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School of Chemical Engineering, Chemistry, Biological Engineering and Materials Science Engineering
Heat of Combustion
Salen, Vladimir A. , Salvacion, Sarah Katrina V. , Santos, John Harvey
Abstract
Calorimetry is defined as the process to measure the quantity of heat that the process of combustion obtained. The
objectives of the experiment are for the students to be familiar with bomb calorimeter and its water handling system.
It aims to determine and compare the heat of combustion of aromatic and non-aromatic compounds and to be able to
use the calorimeter to study the compounds. Through the use of a bomb calorimeter, the three samples namely;
benzoic acid, naphthalene and sucrose were tested for their specific heat of combustion. The bomb calorimeter gave
the gross heat. These theoretical values were used to be compared to its literature value. Upon comparison, the
percent difference for each of the samples was 0.71%, 0.57%, 0.0064% respectively for benzoic acid, naphthalene
and sucrose. Through the data gathered, compounds with higher aromaticity have greater heat of combustion due to
their stable aromatic ring and strong bonds in comparison to non-aromatic compound.
Keywords: Calorimetry, heat of combustion, non-aromatic compound, aromatic compound, combustion
Introduction
Energy is released in the form of heat in the
combustion of compound or substance in
combustion reaction under standard condition. It
is also known as the heat of combustion. The
amount of heat released during combustion
process is identified through the use of what we
called bomb calorimeter [1]. Combustion is the
process
wherein
oxidizable
substance
or
compound react with oxygen.
Calorimetry is an experimental technique used to
determine the change in energy in both physical
and
chemical
process.
This
experimental
technique focused on the energy released or
absorbed in the form of heat due to the change in
temperature [2].
Bomb calorimeter is constant volume type of
calorimeter used to determine the amount of
energy transfer in the form of heat between the
system and the surroundings. This calorimeter
produces carbon dioxide and water in an excess
oxygen as the combustion reaction goes to
completion. A sealed metal container in a bucket
containing water is where the reaction occur .
The temperature of the water in the bucket
increased as the energy in the form of heat is
released due to reaction of subtances in the
sealed metal container passing through the walls
of sealed container to the water in the bucket
Experiment 6 | Group 6 | Dr. Allan Soriano | 24 October 2014
computed by
H = U + (pV)
equation 1
(pV) = nRT
equation 2
equation 3
Ccal = qv,known /T
equation 4
Figure 3: Napthalene
[9]
http://hyperphysics.phyastr.gsu.edu/hbase/therm
o/adiab.html
[7] Atkins, P., De Paula, J. (2006). Atkins
Physical Chemistry 8th edition. Oxford University
Press, New York.
References
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