AIEEE2006Paper

IMPORTANTINSTRUCTIONS:
1. TheAnswerSheetisKeptinsidetheTestBooklet.WhenyouaredirectedtoopentheTest
Booklet,takeouttheAnswerSheetandfillintheparticularscarefully.
2. Thetestisof3hoursduration.

3.

4. UseBlue/BlackBallPointPenonlyforwritingparticulars/markingresponsesonSide1andSide
2oftheAnswerSheet.Useofpencilisstrictlyprohibited
5. Nocandidateisallowedtocarryanytextualmaterial,printedorwritten,bitsofpapers,pager,
mobilephone,anyelectronicdevice,etc.,excepttheAdmintCardinsidetheexamination
hall/room.
6. RoughworkistobedoneonthespaceprovidedforthispurposeintheTestBookletonly.

7. Thereisonlyonecorrectresponseforeachquestion.Fillingupmorethanoneresponseineach
questionwillbetreatedaswrongresponseandmarksforwrongresponsewillbededucted
accordinglyasperinstruction6above.
8. OnCompletionofthetest,thecandidatemusthandovertheAnswerSheettotheInvigilatoron
dutyintheRoom/Hall.However,thecandidatedareallowedtotakeawaythistestbookletwith
them.
9. DonotfoldormakeanystraymarksonAnswerSheet.

PART1
8522
Q
No.
1.

(1)

(2)

(3)

(4)

8523 SupposeapopulationAhas100observations101,102...,200,andanotherpopulationBhas100
Q observations151,152...250.IfVAandVBrepresentthevariancesofthetwopopulations,
No. respectively,thenVA/VBis:
2.
(1) 1
(2)
(3)
(4)

9/4
4/9
2/3

8524
Q
No.
3.
(1)

(2)

(3)

(4)

8525
Q
No.
4.

(1)
(2)

1/2
3/2

(3)

(4)

8526
Q
No.
5.
(1)
(2)

4
6

(3)

(4)

8527
Q
No.
6.

(1)

(2)
(3)
(4)

Perpendicular
Parallel

8528
Q
No.
7.
(1)
(2)
(3)

Notreflexive,symmetricandtransitive
Reflexive,symmetricandnottransitive
Reflexive,symmetricandtransitive

(4)

Reflexive,notsymmetricandtransitive

8529
Q
No.
8.
(1)
(2)
(3)
(4)

A=B
AB=BA
EitherofAorBisazeromatrix
EitherofAorBisanidentitymatrix

8530
Q
No.
9.
(1)
(2)
(3)
(4)

I
1
1
i

8531 Allthevaluesofmforwhichbothrootsoftheequations
Q
2butlessthan4,lieintheinterval:
No.
10.
(1) 2
(2) m>3
(3) 1
(4) 1

8532
Q
No.
11.
(1)
(2)

aregreaterthan

(3)
(4)

8533 Atatelephoneenquirysystemthenumberofphonecallsregardingrelevantenquiryfollow
Q Poissondistributionwithanaverageof5phonecallsduring10minutetimeintervals.The
No. probabilitythatthereisatmostonephonecallduringa10minutetimeperiodis:
12.
(1)

(2)

(3)

(4)

8534
Q
No.
13.

(1)
(2)
(3)
(4)

8535
Q
No.
14.
(1)

(2)

720m
900m
320m
680m

(3)

(4)

8536 AstraightlinethroughthepointA(3,4)issuchthatitsinterceptbetweentheaxesisbisectedat
Q A.Itsequationis:
No.
15.
(1)
(2)
(3)
(4)

8537
Q
No.
16.
(1)
(2)
(3)

(4)

8538
Q
No.
17.
(1)

(2)

(3)

(4)

8539
Q
No.
18.

(1)

2and1

(2)

2and1

(3)

2and1

(4)

2and1

8540
Q
No.
19.

(1)

(2)

(3)

(4)

