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Quiz

CHENNAI CENTRE
Subject:

ADPA90A01

CHEMISTRY

FIITJEE

Topic:

NAME:

1.

2.

Single Answer Questions


Which of the following is strongest oxidising agent?
(a) ClO
ClO2
(c) ClO3

(d) ClO4

Given standard electrode potential;


Fe3 3e Fe;
E 0 0.036 volt
Fe 2 2e Fe;
(a) -0.476 volt

E 0 0.440 volt The standard electrode potential E 0 for Fe3 e Fe 2 is:


(b) +0.476 volt
(c) -0.772 vol volt
(d) +0.772 volt

3.

When electrons are trapped into the crystal in anion vacancy, this locations are known as:
(a) Schottky defect
(b) Frenkel defect
(c) Stoichiometric defect
(d) F-centres

4.

The vapour pressure of a dilute aqueous solution of glucose is 750 mm of mercury at 373 K. The mole fraction of
solute is:
1
1
1
1
(a)
(b)
(c)
(d)
10
7.6
35
76
The number of d electrons in Fe 2 (at. no. of iron = 26) is not equal to that of:
(a) p electrons in neon (at . no. = 10)
(b) s electrons in Mg (at. no. = 12)
(c) d electrons in Fe
(d) p electrons in Cl (at. no. of Cl = 17)

5.

6.

One or more than one correct option questions


Which of the following reaction, will produce Cl 2 as one of the product?
(a) NaCl MnO2 H 2 SO4 (b) MnO2 HCl

7.

9.

(d) CaOCl2 HCl

Given that Ni 2 / Ni 0.25 V, Cu 2 / Cu 0.34V, Ag / Ag 0.80Vand Zn 2 / Zn 0.76V Which of the following


reactions under standard condition will not take place in the specified direction?
2
2

2
(a) Ni aq Cu s Ni s Cu aq
(b) Cu s 2Ag aq Cu aq 2Ag s

2
(c) Cu s 2H aq Cu aq H 2 g

8.

(c) PbO2 HCl

Which among the following are diamagnetic?


(a) Cu 2
(b) Zn 2

2
(d) Zn s 2H aq Zn aq 3H 2 g

(c) Ag

(d) Cu

(b) Cu 2
(c) Ag
Comprehension 1

(d) Sn 2

The ions which can be precipitated with both HCl and H 2S are:
(a) Pb 2

The E 0 values for the changes given below are measured against SHE at 27 0 C Cu 2 e Cu E 0 0.15V
Cu e Cu E 0 0.50V
Zn 2 2e Zn E 0 0.76V

The temperature Coefficient of emf a cell designed as Zn / Zn 2 // Cu 2 / Cu is 1.4 104 V per degree. For a cell reaction in
equilibrium G 0 and G 0 = -2.303 RT log10 K c the heat of reaction and entropy change during the reaction are related
by G H T S
10. The E 0 for the reaction 2Cu Cu 2 Cu is
(a) + 0.35 V
(b) -0.35 V

(c) + 0.65 V

(d) -0.65

2
// Cu 2 / Cu is
11. The decrease in free energy during the cell reaction in Zn / Zn
1M
0.1M

(a) 2.037 105 J

(b) 2.116 105 J

(c) 2.037 106 J

(d) 2.116 106 J

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Quiz
12. The Equilibrium constant for the reaction Zn Cu 2 Zn 2 Cu is
(a) 6.0 1036
(b) 1.94 1037
(c) 1.47 1038

(d) 7.0 1030

Comprehension 2
Many chemical and biological processes depend on osmosis, the selective passage of solvent molecules through porous
membrane from a dilute solution to a more concentrated one. The osmotic pressure depends on molar concentration of
the solution CRT . If two solutions are of equal solute concentration and, hence, have the same osmotic pressure,
they are said to be isotonic. If two solutions are of unequal osmotic pressure, the more concentrated solution is said to be
hypertonic and the more diluted solution is described as hypotonic.
Osmosis is the major mechanism for transporting water upward in the plants. Transpiration in the leaves supports the
transport mechanism of water. The osmotic pressure of sea water is about 30 atm; this is the pressure that must be applied
to the sea water (separated from pure water using semi permeable membrane) to get drinking water.
13. A plant cell shrinks when it is kept in:
(a) hypotonic solution
(b) hypertonic solution
(c) isotonic solution
(d) pure water
14. Isotonic solutions have same:
(a) density

