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CHENNAI CENTRE
Subject:
ADPA90A01
CHEMISTRY
FIITJEE
Topic:
NAME:
1.
2.
(d) ClO4
3.
When electrons are trapped into the crystal in anion vacancy, this locations are known as:
(a) Schottky defect
(b) Frenkel defect
(c) Stoichiometric defect
(d) F-centres
4.
The vapour pressure of a dilute aqueous solution of glucose is 750 mm of mercury at 373 K. The mole fraction of
solute is:
1
1
1
1
(a)
(b)
(c)
(d)
10
7.6
35
76
The number of d electrons in Fe 2 (at. no. of iron = 26) is not equal to that of:
(a) p electrons in neon (at . no. = 10)
(b) s electrons in Mg (at. no. = 12)
(c) d electrons in Fe
(d) p electrons in Cl (at. no. of Cl = 17)
5.
6.
7.
9.
2
(a) Ni aq Cu s Ni s Cu aq
(b) Cu s 2Ag aq Cu aq 2Ag s
2
(c) Cu s 2H aq Cu aq H 2 g
8.
2
(d) Zn s 2H aq Zn aq 3H 2 g
(c) Ag
(d) Cu
(b) Cu 2
(c) Ag
Comprehension 1
(d) Sn 2
The ions which can be precipitated with both HCl and H 2S are:
(a) Pb 2
The E 0 values for the changes given below are measured against SHE at 27 0 C Cu 2 e Cu E 0 0.15V
Cu e Cu E 0 0.50V
Zn 2 2e Zn E 0 0.76V
The temperature Coefficient of emf a cell designed as Zn / Zn 2 // Cu 2 / Cu is 1.4 104 V per degree. For a cell reaction in
equilibrium G 0 and G 0 = -2.303 RT log10 K c the heat of reaction and entropy change during the reaction are related
by G H T S
10. The E 0 for the reaction 2Cu Cu 2 Cu is
(a) + 0.35 V
(b) -0.35 V
(c) + 0.65 V
(d) -0.65
2
// Cu 2 / Cu is
11. The decrease in free energy during the cell reaction in Zn / Zn
1M
0.1M
FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 PH. 044 42859701
Quiz
12. The Equilibrium constant for the reaction Zn Cu 2 Zn 2 Cu is
(a) 6.0 1036
(b) 1.94 1037
(c) 1.47 1038
Comprehension 2
Many chemical and biological processes depend on osmosis, the selective passage of solvent molecules through porous
membrane from a dilute solution to a more concentrated one. The osmotic pressure depends on molar concentration of
the solution CRT . If two solutions are of equal solute concentration and, hence, have the same osmotic pressure,
they are said to be isotonic. If two solutions are of unequal osmotic pressure, the more concentrated solution is said to be
hypertonic and the more diluted solution is described as hypotonic.
Osmosis is the major mechanism for transporting water upward in the plants. Transpiration in the leaves supports the
transport mechanism of water. The osmotic pressure of sea water is about 30 atm; this is the pressure that must be applied
to the sea water (separated from pure water using semi permeable membrane) to get drinking water.
13. A plant cell shrinks when it is kept in:
(a) hypotonic solution
(b) hypertonic solution
(c) isotonic solution
(d) pure water
14. Isotonic solutions have same:
(a) density
(b) molarity
(c) molality
15. Glucose solution to be injected into the bloodstream must have same .. as that of the bloodstream:
(a) molality
(b) vapour pressure
(c) osmotic pressure
(d) viscosity
Assertion and Reasoning
Directions: The questions (16 18) given below consists of STATEMENT 1 and STATEMENT 2. Use the following key
to choose the appropriate answer.
(a) Both STATEMENT 1 and STATEMENT 2 are true and STATEMENT 2 is correct explanation of STATEMENT 1
(b) Both STATEMENT 1 and STATEMENT 2 are true but STATEMENT 2 is not correct explanation of STATEMENT 1.
(c) STATEMENT 1 is true, STATEMENT 2 is false.
(d) STATEMENT 1 is false, STATEMENT 2 is true.
16.
STATEMENT 1:
STATEMENT 2:
17.
18.
0.1 M solution of NaCl has greater osmotic pressure than 0.1 M solution of glucose at same
temperature.
In solution, NaCl dissociates to produce more number of particles.
STATEMENT 1:
If standard reduction potential for the reaction Ag e Ag is 0.80 volts then for the reaction
STATEMENT 2:
STATEMENT 1:
STATEMENT 2:
Part B
Match the following
M1.
COLUMN I
Reaction
COLUMN II
Product
Cu HNO3 dil
NO2
Zn HNO3 conc
N 2O
Cu HNO3 conc
Cu NO3 2
Zn HNO3 dil
Zn NO3 2
M2.
COLUMN I
(Solute)
COLUMN II
(Vant Hoff factor)
FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701
Quiz
A
K 4 Fe CN 6
1 2
Al 2 SO 4 3
Greater than 1
NH 2 C NH 2
1+ 4
CaCl2
||
M3.
COLUMN I
(Radicals)
COLUMN II
(Group reagents)
Pb 2
H 2S
Co 2
NH 4 Cl NH 4 OH
Fe3
HCl
Ba 2
NH 4 2 CO3
M4.
COLUMN I
COLUMN II
Cu NH3 4 SO 4
dsp
Pt NH3 2 Cl 2
Octahedral
K 4 Fe CN 6
sp3 d 2
Fe H 2 O 6 Cl3
Square planar
Part C
Numerical
N1.
N2.
1.22g of non volatile , non electrolyte solute (X) is dissolved in 100g benzene and elevation of boiling point
for this solution was found to be 0.13 K. Find the mol. wt of (X) if Kb for benzene is 2.6 kg K mol-1
Observation -1: NH 4 2 Cr2 O7 on heating, gives nitrogen gas and a green residue
Observation- 2: To a nitrate solution ferrous sulphate solution is added, precipitate if any is filtered off and
concentrated H 2 SO4 is poured along the sides. A dark brown ring is obtained at the junction of the two
liquids.
Observation- 3: When O3 is passed through mercury, it loses it meniscus and sticks to glass. This
phenomenon of mercury sticking to glass is called tailing of mercury.
Find out the sum of molecular masses of green residue in Observation-1, complex ion causing the brown ring
in Observation -2 and the compound responsible for tailing of mercury in Observation- 3 (Atomic mass of
Hg = 200).
FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701
Quiz
CHEMISTRY
1. A
2.D
3.D
4.D
5.D
6. A,B,C,D
7.A,C
8.B,C,D
9.A,C
10.A
11.A
12.A
13.B
14.B
15.C
16.A
17.D
18.B
M1.
A-R
B-P,S
C-P,R
D-Q,S
M2.
A-Q,R
B-Q,R
C-S
D-P,Q
M3.
A-P,R
B-P,Q
C-Q
D-Q,S
M4.
A-P,S
B-P,S
C-Q
D-Q,R
N1.0244
N2. 0744
FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701