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Ministry of Defence

Defence Standard 02-872 Part 2


Issue 1 Publication Date 02 December 2002

Procedures for First Level Nickel


Aluminium Bronze Castings
Part 2
Validation

Category 1

AMENDMENTS ISSUED SINCE PUBLICATION


AMD NO

DATE OF
ISSUE

TEXT AFFECTED

SIGNATURE &
DATE

Revision Note
This Issue of this Standard has been prepared to incorporate changes to text and presentation.
The technical content has been updated in line with current practice.
Historical Record
DPT 1311

DEFENCE STANDARD 02-872


PROCEDURES FOR FIRST LEVELNICKEL ALUMINIUM BRONZE CASTINGS
PART 2
ISSUE 1
VALIDATION

This Defence Standard


is authorised for use in MOD contracts
by the Defence Procurement Agency
and the Warship Support Agency

Published By:
Defence Procurement Agency
An Executive Agency of the Ministry of Defence
UK Defence Standardization
Kentigern House
65 Brown St
Glasgow G2 8EX
1

DEF STAN 02-872 Pt 2 / Issue 1

SCOPE
1.

This specification is to be used for the validation of all Submarine First Level castings made
of Nickel Aluminium Bronze manufactured to Def Stan 02-747 Part 1, 2 or 4. It is to be used
to establish a baseline of data for any weld repairs, wall thickness measurements and the
integrity of the casting at manufacture.

2.

Part 1 of this Defence Standard covers the policy for the recording and updating of Nickel
Aluminium Bronze castings fitted in submarines to meet the First Level Quality Assurance
requirements in accordance with SSP 25.

3.

Part 3 of this Defence Standard is to be used for the revalidation of Submarine First Level
castings made of Nickel Aluminium Bronze manufactured to DGS 8520, DGS 348 or Def
Stan 02-747 Part 1, 2 or 4 which have had service use involving contact with sea water.

4.

Part 4 of this Defence Standard is to be used for in-service inspections carried out outside of
the Long Overhaul Period.

FOREWORD
Sponsorship
1.

This Defence Standard (Def Stan) is sponsored by the Defence Procurement Agency, Ministry
of Defence (MoD).

2.

The complete Def Stan 02-872 comprises of:


Procedures for First Level Nickel Aluminium Bronze castings.
Part 1:

Policy

Part 2:

Validation

Part 3:

Revalidation

Part 4:

Inspections Outside of Long Overhaul Period

3.

If it is found to be unsuitable for any particular requirement the MOD is to be informed in


writing of the circumstances.

4.

Any user of this Defence Standard either within MOD or in industry may propose an
amendment to it. Proposals for amendments that are not directly applicable to a particular
contract are to be made to the Sponsor of the Defence Standard and those directly applicable
to a particular contract are to be dealt with using existing procedures or as specified in the
contract.

5.

No alteration is to be made to this Defence Standard except by the issue of an authorized


amendment.

6.

Unless otherwise stated, reference in this Defence Standard to approval, approved, authorized
or similar terms, means the Ministry of Defence in writing.

DEF STAN 02-872 Pt 2 / Issue 1


7.

Any significant amendments that may be made to this Defence Standard at a later date will be
indicated by a vertical side line. Deletions will be indicated by 000 appearing at the end of the
line interval.

8.

This Defence Standard supersedes DPT 1311.


Conditions of Release
General

9.

This Defence Standard has been prepared for the use of the Crown and its contractors in the
execution of contracts for the Crown. The Crown hereby excludes all liability (other than
liability for death or personal injury) whatsoever and howsoever arising (including but without
limitation, negligence on the part of the Crown, its servants or agents) for any loss or damage
however caused where the Defence Standard is used for any other purpose.

10.

This document is Crown Copyright and the information herein may be subject to Crown or
third party rights. It is not to be released, reproduced or published without written permission
of the MOD.

11.

The Crown reserves the right to amend or modify the contents of this Defence Standard
without consulting or informing any holder.
MoD Tender or Contract Process

12.

This Defence Standard is the property of the Crown. Unless otherwise authorized in writing
by the MOD, it must be returned on completion of the contract or submission of the tender in
connection with which it is issued.

13.

