VIBRANT Indian Embassy Based Model Exam

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Indian Embassy Based Model Examination

INSTRUCTIONS:
There are 120 Multiple Choice Questions (MCQs) each question having four choices of which only one
choice is correct. Fill mark to correct option.

Mark should be dark and completely fill the circle.

Rough work must not be done on the answer sheet.
Make the marks ONLY in the space provided.
Please DO NOT make any stray marks on the answer sheet.
Use gel pen. DO NOT use ball pen or pencil.

Date
Time
Venue
Full Marks

:
:
:
:

2069-11-26, Saturday
11.30 AM - 01.30 PM
VIBRANT Building
120

VIBRANT MBBS ENTRANCE PREPARATION

New Plaza, Putalisadak, (Beside Nepal Yatayat Stoppage)
Kathmandu, Nepal, GPO: 763, Ph +977-1-4426149/4440184

Email: info@vibrant.com.np, www.vibrant.com.np

Join: www.facebook.com/vibrantmbbs

-1-

VIBRANT Indian Embassy Based Model Exam

1.

2.

A body is projected vertically upward from point A, the top of a tower. It reaches the ground
in t1 secs. If it is projected vertically downward from A with same speed, it reaches the
ground in t2 secs. If it falls freely from A, it would reach the ground in:






a.   sec
b.   sec
c. t1t2 sec
d.t
t  sec


A large number of bullets are fired in all direction with same speed V, the maximum area on
the ground in which these bullets spread is:
a.

3.

4.
5.

6.

7.

8.
9.

b.

11.
12.
13.

a.  =

b. f11=f22

d.

c.

 


+  =0


d.

 

- =0

 

A water falls from 84m high. Assuming that half of the K.E. of the falling water is converted
into heat, what will be the rise in temperature? Take g= 10 m/s
b. 0.20c
c. 0.30c
d. 4. 0.40c
a. 0.10c
If the magnet is suspended at an angle 300 to the magnetic meridian, the dip needle makes an
angle of 600 with horizontal. What is the true dip?
a. tan
3/2
c. tan
2/3
d. tan
1/3
a. tan
3
A body is moved along a straight line by a machine delivering a constant power. The
distance moved by the body in a time 't' is proportional to:
a. t 3/4
b. t 3/2
c. t 1/4
d. t 1/2
Packing fraction is given by the relation:


a. A/M-A
b. 
c. M/M-A
d. 
Two conducting spheres of radii r1&r2 are charged to the same surface charge density. The
ratio of electric fields near their surface is:


a. 

c. 

b. 

d. 1:1

If the end A of a wire is irradiated with - rays and the other end B is irradiated with !rays, then:
a. a current will flow from A to B
b. a current will flow from B to A
c. there will be no current in the wire
d. a current will flow from each end to the mid- point of the wire
In thermionic emission, the thermionic current varies with temperature of the filament as:
a. T
b. T
c. T-1
d. T-2
The voltage gain of a triode depends upon:
a. filament voltage
b. plate voltage
c. plate resistance
d. plate current
Energy level A,B,C of a certain atom correspond to increasing values of energy i.e. EA<EB<EC.
If 1, 2, 3 are the wavelengths of radiation corresponding to the transitions C to B, B to A, &
C to A respectively, which of the following statements is correct?
C
1
3
B
A
a. 3=1+2

14.

c.

A charge 'q' is placed at the corner of a cube of side 'a'. The electric flux through any one face
of the cube is:




a.
b.
c.
d.



 
The condition for no chromatic aberration of lenses in contact is:



10.

 

b. 3=

c. 1+2+3=0

  

d. 3=12+22

The increase in length of a wire on stretching is 0.025%. If the poison's ratio is 0.4, then the
percentage decrease in diameter is:
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VIBRANT Indian Embassy Based Model Exam

15.

16.