8541
Q
No.
20.
(1)

1/4

(2)
(3)
(4)

41
1
17/7

8542 Inanellipse,thedistancebetweenitsfociis6andminoraxisis8.Thenitseccentricityis:
Q
No.
21.
(1) 3/5
(2)
(3)

1/2
4/5

(4)

8543
Q
No.
22.
(1)
(2)
(3)
(4)

TherecannotexistanyBsuchthatAB=BA.
ThereexistmorethanonebutfinitenumberofB'ssuchthatAB=BA
ThereexistsexactlyoneBsuchthatAB=BA
ThereexistsinfinitelymanyB'ssuchthatAB=BA

8544
Q
No.
23.
(1)
(2)
(3)
(4)

8545
Q

x=2
x=1
x=0
x=1

No.
24.
(1)

(2)

(3)

(4)

8546
Q
No.
25.

(1)

(2)

(3)

(4)

8547
Q
No.
26.
(1)
(2)
(3)

(4)

8548
Q
No.
27.
(1)
(2)
(3)
(4)

8549 Atriangularparkisenclosedontwosidesbyafenceandonthethirdsidebyastraightriver
Q bank.Thetwosideshavingfenceareofsamelengthx.Themaximumareenclosedbythepark
No. is:
28.

(1)

(2)

(3)
(4)

8550 Atanelection,avotermayvoteforanynumberofcandidates,notgreaterthatthenumbertobe
Q elected.Thereare10candidatesand4aretobeelected.Ifavotervotesforatleastone
No. candidate,thenthenumberofwaysinwhichhecanvoteis:
29.
5040
(1)
(2)
(3)
(4)

6210
385
1110


8551
Q
No.
30.

(1)

(2)

(3)

(4)

8552
Q
No.
31.
(1)
(2)
(3)
(4)

8553
Q
No.
32.
(1)
(2)
(3)
(4)


8554
Q
No.
33.
(1)
(2)
(3)
(4)

8555
Q
No.
34.
(1)
(2)
(3)
(4)

8556
Q
No.
35.

(1)
(2)
(3)

(4)

8557
Q
No.

Secondorderandseconddegree
Firstorderandseconddegree
Firstorderandfirstdegree
Secondorderandfirstdegree

36.

(1)

(2)
(3)

(4)

8558 Theimageofthepoint(1,3,4)intheplanex2y=0is:
Q
No.
37.
(1)

(2)
(3)
(4)

None

8559
Q
No.
38.

(1)
(2)
(3)
(4)

8560

18
54
6
12

Q
No.
39.
(1)
(2)
(3)
(4)

8561
Q
No.
40.
(1)

(2)
(3)
(4)

PART2
8562
Q
No.
41.
(1)
(2)
(3)
(4)

8563 AmassofMkgissuspendedbyaweightlessstring.Thehorizontalforcethatisrequiredto
Q displaceituntilthestringmakesanangleof450withtheinitialverticaldirectionis:
No.
42.
(1)
(2)
(3)
(4)

8564 Abombofmass16kgatrestexplodesintotwopiecesofmassesof4kgand12kg.Thevelocity
Q ofthe12kgmassis4ms1.Thekineticenergyoftheothermassis:
No.
43.
(1) 96J
(2)
(3)
(4)

144J
288J
192J

8565 Aparticleofmass100gisthrownverticallyupwardswithaspeedof15m/s.Theworkdoneby
Q theforceofgravityduringthetimeparticlegoesupis:
No.
44.
(1) 0.5J

(2)
(3)
(4)

0.5J
1.25J
1.25J

8566 Awhistleproducingsoundwavesoffrequencies9500Hzandaboveisapproachingastationary
Q personwithspeedvms1.Thevelocityofsoundinairis300ms1.Ifthepersoncanhear
No. frequenciesuptoamaximumof10,000Hz,themaximumvalueofvuptowhichhecanhearthe
45. whistleis:
(1)
(2)
(3)
(4)

