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For AIEEE/PMET/PPMET

CHAPTER : CHEMICAL BONDING & MOLECULAR STRUCTURE


Q.1 shape and hybridisation of IF5
(a) trigonal bi-pyramidal, sp3d (b) see saw, sp3d (c) square pyramidal, sp3d2 (d) pentagonal pyramidal, sp3d3
Q.2 the bond angle and dipole moment of water are
(a) 109.5, 1.84 D (b) 107.5 , 1.56 D (c) 104.5, 1.84 d (d) 102.5 , 1.56 D
Q.3 the calculated bond order of superoxide ion (O2-) is (a) 1.5 (b) 1 (c) 2.5 (d) 2
Q.4 the number of nodal planes present in s* antibonding orbital is (a) 0 (b) 3 (c) 1 (d) 2
Q.5 which of the following pairs of species have the same bond order (a) O2-, CN- (b) NO+, CN+ (c) CN-, NO+ (d) CN-, CN+
Q.6 which one of the following constitutes a group of the iso-electronic species
(a) CN-, N2, O22-, C22- (b) N2, O2-, NO+, CO (c) C22-, O2-, CO, NO (d) NO+, C22-, CN-, N2
Q.7 the angular shape of ozone molecule (O3) consists of
(a) 1 sigma and 2 pi-bonds (b) 2 sigma and 2 pi-bonds (c) 1 sigma and 1 pi-bond (d) 2 sigma and 1 pi-bond
Q.8 one of the following examples exhibits transient existence (a) H (b) H2+ (c) H+ (d) He|
Q.9 shape of ClF3 is (a) equilateral tringle (b) pyramidal (c) V-shaped (d) T-shaped
Q.10 the magnetic moment of KO2 at room temperature is ______BM (a) 1.41 (b) 1.73 (c) 2.23 (d) 2.64
Q.11 which of the following is correctly based on molecular orbital theory for peroxide ion
(a) its bond order is 2 and it is diamagnetic (b) its bond order is 1 and it is paramagnetic
(c) its bond order is 2 and it is diamagnetic (d) its bond order is 1 and it is diamagnetic
Q.12 which of the following is paramagnetic with bond order 0.5 (a) F2 (b) H2+ (c) N2 (d) B2
Q.13 the hybridisation of oxygen atom in H2O2 is (a) sp3d (b) sp (c) sp2 (d) sp3
Q.14 in TeCl4, the central atom, Te, involves in the hybridisation (a) sp3 (b) sp3d (c) sp3d2 (d) dsp2
Q.15 the %age of p-character in the orbitals forming P-P bonds in P4 is (a) 25 (b) 33 (c) 50 (d) 75
Q.16 the species having bond order different from that of CO is (a) NO- (b) NO+ (c) CN- (d) N2
Q.17 bond order of nitric oxide is (a) 1 (b) 2.5 (c) 2 (d) 1.5
Q.18 the no. of lone pairs of electrons present on the central atom of ClF3 is (a) 0 (b) 1 (c) 2 (d) 3
Q.19 hydrogen bonding is strongest in (a) S-HO (b) O-H..S (c) F-H..F (d) O-H..N
Q.20 the correct order regarding the electronegativity of hybrid orbitals of carbon is
(a) sp < sp2 > sp3 (b) sp < sp2 < sp3 (c) sp > sp2 < sp3 (d) sp > sp2 > sp3
Q.21 which of the following is least volatile (a) HF (b) HBr (c) HCl (d) HI
Q.22 the electronegativity difference between N & F is greater than that between N & H yet the dipole moment of NH3 is
larger than that of NF3. This is because
(a) in NH3 as well as NF3, the atomic & bond dipole are in the same direction
(b) in NH3, the atomic dipole & bond dipole are in same direction while in NF3, these are in opposite direction
(c) in NH3 as well as NF3, the atomic & dipole moment are in opposite direction
(d) in NH3, the atomic & bond dipole are in the opposite direction while in NF3 atomic & bond dipole are in same direction
Q.23 the decreasing value of bond angles from ammonia to SbH3 down the group is due to
(a) increasing bp-bp repulsion (b) increasing p-orbital character in sp3
(c) decreasing lp-lp repulsion (d) decreasing electronegativity
Q.24 what type of bonding is present in Na2 (g) (a) covalent bond (b) ionic bond (c) metallic bond (d) molecular bond
Q.25 which of the following has zero dipole moment (a) ClF (b) PCl3 (c) SiF4 (d) CFCl3

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