17.

a. 0.01
b. 0.02
c. 0.03
d. 0.04
A string when stretched with a weight of 1 kg produce a note frequency 256, the 9 kg weight
produce an octave of the note. The value of x will be:
a. 9.4 kg wt
b. 36 kg wt
c. 18 kg wt
d. 4 kg wt
0
Starting from rest a body slides down at 45 inclined plane in twice the time it takes to slide
down the same distance is the absence of friction. The coefficient of friction between the
body and the inclined plane is:
a.0.33
b. 0.25
c. 0.75
d. 0.80
A particle is moving in a circle of radius 'r' with a uniform speed 'v'. It's angular acceleration is:
a. directed towards centre

b.

18.

19.

20.

21.

22.

23.

24.

25.
26.

28.
29.

"

directed towards centre

c.
directed along the axis
d. zero
"
A uniform disc is rotating at a constant speed about a vertical axis through its centre. Some
wax is dropped gently on the disc, the angular velocity of disc:
a. does not change
b. increases
c. decreases
d. becomes zero
A bomb explodes in mid-air. Its:a. total kinetic energy increases
b. total momentum increases
c. total momentum decreases
d. total K.E decreases
The total energy of an object in SHM is:
a. maximum at the extreme position
b. maximum at the mean position
c. maximum midway between extreme and mean position
d. constant throughout the motion
A car not engine has same efficiency in between (i) 100K & 500K & (ii) TK & 900K. What is
the temperature T?
a. 100K
b. 180K
c. 360K
d. 720K
How much lead of specific gravity 11 should be added to a piece of cork of specific gravity 0.2
weighing 10g so that it may just float on water?
a. 4.4g
b. 44g
c. 440g
d. 2.2g
0
0
The emf in a thermo couple circuit with one junction at 0 c and other at t c is given by:
e= At+Bt, the neutral temperature (tn) is given by:
a. A/B
b. -A/2b
c. -B/2A
d. A/2B
A uniform rope of length 'L' lies on a table. If the coefficient of friction is #$' then the maximum
length 'L' of the part of this rope which can over hung from edge of table without sliding is:
%
%
a. L/
b. L/+1
c.

d. %

Braggs equation 2dsin=n

will have no solution if:
b. >2d
c. <d
d. >d
a. 2d
Two concentric circular coils of ten turns each are situated in the same plane. Their radii are
20 cm & 40 cm and they carry currents of 0.2 & 0.3 ampere respectively in opposite direction.
The magnetic field in Wb/m at centre is:
'

27.

'

d. & )o
a. & ( )o
b. +*
c. &+)o
(
The beam of light strikes a piece of glass at an angle of incidence 600. It is found that the
reflected beam is completely plane polarized. Then refractive index of glass is:
a. 1.5
b. 3
c. 2
d. 3/2
The mean free path of a gas varies with absolute temperature as:
a. T
b. T-1
c.T
d. T4
Radio receiver aerial is roatated to obtain a maximum signal on account of:
a. diffraction
b. scattering
c. interference
d. polarization

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VIBRANT Indian Embassy Based Model Exam

30.

31.
32.

33.

34.
35.

36.
37.

38.
39.

40.

41.
42.

43.

44.
45.

An air filled parallel plate capacitor has a capacitance 1pf. The seperation of the plates is
doubled and wax is inserted between them, which makes the capacitance 2pf. This implies
that dielectric constant of wax is:
a. 2.0
b. 4/3
c. 4.0
d. 8.0
Soft drink bottles and baby feeding bottles are generally made up of:
a. polyurethane
b. polyurea
c. polyamide
d. polystyrene
1.1 mole of A is mixed with 2.2 moles of B and the mixture is kept in a one litre flask till the
equilibrium,
A+2B 2C+D is reached. At equilibrium 0.2 moles of C is formed. Calculate the
equilibrium constant for the above reaction:
a. 1x10-3
b. 2x10-3
c. 3x10-3
d. 4x10-3
Calculate the difference between heats of reaction at constant pressure and constant volume
for the reaction at 250c in j ;
2C6H6(l.)+15O2(g) 12 CO2(g)+6H2O(l.)
a. -8.4 j
b. -7.4 j
c. 10.4 j
d. 12 j
0
0
The crystal system for which a=b
c, =
=90 , = 120 is:
a. cubic system
b. hexagonal system
c. triclinic system
d. monoclinic system
The free energy change is related to equilibrium constant as:
a. G= RT ln Kc
b. -G=RT logKc
c. G= -2.303 RT log Kp
d.-G=(RT log Kc)/2.303
The unit of second order reaction rat constant is:
a. Litre-1 mol sec-1
b. litre2 mol-2 sec-1
c. litre mole-1 sec-1
d. sec-1
The edge length of a face centred cubic unit cell is 508 pm.
If the radius of cation is 110 pm, the radius of the anion is:
a. 288 pm
b. 398 pm
c. 144 pm
d. 618 pm
Which of the following is not a protonic acid?
a. PO(OH)2
b. SO (OH)2
c. SO2(OH)2
d. B (OH)3
--.