8567 Anelectricaldipoleisplacedatanangleof300toanonuniformelectricfield.Thedipolewill
Q experience:
No.
46.
(1) Atorqueonly
(2)
(3)
(4)

Atranslationalforceonlyinthedirectionofthefield
Atranslationalforceonlyinadirectionnormaltothedirectionofthefield
Atorqueaswellasatranslationalforce

8568 Amaterial'B'hasthespecificresistanceof'A'.Acircularwiremadeof'B'hastwicethediameter
Q ofawiremadeof'A'.Thenforthetwowirestohavethesameresistance,theratiolA/lBoftheir
No. respectivelengthsmustbe:
47.
(1) 2
(2)
(3)
(4)

8569
Q
No.

48.

(1)
(2)
(3)
(4)

conservationofcharge,conservationofenergy
conservationofcharge,conservationofmomentum
conservationofenergy,conservationofcharge
conservationofcharge,conservationofenergy

8570 Inaregion,steadyanduniformelectricandmagneticfieldsarepresent.Thesetwofieldsare
Q paralleltoeachother.Achargedparticleisreleasedfromrestinthisregion.Thepathofthe
No. particlewillbea:
49.
circle
(1)
(2)
(3)
(4)

helix
straightline
ellipse

8571 NeedlesN1,N2andN3aremadeofaferromagnetic,aparamagneticandadiamagneticsubstance
Q respectively.Amagnetwhenbroughtclosetothemwill:
No.
50.
Attractallthreeofthem
(1)
(2)

AttractN1andN2stronglybutrepelN3

(3)

AttractN1strongly,N2weaklyandrepelN3weakly

(4)

AttractN1stronglybutrepelN2andN3weakly.

8572
Q
No.
51.
(1)

Weber(Wb)

(2)
(3)

Henry(H)

(4)

8573 Aplayercaughtacricketballofmass150gmovingatarateof20m/s.Ifthecatchingprocessis
Q completedin0.1s,theforceoftheblowexertedbytheballonthehandoftheplayerisequalto:
No.
52.
300N
(1)
(2)
(3)
(4)

150N
3N
30N

8574 Aballofmass0.2kgisthrownverticallyupwardsbyapplyingaforcebyhand.Ifthehand
Q moves0.2mwhichapplyingtheforceandtheballgoesupto2mheightfurther,findthe
No. magnitudeoftheforce.Considerg=10m/s2.
53.
(1)
(2)
(3)
(4)

22N
4N
16N
20N

8575 Consideratwoparticlesystemwithparticleshavingmassesm1andm2.Ifthefirstparticleis
Q pushedtowardsthecentreofmassthroughadistanced,bywhatdistanceshouldthesecond
No. particlebemoved,soastokeepthecentreofmassatthesameposition?
54.
d
(1)
(2)

(3)

(4)

8576 Startingfromtheorigin,abodyoscillatessimpleharmonicallywithaperiodof2s.afterwhat
Q timewillitskineticenergybe75%ofthetotalenergy?
No.

55.
(1)

(2)

(3)

(4)

8577 Themaximumvelocityofaparticle,executingsimpleharmonicmotionwithanamplitude7mm,
Q is4.4m/s.Theperiodofoscillationis:
No.
56.
100s
(1)
(2)
(3)
(4)

0.01s
10s
0.1s

8578 Astringisstretchedbetweenfixedpointsseparatedby75cm.Itisobservedtohaveresonant
Q frequenciesof450Hzand315Hz.Therearenootherresonantfrequenciesbetweenthesetwo.
No. Then,thelowestresonantfrequencyforthisstringis:
57.
10.5Hz
(1)
(2)
(3)
(4)

8579
Q
No.
58.

(1)

105Hz
1.05Hz
1050Hz

(2)

(3)

(4)

8580 Therefractiveindexofglassis1.520forredlightand1.535forbluelight.LetD1andD2be
Q angleofminimumdeviationforredandbluelightrespectivelyinaprismofthisglass.Then:
No.
59.
(1)
(2)
(3)
(4)

8581 InaWheatstone'sbridge,thereresistancesP,QandRconnectedinthethreearmsandthefourth
Q armisformedbytworesistancesS1andS2connectedinparallel.Theconditionforbridgetobe
No. balancedwillbe:
60.

