.
A number o f changes i n basic p r o p e r t i e s and s t r u c t u r e a r e
b r o u g h t about by t h e removal of chemically bound hydrogen from t h e
hydrocarbons i n o r d e r t o produce e l e m e n t a l carbon. Some o f t h e s e
are as follows:
A.
After
B.
C.
125
w i l l be c a r r i e d over i n t o t h e coke,.
SUMMARY
I n summarizing t h e information j u s t p r e s e n t e d , we f i n d
t h a t a r e a s o n a b l e amount o f c a r e should be e x e r c i s e d a t each s t e p
o f handling petroleum coke.
I t i s recongnized t h a t some o f t h e
p h y s i c a l p r o p e r t i e s ( s i z i n g ) o f a c a l c i n e d coke can b e destroyed
i f t h e c u t t i n g o p e r a t i o n i s n o t c a r r i e d o u t properly. . A l s o s o u r c e s
o f contamination should be avoided i n o r d e r t o keep the i r o n and
s i l i c o n c o n t e n t w i t h i n r e q u i r e d l i m i t s . Where a carbon a g g r e g a t e
w i t h low s i l i c o n o r low i r o n is r e q u i r e d a s e l e c t i o n c a n be made
from a given shipment i f t h e m a t e r i a l is d e l i v e r e d i n r a i l c a r s .
References
1.
T r a m e l l , W. D.,
June 5 , 1961.
G l a s e r , D.,
2.
Wright, P. G.,
3.
Maas, R . , Lauterbach, R.
F e b . 1947.
O i l and G a s J o u r n a l p.
O i l and G a s Journal p. 93
E.,
94. Aug.
65,
11, 1958.
Petroleum Engineer p. 1 1 0
124,
127
VAPOR
OUT
1 0 PSIG.
VAPOR
IOFTI
'
FROTH
Figure 1.
128
>
3
K
CARBON
HYDROGEN
OXYGEN
NITROGEN
SULFUR
ASH
CARBON-HYDROGEN RATIO
Green
Petroleum Coke
(Polymerized Residual)
Calcined
Petroleum Coke
(Pure Carbon)
91-80
3.82
1.30
0.95
1.29
0.35
24
98.40
0.14
0.02
0.22
1.20
0.35
910
TABLE II
ANALYSIS OF CALCINED COKE SHIPMENTS
CARS LOADED FROM PRODUCT SILO
. ORDER OF LOADING
CAR NO.
1
2
ASH
%
IRON
%
SILICON
%
.24
.21
.019
-021
.065
.073
.043
-030
.020
-035
-065
.041
.010
.012
.028
.022
-025
.010
.015
.025
.015
.021
.40
3
4
5
6
7
8
9
10
.42
.34
.24
-23
.33
.41
.26
TABLE 111
EFFECT OF SCREENING
ON SILICON CONTENT OF
CALCINED PETROLEUM COKE
SIZE
% SILICON
Run of Kiln
.021
.008
.022