When this Defence Standard is used in connection with a MOD tender or contract, the user is
to ensure that he is in possession of the appropriate version of each document, including
related documents, relevant to each particular tender or contract. Enquiries in this connection
may be made of the Authority named in the tender or contract.

14.

When Defence Standards are incorporated into contracts, users are responsible for their
correct application and for complying with contracts and any other statutory requirements.
Compliance with a Defence Standard does not of itself confer immunity from legal
obligations.
Categories of Naval Defence Standard

15.

The Category of the Naval Defence Standard has been determined using the following criteria:
a)

Category 1. If not applied may have a Critical affect on the following:


Safety of the Vessel, its complement or third parties
Operational performance of the vessel, its systems or equipment.

b)

Category 2. If not applied may have a Significant affect on the following;


Safety of the Vessel, its complement or third parties
Operational performance of the vessel, its systems or equipment.
Through life costs and support.

c)

Category 3. If not applied may have a Minor affect on the following.


MOD best practice and fleet commonality.
Corporate experience and knowledge.
Current support practice.
3

DEF STAN 02-872 Pt 2 / Issue 1

Related Documents
16.

In the tender and procurement processes the related documents in each Section and Annex A
can be obtained as follows:
a)

British Standards

British Standards Institution,


389 Chiswick High Road, London, W4 4AL

b)

Defence Standards

Defence Procurement Agency


An Executive Agency of the MoD
UK Defence Standardization,
Kentigern House, 65 Brown Street,
Glasgow, G2 8EX

c)

Other documents

Tender of Contract Sponsor to advise.

17.

All applications to Ministry Establishments for related documents are to quote the relevant
MOD Invitation to Tender or Contract Number and date, together with the sponsoring
Directorate and the Tender or Contract Sponsor.

18.

Prime Contractors are responsible for supplying their subcontractors with relevant
documentation, including specifications, standards and drawings.
Health and Safety
Warning

19.

This specification calls for the use of processes, substances and procedures that may be
injurious to health if adequate precautions are not taken. It refers only to technical suitability
and in no way absolves either the supplier or any user from statutory obligations relating to
health and safety at any stage of manufacture or use. Where attention is drawn to hazards,
those quoted may not necessarily be exhaustive.

20.

This Defence Standard has been written and is to be used taking into account the policy
stipulated in JSP430: MOD Ship Safety Manual System Handbook.
Use of ARDROX 160 and Silver Nitrate solution

21.

Before using this Defence Standard in conjunction with Ardrox and the silver nitrate solution,
users should make themselves familiar with the precautionary measures set out in this Section.

22.

Care is to be taken to ensure that the silver nitrate etching solution does not come into contact
with the skin or eyes, e.g. a face mask and rubber gloves must be worn.

23.

Protective clothing should be worn and other measures taken as necessary in handling the
materials referred to in this Defence Standard.

24.

Ardrox 160 is a proprietary product and the manufacturers health and safety instructions must
be followed.
Additional Information
(There is no relevant information)

DEF STAN 02-872 Pt 2 / Issue 1


CONTENTS
Page No
TITLE PAGE

SCOPE

FOREWORD

Sponsorship

Conditions of Release

Related Documents

Health and Safety

CONTENTS

SECTION

1.

GENERAL REQUIREMENTS

SECTION

2.
2.1
2.2

CLEANING OF CASTINGS
Cleaning and Etching
Visual Inspection

7
7
7

SECTION

3.
3.1
3.2
3.3
3.4

VALIDATION OF CASTINGS
General
Weld Repairs
Thickness Examination
Recording of Examination Results

8
8
8
8
8

SECTION

4.
4.1
4.2
4.3
4.4
4.5

ACCEPTANCE CRITERIA
Weld Repairs
Wall Thickness
Quality Assurance Documentation
Stamping of castings
Records

9
9
9
9
9
10

ANNEX A.

RELATED DOCUMENTS

11

ANNEX B.

DEFINITIONS AND ABBREVIATIONS

12

ANNEX C.

PROCUREMENT CHECK LIST

13

ANNEX D.

VALIDATION CERTIFICATE FOR NAB CASTINGS

14

ANNEX E.

CHECK LIST FOR DOCUMENTS TO BE INCLUDED


IN QA PACK FOR VALIDATED CASTINGS

15

ALPHABETICAL INDEX

16

DEF STAN 02-872 Pt 2 / Issue 1

1.