(1)

(2)

(3)

(4)

8582
Q
No.
61.

(1)
(2)
(3)
(4)

0.17A
0.33A
0.5A
0.67A

8583
Q
No.
62.
(1)
(2)
(3)
(4)

8584
Q
No.
63.

(1)
(2)
(3)

40V
250V

(4)

8585
Q
No.
64.
(1)
(2)
(3)
(4)

8586
Q
No.
65.
(1)
(2)
(3)
(4)

8587
Q
No.
66.
(1)
(2)
(3)
(4)

190V
190V
10V
10V

8588 Athermocoupleismadefromtwometals,AntimonyandBismuth.Ifonejunctionofthecouple
Q iskepthotandotheriskeptcoldthen,anelectriccurrentwill:
No.
67.
flowfromAntimonytoBismuthatcoldjunction
(1)

(2)
(3)
(4)

flowfromAntimonytoBismuthathotjunction
flowfromBismuthtoAntimonyatcoldjunction
notflowthroughthethermocouple

8589 Thetimebyaphotoelectrontocomeoutafterthephotonstrikesisapproximately:
Q
No.
68.
(1)
(2)
(3)
(4)

8590
Q
No.
69.
(1)
(2)
(3)

(4)

8591 Thethresholdfrequencyforametallicsurfacecorrespondstoanenergyof6.2eV,andthe
Q stoppingpotentialforaradiationincidentonthissurface5V.theincidentradiationliesin:
No.
70.
Xrayregion
(1)
(2)
(3)
(4)

Ultravioletregion
Infraredregion
Visibleregion


8592
Q
No.
71.

(1)

(2)

(3)

(4)

8593
Q
No.
72.
(1)
(2)
(3)
(4)

Neutrons
Alphaparticles
Betaparticles
Gammaparticles

8594 Asolidwhichistransparenttovisiblelightandwhoseconductivityincreaseswithtemperatureis
Q formedby:
No.
73.
Metallicbonding
(1)
(2)
(3)

Ionicbonding
Covalentbonding

(4)

VanderWaalsbinding

8595 Iftheratiooftheconcentrationofelectronsthatofholesinasemiconductoris7/5andtheratioof
Q currentsis7/4,thenwhatistheratiooftheirdriftvelocities?
No.
74.
(1)

(2)

(3)

(4)

8596
Q
No.
75.
(1)
(2)
(3)
(4)

48
49
50
51

8597
Q
No.
76.

(1)
(2)
(3)
(4)

8598
Q
No.
77.
(1)
(2)
(3)
(4)

8599
Q
No.
78.

(1)

(2)

(3)

(4)

8600 Iftheterminalspeedofasphereofgold(density=19.5kg/m3)is0.2m/sinaviscousliquid
Q (density=1.5kg/m3)ofthesamesizeinthesameliquid:
No.
79.
(1)
(2)
(3)
(4)


8601
Q
No.
80.
(1)
(2)
(3)
(4)

Monoatomic
Diatomic
Triatomic
Amixtureofmonoatomicanddiatomic

8602 ThermsvalueoftheelectricfieldofthelightcomingfromtheSunis720N/C.Theaveragetotal
Q energydensityoftheelectromagneticwaveis:
No.
81.
(1)
(2)
(3)
(4)

8603
Q
No.
82.
(1)
(2)

Atthehighestpositionforthefirsttime
Atthemeanpositionoftheplatform

(3)

(4)

