Professional Documents
Culture Documents
ULUSLARARASI
EVRE VE AHLAK
SEMPOZYUMU
BLDRLER KTABI
PROCEEDINGS
2. Cilt
Volume 2
EDTRLER
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
EDITORS
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
EDTR YARIMCILARI
Do. Dr. Tanju TEKER
rt. Gr. Faruk KRKER
rt. Gr. Hseyin KUTLU
Co-EDITOR
Assoc. Prof. Dr. Tanju TEKER
Instructor Faruk KRKER
Instructor Hseyin KUTLU
ORGANZASYON
ADIYAMAN NVERSTES
TRKYE
ORGANIZATION
ADIYAMAN UNIVERSITY
TURKEY
ISBN: 978-605-60221-8-0
EDTRLER
Prof. Dr. Ahmet PINARBAI
Prof. Dr. Murat PALA
EDTR YARIMCILARI
Do. Dr. Tanju TEKER
rt. Gr. Faruk KRKER
rt. Gr. Hseyin KUTLU
YAYINCI
Adyaman niversitesi Yaynlar
Telefon: 0 416 2233800
www.adiyaman.edu.tr
BASKI
Mesut Matbaa
Yeni Pnar Mah. 305. Sokak No: 14
ADIYAMAN
Tel: 0 416 213 30 37
KURULLAR/ COMMITTEES
ONUR KURULU/ HONORY COMMITTEE
Mahmut DEMRTA (Adyaman Governer)
Prof. Dr. M. Talha GNLL (Adiyaman University, Rector)
Assoc. Prof. Dr. Eyp DEBK (President of Cevre Foundation)
Advt. Muzaffer ZCAN (President of CEKUD)
DZENLEME KURULU/ ORGANIZING COMMITTEE
Prof. Dr. Ahmet PINARBAI (Adiyaman University, Chair)
Assoc. Prof. Dr. Naci CAGLAR (Sakarya University, Co Chair)
Prof. Dr. Bedri GENCER (Yildiz Technical University)
Prof. Dr. Hr Mahmut YUCER (Karabuk University)
Assoc. Prof. Dr. Eyp DEBK (President of Cevre Foundation)
Assoc. Prof. Dr. Murat PALA (Adiyaman University)
Prof. Dr. Mehmet SARIBIYIK (Sakarya University)
Assist. Prof. Dr. Ozer UYGUN (Sakarya University)
Assist. Prof. Dr. Hakan ASLAN (Sakarya University)
Dr. Huseyin BUDAK (CEKUD)
BLM KURULU/ SCIENTIFIC COMMITTEE
Dr. Abdullah SOYSAL (Kahramanmaras Sutcu Imam University, Turkey)
Dr. Ahmet ALP (Sakarya University, Turkey)
Dr. Ahmet DEMR (Yildiz Technical University, Turkey)
Dr. Ahmet Zafer TEL (Adiyaman University, Turkey)
Dr. Alfina SIBGATULLINA (Russian Academy of Sciences, Russia)
Dr. Ali ATA (Gebze Institute Of Technology, Turkey)
Dr. Ali Caglar CAKMAK (Karabuk University, Turkey)
Dr. Almaz Ulvi BINNATOVA (Azerbaijan National Academy of Sciences)
Dr. Aysel Alkan UCKUN (Adiyaman University, Turkey)
Dr. Bakhtiyor KARIMOV (Institute Of Plant And Animal World Genetic Resources,
Uzbekistan)
Dr. Bekir KAYACAN (Duzce University, Turkey)
Dr. Benjamin HALE (University of Colorado, USA)
Dr. Beytullah EREN (Sakarya University, Turkey)
Dr. Bilal DELISER (Gumushane University, Turkey)
Dr. Bilal KUSPINAR (Necmettin Erbakan University, Turkey)
Dr. Bilal SAMBUR (Yildirim Beyazt University, Turkey)
Dr. C. Zehra KOROGLU (Gumushane University, Turkey)
Dr. Cihan OKUYUCU (Suleymansah University, Turkey)
Dr. Cumali KINACI (Istanbul Technical University, Turkey)
Abstract
One of the most important issues in waste disposal is to prevent the transport of pollutants. Especially
in environments where solvents such as water, disperse of pollutants from waste or material into the
liquid medium the environment are the unwanted event in terms of the protection of the environment
and human health.
Various extraction tests have been developed for the detection of pollutants passage from raw or
treated wastes/materials into liquid environment. These tests are used to determine pass degree of
pollutants into liquid environment under model situations of natural environment.
In this paper, the present extraction tests examined and these tests compared with each other in terms
of the model conditions of environment.