GENERAL REQUIREMENTS
Related Documents: Def Stan 02-747 Parts 1, 2 and 4, see also Annex A
a.

Extensive examinations have shown that the Nickel Aluminium Bronze (NAB)
castings used since the early 1960s are, to varying degrees, susceptible to normal
corrosion and selective phase attack by sea water. The selective phase corrosion
occurs under crevices and in the Heat Affected Zones (HAZ) of weld repairs. This
destroys the mechanical properties of the material without any obvious change in the
appearance of the materials surface.

b.

To limit the effect of this corrosion problem, it is necessary to examine NAB castings
prior to fitting in critical positions, and to carry out periodic examinations during
their life. These examinations are termed Validation and Revalidation
respectively.

c.

Validation of NAB castings is to be carried out during manufacture. Castings which


have had any previous service use in contact with sea water to be revalidated in
accordance with Part 3 of this Defence Standard.

d.

All Submarine First Level sea wetted castings made of NAB manufactured to Def
Stan 02-747 Part 1, 2 or 4 are to be validated to the requirements of this Defence
Standard. Contracts for new NAB castings are to state where validation is required.

e.

The requirements of this standard are in addition to the requirements laid out in Def
Stan 02-747 Part 1, 2 or 4.

f.

The Validation Contractor is to demonstrate to the Design Authority that the


procedures to control and document the application of this Defence Standard are in
place before work is carried out.

g.

The following documentation is to be made available to the personnel making the


inspection:(1)
(2)

h.

drawings with dimensions and wall thicknesses.


all non conformance documentation (concessions etc.) affecting casting
integrity.

The following record sheets are required for recording results and for certification by
personnel making the inspection:(1)
(2)
(3)
(4)

Weld Repair Recording Sheet


Gridded Sketch of casting
Wall Thickness Recording Sheet
Validation Certificate

DEF STAN 02-872 Pt 2 / Issue 1

2.

CLEANING OF CASTINGS
Related Documents: Def Stan 68-188, Def Stan 02-747 Part 4, Def Stan 02-872 Part 3,
see also Annex A

2.1

Cleaning and Etching


a.

Castings are to be cleaned and etched to show up the weld repaired areas before
heat treatment is carried out.

b.

If a casting has been weld repaired in accordance with the requirements of Def
Stan 02-747 Part 4, or has not been weld repaired, then the etching process in
Clause 2.2d may be omitted.

c.

If the casting to be examined is contaminated with grease, then it is to be


degreased in a cold agitated solvent agent to Def Stan 68-188 or similar approved
alternative for between 30 minutes and one hour. On completion of degreasing, it
is to be washed in hot water (80C - 90C) for several minutes until the degreasing
solvent is removed.

d.

The casting is then to be dipped for between 5 and 10 minutes in an approved


brightening solution e.g. Ardrox 160 (available under NSN 99 220 1162) or
similar approved alternative. This process will etch the surface of the casting,
highlighting areas of weld repair. The solution must be sufficiently fresh not to
contaminate the casting surface with redeposited copper. After removal from the
dip bath, the casting is to be thoroughly washed in cold fresh water to remove all
traces of the brightening solution.

e.

If the castings have been heat treated in error prior to validation, the oxide film on
the surface of castings may reduce the effectiveness of the etching process.
Castings therefore, which are weld repaired but which have been heat treated, may
be lightly shot blasted using fine glass beads prior to etching provided this is not
so severe as to materially damage machined surfaces.

NOTE: Due to the toxicity of Ardrox 160, contractors may prefer to use an alternative
general etching chemical, e.g. ferric chloride. Where such a change is proposed, prior
approval should be obtained from the Design Authority.
2.2

Visual Inspection
a.

In general, the appearance of the various exposed surfaces of the casting following
dipping in Ardrox 160 will be roughly as follows:
Weld metal
Parent Metal

- Dark Grey or Black


- Mid Grey

DEF STAN 02-872 Pt 2 / Issue 1

3.

VALIDATION OF CASTINGS
Related Documents: Def Stan 02-747 Parts 1, 2 and 4, see also Annex A

3.1

3.2

General
a.

The main corrosion mechanism causing concern with NAB castings is selective
phase corrosion, which occurs under crevices and biofouling (plug corrosion), or
around weld repairs in the heat affected zone (HAZ corrosion). Selective phase
corrosion can penetrate the thickness of the casting at up to 1.1mm per year with
no apparent surface loss of metal.

b.