8604 Anelectricbulbisrated220volt100watt.Thepowerconsumedbyitwhenoperatedon110
Q voltwillbe:
No.
83.
50watt
(1)

(2)
(3)
(4)

75watt
40watt
25watt

8605
Q
No.
84.

(1)

(2)

(3)

(4)

8606 The'rad'isthecorrectunitusedtoreportthemeasurementof:
Q
No.
85.
(1) therateofdecayofradioactivesource
(2)
(3)
(4)

8607
Q

theabilityofabeamofgammarayphotonstoproduceionsinatarget
theenergydeliveredbyradiationtoatarget
thebiologicaleffectofradiation

No.
86.

(1)
(2)
(3)
(4)

39.2MeV
28.24MeV
17.28MeV
1.46MeV

8608
Q
No.
87.

(1)

AllEc,Eg,EVdecrease

(2)

AllEc,,Eg,Evincreases

(3)

Ec,andEvincreasesbutEgdecreases

(4)

Ec,andEvdecreasesEgincreases

8609 Inthefollowing,whichoneofthediodesisreversebiased?
Q
No.
88.

(1)

(2)

(3)

(4)

8610
Q
No.
89.

(1)
(2)
(3)
(4)

8611
Q
No.
90.
(1)

(2)

(3)
(4)

8612
Q
No.
91.

1.33A
1.71A
2.00A
2.31A

(1)
(2)
(3)
(4)

8613
Q
No.
92.
(1)
(2)
(3)
(4)

Zero

8614 Tworigidboxescontainingdifferentidealgasesareplacedonatable.BoxAcontainsonemole
Q ofnitrogenattemperatureT0,whileboxBcontainsonemoleofheliumattemperature(7/3)T0.
No. Theboxesarethenputintothermalcontactwitheachotherandheatflowsbetweenthemuntilthe
93. gasesreachacommonfinaltemperature.(Ignoretheheatcapacityofboxes).Then,thefinal
temperatureofgases,Tf,intermsofT0is:

(1)

(2)

(3)

(4)

8615 TwosphericalconductorsAandBofradii1mmand2mmareseparatedbyadistanceof5cmand
Q areuniformlycharged.Ifthespheresareconnectedbyaconductingwiretheninequilibrium
No. condition,theratioofthemagnitudeoftheelectricfieldsatthesurfaceofspheresAandBis:
94.
(1)

(2)
(3)
(4)

8616
Q
No.
95.

(1)

1A

(2)
(3)
(4)

0.1A

8617
QNo.
96.

PART3
Thesmogisessentiallycausedbythepresenceof

(1)

O2andO3

(2)

O3andN2

(3)
(4)

oxidesofSulphurandNitrogen
O2andN2

8618 HBrreactswithCH2=CHOCH3underanhydrousconditionsatroomtemperaturetogive
QNo.
97.
CH3CHOandCH3Br
(1)
(2)

BrCH2CHOandCH3OH

(3)

BrCH2CH2OCH3

(4)

H3CCHBrOCH3

8619 TheIUPACnameofthecompoundshownbelowis
QNo.
98.

(1)
(2)
(3)
(4)

2bromo6chlorocyclohex1ene
6bromo2chlorocyclohexene
3bromo1chlorocyclohexene
1bromo3chlorocyclohexene

8620 TheincreasingorderoftherateofHCNadditiontocompoundsADis(A)HCHO(B)
QNo.
(C)
(D)PhCOPh
99.
(1)
(2)
(3)

A<B<C<D
D<B<C<A
D<C<B<A

(4)

C<D<B<A

8621 Howmanymolesofmagnesiumphosphate,Mg3(PO4)2willcontain0.25moleofoxygen
QNo. atoms?
100.
0.02
(1)
(2)
(3)
(4)

3.125x102
1.25x102
2.5x102

8622 AccordingtoBohr'stheory,theangularmomentumofanelectronin5thorbitis
QNo.
101.
(1)

(2)