/
X
C6H5OH 0123

45 6789
3:19

;01

Y ;;8<61 .;=: Z

What at is Z ?
a. Cresol
b. Benzene
c. Toulene
d. Benzyl alcohol
-10
The precipitate of CaF2 (Ksp= 1.7x10 ) is obtained when equal volumes of the following are
mixed:
a. 10-4 M ca++ + 10-4 MFb. 10-2M Ca ++ + 10-3 MFc. 10-5 M Ca ++ + 10-3 MFd. 10-3M Ca++ + 10-5 MFWhich produces NH3 on reaction with caustic soda ?
a. ethylamine
b. dimethylamine
c. acetamide
d. aniline
Portland cement is manufactured by using:
a. limestone, clay & sand
b. limestone, gypsum & sand
c. limestone, gypsum & alumina
d. limestone, clay & gypsum
The minimum amount of energy required by the reacting molecules at the time of collisions
in order to produce effective collision is called:
a. threshold energy
b. activation energy
c. internal energy
d. potential energy
Which can exist in optically active form?
a. 1-Butanol
b. 2-Butanol
c. 3- Pentanol
d. 4- Heptanol
In the keto-enol tautomerism of dicarbonyl compounds, the enol is preferred is contrast to
the keto form, this is due to:
a. presence of carbonyl group on each side of the -CH2 b. resonance stabilization of the enol form
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VIBRANT Indian Embassy Based Model Exam

46.
47.
48.

49.
50.

51.
52.

53.
54.

55.

56.

57.
58.
59.
60.

61.

c. presence of methylene group

d. rapid chemical change
When propyne is treated with dil. H2SO4 in presence of HgSO4, the major product is:
a. propanal
b. acetaldehyde
c. acetone
d. butanone
C6H5C
N+2 [H] SnCl2/HCl C6H5CHO+ NH3. The above reaction is:
a. Mendius reaction
b. Schmidt reaction
c. Rosenmund reaction d. Stephen reaction
Which is most acidic?
a. CH3CH2CH2CH-CH2COOH
b. H3C-CH-CH2-COOH
Cl
Cl
c. CH3CH2-CH-CH2-COOH
d. CH2-CH2-CH2-CH2 COOH
Cl
Cl
The useful by products obtained in the solvay's process of manufacturing sodium carbonate are:
a. quick lime and CO2
b. CaCl2
c. NaHCO3 and NH4 Cl
d. NaHCO3 and CO2
If the reaction involves only solids & liquids which of the following is true?
a. H<E
b. H=E
c. H>E
d. H=E+n RT
A galvanic cell with electrode potential of zinc = +0.76V and copper =-0.34v. The emf is:
a. +0.76V
b. +0.34v
c. +1.1v
d. -1.1v
For the reaction;
2NH3(g) N2 (g)+3H2(g), the units of Kp will be:
c. (atm)-2
d. (atm)
a. atm
b. (atm)3
+
The bond length of species O2,O2 and O2 are in the order of:
a. O2+>O2>O2b. O2->O2>O2+
c. O2>O2+>O2d. O2>O2->O2+
Aniline is purified by:
a. steam distillation
b. simple distillation
c. vacuum distillation
d. extraction with a solvent
A mixture of CO & N2 in equal amount have total 1 atm. pressure, find out the partial
pressure due to N2:
a. 1 atm
b. 0.50 atm
c. 2 atm.
D. 3 atm.
From the following reactions product Z is:
O=C-OH
NH3
P2O5
Y
Z
heat
a. Benzamide
b. Aniline
c. Benzanilide
d. Benzonitrile
Medicines used in Angina pectoris is:
a. Oil of mirbane
b. Oil of bitter almond c. Noble oil
d. Cordite
A gas which is used in dental surgery is:
a. N2
b. N2O5
c. C2H2
d. N2O
Structure of PF5 is:
a. Octahedral
b. Trigonal bipyramidal c. Pentagonal bipyramidal
d. Hexagonal
In galvanic cells:
a. Electrical energy is converted into chemical energy
b. Chemical energy is converted into electrical energy
c. Electrical energy is converted into mechanical energy
d. Chemical energy is converted into heat energy
If thyroid gland is completely removed from a tadpole, it will:
a. die immediately
b. turn into a giant frog
c. turn into a dwarf frog
d. remain tadpole throughout its life
-5-