Information on the location and size of weld repairs on the wetted and non-wetted
surfaces, combined with wall thickness measurements, provides baseline data for
use during the through life monitoring process for NAB castings.

c.

If a casting has not been weld repaired, then the examination detailed in Clause
3.2 can be omitted.

Weld Repairs
a.

3.3

3.4

All areas of weld repair, in particular where the HAZ is exposed to sea water, are
to be sketched or photographed and sized so that each area is referenced to an
identifiable position on the casting. The depth of weld repair is also to be noted.

Thickness Examination
a.

Checks for wall thickness are to be carried out as laid out in Def Stan 02-747 Part
1, 2 or 4. In addition, the areas of weld repair noted in Clause 3.2 are to be
thickness checked and the results noted.

b.

The use of NDE methods such as ultrasonic examination for measuring wall
thickness must be supported by written procedures to a specification approved by
the Design Authority.

Recording of Examination Results


a.

Each weld repair is to be given a number, which is to be marked on the weld


repair sketch and cross referenced to the Weld Repair Recording Sheet.

b.

The wall thickness values are to be recorded on a Wall Thickness Recording Sheet
in such a way that they are cross-referenced to a grid based sketch.

c.

Grid based thickness sketches for the larger NAB castings should be available
from the Design Authority. If these are not available then general wall thicknesses
should be referenced to a gridded sketch at a spacing to be agreed with the Design
Authority, which gives sufficient detail to provide confidence on the general wall
thickness. For guidance the grid spacing will be typically 70 mm to 100 mm.

DEF STAN 02-872 Pt 2 / Issue 1

4.

ACCEPTANCE CRITERIA
Related Documents: Def Stan 02-747 Parts 1, 2 and 4, see also Annex A

4.1

4.2

Weld Repairs
a.

All weld repairs are to meet the requirements of Def Stan 02-747 Part 2 or 4.

b.

All weld repairs are to be sketched, sized and recorded on the Weld Repair
Recording Sheet.

Wall Thickness
a.

4.3

4.4

Wall thickness results are to comply with the drawing requirements and the
requirements laid out in Def Stan 02-747 Part 1, 2 or 4 as applicable.

Quality Assurance Documentation


a.

Quality Assurance Documentation is to give the actual results of all tests carried out
in accordance with the requirements of Def Stan 02-747 Part 1, 2 or 4 as applicable,
and is to include details of the weld procedure and weld consumables employed.

b.

Records and sketches of the weld repair and wall thickness examinations carried out
to the requirements of this Defence Standard are to form part of the total QA
documentation for the casting.

c.

All record sheets are to be annotated with the castings ship fitting number,
description, and unique radiograph number. Records are to be retained and are to be
available for inspection by a MoD representative on request.

d.

On completion of the examination, a Validation Certificate is to be completed in the


format of Annex D. Completion of the NDE to the requirements of Defence Standard
02-747 Part 1, 2 or 4 is to be documented on the Validation Certificate.

e.

A check list for all the Quality Assurance documentation required for validated
Submarine First Level NAB castings is given in Annex E. A check list of this format
should be completed and submitted with the Quality Assurance documentation.

Stamping of Castings
a.

The officer signing the validation certificate is to witness the stamping of the casting.

b.

In addition to the identification requirements given in Def Stan 02-747 Part 1, 2 or 4,


castings validated to the requirements of this specification are to be stamped on the
flange edge H as a prefix to the radiograph number if heat treated during
manufacture and also A if weld repaired. The letters VAL followed by the date are
to be stamped as a suffix to the radiograph number.

DEF STAN 02-872 Pt 2 / Issue 1

4.5

Records
a.

A copy of the Validation Certificate, together with copies of the full set of QA
records, including Weld Repair Recording Sheet, Wall Thickness Recording Sheet
and sketches/ photographs, are to accompany the casting. These are to be held by the
Through Life Records Contractor when the casting is fitted to the vessel, and are to
be available for future revalidation. The original documents are to be held by the
supplier / manufacturer until the casting is fitted to the vessel as a minimum. The
contract will state if the supplier / manufacturer is required to retain the documents
for a longer period.

b.