(3)

(4)

8623 Whichofthefollowingmolecules/ionsdoesnotcontainunpairedelectrons?
QNo.
102.
(1)
(2)
(3)
(4)

8624 Totalvolumeofatomspresentinafacecentrecubicunitcellofametalis(risatomicradius)
QNo.
103.
(1)

(2)

(3)

(4)

8625 Areactionwasfoundtobesecondorderwithrespecttotheconcentrationofcarbon
QNo. monoxide.Iftheconcentrationofcarbonmonoxideisdoubled,witheverythingelsekeptthe
104.
same,therateofreactionwill
(1)
(2)
(3)
(4)

remainunchanged
triple
increasebyafactorof4
double

8626 WhichofthefollowingchemicalreactionsdepictstheoxidizingbehaviorofH2SO4?
QNo.
105.
(1)
(2)
(3)
(4)

8627 TheIUPACnameforthecomplex[Co(NO2)(NH3)5]Cl2is
QNo.
106.
nitritoNpentaamminecobalt(III)chloride
(1)
(2)
(3)
(4)

8628

nitritoNpentaamminecobalt(II)chloride
pentaamminenitritoNcobalt(II)chloride
pentaamminenitritoNcobalt(III)chloride

Thetermanomersofglucoserefersto

QNo.
107.
(1)
(2)
(3)
(4)

isomersofglucosethatdifferinconfigurationsatcarbonsoneandfour(C1andC4)
amixtureof(D)glucoseand(L)glucose
enantiomersofglucose
isomersofglucosethatdifferinconfigurationatcarbonone(C1)

8629
QNo.
108.
(1)
(2)
(3)
(4)

8630 Phenylmagnesiumbromidereactswithmethanoltogive
QNo.
109.
amixtureofanisoleandMg(OH)Br
(1)
(2)
(3)
(4)

amixtureofbenzeneandMg(OMe)Br
amixtureoftolueneandMg(OH)Br
amixtureofphenolandMg(Me)Br

8631
QNo.
110.

(1)

D>C>A>B

(2)

D>C>B>A

(3)

A>B>C>D

(4)

B>D>C>A


8632 ThepyrimidinebasespresentinDNAare
QNo.
111.
cytosineandadenine
(1)
(2)
(3)
(4)

cytosineandguanine
cytosineandthymine
cytosineanduracil

8633 AmongthefollowingtheonethatgivespositiveiodoformtestuponreactionwithI2and
QNo. NaOHis
112.
CH3CH2CH(OH)CH2CH3
(1)
(2)

(3)

(4)

PhCHOHCH3

8634 Theincreasingorderofstabilityofthefollowingfreeradicalsis
QNo.
113.
(1)
(2)
(3)
(4)

8635 Uncertaintyinthepositionofanelectron(mass=9.1x1031kg)movingwithavelocity300
QNo. ms1,accurateupto0.001%,willbe
114.
(h=6.63x1034Js)

(1)
(2)
(3)
(4)

19.2x102m
5.76x102m
1.92x102m
3.84x102m

8636
QNo.
115.

(1)

(2)

(3)

(4)

8637
QNo.
116.

(1)

thedissociationenergyofH2andenthalpyofsublimationofcarbon

(2)

latentheatofvaporizationofmethane

(3)
(4)

thefirstfourionizationenergiesofcarbonandelectrongainenthalpyofhydrogen
thedissociationenergyofhydrogenmolecule,H2

8638 Amongthefollowingmixtures,dipoledipoleasthemajorinteraction,ispresentin
QNo.
117.
benzeneandethanol
(1)

(2)
(3)
(4)

acetonitrileandacetone
KClandwater
benzeneandcarbontetrachloride

8639 Fluorobenzene(C6H5F)canbesynthesizedinthelaboratory
QNo.
118.
byheatingphenolwithHFandKF
(1)
(2)

fromanilinebydiazotisationfollowedbyheatingthediazoniumsaltwithHBF4

(3)

bydirectfluorinationofbenzenewithF2gas

(4)

byreactingbromobenzenewithNaFsolution

8640 Ametal,Mformschloridesinits+2and+4oxidationstates.Whichofthefollowing
QNo. statementsaboutthesechloridesiscorrect?
119.
MCl2ismorevolatilethanMCl4
(1)
(2)