VIBRANT Indian Embassy Based Model Exam

62.

63.

64.
65.

66.
67.
68.
69.

70.

71.
72.

73.

74.

75.

76.

77.
78.
79.
80.

Majority of mammalian spermatozoa acquire capacitation in:

a. female reproductive tract
b. epididymis
c. vas deferens
d. seminal vesicle
Erythroblastosis foetalis occurs when:
a. Husband is Rh- & wife Rhb. Wife is Rh+ husband Rhc. Wife is Rh+ & husband Rh+
d. Wife is Rh- & husband Rh+
The possible blood group of children born to parents having A& AB groups are:
a. O,A
b. A,B,AB
c. O,A,B
d. O,A,B,AB
Cork cambium results in the formation of cork which becomes impermeable to water due to
the accumulation of:
a. Resins
b. Suberins
c. Lignins
d. Tannins
Largest human gene is:
a. Oncogene
b. Tumour suppressor gene c. Dystrophin
d. Insulin
Black foot disease is due to ground water contamination of:
a. Nitrate
b. Fluoride
c. Arsenic
d. Sulphur
Viscum is:
a. Total rood parasite
b. Total stem parasite
c. Partial rood parasite Partial steam parasite
Which one of the following bacteria has found extensive use in genetic engineering work in plants?
a. Clostridium septicum
b. Xanthomonas citri
c. Bacillus coagulens
d. Agrobactericon tumefaciens
Short lived immunity acquired from mother to foetus across placenta or through mother's
milk to the infant is categorized as:
a. Active immunity
b. Passive immunity
c. Cellular immunity
d. Innate non specific immunity
Genes for cytoplasmic male sterility in plants are generally located in:
a. chloroplast genome
b. mitochondrial genome c. Nuclear genome d. Cytosol
Most of the lichen consists of:
a. Brown algae and higher plant
b. Red algae and ascomycetes
c. Blue- green algae and ascomycetes
d.Blue green algae and basidiomycetes
An aggregate fruit is found in:
a. Pyrus malus
b. Ananas sativus
c. Anona squamosa
d. Artocarpus integrifolia
Cytochromes are:
a. Lipids
b. Glycoproteins
c. Metalloporphyrins
d. Fe containing with porphyrin
The enzyme involved is transcription is:
a. RNA polymerase
b. DNA polymerase- I
c. DNA polymerase-II
d. DNA polymerase-III
An edible part of mushroom is:
a. Basidiocarp
b. Tertiary mycelium
c. Primary mycelium
d. secondary mycelium
The first reaction is photorespiration is:
a. carboxylation
b. Decarboxylation
c. Oxygenation
d. Phosphorytation
Nitrogenase enzyme is found in Nostoc in the cell of:
a. Vegetative
b. Heterocyst
c. Both vegetative & heterocyst d. None
The zygospore in spirogyra is:
a. one layered
b. two layered
c. three layered
d. multi-layered
Most water absorption in plants takes place through:
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VIBRANT Indian Embassy Based Model Exam