The Through Life Records Contractor is to hold the master records.

10

DEF STAN 02-872 Pt 2 / Issue 1


ANNEX A.
RELATED DOCUMENTS
A1.

The following documents and publications are referred to in this Defence Standard:

JSP430

MOD Ship Safety Management System Handbook

Def Stan 68-188

Emulsifier for solvent cleaner

Def Stan 02-747

Requirements for Nickel Aluminium Bronze Castings and ingots


Part 1 - Nickel Aluminium Bronze (Naval alloy) centrifugal castings and
ingots
Part 2 - Nickel Aluminium Bronze (Naval alloy) sand castings and ingots
Part 4 - Nickel Aluminium Bronze (Naval alloy) sand castings with
welding restricted to the non-wetted surface (Class I and II castings only)

Def Stan 02-872

Procedure for First Level Nickel Aluminium Bronze Castings


Part 1 - Policy
Part 3 - Revalidation

DGS 348

Part 4 - Inspections Outside of Long Overhaul Period


Cast Nickel Aluminium Bronze

DGS 8520

Cast Nickel Aluminium Bronze

SSP 25

Quality Assurance for Safety in Submarines

11

DEF STAN 02-872 Pt 2 / Issue 1


ANNEX B.
DEFINITIONS AND ABBREVIATIONS
B1.

For the purposes of this Defence Standard the following definitions and abbreviations apply:

Design Authority

Authority within MOD with design responsibility for the equipment

First Level Quality Where the consequences of failure of a hull area, system or equipment are
Assured
such that it would lead to loss of the submarine, these areas, systems and
equipments will be classified First Level and additional Quality Assurance
measures will be implemented. SSP 25 refers.
HAZ
Heat Affected Zone around a weld.
NAB

Nickel Aluminium Bronze to DGS 8520, DGS 348 or Def Stan 02-747

NDE

Non Destructive Examination

NSN

NATO Stock Number

QA

Quality Assurance

Revalidation

Examination of used NAB castings during their life to the requirements of


Part 3 of this Defence Standard to determine the castings fitness for further
service
Facility contracted to maintain the QA records for castings through life

Through Life
Records Contractor
Validation

The Post manufacture examination of new NAB castings prior to fitting in


critical positions to the requirements of this part of this Defence Standard

12

DEF STAN 02-872 Pt 2 / Issue 1

ANNEX C.
PROCUREMENT CHECK LIST
Notes:
C.1
This check list is to ensure that certain aspects of this Naval Engineering
Standard are consulted when preparing a Procurement Specification for a
particular application.
C.2

Clauses where a preference for an option is to be used or where specific data is


to be added are included in the Check List.

C.3

Each item is to be marked either:


= included
NA = not applicable

CHECK
No.
1
2

CLAUSE
No.

CHECK
State where NAB validation is required
State if the supplier / manufacturer is required
to retain casting QA documents for a specified
period.

13

1d
4.5a

or
NA

DEF STAN 02-872 Pt 2 / Issue 1


ANNEX D
VALIDATION CERTIFICATE FOR NAB CASTINGS

PART I - IDENTIFICATION
A.

EQUIPMENT SERIAL No.

F.

PIL No (VSN/

B.

UNIQUE RADIOGRAPH No.

G.

PIL LINE ENTRY No

C.

COMPONENT DRAWING No.

H.

COMPONENT ADREFNO

D.

SHIP FITTING No. (e.g. BS 123)

I.

MANUFACTURER

E.

COMPONENT DESCRIPTION

MATERIAL SPEC. (DEF


STAN 02-747 Pt. 1, 2 OR 4)

PART II REPAIR AND VALIDATION


A.

WELD AREAS MAPPED (a, b, c, etc)

B.

WALL THICKNESS CHECK

C.

SUBSEQUENT WELD REPAIR

D.

COMPONENT HEAT TREATED

E.

COMPONENT RADIOGRAPHED AND LIQUID PENETRANT EXAMINED

F.

DIMENSIONAL CHECKS

G.

WELD AREAS RE-MACHINED

H.

INTERNAL WELD REPAIRS/ HAZ EXPOSED TO SEA WATER

Signature

Indicate action taken by signature (or NA if not applicable in appropriate box).