MCl2ismoresolubleinanhydrousethanolthanMCl4

(3)

MCl2ismoreionicthanMCl4

(4)

MCl2ismoreeasilyhydrolysedthanMCl4

8641 Whichofthefollowingstatementsistrue?
QNo.
120.
H3PO3isastrongeracidthanH2SO3
(1)
(2)

InaqueousmediumHFisastrongeracidthanHCl

(3)

HClO4isaweakeracidthanHClO3

(4)

HNO3isastrongeracidthanHNO2

8642
QNo.
121.

(1)

(2)
(3)
(4)

8643 Whichoneofthefollowingsetsofionsrepresentsacollectionofisoelectronicspecies?
QNo.
122.
K+,Cl,Ca2+,Sc3+
(1)
(2)
(3)
(4)

Ba2+,Sr2+,K+,S2
N3,O2,F,S2
Li+,Na+,Mg2+,Ca2+

8644
QNo.
123.

(1)
(2)
(3)
(4)

b<d<a<c
d<a<c<b
d<a<b<c
a<d<c<b

8645 Inwhichofthefollowingmolecules/ionsareallthebondsnotequal?
QNo.
124.
SF4
(1)
(2)

SiF4

(3)

XeF4

(4)

BF4

8646 Whatproductsareexpectedfromthedisproportionationreactionofhypochlorousacid?
QNo.
125.
HClO3andCl2O
(1)
(2)

HClO2andHClO4

(3)

HClandCl2O

(4)

HClandHClO3

8647
QNo.
126.

(1)
(2)
(3)
(4)

one,tetrahedral
two,tetrahedral
one,squareplanar
two,squareplanar

8648
QNo.
127.
(1)
(2)
(3)

ioniccharacter

(4)

8649 TheincreasingorderofthefirstionizationenthalpiesoftheelementsB,P,SandF(lowest
QNo. first)is:
128.
F<S<P<B
(1)
(2)

P<S<B<F

(3)

B<P<S<F

(4)

B<S<P<F

8650 Anidealgasisallowedtoexpandbothreversiblyandirreversiblyinanisolatedsystem.If
QNo.
istheinitialtemperatureandTfisthefinaltemperature,whichofthefollowingstatementsis
129.
correct?
(1)

(Tf)irrev>(Tf)rev

(2)

Tf>TiforreversibleprocessbutTf=Tiforirreversibleprocess

(3)

(Tf)rev=(Tf)irrev

(4)

Tf=Tiforbothreversibleandirreversibleprocesses

8651 InLangmuir'smodelofadsorptionofagasonasolidsurface:
QNo.
130.
therateofdissociationofadsorbedmoleculesfromthesurfacedoesnotdependonthe
(1)
surfacecovered
(2)
(3)
(4)

theadsorptionatasinglesiteonthesurfacemayinvolvemultiplemoleculesatthesametime
themassofgasstrikingagivenareaofsurfaceisproportionaltothepressureofthegas
themassofgasstrikingagivenareaofsurfaceisindependentofthepressureofthegas

8652 RateofareactioncanbeexpressedbyArrheniusequationas:
QNo. k=AeE/RTInthisequation,Erepresents:
131.
theenergyabovewhichallthecollidingmoleculeswillreact
(1)
(2)
(3)
(4)

8653
QNo.
132.

theenergybelowwhichcollidingmoleculeswillnotreact
thetotalenergyofthereactingmoleculesatatemperature,T
thefractionofmoleculeswithenergygreaterthantheactivationenergyofthereaction