a. Root cap
b. Root apex
c. Root hair zone
d. Meristematic zone
81. Most abundant lipid in the cell membrane is:
a. cholesterol
b. phospholipids
c. glycolipids
d. cerebrosides
82. The drug that depresses CNS is:
a. Amphetamine
b. Caffeine
c. Opium
d. Coccaine
83. Which of the following is a coelenterate:
a. sea cucumber
b. sea pen
c. sea fish
d. sea urchin
84. 'Y' shaped bone is:
a. Squamosal
b. Quadrato jugal
c.Palatine
d. Pterygoid
85. Which of the following extra embryonic membrane has its main function as nutrition?
a. Amnion
b. Chorion
c.Allantois
d. Yolk sac
86. At fovea centralis:
a. Number of rod cells are higher
b. Number of cone cells are higher
c. Both rods & cones are absent
d. both are present equally
87. Ornithine cycle takes place in:
a. Liver
b. Kidney
c. Lungs
d. Stomach
88. Mode of secretion by sebaceous gland is:
a. Holocrine
b. Merocrine
c. Eocrine
d. Apocrine
89. Foramen ovale is present only in the heart of embryos leading from right auricle to:
a. right ventricle
b. postcaval vein
c. pulmonary artery
d. left auricle
90. RBC's are seen in the food vacuole of:
a. Plasmodium
b. Trypanosoma
c. Entamoeba histolytica
d. Leishmania donovani
91. Rule by desk officials/department of states is called:
a. Aristocracy
b. Bureaucracy
c. Autocracy
d. Ochlocracy
92. Fear of wide open places is:
a. Agoraphobia
b. Acrophobia
c. Anglophobia
d. Anthrophobia
93. A speech or writing praising a person or a thing:
a.panegyric
b. plebiscite
c. perjury
d. mannequin
94. Rule by one's wife:
a. Cock-pecked
b. Hen- pecked
c. pig pecked
d. wifious
95. 'To ooze out' means:
a. To move slowly
b. to run fast
c. to discover
d. to evolve
96. The bank clerk tried to ________ money from his friends account.
a. empower
b. embellish
c. embroil
d. embezzle
97. Do sit down,.?
a. can you
b. can't you
c. will you
d. won't you
98. He died:
a. on 14 July in the year 1960 at 11 pm
b. in the year 1960 on 14 July at 11 pm
c. at 11pm on 14 July in the year 1960
d. in the year 1960 at 11 pm on 14 July.
99. 'Nepotism' means:
a. Eliminating enemies
b. ruling a country
c. giving favour to one's relatives
d. government by cruel ruler
100. No other, except a few students, ___________ there
a. was
b. were
c. has
d. have
101.Choose the correct spelling:
a. proffesor
b. Proffessor
c.Professor
d. Profesor
102. Choose the right synonym for the word 'Herculean'.
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VIBRANT Indian Embassy Based Model Exam

103

104.

105.
106.
107.
108.
109.
110.
111.
112.

113.

114.
115.

116.
117.
118.
119.
120.

a. tiny
b. stunted
c. tarnish
d. enormous
The phrase 'Don't move a single hair' means:
a. not to move your hair
b. stand still
c. he is allowed to comb his hair
d. none of the above
Which of the following sentences is correct?
a. She is very beautiful but fat
b. She is beautiful but very fat
c. She is very fat but beautiful
d. She is fat but very beautiful
She insisted that her father______________a scooty.
a. Got
b. should get
c. Get
d. Must get
He is__________his lessons.
a. busy to prepare
b. busy of preparing
c. busy preparing
d. busy for preparing
He soon__________ in his job.
a. lost his heart
b. lost heart
c. lost one's heart
d. lost hearts
Which expression is incorrect?
a. go over- review
b. bring out-publish
c. put up at--- tolerate d. call off -cancel
The more,___________
a. the better
b. the worse
c. the happier
d. the merrier
She looked as thought she_______sick.
a. had been
b. were
c. has been
d. was
We should all_______our sins.
a. atone at
b. atone with
c. atone by
d. atone for
..are friendly.
a. You, my father and I
b. My father, you and I
c. I, my father and you
d. You, I and my father
All the people at this conference are:
a. mathematic teachers
b. mathematics teachers
c. mathematics teacher
d. none
Jaya's face spoke_____________for the happiness she was feeling.
a. volumes
b. highly
c. wonders
d. laurels
Neologism: Language::
a. rhetoric : oratory
b. syllogism : grammar
c. innovation : technology
d. iconography : art
Elephant : amble::
a. goat : bleed
b. crow : sheep
c. mouse : scamper
d. donkey : gallop
The antonym of 'beguile' is:
a. deceive
b. charm
c. cheat
d. persuade
He always wears________ clothes.
a. decent
b. descent
c. dessent
d. dicent
They connived to alert the police to the possibility of a bomb blast.
a. helped
b. to conspire
c. forced
d. to try
The magnificent ________ temple was constructed by the Chinese.
a. eight-centuries-old
b. eight-century's-old c. old- eight- centuries d. eight-century-old
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VIBRANT Indian Embassy Based Model Exam