Key words: Waste, solidification/stabilization, convection, extraction, TCLP
Test
alkalamal ztleme Testleri
Toxicity Characteristic Leaching
Procedure (TCLP) (tur: Zehirlilik
zellikleri Szma lemi)
Extraction Procedure Toxicity (EP
Tox) Test (tur: Zehirlilik ztleme
lemi)
TCLP Cage Modification (tur:
Deitirilmi TCLP Kafes)
California Waste Extraction Test (Cal
WET) (tur: Kaliforniya Atk
ztleme Deneyi)
Synthetic Precipitation Leach Test
(SPLP) (tur: Sentetik Ya Szdrma
Deneyi)
Agitated Powder Leach Test (tur:
alkalamal Toz Szdrma Deneyi)
Malzeme
Uygulama(a) Ama
U S L
Yntem
USEPA SW-846
1311(b)
USEPA SW-846
1310B(b)
USFR(c)
California Code()
USEPA SW-846
1312(b)
MCC-3S(d)
1082
Test
Yntem
WTC-ANC(g)
Malzeme
Uygulama(a) Ama
U S L
X X X Bir malzemenin asidi ntralize
edebilme yeteneinin llmesi iin
ASTM C1220(f)
MCC-1P(d)
MCC-2P(d)
USEPA SW-924()
WTC-ELT(g)
ASTM D5284(f)
Bishop(h)
WTC-SCET(g)
USEPA SW-846
X
1320(b)
EN 12457-(1-4) ()
X
TS EN 12457-(1-4) (e)
NEN 7341(i)
ANSI/ANS/16.1(j)
NEN 7345(i)
ISO 6961(k)
WTC-DLT(g)
ASTM D4874(f)
NEN 7374(i)
1083
Test
Yntem
MCC-5S(d)
Malzeme
Uygulama(a) Ama
U S L
X
Kaynak
Yaymc
ANSI/ANS/16.1-2003:R2008, Measurement of the Leachability of American Nuclear
Solidified Low-Level Radioactive Wastes by a Short-Term Test Society (ANS)
Procedure http://www.ans.org/store/i_240249
http://www.ans.org/
ASTM C1220
ASTM C1220-10, Standard Test Method for Static Leaching of ASTM International.
Monolithic Waste Forms for Disposal of Radioactive Waste
http://www.astm.org/
http://www.astm.org/Standards/C1220.htm
ASTM D3987
ASTM D3987-12, Standard Practice for Shake Extraction of Solid
Waste with Water http://www.astm.org/Standards/D3987.htm
ASTM D4874
ASTM D4874-95(2014), Standard Test Method for Leaching
Solid Material in a Column Apparatus
http://www.astm.org/Standards/D4874.htm
ASTM D5284
ASTM D5284-09, Standard Test Method for Sequential Batch
Extraction of Waste with Acidic Extraction Fluid
http://www.astm.org/Standards/D5284.htm
Bishop
Bishop, P.L., Prediction of Heavy Metal Leaching Rates from
Stabilization/Solidification Hazardous Wastes, Toxic and
Hazardous Wastes: Proceedings of the Eighteenth Mid-Atlantic
Industrial Waste Conference, Technomic Publishing, USA, 1986.
California Code
California Code Title 22, Article 11, pp. 1800.75-1800.82.
EN 12457-(1-4)
EN 12457-(1-4), Characterisation of waste - Leaching European Committee for
Compliance test for leaching of granular waste materials and
Standardization (CEN)
sludges
http://standards.cen.eu/
ISO 6961
ISO 6961:1982, Long-term leach testing of solidified radioactive International
waste forms
Organization for
http://www.iso.org/iso/home/store/catalogue_tc/catalogue_detail.h Standardization
tm?csnumber=13511
http://www.iso.org/
MCC-1P
MCC, Materials Characterization Center, Pacific Northwest
Materials
MCC-2P
Laboratory (PNL), Nuclear Waste Materials Handbook: Test
Characterization Center
MCC-3S
Methods, USDOE, DOE/TIC-11400, 1981.
(MCC)
MCC-5S
http://www.worldcat.org/oclc/9285773
NEN 7341
NEN 7341:1995, http://www.nen.nl/NEN-Shop/Norm/NENNetherlands
73411995-nl.htm
Standardization Institute
NEN 7374
NEN 7374:2004, http://www.nen.nl/NEN-Shop/Norm/NEN(NEN)
73742004-nl.htm
http://www.nen.nl/
NEN 7345
NEN 7345:1995, http://www.nen.nl/NEN-Shop/Norm/NEN73451995-nl.htm
USEPA SW-846 1310B USEPA SW-846 On Line, Test Methods for Evaluating Solid
United States
USEPA SW-846 1311 Waste, Physical/Chemical Methods.