(1)

(2)

(3)

(4)

8654 Reactionoftrans2phenyl1bromocyclopentaneonreactionwithalcoholicKOHproduces:
QNo.
133.
(1)4phenylcyclopentene
(1)
(2)
(3)
(4)

(2)2phenylcyclopentene
(3)1phenylcyclopentene
(4)3phenylcyclopentene

8655 Increasingorderofstabilityamongthethreemainconformations(i.e.Eclipse,Anti,Gauche)
QNo. of
134.
2fluoroethanolis:
(1)
(2)
(3)

Eclipse,Gauche,Anti
Gauche,Eclipse,Anti
Eclipse,Anti,Gauche

(4)

Anti,Gauche,Eclipse

8656 Thestructureofthecompoundthatgivesatribromoderivativeontreatmentwithbromine
QNo. wateris:
135.

(1)

(2)

(3)

(4)

8657 ThedecreasingvaluesofbondanglesfromNH3(106o)toSbH3(101o)downgroup15ofthe
QNo. periodictableisdueto:
136.
increasingbpbprepulsion
(1)
(2)
(3)
(4)

8658
QNo.
137.

increasingporbitalcharacterinsp3
decreasinglpbprepulsion
decreasingelectronegativity

(1)

(2)

(3)

(4)

8659
QNo.
138.
(1)
(2)
(3)
(4)

8660
QNo.
139.

2.84
4.90
0
1.73

(1)

416

(2)
(3)
(4)

8661 Followingstatementsregardingtheperiodictrendsofchemicalreactivityofthealkalimetals
QNo. andthehalogensaregiven.Whichofthesestatementsgivesthecorrectpicture?
140.
Thereactivitydecreasesinthealkalimetalsbutincreasesinthehalogenswithincreasein
(1)
atomicnumberdownthegroup
(2)

Inboththealkalimetalsandthehalogensthechemicalreactivitydecreaseswithincreasein
atomicnumberdownthegroup

(3)

Chemicalreactivityincreaseswithincreaseinatomicnumberdownthegroupinboththe
alkalimetalsandhalogens

(4)

Inalkalimetalsthereactivityincreasesbutinthehalogensitdecreaseswithincreasein
atomicnumberdownthegroup

8662
QNo.
141.

(1)
(2)
(3)

8.12
8.612
37.83

(4)

16.13

8663
QNo.
142.

(1)
(2)
(3)
(4)

1
0
3
2

8664 Lanthanoidcontractioniscauseddueto:
QNo.
143.
Theappreciableshieldingonouterelectronsby4felectronsfromthenuclearcharge
(1)
(2)
(3)
(4)

Theappreciableshieldingonouterelectronsby5delectronsfromthenuclearcharge
ThesameeffectivenuclearchargefromCetoLu
Theimperfectshieldingonouterelectronsby4felectronsfromthenuclearcharge.

8665
QNo.
144.

(1)
(2)
(3)
(4)

8666 Theionicmobilityofalkalimetalionsinaqueoussolutionismaximumfor:
QNo.
145.
(1)

(2)
(3)
(4)

8667
QNo.
146.
(1)
(2)
(3)
(4)

8668
QNo.
147.

(1)
(2)
(3)
(4)

14.6kJmol1
16.8kJmol1
16.8kJmol1
244.8kJmol1

8669 HowmanyEDTA(ethylenediaminetetraaceticacid)moleculesarerequiredtomakean
QNo. octahedralcomplexwithCa2+ion?
148.
Six
(1)
(2)
(3)

Three
One

(4)

Two

8670
QNo.
149.

(1)

(2)

(3)

(4)

8671 18gofglucose(C6H12O6)isaddedto178.2gofwater.Thevapourpressureforthisaqueous
QNo. solutionat1000Cis:
150.
759.00Torr
(1)
(2)
(3)
(4)

7.60Torr
76.00Torr
752.40Torr