Nepal's Largest
The backbone of Medical Entrance Institute is solely the quality of Teachers

Indian Embassy Based Model Examination

Hints and Solutions

Date: 2069-11-26, Saturday
Time: 11.30 AM 01:30 PM

VIBRANT MBBS ENTRANCE PREPARATION

New Plaza, Putalisadak, (Beside Nepal Yatayat Stoppage).
Kathmandu, Nepal, GPO: 763, Ph +977-1-4426149/4440184
Email: info@vibrant.com.np, www.vibrant.com.np
Join: www.facebook.com/vibrantmbbs

-9-

1.d

VIBRANT Indian Embassy Based Model Exam

h=-ut1+ gt12 ..(i)



h= ut2 + gt2(ii)


h= t 32 (iii)


Eqn (i)xt2 + eqn (ii) x t1, we get

H= g t1 t2(iv)


2.b

From (iii) & (iv)

T3=>
>
Max. range occurs at 450;
V/R max g= tan 450
or, Rmax =

Max. area covered by bullets = R= & ) =

3.b
4.c
5.a

Total flux = q/o

Flux through each face = q/Qo
Condition for achromatic combination of Lens is:
?
?

=-




If m is mass of falling water & be rise in temperature, then,

mgh =ms


or, =
6.b

A
B

+ C (

= C (++ = 0.1 0c

tan =V/H

also, tan1=

tan = tan1 cos

DEFBG

=tan 600. cos 300

= = tan-1 (3/2)
7.(b)

[Power] = [MLT-3]
L2 T-3 =K
or L T3
I

or L T 
I

S t
8.d

Packing fraction=

9. d

We have, Q1=Q2

or
or,

J
(K"
J
(KL* "

or, E1=E2
M

10.a
11.b




=
J

= (KL "

J
(K"

* 

M = 1:1


-rays are charged He particles. The currect flows in the direction opposite to flow of e-s.
A/c to Richarson's Dushmann formula;
I= CATe/KT
IT

12.c
13.b

for such transition;

3=
14.a

Poisson's ratio (O)=



 

N 

P/P
Q/Q

d/d x 100% = 0.4x0.025x100

- 10 -

VIBRANT Indian Embassy Based Model Exam

= 0.01%
15.b

16.c

fM

R

or

V

R

=S

=S

x = 36 kg wt
In absence of friction;
tW

XYZ

[

S \ . (i)

In presence of friction;
T1 =
2t =

[

XYZ

S\ ]^_ `X

XYZ

S\ ]^_ `X .. (ii)

[

Dividing (ii) by (i) ; 2 =S

or 4=

XYZa`X


or 4=
17.d
18.c
19.a
21.b

22.b

/ 

/ a

or 4-4=2

=2.6/4 0.75

Workdone, angular acceleration and moment of force about axis are each zero in a uniform circular motion
m = k
1/m
20.d
b
n = 1-  x 100 %
b

l- 100/500 = 1-T/900
or 1/5 = T/900
T= 180 K
Total weight = weight of water displaced
or m1g+m2g
= ( V1+V2) wg
or, m1+10 = &

m1= 44g
23.b


a

XYZa`X

cd

+.

E=At+Bt
g
W h i> jklm>nio >kpqni>lnk
g

O= A+2Btn
tn ( neutral temperature) = -A/2B

24. c.