Environmental
USEPA SW-846 1312 http://www.epa.gov/epawaste/hazard/testmethods/sw846/online/ Protection Agency
USEPA SW-846 1320
(USEPA)
1084
WTC-ANC
WTC-DLT
WTC-ELT
WTC-SCET
Kaynak
USEPA, SW-924, Solid Waste Leaching Procedure, 1984.
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=2000OL4A.txt
USFR, 53 FR 18792, May 24, 1988.
http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=10003P0J.txt
TS 9394:1991, Atklar-Kat atklarn su ile alkalanarak
ekstraksiyon metodu
TS EN 12457-(1-4), Atklarn nitelendirilmesi - Katdan ztleme
analizi - Granl kat atklarn ve amurlarn kat ztlemesi iin
uygunluk deneyi
WTC, Wastewater Technology Centre, Environment Canada,
Investigation of Test Methods for Solidified Waste Evaluation A Cooperative Program, Report: EPS 3/HA/8, 1991.
http://www.worldcat.org/oclc/23220612
Yaymc
Trk Standartlar
Enstits (TSE)
https://intweb.tse.org.tr/
Standard/Standard/Stand
ardAra.aspx
Wastewater Technology
Centre, Environment
Canada (WTC)
SPLP
MCC-3S
Sv:Kat
Oran
Asetat tamponu(a)
20:1
0,04 M asetik asit (pH 5,0) 16:1-20:1
Asetat tamponu(a)
20:1
0,2 M sodyum sitrat (pH
10:1
5,0) veya Cr6+l su
(c)
20:1
()
10:1
ASTM D3987
Deiyonize su
20:1
ANC Test
3:1
()
MWEP
Deiyonize/distile su
ELT
SET
SCET
Deiyonize su
0,04 M asetik asit
Asiditesi artan 5 szdrma
suyu
MEP
Test Yntemi
TCLP
EP Tox
TCLP cage
Cal WET
MCC-1P,
MCC-2P
Szma Ortam
Parack Boyutu
< 9,5 mm
< 9,5 mm
(b)
< 2,0 mm
ztleme
Says
1
1
1
1
< 9,5 mm
Yars <0,044
mm, yars 0,0740,149 mm aras
Alnd ekliyle
parack veya
btn
< 150 m
1
1
(d)
10:1 (her
ztleme
iin)
4:1
50:1
16:1den
40:1e
kadar
eitli
20:1
ztleme Sresi
182 saat
24 saat
18 saat
48 saat
18 saat
Her bir numune iin 28,
56, 91, 182, 273 ve 364
gn
18 saat
Yekpare
< 150 m
< 9,5 mm
< 45 m
< 150 m
1
15
5
< 9,5 mm
9 (veya
ztleme bana 24 saat
daha fazla)
1085
7 gn
ztleme bana 24 saat
2den 24 saate kadar
eitli
Szma Ortam
Grld zere uygulamada birok farkl ztleme testi bulunmaktadr. Temel amalar ayn
olsa da uygulama artlar farkl olduu iin bu testlerden farkl sonular elde edilmesi tabiidir.
nemli olan mukayese ve muhakeme asndan ayn olmasa bile benzer nitelikteki ztleme
testlerinin kullanlmasdr. Bu ztleme testlerinin seiminde kanuni zorunluluun bulunmasnn
yannda uygulama kolayl, ksa srede sonu elde edilmesi ve ekonomiklik tercih sebebidir.
ztleme testleri ierisinde en ok kullanlanlardan biri Toxicity Characteristic Leaching
Procedure (TCLP)dir.
2.1. Toxicity Characteristic Leaching Procedure (TCLP)
USEPA SW-846 1311 Toxicity Characteristics Leaching Procedure (TCLP) (tur: Zehirlilik
zellikleri Szma lemi), United States Environmental Protection Agency (tur: Amerika Birleik
Devletleri evre Koruma Ajans) tarafndan yaymlanm olan SW-846: Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods deney yntemleri ierisinde yer alan bir
yntem olup ABDde tehlikeli atk ve katlatrlm malzeme zelliklerinin belirlenmesi iin
uygulanmas zorunlu olan deney yntemlerinden biridir.
Deney, yntem uyarnca malzemenin 9,5 mmden daha kk hale getirilmesinin ardndan 20:1
oranndaki sv asidik ortamda 18 saat alkalanmas sonucu zeltide kirletici tayini yaplmas
eklinde uygulanr [8]. Bylece atk malzemenin uzun vadede tabii artlar altnda gsterecei
davran, 18 saatlik bir srede asidik ortamda hzlandrlm olarak gerekletirilmekte ve uzun
sreler sonunda elde edilebilecek sonular nceden tahmin edilebilmektedir.
1086
[2]
[3]
[4]
[5]
[6]
[7]
[8]
1087