(b) molarity

(c) molality

(d) mole fraction

15. Glucose solution to be injected into the bloodstream must have same .. as that of the bloodstream:
(a) molality
(b) vapour pressure
(c) osmotic pressure
(d) viscosity
Assertion and Reasoning
Directions: The questions (16 18) given below consists of STATEMENT 1 and STATEMENT 2. Use the following key
to choose the appropriate answer.
(a) Both STATEMENT 1 and STATEMENT 2 are true and STATEMENT 2 is correct explanation of STATEMENT 1
(b) Both STATEMENT 1 and STATEMENT 2 are true but STATEMENT 2 is not correct explanation of STATEMENT 1.
(c) STATEMENT 1 is true, STATEMENT 2 is false.
(d) STATEMENT 1 is false, STATEMENT 2 is true.
16.

STATEMENT 1:
STATEMENT 2:

17.

18.

0.1 M solution of NaCl has greater osmotic pressure than 0.1 M solution of glucose at same
temperature.
In solution, NaCl dissociates to produce more number of particles.

STATEMENT 1:

If standard reduction potential for the reaction Ag e Ag is 0.80 volts then for the reaction

STATEMENT 2:

3 Ag 3e 3Ag it will be 2.4 volts


If conc is increased reduction electrode potential is increased

STATEMENT 1:

Ni CO 4 is diamagnetic in nature and tetrahedral

STATEMENT 2:

Ni-atom undergoes sp3 hybridization

Part B
Match the following
M1.
COLUMN I
Reaction

COLUMN II
Product

Cu HNO3 dil

NO2

Zn HNO3 conc

N 2O

Cu HNO3 conc

Cu NO3 2

Zn HNO3 dil

Zn NO3 2

M2.
COLUMN I
(Solute)

COLUMN II
(Vant Hoff factor)

FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701

Quiz
A

K 4 Fe CN 6

1 2

Al 2 SO 4 3

Greater than 1

NH 2 C NH 2

1+ 4

CaCl2

||

M3.
COLUMN I
(Radicals)

COLUMN II
(Group reagents)

Pb 2

H 2S

Co 2

NH 4 Cl NH 4 OH

Fe3

HCl

Ba 2

NH 4 2 CO3

M4.
COLUMN I

COLUMN II

Cu NH3 4 SO 4

dsp

Pt NH3 2 Cl 2

Octahedral

K 4 Fe CN 6

sp3 d 2

Fe H 2 O 6 Cl3

Square planar

Part C
Numerical
N1.

N2.

1.22g of non volatile , non electrolyte solute (X) is dissolved in 100g benzene and elevation of boiling point
for this solution was found to be 0.13 K. Find the mol. wt of (X) if Kb for benzene is 2.6 kg K mol-1
Observation -1: NH 4 2 Cr2 O7 on heating, gives nitrogen gas and a green residue
Observation- 2: To a nitrate solution ferrous sulphate solution is added, precipitate if any is filtered off and
concentrated H 2 SO4 is poured along the sides. A dark brown ring is obtained at the junction of the two
liquids.
Observation- 3: When O3 is passed through mercury, it loses it meniscus and sticks to glass. This
phenomenon of mercury sticking to glass is called tailing of mercury.
Find out the sum of molecular masses of green residue in Observation-1, complex ion causing the brown ring
in Observation -2 and the compound responsible for tailing of mercury in Observation- 3 (Atomic mass of
Hg = 200).

FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701

Quiz

CHEMISTRY
1. A

2.D

3.D

4.D

5.D

6. A,B,C,D

7.A,C

8.B,C,D

9.A,C

10.A

11.A

12.A

13.B

14.B

15.C

16.A

17.D

18.B

M1.

A-R

B-P,S

C-P,R

D-Q,S

M2.

A-Q,R

B-Q,R

C-S

D-P,Q

M3.

A-P,R

B-P,Q

C-Q

D-Q,S

M4.

A-P,S

B-P,S

C-Q

D-Q,R

N1.0244

N2. 0744

FIITJEE CHENNAI CENTRE. 175 Poonamallee High Road. Opp. Ega Theatre, Kilpauk. Chennai-10 Ph. 044 - 42859701

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