CONCESSION NOS
CONCESSIONS GRANTED FOR ABOVE COMPONENT
I certify that the above NAB casting has been validated in accordance with Def Stan 02-872
Part 2 and stamped *
SIGNATURE
NAME IN BLOCK LETTERS
AUTHORITY/DEPT
DATE
* FULL CASTING IDENTIFICATION TO THE REQUIREMENTS OF DEF STAN 02-747 PART
1, 2 OR 4 AND DEF STAN 02-872 PART 2 TO BE INSERTED

14

DEF STAN 02-872 Pt 2 / Issue 1


ANNEX E
CHECK LIST FOR DOCUMENTS TO BE INCLUDED IN QA PACK FOR VALIDATED
CASTINGS
E1.

All certification and record sheets for the validated castings are to be annotated with the
appropriate ship fitting number or pump serial number (as applicable), description, and
unique radiograph number.

QA CERTIFICATE OF COMPLIANCE
CHEMICAL ANALYSIS RESULTS RECORD SHEET
MECHANICAL TESTS RESULTS RECORD SHEET
VISUAL INSPECTION RESULTS RECORD SHEET
LIQUID PENETRANT RESULTS RECORD SHEET
RADIOGRAPHY/ULTRASONIC RESULTS RECORD SHEET
HEAT TREATMENT CERTIFICATE
PRESSURE TEST RESULTS RECORD SHEET/ CERTIFICATE OF COMPLIANCE
VALIDATION CERTIFICATE
GRIDDED SKETCH FOR WALL THICKNESSES
WALL THICKNESS RECORDING SHEET CROSS-REFERENCED TO GRIDDED
SKETCH
SKETCH/PHOTOGRAPH OF WELD REPAIRS
WELD REPAIR RECORDING SHEET CROSS-REFERENCED TO SKETCH/
PHOTOGRAPH
All QA records complete:

SIGNATURE
NAME IN BLOCK LETTERS
AUTHORITY/DEPT
DATE

15

DEF STAN 02-872 Pt 2 / Issue 1


ALPHABETICAL INDEX
(Note: Page Numbers are given)

P
A

Photographs 8, 9

Ardrox 4, 7

C
Certificate
Validation 6, 9, 14, 15
Concessions 6
Corrosion 6, 8

D
Design Authority 8
Drawings 6, 9
Degreasing 7

Quality Assurance Documentation 9

R
Radiograph number 9, 14, 15
Records Sheets
Wall Thickness 6. 8, 9
Weld Repair 6, 8, 9

S
Sketches 8, 9

Etching 7

Through Life Records Contractor 9

First Level 6, 9

Ultrasonic Examination 8

H
Heat Affected Zone 6, 8
Heat Treatment 7

V
Validation 6, 7, 8, 9
Validation Contractor 6

I
W

Identification 9

Wall Thickness 6, 8, 9
Weld repairs 6, 7, 8, 9

Master Records 10

N
NDE 8
Nickel Aluminium Bronze 2, 6, 7, 8, 9

16

Inside Rear Cover

Crown Copyright 2002


Copying Only as Agreed with DStan

Defence Standards are Published by and Obtainable from:


Defence Procurement Agency
An Executive Agency of The Ministry of Defence
UK Defence Standardization
Kentigern House
65 Brown Street
GLASGOW G2 8EX

DStan Helpdesk
Tel 0141 224 2531/2
Fax 0141 224 2503
Internet e-mail enquiries@dstan.mod.uk

File Reference
The DStan file reference relating to work on this standard is D/DStan/69/02/872 Pt 2.
Contract Requirements
When Defence Standards are incorporated into contracts users are responsible for their correct
application and for complying with contractual and statutory requirements. Compliance with
a Defence Standard does not in itself confer immunity from legal obligations.
Revision of Defence Standards
Defence Standards are revised as necessary by up issue or amendment. It is important that
users of Defence Standards should ascertain that they are in possession of the latest issue or
amendment. Information on all Defence Standards is contained in Def Stan 00-00 Standards
for Defence Part 3 , Index of Standards for Defence Procurement Section 4 Index of Defence
Standards and Defence Specifications published annually and supplemented regularly by
Standards in Defence News (SID News). Any person who, when making use of a Defence
Standard encounters an inaccuracy or ambiguity is requested to notify the Directorate of
Standardization (DStan) without delay in order that the matter may be investigated and
appropriate action taken.

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