25.b
26.d

Wt. of hanging part = Friction force on chain

or, mgl =m (L-1)g
or 1/L = /+1
The max. value of sin=1, If is greater than 2d; Bragg's equation is invalid
ars
B centre =
Bnet =

ar




&  ! ) =


= o x 5 (1/4)



(+T
+


&

+.
+.

= o (5/4)

+.
+.(

27. b
28.a

= tan 600
= 3
tb
Mean free path ( ) =
T

 v

- 11 -

VIBRANT Indian Embassy Based Model Exam

29.a
30.c

Co=

wx
P

& C=

C/Co=

x




P

or





=4

31.d
32.a

A+2B 2C+D
At initial : 1.1 mile 2.2 mole
0
0
At equilibrium ( 1.1-0.1) (2.2-0.2) 0.2 mile 0.1 mol
= 1 mol = 2 mol
Thus; [c]=0.2 mollL-1, [D]=0.1 Moll-1, [A]= a moll-1, [B]= 2 moll-1
y  z{|

33.b

34.b
35.c
36.c
37.c

38.d
39.b

Kc = zx|z}| =

+. T z+.
|

T 

+. T +. T +.

TT

= 1x10-3

n = 12-15=-3
We know that, H=E+nRT
or H-E=mRT= -3x8.314x10-3x298

= -7.4 J

G= -2.303RT log Kp

In fcc lattice,
Side of the cube = 2 x (rc+ra) = 508 pm
Or, 2 (110+ra)=508 pm
ra= 144 pm
H3BO3 is monobasic weak acid (lewis)

C6H5OH CCl4/NaOH
(CaO+NaOH)
Soda lime
40.b

C 6H 4

COOH
Zndust C6H5 COOH Na C6H5COONa
OH
Heat
(Sodium benzoate)

C 6H 6

Ionic product = [Ca++] [F J]

=

+~


x&

+~I
)


= 1/8 x 10-2 x 10-6

= 1.25 x 10-9
In option (b) only ionic product exceeds solubility product
41.c
42.d
44.b

45.b
46.c

CH3CONH2 NaOH CH3 COONa+ NH3

43.a
H H
H3C-C-C- CH3
H OH
2 - Butanol bears chiral carbon centre
O
HgSO
4
CH3 C CH + dil. H2SO4
CH3-C=CH2 CH3-C-CH3
OH

47.d
48.a
49.b

( acetone)

-I effect of (a) is more because Cl is near to COOH.

50. b

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VIBRANT Indian Embassy Based Model Exam

H= E+PV
For solids & liquids V in negligible
H=E
51.c
Cell reaction is:
Zn+Cu Zn+ + Cu
Zn is axode and cu is cathode in this galvanic cell.
Oxidation occurs at anode & reduction occurs at cathode
Ezn/zn+ = +0.76V
Ezn+/zn = - 0.76V
Ecu/cu=-0.34V
E cu2+/cu = +0.34V
Ecell = Ecathode - Eanode
= 0.34V- (-0.76V)
= +1.1V
52.d.

2 NH3 (g) N2 (g) + 3H2(g)

Kp =

r T  I
rI

c

c

= (atm)

53.bBond length 1/ Bond order 1/Bond energy

54. c
55.b
Partial pressure of a gas = miles of gas/total moles x total pressure
= 1/2 x 1 = 0.5 atm.
56.d
C6H5 COOH NH3
C6H5COONH4 P2O5 C6H5CN+2H2O

57.c
71.b
85.c
99.c
113.b

58.d
72.c
86.b
100.a
114.b

59.b
73.c
87.a
101c
115.c

(X)

60.b
74.d
88.a
102.d
116.c

Benzonitrile
(Z)
61.d
75.a
89.d
103.b
117.d

62.a
76.a
90.c
104.a
118.a

63.d
77.c
91.b
105.c
119.b

64.c
78.b
92.a
106.c
120.d

ALL THE BEST

- 13 -

65.b
79.c
93.a
107.a

66.c
80.c
94.b
108.c

67.c
81.b
95.a
109.b

68.d
82.c
96.d
110.a

69.d
83.b
97.d
111.b

70.b
84.d
98.c
112.a